Sedimentary Rocks 7 Sedimentary Rocks begins with a discussion of diagenesis and lithification of sediment followed by a detailed examination of the various detrital and chemical sedimentary rocks, including shale, sandstone, conglomerate, limestone, dolostone, chert, and coal, as well as several evaporites. Following a look at the classification of sedimentary rocks and the various sedimentary environments, the chapter concludes with a discussion of sedimentary structures. Learning Objectives After reading, studying, and discussing the chapter, students should be able to: Discuss the physical and chemical processes involved in diagenesis. List the common minerals found in detrital sedimentary rocks. Explain how detrital sedimentary rocks are formed. List and briefly define the major types of detrital sedimentary rocks. Explain how chemical sedimentary rocks are formed. List and briefly define the major types of chemical sedimentary rocks. Discuss the classification of sedimentary rocks. List and briefly discuss the major sedimentary depositional environments. Explain the concept of sedimentary facies. List and discuss the importance of sedimentary structures. Chapter Outline___________________________________________________________________ I. What is a sedimentary rock? A. Products of mechanical and chemical weathering B. Account for about 5 percent (by volume) of Earth’s outer 16 kilometers (10 miles) C. Contain evidence of past environments 1. Provide information about sediment transport 2. Often contain fossils D. Economic importance 1. Coal 2. Petroleum and natural gas 3. Sources of iron, aluminum, and manganese B. Diagenesis – all chemical, physical, and biological changes that take place after sediments are deposited 1. Occurs within the upper few kilometers of Earth’s crust 2. Includes: a. Recrystallization – development of more stable minerals from less stable ones b. Lithification – unconsolidated sediments are transformed into solid sedimentary rocks by 1. Compaction 2. Cementation by the materials a. Calcite and/or b. Silica c. Iron oxide II. Turning sediment into sedimentary rock A. A great deal of change can occur to sediment after it is deposited 57 58 CHAPTER 7 III. Types of sedimentary rocks A. Material originates from mechanical and/or chemical weathering B. Rock types are based on the source of the material 1. Detrital rocks – material is solid particles 2. Chemical rocks – material that was once in solution IV. Detrital sedimentary rocks A. Chief constituents 1. Clay minerals 2. Quartz 3. Others a. Feldspars b. Micas B. Particle size is used to distinguish among the various types of detrital rocks C. Common detrital sedimentary rocks (in order of increasing particle size) 1. Shale a. Thin layers (lamina) b. Most common sedimentary rock 2. Sandstone a. Form in a variety of environments b. Sorting, shape, and composition of the grains can be used to interpret the rock’s history c. Quartz is the most predominant mineral 3. Conglomerate and breccia a. Conglomerate consists largely of rounded gravels b. Breccia composed mainly of large angular particles V. Chemical sedimentary rocks A. Consist of precipitated material that was once in solution B. Precipitation of material occurs in two ways 1. Inorganic processes 2. Organic processes (biochemical origin) C. Common chemical sedimentary rocks 1. Limestone a. Most abundant chemical rock b. 2. 3. 4. 5. Composed chiefly of the mineral calcite c. Marine biochemical limestones 1. Coral reefs 2. Coquina 3. Chalk d. Inorganic limestones 1. Travertine 2. Oolitic limestone Dolostone Chert a. Made of microcrystalline quartz b. Forms 1. Flint 2. Jasper (banded form called agate) Evaporites a. Evaporation triggers deposition of chemical precipitates b. Examples 1. Rock salt 2. Rock gypsum Coal a. Different from other rocks – made of organic material b. Stages in coal formation 1. Plant material 2. Peat 3. Lignite 4. Bituminous VI. Classification of sedimentary rocks A. Classified according to the type of material B. Two major groups 1. Detrital 2. Chemical C. Two major textures used in the classification of sedimentary rocks 1. Clastic a. Discrete fragments and particles b. All detrital rocks have a clastic texture 2. Nonclastic a. Pattern of interlocking crystals b. May resemble igneous rocks Sedimentary Rocks VII. Sedimentary environments A. A geographic setting where sediment is accumulating B. Determines the nature of the sediments that accumulate C. Types of sedimentary environments 1. Continental a. Dominated by erosion and deposition associated with streams b. Glacial c. Wind (eolian) 2. Marine a. Shallow (to about 200 meters) b. Deep (seaward of continental shelves) 3. Transitional (shoreline) a. Tidal flats b. Lagoons c. Deltas D. Sedimentary facies 1. Different sediments often accumulate adjacent to one another at the same time 59 2. Each unit (called a facies) possesses