MATERIAL SAFETY DATA SHEET
Document No:EMLÜGBF-01-0 Issue Date :01/06/2014 Page No: 1/8
[(EC) No 1907/2006 (REACH), (EC) No 1272/2008 (CLP) -
Materıal Safety Data Sheet (MSDS)]
1.
MATERIAL / MIXTURE AND COMPANY IDENTIFICATION:
Commercial Name
Chemical Name
Company Identification
SUPERPOWER
No
SOLAR PATLAYICI
Eskis ehir Yolu 9. km. Dumlupınar Bulvarı
No: 266 Tepe Prime B Blok No: 79 06800
Cankaya-ANKARA/ TÜRKİYE
Emergency Call: e-mail: info@solarpatlayici.com
+90. 312. 286 24 25
Usage of Material/Mixture Cap sensitive explosive for industrial use
2.
RISK DEFINITON:
67/548/EEC
R2.
Explosive material. Avoid all ignition sources.
R21/22 : It is harmful to health when in contact with skin and if swallowed.
.
(EC) No.1272/2008 [CLP]
H201: Explosive material; Danger of explosion on a large scale
H302: It is harmful to health if swallowed.
H312: It is harmful to health when in contact.
MATERIAL SAFETY DATA SHEET
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3.
İÇERİK / BİLEŞENLER HAKKINDA BİLGİ:
İnorganic Nitrate
Emulsifier
Chemicals CAS No
6484-52-2
7631-99-4
7779-88-6
9005-65-6
Proportion
(wt %)
> 55
< 8
Classification
Regulation
67/548/EEC
1272/2008
[CLP]
O;R8-9,
Xi;R36/37/38
R-40, R-65,
R-66
R-52/53
H271
H315-319-
335
H411
H351
H304
,EUH066
Paraffin Wax
Alüminnum Powder
67742-51-2/
8002-74-2
7429-90-5
< 8
< 8 R15;R17 H250-H260
R8
H272
Additive/ Sensitiser 7632-00-0 < 3
R25
H301
R50
H400
4.
FIRST AID:
Eye Immediately irrigate with copious quantities of water for atleast 15 minutes. Eyelids should be held open. Seek immediate medical assistance.
Skin Wipe material from skin, then wash contaminated skin with plenty of soap and water. Remove contaminated clothing and wash before reuse. If irritation occurs, seek medical advice.
Swallowed Rinse mouth with water. Give plenty of water to drink. Seek medical assistance.
Inhalation
5.
FIREFIGHTING PRECAUTION
Take some fresh air. The persistence of the problem take medical support.
General Warnings:
Firefighting Precautions:
Explosive. Remove non-authorized.
For small fires, remove the uninfected explosive products from fire area with.
Use water-based fire extinguishing tools to prevent the spread of the fire explosive.
MATERIAL SAFETY DATA SHEET
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6.
7.
Extraordinary Fire and Explosion Dangers:
In correlation with the fire can ignite or explode . Burning may produce substances toxic fumes.
Firefighting Precautions: Do not fight fire borne improvised explosive devices. Evacuate personnel to safe areas identified earlier.
PRECAUTIONS AGANIST ACCIDENTS:
Personal Precautions Gloves, glasses and dressed in overalls. Avoid contact with eyes and skin as well.
Environmental Precautions:
Cleaning Methods:
Avoid contact with soil, water and sewage.
Collect the spread to regain or for destruction and clean the area with water. Contact the manufacturer for the method of destruction (Chapter 13).
STORAGE AND TRANSPORT
Transportation: The product must be transported in accordance with local and national regulations. Smoking, welding near the product and to approach the fire to the product is prohibited. Keep away from sources of ignition. Do not accommodate in the residential neighborhood during transport.
Storage: B e sure to store it in a dry, cool, well -ventilated place. Storage, should be done according to local / national regulations.
Smoking, fire, sparks or welding is prohibited. Explosives, with a combination of flammable substances and ignition should not be stored . It is recommended to store between -5 °C and 35 °C.
Special use: Avoid breathing the fumes arising from the ignition of explosive.
Use safety apllication accepted industry practices. Accidental explosions or ignition of explosive devices can cause serious injury or death.
MATERIAL SAFETY DATA SHEET
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8.
EXPOSURE CONTROLS / PERSONAL PROTECTION:
Exposure Limit Values: No
Respiratory System Protection : Not required during transport and daily use.
Note that CO
2
, CO and NOx containing gas formation occurs after firing smoke
.
Wear overgloves. Hand Protection :
Eye Protection:
Skin Protection:
Wear safety goggles.
Wear antistatic clothes.
General Protection:
9.
STABILITY / REACTION:
Stability:
Conditions to avoid:
Don’t eat and drink during usage.
