המחלקה להוראת המדעים Name ____________________________ Class ________________ Team members _________________________________________ Research and development of a “Hot-Cold” coffee can Edited by Dr. Hannah Margel, Dr. Miri Kesner, Ms. Malka Yayoon, Ms. Susanna David. Attention: Protective gloves and goggles must be worn You have read the article about a warming coffee can at: http://stwww.weizmann.ac.il/g-chem/learnchem As a research and development team of the “Hot-Cold” company you have to design a warm or cold coffee can. You will work in a computerized environment. At the first stages you will be introduced to the principles of a computerized sensor. You will use such sensors for the design of the heating/cooling can. Part A – Sensor – Thermometer – Potential - What is the connection? 1. What is temperature? _________________________________________ 2. How is temperature measured? _________________________________ A mercury thermometer or an alchohol thermometer 3. A mercury (alcohol) thermometer is based on the properties of glass and those of mercury. a. What are the properties of mercury on which the thermometer is based? _______________________________________________________________ b. What are the properties of glass on which the thermometer is based? _______________________________________________________________ c. Why is the tube in which the mercury expands very narrow (a capillary tube)?__________________________________________________________ . מכון ויצמן למדע, המחלקה להוראת המדעים,כל הזכויות שמורות מכון דוידסון לחינוך מדעי copyright 2 Given the following data: Material Melting Temperature ºC Boiling Temperature ºC Mercury -38 357 Alcohol -114 78 d. What is the temperature range in which Mercury can be used in a thermometer? _________ e. What is the temperature range in which alcohol can be used in a thermometer? _________ In every thermometer the temperature is converted into a variable that can be quantitatively determined. For example: in the mercury (alcohol) thermometer we measure the expansion volume of the mercury (alcohol) in the capillary tube. Construction of a digital temperature sensor Every metal has a characteristic electrical potential. When two metals are in contact, a potential gradient is created due to the difference in potential of each metal. This gradient is temperature dependent. In a digital temperature sensor the potential measured in the electrical circuit is translated to temperature units. Materials and equipment for construction of a digital temperature sensor (demonstration) 20cm iron wire, 20cm copper wire, multitester (for potential V measurement), candle, matches, electrical wires and clips for an electrical circuit, digital thermometer. Experimental protocol: a. Wind together the iron and copper wires. Use the electrical wires and clips to connect the co-wind iron and copper wires to the multitester and measure the potential in miliVolt units (mV). The measured potential is: ____________ b. Light the candle and warm the co-wind wire into the flame. The measured potential is: ____________ c. Repeat step b with a temperature sensor connected to the multitester, turn the multitester switch to temperature measurement. Predict: What is the temperature of the candle flame? _______________________________ Is the temperature constant in different areas of the flame? ____________________ If not, where would you expect the temperature to be higher? __________________ 2 3 Complete the table: Area of the flame Temperature ºC The outer, brighter part of the flame The inner, dark area of the flame The molten wax The solid wax Did the result match your predictions? __________________________________________________________________________ Interpret the results you observed _____________________________________________________________________ _____________________________________________________________________ Part B – Introduction to a computerized environment We will measure the temperature using a computer-activated sensor Experiment A = teacher demonstration Light the candle. Switch the logger on Open the ‘Multilab’ software. Program the data collector according to the following instructions: At the top ruler choose ‘collector/restart collector’. A dialog box will open saying ‘restart wizard step 1 of 3.’ Click ‘next’. The following window will appear 3 4 Set the data collector to a sample rate = 1 second, click ‘next’. The following window will appear: Select number of samples = 1000. Click ‘Done’. Start the data collector by clicking the “running man” icon. Follow the values that are being recorded by the computer in the graph and the table. Experiment B = student work 1. Use a graduated cylinder to measure 40ml water, transfer to a Styrofoam cup and add a magnet. Place the Styrofoam cup in a glass beaker, and place the beaker on the magnetic stirrer. 