a distinctive set of characteristics reflecting the conditions in a particular environment 3. The merging of adjacent facies tends to be a gradual transition VIII. Sedimentary structures A. Provide information useful in the interpretation of Earth history B. Types 1. Strata, or beds (most characteristic feature of sedimentary rocks) 2. Bedding planes that separate strata 3. Cross-bedding 4. Graded beds 5. Ripple marks 6. Mud cracks 7. Fossils Answers to the Review Questions 1. In Earth's crust, igneous rocks exceed sedimentary rocks in volume. Neither rock type is evenly distributed. In the interiors of continents, sedimentary rocks occur as thin veneers covering over much larger volumes of igneous and metamorphic rocks deeper in the crust. Ocean basin rocks are mainly igneous with very thin covers of sediments. Sedimentary strata many kilometers in thickness accumulate only in relatively restricted basins along the edges of continents or in deep rift basins where continental blocks are splitting apart. 2. The three basic categories of sedimentary rocks are detrital, chemical, and organic. Detrital sedimentary rocks originate from the weathering, transportation, and deposition of solid particles (preexisting earth materials). Chemical sedimentary rocks are formed from soluble material that is produced mainly by chemical weathering. The ions in solution are then precipitated by either inorganic or biologic processes to form various chemical rocks. Organic sedimentary rocks owe their origin to the accumulation of undecayed plant material that constitutes the “sediment” in such rocks. Coal, formed from the remains of plants that accumulated in ancient terrestrial swamps, is the primary example of an organic sedimentary rock. 60 CHAPTER 7 3 Detrital refers to mineral grains and rock fragments, such as sand grains or pebbles, which are produced during the weathering process and transported to the site of deposition as particles. The most abundant detrital minerals in sediments are quartz and clays. Quartz is an abundant mineral in many rocks. It resists fracturing and mechanical weathering and is resistant to solution and decomposition from chemical weathering. Thus quartz can be thought of as a residual mineral, left over and concentrated in detrital sediments after the other rock-forming minerals, such as feldspars and ferromagnesians, have decomposed. Clays are a major component of shales and mudstones, but they are rarely abundant in other common rocks. Clays are the weathering products of feldspars and aluminum-bearing, ferromagnesian minerals like hornblende and biotite. Being stable in the weathering environment, clays are major soil components; thus they are readily eroded, transported, and deposited as detrital sediments. 4. This is done on the basis of clast size, as shown in the following table. Detrital Fragment (Clast) Size Dominant sediment clast pebble, cobble, boulder; > 2 mm sand; between 1/16 & 2 mm silt; between 1 / 16 & 1 / 256 mm mud; clay and silt mixture clay; < 1/256 mm Name of lithified rock conglomerate sandstone siltstone mudstone shale 5. Shales are typically fissile with numerous, small cracks that allow water ready access during weathering, and they contain clay minerals as their dominant component. Many clay minerals strongly absorb water and swell, a process that greatly lowers the mechanical strength of the shale. This process generates internal stresses that push open new cracks and extend old ones deeper into the unweathered portions of the rock. Thus deeply weathered shales typically crumble; fresh, unweathered shales are brittle and splintery, and the broken fragments can be very hard and tough. Black shales typically contain disseminated pyrite; which readily decomposes in the presence of water and oxygen, generating acidic waters that hasten disintegration of the rock. 6. A sand grain, regardless of initial shape, is gradually rounded during transport. Sharp corners and edges are preferentially abraded, resulting in rounded but not necessarily spherical grains. Well-sorted sands are deposited in aqueous and terrestrial environments characterized by vigorous current activity. Finer particles are winnowed out and carried elsewhere; coarser, gravel-sized clasts have already been deposited or abraded and broken into smaller particles. The currents are highly selective and although finer particles may be available, only sand grains of roughly equal size are deposited, such as in a sand dune or on a beach. Generally, well-sorted sands are also well-rounded, the grains having been extensively transported prior to deposition. 