MATERIAL SAFETY DATA SHEET CE Item # CEB50888 MSDS Rev.DATE: 6-4-2009 NAME OF PRODUCT : Duramark SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Duramark Permanent Marker Black chisel SYNONYMS: N.A. PRODUCT CODES: CEB50888 MANUFACTURER: Corporate Express, Inc. DIVISION: ADDRESS: 1 Environmental Way Broomfield CO 80021 EMERGENCY PHONE: 86-574-86186588 CHEMTREC PHONE: OTHER CALLS: FAX PHONE: CHEMICAL NAME: Mixture CHEMICAL FAMILY: N.A. CHEMICAL FORMULA: N.A. PRODUCT USE: Mark on paper PREPARED BY: SECTION 1 NOTES: SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT: Industrial Methylated Spirits 1-methoxy-2-propanol Solvent Black 7 Solvent Black 3 Pigments, Resins, Surfactants ppm CAS NO. 64-17-5 107-98-2 8005-02-5 4197-25-5 various % WT 70% 25% 2% 2% 1% % VOL mg/m3 OSHA PEL-TWA: OSHA PEL STEL : OSHA PEL CEILING: ACGIH TLV-TWA: ACGIH TLV STEL: ACGIH TLV CEILING: SECTION 2 NOTES: SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Not hazardable products. ROUTES OF ENTRY: POTENTIAL HEALTH EFFECTS EYES: N.A. SKIN: N.A. INGESTION: N.A. INHALATION: N.A. ACUTE HEALTH HAZARDS: N.A. CHRONIC HEALTH HAZARDS: N.A. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N.A. CARCINOGENICITY OSHA: ACGIH: OTHER: Page 1 of 5 NTP: IARC: SARA 313 REPORTABLE SECTION 3 NOTES: SECTION 4: FIRST AID MEASURES EYES: IMMEDIATELY FLUSH WITH WATER CONTINUOUSLY FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION AS NEEDED. SKIN: WASH WITH SOAP AND WATER. SEEK MEDICAL ATTENTION AS NEEDED FOR HYPERSENSITIVITY. INGESTION: DO NOT INDUCE VOMITING. CALL PHYSICIAN AND SEEK MEDICAL ATTENTION PROMPTLY. INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION AS NEEDED. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: SECTION 4 NOTES: SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS IN AIR, UPPER: N.A. (% BY VOLUME) LOWER: N.A. FLASH POINT: N.A. F: C: METHOD USED: AUTOIGNITION TEMPERATURE: N.A. |F: C: NFPA HAZARD CLASSIFICATION HEALTH: N.A. FLAMMABILITY: N.A. OTHER: N.A. REACTIVITY: N.A. HMIS HAZARD CLASSIFICATION HEALTH: N.A. FLAMMABILITY: N.A. PROTECTION: N.A. REACTIVITY: N.A. EXTINGUISHING MEDIA: CO2,POWDERS,WATER SPRAY SPECIAL FIRE FIGHTING PROCEDURES: No special measurement required UNUSUAL FIRE AND EXPLOSION HAZARDS: N.A. HAZARDOUS DECOMPOSITION PRODUCTS: N.A. SECTION 5 NOTES: SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Wear protective equipment.Keep unprotected persons away. SECTION 6 NOTES: SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: Ensure good ventilation/exhaustion at the workshops. Prevent formation of aerosols. Keep ignition sources away-Do not smoke. Portect against electrostatic charges. OTHER PRECAUTIONS:Keep receptacle tightly sealed. SECTION 7 NOTES: SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Page 2 of 5 ENGINEERING CONTROLS: VENTILATION : N.A. RESPIRATORY PROTECTION: EYE PROTECTION: SAFETY GOGGLES SKIN PROTECTION: PLASTIC GLOVES OTHER PROTECTIVE CLOTHING OR EQUIPMENT: IMPERMEABLE APRON TO PREVENT THE STAINING OF CLOTHES. WORK HYGIENIC PRACTICES: ALWAYS WASH THOROUGHLY AFTER HANDLING PRODUCT AND BEFORE EATING, DRINKING, SMOKING OR USING THE RESTROOM. EXPOSURE GUIDELINES: Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. SECTION 8 NOTES: SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Fluid,Black Medium ODOR: Characteristic PHYSICAL STATE: Fluid pH AS SUPPLIED: pH (Other): BOILING POINT: F: 212 C: 100 MELTING POINT: undetermined F: C: FREEZING POINT: N.A. F: C: VAPOR PRESSURE (mmHg): 14mm Hg @ F: 68 C: 20 VAPOR DENSITY (AIR = 1):0.85 g/cm3 @ F: >68 C: >20 SPECIFIC GRAVITY (H2O = 1): N.A. @ F: C: EVAPORATION RATE: N.A. BASIS (=1): N.A. SOLUBILITY IN WATER: N.A. PERCENT SOLIDS BY WEIGHT: N.A. PERCENT VOLATILE: BY WT/ : BY VOL @: F: C: Page 3 of 5 VOLATILE ORGANIC COMPOUNDS (VOC):90.3% Organic solvents WITH WATER: LBS/GAL WITHOUT WATER: LBS/GAL MOLECULAR WEIGHT: 6.1% Solids contents VISCOSITY: N.A. @ F: C: SECTION 9 NOTES: SECTION 10: STABILITY AND REACTIVITY STABLE STABILITY: STABLE UNSTABLE CONDITIONS TO AVOID (STABILITY): N.A. INCOMPATIBILITY (MATERIAL TO AVOID): N.A. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: N.A. HAZARDOUS POLYMERIZATION: N.A. CONDITIONS TO AVOID (POLYMERIZATION): N.A. SECTION 10 NOTES: SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: Primary irritant effect: On the skin: No irritant effect; On the eye: Strong irritant with the danger of severe eye injury; Sensitization: No sensitizing effects known. The products shows the following dangers according to internally approved calculation methods for preparations: irritant. SECTION 11 NOTES: SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION:Water hazard class1(self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water,water course or sewage system. SECTION 12 NOTES: SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. RCRA HAZARD CLASS:Disposal must be made according to official regulations. SECTION 13 NOTES: SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: N.A. HAZARD CLASS: N.A. ID NUMBER: N.A. PACKING GROUP: N.A. LABEL STATEMENT: N.A. Page 4 of 5 WATER TRANSPORTATION PROPER SHIPPING NAME: N.A. HAZARD CLASS: N.A. ID NUMBER: N.A. PACKING GROUP: N.A. LABEL STATEMENTS: N.A. AIR TRANSPORTATION PROPER SHIPPING NAME: N.A. HAZARD CLASS: N.A. ID NUMBER: N.A. PACKING GROUP: N.A. LABEL STATEMENTS: N.A. OTHER AGENCIES: SECTION 14 NOTES: SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): N.A. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): N.A. SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): N.A. 311/312 HAZARD CATEGORIES: N.A. 313 REPORTABLE INGREDIENTS: N.A. STATE REGULATIONS: N.A. INTERNATIONAL REGULATIONS: N.A. SECTION 15 NOTES: SECTION 16: OTHER INFORMATION OTHER INFORMATION: This information is based on our present knowledge.However,shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. PREPARATION INFORMATION: DISCLAIMER: Page 5 of 5