MALCOLM HALCROW
b. 1966.
2010-(date). Professor of Inorganic Chemistry, University of Leeds.
2005-2010. Reader in Coordination Chemistry, University of Leeds.
2004-2005. Senior Lecturer in Inorganic Chemistry, University of Leeds.
2002-2004. Lecturer in Inorganic Chemistry, University of Leeds.
1998-2002. Royal Society University Research Fellow, University of Leeds.
1995-1998. Royal Society University Research Fellow, University of Cambridge.
1993-1994. Post-Doctoral Research Fellow, Indiana University, Bloomington, Indiana, USA.
1992. Royal Society Exchange Post-Doctoral Fellow, Laboratoire de Chimie de Coordination
du CNRS, Toulouse, France.
1988-1991. Ph.D., University of Edinburgh.
1985-1988. B.A. (Hons), University of Cambridge.
F.R.S.C., C.Chem.
PUBLICATIONS (January 2012)
174. “Photomagnetic studies on spin-crossover solid solutions containing two different
metal complexes, [Fe(1-bpp)2]x[M(terpy)2]1–x[BF4]2 (M = Ru or Co)” G. Chastanet,
C.A. Tovee, G. Hyett, M.A. Halcrow* and J.-F. Létard*, Dalton Trans., in the press.
173. “Iron(II) complexes of new hexadentate 1,1,1-tris-(iminomethyl)ethane podands, and
their 7-methyl-1,3,5-triaza-adamantane rearrangement products”, S. Diener, A. Santoro,
C.A. Kilner, J.J. Loughrey and M.A. Halcrow*, Dalton Trans., in the press. View
paper
172. “Six new crystalline clathrates of cyclotricatechylene (CTC), including two donoracceptor complexes”, J.J. Loughrey, CA. Kilner, M.J. Hardie* and M.A. Halcrow*,
Supramol. Chem. (special issue for the 6th International Symposium on Macrocyclic
and Supramolecular Chemistry, Brighton), in the press. View paper
171. “Synthesis and methane binding properties of a disulfide-linked cryptophane-0.0.0”,
M.A. Little, J. Donkin, J. Fisher, M.A. Halcrow, J. Loder and M.J. Hardie*, Angew.
Chem., Int. Ed., 2012, 51, 764–766. View paper
170. “An iron(II) complex exhibiting five anhydrous phases, two of which interconvert by
spin-crossover with wide hysteresis”, T.D. Roberts, F. Tuna, T.L. Malkin, C.A. Kilner
and M.A. Halcrow*, Chem. Sci., 2012, 3, 349–354. View paper
169. “1D and 2D assembly structures by imidazole…chloride hydrogen bonds of iron(II)
complexes [FeII(HLn-Pr)3]Cl·Y (HLn-Pr = 2-methylimidazol-4- yl-methylideneamino-npropyl; Y = AsF6, BF4) and their spin states”, T. Fujinami, K. Nishi, N. Matsumoto*, S.
Iijima, M.A. Halcrow, Y. Sunatsuki and M. Kojima, Dalton Trans. (special issue on
Self Assembly in Inorganic Chemistry), 2011, 40, 12301–12309. View paper
168. “Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – a dramatic stabilisation of
the low-spin state in water”, S.A. Barrett, C.A. Kilner and M.A. Halcrow*, Dalton
Trans. (special issue on Self Assembly in Inorganic Chemistry), 2011, 40, 12021–
12024. View paper
167. “A hydrogen bond motif giving a variety of supramolecular assembly structures and
spin-crossover behaviors”, K. Nishi, N. Matsumoto*, S. Iijima, M.A. Halcrow, Y.
Sunatsuki and M. Kojima, Inorg. Chem., 2011, 50, 11303−11305. View paper
166. “Structure:function relationships in molecular spin-crossover complexes”, M.A.
Halcrow*, Chem. Soc. Rev., 2011, 40, 4119–4142. View paper
165. “Exploring the reactivity of an N-pyrazole, P-phosphine hybrid ligand with Cu(I), Ag(I)
and Au(I)”, S. Muñoz, J. Pons*, J. Ros, C.A. Kilner and M.A. Halcrow*, J.
Organomet. Chem., 2011, 696, 2736–2741. View paper
164. “Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl)ethanol against
Pd(II), Zn(II) and Cu(II)”, S. Muñoz, J. Pons*, J. Ros, M. Font-Bardia, C.A. Kilner and
M.A. Halcrow*, Inorg. Chim. Acta, 2011, 373, 211–218. View paper
163. “New insights into the aggregation of silver pyrazolides using sterically hindered
bidentate pyrazole ligands”, J.J. Henkelis, C.A. Kilner and M.A. Halcrow*, Chem.
Commun. (on-line collection on Supramolecular Chemistry), 2011, 47, 5187–5189.
View paper
162. “Assembly structures and spin crossover properties of facial and meridional isomers of
tris[benzyl(2-methylimidazol-4-ylmethylidene)amine]iron(II) chloride
hexafluorophosphate”, D. Furusho, K. Nishi, T. Hashibe, T. Fujinami, H. Hagiwara, N.
Matsumoto*, M.A. Halcrow, S. Iijima, Y. Sunatsuki and M. Kojima, Chem. Lett.,
2011, 40, 72–74. View paper
161. “Two heptacopper(II) disk complexes with a [Cu7(3-OH)4(-OR)2]8+ core”, J.J.
Henkelis, L.F. Jones, C.A. Kilner and M.A. Halcrow*, Inorg. Chem., 2010, 49,
11127–11132. View paper
160. “Ag(I) organometallic coordination polymers and capsule with tris-allyl
cyclotriveratrylene derivatives”, M.A. Little, M.A. Halcrow, L.P. Harding and M.J.
Hardie*, Inorg. Chem., 2010, 49, 9486–9496. View paper
159. “An unusual discontinuity in the thermal spin transition in [Co(terpy)2][BF4]2”, C.A.
Kilner and M.A. Halcrow*, Dalton Trans., 2010, 39, 9008–9012. View paper
158. “A trinuclear iron(III) compound with an unusual T-shaped [Fe3(3-O)]7+ core”, L.F.
Jones, C.A. Kilner and M.A. Halcrow*, J. Cluster Sci. (special issue for M.H.
Chisholm), 2010, 21, 279–290. View paper
157. “Using one spin-transition to trigger another in solid solutions of two different spincrossover complexes”, M.A. Halcrow*, Chem. Commun., 2010, 46, 4761–4763. View
paper
156. “Change in electronic structure in a six-coordinate copper(II) complex accompanied by
an anion order/disorder transition”, C.A. Kilner and M.A. Halcrow*, Acta
Crystallogr., Sect. B, 2010, 66, 206–212. View paper
155. “A back-to-back ligand with dipyrazolylpyridine and dipicolylamine metal-binding
domains”, C.A. Tovee, C.A. Kilner, S.A. Barrett, J.A. Thomas and M.A. Halcrow*,
Eur. J. Inorg. Chem., 2010, 1007–1012. View paper
154. “The effect of different ligand substituents on the chemistry of a zinc/pyrazole anion
host”, J. Day, K.E.R. Marriott, C.A. Kilner and M.A. Halcrow*, New J. Chem., 2010,
34, 52–60. View paper
153. “Iron(II) complexes of 2,6-di(pyrazolyl)pyridines – a versatile system for spincrossover research”, M.A. Halcrow*, Coord. Chem. Rev., 2009, 253, 2493–2514.
