123
REFERENCES
1.
Abe H., Cheung T. and Bell A.T. (1993), ‘The activity of transition
metal nitrides for hydrotreating quinoline and thiophene’, Catal. Lett.,
Vol.21, No.1-2, pp.8-11.
2.
Aboul-Gheit and Kadry A. (1985), ‘Comparison of the
hydrodenitrogenation of the petroleum model nitrogen compounds
quinoline and indole’, Appl. Catal., Vol.16, No.1, pp.39-47.
3.
Ahuja S.P., Derrien M.L., Page L. and Jean F. (1970), ‘Activity and
selectivity of hydrotreating catalysts’, Ind. Eng. Chem. Pro. Res. Dev.,
Vol.9, No.3, pp.272-281.
4.
Ali M.A., Tatsumi T. and Masuda T. (2002), ‘Development of heavy
oil hydrocracking catalysts using amorphous silica-alumina and
zeolites as catalyst supports’, Appl. Catal. A: Gen., Vol.233, No.1-2,
pp.77-90.
5.
Atanasova P., Halachev T. and Kraus M. (1988), ‘Effect of phosphorus
on the surface concentration of molybdenum and nickel in the oxide
form of nickel-molybdenum/alumina catalysts and on their
hydrodesulphurization activity’, Appl. Catal. A: Gen., Vol.38, No.2,
pp.235-240.
6.
Atanasova P., Uchytil J., Kraus M. and Halachev T. (1990), ‘Effect of
calcination and water extraction on the distribution of the active
components in the oxide form of phosphorus-nickel-molybdenum/
alumina catalysts for hydrodesulfurization’, Appl. Catal. A: Gen.,
Vol.65, No.1, pp.53-68.
7.
Beck J.S., Vartuli J.C., Roth W.J., Leonowicz M.E., Kresge C.T.,
Schmitt K.D., Chu C.T.W., Olson D.H. and Sheppard E.W.
(1992), ‘A new family of mesoporous molecular sieves prepared with
liquid crystal templates,’ J. Am. Chem. Soc., Vol.114, No.27,
pp.10834-10843.
8.
Benitez A., Ramirez J., Fierro L.G. and Lopez A.A. (1996), ‘Effect of
fluoride on the structure and activity of NiW/Al2O3 catalysts for HDS
of thiophene and HDN of pyridine’, Appl. Catal. A: Gen., Vol.144,
No.1-2, pp.343-364.
124
9.
Benitez A., Ramirez J., Vazquez A., Acosta D. and Lopez A.A. (1995),
‘Influence of alumina fluoridation on the dispersion and hydrotreating
activity of W/Al2O3 catalyst’, Appl. Catal. A: Gen., Vol.133, No.1,
pp.103-119.
10.
Borade R.B. and Clearfield A. (1995), ‘Synthesis of Al rich MCM-41’,
Catal. Lett., Vol.31, pp.267-272.
11.
Bunch A.Y. and Ozkan U.S. (2002), ‘Investigation of the reaction
network of benzofuran hydrodeoxygenation over sulfided and reduced
Ni-Mo/Al2O3 catalysts’, J. Catal., Vol.206, pp.177-187.
12.
Caceres C.V., Fierro J.L.G., Lazaro J., Lopez A.A. and Soria J. (1990),
‘Effect of support on the surface characteristics of supported
molybdena catalysts’, J. Catal., Vol.122, No.1, pp.113-125.
13.
Candia R., Soerensen O., Villadsen J., Topsoe N.Y., Clausen B.S. and
Topsoe H. (1984), ‘Effect of sulfiding temperature on activity and
structure of cobalt-molybdenum/γ-alumina catalysts. II’, Bull. Des.
Soc. Chimi. Belges., Vol.93, No.8-9, pp.763-773.
14.
Chakraborty B. and Viswanathan B. (1999), ‘Surface acidity of
MCM-41 by in situ IR studies of pyridine adsorption’, Catal. Today,
Vol.49, No.1-3, pp.253-260.
15.
Chen C.Y., Burkett S.L., Li H.X. and Davis M.E. (1993), ‘Studies on
mesoporous materials synthesis mechanism of MCM-41, Mesoporo.
Microporo. Mater., Vol.2, pp.27-34.
16.
Cheng M., Kumataa F., Saitoa T., Komatsub T. and Yashimab T.
(1999), ‘Preparation and characterization of Mo catalysts
over AlMCM-41/γ-Al2O3 extruded supports’, Appl. Catal. A: Gen.,
Vol.183, No.1, pp.199-208.
17.
Choi J.G., Brenner J.R., Colling C.W., Demczyk B.G., Dunning J.L.
and Thompson L.T. (1992), ‘Synthesis and characterization of
molybdenum nitride hydrodenitrogenation catalysts’, Catal. Today.,
Vol.15, No.2, pp.201-22.
18.
Cid R., Lopez A.A., Orellana F. and Fierro J.L.G. (1986), ‘Stability
and catalytic properties of molybdenum-containing Y-type zeolite
catalysts calcined by an isobaric thermal decomposition procedure’,
Polyhedron, Vol.5, No.1-2, pp.187-190.
125
19.
Cid R., Orellana F. and Lopez A.A. (1987), ‘Effect of cobalt on
stability and hydrodesulfurization activity of molybdenum containing
Y zeolites’, Appl. Catal. A: Gen ., Vol.32, pp.327-336.
20.
Cid R., Villaseor J., Orellana F., Fierro J.L.G and Lopez A.A. (1985),
‘Surface and catalytic properties of alumina-, silica-, and NaY zeolitesupported CoMo catalysts’, Appl. Catal.,Vol.18, pp.357-372.
21.
Corma A., Grande M.S., Gonzalez-Alfaro V and Orchilles A.V.
