5th Swiss Geoscience Meeting, Geneva 2007 Petrography and geochemistry investigation on hyrothermal altered igneous rocks in NE of Arak Ayati Fezzeh*, Asadi Haroni Hooshang**, Noghreyan Mosa* and Mahdevari Saeed** *Geology Department, Isfahan University, Hezar Jarib Street, Iran (F_ayati@geol.ui.ac.ir) (Mosa.Noghreyan@hotmail.com) **Mining Department, Isfahan University of technology, Iran (hooshang_asadi@yahoo.com)(mahdevari@yahoo.com) The study area is emplaced within the central province of Iran about 120 km SW Tehran. Regionally, this area lies near the contact of the main Iranian volcanic belt (Urumieh-Dokhtar) and Sanandaj-Sirjan zone (volcanosedimentary), of which both are subdivisions of the Zagros orogenic belt and product of subduction and closure of the new Tethys Ocean. Urumieh-Dokhtar magmatic belt is part of the Alpian-Himalyan orogenic and metallogenic belt and represents an Andean type magmatism belt formed by subduction along the active continental margines of central Iranian block, during the Alpian orogeny (Tackin, 1979, Berberian et al., 1982, Sengor, 1990, Alavi, 1994). Locally, the area is underlain by Paleogene andesitic volcanics and pyroclastics intruded by Pliocene lensoid bodies of diorite, q- diorite, tonalite, dacite and rarely granodiorite porphyries with calcalkaline affinity. The calkalkaline igneous roks are in porphyritic texture and composed mainly of plagioclase, amphibole, biotite and quartz as major minerals. The principal opaque phases are magnetite, hematite and to a lesser extent pyrite. Zircon, apatite and sphene are accessory minerals. Plagioclase occurs as phenocryst and microphenocryst of variable size, almost displaying oscillatory zoning. The groundmass of volcanic rocks is composed of microlites of plagioclase associated with a lesser amount of sanidine. The average composition of plagioclase is An40-45. Initial surface sampling, which was carried out to produce the first geological and geochemical reports in the study area and its surroundings recognized a porphyry type Cu-Au mineralization (Asadi, 2005). On the basis of detailed petrographic studies on rock samples, it was established an extensive potassic alteration zone, which is characterized by the secondary biotite and rare or without secondary K-feldspar grains. This alteration assemblage is represented by secondary biotite, feldspar, quartz, chalcopyrite, pyrite, and magnetite. Magmatic biotite grains subjected to potassic alteration are either partially chloritized or completely recrystallized to secondary biotite; the latter are observed as small aggregate clusters. The euhedral to subhedral mica phenocrysts up to 3 mm in size display khaki to dark brown colors. They show different degreee of alteration to secondary biotite, chlorite and sphene. Sometimes they replace amphibole. Pleochroic amphiboles, the dominant ferromagnesian minerals in these igneous rocks are green with euhedral to subhedral forms which together with plagioclase and minor amount of pyroxene phenocrysts in groundmass yield a porphyritic texture to volcanoplutonic rocks. Amphiboles are very sensitive to potassic alteration and replace by secondary biotite, sericite and chlorite. Quartz, sericite and pyrite constitute another alteration assemblege called phyllic zone. This alteration is associated with quartz veins. It is highly destructive, commonly showing complete replacment of 5th Swiss Geoscience Meeting, Geneva 2007 the original mineral assemblage. In the phyllic alteration zone, plagioclase is mainly altered to sericite and biotite is altered to chlorite. The Propylitic alteration forms a halo around the mineralized pottasic zone. It is characterized by epidote, chlorite, calcite, and locally actinolite. These alteration minerals are formed by the replacement of primary amphibole and plagioclase in groundmass. Biotite phenocrysts are partially altered to epidote, chlorite and sericite. The argillic zone was locally developed in this area. These rocks are moderate to strongly enriched in highly incompatible elements, whereas depleted in compatible elements. On the primitive mantle – normalized diagram, rocks are enriched in LILE with respect to LREE and HFSE. All these evidences along with strong negative anomalies for Nb and Ti and positive anomalies for Pb are characteristics of an orogenic magmatism and convergent margin magmas. REFERENCES Alavi, M., 1994: Tectonic of the Zagros orogenic belt of Iran, new data and interpretations. Tectonophysics 229, 211-238. Asadi H., 2005: Preliminary Exploration at Dalli Porphyry Cu Prospect, Central Province of Iran, DORSA Engineering Limited, 22p. Berberian F., Muir, L. D., Pankhurst, R. J. & Berberian M., 1982: Late Cretaceous and Early Miocene Andean – type plutonic activity in northern Makran and central Iran: Journal of Geological Society of London 139, 605-614. Sengor, A. M. C., 1990: A new modle for the Late Palaeozoic-Mesozoic tectonic evolution of Iran and implication for Oman. Geological Society of London Special Publication 49, 797-831. Takin, M., 1972: Iranian geology and continental drift in the Middle East., Nature 235,147-150.