Heat, flames, ignition sources, strong shock, electrostatic discharge.
PHYSICAL AND CHEMICAL DESCRIPTION / PROPERTIES:
General Information: Appereance:
Odour:
Grey slurry
Negligible
Water resistance: High
Important Information about Health, Safety and Environment:
Flash point ( C )
Boiling point ( C )
:
:
Vapour pressure (20 C) : pH density
Solubility in water (g/l) :
(N Av = Not available
:
:
N App
N App
N App
N App
1120-1200
Insoluble
N App = Not applicable)
Stable under normal conditions.
Materials to avoid: Acid (ex: Nitric acid), metal powder, flammable materials, alkali, (ex: hydroxside), oksidiser materials (hypochloroid), chloride salts,sulfur, urea, nitrite and reductive materials
MATERIAL SAFETY DATA SHEET
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Hazardous Decomposition Products:
TOXICOLOGY:
General Information:
When it is heated, toxic gases may occur (Carbon, nitrogen oxid, hydrocarbons).
It is a highly reactive explosive . When ignited or heated, decomposes and extremely toxic gases occurs.
Eye:
Inhalation:
If contacts irritation , tearing, pain and redness may occur.
It doesn’t have danger for respiratory System except heating the product for decomposition or explosion with toxic nitrogen oxids.
Skin : The result of prolonged contact, slight irritation , itching and infection may occur.
Swallow:
.
If swallowed digestive tract irritation, nausea and vomiting may occur.
10.
ECOLOGY INFORMATION:
Eco toxicity:
Persistence and degradability:
Variability :
Environment Protection: sewerage.
DISPOSAL:
No information
No information
No information
Prevent this product to enter water channel, drainage and
-It must be treated as special waste. Please contact the manufacturer.
- Disposal of waste should be carried out in accordance with local and national regulations.
MATERIAL SAFETY DATA SHEET
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11.
TRANSPORTATION INFORMATION:
Product definition
UN No
Package type
IMDG Class (sea route)
Explosive, detonator, type B
0241
II
ADR / RID (overland / train) 1.1D
1.1D
MATERIAL SAFETY DATA SHEET
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12.
REGULATIONS:
Labeling:
67/548/EEC uyarınca (EC) No.1272/2008 [CLP] yönetmeliği uyarınca
R2-. Explosive material. Avoid all ignition sources.
R5: heating causes explosion.
R21/22: It is harmful to health when in contact with skin or swallowed
.
S1: Keep locked.
S4: Keep away from life space.
S9: Keep container in well- ventilated area.
S15: Keep away from heat.
S16: Keep away from sources of ignition – No smoking.
S20/21: Do not consume food or drinks while using, No smoking.
S24 / 25: Avoid contact with skin or eyes.
S35: Dispose safely.
S41: Fire and / or explosion do not breathe the gas.
S60: This material must be disposed of as hazardous waste.
H201: Explosive material; Danger of explosion on a large scale
H302: Swallowing of contents can result in nausea, vomiting and mild gastric irritation.
H312: Hazardous effect when skin contact
H319: Cause eye irritation.
H335: Cause respiratory irritation.
P210: Keep away from hot surfaces /heat / sparks / open flames /. - No smoking.
P250: Avoid explosion grinding / shock / pressure / friction
P261: Do not breathe dust / fume / gas / steam / spray.
P270: Do not consume food or drinks while using, No smoking.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves / protective clothing / eye protection / face protection.
P370 / P380: In case of fire : Evacuate area .
P372: In case of fire: Explosion risk.
P373: Do not fight fire when fire reaches explosives
P401: Storage in accordance with local / regional / national / international regulations.
P405: Keep locked.
P501: Content destruction act will be carried out in accordance with local / regional / national / international regulations.
MATERIAL SAFETY DATA SHEET
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13.
DİĞER BİLGİLER:
Tedarikçi notları:
Informations in this document sholud be available for people that will use this product.
Risk informations about product (Article 3)
R8: Contact with flammable materials may cause fire.
R9: Mixing with flammabel materials makes it ready to explosion
R36 / 37 / 38: Contents are a moderate eye, skin and respiratory irritant.
R40: Limitted information about carcinogenic effect.
R65: Hazard: Swallowing of contents can result in nausea, vomiting and mild gastric irritation.
R66: Repeated or prolonged contact may cause dry skin problem.
R52/53: Hazardous for water organisms. May cause log term negative effects.
Tecnical Contact Point: SOLAR PATLAYICI
Eskişehir Yolu 9. km. Dumlupınar Bulvarı
No: 266 Tepe Prime B Blok No: 79 06800
Çankaya - ANKARA / TÜRKİYE
Phone:
+90. 312. 286 24 25 e-mail : info@solarpatlayici.com
Production Site : Seyitgazi/Eskişehir