7. Conglomerates are detrital sedimentary rocks dominated by pebbles or larger clasts. The clasts are rounded, mainly by stream transport, and many conglomerates exhibit good stratification. Breccias are rocks also dominated by pebbles or larger particles, but the clasts are angular rather than rounded. They can form by explosive fragmentation during volcanism, by fracturing along faults and as products of mass wasting. Breccias of sedimentary origin are closely related to mass-wasting processes, and the detrital clasts have moved only a short distance from their bedrock source. Sedimentary Rocks 61 8. The dominant constituents of chemical sedimentary rocks were transported to the site of deposition in solution. Two different categories are defined on the basis of the precipitation mechanism. If evaporation caused precipitation, the rocks are termed evaporites. If living organisms were involved, such as with the precipitation of calcium carbonate by algae or invertebrate animals, the rocks are biogenic (biochemical) in origin. 9. Evaporites are chemical sedimentary rocks, such as bedded salts, precipitated from isolated bodies of seawater or saline lakes undergoing intense evaporation. Gypsum, anhydrite (calcium sulfate), and halite (sodium chloride) are all examples of evaporites. 10. Minerals precipitate from the evaporation of seawater in the order of their relative solubilities. Calcium carbonate (calcite and aragonite) and dolomite are the least soluble and precipitate first. However, much of the dolomite associated with evaporite deposits is known to originate secondarily by reaction of primary calcium carbonate and very late stage, Mg-rich brines. The calcium sulfates (anhydrite and gypsum) reach saturation next. Extensive, additional evaporation is required for sodium chloride to reach saturation, and the highly soluble salts such as potassium chloride (sylvite) reach saturation only after most of the sodium chloride has been removed from the brine by precipitation of halite. 11. (a) Gypsum (calcium sulfate) is a major ingredient of plasters. (b) Shale typically breaks into thin plates or pen-shaped fragments, as contrasted to mudstone, which typically breaks into more equidimensional pieces or blocks. (c) Coal, formed from the accumulation of land plants in ancient swamps, is the primary example of an organic sedimentary rock (d) The most abundant chemical sedimentary rock is limestone, which is composed of calcium carbonate (CaCO3). (e) Chert is a bedded deposit of very fine-grained quartz (silica). (f) Oolitic limestone is composed of small, concentric grains of calcite called oolites. 12. Chemical sedimentary rocks are distinguished from one another by their mineralogy. Limestones are calcite and dolostones are dolomite, a calcium magnesium carbonate mineral. Evaporites include bedded halite (sodium chloride) and gypsum or anhydrite (calcium sulfates). Hardness, taste, luster, and response to acids help in mineral identification; microscopic and x-ray analyses can be employed if necessary. 13. Diagenesis refers to the collective chemical, physical, and biological changes that take place following deposition and during and after lithification of sediments. Typically, diagenesis occurs within the upper few kilometers of Earth’s crust at temperatures below 200ºC. An example of diagenesis is recrystallization, which involves the formation of more stable minerals from less stable ones. 14. Compaction is most important as a diagenetic process in fine-grained sedimentary rocks such as shales or mudstones. Sand and other coarse sediments are much less compressible so that compaction is not as significant as it is in finer sediments. 15. The three common cementing agents for sedimentary rocks are calcite, silica (quartz), and iron oxide. They are relatively easy to distinguish from one another by their physical or chemical properties. Calcite will readily effervesce with dilute hydrochloric acid, silica is much harder than the other two, and a distinctive orange to dark red color normally identifies iron oxide. 16. Clastic means fragmental or broken and texture describes the shapes, sizes, and mutual packing arrangements of the mineral grains in a rock. Since they form from transported mineral grains and/or rock fragments, all detrital sediments and sedimentary rocks have clastic textures. Nonclastic textures include 62 CHAPTER 7 the crystalline textures of chemical rocks like chert and evaporites. Limestones may have crystalline or clastic textures, depending on the nature of the original sediment and on the subsequent geologic history of calcite solution and crystallization in the rock. 17. The similarities arise because many igneous and chemical sedimentary rocks have crystalline textures, in which the mineral grains are tightly interlocked and bonded together. Most igneous rocks consist of two or more dominant silicate minerals. All sedimentary rocks may show stratification, and those with crystalline textures are typically composed of only one dominant mineral, such as calcite, dolomite, or silica. The minerals (calcite, dolomite, and evaporites) of nonclastic sedimentary rocks are much softer than the silicate minerals of igneous rocks. Carbonate minerals react with strong acids and the common evaporite minerals such as halite are easily soluble and can be identified by taste. Fine-grained to microcrystalline, siliceous, sedimentary rocks such as chert might be confused with aphanitic igneous rocks. However, “bedded” chert is monomineralic and is commonly stratified. 