SDS Sheet Page 1 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. 1. Identification of the Substance/Mixture and the Company Undertaking Product Identifier Product Name: Chloracoat Rubber Paint Product Code: 1122181050 (Light Blue 5 Litres) 1122182050 (Mid Blue 5 Litres) 1122183050 (White 5 Litres) Relevant Identified Uses of the Substance or Mixture and Uses Advised Against: Application of the substance/ the Preparation: Coating Compound/surface coating/paint Details of the Supplier of the Safety Data Sheet 2. Name of Supplier: Golden Coast Ltd Address of Supplier: Fishleigh Road, Roundswell Commercial Park West, Barnstaple, Devon. EX31 3UA Telephone: 01271 378100. Responsible Person: Jamie Adams Email: swimmer@goldenc.com Emergency Telephone Number 01271 378100 (office hours) Hazards Identification Classification of the Substance or Mixture Classification according to Directive 67/548/EEC or directive 199/45/EC: Xn: Harmful R20/21/22-40-48/20: harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Harmful: Danger of serious damage to health by prolonged exposure through inhalation Xi: Irritant R38 Irritating to skin SDS Sheet Page 2 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. N: Dangerous for the environment R51/53-59: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Dangerous to ozone layer R10: Flammable Information concerning particular hazards for humans and environment: The product has to be labelled due to the calculation procedure of the “General Classification guideline for preparations of the EU” In the latest version. Classification System The classification is according to the latest editions of the EU-lists and extended by company and literature data. Chemical: Xylene (mix) CAS No: 1330-20-7 Chemical: Carbon tetrachloride CAS No: 56-23-5 Label Elements Labelling According to EU Guidelines: The product has been classified and marked in accordance with EU Directives/Ordinance on Hazardous Materials Code Letter and Hazard Xn: Harmful Designation of Product: N: Dangerous to the environment Hazard Determining Chloropolyolefin Components of Labelling: Chlorinated paraffins, C10-13 Carbon tetrachloride Xylene (mix) Risk Phrases: R10 Flammable R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R38 Irritating to skin R40 Limited evidence of a carcinogenic effect R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R59 Dangerous to the ozone layer SDS Sheet Page 3 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Safety Phrases: S9 Keep container in a well-ventilated place S23 Do not breathe fumes/vapour/spray S25 Avoid contact with eyes S36/37 Wear suitable protective clothing and gloves S43 In case of fire, use water or powdered extinguishing agent S59 Refer to manufacturers/supplier for information on recovery/recycling Other Hazards Results of PBT and vPvB assessment 3. PBT: chlorinated paraffins C10-13 vPvB: Chlorinated parrafins C10-13 Composition/Information on Ingredients Chemical Characterization Mixtures Chemical Name: Chloropolyolefin Concentration: 25-50% CAS Number: 9006-03-5 R/H Phrases R20/21/22-48 Symbols: Xn Chemical Name: Xylene (mix) Concentration: 10-25% CAS Number: 1330-20-7 EINECS Number: 215-535-7 R/H Phrases R20/21 R38 R10 Symbols: Chemical Name: Xi; Xn chlorinated paraffins, C10-13 PBT; vPvB Concentration: 2.5-10% R/H Phrases R40 R50/53 Symbols: Xn N Carc. Cat. 3 SDS Sheet Page 4 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Chemical Name: Carbon tetrachloride Concentration: < 2.5% CAS Number: 56-23-5 EINECS Number: 200-262-8 R/H Phrases R23/24/25-48/23 R40 R52/53 R59 Symbols: Xn N T Carc. Cat. 3 4. SVHC: Chlorinated paraffins C10-13 Additional Information: For the wording of the listed risk phrases refer to Section 16 First Aid Measures Description of First Aid Measures General Information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident After Inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist In case of unconsciousness place the patient stably in side position for transportation After Skin Contact: Immediately wash with water and soap rinse thoroughly. After Eye Contact: Rinse opened eye for several minutes under running water After Swallowing: Call for a doctor immediately Information for Doctor: Most Important Symptoms and Effects, both Acute and Delayed: No further relevant information available Indication of Immediate Medical Attention & Special Treatment Needed No further information available SDS Sheet Page 5 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. 