Pre-Lab Requirements 1. 2. 3. 4. 5. 6. 7. 8. 9. Read the entire lab before you begin Set up headings and add the lab to your table of contents Write your purpose. In your own words, write a few statements that describe why you are doing the lab Write your method. In your own words, write a few statements that summarize the procedure for Part A and Part B Complete vocabulary and answer any pre-lab questions Transfer materials into your lab notebook Procedure: See lab sheet For both Part A and Part B identify both the independent and dependent variables Design data tables for both Part A and Part B. Be sure to use a straight edge ** Notice there are two parts to the lab, complete Part A & B together under purpose, method, and vocabulary. ***Remember to always write in 3rd person. Lab 1 Investigating the Activity Series of Metals Part A Alkaline Earth Metals Purpose: The arrangement of the elements in the periodic table is one of the most important achievements in modern chemistry. The physical and chemical properties of elements change in a regular pattern as you go both across the rows and down the columns of the periodic table. One of the properties that change in a regular pattern within this group is the ability to form a precipitate, or solid substance, as a result of a chemical reaction. The precipitate cannot dissolve in water and eventually settles to the bottom of the container. Method: You will be combining alkaline earth metal solutions with potassium solutions to discover which alkaline earth metal reacts most often (most reactive) and which reacts the least often (least reactive). This will enable you to conclude the relationship between placement in the periodic table within a group and ability to react. Vocabulary: precipitate period group activity series Find a copy of an activity series and print one out. Paste (or tape) the activity series into your lab notebook. Materials: safety goggles sheet of notebook paper calcium nitrate {Ca(NO3)2} barium nitrate {Ba(NO3)2} potassium sulfate {K2SO4} spot plate magnesium nitrate {Mg(NO3)2} strontium nitrate {Sr(NO3)2} potassium carbonate {K2CO3} potassium chromate {K2CrO4} Procedure: 1. Place the spot plate in the center of a sheet of notebook paper so that there are 4 spots running down and 3 spots running across. You will need to perform this procedure 2 times for accuracy. Are there enough clean spots to use in the spot plate or should you perform, wash, and then perform again? 2. Along the side of the notebook paper next to each of the four spots, write the names of the four alkaline earth metals that are present in each nitrate compound listed in the materials you are using. Along the top of the notebook paper write the names of each of the three potassium compounds you are using. See figure below. carbonate sulfate chromate Ba Sr Ca Mg 3. Put on your safety goggles. Place several drops of potassium carbonate in each of the four spots under the word “carbonate”. Place several drops of potassium sulfate in each of the four spots under the word “sulfate”. Place several drops of potassium chromate in each of the four spots under the word “chromate”. Be very careful not to mix the liquid from one spot with the liquid from another. 4. Take the dropper of magnesium nitrate and place several drops in each of the three spots in the row labeled “magnesium”. Observe each spot carefully and record the result in the data table. Repeat this procedure using the dropper battles containing calcium, strontium, and barium. Be careful not to mix the liquid from one spot with the liquid from another. 5. After recording your results, wash your spot plate thoroughly with a brush. Do you have a total of 2 sets of results? Analysis: Was there evidence of a chemical reaction occurring in any of the spots? Explain. If the ability of an alkaline earth element to form a precipitate is an indication of its ability to chemically react with other substances, which is the most reactive element? the least reactive element? Conclusions: How does the order of the alkaline earth metals from most reactive to least reactive compare with their order in the periodic table? Based on the investigation, list the alkali metals (group IA) in order from most reactive to least reactive. If there is a solution containing a mixture of calcium and strontium, how could the two elements be separated? (HINT: precipitates can be filtered) Part B Transition Metals Purpose: The purpose of this lab is to arrange several metals in the periodic table in order of their activity. A metal is said to be more active than another metal if it will replace the less active metal from a solution of one of its compounds. Method: Students will test zinc, copper, and lead to see if they will replace one another in solutions of their compounds in order to develop a list of metals in order of their activity. Materials: copper sulfate Zinc sulfate Lead Nitrate Procedure: 1. Arrange the nine test tubes in three groups of three each. Using a piece of paper, label three test tubes “lead nitrate”, three “zinc sulfate”, and three “copper sulfate” 2. Fill the appropriately labeled three test tubes one-fourth full of lead nitrate solution. Repeat for the zinc sulfate and the copper sulfate. 3. Place a strip of lead in each of the three compound solutions, lead nitrate, copper sulfate, and zinc sulfate. Repeat for strips of zinc and copper. 4. After several (maybe 10 or more?) minutes, remove the strips from the solutions with a tweezers and examine them for evidence of a reaction. Record your observations in the data table. Analysis: lead strip (3 cm) zinc strip (3 cm) copper strip (3 cm) 9 small test tubes test-tube rack safety goggles List the metals in order of decreasing activity. How can it be determined which of the three metals is the most active? Compare your list of metals to the activity series of metals. Conclusion: Magnesium is more active than zinc. How would a strip of magnesium have reacted in each of the three solutions in this investigation? Tin is less active than zinc but more active than lead. How would a strip of tin have reacted in each of the three solutions in this investigation? If a strip of silver does not react with any of the three solutions tested in this investigation, what must be true about silver? Describe how it could be determined if iron is more active than copper. If a strip of silver turns dark in a nickel nitrate solution, what is true? If Rb does not react in a copper nitrate solution, what is true? Is it possible to determine the reactivity of a transition metal by looking at its location on the periodic table?