View paper
152. “Co-crystallising two functional complex molecules in a terpyridine embrace lattice”,
C.A. Tovee, C.A. Kilner, J.A. Thomas and M.A. Halcrow*, CrystEngComm (special
issue on Crystal Engineering in Molecular Magnetism), 2009, 11, 2069–2077. View
paper
151. “3-(1H-Pyrrol-2-yl)-1H-pyrazole forms an unusual hydrogen-bonded two-dimensional
(3,4)-connected net”, K.E.R. Marriott, C.A. Kilner and M.A. Halcrow*, Acta
Crystallogr., Sect. C, 2009, 65, o506–o508. View paper
150. “Two new 4’,4’’-disubstituted dipyrazolylpyridine derivatives, and the structures and
spin states of their iron(II) complexes”, R. Pritchard, C.A. Kilner, S.A. Barrett and
M.A. Halcrow*, Inorg. Chim. Acta (special issue for S. Trofimenko), 2009, 362, 4365–
4371. View paper
149. “Thermal and light-induced spin-transitions in iron(II) complexes of 2,6-bis(4halopyrazolyl)pyridines: the influence of polymorphism on a spin-crossover
compound”, R. Pritchard, H. Lazar, S.A. Barrett, C.A. Kilner, S. Asthana, C.
Carbonera, J.-F. Létard and M.A. Halcrow*, Dalton Trans., 2009, 6656–6666. View
paper
148. “A cobalt metallacrown anion host with guest-dependent redox activity”, L.F. Jones,
C.A. Kilner and M.A. Halcrow*, Chem. Eur. J., 2009, 15, 4667–4675. View paper
147. “Unexpected product distributions in the synthesis of 2,6-bis-(indazolyl)pyridine and 2(pyrazol-1-yl)-6-(indazolyl)pyridine”, R. Pritchard, C.A. Kilner and M.A. Halcrow*,
Tetrahedron Lett., 2009, 50, 2484–2486. View paper
146. “Pyrazoles and pyrazolides – flexible synthons in self-assembly” (Perspective article),
M.A. Halcrow*, Dalton Trans., 2009, 2059–2073. View paper
145. “A crystalline hydrogen-bonded network with a poly-catenate topology”, A.A.
Salaudeen, C.A. Kilner and M.A. Halcrow*, Chem. Commun., 2008, 5200–5202.
View paper
144. “Cross-link formation of the cysteine 228-tyrosine 272 catalytic cofactor of galactose
oxidase does not require dioxygen”, M.S. Rogers, R. Hurtado-Guerrero, S.J. Firbank,
M.A. Halcrow, D.M. Dooley, S.E.V. Phillips, P.F. Knowles and M.J. McPherson*,
Biochemistry, 2008, 47, 10428–10439. View paper
143. “Mononuclear and dinuclear iron thiocyanate and selenocyanate complexes of trispyrazolylmethane ligands”, A.A. Salaudeen, C.A. Kilner and M.A. Halcrow*,
Polyhedron, 2008, 27, 2569–2576. View paper
142. “The influence of ligand conformation on the thermal spin transitions in iron(III)
saltrien complexes”, R. Pritchard, S.A. Barrett, C.A. Kilner and M.A. Halcrow*,
Dalton Trans., 2008, 3159–3168 and 2009, 10622 (correction). View paper
141. “Trapping and manipulating excited spin states of transition metal compounds”, M.A.
Halcrow*, Chem. Soc. Rev., 2008, 37, 278–289. View paper
140. “Ammonium, alkylammonium and amino acid complexes of a hexacopper fluorometallacrown cavitand”, L.F. Jones, S.A. Barrett, C.A. Kilner and M.A. Halcrow*,
Chem. Eur. J., 2008, 14, 223–233. View paper
139. “Mononuclear and unsymmetric dinuclear complexes of the tripodal ligand 2hydroxyethyl-bis(2-{pyrid-2-yl}ethyl)amine”, Q.F. Mokuolu, C.A. Kilner, P.C.
McGowan and M.A. Halcrow*, Inorg. Chim. Acta, 2007, 360, 4025–4030. View paper
138. “Thermal and light-induced spin-crossover in salts of the heptadentate complex [tris(4{pyrazol-3-yl}-3-aza-3-butenyl)amine]iron(II)”, H.Z. Lazar, T. Forestier, S.A. Barrett,
C.A. Kilner, J.-F. Létard* and M.A. Halcrow*, Dalton Trans., 2007, 4276–4285. View
paper
137. “The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogendonor ligands”, M.A. Halcrow*, Polyhedron, 2007, 26, 3523–3576. View paper
136. “A comparison of different methods for fitting susceptibility data of cobalt(II)
coordination polymers in a new cobalt(II)/sulfate 1-D chain”, L.F. Jones, C.A. Kilner
and M.A. Halcrow*, New J. Chem., 2007, 31, 1530–1534. View paper
135. “Interplay between kinetically slow thermal spin-crossover and metastable high-spin
state relaxation in an iron(II) complex with similar T½ and T(LIESST)”, V.A. Money,
C. Carbonera, J. Elhaïk, M.A. Halcrow*, J.A.K. Howard* and J.-F. Létard*, Chem.
Eur. J., 2007, 13, 5503–5514. View paper
134. “Variable temperature structural and magnetic characterisation of the cubane cluster
[Cu4(µ3-OH)4(L)4][ClO4]4 (L = 5-tertbutyl-3-(pyrid-2-yl)-1H-pyrazole)”, L.F. Jones*,
C.A. Kilner and M.A. Halcrow, Polyhedron (special issue: Proceedings of the 10th
International Conference on Molecular Magnets), 2007, 26, 1977–1983. View paper
133. “2-[5-(2,2-Dimethylpropanamido)-1H-pyrazol-3-yl]pyridinium chloride”, C.M. Pask,
C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. E, 2007, 63, o2933. View
paper
132. “A hexacopper fluoro metallacrown cavitand and its alkali metal complexes”, L.F.
Jones, C.A. Kilner, M.P. de Miranda, J. Wolowska and M.A. Halcrow*, Angew.
Chem., Int. Ed., 2007, 46, 4073–4076. View paper
131. “Zwitterionic 2-(4-pyridyl)malondialdehyde sesquihydrate forms a helical, threedimensional hydrogen-bonded lattice”, C.A. Tovee, C.A. Kilner, J.A. Thomas and
M.A. Halcrow*, CrystEngComm, 2007, 9, 361–363. View paper
130. “Four copper(II) pyrazolido complexes derived from reactions of 3{5}-substituted
pyrazoles with CuF2 or Cu(OH)2“, Q.F. Mokuolu, D. Foguet-Albiol, L.F. Jones, J.
Wolowska, R.M. Kowalczyk, C.A. Kilner, G. Christou, P.C. McGowan and M.A.
