PRELIMINARY CHEMISTRY PROGRAM MODULE: WEEK 1 2. METALS SYLLABUS OUTCOMES TEACHING STRATEGIES & ACTIVITIES Jacaranda Chemistry 1 Page Reference 6. Metals and Alloys The History of Metals Chapter 6 1. Gather and process data in the uses of metals such as copper, magnesium, lead and titanium throughout history. 2. Use examples of modern and historical furnaces to identify that metals can only be obtained from ores by the input of energy. 3. Identify the emergence of new technologies that were responsible for the greater use of metals in the last two centuries. Relate the production of active metals to the discovery of electrolysis. 4/5. Use a time line to analyse gathered information about the ages of metals and alloys. Relate this chronology to improvements in designs of furnaces and the discovery of electricity. DATA ANALYSIS 6.1 -- Timeline: the History of Copper Revision Questions - Jacaranda Chemistry 1. Set 6.1 1. 109-111 The History of Metals 1. Outline and examine some uses of different metals through history, including contemporary uses, as uncombined metals or as alloys. 2. Explain why energy input is necessary to extract a metal from its ore. 3. Identify why there are more metals available for people to use now than there were 200 years ago. 4. Analyse information to relate the chronology of the Bronze Age, the Iron Age and the modern era and possible future developments. 5. Gather information from secondary resources by summarising and collating information from a range of resources Sign 2. 112-113 3. 114- 115 4/5. 111-114 124-125 Revision 6.1 Pages 116-117 1 Alloys Alloys 6. Describe the use of common alloys including steel, brass and solder and explain how these relate to their properties. 7. Gather, process, analyse and present information from secondary sources on the range of alloys produced and the reasons for the production and use of these alloys. 6. Use particle diagrams to compare the compositions of common alloys such as steel, brass and solder. 7. Use gathered data to analyse the properties and uses of a range of alloys. DATA ANALYSIS 6.2- The Melting Points of Solders 6. 117- 121 7. 118-121 126 Revision Questions - Jacaranda Chemistry 1. Set Revision 6.2 Pages 122-123 6.2 2 Chapter 7 7. Metals and reactions Metals and their reactivity 8. Describe observable changes when metals react with dilute acid, water and oxygen. 9. Describe and justify the criteria used to place metals into an order of activity based on their ease of reaction with oxygen, water and dilute acids. 10. Identify the reaction of metals with acids as requiring the transfer of electrons. 11. Perform a first-hand investigation incorporating information from secondary sources to determine the metal activity series. Metals and their reactivity 8. Demonstrate the relative reactivity of metals such as magnesium and iron (steel wool) in water, dilute acid and when heated in oxygen. Describe the observations made. 9. Use data concerning the reactivity of metals in water, acid and oxygen to develop an activity series of metals. 10. Write half-equations and ionic equations to describe electron loss and gain when metals react with acids. 11. PRACTICAL ACTIVITY 7.1 The activity series of metals 8. 128-130 9. 130-131 10. 131 11. 138-139 2 3 12. Construct word and balanced formulae equations for the reaction of metals with water, oxygen, dilute acid. 13. Construct half-equations to represent the electron transfer reactions occurring when metals react with dilute hydrochloric and dilute sulfuric acids. 14. Present information by using symbols and formulae to express relationships and using appropriate units for physical quantities. 12. Write word and whole formula equations for the reactions of metals with water, dilute acids and oxygen. 13. Write ionic-electron half equations for reactions of metals with dilute acids. 14. Use symbols and formulae correctly. Reactivity and uses of metals 15. Outline examples of the selection of metals for different purposes based on their reactivity, with a particular emphasis on current developments in the use of metals. 16. Identify the importance of first ionisation energy in determining the relative reactivity of metals. 17. Outline the relationship between the relative activities of metals and their positions on the Periodic Table. 18. Present information by using a variety of pictorial representations to show relationships and presenting information clearly and succinctly. Reactivity and uses of metals 15. Tabulate the properties and uses of selected metals such as magnesium, aluminium, titanium, zinc, tin and copper. 16. Define the term "ionisation energy" and uses tabulated data to compare the relative activity of metals. 17/18. Use an outline map of the periodic table to map the zones of reactive and unreactive metals. 12. 128-130 13. 131 14. 128-131 Revision Questions - Jacaranda Chemistry 1. Set Revision 7.1 Pages 131- 132 7.1 Chapter 7 15. 132- 133 16. 133-135 17/18. 135-136 Revision Questions - Jacaranda Chemistry 1. Set Revision 17.2 Pages 136-137 7.2 3 4 8. The Periodic Table The historical development of the Periodic Table 19. Identify an appropriate model that has been developed to describe atomic structure. 20. Outline the history of the development of the Periodic Table including its origins, the original data used to construct it and the predictions made after its construction. 21. Process information from secondary sources to develop a Periodic Table by recognising patterns and trends in the properties of elements and use available evidence to predict the characteristics of unknown elements both in groups and across periods. Periodic Trends 22. Explain the relationship between the position of elements in the Periodic Table, and: electrical conductivity; ionisation energy; atomic radius; melting point; boiling point; combining power (valency); electronegativity; reactivity 23. Use computer-based technologies to produce a table and a graph of changes in one physical property across a period and down a group. The historical development of the Periodic Table Chapter 8 19. Use diagrams to explain Bohr's theory of the atom. 20. Draw up a timeline to analyse the history of the periodic table. Exercises should be based on analysing original data (where possible) to show the development of ideas. 