18. The three main categories of sedimentary environments are continental, marine, and transitional. Continental environments include streams, alluvial fans, glacial deposits, eolian (deposited by wind) deposits, and playa lakes. Marine environments are subdivided into shallow marine deposits (depths of 200 meters or less) such as coral reefs and deep marine deposits (depths greater than 200 meters) like those that accumulate on the bottom of deep ocean basins. Transitional environments, as the name implies, are those areas in between continental and marine settings such as beaches, tidal flats, barrier islands, and deltas. 19. Terrigenous – These sediments are composed of rock and mineral grains derived by subaerial and submarine weathering, erosion, and mass wasting of preexisting rocks and minerals. They are detrital sediments with clastic textures. Biogenous – The sediment particles were precipitated by once-living organisms. Most biogenous or biogenic sediments are oozes, consisting mainly of minute coccolithophores and foraminifera (calcareous; calcium carbonate) or diatoms and radiolarians (siliceous; silica). Hydrogenous – These are sediments chemically precipitated from seawater without biological intervention. Examples would be the manganese-rich nodules on parts of the ocean bottom and metal-rich sediments around seafloor, hot spring vents. 20. Most sediments and sedimentary rocks show an original layering (stratification) because they were deposited in nearly horizontal sheets or layers. Numerous thin strata in shales and some sandstones are easily visible. In other rocks such as graywacke and reef-deposited limestone, the deposit is a single, massive bed or lens and therefore internal stratification may not be so evident. 21. Both are characteristic of sedimentary rocks, but they originate in quite different environments. Graded bedding indicates that bottom currents were absent from the depositional environment. The sediment was not reworked following deposition. A sediment-laden turbidity current, initiated by slumping of sediments in shallower waters, loses energy and slows down as it moves along the bottom into deeper waters. Unaffected by bottom currents, the particles settle out in the order of their grain sizes, the coarser ones first and the fine silts and clays last. Thus the deposit exhibits an internal, vertical grading in particle sizes but lacks internal stratification (bedding) surfaces. Sedimentary Rocks 63 Cross-bedding describes the multiple sets of typically thin, non-parallel strata that develop internally as sand dunes, ripples, and some fluvial beds accumulate. Some sets of strata are laid down parallel to subhorizontal, gently inclined, transport surfaces. Others are inclined at angles up to 35°, the angle of repose for sand. These inclined strata are deposited on the steeper, leeward, slopes (usually a slip face) of mound-like sand accumulations such as dunes, ripples, or sand waves in a stream channel. By definition, deposits with graded bedding are poorly sorted whereas cross-bedded sands are commonly well-sorted. 22. Current ripples result from unidirectional flowing currents. They can be considered as small-scale dunes that migrate up current in higher velocity regimes and down current in moderate to low velocity regimes. The ripples are asymmetric with a gentler slope facing up current and the steeper slip face inclined downstream. The different slope inclinations can be used to infer paleocurrent directions and the “dunes” are usually cross-bedded, allowing the original stratigraphic top direction to be determined in most cases. Current ripples are common features in fluvial and eolian sandstones and they can also form in other environments, such as in a tidal channel. Oscillation ripples form in response to the back and forth sloshing of bottom waters as shallow-water waves pass overhead. The ripples are symmetrical with relatively narrow, peaked crests and broad, shallow depressions. Slightly coarser “lag deposit” grains typically occupy the centers of the depressions. These ripples form in shallow water environments subjected to a steady supply of incoming waves that pass by in more or less a consistent direction. Because they require steady, consistent, incoming waves to develop, symmetrical ripples are formed mainly in coastal marine environments. Lecture outline, art-only, and animation PowerPoint presentations for each chapter of Earth, 9e are available on the Instructor’s Resource Center CD (0131566911). 64 NOTES: CHAPTER 7