General Chemistry 0112001 A 12 11002 51 0317 165509 There are only four fundamental types of force in the universe. 9 A. True B. False 0041 0112002 B 12 11004 51 18251826182709 Converting a common logarithm (base 10) to a natural logarithm (base e) can be accomplished by multiplying by 2.303. 9 A. True B. False 0043 0120001 A 12 11006 31 15250787007209 Haber developed a process for synthesizing ammonia. 9 A. True B. False 0041 0120002 B 12 11008 31 14860606018909 More elements were discovered before 1800 than after. 9 A. True B. False 0040 0120003 B 12 11010 31 14860189060609 The last of the elements known today was discovered prior to 1940. 9 A. True B. False 0040 0130001 B 12 11012 31 01960066000409 Hydrogen compounds are known as halogens. 9 A. True B. False 0041 0130002 B 12 11013 Titanyl sulfate is Ti SO . 4 2 4 9 A. True B. False 0043 51 14610701022409 0130003 B 12 11015 31 02241323 09 It is incorrect to write P O for the formula for phosphoric 4 25 oxide. 9 A. True B. False 0043 0130004 A 12 11017 31 08460066003509 A hydride is a compound containing hydrogen in the _1 oxidation state. 9 A. True B. false. 0043 0130005 A 12 11019 31 08461296117809 Some hydrides do not contain the hydride ion. 9 A. True B. false. 0043 0130006 B 12 11020 31 08130066019609 An anhydrous compound is one which contains no hydrogen. 9 A. True B. false. 0043 0130007 A 12 11022 31 00770804002809 Acidic anhydrides are oxides of nonmetals. 9 A. True B. false. 0043 0130008 B 12 11023 31 14861461018909 All of the elements are named following a set pattern. 9 A. True B. False 0040 0130009 B 12 11025 31 Na S is named sodium sulfate. 4 2 9 A. True B. False 0040 14861461001809 0130010 B 12 11026 31 148604581178 5 2_ The SO ion is called a sulfate ion. 4 3 9 A. True B. False 0040 0130011 B 12 11028 31 054818390730 5 3+ A gaseous ferric ion (Fe ; Z = 26) and a gaseous chromium atom (Z=24) are isoelectronic. 9 A. True B. False 0043 0160002 AACBABB 73 11030 52 049980010195149006 MACROITEM STEM 2The following questions refer to the kinetic_molecular theory. 2After each item number on the answer sheet, blacken space 2 A. if the item refers to observational or experimental 2 evidence which supports the theory 2 B. if the item refers to an hypothesis or an assumption 2 concerning the theory which was formulated long 2 before there was experimental evidence to test it, 2 or has not as yet been entirely proven to be true 2 experimentally 2 C. if the item refers to something which has nothing to do 0 with the theory MACRO SUB_ITEM # 1 The volume of a gas increases with an increase in temperature when 1 the pressure remains constant. ETS2 OS MACRO SUB_ITEM # 2 2 A gas always exerts pressure no matter how much it expands. MACRO SUB_ITEM # 3 3 Most gases are colorless. MACRO SUB_ITEM # 4 Gases are composed of small particles called molecules which are 4 relatively far apart and in rapid motion. MACRO SUB_ITEM # 5 5 Gases diffuse readily. MACRO SUB_ITEM # 6 6 Molecules are perfectly elastic. MACRO SUB_ITEM # 7 9 Molecules on colliding lose no energy. 0170001 A 13 11043 Potential energy is A. energy of position B. energy of motion 9 C. heat energy 31 80018002 11 06 ETS2 OS 0170002 B 12 11045 31 149504710149 Appropriate conversion factors would allow you to convert from a volume measurement in cubic feet to a density measurement in grams per cubic centimeter. 9 A. True B. False 0009 0170003 B 12 11048 32 14860795 The carat unit of weight is larger than a gram. 9 A. True B. False 0040 09 0170004 B 12 11050 31 14860445015009 A 1000_carat diamond weighs more than one kg. 9 A. True B. False 0172001 A 12 11051 31 01500149 09 Nearly all countries, including England and excepting America, have already adopted or are now adopting a metric system as the single recognized system of measurement. 9 A. True B. False 0040 0009 0172002 A 12 11054 31 01500385149409 The simplification in using the metric system is that, when converting units within the system, a decimal point is moved. 9 A. True B. False 0009 0172003 B 0040 12 11056 31 14861316079509 AMU are the same as grams. 9 A. True B. False 0174001 B 13 11057 32 01611403 Which of the following represents the highest temperature? 5 o o o o 9 A. 40 F B. 40 C C. 304 K D. 492 R 0176001 A 12 11060 32 0207 09 The specific heat of a substance is expressed in calories per gram per degree centigrade. A. True 9 B. False 0176002 B 12 11062 32 0207 09 The specific heat is the number of calories required to raise the temperature of any sample of a specific compound to a specific final temperature. A. True 9 B. False 0176003 B 12 11065 32 0207 09 The specific heat of a compound changes as the mass of compound changes. A. True 9 B. False 0176004 B 12 11067 32 02070206 09 Two equal masses of different compounds at the same temperature can have the same heat content only if their specific heats are different. A. True 9 B. False 0176005 B 13 11070 32 0207 05 The specific heat of a compound is A. the amount of heat required to melt 1 g of the compound. B. The quantity of heat required to raise the temperature of 1 g one degree C. C. the quantity of heat required to increase the 9 temperature one degree C. 0176006 A 12 11074 52 02070648 09 Consider two