(1996), ‘Cracking activity and hydrothermal stability of MCM-41 and
its comparison with amorphous silica-alumina and a USY zeolite’,
J. Catal., Vol.169, pp.375-382.
22.
Corma A., Martinez A., Martinez-Soria V. and Monton J.B. (1995),
‘Hydrocracking of vacuum gas oil on the novel mesoporous MCM-41
aluminosilicate catalyst’, J. Catal., Vol.153, No.1, pp.25-31.
23.
Cruz-Reyes J., Avalos-Borja M., Lopez Cordero R. and Lopez A.A.
(1994), ‘Influence of phosphorus on the structure and the
hydrodesulphurization and hydrodenitrogenation activity of W/Al2O3
catalysts’, Appl. Catal. A: Gen., Vol.120, No.1, pp.147-162.
24.
Davidova N., Kovacheva P. and Shopov D. (1985), ‘Nickel and/or
molybdenum containing zeolites as catalysts for hydrodesulfurization’,
Stud. Surf. Sci. Catal., Vol.24, (Zeolites: Synth., Struct., Tech. Appl.),
pp.659-665.
25.
Davidova N., Kovacheva P. and Shopov D. (1986), ‘ESR study of
zeolites containing transition metals and their hydrodesulfurizing
activity’, Zeolites, Vol.6, No.4, pp.304-306.
26.
DeCanio E.C., Edwards J.C., Scalzo T.R., Storm D.A and Bruno J.W.
(1991), ‘FT-IR and solid-state NMR investigation of phosphorus
promoted hydrotreating catalyst precursors’, J. Catal., Vol.132, No.2,
pp.498-511.
27.
Delce G. M. and Thompson L.T. (1996), Proc. Mater. Res. Soc. Sym.,
Ad. Catal. Mat., Bostan, USA.
28.
Diaz-Real R.A., Mann, Ranveer S., Sambi and Inderjet S. (1993),
‘Hydrotreatment of Athabasca bitumen derived gas oil over nickelmolybdenum, nickel-tungsten, and cobalt-molybdenum catalysts’, Ind.
Eng. Chem. Res., Vol.32, No.7, pp.1354-1358.
126
29.
Dufresne P., Payen E., Grimblot J. and Bonnelle J.P. (1981), ‘Study of
Ni-Mo-γ-Al2O3 catalysts by X-ray photoelectron and Raman
spectroscopy. Comparison with Co-Mo- γ-Al2O3 catalysts’, J. Phy.
Chem., Vol.85, pp.2344-2351.
30.
Eijsbouts S., de Beer V.H.J and Prins R. (1991),
‘Hydrodenitrogenation of quinoline over carbon-supported transition
metal sulfides’, J. Catal., Vol.127, No.2, pp.619-630.
31.
Eijsbouts S., Sudhakar C., de Beer V.H.J and Prins R. (1991a),
‘Hydrodenitrogenation of decahydroquinoline, cyclohexylamine and
o-propylaniline over carbon-supported transition metal sulfide
catalysts’, J. Catal., Vol.127, No.2, pp.605-618.
32.
Eijsbouts S., van Gestel J.N.M., van Veen J.A.R., de Beer V.H.J. and
Prins R. (1991b), ‘The effect of phosphate on the hydrodenitrogenation
activity and selectivity of alumina-supported sulfided Mo, Ni, and
Ni-Mo catalysts’, J. Catal., Vol.131, No.2, pp.412-432.
33.
Eijsbouts S.D., de Beer V.H.J. and Prins R. (1988), ‘Periodic trends in
the hydrodenitrogenation activity of carbon-supported transition metal
sulfide catalysts’, J. Catal., Vol. 109, No.1, pp.217-20.
34.
Eswarmoorthi I., Sundaramurthy V. and Lingappan N. (2004),
‘Hydroisomerisation of C6-C7 n-alkanes over Pt loaded zirconium
containing Al-MCM-41 molecular sieves’, Microporo. Mesoporo.
Mater. Vol.7, pp.109-115.
35.
Farag H., Whitehurst D.D. and Mochida I. (1998), ‘Synthesis of active
hydrodesulfurization carbon-supported Co-Mo catalysts. Relationships
between preparation methods and activity/selectivity’, Ind. Eng. Chem.
Res., Vol.37, No.9, pp.3533-3539.
36.
Fitz C.W. Jr. and Rase H.F. (1983), ‘Effects of phosphorus on nickelmolybdenum hydrodesulphurization/hydrodenitrogenation catalysts of
varying metals content’, Ind. Eng. Chem. Pro. Res. Dev., Vol.22, No.1,
pp.40-44.
37.
Fornes V., Vazquez M.I. and Corma A. (1986a), ‘Surface interaction
of Ni/Mo oxides on ultrastable Y zeolites’, Zeolites, Vol.2,
pp.125-128.
38.
Frost C.M. and Jensen H.B. (1973), ‘Hydrodenitrification of crude
shale oil’, Preprints-American Chemical Society, Division of
Petroleum Chemistry, Vol.18, No.1, pp.119-128.
127
39.
Furimsky E., Ranganathan R. and Parsons B.I. (1978), ‘Catalytic
hydrodenitrogenation of basic and non-basic nitrogen compounds in
Athabasca bitumen distillates’, Fuel, Vol.57, No.7, pp.427-430.
40.
Gil A., Gandia L. M. and Vicente M.A. (2000), ‘Recent advances in
the synthesis and catalytic applications of pillared clays’, Catal. Rev.–
Sci. Eng., Vol.42, No.1-2, pp.145-212.
41.