21. Process supplied data to develop a Periodic Table . Use the structure of the table to solve problems related to trends in various properties. DATA ANALYSIS 8.1 - Modelling the periodic table Revision Questions - Jacaranda Chemistry 1. Set 8.1 Periodic Trends 22. Describe and explain the following trends in properties in the periodic table: electrical conductivity; ionisation energy; atomic radius; melting point; boiling point; combining power (valency); electronegativity; reactivity 23. Process supplied data on the changes in a physical property across a period and down a group. DATA ANALYSIS 8.2- Computer graphingperiodic trends Revision Questions - Jacaranda Chemistry 1. Set 8.2 19. 137 20. 138-143 21. 154-155 Revision 8.1 Pages 143- 144 22. 144-150 23. 151 156 Revision 8.2 Page 152 4 5 9. Chemical Analysis Atomic weight and the mole theory 24. Define the mole as the number of atoms in exactly 12g of carbon-12 (Avogadro’s number). 25. Compare mass changes in samples of metals when they combine with oxygen. 26. Describe the contribution of Gay-Lussac to the understanding of gaseous reactions and apply this to an understanding of the mole concept. 27. Recount Avogadro’s law and describe its importance in developing the mole concept. 28. Process information from secondary sources to interpret balanced chemical equations in terms of mole ratios. 29. Solve problems and analyse information from secondary sources to perform calculations involving Avogadro’s number and the equation for calculating the number of moles of a substance: n m M 30. Process information from secondary sources to investigate the relationship between the volumes of gases involved in reactions involving a metal and relate this to an understanding of the mole. Atomic weight and the mole theory Chapter 9 24. Develop and understanding of mass and quantity using the terms atomic weight, molecular weight and the mole. Define the term "mole". Show weighed samples of a mole of various elements and compounds. 25. Analyse problems involving weight changes when metals react with oxygen to form oxides. 26. Describe the work of Gay-Lussac on combing gas volumes and apply these ideas to the mole concept. 27. State Avogadro's Law and relate this law to Gay-Lussac experiments and Dalton's atomic weight scale. 28/29. Write balanced equations and solve problems related to mass and moles using the 24. 158-160, 164 formula: n 25. 159-161 26. 161-162 27. 162-165 28/29. 165-168 30. 176 m M 30. Analyse second hand data to demonstrate GayLussac's law and relate this to mole theory. DATA ANALYSIS 9.2 - Moles and volumes of gases Revision Questions - Jacaranda Chemistry 1. Set Revision 9.1 9.1 Page 169 5 6 Empirical and molecular formulae 31, Distinguish between empirical formulae and molecular formulae. 32. Perform a first-hand investigation to measure and identify the mass ratios of metal to non-metal(s) in a common compound and calculate its empirical formula. Empirical and molecular formulae 31. Use examples such as hydrogen peroxide, ethylene and ethyl acetate to distinguish between empirical and molecular formulae. 32. PRACTICAL ACTIVITY 9.1 - The empirical formula of magnesium oxide 10. Extraction and the recycling of metals Ores and resources 33. Distinguish between ores and minerals. Use data to explain why some ores are economic whilst others are not. 34. Discuss the economics of metal production with reference to location and size of the ore body, concentration of metal in the ore body, yield, costs of extraction and mine establishment costs; world metal prices. 35. Describe ores as non-renewable resources because they cannot be reformed once used. 36. Use examples and solve problems to establish that prediction of yield is important in the decision to extract a metal from an ore. DATA ANALYSIS 10.1- The viability of mining a vanadium ore deposit Revision Questions - Jacaranda Chemistry 1. Set 10.1 Ores and resources 33. Define the terms mineral and ore with reference to economic and non-economic deposits of natural resources. 34. Describe the relationship between the commercial prices of common metals, their actual abundances and relative costs of production. 35. Explain why ores are non-renewable resources. 36. Discuss the importance of predicting yield in the identification, mining and extraction of commercial ore deposits. Chapter 9 31. 170-173 32. 175 Revision Questions - Jacaranda Chemistry 1. Set Revision 9.2 Pages 173-174 9.2 Chapter 10 33. 178 34. 179-182 35. 178 36. 180-181 191-192 Revision 10.1 Page 182 6 7 Extraction and recycling 37. Describe the separation processes, chemical reactions and energy considerations involved in the extraction of copper from one of its ores. 38. Recount the steps taken to recycle aluminium. 39. Justify the increased recycling of metals in our society and across the world. 40. Analyse information to compare the cost and energy expenditure involved in the extraction of aluminium from its ore and the recycling of aluminium. 8 GENERAL REVISION Extraction and recycling 37. Identify some copper ores and use a flow chart to describe the separation of copper metal from chalcopyrite. 38. Using aluminium as an example, construct a flow chart for the recycling of aluminium. 39. Describe reasons why metals should be recycled. 40. DATA ANALYSIS 10.2- Recycling aluminium and steel. Revision Questions - Jacaranda Chemistry 1. Set 10.2 CD- Preliminary MODULE 2 - REVISION QUESTIONS - Chapters 6,7,8,9 and 10 Use the supplied set of questions to revise all of Module 2. 15 Multiple Choice and 20 open-ended questions in the style of the HSC are available. Model answers are available on the CD. Chapter 10 37. 183-188 38. 188-189 39. 188 40. 192-193 Revision 10.2 Page 190 CD Preliminary MODULE 2 REVISION QUESTIONS REVISION SETS PROBLEM SOLVING SETS CD- MODULE 2 REVISION SET Two sets of ten short and long answer questions based on Module 2. Set 3- Extraction of metals and alloys Set 4- Reaction of metals and periodic table trends 7 CD- MODULE 2 PROBLEM SOLVING SETS Five problem-solving worksheets are available. Set 3- Combining volumes of gases and Avogadro's Law Set 4- Molecular weight and percentage composition Set 5- Empirical and molecular formulae Set 6- Mole calculations A Set 7- Mole calculations B Worked answers are supplied. 8