CONFERENCE PROGRAM SUMMARY Day Morning Sunday Monday Afternoon Thermodynamics Jill Buckley* Tuesday Emulsions Johan Sjöblom* Wednesday Waxes Klaus Weispfennig* Registration Macromolecules Peter Kilpatrick* Excursion Bill Power* Upgrading Murray Gray* Thursday Departure * # Production Harvey Yarranton* Event organizer Chair Evening Mixer Posters Shawn Taylor* Conference dinner Asphaltene standardization discussion / Posters THERMODYNAMICS, Monday, June 14th, morning 1 Time 8:15 – 8:55 Authors Jefferson L. Creek 2 8:55 – 9:20 3 9:20 – 9 45 4 9:45 – 10:10 5 10:10 – 10 30 10:30 – 10:55 6 10.55 – 11:20 7 11:20 – 11:45 8 11:45 – 12:10 S. Correra, F. Capuano, N. Panariti Yadolla Maham, Martin Chodakowski, Xiaohui Zhang and John M. Shaw Doris L. Gonzalez , David P. Ting, George J. Hirasaki, and Walter G. Chapman Coffee break Kurt A. G. Schmidt, Sergio E. Quiñones-Cisneros, Bjørn Kvamme, and Erling H. Stenby Niels Lindeloff, Abul K. M. Jamaluddin and Karen S. Pedersen N. Impens, J. Van Laer, R. Vandevoorde Keith L. Gawrys and Peter K. Kilpatrick Return to program summary Title Keynote: ☺Freedom of action in the state of asphaltenes: escape from conventional wisdom ☺Onset of Asphaltene Precipitation: Analysis of Measurement Methods ☺Asphaltene phase behavior ☺Prediction of asphaltene instability under pressure depletion and gas injection using the SAFT EOS ☺Density and viscosity behaviour of a North Sea crude oil, natural gas liquid and their mixtures ☺Upstream live oil asphaltene modeling ☺Stability of concentrated bitumen-salt-solvent mixtures ☺Small-angle neutron scattering determination of second virial coefficients for asphaltenes in the presence of various dispersants MACROMOLECULES, Monday, June 14th, afternoon 9 Time 13:15 – 13:55 Authors Oliver Mullins 10 13:55 – 14:20 11 14:20 – 14 45 12 14:45 – 15:10 Piyarat Wattana, H Scott Fogler, and Andrew Yen Ryan P. Rodgers, Geoffrey C. Klein, Lateefah A. Stanford and Alan G. Marshall J.M Sheremata, M.R. Gray and W.C. McCaffrey 15:10 – 15 30 15:30 – 15:55 Coffee break Eric B. Sirota Title Keynote: ☺Molecular structure and primary aggregation of asphaltenes ☺Characterization of polarity based asphaltene subfractions ☺Petroleomics: FT-ICR high resolution mass spectral analysis of petroleum derived materials ☺Development and refinement of quantitative molecular representations of Athabasca vacuum residue ☺Understanding the physical structure of asphaltenes 14 15.55 – 16:20 Arnaud Lager, Barry Bennett , ☺Petroleum sample instability: implications for Steve Larter “asphaltene” description 15 16:20 – 16:45 Haruo Kumagai, Ryuzo ☺Kinetic study of asphaltene aggregates Tanaka and Tadatoshi Chiba dissociation by means of pulse 1H-NMR 16 15:45 – 17:10 Géza Horváth-Szabó, Jacob ☺Is there any water pool in asphaltene micelles? H. Masliyah Return to program summary 13 POSTERS, Monday, June 14th, evening EMULSIONS, Tuesday, June 15th, morning 17 Time 8:15 – 8:55 18 19 8:55 – 9:20 9:20 – 9 45 Authors Clayton Radke Stig E. Friberg Géza Horváth-Szabó, Jacob H. Masliyah, Janet A. W. Elliott, Harvey W. Yarranton, and Jan Czarnecki 20 9:45 – 10:10 S. Poteau, J-F. Argillier, D. Langevin 10:10 – 10 30 Coffee break 21 10:30 – 10:55 R.C.G. Oliveira, M.C.K. Oliveira 22 10.55 – 11:20 Alejandro A. Peña, George J. Hirasaki, and Clarence A. Miller 23 11:20 – 11:45 Paul M. Lindemuth and Neil Grainger 24 11:45 – 12:10 A.P. Sullivan, N.N. Zaki, J. Sjöblom, M.L. Marques and P.K. Kilpatrick Return to program summary Title Keynote: ☺Asphaltene adsorption at the crude oil/water interface: Implications for emulsion stability and wettability alteration ☺Hydrotropes - Performance Chemicals ☺Thermodynamic characterization of adsorption layers of crude components at aqueous / oleic interfaces: adsorption isotherms of associating asphaltenes ☺Influence of pH on dynamic properties of asphaltenes and surfactants at the oil-water interface ☺The impact of the droplet size distribution on the crude oil emulsion flow insurance ☺On the mechanism of demulsification of oilfield emulsions by chemical treatment ☺Oilfield vs. refinery demulsification: learning from the differences ☺The stability of water-in-crude and model oil emulsions WAXES, Wednesday, June 16th, morning 25 Time 8:15 – 8:55 Authors George Broze 26 8:55 – 9:20 Xiaoli Yang and Peter Kilpatrick 27 9:20 – 9 45 Nitin V. Bhat and Anil K. Mehrotra 28 9:45 – 10:10 29 10:10 – 10:30 10:30 – 10:55 Mohammed Zougari, George Broze, Adbel Kharrat, Nick Fuex, Moin Muhammad, and Ahmed Hammami Coffee break David W. Jennings and Klaus Weispfennig 30 10.55 – 11:20 Jamal Ibrahim, Peter Toma, John Ivory, Gerard Korpany, Mario de Rocco, Larry Holloway 31 11:20 – 11:45 Kristofer G. Paso and H. Scott Fogler 32 11:45 – 12:10 Gian-Paolo Borghi and Sebastiano Correra Return to program summary Title Keynote: ☺Wax deposition: essential physics for accurate modeling ☺Isolation and characterization of asphaltenes and waxes from solid organic deposits: relationship to parent crude petroleum ☺Phase behavior of wax-solvent mixtures between wax disappearance temperature (WDT) and wax appearance temperature (WAT) ☺Wax deposition from GOM waxy crude: A parametric study ☺Effects of shear & temperature on wax deposition: cold finger investigation with a GOM crude oil ☺Direct observations on paraffin deposition mechanism under laminar and turbulent flow for direct applications to paraffin oil transportation ☺Bulk stabilization in wax deposition systems ☺A new gelled oil restart model UPGRADING, Wednesday, June 16th, afternoon 33 Time 13:15 – 13:55 34 13:55 – 14:20 35 14:20 – 14 45 36 14:45 – 15:10 37 15:10 – 15 30 15:30 – 15:55 38 15.55 – 16:20 39 16:20 – 16:45 Authors Isao Mochida, Yosuke Kinoshita, Masahito Kuramae, Ki-Hyouk Choi and Yozo Korai Pedro R. Pereira, Igzobel Castro, Maria L. Frauwallner, Carmen Galarraga, Jimmy Castillo, Maria A. Ranaudo Adrienne M. Inman, Sara L. Salmon, Heather D. Dettman, Kerry T. Scott, and Bryan J. Fuhr Dai-wei Gao, Jin-sen Gao, Chunming Xu Coffee break Christopher A. Bennett, Thomas M. Rudy, Himanshu M. Joshi, Tin Yin Lam, and Dave C. King Hong E and Paul Watkinson Wim M. Bond, Fred A.A. Hoeve, Don F. Mulder, Sacha Imamkhan, Erwin H. Munsterman and Frans G.A. van den Berg 40 15:45 – 17:10 Sanyi Wang, Dale Nesbitt, Larry Paul, Eric Axcell, Virgil Little and Ron Bosch Return to program summary Title Keynote: ☺Unexpected problems caused by dry sludge in the upgrading processes of petroleum products ☺Comparison of asphaltenes processed under thermal conversion and catalytic steam cracking ☺Characterization of asphaltene fractions from gel permeation chromatography using NMR spectroscopy, high temperature simulated distillation and vapor pressure osmometry ☺Study of coking mechanisms of the heavy fraction of FCC slurry ☺Industry-recommended procedures for crude oil fouling research ☺Heat Exchanger Fouling in Heavy Oil Systems ☺Integrated approaches to fouling abatement in crude oil heat exchanger trains ☺Mitigation of heat exchanger fouling in a SAGD pilot plant ASPHALTENE STANDARDIZATION DISCUSSION and POSTERS, Wednesday, June 16th, evening