Hadjiloizou G.C., Butt J.B., Dranoff and Joshua S. (1992), ‘Catalysis
and mechanism of hydrodenitrogenation: the piperidine hydrogenolysis
reaction’, Ind. Eng. Chem. Res., Vol.31, No.11, pp.2503-2510.
42.
Hayashi E., Iwamatsu E., Mohammad Elias Biswas, Sanada Y.,
Shakeel Ahmed, Halim Hamid and Yoneda T. (1999),
‘Characterization of high surface area smectite supported cobalt oxides
catalysts for hydrodesulfurization by means of TPR, TPS and ESR’,
Appl. Catal. A: Gen., Vol.179, pp.203-216.
43.
Hedoire C-E., Louis C., Davidson A., Breysse M., Mauge F. and
Vrinat M. (2003), ‘Support effect in hydrotreating catalysts:
hydrogenation properties of molybdenum sulfide supported on
β-zeolites of various acidities’, J. Catal., Vol.220, No.2, pp.433-441.
44.
Ho T.C. (1988), ‘Hydrodenitrogenation catalysis’, Catal. Rev. – Sci.
Eng., Vol.30, No.1, pp.117-160.
45.
Ho T.C., Chianelli R.R. and Jacobson A.J. (1994), ‘Promotion effects
in bulk metal sulfide catalysts’, Appl. Catal. A: Gen., Vol.114,
pp. 127-139.
46.
Ho T.C., Mottangna A. and Steger J.J. (1984), Proc. 8th Int. Cong.
Catal. DECHEMA, pp.11-257.
47.
Houssenbay S., Mauge F., Duchet J.C., Lavalley J.C., Payen E. and
Kasztelan S. (1991) ‘Sulphided state of nickel molybdenum catalysts
supported on zirconia and aluminates’, Catal. Today, Vol.10, No.4,
pp.561-577.
48.
Iannibello A., Marengo S. and Girelli A. (1982), ‘Bauxite-based
catalysts in heavy crude oil hydrotreating’, Appl. Catal., Vol.3, No.3,
pp.261-272.
49.
Inagaki S., Fukushima Y. and Kuroda K. (1993), ‘Synthesis of highly
ordered mesoporous materials from a layered polysilicate’, J. Chem.
Soc., Chem. Commun., Vol.8, pp.680-682.
128
50.
Iwamatsu E., Hayashi E., Sanada Y., Shakeel Ahmed., Syed Ahmed
Ali., Lee. A.K.K., Halim Hamid and Yoneda T. (1999), ‘Temperatureprogrammed desorption and reductionofsulfided alumina-pillared
montmorillonite’, Appl. Catal. A: Gen., Vol.179, pp.139-144.
51.
Jenny M. Jones., Ronald A. Kydd, Michael Boorman P. and Phyllis H.
van Rhyn (1995), ‘Ni-Mo/Al2O3 catalysts promoted with phosphorus
and fluoride’, Fuel, Vol.74, Issue 12, pp.1875-1880.
52.
Jian M. and Prins R. (1998), ‘Determination of the nature of distinct
catalytic sites in hydrodenitrogenation by competitive adsorption’,
Catal. Lett., Vol.50, No.2, pp.9-13.
53.
Jones D.J., Aptel G., Markus Brandhorst., Mélanie Jacquin., José
Jiménez-Jiménez, Antonio Jiménez-López, Pedro Maireles-Torres,
Ireneusz Piwonski, Enrique Rodríguez-Castellón, Jerzy Zajac and
Jacques Rozière (2000), ‘Surface area mesoporous titanium phosphate:
synthesis and surface acidity determination’, J. Mater. Chem., Vol.8,
pp.1957-1963.
54.
Joo H.S. and Guin J.A. (1996), ‘Activity of noble metal-promoted
hydroprocessing catalysts for pyridine HDN and naphthalene
hydrogenation’, Fuel Pro. Tech., Vol.49, No.1-3, pp.137-155.
55.
Kaluza, L., Zdrazil M. and Zilkova N. and Cejka J. (2002), ‘High
activity of highly loaded MoS2 hydrodesulfurization catalysts
supported on organized mesoporous alumina’, Catal. Commn., Vol.3,
pp.151-157.
56.
Katritzky A.R. (1985), ‘Hand book of heterocyclic chemistry’,
Pargamon press.
57.
Katzer J.R. and Sivasubramanian R. (1979), ‘Process and catalyst
needs for hydrodenitrogenation’, Catal. Rev. Sci. Eng., Vol.20, No.2,
pp.155-208.
58.
Kim J-W., Longstaff D.C. and Hanson F.V. (1998), ‘Catalytic and
thermal effects during hydrotreating of bitumen-derived heavy oils’,
Fuel, Vol.77, No.15, pp.1815-1823.
59.
Kim K.S. and Winograd N. (1974), ‘X-ray photoelectron spectroscopic
studies of nickel-oxygen surface using oxygen and argon ionbombardment’, Surf. Sci., Vol.43, No.2, pp.625-643.
129
60.
Klimova T., Calderon M. and Ramirez J. (2003), ‘Ni and Mo
interaction with Al-containing MCM-41 support and its effect on the
catalytic behavior in DBT hydrodesulfurization’, Appl. Catal. A: Gen.,
Vol.240, pp.29-40.
61.
Kloprogge J.T., Welters W.J.J., Booy E., de Beer V.H.J., van Santen
R.A., Geus J.W. and Jansen J.B.H. (1993), ‘Catalytic activity of nickel
sulfide catalysts supported on Al-pillared montmorillonite for
thiophene hydrodesulfurization’, Appl. Catal. A: Gen., Vol.97,
pp.77-85.
62.
Kohno T., Yokono T., Sanada Y., Yamashita K., Hattori H. and
Makino K.(1986), ‘High temperature, high pressure ESR study of
molybdenum-containing catalysts’, Appl. Catal., Vol.22, pp.201-210.
