PA Benchmarks: Science Draft: January 30, 2007 EARTH & SPACE SCIENCE 1 LIFE SCIENCE 1. The Chemistry of Life Central Concept: Chemical elements form organic molecules that interact to perform the basic functions of life. 1.1 1.2 1.3 1.4 Recognize that biological organisms are composed primarily of very few elements. The six most common are C, H, N, O, P, and S. Describe the basic molecular structures and primary functions of the four major categories of organic molecules in plants and animals (carbohydrates, lipids, proteins, nucleic acids, ATP). Explain the role of enzymes as catalysts that lower the activation energy of biochemical reactions. Life has a very narrow range of acceptable conditions in which to flourish. Identify factors, such as pH and temperature, which have an effect on biochemical reactions. 2. Cell Biology Central Concepts: Cells have specific structures and functions that make them distinctive. Processes in a cell can be classified broadly as growth, maintenance, and reproduction. 2.1 2.2 2.3 2.4 2.5 Relate cell parts/organelles (plasma membrane, nuclear envelope, nucleus, nucleolus, cytoplasm, mitochondrion, endoplasmic reticulum, Golgi apparatus, lysosome, ribosome, vacuole, cell wall, chloroplast, cytoskeleton, centriole, cilium, flagellum, pseudopod) to their functions. Explain the role of cell membranes as a highly selective barrier cytoplasm and the environment. Processes that allow transport across this barrier include diffusion, osmosis, facilitated diffusion, active transport. Compare and contrast, at the cellular level, the cell parts/organelles of prokaryotes and eukaryotes. Use cellular evidence (e.g., cell structure, cell number, cell reproduction) and modes of nutrition to describe the known kingdoms i.e.; Archaebacteria, Eubacteria, Protista, Fungi, Plantae, Animalia. Identify the reactants, products, and basic purposes of photosynthesis and cellular respiration. Explain the interrelated nature of photosynthesis and cellular respiration in the cells of photosynthetic organisms. Identify the reactants, products and metabolic cycles that generate ATP. Identify the important role that ATP serves in cell metabolism. Demonstrate the network of pathways that interact with the ATP metabolic cycle or any other reaction utilizing online bioinformatics tools such as the ExPASy Biochemical Pathways (http://www.expasy.ch/cgibin/search-biochem-index) or the KEGG Pathway (http://www.genome.jp/kegg/pathway.html) 2 2.6 2.7 2.8 Describe cell replication and the process of mitosis. Explain the role of mitosis in the formation of new cells, and its importance in maintaining chromosome number during asexual reproduction. Describe how the process of meiosis results in the formation of haploid cells. Explain the importance of this process in sexual reproduction, and how gametes form diploid zygotes in the process of fertilization. Compare and contrast a virus and a cell in terms of structure and function. 3. Genetics and Molecular Biology Central Concepts: Genes allow for the storage and transmission of genetic information. They are a set of instructions encoded in the nucleotide sequence of each organism. Genes code for the specific sequences of amino acids that comprise proteins. 3.1 3.2 3.3 3.4 3.5 3.6 Describe the basic structure (double helix, sugar/phosphate backbone, linked by complementary nucleotide pairs) of DNA Describe the basic process of DNA replication and how it relates to the transmission and conservation of the genetic code. Explain the basic processes of transcription and translation, and how they result in the expression of genes. Distinguish among the end products of replication, transcription, and translation. Explain how variation (as in the DNA sequence of a gene may or may not (positive, neutral or negative) result in phenotypic change in an organism. Naturally occurring variations are rare and random. Discuss the environmental factors that increase the frequency of mutation (tetrogenic; UV, chemical, viral). Explore the significance of conservative and non-conservative sequences within the genome of an organism using online public bioinformatics tools such as UCSC’s Genome Browser (http://genome.ucsc.edu/cgi-bin/hgGateway) or NCBI OMIM (http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=OMIM) Distinguish among observed inheritance patterns caused by several types of genetic traits (dominant, recessive, codominant, sex-linked, polygenic, incomplete dominance, multiple alleles). Describe how Mendel’s laws of segregation and independent assortment can be observed through patterns of inheritance (e.g., dihybrid crosses). Use a Punnett Square to determine the mathematical probabilities for genotype and phenotype combinations in monohybrid crosses. 4. Mammalian Anatomy and Physiology Central Concepts: There is a relationship between the organization of cells into tissues and the organization of tissues into organs. The structures and functions of organs determine their relationships within body systems of an organism. Homeostasis allows the body to perform its normal functions. 3 4.1 Explain how the digestive system (mouth, pharynx, esophagus, stomach, small and large intestines, rectum) converts macromolecules from food into smaller molecules that can be used by cells for energy and for repair and growth. 4.2 Explain how the circulatory system (heart, arteries, veins, capillaries, red blood cells) transports nutrients and oxygen to cells and removes cell wastes. Describe how the kidneys and the liver are closely associated with the circulatory system as they perform the excretory function of removing waste from the blood. 