MODEL MATCHING TREATED EFFLUENT QUALITY TO NON – POTABLE WATER REUSES IN SOUTH AFRICA J.R. Adewumia, A.A. Ilemobadea and J.E. van Zylb a School of Civil and Environmental Engineering, University of the Witwatersrand, Johannesburg. South Africa b Department of Civil Engineering Science, University of Johannesburg, South Africa ABSTRACT: Growing environmental awareness and increasing freshwater resources scarcity has given rise to the use of treated effluent as an unconventional source of water supply in many arid and semiarid regions of the world in which South Africa can be classified. To ensure environmental sustainability, food security and to promote economic growth, the society will be compelled to adopt treated effluent reuse strategies. However, the amount of treated effluent that can be reclaimed for reuse is highly dependent on a number of factors, ranging from technical to socioeconomic and institutional conditions. Technically, if the treated effluent quality from a treatment works is to meet all potential end uses, it is necessary that the quality be satisfactory. If however, several units are involved in the treatment processes, with each unit producing different effluent qualities, it is necessary that scenarios be built to appropriately match the qualities required for different potential end uses and the treated effluent quality produced. This is necessary to determine if further treatment is needed to meet users’ requirements and to protect public health. Planning this is a very complex exercise, which needs to consider the selection of additional treatment processes required to achieve the desired effluent quality and the selection of possible end-users with differing quantity and quality requirements. In any case, the use of adequate tools to build scenarios is paramount. Facilities ranging from Decision Support Systems to the simplest analytical tools could help the stakeholders to select the best match between the user’s quality requirements and the effluent quality and take the final decision whether the scheme can be implemented or not. This paper provides a systematic framework for the analysis of potential treated effluent reuse under various driving forces and constraints. The input data for this model includes information on water quality requirements for different types of end users of treated effluent, design and costing of additional treatment unit process, suggestions for treatment matrix that could be used and the rules for combining unit processes. This model will guide the responsible authority to take the most economical reuse option in any locality based on the existing wastewater treatment infrastructure. Keywords: Potential uses; Quality requirements; Support tool; Wastewater reuse Sub-theme: Water and Environment Corresponding author: E-mail address: James.Adewumi@students.wits.ac.za (J.R.Adewumi) 1 1.0 INTRODUCTION As both industry and populations continue to increase, there is an increase in wastewater generation in urban areas and a great decrease in freshwater availability. Community concerns about environmental pollution resulting from the quality of wastewater disposed to sensitive environments has led to pressures on water industry to treat wastewater to a higher level before discharge to receiving rivers or streams. As this trend continues, wastewater reuse is gaining popularity as an unconventional source of non-potable water in different countries around the world. While the nutrients in wastewater can assist plant growth when reused for irrigation, their disposal, in extreme cases, is detrimental to ecosystems of the receiving environment. Also, water scarcity experienced globally has led to the embracing of wastewater, salinewater and greywater reuse in many large urban areas in regions previously considered to have sufficient water sources like China (Junying et al, 2004, Weizhen and Andrew, 2003), Japan (Dixon et al, 1999), Germany (Nolde, 1999), United Kingdom (UKEA, 2000) and the United States of America (Okun, 1996). A large part of South Africa is predominantly located in a semi-arid part of the world with a mean annual precipitation of about 450 mm, which is well below world average of about 860 mm per annum. This low quantity of precipitation is highly uneven and also accompanied with high evaporation rates which make the country’s water resources extremely limited and scarce. Also, the surface runoff is highly variable and stream flow in South African rivers is at relatively low levels for most of the time thereby, limiting the proportion of stream flow that can relied upon to be available for use without adverse effect on the aquatic plants and animals (DWAF, 2004). The scarcity of water in South Africa is also aggravated by pollution of the surface and groundwater resources. An indication of the pollution pressure on South African freshwater resources could be found in Vaal Barrage catchment that supplies freshwater to Gauteng province. The catchment receives 859 Ml/d of domestic effluents, 240 Ml/d of mine effluents and about 100Ml/d of industrial effluents (NSER, 2007). This results in increase in phosphate, chemical oxygen demand (COD), ammonium, suspended solids, faecal coliforms, sulphate, metals (manganese, aluminium, iron) and a decrease in pH of the Vaal River. Also, in the City of Cape Town, algae blooms and geosmin in the raw water is increasingly becoming problematic, particularly at Theewaterskloof, Voelvlei, Steenbras and Constantia Nek. (CCT, 2007). 