Diverse Applications of Membrane Extraction in Real-time Water Monitoring Ken Gethard, Ornthida Sae Khow, D. Kow and Somenath Mitra New Jersey Institute Of Technology, Newark, New Jersey 07102. Department of Chemistry and Environmental Science Abstract The increasing needs for inexpensive, real-time monitoring devices have added new impetus to developing chemical analysis systems that integrate sampling, sample preparation and detection. One way to enhance sensitivity in these measurements is to provide concentration, and/or extraction along with other functionalities. The goal is to integrate these components to develop total analytical systems for on-line, real-time analysis This presentation covers some recent developments in our group including membrane sampling and microconcentration techniques (1-4). The water monitoring devices developed here can be used as, laboratory instruments, field analytical and as online monitoring devices. Applications in the monitoring of different classes of compounds are covered that include volatile organics, semi-volatile organics, haloacetic acids, pesticides, pharmaceutical products and metals. Microfabricated devices using MEMS technology have also been developed, which can lead to miniaturization. References: 1. 2. 3. 4. “Automated analysis via membrane extraction”. K. Hylton and S. Mitra. In Press, J. of Chromatogr. (A), 2007, doi:10.1016/jchroma.2006.12.04. “Development of supported liquid membrane microextraction for the trace determination of haloacetic acids”. D. Kou and S. Mitra, J. of Chromatogr. A, 1055, 63-69 (2004). “Gas Injection Membrane Extraction with Fast On-line Analysis with GC Detection”. D. Kou, A. San Juan and S. Mitra, Anal. Chem., 73-22, 5462, (2001). “Development of total analytical system by online Coupling of Membrane Extraction with Membrane Pervaporation”. Xiaoyan Wang and Somenath Mitra. J. of . Chromatogr. A. 1068, 237242 (2005).