4.3 Recognize that kidneys remove nitrogenous wastes, the liver removes many toxic compounds from blood, and the spleen recovers as hemoglobin from non-functioning red blood cells. 4.4 The presence of foreign particles initiates an immunological response. This includes the recognition by and activation of several white blood cells(B & T cells, macrophages, platelets) 4.5 Explain how the respiratory system (nose, pharynx, larynx, trachea, lungs, alveoli) provides exchange of oxygen and carbon dioxide. 4.6 Explain how the nervous system (brain, spinal cord, sensory neurons, motor neurons) mediates communication among different parts of the body and mediates the body’s interactions with the environment. Identify the basic unit of the nervous system, the neuron, and explain the process of neuronal communication. 4.7 Explain how the muscular/skeletal system (skeletal, smooth and cardiac muscles, bones, cartilage, ligaments, tendons) works with other systems to support the body and allow for movement. Recognize that bones produce blood cells. 4.8 Recognize that the sexual reproductive system allows organisms to produce offspring that receive half of their genetic information from their mother and half from their father, and that sexually produced offspring resemble, but are not identical to, either of their parents. 4.9 Recognize that communication among cells is required for coordination of body functions. The nerves communicate with electrochemical signals, hormones circulate through the blood, and some cells produce signals to communicate only with nearby cells. 4.10 Recognize that the body’s systems interact to maintain homeostasis. Describe the basic function of a physiological feedback loop. 5. Evolution and Biodiversity Central Concepts: Evolution is the result of genetic changes that occur in constantly changing environments. Over many generations, changes in the genetic make-up of populations may affect biodiversity through speciation and extinction. 5.1 Explain how evolution is demonstrated by evidence from the fossil record, comparative anatomy and embryology, genetics, molecular 4 5.2 5.3 5.4 5.5 5.6 5.7 5.8 biology, and examples of natural selection. This type of evidence can also be used to demonstrate and classify evolutionary relationships in a hierarchical manner. Explore hierarchical relationships using bioinformatics tools designed to analyze evolutionary classification and relationships. For example; online public bioinformatics tools like BLAST (http://www.ncbi.nlm.nih.gov/BLAST) . Describe an inherited trait as a physical expression of a gene. Explain how mutations result in genetic and physical changes which can affect the survival and reproductive success of an individual organism and successive generations which carry the same mutations. Explain how evolution, through natural selection can result in changes in biodiversity through the increase or decrease of genetic diversity within a population. Discuss factors that play a role in natural selection, i.e.; genetic variability, environmental selective pressures, competition, overproduction for available resources and reproductive success. Provide evidence that evolution is not a static process and is occurring in organisms today. Changes in viruses, antibiotic resistance of bacteria, genes from genetically modified plants appearing in native plants, resistance of insects to pesticides) Provide evidence of environmental changes or pressures which result in natural selection for or against some species. Identify species as a reproductively distinct group of organisms, and how natural selection can lead to speciation. Understand the effect of geographic isolation and resource partitioning leading to unique species (Australia, Galapagos Islands). Explore the theory of evolution based on the mechanism of natural selection as proposed by Darwin and Wallace. Explore additional the scientific principles beyond those of Darwin and Wallace supporting the theory of evolution. 6. Ecology Central Concept: Ecology is the interaction among organisms and between organisms and their environment. 6.1 6.2 6.3 6.4 Explain the energy flow within a food web: identify and distinguish producers, consumers, and decomposers; the transfer of energy through trophic levels. Explain how water, carbon, and nitrogen cycle between abiotic resources and organic matter in an ecosystem, and how oxygen cycles through photosynthesis and respiration. Examine and explain the path of a recyclable material from collection to waste, reuse or recycling identifying the market forces. Explain the effects on the environment and sustainability through the use of renewable and nonrenewable resources. 5 6.5 6.6 6.7 6.8 6.9 6.10 6.11 6.12 6.13 Analyze the interdependence, limiting factors, and stability within an ecosystem. Describe how relationships among organisms (predation, parasitism, competition, commensalisms, mutualism) add to the complexity of biological communities. Analyze changes in population size and biodiversity (speciation and extinction) that result from: natural causes, climatic changes, human activity and introduction of invasive species. Explain how birth, death, immigration and emigration influence population size. Analyze the effect of natural resource conservation on a product over time (e.g., automobile manufacturing, aluminum can recycling, paper products). Identify environmental health issues; visible and invisible pollutants and explain their effects on human health. Explain and compare short and long term, traditional and environmental sound pest management practices may affect the environment. Describe the ecosystems of watersheds and wetlands and the effects of human activities on these ecosystems; e.g., the Chesapeake Bay. Explain how man-made systems affect the environment; e.g., Deforestation greenhouse effect 7. Organismic Biology Broad Concepts: The living world is very diverse. Beginning with the simplest forms of life, the prokaryotes, to the most complex forms of life, the eukaryotes, organisms differ in size, structure, how they survive, reproduce, and evolve in their environments. 