[Geophysical Research Letters] Supporting Information for [Abrupt Intensification of North Atlantic Deep Water formation at the late Pliocene climate transition] [Masahiko Sato1,2*, Masato Makio2, Tatsuya Hayashi3, Masao Ohno2] [1Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology, Tsukuba 305-8567, Japan, 2Department of Environmental Changes, Faculty of Social and Cultural Studies, Kyushu University, Fukuoka 819-0395, Japan, 3Mifune Dinosaur Museum, Kumamoto 861-3207, Japan] Contents of this file Figures S1 to S4 Additional Supporting Information (Files uploaded separately) Captions for Table S1 Figures S1 and S2 To convert the depth of core into ages, we used the method of Hayashi et al. [2010]. They constructed a hybrid environmental proxy of the U1314 sediments by combining magnetic susceptibility (χ) and natural gamma radiation (NGR), in which glacial– interglacial variations are extracted and the small-scale variations (attributed to icerafted debris) are eliminated. They tuned the hybrid environmental proxy record between 188.0 and 262.5 mcd to the global-standard oxygen isotope curve (LR04 δ18O stack record) [Lisiecki and Raymo, 2005], and established the age model during the period 2.1–2.75 Ma. This paper applied the same method as used in Hayashi et al. [2010] to 188.0–299.2 mcd data, and extend the age model up to 2.91 Ma (Figure S1). We constructed an age model of IODP Site U1314 sediments by tuning the χ + NGR index record between 188.0 and 299.2 mcd to the LR04 δ18O stack record between the marine oxygen isotope stage (MIS) 80 and the MIS G13 with the use of an automated graphic correlation software, Match 2.0 [Lisiecki and Lisiecki, 2002]. We ran the Match 2.0 software with the same parameter values as used in Hayashi et al. [2010], other than the tie points. In our age model, the additional tie point was given at 299.15 mcd 1 with 2.875 Ma (at the bottom of the core) and the tie point given at 262.45 mcd with 2.755 Ma (at the bottom of the age model in Hayashi et al. [2010]) was removed. As the result, the age model in this study clearly differs before 2.69 Ma from the age model of Hayashi et al. [2010], although a very subtle difference between them exists from around 2.62 Ma to 2.69 Ma. There was no hiatus reported throughout the study interval [Expedition 306 Scientists, 2006], and the obtained age-depth curve shows smooth change in sedimentation rate throughout the study interval. Therefore, it seems unlikely that about 40 kyr (an obliquity cycle) are add to or subtracted from the age of the sediments. Although there is a negative (downward in the figure) excursion in the normalized χ + NGR index at around MIS G8 in our age model, which is not seen in the LR04 stack, the negative excursion is clearly seen at around MIS G8 in the benthic δ18O data from the North Atlantic (Figure 2 in Bartoli et al., [2005]). The age model for the Site U1314 will be improved by future δ18O analyses. Reference Lisiecki, L. E., and P. A. Lisiecki, (2002), Application of dynamic programming to the correlation of paleoclimate records, Paleoceanography, 17(4), 1049, doi:10.1029/2001PA000733. 2 Figure S1. (a) Normalized x + NGR index vs. sediment depth of spiced section. (b) LR04 global benthic δ18O stack [Lisiecki and Raymo, 2005]. Numbers indicate marine oxygen isotope stage. Tie points are show as TP1–TP4. (c) Normalized χ + NGR index (green curve) is tuned to normalized LR04 global benthic δ18O stack (red curve). 3 Figure S2. Age-depth plot of the automated tuning result (solid curve). The dashed line indicates the age-depth model of Hayashi et al. [2010]. Tie points (TP1–TP4) are show as grey circles. Figure S3 Grützner and Higgins [2010] measured the X-ray fluorescence of Gardar Drift sediments (IODP Site U1314) and reported changes in the terrigenous province during the last 1.1 Ma. During the interglacial periods, vigorous Iceland–Scotland Overflow Water (ISOW) flowed south over the Iceland–Faroe Ridge and delivered high amounts of basaltic material (low K/Ti) to the Gardar Drift. Conversely, during the glacial periods, the core of the ISOW shoaled and sedimentation at depth of site U1314 became influenced by the acidic sediment (high K/Ti) transported by the Northeast Atlantic Deep Water (NEADW) and/or Lower Deep Water (LDW) flow. For 39 samples of the U1314 sediment, we measured Ti and K contents using an EDX800 Energy Dispersive X-ray Fluorescence Spectrometer (SHIMADZU) at Kyushu University. The relationship between the fraction of component 1 and the Ti/K ratio showed a clear positive correlation (Figure S3), while data at around the marine oxygen isotope stage (MIS) G9 slightly deflected from this trend, thus indicating that the fraction of component 1 represents the fraction of basaltic components. 4 1.5 Ti/K 1 0.5 0 0 0.2 0.4 0.6 0.8 Component 1 fraction (%) 1 Figure S3. Relationship between the fraction of component 1 and the Ti/K ratio. Data from interval 2.33–2.73 Ma are shown in red color. Data at around the MIS G9 (2.77–2.80 Ma) are shown in black color. Figure S4 Fraction of component 1 calculated from isothermal remanent magnetization (IRM) gradient curves, the LR04 global benthic δ18O stack [Lisiecki and Raymo, 2005], and IRM intensity normalized by mass are plotted as a function of age in Figure S3a, S3b, and S3c. Mode, median, and mean of IRM gradient curves are also plotted as a function of age in Figure S3d, S3e, and S3f. The component fraction data show the clear periodic variations, which are not apparent in the raw coercivity data such as the mode, median, mean of IRM gradient curves. 5 Figure S4. (a) The fraction of component 1. (b) The LR04 global benthic δ18O stack [Lisiecki and Raymo, 2005]. Numbers indicate the marine oxygen isotope stage. Shaded areas mark warmer climate intervals. (c) The IRM intensity. (d) Mode, (e) median, and (f) mean of IRM gradient curves. Table S1 Fraction of component 1 (C1) and component 2 (C2), integral of residual curve (R), IRM intensity (Mr), and mode, median, and mean of IRM gradient curves are summarized in Table S1. 6