Halcrow*, Dalton Trans., 2007, 1392–1399. View paper
129. “Anion doping as a probe of cooperativity in the molecular spin-crossover compound
[FeL2][BF4]2 (L = 2,6-di{pyrazol-1-yl}pyridine)”, C. Carbonera, C.A. Kilner, J.-F.
Létard and M.A. Halcrow*, Dalton Trans., 2007, 1284–1292. View paper
128. “Iron(II) complexes with a terpyridine embrace packing motif show remarkably
consistent cooperative spin-transitions”, R. Pritchard, C.A. Kilner and M.A. Halcrow*,
Chem. Commun., 2007, 577–579. View paper
127. “Synthesis of 2,6-di(pyrazol-1-yl)-4-bromomethylpyridine, and its conversion to other
2,6-di(pyrazol-1-yl)pyridines substituted at the pyridine ring”, J. Elhaïk, C.M. Pask,
C.A. Kilner and M.A. Halcrow*, Tetrahedron, 2007, 63, 291–298. View paper
126. “Homoleptic zinc(II) complexes with first and second coordination shells of 5-tertbutylpyrazole”, S.L. Renard, I. Sylvestre, S.A. Barrett, C.A. Kilner and M.A.
Halcrow*, Inorg. Chem., 2006, 45, 8711–8718. View paper
125. “Novel hydrogen bond network topologies in complexes of the ditopic ligand 5-amino3-(pyrid-2-yl)-1H-pyrazole”, L.F. Jones, K.D. Camm, C.A. Kilner and M.A. Halcrow*,
CrystEngComm, 2006, 8, 719–728. View paper
124. “An unusual example of a linearly coordinated acetone ligand in a six-coordinate
iron(II) complex”, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2006,
62, m437–m439. View paper
123. “Photomagnetic properties of iron(II) spin crossover complexes of 2,6dipyrazolylpyridine and 2,6-dipyrazolylpyrazine ligands”, C. Carbonera, J.S. Costa,
V.A. Money, J. Elhaïk, J.A.K. Howard*, M.A. Halcrow* and J.-F. Létard*, Dalton
Trans., 2006, 3058–3066. View paper
122. “Synthesis of a new series of ditopic proligands for metal salts: differing regiochemistry
of electrophilic attack at 3{5}-amino-5{3}-(pyrid-2-yl)-1H-pyrazole”, C.M. Pask, K.D.
Camm, C.A. Kilner and M.A. Halcrow*, Tetrahedron Lett., 2006, 47, 2531–2534.
View paper
121. “Copper(II) complexes of sterically hindered Schiff base ligands: synthesis, structure,
spectra and electrochemistry”, R. Balamurugan, M. Palaniandavar* and M.A.
Halcrow, Polyhedron, 2006, 25, 1077–1088. View paper
120. “Structural diversity in iron(II) complexes of 2,6-di(pyrazol-1-yl)pyridine and 2,6-di(3methylpyrazol-1-yl)pyridine”, J. Elhaϊk, C.A. Kilner and M.A. Halcrow*, Dalton
Trans., 2006, 823–830. View paper
119. “Two complexes of copper(II) salts with 5-amino-3-(pyrid-2-yl)-1H-pyrazole, the
prototype for a new class of ditopic ligand”, C.M. Pask, K.D. Camm, N.J. Bullen, M.J.
Carr, W. Clegg, C.A. Kilner and M.A. Halcrow*, Dalton Trans., 2006, 662–664. View
paper
118. “An iron(II) complex of 2,6-di(pyrazol-1-yl)pyrazine that crystallises in three forms,
two of which exhibit an unusual angular Jahn-Teller distortion”, C.A. Kilner and M.A.
Halcrow*, Polyhedron (special issue for M.H. Chisholm), 2006, 25, 235–240. View
paper
117. “The synthesis and coordination chemistry of 2,6-di(pyrazolyl)pyridines and related
ligands – versatile terpyridine analogues”, M.A. Halcrow*, Coord. Chem. Rev., 2005,
249, 2880–2908. View paper
116. “Copper(II) complexes of thioether-substituted salcyen and salcyan derivatives and
their silver(I) adducts”, I. Sylvestre, J. Wolowska, C.A. Kilner, E.J.L. McInnes and
M.A. Halcrow*, Dalton Trans., 2005, 3241–3249. View paper
115. “Copper(II) complexes of tridentate pyridylmethylethylenediamines: role of steric
hindrance on DNA binding and cleavage”, A. Raja, V. Rajendiran, P.U. Maheswari, R.
Balamurugan, C.A. Kilner, M.A. Halcrow and M. Palaniandavar*, J. Inorg. Biochem.,
2005, 99, 1717–1732. View paper
114. “An unusual zinc-promoted decomposition of a bis(2-{pyrid-2-yl}ethyl)amine
derivative”, Q.F. Mokuolu, C.A. Kilner, S.A. Barrett, P.C. McGowan and M.A.
Halcrow*, Inorg. Chem., 2005, 44, 4136–4138. View paper
113. “Two regioisomers of (pyrid-2-yl)tetrazole which form two-dimensional five- and sixconnected nets through hydrogen bonding”, A.T. Rizk, C.A. Kilner and M.A.
Halcrow*, CrystEngComm, 2005, 7, 359–362. View paper
112. “A structural, magnetic and Mössbauer spectroscopic study of an unusual angular JahnTeller distortion in a series of high-spin iron(II) complexes”, J. Elhaϊk, D.J. Evans, C.A.
Kilner and M.A. Halcrow*, Dalton Trans., 2005, 1693–1700. View paper
111. “2-[Bis(pyrazol-1-yl)methyl]-4-tertbutyl-6-(phenylsulfanyl)phenol”, I. Sylvestre, C.A.
Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2005, 61, o294–o296. View
paper
110. “An unexpected destabilisation of copper(II) phenoxyl radical species by increased
steric protection”, I. Sylvestre, J. Wolowska, E.J.L. McInnes, C.A. Kilner and M.A.
Halcrow*, Inorg. Chim. Acta, 2005, 358, 1337–1341. View paper
109. “An iron(II) complex salt that crystallises in three forms, one of which undergoes a
sterically controlled incomplete spin-state transition on cooling”, J. Elhaϊk, C.A. Kilner
and M.A. Halcrow*, CrystEngComm, 2005, 7, 151–157. View paper
108. “Stereocontrol in asymmetric phospho-aldol catalysis. Chirality relaying in action”,
T.D. Nixon, S. Dalgarno, C.V. Ward, M. Jiang, M.A. Halcrow, C. Kilner, M.
Thornton-Pett and T.P. Kee*, C. R. Chimie (special issue on Main Group Compounds
in Catalysis and Coordination Chemistry), 2004, 7, 809–821. View paper
107. “Iron complexes of 3-(pyrazinyl)-1,2,4-triazole derivatives”, F.E. Bradford, L.P.
Connor, C.A. Kilner and M.A. Halcrow*, Polyhedron, 2004, 23, 2141–2151. View
paper
106. “A photomagnetic study of three iron(II) compounds containing ligands from the 2,6di(pyrazol-1-yl)pyridine series”, V.A. Money, J. Sánchez Costa, S. Marcén, G.