63.
Kosslick H., Landmesser H. and Fricke R.J. (1997), ‘Acidity of
substituted MCM-41 type mesoporous silicates probed by ammonia’,
J. Chem. Soc., Faraday Trans., Vol.93, pp.1849-1854.
64.
Kosslick H., Lischke G., Parlitz B., Storek W. and Fricke. (1999),
‘Acidity and active sites of Al-MCM-41,’ Appl. Catal. A : Gen.,
Vol.84, pp.49-60.
65.
Kostova N.G., Spojakina A.A., Minchev C.I., Mavrodinova V.P.,
Neinska Y.G. and Dimitrov M.D. (2002), ‘Si-MCM-41 supported HDS
catalysts prepared with different molybdenum sources’, Bul. Bulg.
Chem. Commn., Vol.34, No.3-4, pp.505-515.
66.
Kozhevnikov V.I. (1995), ‘Heteropoly acids and related compounds as
catalysts for fine chemical synthesis,’ Catal. Rev.-Sci. Eng., Vol.37,
pp.311-352.
67.
Kresge C.T., Leonowicz M.E., Roth W.J., Vartuli J.C. and Beck J.S.
(1992), ‘Ordered mesoporous molecular sieves synthesized by a liquid
crystal template mechanism’, Nature, Vol.359, pp.710-712.
68.
Kumar S. D. and Mohan S. J. (1979), Indian Patent, 146409.
69.
Landau M.V. (1997), ‘Deep hydrotreating of middle distillates from
crude and shale oils’, Catal. Today, Vol.36, No.4, pp.393-429.
70.
Landau M.V., Vradman L., Herskowitza M., Koltypinb Y. and
Gedanken A. (2001), ‘Ultrasonically Controlled DepositionPrecipitation Co-Mo HDS Catalysts Deposited on Wide-Pore MCM
Material’, J. Catal., Vol.201, No.1, pp.22-36.
130
71.
Laredo G.C. and. Cortes C.M. (2003), ‘Kinetics of
hydrodesulfurization of dimethyldibenzothiophenes in a gas oil
narrow-cut fraction and solvent effects’, Appl. Catal. A: Gen.,
Vol.252, No.2, pp.295-304.
72.
Laredo G.C., Reyes J.A.D.H., Cano J.L.D. and Casitillo J.J.M. (2001),
‘Inhibition effects of nitrogen compounds on the hydrodesulfurization
of DBT’, Appl. Catal. A. Gen., Vol.207, pp.103-112.
73.
Le Page J.F. (1987), Appl. Heterogeneous Cat., Technip., Paris, pp.143
74.
Ledoux M.J. and Djellouli B. (1989), ‘Hydrodenitrogenation activity
and selectivity of well-dispersed transition metal sulfides of the second
row on activated carbon’, J. Catal., Vol.115, No.2, pp.580-590.
75.
Ledoux
M.J.
and
Djellouli
B.
(1990),
‘Comparative
hydrodenitrogenation activity of molybdenum, Co-Mo and
Ni-Mo/γ-Al2O3 catalysts’, Appl. Catal., Vol.67, pp.81-91.
76.
Ledoux M.J., Michaux O., Giorgio A. and Panissod P. (1986), ‘The
influence of sulfide structures on the hydrodesulfurization activity of
carbon-supported catalysts’, J. Catal., Vol.102, No.2, pp.275-288.
77.
Lee V. and Gioia F. (1986), ‘Effect of hydrogen pressure on catalytic
hydrodenitrogenation of quinoline’, Ind. Eng. Chem. Pro. Des. Dev.,
Vol.25, No.4, pp.918-925.
78.
Leglise J., Janin A., Lavalley J.C. and Cornet. D. (1988), ‘Nickel and
molybdenum sulfides loaded into zeolites: activity for catalytic
hydrogenation’, J. Catal., Vol.114, No.2, pp.388-397.
79.
Lemberton J.L., Gnofam N. and Perot G. (1992), ‘Effect of the zeolite
content on the hydrodenitrogenation of 1,2,3,4-tetrahydroquinoline
over sulphided NiMo on aluminacatalysts’, Appl. Catal. A: Gen.,
Vol.90, pp.175-182.
80.
Leviveld R.G., Ros T.G., van Dillen A.J., Geus J.W. and
Koningsberger D.C. (1999), ‘Influence of Si/Al ratio on catalytic
performance of (Co)Mo/Saponite catalysts’, J. Catal., Vol.185, No.2,
pp.513-523.
81.
Lewis J.M. and Kydd R.A. (1991), ‘Adsorption mechanism of
phosphoric acid on γ-alumina’, J. Catal., Vol.132, No.2, pp.465-467.
131
82.
Leyrer J., Vielhaber B., Zaki M.I., Zhuang S., Weitkamp J. and
Knoezinger H. (1985), ‘Structure and surface properties of supported
oxides’, Mater. Chem. Phy., Vol.13, No.3-4, pp.301-314.
83.
Li X., Wang A., Sun Z., Li C., Ren J., Zhao B., Wang Y., Chen Y. and
Hu Y. (2003), ‘Effect of surface proton exchange on
hydrodesulfurization performance of MCM-41-supported catalysts’,
Appl. Catal. A : Gen., Vol.254, No.2, pp.319-326.
84.
Li Z. and Gao L. (2002), ‘Investigation of the dispersion of MoO3 onto
the support of mesoporous silica MCM-41’, Appl. Catal. A: Gen.,
Vol.236, No.1-2, pp.163-171.
85.
Li Z., Gao L. and Zheng S. (2002), ‘Investigation of the dispersion of
MoO3 onto the support of mesoporous silica MCM-41’, Appl. Catal.