7.1 7.2 7.3 7.4 7.5 7.6 7.7 Differentiate between structures of prokaryotic and eukaryotic cells. Already in 2.2? Identify the characteristics of the three major Domains. I think we reached a consensus that Domains were more relevant than Kingdoms based on molecular bio? Describe the methods of locomotion in microorganisms. (bacteria, algae, protozoans) Distinguish the methods of obtaining food among the microorganisms. (autotrophic and hererotrophic) Is this covered by 2.3? Describe the methods of asexual and sexual reproduction in the microorganisms. Explain the positive and negative roles that the microorganisms play in their environments. (disease, decomposition, food chain, effect on humans) Could this go into environmental? Identify the characteristics of the bryophytes and tracheophytes. (ferns, gymnosperms, and angiosperms) 6 7.8 Explain Alternation of Generations as the method of reproduction in the fungi and each of the higher plant groups. Identify the reproductive organs utilized by each group. 7.9 Identify the structural (cellular and organ) adaptations that provided for the transition of plant life from the aquatic to the terrestrial environments. If this section is too long, I might recommend removing this. 7.10 Describe the structure and function of each of the higher plant vegetative organs. (roots, stems, and leaves) 7.11 Discuss how water and food are transported through the vascular plants. Can this be combined with 7.10? 7.12 Describe the processes of pollination and (double??) I think just fertilization would be OK. fertilization in the seed plants. 7.13 Differentiate between the invertebrate and vertebrate groups of animals. Identify the major phyla of each group, their general characteristics, and examples of each group. 7.14 Place the major animal phyla on a phylogenetic tree to demonstrate the possible evolutionary relationships among the animal phyla. 7.15 Compare the advantages and disadvantages of symmetry (radial or bilateral) in animals. 7.16 Trace the development of body plan in the invertebrates. [two layer ectoderm and endoderm, and three layer - ectoderm, endoderm, and mesoderm (without and with coelom)] 7.17 Describe the structural and reproductive adaptations that led to the great diversity and success of the insects in their environments. 7.18 Describe the evolutionary advances of early vertebrates that led to their great diversity in all environments. 7.19 Describe the various forms of asexual and sexual reproductions demonstrated by the members of the animal kingdom. [7.9, 7.14, 7.17, 7.19 are very broad in scope. I think we need to evaluate if this knowledge is 1) necessary for graduating high-school students and 2) if it is, can we make the objectives more precise. Highlights in turquoise: Appropriate for high-school?] 7 PHYSICAL SCIENCE PHYSICS Note: Certain Physics benchmarks are marked with an asterisk (*). These asterisked benchmarks represent content that is recommended for all students, but is required for those students who plan to continue with Physics coursework at the college level and for many physics intensive majors. A. Motion and Forces A1. Understand that motion can be described and analyzed conceptually and quantitatively. A1.1. Be able to describe the difference between scalar and vector quantities and cite examples. A1.2. Be able to compare and contrast the vector quantities (such as displacement, velocity, acceleration, force, linear momentum) and scalar quantities (distance, speed, energy, mass, work) that are used to describe kinematics (the science of motion). A1.3. Demonstrate a conceptual understanding of a reference frame by explaining why one is needed when describing motion, and by using reference frames to explain and represent the relative motion of two objects. A1.4. Demonstrate a conceptual understanding of average velocity, average speed and average acceleration during intervals of time by determining these quantities using tables and/or graphs of data representing position versus time and velocity versus time. *A1.5. Be able to analyze one-dimensional motion using the description of position, velocity, and acceleration as functions of time, using algebraic descriptions for simple motions (uniform velocity or uniform acceleration). A1.6. Be able to convert between the different sets of units (MKS, English, etc.)often used in kinematics and dynamics. A1.7. Be able to use dimensional analysis to predict the results of simple problems and check the results of more challenging ones. A2. Understand that Newton's laws of motion describe and predict the motion of macroscopic objects, and be able to interpret and apply Newton’s three laws of motion. A2.1.Be able to add and subtract vectors graphically and algebraically in one or more dimensions. A2.2. Demonstrate understanding that a net force is required to alter an object’s motion by describing how the magnitude of the object's acceleration is proportional to the magnitude of the total applied force and the direction of acceleration that of the total applied force. A2.3. Be able to describe the concept of mass as inertia, i.e., as a measure of resistance to change in motion by an applied force. 