Chastanet, J. Elhaϊk, M.A. Halcrow, J.A.K. Howard and J.-F. Létard*, Chem. Phys.
Lett., 2004, 391, 273–277. View paper
105. “The thermal and light induced spin transition in [FeL2](BF4)2 (L = 2,6-dipyrazol-1-yl4-hydroxymethylpyridine)”, V.A. Money, J. Elhaïk, M.A. Halcrow and J.A.K.
Howard*, Dalton Trans., 2004, 1516–1518. View paper
104. “Cofactor processing in galactose oxidase”, S.J. Firbank, M. Rogers, R. HurtadoGuerrero, D.M. Dooley, M.A. Halcrow, S.E.V. Phillips, P.F. Knowles and M.J.
McPherson*, Biochem. Soc. Symp., vol. 71: Free Radicals: Enzymology, Signalling
and Disease, eds. C. Cooper, M. Wilson and V. Darley-Usmar, Portland Press, London,
2004, 15–25. View paper
103. “Reactions of copper(II) salts with 3{5}-tertbutylpyrazole. Double-cubane complexes
with bound exogenous anions, and a novel pyrazole coordination mode”, X. Liu, J.A.
McAllister, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner and M.A. Halcrow*, Chem.
Eur. J., 2004, 10, 1827–1837. View paper
102. “[Tris-(4-{1H-pyrazol-3-yl}-3-aza-3-butenyl)amine]iron(II) diperchlorate
monohydrate”, M.J. Hardie, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect.
C, 2004, 60, m177–m179. View paper
101. “Temperature dependence of the electronic ground states of two mononuclear, sixcoordinate copper(II) centres”, M.A. Halcrow*, C.A. Kilner, J. Wolowska, E.J.L.
McInnes and A.J. Bridgeman*, New J. Chem., 2004, 28, 228–233 and 2004, 28, 887
(correction). View paper
100. “An X-ray powder diffraction study of the spin-crossover transition and structure of
bis(2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate”, V.A. Money, I. Radosavljevic
Evans, J. Elhaïk, M.A. Halcrow and J.A.K. Howard*, Acta Crystallogr., Sect. B, 2004,
60, 41–45. View paper
99.
“A crystallographic, EPR and theoretical study of the Jahn-Teller distortion in [CuTp2]
(Tp– = tris-{pyrazol-1-yl}hydridoborate)”, C.A. Kilner, E.J.L. McInnes, M.A. Leech,
G.S. Beddard, J.A.K. Howard, F.E. Mabbs, D. Collison, A.J. Bridgeman and M.A.
Halcrow*, Dalton Trans., 2004, 236–243. View paper
98.
“A study of the thermal and light-induced spin transition in [FeL2](BF4)2 and
[FeL2](ClO4)2 L = 2,6-di(3-methylpyrazol-1-yl)pyrazine”, V.A. Money, J. Elhaïk, I.
Radosavljevic Evans, M.A. Halcrow and J.A.K. Howard*, Dalton Trans., 2004, 65–
69. View paper
97.
“Antisymmetric exchange in two tricopper(II) complexes containing a [Cu3(3-OMe)]5+
core”, X. Liu, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner and M.A. Halcrow*,
Dalton Trans., 2004, 59–64. View paper
96.
“Di--hydroxobis({bis[2-(pyrid-2-yl)ethyl]amine-N3}copper(II)) dichloride
hexahydrate”, S.A. Leaver, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect.
C, 2004, 60, m1–m3. View paper
95.
“Monocopper oxygenases”, M.A. Halcrow* in Comprehensive Coordination
Chemistry II –From Biology to Nanotechnology, eds. J. McCleverty and T.J. Meyer,
Elsevier, Oxford, 2003; vol. 8 (eds. L. Que jr. and W.B. Tolman), ch. 8.16, pp. 395–
436. View paper
94.
“Interpreting and controlling the Jahn-Teller structures of six-coordinate copper(II)
centres – When is a compression really a compression?” (Perspective article), M.A.
Halcrow*, Dalton Trans., 2003, 4375–4384. View paper
93.
“A new synthesis of bis(2-{pyrid-2-yl}ethyl)amine (LH) from bis(2-{pyrid-2-yl}ethyl)hydroxylamine (LOH), and a copper-dependent reduction of LOH to LH”, S.A. Leaver, M.
Palaniandavar, C.A. Kilner and M.A. Halcrow*, Dalton Trans., 2003, 4224–4225.
View paper
92.
“Cofactor processing in galactose oxidase”, S.J. Firbank, M. Rogers, R. HurtadoGuerrero, D.M. Dooley, M.A. Halcrow, S.E.V. Phillips, P.F. Knowles and M.J.
McPherson*, Biochem. Soc. Trans., 2003, 31, 506–509. View Paper
91.
“The spin-states and spin-crossover behaviour of iron(II) complexes of 2,6-dipyrazol-1ylpyrazine derivatives”, J. Elhaïk, V.A. Money, S.A. Barrett, C.A. Kilner, I.
Radosavljevic Evans and M.A. Halcrow*, Dalton Trans. (special issue on Ligand
Design for Functional Complexes), 2003, 2053–2060. View paper
90.
“The structures and decomposition products of palladium(II) and platinum(II)
terpyridine phenoxide complexes”, X. Liu, S.L. Renard, C.A. Kilner and M.A.
Halcrow*, Inorg. Chem. Commun., 2003, 6, 598–603. View paper
89.
“(2-Tetracyanoethene)bis(triphenylphosphine-P)palladium dichloromethane (1/0.7)”,
Z. Shackleton, C.A. Kilner, G.D. Reid and M.A. Halcrow*, Acta Crystallogr., Sect. C,
2003, 59, m136–m138. View paper
88.
“Iron(II) complexes of (pyrazol-3-yl)pyrazine. Anion-dependent formation of a
hydrogen-bonded, chiral nanoporous lattice”, R.J. Smithson, C.A. Kilner, A.R. Brough
and M.A. Halcrow*, Polyhedron (special issue on Supramolecular Chemistry), 2003,
22, 725–733. View paper
87.
“Copper enzymes and models”, M.A. Halcrow* in Encyclopedia of Catalysis, ed. I.T.
Horváth, John Wiley and Sons, New York, 2003; vol. 2, pp. 669–706. View paper
86.
“Hexa--chloro-4-oxotetrakis{[5-(2,4,6-trimethylphenyl)pyrazole-N2]copper(II)}”,
X. Liu, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2003, 59, m100–
m102. View paper
85.
“Interpretation of the temperature dependence of the crystal structure of [CuL2][BF4]2
(L = 2,6-dipyrazol-1-ylpyridine)”, G.S. Beddard, M.A. Halcrow*, M.A. Hitchman*,
M.P. de Miranda, C.J. Simmons and H. Stratemeier, Dalton Trans., 2003, 1028–1032.
View paper
84.