PRODUCTION, Thursday, June 17th, morning 41 Time 8:15 – 8:55 42 8:55 – 9:20 43 9:20 – 9 45 44 9:45 – 10:10 45 10:10 – 10 30 10:30 – 10:55 46 10.55 – 11:20 47 11:20 – 11:45 Authors J. Ratulowski, A. Hammami, M. Muhammad and M. Zougari Matthew Flannery, Peter Cornelisse, Nancy Utech, and Nick Fuex Yongsheng Zhang, Jianxin Wang, Norman R. Morrow, and Jill S. Buckley Moin Muhammad, Nikhil Joshi, Jeff Creek, and Jim McFadden Coffee break Francois Gelin, Mark Grutters, Peter Cornelisse and Shawn Taylor Hussein Alboudwarej, David Pole, William Y. Svrcek, Harvey W. Yarranton Kunal Karan and Kui Xie 48 11:45 – 12:10 Sen J. Ubbels Return to program summary Title Keynote: ☺Flow assurance implications of asphaltene precipatation and deposition ☺Impact of asphaltene stability on commingled production design: A deepwater Gulf of Mexico case study ☺Effect of synthetic drilling fluid base oils on asphaltene stability and wetting in sandstone cores ☺Effect of oil based mud contamination on live fluid asphaltene precipitation pressure ☺Asphaltene precipitation from live oil containing emulsified water ☺Adsorption of Asphaltenes on Metals ☺A study of asphaltene adsorption on metal surfaces using quartz crystal microbalance ☺Preventing naphthenate stabilised emulsions and naphthenate deposits during crude oil processing GENERAL TOPICS POSTER SESSION Please check after March 31, 2004 for your assigned Poster ID and Room . Poster ID & Room No 49 50 51 52 53 54 55 56 57 58 59 60 61 Authors Title Jianxin Wang and Jill S. Buckley Douglas Fisher, Nintoku Yazawa, Hemanta Sarma, Marcel Girard, Haibo Huang Kamran Akbarzadeh, Hussein Alboudwarej, William Y. Svrcek, Harvey W. Yarranton Hélène Buron, Pascal Bru, Jim Munhall Haibo Huang, Douglas Fisher, Ted Frauenfeld and Kevin Rispler ☺Solubility conditions at the onset of asphaltene flocculation ☺Size and Shape Characterization of Asphaltene Particles during Precipitation and Flocculation ☺Towards generalization of the regular solution model for predicting asphaltene precipitation from n-alkane diluted heavy oils ☺Asphaltenes stability in crude oil and heavy fuel ☺Asphaltene precipitation/flocculation behavior in heavy oils mixed with aliphatic solvents ☺Comparison of bitumen fractionation methods Bryan J. Fuhr, Craig Hawrelechko, Larry R. Holloway and Haibo Huang Y. Wen, A. Kantzas, and G. Wang ☺Estimation of diffusion coefficients in bitumen solvent mixtures using x-ray cat scanning and low field NMR Marek Rogalski, Pierre ☺Scanning calorimetry of crude Magri and Gédeon Ekulu oils Emmanuel Behar ☺Physico-chemical characterization of unstable asphaltenic reservoir crudes C. Pierre, I. Hénaut and ☺Comparative organization of J-F. Argillier asphaltenes and resins in model solvent and in heavy oil Juan Pereira, Edgar ☺Interaction study of resins with Carrasquero, Leyan Becerrit colloidal fractions of asphaltene Toshimasa Takanohashi, ☺Molecular dynamics simulation Shinya Sato, Ikuo Saito and of structural relaxation for Ryuzo Tanaka asphaltene aggregates in solvents Alexandre N.M. Carauta, ☺Modeling the effect of solvents Julio C.G. Correia, Daniel M. on asphaltene aggregates 62 63 64 65 66 67 68 69 70 71 72 73 74 75 Silva, Peter R. Seidl, Erika C.A.N. Chrisman, Sonia M.C. de Menezes, Wladimir F. de Souza, Marco A.G. Teixeira Peter R. Seidl, Erika C.A.N. Chrisman, Príscila O. Menechini, Katia Z. Leal, Sonia M.C. de Menezes D. Kvostichenko and S.I.Andersen ☺Modeling structures from NMR data ☺Investigations of electrodeposition of asphaltenes and asphaltenic subfractions Géza