8 A2.4. Be able to represent forces acting on a system of objects utilizing freebody diagrams. *A2.5. Be able to use Newton's Laws to solve problems in static equilibrium, and problem situations that yield constant acceleration. A2.6. Be able to apply Newton's laws to free fall and projectile motion. A2.7. Be able to describe motion in 2-D and 3-D as the net motion due to independent motions in a rectangular coordinate system. A2.8. Demonstrate conceptual understanding of the circular motion of an object by describing the acceleration(s) it undergoes, and the forces that produce these accelerations. A2.9. Describe the nature of static and kinetic friction, and describe their effects on motion. A2.10. Describe Newton's law of universal gravitation in terms of the attraction between two objects, their masses, and the distance between them. *A2.11. Be able to apply principles of rotational motion to solve problems relating to angular momentum and torque. B. Conservation of Energy and Momentum B1. Understand that the law of conservation of energy provides an alternate approach that can be used to predict and describe the motion of objects. B1.1. Be able to explain work as being due to the action of a force on an object undergoing a displacement. B1.2. Be able to describe using appropriate examples how energy can be converted from gravitational potential energy to kinetic energy and vice versa. B1.3. Demonstrate an understanding of the law of conservation of energy in mechanical systems by using this law to solve for kinematic variables in appropriate problem situations. B1.4. Be able to describe both qualitatively and quantitatively how work can be expressed as a change in mechanical energy. B1.5. Be able to describe both qualitatively and quantitatively the concept of power as work done per unit time. B2. Understand that the law of conservation of momentum provides a complementary approach to the law of conservation of energy that can be used to predict and describe the motion of objects. B2.1. Be able to describe linear momentum as the product of mass and velocity and understand the relationship between the momentum change of an object and the forces acting on it. B2.2. Demonstrate an understanding of the conditions for which momentum is conserved by applying momentum conservation methods in appropriate situations (e.g. those involving collisions). B2.3. Demonstrate a conceptual understanding of the difference between the laws of conservation of momentum and conservation of energy by describing the conditions under which one law or the other, or both, apply. 9 C. Heat and Heat Transfer C1. Understand that heat is energy that is transferred between objects or regions that are at different temperatures, by the processes of convection, conduction, and radiation. C1.1. Explain qualitatively how heat energy is transferred by the processes of convection, conduction, and radiation. C1.2. Explain how heat energy will move from an object at higher temperature to one at lower temperature until equilibrium is reached. Apply to understand everyday phenomena or technological applications, such as how a thermos bottle or insulation works. C2. Understand the concept of energy conservation (First Law of Thermodynamics) and use it to relate various forms of energy. C2.1. Describe the relationship between average molecular kinetic energy and temperature. Understand that heat energy consists of the random motion and vibrations of atoms, molecules, and ions. C2.2. Explain the relationships between the temperature change in a substance for a given amount of heat transferred, the amount (mass) of the substance, and the specific heat. C2.3. Describe the difference between energy and power. Be able to convert between the many units used to describe both energy and power. Use such conversions to discuss the amount of energy (in various forms) contained in disparate systems. C2.4. Describe the various sources of energy used in society. *C2.5. Demonstrate a qualitative understanding of the Second Law of Thermodynamics by describing the Law and the limits it places on the efficiency of devices such as refrigerators and engines. D. Waves D1. Understand that waves carry energy from place to place without the transfer of matter. D1.1. Describe the properties of simple harmonic motion of an object from a basic mechanics viewpoint, and how the period, frequency, and amplitude of motion are determined by the conditions and material properties of the object. D1.2. Describe the measurable properties of waves (speed, frequency, wavelength, amplitude, and period)and explain the relationships among them. D1.3. Describe the differences between standing and traveling waves in mechanical systems and cite examples. D1.4. Describe the differences between transverse and longitudinal waves in mechanical systems and cite examples. D1.5. Recognize the effects of media on the speed of a mechanical wave by explaining that mechanical waves move faster through a solid than through a liquid and faster through a liquid than through a gas. D1.6. Describe the differences between mechanical waves (especially sound) and electromagnetic waves, especially including their propagation speeds. 