“Bis{2,6-bis[3-(2,4,6-trimethylphenyl)pyrazol-1-yl-N2]pyridine-N}cobalt(II)
dinitrate at 290 and 150 K”, M.A. Halcrow* and C.A. Kilner, Acta Crystallogr., Sect.
C, 2003, 59, m61–m63. View paper
83.
“Light induced excited high spin-state trapping in [FeL2](BF4)2 (L = 2,6-di(pyrazol-1yl)pyridine)”, V.A. Money, I. Radosavljevic Evans, M.A. Halcrow, A.E. Goeta and
J.A.K. Howard*, Chem. Commun., 2003, 158–159. View paper
82.
“A cyclic hexacopper(II) fluoro complex that encapsulates two fluoride anions”, X. Liu,
A.C. McLaughlin, M.P. de Miranda, E.J.L. McInnes, C.A. Kilner and M.A. Halcrow*,
Chem. Commun., 2002, 2978–2979. View paper
81.
“Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tertbutylpyrazole)”, S.L. Renard, A. Franken, C.A. Kilner, J.D. Kennedy and M.A.
Halcrow*, New J. Chem., 2002, 26, 1634–1637. View paper
80.
“Supramolecular anion binding by the [ZnCl(HpztBu)3]+ cation (HpztBu = 5-tertbutylpyrazole)”, S.L. Renard, C.A. Kilner, J. Fisher and M.A. Halcrow*, J. Chem.
Soc., Dalton Trans., 2002, 4206–4212. View paper
79.
“Dissecting an enzyme – model compounds for the galactose oxidase radical site”,
M.A. Halcrow*, Heteroatom Chem. (special issue: Proceedings of the 6th AngloGerman Inorganic Chemistry “AGICHEM” Conference), 2002, 13, 494–500. View
paper
78.
“Bis[-3{5}-(2-pyridyl)pyrazolido]bis[(acetonitrile)copper(II)] diperchlorate”, M.J.
Hallam, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002, 58, m445–
m446. View paper
77.
“[2,6-Bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine]iodocopper(I) dichloromethane
solvate”, M.A. Halcrow* and C.A. Kilner, Acta Crystallogr., Sect. C, 2002, 58, m424–
m426. View paper
76.
“Tetrakis(5-tertbutyl-pyrazole-1N2)-tetrachloro-1Cl,23Cl--oxo-1:22Odiiron(III)”, X. Liu, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002,
58, m290–m291. View paper
75.
“Control of the spin state of Fe(II) 2,6-di(pyrazol-1-yl)pyridine complexes by distal
ligand substitution”, J.M. Holland, S.A. Barrett, C.A. Kilner and M.A. Halcrow*,
Inorg. Chem. Commun., 2002, 5, 328–332. View paper
74.
“Steric effects on the stereochemistry of copper complexes of 2,6-bis(pyrazol-1-ylmethyl)pyridines”, C.L. Foster, C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*,
Polyhedron, 2002, 21, 1031–1041. View paper
73.
“3,4-(4-Methoxybenzo):8,9-benzobicyclo[4.4.1]undeca-3,9-dien-11-one ethylene
acetal”, X. Liu, C.A. Kilner and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002, 58,
o218–o219. View paper
72.
“Copper(II) complexes of 2,6-bis(3-tert-butylpyrazol-1-yl)pyridine”, N.K. Solanki,
E.J.L. McInnes, D. Collison, C.A. Kilner, J.E. Davies and M.A. Halcrow*, J. Chem.
Soc., Dalton Trans., 2002, 1625–1630. View paper
71.
“3{5}-Tertbutylpyrazole is a ditopic receptor for zinc(II) halides”, X. Liu, C.A. Kilner
and M.A. Halcrow*, Chem. Commun., 2002, 704–705. View paper
70.
“A crystallographic and EPR study of the fluxional Cu(II) ion in [CuL2][BF4]2 (L = 2,6dipyrazol-1-ylpyridine)”, N.K. Solanki, M.A. Leech, E.J.L. McInnes, F.E. Mabbs,
J.A.K. Howard, C.A. Kilner, J.M. Rawson and M.A. Halcrow*, J. Chem. Soc., Dalton
Trans., 2002, 1295–1301. View paper
69.
“Supramolecular templating of the double-cubane [{Cu3(HpztBu)6(3-Cl)(3OH)3}2Cu]Cl6 (HpztBu = 5-tert-butylpyrazole)”, X. Liu, J.A. McAllister, M.P. de
Miranda, B.J. Whitaker, C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*, Angew.
Chem., Int. Ed., 2002, 41, 756–758. View paper
68.
“Stereochemical effects on the spin-state transition shown by salts of [FeL2]2+ [L = 2,6di(pyrazol-1-yl)pyridine]”, J.M. Holland, J.A. McAllister, C.A. Kilner, M. ThorntonPett, A.J. Bridgeman* and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 2002, 548–
554. View paper
67.
“Bis[2-(pyrazol-3-yl)phenolato-2N2,O]copper(II) dimethanol solvate”, X. Liu, C.A.
Kilner, M. Thornton-Pett and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2002, 58,
m10–m11. View paper
66.
“Syntheses of new hydroxy-[3.3]orthocyclophanes as models for the galactose oxidase
Tyr-Cys cofactor”, X. Liu, S.A. Barrett, C.A. Kilner, M. Thornton-Pett and M.A.
Halcrow*, Tetrahedron, 2002, 58, 603–611. View paper
65.
“Crystal structure of the precursor of galactose oxidase: an unusual self-processing
enzyme”, S.J. Firbank, M.S. Rogers, C.M. Wilmot, D.M. Dooley, M.A. Halcrow, P.F.
Knowles, M.J. McPherson and S.E.V. Phillips*, Proc. Natl. Acad. Sci. USA, 2001, 98,
12932–12937. View paper
64.
“Two complexes of CuBr2 with 5-tertbutylpyrazole”, X. Liu, C.A. Kilner, M.
Thornton-Pett and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2001, 57, 1253–1255.
View paper
63.
“Metal complexes of 4’-(3-phenylpropoxy)-2,2’:6’,2’’-terpyridine and 4’-(3-propoxy)2,2’:6’,2’’-terpyridine”, X. Liu, E.J.L. McInnes, C.A. Kilner, M. Thornton-Pett and
M.A. Halcrow*, Polyhedron, 2001, 20, 2889–2900. View paper
62.
“Steric effects on the electronic and molecular structures of nickel(II) and cobalt(II)
2,6-dipyrazol-1-ylpyridine complexes”, J.M. Holland, C.A. Kilner, M. Thornton-Pett
and M.A. Halcrow*, Polyhedron, 2001, 20, 2829–2840. View paper
61.
“The effects of distal ligand substitution on the copper(II)/bis-(2,6-dipyrazol-1-ylpyridine) centre”, N.K. Solanki, M.A. Leech, E.J.L. McInnes, J.P. Zhao, F.E. Mabbs, N.
Feeder, J.A.K. Howard, J.E. Davies, J.M. Rawson and M.A. Halcrow*, J. Chem. Soc.,
Dalton Trans., 2001, 2083–2088. View paper
60.
