PHOENICS – EU project http://phoenics.chemistry.uoc.gr/organic_aerosol Organic Aerosol Workshop Best Western Hotel Villa Carlotta, Belgirate, Italy. Sunday 21 (10:00)- Tuesday 23 (17:00) September 2003 PRELIMINARY AGENDA Sunday 21/9/2003 (10:00-18:00) 10:00-10:15 Frank Dentener welcome - Mrs Carol Jackson practical information 10:15-10:30 Sandro Fuzzi - Announcement of the OA joint workshop by IGAC/SOLAS/ELIPSE spring 2004 and other related IGAC activities Maria 10:30-11:00 Kanakidou & Frank Dentener (Introduction –The PHOENICS project Objectives of the workshop and how to achieve them) 11:00-11:30 Coffee break Laboratory studies (rapporteurs; Ian Barnes, Jens Hjorth, Th. Hoffmann) Major Questions to be discussed (shortly introduced by the rapporteurs) Secondary Organic Aerosol formation: Chemical formation mechanisms. Lumping into categories Chemical reactivity and change in hygroscopicity of OA What do we know on physico-chemical/ thermodynamic properties of OA species and of the complex organic –inorganic mixtures present in atmospheric aerosol? (water activity coefficient, solubility etc.)? Discussion presentations (20min + 5 min questions): 11:30-11:45 11:45-12:10 Ian Barnes : Aromatic hydrocarbon aerosol formation: some new endeavours 12:10-12:35 Thorsten Hoffmann Summary of OSOA results 12:35-14:30 Lunch break 14:30 -14:55 Borris Bonn et al. : Atmospheric SOA formation from biogenic terpenes - laboratory nucleation thresholds and aerosol mass yields using a global chemistry model 14:55-15:20 Luisa Marelli Photo-oxidation of VOC: Organic aerosol yields and their hygroscopic properties. 15:20-15:45 Richard Winterhalter et al. Gas-particle partitioning of terpene-ozonolysis products 15:45-16:00 Thomas Peter (only 1st day): Short review on organics and put this in perspective with its own ice measurements 16:00-16:30 Coffee break 16:30-16:55 Erik Swietlicki Hygroscopic Growth, Critical Supersaturations and Thermodynamic Modelling for Mixed Aerosol Particles of Inorganic and Organic Compounds of Atmospheric Relevance 16:55-17:20 Johannes Schneider Organics aerosol measurements with the Aerodyne Aerosol Mass Spectrometer (AMS): Results from field and lab studies. 17:20-18:00 General discussion- What do we urgently need to know and how can we address the topics (contributors all participants) Monday 22/9/2003 (9:30-18:00) Field studies (rapporteurs: Rita van Dingenen, Spyros Pandis, Cristina Facchini) 9:30-9:45 Major Questions to be discussed (shortly introduced by the rapporteurs) Phenomenology of organic aerosol (microscope picture/coating etc) What do we learn on OA from single particle analysis/ state of mixing? Chemical composition of OA sampling techniques (primary/secondary) Heterogeneous reactions producing + modifying OA species and properties Optical properties measurements Discussion presentations (20min + 5 min questions): 9:45- 10:10 Euripides Stephanou: Field Studies: A useful tool for the elucidation of SOA formation - Sampling and chemical characterization of OA: How well is done and what do we learn from it? 10:10-10:35 Stefano Decesari, Organic functional groups analysis by Nuclear Magnetic Resonance spectroscopy: An overview of the results on WSOC composition (coauthros M-C. Facchini, M. Mircea, F. Cavalli, S. Fuzzi, E. Tagliavini) 10:35-11:00 Christian Dye: Aerosol work within EMEP 11:00-11:30 Coffee break 11:30-11:55 M. Cristina Facchini: A new insight on organics in marine aerosol and consequences on cloud micro physics and climate 11:55-12:20 Jean Philippe Putaud: Measurement techniques and aerosol mass closure studies 12:20-12:40 short -general discussion- points to be raised after lunch 12:30-14:30 Lunch break 14:30-14:55 Claus Jørgen Nielsen: New results on the optical properties of different aerosol constituents 14:55-15:20 M.O. Andreae: Biomass burning aerosols in SMOCC 15:20-16:00 General discussion - continues 16:00-16:30 Coffee break 16:30-16:45 Model studies - Introduction of the modelling session by the rapporteurs (rapporteurs: Elisabetta Vignati, Barbara Ervens, Athanassios Nenes) Major Questions to be discussed (shortly introduced by the rapporteurs) Chemical formation of OA and properties (lumping): how can we simplify the system without missing critical information complex organic inorganic mixtures for the different aerosol types (marine, urban, rural, etc)? Role of organics in nucleation in the atmosphere: How important is, when and where, nucleation of organics is occurring? Optical properties of OA representation in models (lumping) Cloud processing of organic aerosols. Modelling on regional and global scales. Direct effect. Modelling on regional and global scales. Indirect effect The best way of comparing to measurements Discussion presentations (20min + 5 min questions): 16:45-17:10 Spyros Pandis: field and modelling studies on organic aerosols (Secondary OC using the EC tracer method, OC and EC measurement issues, Hygroscopic properties of OC +, Results on Nucleation modelling. Source contributions to OC in the Eastern US) 17:10-17:35 Hannele Korhonen: Formation of organic nucleation mode aerosols: initial steps of the growth 17:35-18:00 Manuel Capouet, Jean Francois Muller: Modelling aerosol formation from the degradation of alpha-pinene Tuesday 23/9/2003 (9:30-17:00) Model studies (rapporteurs: Elisabetta Vignati, Barbara Ervens, Athanassios Nenes) continue Discussion presentations (20min + 5 min questions): 9:30-9:55 Kostas Tsigaridis: Challenges in global modelling of SOA 9:55-10:20 Barbara Ervens: Cloud processing of organic/ inorganic aerosols: Organic mass production rates and implications for cloud physics 10:20-10:45 Hartmut Herrmann: Cloud processing of organic material: Lab studies and model development 10:45-11:10 Susanne Jungen: The impact of the mixing state of organic-inorganic aerosol mixtures on cloud microphysics and chemistry: a model study 11:10-11:40 Coffee break 11:30-11:55 Athanassios Nenes: The role of carbonaceous aerosol in aerosol-cloud interactions 11:55-12:30 general discussion 12:30-14:00 Lunch break +Coffee 14:00-14:30 Emissions – primary particles Zbigniew Klimont, Kaarle Kupiainen, Tami Bond: Modeling Emissions of Carbonaceous Particles EC/OC emission inventories, main uncertainties (to be addressed among others: is primary OA mainly from combustion? what do we know for marine OA primary aerosol? for biological particle emissions? and for other potential primary emissions?) 14:30-14:50 Presentation of the session highlights (10 min per session) 14:50-15:00 Overall summary of the workshop (Frank Dentener, Maria Kanakidou) 15:00–15:15 15:15-16:15 Concluding remarks (John Seinfeld) OPEN SEMINAR (S. Pandis) 16:30 DEPARTURE OF BUS TO THE AIRPORT