A: Gen., Vol.236, pp.163-171.
86.
Maheswari R., Shanthi K., Sivakumar T. and Narayanan S. (2003),
‘Beckmann rearrangement over phosphotungstic acid/SiMCM-41
cyclohexanone oxime to ε-caprolactam’, Appl. Catal. A: Gen.,
Vol.248, pp.291-301.
87.
Mauchausse C., Mossanega H., Turlier P. and Dalmon J.A. (1988),
‘Proc. 9th Inter. Cong. Cat. (Calgary)’. In : Phillips M.J and Ternan M.
(Eds.), Vol.2, pp.775-785.
88.
Michelson G.A. (1973), US Patent Nos. 3749633, 3749644, 3755148,
3755150 and 3755196.
89.
Miki Y. and Sugimoto Y. (1999), ‘Hydrodenitrogenation of
isoquinoline’, Appl. Catal. A: Gen., Vol.180, pp.133-140.
90.
Miller J.T. and Hineman M.F. (1984), ‘Non-first-order
hydrodenitrogenation kinetics of quinoline’, J. Catal., Vol.85, No.1,
pp.117-126.
91.
Morales M.M. and Ramirez de Agudelo (1986), ‘Promoter role of
octahedral Co (and Ni) in modified Co(Ni)Mo-Al2O3 catalysts for
hydrodesulfurization reactions’, Appl. Catal., Vol.23, No.1, pp.23-34.
92.
Muralidhar G., Massoth F.E. and Shabtai J. (1984), ‘Catalytic
functionalities of supported sulfides. II. Effect of support on
molybdenum dispersion’, J. Catal., Vol.85, No.1, pp.53-62.
132
93.
Muralidhar G., Massoth F.E. and Shabtai J. (1994), ‘Catalytic
functionalities of supported sulfides. I. Effect of support and additives
on the cobalt-molybdenum (CoMo) catalyst’, J. Catal., Vol.85, No.1,
pp.44-52.
94.
Muralidhar G., Rana M.S., Maits S.K., Srinivas B.N., Prasad Rao
T.S.R., Song C., Hsu S. and Mochida I. (2000), ‘Chemistry of diesel
fuels’, C.8, p.157.
95.
Nag and Nabin K. (1987), ‘A comparative study on the dispersion and
carrier-catalyst interaction of molybdenum oxides supported on various
oxides by electron spectroscopy for chemical analysis’, J. Phy. Chem.,
Vol.91, No.9, pp.2324-2327.
96.
Nagai M. and Masunaga T. (1988), ‘Hydrodenitrogenation of a
mixture of basic and non-basic polynuclear aromatic nitrogen
compounds’, Fuel, Vol.67, pp.771-774.
97.
Nat P.J. and Wogt. E.T.C.W 094/26847 (1994)
98.
Ng K.Y.S and Gulari E. (1985), ‘Molybdena on titania. I. Preparation
and characterization by Raman and Fourier transform infrared
spectroscopy’, J. Catal., Vol.92, No.2, pp.340-354.
99.
Nishijima A., Shimada H., Sato T., Yoshimura Y. and Hiraishi. J.
(1986), ‘Support effects on hydrocracking and hydrogenation activities
of molybdenum catalysts used for upgrading coal-derived liquids’,
Polyhedron, Vol.5, No.1-2, pp.243-247.
100.
Occelli. M.L. and Rennard. R.J. (1988), ‘Hydrotreating catalysts
containing pillared clays’, Catal. Today, Vol.2, No.2-3, pp.309-319.
101.
Okamoto Y., Maezawa A. and Imanaka T. (1989), ‘Active sites of
molybdenum sulfide catalysts supported on Al2O3 and TiO2 for
hydrodesulfurization and hydrogenation’, J. Catal., Vol.120, No.1,
pp.29-45.
102.
Okamoto Y., Maezawa A. H. and Imanakakane T. (1988), ‘Proc. 9th
Inter. Cong. Cat. (Calgary)’, In : Phillips M.J and Ternan M. (Eds.),
Vol.1, p.11.
103.
Okamoto Y., Maezawa A., Kane H. and Imanaka T. (1989a), ‘Highly
dispersed molybdenum sulfide catalysts prepared from Mo(CO)6
encaged in a zeolite’, J. Mol. Catal., Vol.52, No.3, pp.337-348.
133
104.
Papadopoulou Ch., Vakros J., Matralis H.K., Voyiatzis G.A. and
Kordulis Ch. (2004), ‘Preparation, characterization, and catalytic
activity of CoMo/γ-Al2O3 catalysts prepared by equilibrium deposition
filtration and conventional impregnation techniques’, J. Coll. Inter.
Sci., Vol.274, pp.159-166.
105.
Park Y-C., Oh E-S. and Rhee H-K. (1997), ‘Characterization and
catalytic activity of WNiMo/Al2O3 catalyst for hydrodenitrogenation of
Pyridine’, Ind. Eng. Chem. Res., Vol.36, No.12, pp.5083-5089.
106.
Pecoraro T.A. and Chianelli R.R. (1981), ‘Hydrodesulfurization
catalysis by transition metal sulfides’, J. Catal., Vol.67, No.2,
pp.430-445.
107.
Portefaix J.L., Catterot M., Dalmon A. and Mauchausse C. (1989),
‘Advances in catalysis’. In : Ocelli M.L. and Antonym R.G. (Eds),
Elsevier Science publishers, p.243.
108.
Prins R. (2001), ‘Catalytic hydrodenitrogenation’, Adv. Cat., Vol.46,
pp.399-464.
109.
Prins R., Jian M. and Flechsenhar (1997), ‘Mechanism and kinetics of
hydrodenitrogenation’, Polyhedron, Vol.16, No.18, pp.3235-3245.