2.0 OVERVIEW OF WASTEWATER TREATMENT DECISION SUPPORT SYSTEMS Several contributions have been made in wastewater treatment plant design by the use of computer programs. Many of these programs simulate treatment trains, evaluate, screen and select the optimum treatment scheme using different techniques to generate and screen unit process combinations. Computer technologies have been adopted in solving specific problems in the field of wastewater treatment by adopting routine computational techniques (Chang and Liaw, 1985; Gasso, et al, 1992). With the growth and confidence in algorithm development and optimization techniques, more sophisticated problems are solved using various research tools like Monte Carlo simulation (Chen and Beck, 1997), expert systems (Ahmed et al, 2002; Economopoulou and Economopoulos, 2003), integer programming (Balkema et al, 2001), stepwise approach with genetic algorithm (Jaksimovic et al, 2006; Jasmovic, et al, 2008) and multi criteria analysis (Hidalgo, 2007). Most of these models based their evaluation on technical functionality and economic factors without detailed consideration of other important factors like environmental and socio-cultural factors while suggestions for complete treatment modules were 2 based on local conditions which limit their practical applications globally. However, Eliss and Tang (1990) and Tang and Ellis (1994) considered many other factors in their model but it proves to be too ambiguous to use in other locations because of their non-flexibility. The objective of this study is to present a model for selecting treatment unit processes that will treat municipal wastewater to the quality required to meet end uses. This model will use multi-criteria factors in selecting optimum treatment processes suitable in any local condition. 2.1 Components of a Wastewater Treatment Decision Support System In general, Decision Support System models have three system components namely: knowledge base, user interface or control module and reasoning engine. Knowledge base The knowledge base is encoded in the form of case based and rules. The case based reasoning is a computer based problem solver which uses the solution from an established case to solve existing problems. A set of rules are formulated and coded to allow the system deduce new results from the initial set of cases. The robustness of any model highly depends on the information (number of unit process, cost, etc.) contained in the knowledge base. Most of the models developed to simulate treatment trains for wastewater reuse have a limited number of unit processes with limited number of rules that describe the acceptable combinations of unit processes in treatment trains. Reasoning engine This is the thinking machine of the system dealing with the solving of the problem by interpreting the knowledge activated by case based and rules. With the help of any suitable advance computing programming language, the developed algorithm is coded for easy interpretation by computer. User interface The user interface provides interactive access to the input and output. Modifications can be made easily and the results immediately updated during the design process. It includes natural communication medium with the users, reasoning explanation interface, other information entered by the users and computing results. The information required in the Input unit is the basic data about the operating systems and constraints and includes the characteristics of wastewater (BOD, TS, TSS, N, P FC, heavy metals, etc.), land requirements, energy consumption and the proposed water reuse purposes and quantities. In the output unit, information such as optimum treatment schemes, the estimated capital and operational costs are displaced for the users. 2.2 Indicators For Selecting Wastewater Treatment Wastewater treatment process schemes are categorized as a function of the raw wastewater quality and the disposal methods or intended reuse application. Different indicators have been used in the past to generate, screen and select treatment trains in wastewater. The most common ones are based on technical and economic considerations of the unit process. However, other important factors have been included in recent times. For example, in addition to economic life cycle cost, Metcalf and Eddy Inc. (2003) outline 23 important factors that should be considered in the evaluation and selection of wastewater treatment facilities. In Eliss and Tang (1990); Tang and Ellis (1994); Lundin et al., (1999); Mels et al., (1999) and Balkema et al., (2001), multidisciplinary sets of sustainability indicators that include technical, economic, environmental and socio-cultural have been used in the selection of treatment trains for domestic and municipal wastewater. The differences in indicators used by various researchers depend on the methodology 3 used in the selection of the preferred alternatives as well as the goals and scope of the work (i.e. methods of disposal – reuse or no reuse). From a practical point of view, the rates at which physical, chemical and biological reactions and conversions occur are important as they will affect the size of the treatment facilities that must be provided. The fundamental basis for evaluating the efficiency of technologies used in wastewater treatment is the materials mass balance principle in which an account of mass is made before and after reactions and conversions have taken place. 