10 D1.7. Demonstrate an understanding of the basic interactions of waves with matter by describing reflection and refraction. D1.8. Explain how changes in the wavelength and frequency of waves as they pass through media affect the propagation of the waves. D1.9. Describe the apparent change in frequency of waves due to the motion of a source or observer (the Doppler effect) and cite examples from everyday life or use in technological applications, such as radar guns. D1.10. Be able to apply basic wave concepts to understand everyday phenomena or technological applications, such as ultrasound and sonar. E. Electromagnetism E1. Understand that stationary and moving charged particles result in the electrical and magnetic phenomena. E1.1. Be able to describe the attractive and repulsive electrostatic forces between objects in terms of their charges and the distances between them, as described by Coulomb’s law. E1.2. Be able to compare and contrast the forms of Newton’s law of gravity (between two masses) and Coulomb’s law (between two charges) in terms of their functional form (inverse square laws) and magnitudes. Be able to explain that gravitational forces play a more important role in macroscopic systems than electrical forces due to the overall charge neutrality of matter. E1.3. Demonstrate a conceptual understanding of the differences between insulators and conductors by explaining how electric charge tends to be static on insulators and can move on the surface of and inside conductors. E1.3a. Be able to explain that energy can produce a separation of charges, with a subsequent change in electrostatic potential energy. E1.3b. Demonstrate a conceptual understanding of electric potential (voltage) as a potential energy per unit of charge. E1.4. Explain how electric current is a flow of charge caused by a difference in electric potential (voltage) and that power dissipation is given by the product of current and voltage. E1.5. Be able to describe a qualitative and quantitative understanding of current, voltage, resistance and the connection between them, as described by Ohm's law. E1.6. Be able to recognize circuit symbols and the common circuit elements (battery, wires, resistance) in a schematic diagram. E1.7. Be able to predict qualitatively how different combinations of components such as batteries, light bulbs, and switches will behave in series and parallel configurations. *E1.8. Be able to analyze simple arrangements of electrical components, in both series and parallel configurations. E1.9. Apply concepts related to electricity and circuits to understand everyday phenomena or technological applications, such as batteries, household circuitry, and power grids. 11 *E1.10. Recognize that moving electric charges create (and experience) magnetic forces and moving magnets produce electric forces. Recognize that the interplay of electric and magnetic forces form the basis for the operation of electric motors, generators, and other technologies. F. Electromagnetic radiation F1. Understand concepts dealing with electromagnetic waves F1.1. Recognize that electromagnetic waves are transverse waves and travel at the speed light (in vacuum). F1.2. Describe the electromagnetic spectrum in terms of frequency and wavelength, and identify the location of radio waves, microwaves, infrared radiation, visible light (rainbow spectrum), ultraviolet rays, x-rays, and gamma rays. F1.3. Apply concepts of electromagnetic waves to understand everyday phenomena or technological applications, such as radio, microwave, and X-ray devices. F2. Understand the physics underlying the use of optical instruments. F2.1. Using diagrams, describe the interactions of electromagnetic waves (especially light) and matter leading to the phenomena of refraction and reflection. *F2.2. Demonstrate an understanding of how refraction and reflection effects are used in the design and performance of optical instruments by solving basic geometric optics problems consisting of mirrors, microscopes, telescopes, etc. CHEMISTRY Overview: Chemistry is the study of matter – its properties, the changes it goes through, and the underlying structure that helps us account for the specific properties and possible changes. There are two separate contexts in which students encounter the impact of chemistry in their lives: The context of their interactions with matter as part of their everyday experiences and the context of their study of this field in their educational experiences. This set of standards attempts to recognize and address these different contexts. As a result, there are those standards for which all students are expected to achieve proficiency in order to produce a citizenry scientifically literate with relation to chemistry [these standards are identified by a “B” in brackets, for basic]; there are also those standards for which students who will be pursuing math- / science-related careers are expected to achieve proficiency in order to prepare them for studies at the ‘next level’ [these standards are identified by an “A” in brackets, for advanced]. It is important for the users of this document to understand that the organization of the content topic areas (e.g. The Macroscopic Realm of Matter, An Atomic Perspective, Heat, and Phase Change) reflects arbitrary conceptual divisions and does not necessarily indicate the way a particular chemistry course should be organized. For instance, instead of completely separating the macroscopic perspective of 12 matter from the atomic molecular view, it makes pedagogical sense to constantly intertwine the two so that students may become more ‘fluent’ in moving back and forth between the two realms. A. The Macroscopic Realm of Matter A.1. Interpret the warning labels on reagent bottles and household chemicals to identify potential dangers in both the use and the interactions with other materials of the substance present in the container. [B] A.2. Explain the properties of materials (e.g. density, melting point, conductivity, corrosiveness), describe their relative utility