110.
Quincy R.B., Houalla M., Proctor A. and Hercules D. M. (1989),
‘Surface structure and thiophene hydrodesulfurization activity of
molybdenum/titania catalysts’, J. Phy. Chem., Vol.93, No.15,
pp.5882-5888.
111.
Ramanathan S., Yu C., Oyama C. and Ted S. (1998), ‘New catalysts
for hydroprocessing: bimetallic oxynitrides. II. Reactivity studies’,
J. Catal., Vol.173, No.1, pp.10-16.
112.
Ramirez J., Fuentes S., Díaz G., Vrinat M. and Michele. (1989),
‘Hydrodesulphurization activity and characterization of sulphided
molybdenum and cobalt-molybdenum catalysts comparison of
alumina-, silica-alumina- and titania-supported catalysts’, Appl. Catal.
A: Gen ., Vol.52, No.3, pp.211-223.
113.
Ramos-Galvan C.E., Sandoval-Robles G., Castillo-Mares A. and
Dominguez J.M. (1997), ‘Comparison of catalytic properties of
NiMo/Al2O3 with NiMo supported on Al-, Ti-pillared clays in HDS of
residual oils’, Appl. Catal. A: Gen., Vol.150, pp.37-52.
134
114.
Rangwala H.A., Dalla Lana I.G., Otto F.D., Yeniova H. and
Al-Nuaimi K. (1990), ‘Influence of catalyst properties and operating
conditions on hydrodenitrogenation of quinoline’, Energy and Fuels,
Vol.4, No.5, pp.599-604.
115.
Rives A., Payen E., Hubaut R., Vazquez P., Pizzio L., Caceres C. and
Blanco M. (2001), ‘Silica and alumina impregnated with
dimethylformamide
solutions
of
molybdophosphoric
or
tungstophosphoric acids for hydrotreatment reactions’, Catal. Lett.,
Vol.71, No.3-4, pp.193-201.
116.
Robert M., William J., Zhaohua L., Maria D. A. and Jacek K. (1996),
‘Acidity and catalytic activity of the mesoporous aluminosilicate
molecular sieve MCM-41’, Catal. Lett., Vol.37, pp.113-120.
117.
Saban M.D., Skala D.U., Jovanovic J.A., Mayn V.W. and Rahimian
I.G.H. (1992), ‘Hydrodenitrogenation of Aleksinac shale oil distillates
in a pilot trickle-bed reactor’, Fuel Proc. Tech., Vol.30, No.1,
pp.15-31.
118.
Sakata Y. and Hamrin Jr C.E. (1983), ‘Comparison of
hydrodesulfurization and hydrodenitrogenation over API reference
clays, silica, alumina, and cobalt molybdate’, Ind. Eng. Chem. Pro.
Res. Dev., Vol.22, No.2, pp.250-255.
119.
Salerno P., Mendioroz S. and Lopez Agudo A. (2004), ‘Al-pillared
montmorillonite-base NiMo catalysts for HDS and HDN of gas oil:
influence of the method and order of Mo and Ni impregnation’, Appl.
Catal. A : Gen., Vol.259, pp.17-28.
120.
Sambi I.S., Khulbe K.C., Mann and Ranveer S. (1982), ‘Catalytic
hydrotreatment of heavy gas oil’, Ind. Eng. Chem. Pro. Dev., Vol.21,
No.4, pp.575-580.
121.
Sarbak Z. and Lewandowski M. (2001), ‘Catalytic elimination of
nitrogen organic compounds from the coal-liquid and structural
properties of Ni/Mo catalysts supported on NaX and NaY zeolites
modified with transition metal cations’, Appl. Catal. A : Gen., Vol.208,
No.1-2, pp.317-321.
122.
Satterfield C. N. and Gultekin S. (1981), ‘Effect of hydrogen sulfide on
the catalytic hydrodenitrogenation of quinoline’, Ind. Eng. Chem. Proc.
Des. Dev., Vol.20, No.1, pp.62-68.
135
123.
Satterfield
C.N.
and
Yang
S.H.
(1984),
‘Catalytic
hydrodenitrogenation of quinoline in a trickle-bed reactor. Comparison
with vapor phase reaction’, Ind. Eng. Chem. Pro. Des. Dev., Vol.23
No.1, pp.11-19.
124.
Schlatter J.C., Oyama S.T., Metcalfe J.E. III and Lambert J.M. Jr.,
(1988), ‘Catalytic behavior of selected transition metal carbides,
nitrides, and borides in the hydrodenitrogenation of quinoline’, Ind.
Eng. Chem. Res., Vol.27, No.9, pp.1648-1653.
125.
Shanthi K., Pillai C.N. and Kuriacose J.C. (1989),
‘Hydrodenitrogenation of simple aromatic amines on molybdena
catalysts’, Appl. Catal., Vol.46, No.1-2, pp.241-249
126.
Shanthi K., Pillai C.N. and Kuriacose J.C. (1991),
‘Hydrodenitrogenation of simple aromatic amines on molybdena
catalysts: Nature of active sites’, Ind. J. Chem., Vol.30A, pp.584-587.
127.
Shimada H., Sato T., Yoshimura Y., Hiraishi J. and Nishijima. A.
(1988), ‘Support effect on the catalytic activity and properties of
sulfided molybdenum catalysts’, J. Catal., Vol.110, No.2, pp.275-284.
128.
Sivasanker S. (2002), ‘Catalysis : Principle and Applications’,
Viswanathan B., Sivasanker S. and Ramaswamy A.V. (Eds.), Narosa
Publishing House, New Delhi, pp.362-376.
129.