3.0 MODEL TO MATCH WASTEWATER TREATMENT TRAINS TO NONPOTABLE WATER REUSES To assist the decision makers in selecting suitable wastewater treatment systems, knowledge of the efficiency of a wide range of treatment trains should be provided in an unambiguous manner for adaptation and interpretation according to the local situation. The starting point of building wastewater treatment trains is the definition of potential reuse applications. In the South African context, municipal wastewater can be reused for industrial (cooling, boiler feed and process water), domestic (toilet flushing, garden/ lawn irrigation and cleaning), landscape and recreational irrigation (Urban), construction and Agricultural irrigation purposes. These reuse options require water of different quality which can be achieved by using specific method of treatment, depending on the source quality. In all situations, a series of treatment processes is needed to achieve the required water quality for reuse through a system analysis approach in which one chooses from a wide variety of unit operations using case based rules with suggestions on new combinations for comparing alternatives. When considering treatment for a reuse system, the overriding concern continues to be whether the quality of the treated effluent is appropriate for the intended use. Higher level uses, such as toilet flushing, irrigation of public-access lands or vegetables to be consumed without processing, require a higher level of wastewater treatment and reliability prior to reuse than with lower level uses, such as irrigation of forage crops and restricted access area irrigation. For instance, in urban settings, where there is a high potential for human exposure to reclaimed water used for landscape irrigation, industrial purposes, and toilet flushing, the reclaimed water must be clear, colourless, and odourless to ensure that it is aesthetically acceptable to the users. To ensure minimum health risk to the public, it must also be free from pathogens. As the first step in developing this model, all realistic processes involved in wastewater treatment schemes in the South African context are described with special attention to their efficiency in removing constituents to meet the water quality requirements for various reuse applications. A clear distinction is made between primary, secondary and advanced treatment processes, which includes both conventional and innovative options as shown in Table 1. Table 1: Unit process operations included in the model Treatment Unit Process Preliminary Bar Screen Comminution Grit chamber Coarse screen Primary Sedimentation w/o Coagulant 4 Secondary Tertiary Disinfection Sedimentation w/ Coagulant Anaerobic ponds Activated sludge + Secondary sedimentation Trickling filter + Secondary sedimentation Rotating Biological Contractors + Secondary sedimentation Membrane bioreactor Stabilization Pond: Aerobic ponds Stabilization Pond: Anaerobic ponds Stabilization Pond: facultative ponds Biological phosphorus removal P-precipitation Constructed Wetland Denitrification Maturation pond Dual media filter Micro filtration Ultra filtration Nano filtration Reverse osmosis Soil Aquifer Treatment (SAT) Activated carbon Ion exchange Advanced oxidation process Electrodialysis Chemical precipitation Chlorine gas Chlorine dioxide UV radiation Ozone 3.1 Selection of Treatment Trains The combination of unit processes shown in Table 1 to form treatment train is not a very simple design process. Therefore, a selection has to be made among the treatment unit processes to form standard treatment trains for reuse purposes. The assemblage of the treatment train from individual unit processes is simulated using a well developed algorithm. The selection model is developed using MATLAB and provides a user-friendly graphical interface consisting of forms used in editing the input and output data and the display of results. The model uses a project file to store the knowledge base and user entered information. The basic data contained in the knowledge base are water quality requirements for different types of end uses of treated effluent, design and costing information on unit processes, suggestions for treatment trains that could be used for influent quality/end use combinations, rules for combining units processes and the design costing information for the distribution