CHEMISTRY LAB: DENSITY OF SOLUTIONS (DENSOLN.DOC) 1. Introduction: The more solid material that is dissolved in a solution, the more dense is the solution. If given the opportunity, the more dense of two solutions naturally settles to the bottom. (After a long period of time, natural random motion of the particles mixes the two solutions until no difference can be detected.) These facts can be used to detect which of several solutions is the most dense, and least dense, and the correct order of all the solutions of intermediate density. 2. Safety: Do not drink or taste any material while in lab. These chemicals are generally considered safe, but you never know who has used what before you. If a spill stains your clothing, rinse it out immediately with tapwater; any residue of food coloring dye should come out in the wash at home. Wear your lab apron to protect your clothing just in case. Goggles are not necessary in this lab, but the saltwater would sting if it got in your eyes: rinse it out immediately with tapwater. Do not return any chemical solutions to any stock bottles; this will avoid contamination for others. You may dispose of any leftover solutions down the drain. Rinse the glassware with tapwater. Rinse your hands before you leave the lab. 3. Materials and Supplies Needed: a. From the prep area: Samples of four salt solutions, color-coded with food coloring One clear glass tubing section about 15 to 20 cm long, fire-polished, or a translucent drinking straw b. From the lab station supply cupboard: Test tube rack with test tubes 4. Procedure: a. Getting Ready. Use four test tubes to obtain samples of the four colored salt solutions from the preparation area. A test tube approximately half full will be plenty of solution. Place some tap water in a fifth test tube to use to rinse the glass tube or straw between uses. b. Learning the Technique. Samples of the solutions can be collected in the glass tube as follows. Place your index finger over the upper end of the open glass tube or straw. Grasp the tube between your thumb and the other three fingers. Now you can hold the tube and open or close the top all with one hand. If you insert the tube into a solution to a depth of a centimeter or so and then open it by lifting your index finger, the solution will rush in. If you now seal it with your fingertip and lift, you can remove a small sample of that solution from that test tube. You can now add a second solution: if you lower it about two centimeters into the second solution and release your finger, the second solution will rush in to the tube which already contains the first solution. If the second solution is more dense than the first, two distinct stable colored layers will be seen. (It may help if you hold a piece of white paper behind the tube.) But if the first solution was more dense than the second, it will try to change places with the second (lower) solution, and mixing will occur. You will then not see layers. c. Conducting Tests of Density. Repeated testing of pairs of solutions should enable you to work out which solution is most dense, next most dense, second lightest, and least dense. d. Final Check. As a final test of your mastery of logic and technique, fill one tube with all four solutions so that the layers can clearly be seen, and call me over quickly to see it. But you will already know if you are right because if you have any in the wrong order, they will mix and you won’t see four layers very long! 5. Data: Record your data on your data sheet. 6. Clean-up: Liquid: Dispose of all liquid down the drain. Test-tubes: Rinse test tubes with water, using test-tube brush as needed. Return all other materials to the central area or as your teacher directs. Remember to wash you hands when you are finished. 2 Density Rainbow Lab- Data Sheet Results of Tests of Two Solutions at a Time: Trial: Top: Bottom: Stable/Mixed: Conclusion: 1 2 3 4 5 6 7 8 9 10 11 12 Conclusion: Based on an analysis of the results above, and as confirmed by the stacking of all four solutions, the order of the solutions from top to bottom is: Color: Position: Relative Density: __________ __________ __________ __________ __________ __________ __________ __________ __________ __________ __________ __________ *** Certification: I saw the tube with the four solutions in it, all in the correct order. Teacher’s Signature _________________ 3 LAB SET-UP- Density Rainbow Translucent plastic straws actually work better than 6 mm glass tubing, and are nonbreakable. In two-liter bottles, make up four color-coded saltwater solutions. Use food coloring. Use kosher salt, or chemically pure sodium chloride, to prevent the cloudiness caused by the anti-caking agent in regular table salt. Since this is not a quantitative lab, measurements can be approximate. For two liters of each solution, use the indicated number of scoops of salt. (The "scoop" is a 50-ml beaker.) Color of solution: blue red yellow green Scoops of NaCl per 2000 ml: none one two three LABELS: Density of Solutions: Blue Density of Solutions: Red Density of Solutions: Yellow Density of Solutions: Green 4