5. Fire Fighting Measures Extinguishing Media Suitable extinguishing Media: CO2 powder or water spray. Fighter larger fires with water spray or alcohol resistant foam Unsuitable extinguishing Media: Water with full jet Special Hazards Arising from the Substance or Mixture No further information available Advice for Fire Fighters Special Protective Equipment: 6. Mount respiratory protective device Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures: Personal Protection: Wear protective equipment. Keep unprotected persons away Environmental Precautions: Inform respective authorities in case of seepage into water or sewage system Do not allow to enter sewers/surface or ground water Methods and Material for Containment and Cleaning Up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) Dispose contaminated material as waste according to item 13 Ensure adequate ventilation Reference to Other Sections: See Section 7 for information on safe handling See Section 8 for information on personal protection equipment See Section 13 for disposal information 7. Handling and Storage Precautions for Safe Handling: Keep receptacles tightly sealed Ensure good ventilation Prevent formation of aerosols Information about Fire Keep ignition sources away – DO not smoke And Explosion Protection: Protect against electrostatic charges SDS Sheet Page 6 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Conditions for Safe Storage, Including any Incompatibilities Storage: Requirements to be met by Storerooms and receptacles: No special requirements Information about storage in one Common storage facility: Not required Further Information about 8. Storage Conditions: Keep receptacle tightly sealed Specific End Use(s) No further relevant information available Exposure Controls/Personal Protection Additional information about design of technical facilities: No further data; see item 7 Control Parameters Ingredients with limit values that require monitoring at the workplace Chemical: Xylene (mix) CAS No: 1330-20-7 WEL Long-term value: 220mg/m3 50ppm Short-term value: 441mg/m3 100ppm Chemical: carbon tetrachloride CAS No: 56-23-5 WEL Long-term value: 13mg/m3 2ppm Sk Additional Information: The lists valid during the making were used as basis SDS Sheet Page 7 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Exposure Controls Personal Protective Equipment: General protective and Immediately remove all soiled and contaminated clothing Hygienic measures: Wash hands before breaks and at end of work Keep away from foodstuffs, beverages and feed Avoid contact with the skin Avoid contact with the eyes and skin Respiratory Protection: When spraying the product, use a respiratory protective device Protection of Hands: When skin exposure may occur, advice should be sought from the glove supplier on appropriate types and usage times for this product Protective Gloves The glove material has to be impermeable and resistant to the product/ the substance/the preparation Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of Gloves: The selection of suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of glove material can not be calculated and has therefore to be checked prior to the application Penetration time of glove material: The exact break through time has to be found out by manufacturer of the protective gloves and has to be observed Eye Protection: Tightly sealed goggles 9. Physical and Chemical Properties 9.1 Information on Basic Physical and Chemical Properties General Information: Odour: Characteristic Odour Threshold: not determined Appearance: Fluid Colour According to product specification pH value: Not determined Melting Point: Undetermined SDS Sheet Page 8 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Boiling Point: 137C Vapour Pressure @ 20C: 23 hPa Density @ 20C: 1.731g/cm3 Water Solubility: NOT MISCIBLE Flammability (solid, gaseous): Not applicable Flash Point: 25C Ignition Temperature: 500C Auto Ignition Point: Product is not self igniting Explosive: Product does not present an explosion hazard. However, formations of explosive air/vapour mixtures are possible Lower Explosion Limit: 1.1 Vol % Upper: Explosion Limit 7.0 Vol % Decomposition Temperature: Not determined Segregation Coefficient: 10. (n-octanol/water): Not determined Evaporation Point: Not determined Viscosity: Not determined Solvent Content: Organic Solvents: 24.1% Solids Content: 51.4% Other Information No further relevant information available Stability and Reactivity Reactivity Chemical Stability