Song C. and Madhusudan Reddy. K. (1999), ‘Mesoporous molecular
sieve MCM-41 supported Co–Mo catalyst for hydrodesulfurization of
dibenzothiophene in distillate fuels’, Appl. Catal. A: Gen., Vol.176,
No.1, pp.1-10.
130.
Sun M. and Prins R. (1999), ‘Influence of sulphidation and fluoridation
on the HDN of o-toluidine over tungsten catalysts ex ammonium
tetrathiotungstate’, Stud. Surf. Sci. Catal., Vol.127 (Hydrotreatment
and Hydrocracking of Oil Fractions), pp.113-120.
131.
Sundaramurthy V., Dalai A.K. and Adjaye J. (2005), ‘Effect of EDTA
on hydrotreating activity of CoMo/γ-Al2O3 catalyst’, Catal. Lett.
Vol.102, No.3-4, pp.299-306.
132.
Sychev M., de Beer V.H.J., Kodentsov A., Van Oers E.M. and
Van Santen R.A. (1997), ‘Chromia and chromium sulfide-pillared
clays: preparation, characterization and catalytic activity for thiophene
hydrodesulfurization’, J. Catal., Vol.168, No.2, pp.245-254.
136
133.
Tanev P.T. and Pinnavia T.J. (1995), ‘A neutral templating route to
mesoporous molecular sieves,’ Science, Vol.267, pp.865-867.
134.
Topsoe H., Candia R., Topsoe N.Y. and Clausen B.S. (1984), ‘On the
state of the cobalt-molybdenum-sulfur model’, Bull. Des Soc. Chimi.
Belges., Vol.93, No.8-9, pp.783-806.
135.
Turaga U.T. and Song C. (2003), ‘MCM-41-supported Co-Mo
catalysts for deep hydrodesulfurization of light cycle oil’, Catal.
Today, Vol.86, No.1-4, pp.129-140.
136.
Vissers J.P.R., Groot C.K., Van Oers E.M., De Beer V.H.J. and
Prins R. (1984), ‘Carbon-supported transition metal sulfides’, Bull.
Des Soc. Chimi. Belges., Vol.93, No.8-9, pp.813-821.
137.
Vogelaar B.M., Steiner P., Dick Van Langeveld A., Eijsbouts S. and
Moulijn J.A. (2003), ‘Deactivation of Mo/Al2O3 and NiMo/Al2O3
catalysts during hydrodesulfurization of thiophene’, Appl. Catal. A:
Gen., Vol.251, pp.85-92.
138.
Volpe L. and Boudart M. (1985), ‘Compounds of molybdenum and
tungsten with high specific surface area I. Nitrides’, J. Solid State
Chem., Vol.59, No.3, pp.332-347.
139.
Vuurman M. and Wachs I. E. (1992), ‘In situ Raman spectroscopy of
Alumina-supported metal oxide catalysts’, J. Phys. Chem., Vol 96,
pp.5008-5016.
140.
Wachs I. E. and Hardcastle F. D. (1988), ‘Proc. 9th inter. cong. cat.
(Calgary)’. In : Phillips M.J. and Ternan M. (Eds.), Vol.3, p.1449.
141.
Wagner C.D., Riggs W.M., Davis L.E., Movlder J. F. and Mullenberg
G.E. (1979), ‘Hand book of X-ray Photoelectron spectroscopy’, ed.,
Perkin – Elmer corporation 80
142.
Wang A., Li X., Chen Y., Han D., Wang Y., Hu Y. and Kabe T.
(2001), ‘Deep hydrodesulfurization over W-based catalysts supported
by siliceous MCM-41’, Chem. Lett., Vol.30, No.5, p.474.
143.
Wang A., Wang Y., Kabe T., Chen Y., Ishihara A., Qian W. and Yao
P. (2002), ‘Hydrodesulfurization of dibenzothiophene over Siliceous
MCM-41 supported catalysts II. Sulfided Ni–Mo Catalysts’, J. Catal.,
Vol.210, No.2, pp.319-327.
137
144.
Wang A., Wang Y., Kabe T., Chen Y., Ishihara A.I. and Qian W.
(2001), ‘Hydrodesulfurization of dibenzothiophene over Siliceous
MCM-41supported catalysts’, J. Catal., Vol.199, No.1, pp.19-29.
145.
Wang I. and Chang R.C. (1989), ‘Catalytic hydrodesulfurization and
hydrodenitrogenation over cobalt-molybdenum on titania-zirconiavanadia’, J. Catal., Vol.117, No.1, pp.266-274.
146.
Wilson M.F. and Kriz J.F. (1984), ‘Upgrading of middle distillate
fractions of a syncrude from Athabasca oil sands’, Fuel, Vol.63, No.2,
pp.190-196.
147.
Xiao S. and Meng Z. (1994), ‘X-ray photoelectron spectroscopy
characterization of the reduction and oxidation behaviour of
Ni-containing HZSM-5 zeolites’, J. Chem. Soc. Fara. Trans., Vol.90,
No.17, pp.2591-2595.
148.
Yang S. H. and Satterfield C. N. (1983), ‘Some effects of sulfiding of a
nickel-molybdenum (NiMo)/alumina catalyst on its activity for
hydrodenitrogenation of quinoline’, J. Catal., Vol.81, No.1, pp.168-78.
149.
Ying J.Y., Mehnert C.P. and Wong M.S. (1999), ‘Synthesis and
applications of supramolecular-templated mesoporous materials’,
Angew. Chem. Int. Ed., Vol.38, pp.56-77.
150.
Yokono T., Iyama S., Sanada Y., Yamaguchi T. and Iizuka T. (1984),
‘Dehydrogenation of coal over catalysts: evaluation of catalysts for
liquefaction’, Sekiyu Gakkaishi., Vol. 27, No.6, pp.512-518.
151.
