Enviro Acid Flush Page 1 of 7 MATERIAL SAFETY DATA SHEET IDENTIFICATION Product Name: ENVIRO ACID FLUSH STATEMENT OF HAZARDOUS NATURE HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA Trade Name: Other Names: Manufacturers Code: Use: U.N. Number: Dangerous Good Class/ & Subsidiary Risk: Hazchem Code: Poison Schedule: NZS3 Disinfectant/cleaner in liquid concentrate form. Physical Description/Properties Specific Gravity: Flash Point (deg C): Lower Explosive Limit (%): Upper Explosive Limit (%): Solubility in Water (g/L): Not available Not applicable Not applicable Not applicable Miscible Ingredients Chemical Entity (Include all hazardous Ingredients) Phosphoric Acid CAS No. 7664-38-2 Quaternary Ammonium Compound Acid Unregulated Water (High 60%) (Medium 10% - 60%) (Low 10%) 5-15% 1-10% <1% >60% NOTE: Manufacturer has supplied full ingredient information to allow CHEMWATCH assessment. Chemwatch Hazard Ratings Flammability: Toxicity: Body Contact: Reactivity: SCALE: 0 1 2 0 Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Enviro Acid Flush Page 2 of 7 HEALTH HAZARD INFORMATION Acute Health Effects Swallowed: Considered an unlikely route of entry in commercial/industrial environments. The liquid is discomforting and may be harmful if swallowed and is capable of causing burns to mouth, throat, oesophagus, with extreme discomfort, pain if swallowed in quantity. Ingestion may result in nausea, abdominal irritation, pain and vomiting. Eye: The liquid is highly discomforting to the eyes and is capable of causing pain and severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of vision, if not promptly and adequately treated. The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. Skin: The liquid is discomforting to the skin and is capable of causing skin sensitization and skin reactions, which may lead to dermatitis from repeated exposures over long periods. Bare unprotected skin should not be exposed to this material. The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterized by skin redness (erythema) and swelling (oedema) which may progress to vesiculation, scaling and thickening of the epidermis. Histological there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epideriias. Contact with broken skin can be painful. Inhaled: Not normally a hazard due to non—volatile nature of product. The mist is discomforting to the upper respiratory tract and may cause breathing difficulty. Chronic Health Effects Primary route of exposure is usually by skin contact. As with any chemical product, contact with unprotected. Bare skin; inhalation of vapour, mist or dust in work place atmosphere; or ingestion in any form, should be avoided by observing good occupational work practice. Enviro Acid Flush This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Page 3 of 7 First Aid Swallowed: Eye: If poisoning occurs, contact a doctor or Poisons Information Centre. In Australia phone 13 1126; New Zealand 03 4747000. If swallowed, do NOT induce vomiting. Give a glass of water. If this product comes in contact with the eyes: Immediately hold the eyes open and wash continuously for at least 15 minutes with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Skin: If product comes in contact with the skin: Immediately remove all contaminated clothing, including footwear (after rinsing with water). Wash affected areas thoroughly with water (and soap if available). Seek medical attention in event of irritation. Inhaled: If fumes or combustion products are inhaled: Remove to fresh air. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag—valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. PRECAUTIONS FOR USE Advice to Doctor: Treat symptomatically. Exposure Standards: None assigned. Refer to individual constituents. <Phosphoric acid> TLV TWA: 1 mg/m3; STEL: 3 mg/m3 ES TWA: 1 mg/m3; STEL: 3 mg/m3 OES STEL: 2 mg/m3 IDLH Level: 1000 mg/m3 Enviro Acid Flush This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Page 4 of 7 The saturated vapour concentration of phosphoric acid exceeds the TLV. The TLV-TWA is based by analogy from comparable experience and data for sulfuric acid. Exposure at or below this limit is thought to prevent throatirritation amongst unacclimatised workers. Fumes of phosphorus pentoxideat concentrations between 0.8 and 5.4 mg/m3 were reported to be noticeable but not uncomfortable whilst concentrations between 3.6 and 11.3 mg/m3 produced coughing in unacclimatised workers but were tolerable. Concentrations of 100 mg/m3 were unbearable except in inured workers. ENGINEERING CONTROLS General exhaust is adequate under normal operating conditions.If risk of overexposure exists, wear SAA. approved respirator.Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. PERSONAL PROTECTION Eyes: Safety glasses with side shields; or as required, Chemical goggles. Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them. Hands/Feet: Butyl rubber gloves. Rubber gloves. PVC gloves. Other: Overalls. Eyewash unit. GLOVE SELECTION INDEX Glove selection is based on a modified presentation of the “Forsberg Protective Clothing Performance Index.” The effect of the following substance(s) is taken into account in the computer—generated selection. Substance ------------------------------------water phosphoric acid Protective Material CPI* ------------------------------------NEOPRENE A NATURAL RUBBER C CPI*:— Chemwatch Performance Index A :— Best Selection B :— Satisfactory; may degrade after 4 hours continuous immersion C :— Poor to Dangerous Choice for other than short term immersion Note: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. Enviro Acid Flush This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Page 5 of 7 RESPIRATOR Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important. Breathing Zone Maximum Level ppm (volume) Protection Factor 1000 1000 5000 5000 10000 10 50 50 100 100 100+ Half-face Respirator Full-Face Respirator B —AUS P Airline* - B - AUS P B -2P B -3P Airline ** * — Continuous Flow ** — Continuous—flow or positive pressure demand. The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information, consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor. NEW ZEALAND POISONS INFORMATION CENTRE Dunedin: (03) 479 1200 (Normal Hours) (03) 474 0999 (Emergency) SAFE HANDLING INFORMATION STORAGE AND TRANSPORT Suitable Container Polyethylene or polypropylene container. Plastic carboy Plastic drum Polyliner drum Packing as recommended by manufacturer Check all containers are clearly labelled and free from leaks. Storage Incompatibility Segregate from alkalies, oxidising agents and chemicals readily decomposed by acids, i.e. cyanides, sulfides, carbonates. Enviro Acid Flush This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Page 6 of 7 Storage Requirement Store in original containers. Keep containers securely sealed. Store in a cool, dry, well—ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer’s storing and handling recommendations. Transportation No restrictions. SPILLS AND DISPOSAL Minor Spills Slippery when spilt. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite. Wipe up. Place in a suitable labelled container for waste disposal. Major Spills Slippery when spilt. Minor hazard. Clear area of personnel. Alert Fire Brigade and tell them location and nature of hazard. Control personal contact by using protective equipment as required. Prevent spillage from entering drains or water ways. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal. Wash area and prevent runoff into drains or waterways. If contamination of drains or waterways occurs, advise emergency services. Disposal Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Treat and neutralise with slaked lime at an effluent treatment plant. Recycle containers, otherwise dispose of in an authorised landfill. Enviro Acid Flush This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Page 7 of 7 FIRE/EXPLOSION HAZARD Non combustible. Not considered to be a significant fire risk. Expansion or decomposition on heating may lead to violent rupture of containers. Decomposes on heating and may produce toxic fumes of carbon monoxide (CO). May emit acrid smoke. Other decomposition products include phosphorus oxides (POx), chlorides and nitrogen oxides (NOx). Contact Point: (09) 262-0800 Date: 10 JULY 2009 This information is, to the best of our knowledge, true and accurate, but any recommendations or suggestions which may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use.