Thermal Decomposition: No decomposition if used according to specifications Possibility of Hazardous Reactions: No dangerous reactions known Conditions to Avoid: No further relevant information available Incompatible Materials: No further relevant information available Hazardous Decomposition Products No dangerous decomposition products known 11. Toxicological Information Information on Toxicological Effects Acute toxicity LD/LC50 values relevant for classification: Chemical: Xylene SDS Sheet Page 9 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. CAS Number: 1330-20-7 Oral LD50 8700 mg/kg (rat) Dermal LD50 2000mg/kg (rabbit) Inhalative: LC50/4h 6530 m g/l Chemical: carbon tetrachloride CAS Number: 56-23-5 Oral LD50 Dermal LD50 Inhalative: LC50/4h 1000 m g/l (rat) 43 mg/kg (HMN) 5070mg/kg (rat) (HMN) Primary Irritant Effect: Contact with Skin: Irritant to skin and mucous membranes Contact with Eyes: No irritating effect Sensitization: No sensitizing effects known Additional toxicological information The product shows the following dangers according to the calculation of the general EU Classification Guidelines for Preparations as issued in the latest version Harmful Irritant 12. Ecological Information Toxicity Aquatic toxicity: No further relevant information available Persistence and Degradability No further relevant information available Behaviour in environmental systems Bioaccumulation Potential: No further relevant information available Mobility in Soil: No further relevant information available Ecotoxical Effects: Remark: Toxic for fish SDS Sheet Page 10 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Additional ecological information: General notes: Water danger class 3 (German regulation) (Self-assessment): extremely hazardous for water. Do not allow to reach ground water, water course or sewage systems, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground Also poisonous for fish and plankton in water bodies Toxic for aquatic organisms Results of PBT and vPvB Assessment 13. PBT: chlorinated paraffins C10-13 vPvB: chlorinated paraffins C10-13 Other Adverse Effects No further relevant information available Disposal Considerations Waste Treatment Methods Recommendation: Must not be disposed together with household waste. Do not allow product to reach sewage system Uncleaned Packaging Recommendation: 14. Disposal must not be made accordingto official regulations Transport Information Un Number: ADR, IMG, IATA UN1263 UN Proper Shipping Name ADR: 1263 PAINT (not viscous), ENVIRONMENTALLY HAZARDOUS IMDG, IATA PAINT Transport Hazard class(es) ADR ADR/RID class: 3 Flammable Liquids Hazard Label 3 IMDG SDS Sheet Page 11 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Class 3 Flammable Liquids Hazard Label 3 IATA Class: 3 Flammable Liquids Label: 3 ICAO Packing Group: III Packing Group ADR IMDG IATA III Environmental Hazards Marine Pollutant: No Special marking (ADR) Symbol (fish and tree) Special Precaution for user: Warning: Flammable Liquids Danger Code (Kemler): 30 EMS Number: F-E, S-E Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Transport/Additional Information: ADR Tunnel Restriction: 15. D/E Regulatory Information Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture National regulations Technical instructions (air): SDS Sheet Page 12 of 12 Creation Date: 22.02.1996 Revision Date: 12.02.2016 Legal Disclaimer The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose. Class: I Share in % 7.3 Class: NK Share in % 47.9 Water Hazard Class: Water hazard class 3 (self-assessment): extremely hazardous to water Substances of very high concern (SVHC) according to REACH 16. Article 57 chlorinated paraffins C10-13 Chemical Safety Assessment A chemical safety Assessment has not been carried out. Other Information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship Relevant Phrases R10 Flammable R20/21 Harmful by inhalation and in contact with skin R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R23/24/25 Toxic by inhalation, in contact with skin or if swallowed R38 Irritating to skin R40 Limited evidence of a carcinogenic effect R48 Danger of serious damage to health by prolonged exposure R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment R59 Dangerous to the ozone layer R66 repeated exposure may cause skin dryness Note: This data sheet does not constitute a user’s assessment of workplace risk as required by HSW act, COSHH, management of health and safety at work regulations, or other health and safety legislation.