in characterizing materials, and use them to determine the identity of unknown substances. [B] A.3. Select and use measurement devices properly (including identification of appropriate units and reading to correct significant figures) to obtain quantitative information about the properties of a material (e.g. mass, volume, etc.). [B] A.4. Convert property information about a material into a properly-constructed graph and analyze/interpret the graph to obtain additional information (such as density from the mass-volume graph of a pure substance). [B] B. Gases and the Beginnings of a Microscopic Perspective B.1. Identify the relationships between the physical properties of gases (e.g. pressure and volume as stated in Boyle’s Law) and describe methods for the chemical preparation of gases (e.g. how oxygen can be prepared by the catalyzed decomposition of hydrogen peroxide). [B] B.2. Apply the principles behind various gas-law relationships to explain everyday / familiar phenomena (e.g. Boyle’s Law to explain how we drink through a straw or Charles’ Law to explain the flight of a hot-air balloon). [B] B.3. Explain the Law of Conservation of Mass (and its implications in terms of recycling) and the Law of Definite Proportions (and its implications in terms of a definition of compound) and describe how these principles – along with the study of gases – lead to the development of the first modern atomic theory. [B] B.4. Identify the main points of the Kinetic Molecular Theory [B] and use them to explain the various relationships between the physical properties of gases. [A] B.5. Perform calculations with the Combined Gas Law / Ideal Gas Law. [A] C. An Atomic Perspective, Heat, and Phase Change C.1. Identify the main points of Dalton’s Atomic Theory and how these can be used to define elements and compounds; describe Dalton’s model of the atom, its limitations, and its usefulness in accounting for the Kinetic Molecular Theory. [B] C.2. Describe the atomic / molecular differences between solids, liquids, and gases using the Kinetic Molecular Theory and explain what happens at 13 the atomic / molecular level as a pure substance goes through phase transitions. [B] C.3. Distinguish between heat and temperature both at the macroscopic level (heat is extensive while temperature is intensive) and at the microscopic level (heat involves both the motion and position of atoms/molecules while temperature measures only motion); identify the direction of heat transfer (into – i.e. endothermic – and out of – i.e. exothermic – a system) during various physical and chemical changes of matter. [B] C.4. Explain entropy in terms of the level of atomic / molecular freedom or the available probability states in a system [B] and use the tendency of nature towards high entropy to predict the spontaneity of physical / chemical processes. [A] C.5. Describe the molecular nature of a closed system that has established a dynamic equilibrium – particularly one involving two different phases of matter [B] – and use this concept to explain why the melting point and freezing point (as well as the boiling point and liquefaction point) are the same for a pure substance. [A] D. Atomic Structure and Radioactivity D.1. Describe Thomson’s and Rutherford’s models of the atom, the experiments leading to each, and the limitations and usefulness of each model (Thomson’s model in terms of accounting for electrical phenomena and Rutherford’s in terms of explaining radioactivity). [B] D.2. Identify the major subatomic particles [protons, neutrons, and electrons], describe the properties of each, and explain the way they interact to control the physical, chemical and nuclear properties of atoms. [B] D.3. Explain what isotopes are in terms of the major subatomic particles, identify how isotopes of the same element relate to each other and explain how isotopes are used in certain applications such as medical diagnostic studies. [B] D.4. Distinguish between radiation and radioactivity (including explaining why the radiation from radioactive materials is so dangerous), identify the atomic source of radioactive decay, [B] and explain the role that the four forces of nature (gravity, electromagnetic, weak, and strong) play (or don’t play) in radioactive processes. [A] D.5. Describe / represent different decay / nuclear processes (including fission and fusion) and explain industrial, medical, military applications that are based on the properties of the particles produced by these processes (e.g. the use of alpha radiation to reduce static electricity in copier machines). [A] D.6. Explain the concept of half-life in terms of the unpredictability of radioactive decay processes [B] and describe the implications of the half-life concept in terms of the relative danger of isotopes and the technique of radioactive dating. [A] E. Patterns, Organizing the Elements, and Periodicity 14 E.1. Use the history of attempts to group the elements (e.g. Dobereiner’s Law of Triads, Newland’s Law of Octaves) to account for the organizational pattern on the modern periodic table, particularly its emphasis on chemical properties over physical ones. [B] E.2. Identify structural features of the standard version of the periodic table (e.g. periods, groups, etc.) and explain how those might be used in generating information about an element. [B] E.3. Distinguish between metals, non-metals and metalloids and use the format of the periodic table to classify an element into these groups. [B] E.4. Use the periodic table and a knowledge of its structure to predict the properties of unknown elements (e.g. element 115) and to identify trends in such