Horváth-Szabó, Jacob ☺Water promotion and maltene H. Masliyah, and Jan inhibition on asphaltene Czarnecki association Henry Labrador, María ☺The amphiphiles effect of Arrázola, Carlos Berroterán, natural and synthetical upon the and Juan Pereira asphaltenes of Monagas crude oils (Venezuela) Fabricio Arteaga-Larios, Eric ☺Two dimensional asphaltene Y. Sheu, Elias Pérez precipitations Abdel M. Kharrat ☺Critical assessment of selected sara methodologies K. K. (Adry) Bissada, Ewa ☺Enhanced SARA and pin groupB. Szymczyk, and David G. type separations and quantification Nolte - in crude-oil and condensate characterization Kenneth M. Barker, and ☺ASTM maximum pour point: Michael E. Newberry What does it really mean? W.M.S. Kassim, H.A. ☺An experimental study of wax Mansoori, E.E. Zorgani deposition in crude oil pipeline. Paul Ross, Stefan Smuk, ☺Quantification of oil based mud John Nighswander filtrate in contaminated reservoir fluid samples A. Cosultchi, B. Zeifert, I. ☺Effect of crude oil adsorption Cordova, M.A. Valenzuela, on natural Montmorillonite P. Bosch, V.H. Lara Zhongxin Huo, Shawn ☺Hydrate equilibrium: prediction Taylor, Moin Muhammad, and measurement and Heng-Joo Ng Alfred Hase ☺Impact of pressure and temperature on different asphaltene solvent / precipitant systems Kevin Moran ☺Coalescence of small bitumen droplets 76 77 78 79 80 81 82 83 84 Sunil L. Kokal, Mohammad Al-Dokhi and Makki Al-Zubail Oswaldo J. Asprino and Murray Gray Michael K. Poindexter, Shannon Chuai, Robert A. Marble, Samuel C. Marsh Liyan Zhao and Phillip Choi Mohammad Al-Dokhi and Sunil L. Kokal Abdullah Al-Ghamdi and Sunil L. Kokal Danuta M. Sztukowski and Harvey W. Yarranton Jonathan Allinson, Barry Bennett, Stephen R. Larter Joseph L. Stark and Samuel Asomaning 85 X.A. Wu and J. Czarnecki 86 Marek Rogalski, Roland Solimando and Ewa Rogalska Li Yan Zhang, Zhenghe Xu and Jacob H Masliyah Yicheng Long, Tadeusz Dabros, and Hassan Hamza 87 88 89 Tadeusz Dabros, Xiaoli Yang, Yicheng Long, and Hassan Hamza ☺Asphaltene precipitation in a saturated, gas-cap reservoir ☺Measurement of contact angle of asphaltenes on different solid surfaces Elucidation of Factors Governing Emulsion Stability ☺A molecular dynamics study of the coalescence of two nanometersized water droplets in an nheptane environment with one being covered by 1naphthalenepentalnoic acid ☺Emulsion studies at reservoir conditions ☺Emulsion separation experience from a large oil field ☺Synergy between asphaltenes and oil sands solids in stabilizing water-in-oil emulsions ☺Role of non-hydrocarbons in crude oil emulsions ☺Synergies between asphaltene stabilizers and demulsifying agents giving improved demulsification of asphaltenestabilized emulsions ☺A thermodynamic model of competitive adsorption of two surface-active species on diluted bitumen-water interface ☺Properties of asphaltene films formed on the water/oil interface ☺Asphaltene monolayers at toluene-water interface ☺Structure of water/solids/asphaltenes aggregates and their settling behavior in solvent-diluted bitumen ☺Settling Properties of SolventDiluted Bitumen Emulsions 90 91 92 93 94 Probjot Singh, William H. Thomason, David Blumer, and Lou Nathanson Xiaoli Yang and Jan Czarnecki E. Musiał, J. Masliyah, S. Bhattacharjee and J. Czarnecki A.R.H. Goodwin, E.P. Donzier, O. Vancauwenberghe, and S. Jacobs Xiaohui Zhang and John M. Shaw 95 A.P. Watkinson 96 Xiaohui Zhang, Bei Zhao and John M. Shaw Return to program summary ☺Flow properties of Alaskan heavy oil emulsions ☺Removal of water and fine solids from