國立成功大學課程大綱及進度表
航空太空工程學系
授課教師： 高騏
課程碼：P473400
課程名稱：
(中文) 奈米材料合成與奈米技術
(英文) Synthesis of Nanomaterials and
Nanotechnologies
研究所：■碩，■博
先修課程：
學分數 3
□必修，■選修
課程教學目標：
課程大綱：
1. Introduction
1.1 Emergence of Nanotechnology
1.2 Strategy of Nanotechnology Development in Other Countries
1.3 Applications in Various Areas
1.4 Bottom-Up and Top-Down Approaches
1.5 Related Fundamental Theory
1.6 Some Properties of Nanomaterials
1.7 Brief Review of Nanotechnology in Various Areas
2. Physical Chemistry of Solid Surfaces
2.1 Introduction
2.2 Surface Energy
2.3 Chemical Potential as a Function of Surface Curvature
2.4 Electrostatic Stabilization
2.4.1 Surface charge density
2.4.2 Electric Potential at the proximity of solid surface
2.4.3 Van der Waals attraction potential
2.4.4 Interactions between two particles: DLVO theory
2.5 Steric Stabilization
2.5.1 Solvent polymer
2.5.2 Interactions between polymer layers
2.5.3 Mixed steric and electric interactions
3. Nanoparticles
3.1 Properties of Nanoparticles
3.2 Nanoparticles through homogeneous nucleation
3.2.1 Fundamentals of homogeneous nucleation
3.2.2 Subsequent growth of nuclei
3.2.2.1 Growth controlled by diffusion
3.2.2.2 Growth controlled by surface process
3.2.3 Synthesis of metallic nanopaticles
3.2.3.1 Influences of reduction reagents
3.2.3.2 Influences of other factors
3.2.3.3 Influences of polymer stabilizer
3.2.4 Synthesis of Semiconducting Nanoparticles
3.2.5 Synthesis of oxide nanoparticles
3.2.5.1 Introduction to sol-gel processing
3.2.5.2 Forced hydrolysis
3.2.5.3 Controlled release of ions
講義 3 小時，實習 小時，上
機 小時
□上學期，■下學期
3.2.6 Vapor phase reactions
3.2.7 Solid state phase segregation
3.3 Nanoparticles Through Heterogeneous Nucleation
3.3.1 Fundamentals of heterogeneous nucleation
3.3.2 Synthesis of nanoparticles
3.4 Kinetically Confined Synthesis of Nanoparticles
3.4.1 Synthesis inside micelles or using microemusions
3.4.2 Aerosol synthesis
3.4.3 Grwoth termination
3.4.4 Spray pyrolysis
3.4.5 Template-based synthesis
4. Nanowires and Nanorods
4.1 Introductions
4.2 Synthesis
4.3 Spontaneous Growth
4.3.1 Evaporation – Condensation Growth
4.3.2 Vapor – Liquid – Solid Growth
4.3.2.1 Fundamentals
4.3.2.2 VLS growth of various nanowires
4.3.2.3 Oxide assisted growth of nanowires
4.3.3 Solution – Liquid – Solid Growth
4.3.4 Control of the Size of Nanowire
4.3.5 Precursors and Catalysis
4.4 Template – Based Synthesis
4.4.1 Electrochemical Deposition
4.4.2 Template Filling
4.5 Characterization and Physical Properties of Nanowires
4.6 Applications
Midterm
5. Carbon Nanotubes
5.1 Introduction
5.2 Carbon Molecules
5.3 Special properties of Carbon Nanotubes
5.4 Important Applications
5.5 Synthesis of Carbon Nanotubes
5.6 Methods of Characterization
5.7 Symmetry and Charity
5.8 Band Gaps of Carbon Nanotubes
5.9 Fundamentals of Raman Spectroscopy
5.10 Different modes of Phonon in Carbon Nanotubes
5.10.1 Radial breathing mode
5.10.2 G-band
5.10.3 D-band
5.10.4 G*-band
5.11 Summary
6. Thin Films
6.1 Introduction
6.2 Fundamentals of Film Growth
6.3 Vacuum Science
6.4 Physical Vapor Deposition
6.4.1 Evaporation
6.4.2 Molecular beam epitaxy
6.4.3 Sputtering
6.5 Chemical Vapor Deposition
6.5.1 Fundamentals of growth process
6.5.2 Growth by transport process
6.5.3 Growth by surface reaction kinetics
6.5.4 PECVD and HDPCVD process
6.6 Atomic Layer Deposition
6.7 Self-Assembly
6.7.1 Monolayers of organosilicon or alkylsilane derivatives
6.7.2 Monolayers of alkanethiols and sulfides
6.7.3 Monolayers of carboxylic acids, amines and alcohols
6.8 Langmuir-Blodgett Films
6.9 Electrochemical Deposition
7. Nanostructure Fabricated by Physical Techniques
7.1 Introduction
7.2 Lithography
7.2.1 Photolithography
7.2.2 Phase-shifting Photolithography
7.2.3 Electron Beam Lithography
7.2.4 X-ray Lithography
7.2.5 Focused Ion Beam Lithography
7.3 Nanomanipulation and Nanolithography
7.3.1 Scaning Tunneling Microscopy
7.3.2 Atomic Force Microscopy
7.3.3 Near – Field Scanning Optical Microscopy
7.3.4 Nanomanipulation and Nanolithography
7.4 Soft Lithography
7.4.1 Microcontact Printing
7.4.2 Molding
7.4.3 Nanoimprint
7.4.4 Dip – Pen Nanolithography
7.5 Assembly of Nanoparticles and Nanowires
8. Characterization and Properties of Nanomaterials
8.1 Introduction
8.2 Structure Characterization
8.2.1 X-ray Diffraction
8.2.2 Small Angle X-ray Scattering
8.2.3 Scanning Electron Microscopy
8.2.4 Transmission Electron Microscopy
8.2.5 Scanning Probe Microscopy
8.3 Chemical Characterization
8.3.1 Optical Spectroscopy
8.3.2 Electron Spectroscopy
Final Project Report
課程進度：
教科書 (作者，書名，出版者，出版日期)
參考書目 (作者，書名，出版者，出版日期)
評分項目及標準