“Bis[tris(3-cyclohexylpyrazol-1-yl)hydridoborato]copper(II) dichloromethane
disolvate”, M.A. Halcrow*, C.A. Kilner and M. Thornton-Pett, Acta Crystallogr., Sect.
C, 2001, 57, 711–713. View paper
59.
“Chiral bis(oxazoline) complexes. Synthesis, structure and application in chiral
phospho-transfer”, M. Jiang, S. Dalgarno, C.A. Kilner, M.A. Halcrow* and T.P. Kee*,
Polyhedron, 2001, 20, 2151–2162. View paper
58.
“Copper proteins in the transport and activation of dioxygen, and the reduction of
inorganic molecules”, M.A. Halcrow*, P.F. Knowles and S.E.V. Phillips in Handbook
on Metalloproteins, eds. I. Bertini A. Sigel and H. Sigel, Marcell Dekker, New York,
2001; ch. 15, pp. 709–762.
57.
“An unusual abrupt thermal spin-state transition in [FeL2][BF4]2 [L = 2,6-di(pyrazol-1yl)pyridine]”, J.M. Holland, J.A. McAllister, Z. Lu, C.A. Kilner, M. Thornton-Pett and
M.A. Halcrow*, Chem. Commun., 2001, 577–578. View paper
56.
“1-(Dibromomethyl)-4-methoxy-2-methylbenzene”, X. Liu, C.A. Kilner, M. ThorntonPett and M.A. Halcrow*, Acta Crystallogr., Sect. C, 2001, 57, 317–318. View paper
55.
“Chemically modified amino acids in copper proteins that bind or activate dioxygen”,
M.A. Halcrow*, Angew. Chem., Int. Ed., 2001, 40, 346–349. View paper
54.
“Amine oxidases and galactose oxidase”, M.A. Halcrow, S.E.V. Phillips and P.F.
Knowles* in Subcellular Biochemistry, vol. 35: Enzyme-Catalyzed Electron and
Radical Transfer, eds. A. Holzenberg and N.S. Scrutton, Plenum Press, London, 2000,
183–231.
53.
“Complexes of 2-hydroxy-5-methyl-1,4-benzoquinone as models for the ‘TPQ-on’
form of copper amine oxidases”, C.L. Foster, X. Liu, C.A. Kilner, M. Thornton-Pett
and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 2000, 4563–4568. View paper
52.
“Bis{2,6-bis[3-(2,4,6-trimethylphenyl)pyrazol-1-yl-N2]pyridine-N}zinc(II)
diperchlorate bis(nitromethane) solvate”, M.A. Halcrow*, C.A. Kilner and M.
Thornton-Pett, Acta Crystallogr., Sect. C, 2000, 56, 1425–1426. View paper
51.
“An intramolecular - interaction has no effect on the lifetime of an aryl radical
cation”, X. Liu, L.M.L. Chia, C.A. Kilner, L.J. Yellowlees, M. Thornton-Pett, S.
Trofimenko and M.A. Halcrow*, Chem. Commun., 2000, 1947–1948. View paper
50.
“Copper complexes of 2,6-bis(iminomethyl)pyridine derivatives and of 1,3-bis(pyridin-2-yl)pyrazole. Effects of ligand bulk and conformational strain on the ground
state of a six-co-ordinate copper(II) ion”, J.M. Holland, X. Liu, J.P. Zhao, F.E. Mabbs,
C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*, J. Chem. Soc., Dalton Trans.,
2000, 3316–3324. View paper
49.
“4’-Vinyl-2,2’:6’,2’’-terpyridine”, X. Liu, C.A. Kilner, M. Thornton-Pett and M.A.
Halcrow*, Acta Crystallogr., Sect. C, 2000, 56, 1142–1143. View paper
48.
“Copper(II) complexes of hydroquinone-containing Schiff bases. Towards a structural
model for copper amine oxidases”, P. Li, N.K. Solanki, H. Ehrenberg, N. Feeder, J.E.
Davies, J.M. Rawson and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 2000, 1559–
1565. View paper
47.
“Bis[N,N’-bis(2,4,6-trimethylphenyl)-1,2-ethanediylidenediamine]copper(I) tetrafluoroborate”, C.L. Foster, C.A. Kilner, M. Thornton-Pett and M.A. Halcrow*, Acta
Crystallogr., Sect. C, 2000, 56, 319–320. View paper
46.
“Syntheses, structures and electrochemistry of [Zn(L1)2](BF4)2·2H2O and
[Zn(L1)(TpR)]BF4 (L1 = 1-{pyrid-2-yl}-3-{2’,5’-dimethoxyphenyl}pyrazole; [TpR]– =
tris-{3-aryl-pyrazolyl}-borate)”, L.M.L. Chia, A.E.H. Wheatley, N. Feeder, J.E. Davies
and M.A. Halcrow*, Polyhedron, 2000, 19, 109–114. View paper
45.
“2,6-Bis-(3-trifluoromethylpyrazol-1-yl)pyridine”, M.A. Halcrow*, C.A. Kilner and
M. Thornton-Pett, Acta Crystallogr., Sect. C, 2000, 56, 213–214. View paper
44.
“Steric control of the reactivity of moderately hindered tris(pyrazolyl)borates with
copper(II) salts”, L.M.L. Chia, S. Radojevic, I.J. Scowen, M. McPartlin and M.A.
Halcrow*, J. Chem. Soc., Dalton Trans., 2000, 133–140. View paper
43.
“The ground state of a tetragonally compressed copper(II) complex”, A.J. Bridgeman*,
M.A. Halcrow, M. Jones, E. Krausz and N.K. Solanki, Chem. Phys. Lett., 1999, 314,
176–181. View paper
42.
“A solid-state phase transition at 41 K involving the cooperative ordering of a fluxional
pseudo-Jahn Teller CuII system”, M.A. Leech*, N.K. Solanki, M.A. Halcrow, J.A.K.
Howard and S. Dahaoui, Chem. Commun., 1999, 2245–2246. View paper
41.
“Electronic structures of copper(II) complexes of tetradentate hydroquinone-containing
Schiff bases”, E.H. Charles, L.M.L. Chia, J. Rothery, E.L. Watson, E.J.L. McInnes,
R.D. Farley, A.J. Bridgeman, F.E. Mabbs, C.C. Rowlands and M.A. Halcrow*, J.
Chem. Soc., Dalton Trans., 1999, 2087–2095. View paper
40.
“Syntheses, structures and electrochemistry of copper(II) salicylaldehyde/tris-(3phenylpyrazolyl)borate complexes as models for the radical copper oxidases”, M.A.
Halcrow*, L.M.L. Chia, X. Liu, E.J.L. McInnes, L.J. Yellowlees, F.E. Mabbs, I.J.
Scowen, M. McPartlin and J.E. Davies, J. Chem. Soc., Dalton Trans., 1999, 1753–
1762. View paper
39.
“Syntheses, structures and magnetism of homoleptic complexes of 4-{pyrid-4-yloxy}2,2,6,6-tetramethyl-1-piperidinoxyl, a new spin-labelled pyridine”, M.A. Halcrow*,
L.M. Rodriguez-Martinez, E.K. Brechin, J.E. Davies, I.J. Scowen and M. McPartlin, J.