characteristics as size, reactivity, etc. [B] E.5. Describe Bohr’s model and use it to give a simplified account of why elements in the same group have similar properties and why atoms of elements become larger as you go down a family. [B] F. Chemical Bonding F.1. Describe the macroscopic differences between covalent and ionic compounds and how those differences can be accounted for in terms of the atomic processes producing these different types of bonds; use Lewis structures and Lewis dot diagrams to provide simple representations of covalent and ionic bonding processes. [B] F.2. Determine the formulas for both simple covalent and ionic compounds based on the positions of the combining elements on the periodic table and trends in combining ratios. [B] F.3. Explain the concept of electronegativity and use it as a tool to explain the presence of charges in bonds and as a first-order explanation of the difference between covalent and ionic compounds. [B] F.4. Explain the concepts of ionization energy and electron affinity and describe / explain trends down and across the periodic table in these properties as well as electronegativity. [A] F.5. Describe what a bond energy (enthalpy) value represents and use a table of these values to account for patterns of reactivity and to predict reactions likely to be spontaneous. [A] G. Ionic / Molecular Structure and the Structure-Property Relationship G.1 Predict the shapes of simple molecules through the use of Valence Shell Electron Repulsion (VSEPR) Theory; identify some basic crystal structures for simple ionic compounds. [B] G.2. Explain how electronegativity differences and molecular symmetry determines whether a molecule is polar or non-polar (especially molecules like water, NH3, CO2, etc.). [B] G.3. Distinguish between chemical bonds and forces of attraction and the impact each has on the physical and chemical properties of a substance. [B] 15 G.4. Describe the relationship between the strength of forces of attraction and the physical properties of a substance such as boiling point and solubility. [B] G.5. Analyze a molecule to identify its attractive forces and use this analysis to predict some of the physical properties of the molecule. [A] H. Solutions and Acids and Bases, Part I H.1. Identify the properties of solutions (including important colligative properties) and describe a microscopic picture that accounts for at least some of these. [B] H.2. Identify the species present in a simple solution system (including important polyatomic ions) and describe how these affect the physical (especially conductivity) and chemical (such as the kinds of reactions possible) properties of that system. [B] H.3. Use qualitative terms (unsaturated, concentrated, etc.) to describe the concentration of a solution [B]; perform calculations to determine quantitatively the concentration of a solution (e.g. % weight, molarity, normality) given the appropriate information [A]. H.4. Identify examples of acids and bases and describe one or more models (e.g. Arrhenius, Brönsted-Lowry, or Lewis) that explain the properties of each of these two classes. [B] H.5. Identify examples of weak and strong acids and bases and connect this classification to the way each is used / handled (e.g. certain weak acids are found in food products; strong laboratory acids must be handled with great caution) [B]; use one of the acid-base models/theories to account for the molecular differences between weak and strong acids [A]. H.6. Explain what the pH scale measures, describe the significance of the fact that it is a logarithmic scale, and connect pH values for a common material (e.g. vinegar or baking soda) to its properties / uses [B]; use the concept of pH to explain buffers [A]. I. Chemical Reactions, Oxidation-Reduction, and Acids and Bases, Part II I.1. Interpret the symbols used in chemical reactions such as subscripts, coefficients, states of matter, heat, equilibrium, etc. [B] I.2. Explain why a chemical reaction must be balanced and the significance of the final set of coefficients [B]; determine the values required to balance an equation and connect these values to a microscopic representation of the reaction. [A] I.3. Identify basic types of chemical reactions (e.g. decomposition, single replacement) [B]; use the understanding of reactions types to identify likely products of simple chemical reactions. [A] I.4. Identify important examples of acid-base neutralization reactions (e.g. the chemistry of antacid tablets) and of oxidation-reduction reactions (e.g. the chemistry of batteries) [B]; describe similarities and differences between these two types of reactions (e.g. both involve an exchange of a particle; one involves exchange of H+ and one exchange of e--) [A]. 16 I.5. I.6. I.7. Explain what is meant by the mole being an amount unit that ‘bridges’ mass and number of particles [B]; perform calculations involving conversions between mass, mole, and number of particles, including stoichiometry calculations [A]. Describe the factors that make a reaction favorable (negative enthalpy, positive entropy) or unfavorable and analyze simple reactions for these factors. [A] Apply the concept of dynamic equilibrium to chemical reactions by indicating the species that would be present in an equilibrium state of a reaction and explaining the effect of a stress on an equilibrium. [A] J. A Modern View of Matter J.1. Identify some of the modern instruments (e.g. STM, AFM) used to study matter at the atomic / nanometer scale and what it means to ‘see’ atoms with such instruments. [B] J.2. Describe what the idea of particle-wave duality indicates about the nature of an electron in our modern view; explain how the modern model replaces the idea of predictability for an electron with the notion of probability. [B] J.3. Use the modern model to qualitatively describe how light interacts with matter, including the idea of ground states and excited states. [A] J.4. Connect features of the modern model of the atom (e.g. the s, p, d, and f subshells) with structural features of the periodic table (e.g. the blocks of elements in the standard version) [B]; use the format of the periodic table to write electron configurations for main group elements and transition metals [A]. 