Supplemental Information: SI_1: Schematic of laser ion acceleration File: SI_1_LaserIonAcceleration.WMV Format: movie, wmv Caption: SI_1: Schematic of laser ion acceleration: A multi-TW laser pulse is focused by an off-axis parabolic mirror onto a thin foil target with an intensity I ~ 1019 W/cm2. Due to the finite contrast of the laser pulse (10-6 @ 2ns) the prepulse intensity on target is strong enough (Iprepulse~1013 W/cm2) to create a plasma about 2 ns before the arrival of the main pulse. The main pulse interacts with the preplasma, ponderemotively pushing relativistic electrons through the target. This electron sheath (red) sets up a quasistatic electric field, normal to the target rear surface, which ionizes and accelerates the ions on the target rear surface (TNSA, Target Normal Sheath Acceleration). Due to the ambient vacuum conditions these usually consist of hydrocarbons. The ions are accelerated in the electric field, the higher charge states are tighter collimated, accelerate faster and gain more energy. In the animation carbon charge states 1+ (green), 2+ (dark blue), 3+ (light blue) and 4+ (magenta) are shown. SI_2: Schematic of monoenergetic laser ion acceleration File: SI_2_2005-08-09670A_CMYK_wText_res1k.pdf Format: Adobe pdf Caption: SI_2: Schematic of monoenergetic laser ion acceleration: Before the experiment, a 20 m palladium foil target (yellow)is heated up to ~1100K, creating a monolayer thin graphite layer on the rear surface (purple). A 30 TW laser pulse is focused onto this target with an intensity I ~ 1019 W/cm2. Due to the finite contrast of the laser pulse (10-6 @ 2ns) the prepulse intensity on target is strong enough (Iprepulse~1013 W/cm2) to create a plasma about 2 ns before the arrival of the main pulse. The main pulse interacts with the preplasma, ponderemotively pushing relativistic electrons through the target. This electron sheath sets up a quasistatic electric field, normal to the target rear surface, which ionizes and accelerates the carbon ions out of the graphite layer. The ions out of the thin source layer are accelerated quasi-instantaneous to the same energy and form a tight bunch (magenta) running in front of the slower and spread out Pd-substrate ions accelerated by a decaying electric field later in time. SI_3: Photograph of an ion acceleration experiment File: S_3_2005-08-09670A_PhotoIonAcceleration_CMYK.psd Format: Adobe photoshop Caption: SI_3: Photograph of an ion acceleration experiment: The target sits in its holder in the center of the picture, the laser comes from the left. The green glow is due to a heating laser used to clean the target instead of the current passing wires in earlier experiments. Plasma (ions and electrons) can be seen streaming away from the target towards the right, hitting the RCF package. A fraction of the ion beam passes through the hole in the film stack traveling on towards the Thomson parabola spectrometers (not in picture). In the upper left corner the snout of an x-ray pinhole camera is visible which is used to measure the focal spot size. SI_4: Analysis of a W-target File: SI_4_W target analysis.pdf Format: Adobe pdf Caption: SI_4: Analysis of a W-target After the target was heated to ~ 1000 °C, it was prepared for transmission electron microscopy and analyzed. The left part shows a crossection image of the target. Three different layers were identified: 1. The W-substrate (25 micron) 2. A 40 nm thick, crystalline Be-W alloy layer, formed from an imbedded 1nm Be-tracer layer. 3. A 40 nm thick Tungsten Carbide layer formed from adhered hydrocarbon contaminations. The right part of the image shows an electron diffraction pattern, used to identify the different materials.