Organomet. Chem. (special issue for B.F.G. Johnson), 1999, 573, 171–179. View
paper
38.
“Structural variations in dicopper(I) double helicate complexes”, N.K. Solanki, A.E.H.
Wheatley, S. Radojevic, M. McPartlin and M.A. Halcrow*, J. Chem. Soc., Dalton
Trans., 1999, 521–523. View paper
37.
“Spectroscopic characterisation of a copper(II) complex of a thioether-substituted
phenoxyl radical: a new model for galactose oxidase”, M.A. Halcrow*, L.M.L. Chia,
X. Liu, E.J.L. McInnes, L.J. Yellowlees, F.E. Mabbs and J.E. Davies, Chem. Commun.,
1998, 2465–2466. View paper
36.
“Co-ordination chemistry of bis(ferrocenylcarbaldimine) Schiff bases”, P. Li, I.J.
Scowen, J.E. Davies and M.A. Halcrow*, J. Chem. Soc., Dalton Trans., 1998, 3791–
3799. View paper
35.
“The noble metals”, M.A. Halcrow*, Annu. Rep. Prog. Chem., Sect. A, 1998, 94, 255–
288. View paper
34.
“Steric control of the electronic ground state in six-coordinate copper(II) complexes”,
N.K. Solanki, E.J.L. McInnes, F.E. Mabbs, S. Radojevic, M. McPartlin, N. Feeder, J.E.
Davies and M.A. Halcrow*, Angew. Chem., Int. Ed., 1998, 37, 2221–2223. View
paper
33.
“Complex chemistry of 2,2,6,6-tetramethyl-4-{2,2’:6’,2’’-terpyridin-4’-yloxy}piperidin-1-oxyl, a spin-labelled terpyridine”, M.A. Halcrow*, E.K. Brechin, E.J.L.
McInnes, F.E. Mabbs and J.E. Davies, J. Chem. Soc., Dalton Trans., 1998, 2477–2482.
View paper
32.
“Metal complexes of sterically hindered pyrazolylpyridines. The single crystal X-ray
structure of [Cu(L1)2]BF4 (L1 = 1-{pyrid-2-yl}-3-{2’,5’-dimethoxyphenyl}pyrazole)”,
M.A. Halcrow*, N.L. Cromhout and P.R. Raithby, Polyhedron, 1997, 16, 4257–4264.
View paper
31.
“The noble metals”, M.A. Halcrow*, Annu. Rep. Prog. Chem., Sect. A, 1997, 93, 241–
267. View paper
30.
“Nickel-dependent redox enzymes”, M.A. Halcrow* in Comprehensive Biological
Catalysis, ed. M.L. Sinnott, Academic Press, 1997; vol. 3, ch. 36, 359–376.
29.
“Urease”, M.A. Halcrow* in Comprehensive Biological Catalysis, ed. M.L. Sinnott,
Academic Press, 1997; vol. 1, ch. 13iii, 506–515.
28.
“Syntheses, structures and electrochemistry of [CuL1(LR)]BF4 [L1 = 3-(2,5dimethoxyphenyl)-1-(2-pyridyl)pyrazole; LR = tris(3-arylpyrazolyl)hydroborate] and
[CuL12][BF4]2. Effects of graphitic interactions on the stability of an aryl radical
cation”, M.A. Halcrow*, E.J.L. McInnes, F.E. Mabbs, I.J. Scowen, M. McPartlin, H.R.
Powell and J.E. Davies, J. Chem. Soc., Dalton Trans. (special issue on Bioinorganic
Chemistry), 1997, 4025–4035. View paper
27.
“The reactivity of CuX2 (X– = Cl–, Br–, MeCO2–) salts towards tris-pyrazolylborates of
differing steric requirements. The single crystal X-ray structure of
[CuCl(pzPhH)(HB{pzPh}3)]·CH2Cl2”, M.A. Halcrow*, J.E. Davies and P.R. Raithby,
Polyhedron, 1997, 16, 1535–1541. View paper
26.
“The noble metals”, M.A. Halcrow*, Annu. Rep. Prog. Chem., Sect. A, 1996, 92, 247–
265. View paper
25.
“One-pot synthesis of a novel tridentate tin(IV) ligand; syntheses and structures of
[BunSn(NC5H4-N,C)3MBr] (M = Li, Cu)”, M.A. Beswick, C.J. Belle, M.K. Davies,
M.A. Halcrow, P.R. Raithby, A. Steiner and D.S. Wright*, Chem. Commun., 1996,
2619–2620. View paper
24.
“Synthesis, molecular structure and palladium(II) and platinum(II) complex chemistry
of 3-(ferrocen-1-yl)-1-(pyridin-2-yl)pyrazole”, R.J. Less, J.L.M. Wicks, N.P.
Chatterton, M.J. Dewey, N.L. Cromhout, M.A. Halcrow* and J.E. Davies, J. Chem.
Soc., Dalton Trans., 1996, 4055–4061. View paper
23.
“Role of bifunctional N/S bridging in the association of metals; syntheses and
structures of heterobimetallic [(Ph3P)2CuL2Li(thf)2]·thf and tetrameric [{CuL(PPh3)}4]
(L = 1,3-benzoxazoline-2-thionate, thf = tetrahydrofuran)”, M.A. Beswick, C. Brasse,
M.A. Halcrow, P.R. Raithby, C.A. Russell, R. Snaith, A. Steiner and D.S. Wright*, J.
Chem. Soc., Dalton Trans., 1996, 3793–3797. View paper
22.
“Tautomerism in 3{5}-(dimethoxyphenyl)pyrazoles”, M.A. Halcrow*, H.R. Powell
and M.J. Duer, Acta Crystallogr., Sect. B, 1996, 52, 746–752. View paper
21.
“Structural and magnetic properties of [Ni4(3-OMe)4(dbm)4(MeOH)4] and [Ni4(1,3N3)4(dbm)4(EtOH)4]. Magnetostructural correlations for [Ni4(X)4]4+ cubane
complexes”, M.A. Halcrow, J.-S. Sun, J.C. Huffman and G. Christou*, Inorg. Chem.,
1995, 34, 4167–4177. View paper
20.
“[Mn6O2{O2C-3,5-(NO2)2-C6H3}10(C5H5N)2{(CH3)2CO}2].2(CH3)2CO.2(C2H5)2O and
[Mn6O2(O2CC6H5)10(CH3CN)4]”, M.A. Halcrow, W.E. Streib, K. Folting and G.
Christou*, Acta Crystallogr., Sect. C, 1995, 51, 1263–1267. View paper
19.
“The structure of the D. gigas [NiFe] hydrogenase and the nature of the hydrogenase
nickel complex”, M.A. Halcrow*, Angew. Chem., Int. Ed., 1995, 34, 1193–1195. View
paper
18.
“A nickel (II) azide cubane: characterization of the magnetic exchange interactions
mediated by a triply-bridging azide group bound end-on”, M.A. Halcrow, J.C.
Huffman and G. Christou*, Angew. Chem., Int. Ed., 1995, 34, 889–891. View paper
17.