17 SCIENTIFIC INQUIRY: UNIFYING PRINCIPLES 1. Systems, Order, and Organization In the final analysis, the main objective of science is to study systems: To characterize them, detail their structure, describe their order and explain their organization. The term system and its implications are, unfortunately, often not explicitly addressed with students, despite the fact that this idea represents one of the first principles of science. Using systems as a starting point for the set of unifying principles allows us to justify the choices of the remaining principles and the grouping of them in terms of their relationship with this central notion. 2. Form and Function In order to have a starting point for studying systems that is simple and accessible to the initially naïve viewpoint of students, teachers often focus the conceptual attention on a single component of a system. That single component then is analyzed in terms of its form and then that form is connected with function. The interplay between form and function is certainly central to biology, but it has an important place in the other disciplines as well. 3. Measurement, Scale, and Tools Any system can be explored at multiple levels. For instance a human being can be explored at the level of organs as well as the cellular level or even the molecular level. Those different levels often (but not always) represent different scales of size; understanding the system at those different scales requires understanding the differences in the measurements used and the tools required to study the levels. 4. Energy, Change, and Equilibrium One of the most fundamental attributes of a system is its tendency towards change. That change is usually a result of a response to an interaction with its environment. In the end, that change normally results in a new state of constancy – an equilibrium – within the system in relationship to its surroundings. Under- standing the forces that spur change – particularly the influx or outflux of energy – and the way that the system responds to that change is one of the most fundamental pursuits of science. 5. Models, Patterns, and Explanations How do we study and characterize all of these different aspects of a system that were discussed above? This is part of the nature of the scientific process. Two of the main cogs in that process are the production of models and the recognition of patterns. Those models and patterns or part of or lead to explanations of why the system has the features that it does and how those features allow it to interact with its 18 environment. Further, these explanations give us a way to make predictions about a system, its unexamined characteristics and features of its interaction with the surroundings that have been previously unexplored. Additional Notes: 1. I recognize that what I have proposed here is highly similar to the NSES notions of unifying principles. I am not trying to take credit for coming up with this on my own because I have certainly read this document at some point in my past. What I am suggesting, though, is a conceptual thread that runs through the themes selected and helps us think in a rational way about what to include and why, and about how to organize those things we include. 2. There are a couple of items conspicuously missing from this list. Most important are inquiry, environment, and technology. I address each one of the separately below: a. Inquiry is problematic. Amy pointed out an important distinction that I have maintained in the list presented above: Each of the things in the unifying principles list is an object of scientific study; inquiry appears (to the extent that there is any agreement on what this term means) to be the process by which that study is conducted. Based on that, it would seem most appropriate to separate inquiry from the unifying principles in a separate portion of the document. However, I would be reluctant to title that section “Inquiry” as a result of the ambiguity of the term and the fact that – as Bruce Smith (?) pointed out – it often has connotations regarding pedagogy more than the process of science. It would seem to make more sense to have a section titled “The Process of Science” that describes many features of the nature of science that have been established by groups such as NSES and Benchmarks. Most important would be to present some clear definitions and examples of terms such as hypothesis, theory, model, etc. so that when they appear in the content standards, they would be used unambiguously. b. My opinion of Environment and Technology is that they should represent a separate unifying theme category. This would allow one to include ideas regarding how technological developments are related to our understanding of systems, how systems dictate the design of technology and how technology impacts the environment through its effect on systems. I did not include this in the list above because my stance did not seem to have much support in the group, making this theme the most controversial. 19