2. Start the magnetic stirrer. (Think: what is the purpose of the stirrer? What instrument that we use in the school lab does it replace?) 3. Insert the sensor in the water. 4. Program the data collector as follows: Set the temperature sensor to a sample rate=1 second, click ‘next’, select number of samples = 500. Click ‘Done’. Start the data logger by clicking the “running man” icon. 5. Put the calcium chloride powder (5gr) in the cup . 6. Follow the temperature measurement. When the temperature is stable, wait 2 minutes and stop the measurement by clicking ‘STOP’. 7. Copy the output graph by choosing graph \ copy graph at the top ruler. 8. Open a word document. Paste the graph and give it a title. Save the graph in a named file in folder _________. The graph will be printed from the teacher’s computer. Write the eqation of the reaction __________________________________________________________________ Is the reaction exothermic or endothermic? ________________________ 4 5 Experiment C = student work Repeat the experiment B with the ammonium nitrate (5gr) powder. Follow the temperature measurement. When the temperature is stable, wait 2 minutes and stop the measurement by clicking ‘STOP’. 1. Save the experimental results in the computer. 2. Copy the output graph: by choosing graph \ copy graph at the top ruler. Open a word document. Paste the graph and give it a title. Save the graph in a named file in folder _________. The graph will be printed from the teacher’s computer. Write the chemical formula of the reaction __________________________________________________________________ Is the reaction exothermic or endothermic? ________________________ Part C – Heating/cooling coffee can design Based on the research you have been doing, as the research and development team of the ‘Hot-Cold’ company you now have to design a heating and cooling coffee can (the coffee temperature should not be higher then 60ºC and the icecoffee temperature should not be lower than 10 ºC). To determine which materials you will be using, the following data is given: Reaction ΔH (Kj/mole) Dissolution of CaCl2 -82.8 Dissolution of NH4NO3 25.7 Dissolution of NH4NO3 -44 Acid-base neutralization -55.4 Other than the materials specified in the table, you also have: drinking soda and citric acid. 5 6 Search for safty information about the materials you chose to work with for the heating/cooling can in the website: http://physchem.ox.ac.uk/MSDS/ or in other MSDS sites (these sites containg safty information about various materials) and copy the relevant and important details. (Note: you have to look for each substance according to alphabetical order.) b. You have the following equipment: cups, made of: plastic, Styrofoam, paper, glass, metal. 1. Suggest a method to prepate your can (techiquely). 2. Consider the benefits and disadvantages of each of the materials you suggested to make the can. 3. Calculate the required amount of every material. (no more than 5gr of each material and no more than 2.5gr if you chose Sodium Hydroxide) 4. Write a detailed proposal, write your name and group number. 5. List the materials and equipment you will need for constructing the can. 6. According to your calculations, what will be the temperature of the hot/cold coffee? 7. Consult your teacher and make changes if necessary. 8. Get your teacher’s approval for your proposed protocol. 9. Submit your required materials and equipment list to the lab technician. Part D – Heating/cooling coffee can construction Construct the can Test if your can fulfils its purpose. Part E – Heating/cooling coffee can marketing Plan an advertising campaign for your product: choose an attractive name, provide scientific data proving the quality of the product. Mention at least three possible used for the coffee can and reasons to purchase it (refer to the application of your invention to daily life as well as to its industrial manufacturing) Part F Prepare a presentation describing your team project to your class. 6 7 References: Activities design by Dr. Oved Kedem, Davidson Institute for Science Education. Wonder can – industrial venture http://stwww.weizmann.ac.il/g-chem/learnchem Experiment 18 Chemistry Through Research – Dept. of Science Education, Weizmann Institute of Science http://stwww.weizmann.ac.il/g-chem/heker/index.html Hershkowitz A., Kaberman T., Sasson A.,(2002) Automated Research Labs and Molecular Imaging in Chemistry, Dept. of Science Education, Technion. 7