system components. The end users of treated effluent in South Africa are classified into six different groups as shown in Table 2. The classification is based on the current treated wastewater reuse applications in the country. The key steps in the development of the knowledge base is the collection of information on individual unit processes that could be used to form treatment trains to be evaluated. Such 5 information includes allowable influent quality design criteria, process efficiencies for a series of pollutants, land and labour requirements, sludge and concentrate production, cost estimates and preference scoring on the qualitative evaluation criteria. All this information is displayed to the decision makers in a series of editable forms, which allow them to review all the information and alter the calculations to suit their conditions. Table 2: Reuse activities of treated effluent in South Africa Reuse Type Description of Reuse Domestic Toilet flushing, garden/ lawn irrigation, home air conditioning systems, car washing and cleaning Landscape and Recreational Open access landscape areas like school fields, parks, golf Irrigation (Urban) courses, sport fields, etc Industrial Industrial cooling, boiler feed and process water except for food industries Construction Blocks and concrete making and laying, dust suppression, composting site, etc. Agricultural Irrigation (unrestricted) Irrigation of raw consumed food crops, fruit trees sprinkler irrigation, greenhouse crop irrigation, etc. Agricultural Irrigation (restricted) Irrigation of pasture for milking or meat animals, fodder, cereals, fibres, seed crops and other areas where public access is prohibited. 3.2 Treatment Scheme Performance Various processes could be adopted for treatment of municipal wastewater. In this model, the developed wastewater treatment trains will produce effluent of sequentially improved characteristics suitable for reuse in different applications as shown in Fig 1. A removal efficiency of individual process modules has been developed based on the performance of local treatment plants and as reported in the literatures (Ahmed et al. 2002, Metcalf and Eddy (2003) and AQUAREC, 2006). 6 Preliminary Primary Secondary Restricted Irrigation Environmental enhancement Construction Tertiary Unrestricted irrigation Urban & domestic use Disinfection Disinfection Bar screen Comminution Grit removal Low Rate Processes Stabilization pond: Anaerobic Stabilization pond: Aerobic Stabilization pond: facultative Constructed wetland Sedimentation Membrane filtration Anaerobic pond High Rate Processes Rotary biological contactors Activated sludge Trickling filter Membrane Bioreactor Sec. Sedimentation Dissolved Solids Removal Dual media filter Micro filtration Ultra filtration Nano filtration Reverse osmosis Soil aquifer treatment Phosphorus & Nitrogen Removal Biological phosphorus removal Constructed wetland Maturation pond P-precipitation Organics & Metals Removal Advance oxidation process Chemical precipitation Activated carbon Ion exchange Electrodialysis Sludge processing Disinfection Industrial Urban & domestic Disposal Fig 1: Wastewater treatment options for various reuse application Optimization Module 3.3 As shown in Table 1, the knowledge base included in this model consists of 34 treatment unit processes. Evaluating all possible combinations of these unit processes will yield large number of total possible combinations. However, the analysis of wastewater reuse options can be conducted in places where some treatment of wastewater is already existing using the municipal wastewater treatment works. In this regard, the treatment works would be considered as the source of the effluent for reuse. In this case, rules incorporated in this model will restrict the search space. In general, the quality of effluent from municipal wastewater treatment works can be classified as either secondary or primary effluent depending on the existing level of treatment. To conduct a simultaneous search of the least cost design alternatives based on the best selection of end users combination and other sustainability indicators (technical, economics, environmental and sociocultural), the optimization algorithm used is a genetic algorithm (GA). GA is a search technique used in computing to find exact or approximate solutions to optimization and search problems. Combinations and sequences chosen entirely at random are not feasible and practicable in getting the desired quality output in an economically feasible space. With the given details of the set of treatment unit, rules must be defined for combining these to make a complete treatment module 7 that will transfer materials across the entire wastewater infrastructure. Fig 2 shows the computational algorithm adopted in this model. Start Wastewater quality Available treatment technologies Reuse options A Define rules for forming treatment matrix No All options ranked? Yes All possible treatment schemes and reuse options considered? No Select the best options Printout Yes Generate all feasible options End Simulate the performance of