Significant Digits and Scientific Notation Scientific Notation: In science, math and computers you will come across some very large and some very small numbers. For example, when we are discussing the universe we know that the distance from the Earth to the Sun is 152, 000, 000, 000 m. When we are in chemistry the number of atoms in a mole of substance is given by Avogadro’s number which is 602,200,000,000,000,000,000,000. On the other side of the scale in physics the mass of an electron is quoted as 0.00000000000000000000000000000911 kg. The point is that these numbers can be very tedious and time consuming to write out in this way. Therefore scientists developed a kind of shorthand for writing these numbers known as Scientific Notation. This shorthand allows us to omit the enormous number of zeros in these large and small numbers. Method 1. Start after the first nonzero digit from the left. 2. Count how many places you move to reach the end 3. Write down the number with all of the nonzero digits and add a X 10N, where N is the number your counted from step 2 4. If you moved the decimal to the left N is negative, if you moved it to the right N is positive Example: 0.00000000000000000000000000000911 1. 9.11 X 10-31 [Since I had to count to the left] Example: 602,200,000,000,000,000,000,000 1. 6.022 X 1023 Significant Digits When we complete calculations with measured numbers or empirical data we must be careful when reporting the calculated value. Consider the following example. Suppose you wish to find the area of your desk with a millimetre ruler. You measure the length to be 50.43 cm and the width to be 75.45 cm. Then the area is given by the length times the width which yields a value of 3804.9435 cm 2. Is this an acceptable value for the area of the desk? Can you really be confident with the precision of this calculation? The answer is no!! It is impossible to measure lengths that are accurate to two decimal places and then expect the area to be accurate to four decimal places. In these types of situations we must take into account significant digits. Identifying Significant Digits 1. All non – zero digits are significant digits 2. Zeros appearing between two non zero digits are significant 3. All zeros appearing to the right of a decimal point and non zero digits are significant 4. All zeros appearing in a number without a decimal point to the right of the last non zero number ARE NOT significant 5. All zeros appearing to the right of a decimal point but before non zero numbers ARE NOT significant NOTE: Zeros like those discussed in 4 and 5 are merely place holders for the number. We can write the number using scientific notation without including these zeros. Examples: 1. 2. 3. 4. 134.45 This number has 5 significant digits 120.403 This number has 6 significant digits 125.300 This number has 6 significant digits 10340000 This number has 4 significant digits the last four zeros are place holders and this number could be written as 1.034 X 10 7. 5. 0.00000234 This number has 3 significant digits since the first five zeros are place holders and this number could be written as 2.34 X 10 -6. Arithmetic with Significant Digits In order to correctly express calculated number with the appropriate amount of significant digits we must adhere to the following rule. Rule of Thumb for Significant Digits When completing calculation with measured numbers complete the calculations as normal and then round to the smallest number of significant digits in the numbers used. Apply scientific notation as necessary. Examples: 1. Calculate the area of the round table whose diameter is 10.5 cm long. d 10.5 r r 5.25 2 2 A r 2 A (3.14159)(5.25) A 16.4933475 r But the number we used in the calculation only had 3 significant digits therefore the area may only have 3 significant digits. Therefore our answer must be rounded to A = 16.5 cm2. 2. Calculate the perimeter of the triangle whose sides measure 14.3 cm, 12.30 cm and 10 cm. P = 14.3 + 12.30 + 10 P = 26.60 cm However one of the numbers only has one significant digit so we must round our answer to P = 30 cm. 3. The energy of an object is given by the formula E = mc2, where c represents the speed of light taken to be 3.00 X 108 m/s. Calculate the energy possessed by an electron whose mass is given by 9.11 X 10-31. E = (9.11 X 10-31)(3.00 X 108) = 2.733 X 10-22 J We must round to three significant digits, therefore the energy is given by E = 2.73 X 10-22 J.