Athabasca bitumen ☺Estimation of a critical electric field (CEF) on individual emulsion droplet pairs using conducting micropipette method ☺Micro Electro Mechanical System (MEMS) for the measurement of density and viscosity ☺Dynamic local phase concentration measurements in emulsions, dispersions and slurries ☺A comparison of crude oil fouling using two different laboratory test units ☺Coke formation and catalyst deactivation in hydroprocessing of resides Authors: Akbarzadeh - 51 Al-Dokhi - 76, 80 Al-Ghamdi - 81 Al-Zubail - 76 Alboudwarej - 46, 51 Allinson - 83 Andersen - 63 Argillier - 20, 58 Arrázola - 65 Arteaga-Larios - 66 Asomaning - 84 Asprino - 77 Axcell - 40 Barker - 69 Becerrit - 59 Behar - 57 Bennett - 14, 37, 83 Berg - 39 Berroterán - 65 Bhat - 27 Bhattacharjee - 92 Bissada - 68 Blumer - 90 Bond - 39 Borghi - 32 Bosch - 40, 72 Broze - 25, 28 Bru - 52 Buckley - 43, 49 Buron - 52 Capuano - 2 Carauta - 61 Carrasquero - 59 Castillo - 34 Castro - 34 Chapman - 4 Chiba - 15 Chodakowski - 3 Choi - 33, 79 Chrisman - 61, 62 Chuai - 78 Cordova - 72 Cornelisse - 42, 45 Correia - 61 Correra - 2, 32 Cosultchi - 72 Creek - 1, 44 Czarnecki - 19, 64, 85, 91, 92 Dabros - 88, 89 Dettman - 35 Donzier - 93 E - 38 Ekulu - 56 Elliott - 19 Fisher - 50, 53 Flannery - 42 Fogler - 10, 31 Frauenfeld - 53 Frauwallner - 34 Friberg - 18 Fuex - 28, 42 Fuhr - 35, 54 Galarraga - 34 Gao - 36, 36 Gawrys - 8 Gelin - 45 Girard - 50 Gonzalez - 4 Goodwin - 93 Grainger - 23 Gray - 12, 77 Grutters - 45 Hammami - 28, 41 Hamza - 88, 89 Hase - 74 Hawrelechko - 54 Hirasaki - 4, 22 Hoeve - 39 Holloway - 30, 54 Horváth-Szabó - 16, 19, 64 Huang - 50, 53, 54 Huo - 73 Hénaut - 58 Ibrahim - 30 Imamkhan - 39 Impens - 7 Inman - 35 Ivory - 30 Jacobs - 93 Jamaluddin - 6 Jennings - 29 Joshi - 37, 44 Kantzas - 55 Karan - 47 Kassim - 70 Kharrat - 28, 67 Kilpatrick - 8, 24, 26 King - 37 Kinoshita - 33 Klein - 11 Kokal - 76, 80, 81 Korai - 33 Korpany - 30 Kumagai - 15 Kuramae - 33 Kvamme - 5 Kvostichenko - 63 Labrador - 65 Laer - 7 Lager - 14 Lam - 37 Langevin - 20 Lara - 72 Larter - 14, 83 Leal - 62 Lindeloff - 6 Lindemuth - 23 Little - 40 Long - 88, 89 Magri - 56 Maham - 3 Mansoori - 70 Marble - 78 Marques - 24 Marsh - 78 Marshall - 11 Masliyah - 16, 19, 64, 87, 92 McCaffrey - 12 McFadden - 44 Mehrotra - 27 Menechini - 62 Miller - 22 Mochida - 33 Moran - 75 Morrow - 43 Muhammad - 28, 41, 44, 73 Mulder - 39 Mullins - 9 Munhall - 52 Munsterman - 39 Musiał - 92 Nathanson - 90 Nesbitt - 40 Newberry - 69 Ng - 73 Nighswander - 71 Nolte - 68 Oliveira - 21, 21 Panariti - 2 Paso - 31 Paul - 40 Pedersen - 6 Pereira - 34, 59, 65 Peña - 22 Pierre - 58 Poindexter - 78 Pole - 46 Poteau - 20 Pérez - 66 Quiñones-Cisneros - 5 Radke - 17 Ranaudo - 34 Ratulowski - 41 Rispler - 53 Rodgers - 11 Rogalska - 86 Rogalski - 56, 86 Ross - 71 Rudy - 37 Saito - 60 Salmon - 35 Sarma - 50 Sato - 60 Schmidt - 5 Scott - 35 Seidl - 61, 62 Shaw - 3, 94, 96 Sheremata - 12 Sheu - 66 Silva - 61 Singh - 90 Sirota - 13 Sjöblom - 24 Smuk - 71 Solimando - 86 Stanford - 11 Stark - 84 Stenby - 5 Sullivan - 24 Svrcek - 46, 51 Sztukowski - 82 Szymczyk - 68 Takanohashi - 60 Tanaka - 15, 60 Taylor - 45, 73 Teixeira - 61 Thomason - 90 Ting - 4 Toma - 30 Ubbels - 48 Utech - 42 Valenzuela - 72 Vancauwenberghe - 93 Vandevoorde - 7 Wang - 40, 43, 49, 55 Watkinson - 38, 95 Wattana - 10 Weispfennig - 29 Wen - 55 Wu - 85 Xie - 47 Xu - 36, 87 Yang - 26, 89, 91 Yarranton - 19, 46, 51, 82 Yazawa - 50 Yen - 10 Zaki - 24 Zeifert - 72 Zhang - 3, 43, 87, 94, 96 Zhao - 79, 96 Zorgani - 70 Zougari - 28, 41