each option No All feasible options simulated? Yes Criteria and rules for ranking and grouping options A Fig 2: Computational algorithm 4.0 CONCLUSIONS Planning a wastewater reuse system is a complex exercise which requires the selection of treatment processes required to achieve the desired effluent quality. To enable decision makers to choose suitable wastewater treatment systems, there must be a good understanding of the best combination of treatment units to form a treatment matrix in a sustainable manner. Therefore, a decision support system is being developed to compare a wide range of alternative treatment schemes evaluate on technical, economic, environmental and socio-cultural grounds to produce water of suitable qualities for particular purposes under prevailing conditions and constraints. The developed tool will allow efficient exploration of design alternatives to be conducted to assist decision makers in the development of highly efficient wastewater reuse schemes. 8 5.0 REFERENCES AQUAREC (2006): “Handbook on feasibility studies for water reuse systems” www.aquarec.org accessed on 13th December, 2007 Juying C, Jining C, Can W and Ping F (2004): “wastewater reuse potential analysis: implications for China water resources management” Water Research Vol. (38) 2746 – 2756 Wizhen L, Andrew Y T (2003): “A preliminary study on potential developing shower/ laundry wastewater reclamation and reuse system” Chemosphere Vol. (52) 1451 – 1459 Dixon A, Butler D and Fewkes A (1999): “Water saving potential of domestic water reuse systems using greywater and rainwater combination” Water Science Technology Vol. (39) 25 – 32 Nolde E (1999): “Greywater reuse systems for toilet flushing in multi – storey buildings – over ten years experience in Berlin” Urban Water Vol. (1) 275 – 284 UK Environmental Agency (UKEA) (2000): “A study of domestic greywater recycles” Okun D A (1996): “Distributing reclaimed water through dual systems” Journal of America Water Works Association Vol. (89) 52 – 64 Department of Water Affairs and Forestry (DWAF) (2004): “National water resources strategy” Pretoria, South Africa National State of Environmental Report on freshwater systems and resources http://www.environment.gov.za/soer/nsoer/issues/water/pressure.htm#climate accessed 11 November 2007 City of Cape Town (2007): “Treated effluent re-uses strategy and master planning within the city of Cape Town” Chang, S. Y. and Liaw, S. L. (1985): “Generating designs for wastewater systems”, Journal of Environmental Engineering, 111(5), 665-679 Gasso, S., Baldasano, J. M. and Celades, C. (1992): Plant design and economic for wastewater treatment plant via the CAD/CAE system SIMTAR, Water Science Technology, 25(4/5), 411-412 Chen, J and Beck, M. B. (1997):” Towards designing sustainable urban wastewater infrastructure: A screening analysis”, Water Science Technology, 35(9), 99-112 Ahmed, S. A., Tewfik, S. R. and Talaat, H. A. (2002): “Development and verification of a decision support system for the selection of optimum water reuse schemes”, Desalination, Vol. (152) 339-352 Economopoulou, M. A. and Economopoulos, A. P. (2003): “Expert system for municipal wastewater management with emphasis on reuse” Water Science and Technology: Water Supply 3(4) 79-88 Balkema, A. J., Preisig, H. A., Otterpohi, R., Lambert, A. J. D. and Weijers, S. R. (2001): “ Developing a model based decision support tool for the identification of sustainable treatment options for domestic wastewater”, Water Science and Technology 43(7) 265-269 Jaksimovic, D., Kubir, J., Hlavinec, P., Savic, D. and Walters, G. (2006): “Development of an integrated simulation model for treatment and distribution of reclaimed water”, Desalination, Vol. (118) 9-20 Jaksimovic, D., Savic, Walters, G., Bixio, D., K. Katsoufidou and Yiantsios S. G. (2008): “Development and validation of system design principles for water reuse systems”, Desalination, Vol. (218) 142-153 Hidalgo, D., Hirsuta, R, Martinez, L., Fatta, D. and Papadopoulos (2007): “Development of a multi-function software decisión support tool for the promotion of the safe reuse of treated urban wastewater”, Desalination, Vol. (215) 90-103 9 Ellis, K. V. and Tang, S. L. (1990): “Wastewater treatment optimization model for developing world, I model development, Journal of Environmental Engineering Vol. (117) 501-518 Ellis, K. V. and Tang, S. L. (1994): “Wastewater treatment optimization model for developing world, II model testing, Journal of Environmental Engineering Vol. (120) 610-624 Metcalf and Eddy Inc. (2003): “Wastewater Engineering Treatment and Reuse” 4th edition, Written and revised by Tchobanoglous, G. and Burton, F. L., McGraw-Hill, New York. Lundin, M., Molander, S. and Morrison, G. M. (1999): A set of indicators for assessment of temporal variations in sustainability of sanitary systems”, Water Science and Technology 39(5) 235-242 Mels, A. R., Nieuwenhuijzen, A. F., Graaf, J. H. J. M., van der and Klapwijk, B.(1999): “ Sustainability criteria as a tool in the development of a new sewage treatment methods”, Water Science and Technology 39(5) 243-250 10