Yu F., Duo L., Gang S. and Xiaojun B. (2006), ‘Synthesis of ZSM5/SAPO-11 composite and its application in FCC gasoline hydroupgrading catalyst’, Catal. Today., Vol.114, pp.388-396
152.
Zaki M.I., Vielhaber B. and Knoezinger H. (1986), ‘Low-temperature
carbon monoxide adsorption and state of molybdena supported on
alumina, titania, ceria, and zirconia. An infrared spectroscopic
investigation’, J. Phy. Chem., Vol.90, No.14, pp.3176-3183.
153.
Zhao D., Luan Z. and Kevan L. (1997), ‘Synthesis of thermally stable
mesoporous hexagonal aluminophosphate molecular sieves’, Chem.
Commun., Vol.11, pp.1009-1010.
138
LIST OF PUBLICATIONS
In Journals
1.
Sasirekha N.R., Sardhar Basha S.J. and Shanthi K. (2005),
‘Photocatalytic performance of Ru doped anatase mounted on silica for
reduction of carbon dioxide’, Appl. Catal. B: Environ., Vol. 62, pp.
169-180.
2.
Sardhar Basha S.J., Sasirekha N.R., Maheswari R. and Shanthi K.
(2006), ‘Mesoporous H-AlMCM-41 supported NiO-MoO3 catalysts for
Hydrodenitrogenation of o-Toluidine I. Effect of MoO3 loading’, Appl.
Catal. A. General (In Press).
3.
Sardhar Basha S.J., Sangeetha P., Mahendiran C., Shanthi K.,
and Narayanan S., ‘Mesoporous H-AlMCM-41 supported NiO-MoO3
catalysts
for
Hydrodenitrogenation
of
o-Toluidine
and
cyclohexylamine. II. Influence of the order and method of
impregnation’, Appl. Catal. A: General (Communicated).
4.
Sardhar Basha S.J., Vijayan P., Shanthi K. and Setua K., ‘Synthesis
and characterization of H-AlMCM-41 supported NiO–MoO3 catalyst
for HDN of cyclohexylamine - Influence of MoO3 loading’, Catal.
Comm., (Communicated).
5.
Sardhar Basha S.J. and Shanthi K., ‘Mesoporous AlMCM-41 and
SiMCM-41 supported NiO-MoO3 catalysts for Hydrodenitrogenation
of o-propyl aniline: Influence of order of impregnation’, Stud. Surf.
Sci. Catal. (Communicated).
Papers presented in International / National Conferences / Symposia
1.
Sardhar Basha S.J. and Shanthi K., ‘H-AlMCM-41 as support for NiMo catalysts in the removal of Nitrogen from simple amines’,
16th Catsymp & IST Indo-German conference, held during February,
2003 at Indian Institute of Chemical Technology, Hyderabad, India
139
2.
Sardhar Basha S.J. and Shanthi K., ‘HDN of aromatic amines over
Ni–Mo / MCM – 41’, Chemists’ Meet 2004 held during March, 2004
at Indian Institute of Technology Madras, Chennai, India.
3.
Sardhar Basha S.J. and Shanthi K., ‘Hydrodenitrogenation activity of
Ni-Mo/Al-H-MCM-41: Effect of order of impregnation’, 17th National
Symposium on Catalysis held during January 2005 at Central Salt and
Marine Chemicals Research Institute, Bhavnagar, Gujarat, India.
4.
Sardhar Basha S.J. and Shanthi K., ‘Hydrodenitrogenation Activity
of Ni-Mo/ H-AlMCM-41: Effect Of Si/Al Ratio on H-AlMCM-41’,
National Workshop On Catalysis For Energy, Held During February,
2006 at Banaras Hindu University, Varanasi, India
5.
Sardhar Basha S.J., Vijayan P. and Shanthi K., ‘Catalytic activity of
NiO-MoO3/ H-AlMCM-41 for hydrodenitrogenation of OPA and
MCHA’, National seminar on Frontier Chemistry, held during March,
2006 at Cochin University of Science and Technology, Cochin, Kerala,
India.
6.
Sardhar Basha S.J. and Shanthi K., Mesoporous AlMCM-41 and
SiMCM-41 supported NiO-MoO3 catalysts for Hydrodenitrogenation
of o-propyl aniline. Influence of order of impregnation, Accepted for
poster presentation, IMMS (2006), During June, 2006 at China
7.
Sardhar
Basha
S.J.,
Vijayan
P.
and
Shanthi
K.,
‘Hydrodenitrogenation of o-Toluidine and Cyclohexylamine: Influence
of supports on the NiO-MoO3 catalysts’, Accepted for poster
presentation, XXIX Annual BZA conference, During August, 2006 at
UK.
140
VITAE
Mr. S. J. Sardhar Basha was born on July 1977 in Omalur, Salem
District, Tamil Nadu. His parents are Mr. S. John Basha and Mrs. E. Pheritha.
He had his schooling at Sri Ramakrishna Saradha Higher Secondary School,
Salem. He received his Bachelor’s degree in Science from University of
Madras through Government Arts College, Salem-7 and obtained his Master’s
Degree of Science in General Chemistry from same university through New
College, Chennai. He completed his Master of Philosophy from University of
Madras through the same college. He joined in Department of Chemistry,
Anna University as a full-time research scholar in January 2002. He has
carried out his research work in the fascinating and demanding field of
Heterogeneous Catalysis and its application in petroleum engineering
chemistry. He joined as a Junior Research Fellow (JRF) in the DRDO funded
project in April 2003.
He has two international papers to his credit. He has participated
and presented at national and international conferences, national symposia
and workshops. His current research interest includes physico-chemical
studies and catalytic application of mesoporous aluminophosphate based
molecular sieves.