“Biomimetic chemistry of nickel”, M.A. Halcrow* and G. Christou, Chem. Rev., 1994,
94, 2421–2481. View paper
16.
“Synthesis, characterization and molecular structure of the new S2O complex
Mo(S2O)(S2CNEt2)3·½Et2O”, M.A. Halcrow, J.C. Huffman and G. Christou*, Inorg.
Chem., 1994, 33, 3639–3644. View paper
15.
“Synthesis of cationic half-sandwich rhodium (I) complexes of 1,4,7-trithiacyclononane
([9]aneS3). The single crystal structures of [Rh([9]aneS3)(C2H4)2]PF6,
[Rh([9]aneS3)(C8H12)]BF4 and [Rh([9]aneS3)(C4H6)]PF6·0.25OEt2”, A.J. Blake, R.O.
Gould, M.A. Halcrow and M. Schröder*, J. Chem. Soc., Dalton Trans., 1994, 2197–
2208. View paper
14.
“Organometallic macrocyclic chemistry: synthesis of cationic half-sandwich iridium (I)
complexes of 1,4,7-trithiacyclononane ([9]aneS3). Crystal structures of
[Ir([9]aneS3)(C2H4)2]PF6, [Ir([9]aneS3)(C8H12)]PF6 and
[Ir([9]aneS3)(C4H6)]PF6·0.5Et2O”, A.J. Blake, M.A. Halcrow and M. Schröder*, J.
Chem. Soc., Dalton Trans., 1994, 1631–1639. View paper
13.
“Nickel thioether chemistry: syntheses and crystal structures of [Ni2(L)2(-Cl)2][BF4]2
(L = 1,4,7,10-tetrathiacyclododecane, 1,4,8,11-tetrathiacyclotetradecane or 1,5,9,13tetrathiacyclohexadecane)”, A.J. Blake, M.A. Halcrow and M. Schröder*, J. Chem.
Soc., Dalton Trans., 1994, 1463–1470. View paper
12.
“Nickel thioether chemistry: synthesis, structures and electrochemistry of fivecoordinate nickel(II) complexes of [9]aneS3. Crystal structures of
[Ni([9]aneS3)(dppm)][PF6]2, [Ni([9]aneS3)(dcpe)][PF6]2.1.25MeCN and
[Ni([9]aneS3)(tdpme)][PF6]2 {[9]aneS3 = 1,4,7-trithiacyclononane, dppm =
Ph2PCH2PPh2, dcpe = (C6H11)2PC2H4-P(C6H11)2, tdpme = CH3C(CH2PPh2)3}”, A.J.
Blake, R.O. Gould, M.A. Halcrow and M. Schröder*, J. Chem. Soc., Dalton Trans.,
1993, 2909–2920. View paper
11.
“Conformational studies on [16]aneS4. Structures of - and -[16]aneS4 ([16]aneS4 =
1,5,9,13-tetrathiacyclohexadecane)”, A.J. Blake, R.O. Gould, M.A. Halcrow and M.
Schröder*, Acta Crystallogr., Sect. B, 1993, 49, 773–779. View paper
10.
“Selective aromatization of the A-ring of steroids through C–C, C–H and C–O bond
activation by an electrophilic ruthenium complex”, F. Urbanos, M.A. Halcrow, J.
Fernandez-Baeza, F. Dahan, D. Labroue and B. Chaudret*, J. Am. Chem. Soc., 1993,
115, 3484–3493. View paper
9.
“Crystal structure of (1,4,7-trithiacyclononane)(1,2bis(diphenylphosphino)ethane)nickel(II) bis(tetrafluoroborate),
C32H36NiP2S3(BF4)2(H2O)0.4”, A.J. Blake, M.A. Halcrow and M. Schröder*, Z.
Kristallogr., 1993, 205, 295–299.
8.
“Tris-pyrazolyl-borate dihydrogen complexes of ruthenium”, M.A. Halcrow, B.
Chaudret* and S. Trofimenko, J. Chem. Soc., Chem. Commun., 1993, 465–467. View
paper
7.
“Aromatization of the B-ring of 5,7-dienyl steroids by the electrophilic ruthenium
fragment [Cp*Ru]+”, M.A. Halcrow, F. Urbanos and B. Chaudret*, Organometallics,
1993, 12, 955–957. View paper
6.
“[Rh([9]aneS3)(CO)(PPh3)]+.PF6–”, A.J. Blake, M.A. Halcrow and M. Schröder*, Acta
Crystallogr., Sect. C, 1993, 49, 85–87. View paper
5.
“Nickel thioether chemistry: a re-examination of the electrochemistry of
[Ni([9]aneS3)2]3+. The single-crystal X-ray structure of a nickel(III) thioether complex,
[NiIII([9]aneS3)2][H5O2]3[ClO4]6 ([9]aneS3 = 1,4,7-trithiacyclononane)”, A.J. Blake,
R.O. Gould, M.A. Halcrow, A.J. Holder, T.I. Hyde and M. Schröder*, J. Chem. Soc.,
Dalton Trans., 1992, 3427–3431. View paper
4.
“Tri--chloro-bis(1,4,7-trithiacyclononane)dinickel(II) tetrafluoroborate acetonitrile
solvate”, A.J. Blake, M.A. Halcrow and M. Schröder*, Acta Crystallogr., Sect. C,
1992, 48, 1844–1846. View paper
3.
“Nickel thioether chemistry: syntheses of nickel(II) complexes of tetra- and pentathia
macrocyclic ligands. The single crystal structures of [Ni([16]aneS4)(OH2)2][BF4]2 and
[Ni([15]aneS5)][PF6]2 ([16]aneS4 = 1,5,9,13-tetrathiacyclohexadecane, [15]aneS5 =
1,4,7,10,13-pentathiacyclopentadecane)”, A.J. Blake, M.A. Halcrow and M.
Schröder*, J. Chem. Soc., Dalton Trans., 1992, 2803–2808. View paper
2.
“Synthesis, structure and reactivity of cationic rhodium(I) and iridium(I) thioether
crowns: structures of [M([9]aneS3)(cod)]+ (M = Rh, Ir; cod = cycloocta-1,5-diene) and
[Rh([9]aneS3)(C2H4)2]+ ([9]aneS3 = 1,4,7-trithiacyclononane)”, A.J. Blake, M.A.
Halcrow and M. Schröder*, J. Chem. Soc., Chem. Commun., 1991, 253–256. View
paper
1.
“The kinetics of crystal growth in the presence of tailor-made additives”, S.N. Black,
R.J. Davey* and M. Halcrow, J. Crystal Growth, 1986, 79, 765–774. View paper
Book Reviews
160. “Molecular orbitals of transition metal complexes (Y. Jean, Oxford University Press,
2005)”, M.A. Halcrow, Chemistry World, 2005, 2(8), 54. View paper
161. “Metal sites in proteins and models: phosphatases, Lewis acids and vanadium (eds.
H.A.O. Hill, P.J. Sadler and A.J. Thomson, Springer Verlag, 1997)”, M.A. Halcrow,
Appl. Organomet. Chem., 1999, 13, 480. View paper