compounds, A and B, of equal mass and at the same temperature, to each of which is added equal amounts of heat. If the specific heat of B is larger than the specific 0019 heat of A, then the final temperature of a will be higher than the final temperature of B. A. True 9 B. False 0176007 B 12 11078 52 02070648 09 Consider two compounds, A and B, of equal mass and at the same temperature, to each of which is added equal amounts of heat. If the specific heat of B is larger than the specific heat of A, then the final temperature of B will be higher than the final temperature of A. A. True 9 B. False 0176008 B 12 11082 52 02070648 09 Consider two compounds, A and B, of equal mass and at the same temperature, to each of which is added equal amounts of heat. If the final temperature of B is higher than the final temperature of A, then the specific heat of B is greater than the specific heat of A. A. True 9 B. False 0176009 A 12 11086 52 02070648 09 Consider two compounds, a and b, of equal mass and at the same temperature, to each of which is added equal amounts of heat. If the final temperature of b is higher than the final temperature of a, then the specific heat of b is smaller than the specific heat of A. A. True 9 B. False 0177001 C 13 11090 31 062203290054 Violet light and red light differ in their 9 A. speed B. nature C. frequency. 0026 0177002 A 13 11092 31 061506641340 White light can be separated into its constituent wavelengths by means of a 9 A. prism B. mirror C. vacuum. 0026 0177003 A 13 11094 31 039206161340 Of the types listed below, the electromagnetic radiation with the greatest frequency is 9 A. x_rays B. visible light C. microwaves. 0026 0177004 C 13 11096 31 033701890616 The atomic number of an element can be determined directly from its 9 A. color B. density C. x_ray spectrum. 0026 0177005 C 15 11098 32 01591340061609 Consider the following regions of the electromagnetic spectrum: 1. x_ray 2. ultraviolet 3. visible 4. infrared The energy associated with individual quanta of these regions increases in the order 9 A. 1,2,3,4 B. 3,4,2,1 C. 4,3,2,1 D. 3,1,4,2 E. 1,4,3,2 0009 0177006 B 12 11102 31 0615 09 Wavelength is defined as the distance between a crest and the succeeding trough of a wave. A. True 9 B. False 0178001 A 12 11104 31 80030161018609 04 Air has a density of 1.29 grams per liter at standard temperature and pressure. A. True 9 B. False 2WVW 0178002 A 12 11106 32 01690438018609 Generally, when a solid melts to form a liquid, the density decreases. 9 A. True B. False 0009 0178003 A 12 11108 32 01860195 09 If a cube with a density of 4 g/cc has a mass of 5 g, then its volume is 1.25 cc. A. True 9 B. False 0178004 A 12 11110 32 01860195 09 A crystal has a density of 9 g/cc and a mass of 3 g. What is its volume? 9 A. 0.33 cc's B. 3.0 cc's C. 27./ cc's 0178005 A 12 11112 32 01860195 09 If a 5 g cube has a density of 2 g/cc, then its volume is 2.5 cc's. A. True 9 B. False 0178006 B 12 11114 32 01860195 09 If a 5 g sphere has a density of 2 g/cc, then its volume is 0.4 cc's. A. True 9 B. False 0178007 B 12 11116 32 01860195 09 If a 2 g block has a density of 5 g/cc, then its volume is 10 cc's. A. True 9 B. False 0178008 B 12 11118 32 01860195 09 If a cube has a density of 5 g/cc and a mass of 4 g, then its volume is 1.25 cc's. A. True 9 B. False 0178009 A 12 11120 32 01860195 09 If a cube has a density of 6 g/cc and a mass of 8 g, then its volume is 1.33 cc's. A. True 9 B. False 0178010 B 12 11122 32 01860195 09 A piece of manganese has a density of 7.0 g/cc and a mass of 3.5 grams. It therefore will have a volume of 2.0 cc's. A. True 9 B. False 0178011 A 12 11124 32 01860195 09 If a 4 cc block has a density of 3 g/cc, then its mass is 12 g. A. True 9 B. False 0178012 B 12 11126 32 01860195 09 If a 3 cc block has a density of 3 g/cc, then its mass is 1 g. A. True 9 B. False 0178013 B 12 11128 32 01860195 09 If a 4 cc block has a density of 3 g/cc, then its mass is 1.33 g. A. True 9 B. False 0178014 B 12 11130 32 01860195 09 A 6 cc block with a density of 20 g/cc would have a mass of 1.2 g. A. True 9 B. False 0178015 A 12 11132 32 01860195 09 An 8 cc block with a density of 2 g/cc would have a mass of 16 g. A. True 9 B. False 0178016 B 12 11134 32 01860195 09 A 4 cc block with a density of 2 g/cc would have a mass of 2 g. A. True 9 B. False 0178017 B 12 11136 32 01860195 09 If a cube with a density of 3.0 g/cc has a volume of 6 cc's, then its mass is 0.5 g. A. True 9 B. False 0178018 B 12 11138 32 01860195 09 If a cube with a density of 6.0 g/cc has a volume of 3 cc's, then its mass is 2 g. A. True 9 B. False 0178019 B 12 11140 32 01860195 09 If a cube with a density of 6.0 g/cc has a volume of 3 cc's, then its mass is 2 g. A. True 9 B. False 0178020 A 12 11142 32 01860195 09 If a 4 g cube is 2.0 cc's in volume, then its density is 2.0 g/cc. A. True 9 B. False 0178021 B 12 11144 32 01860195 09 If a 12 g cube is 4.0 cc's in volume, then its density is 48.0 g/cc. A. True 9 B. False 0178022 B 12 11146 32 01860195 09 If a 3 cc block has a mass of 3 g, then its density is 3 g/cc. A. True 9 B. False 0178023 A 12 11148 32 01860195 09 If a 5 cc block has a mass of 10 g , then its density is 2 g/cc. A. True 9 B. False 0178024 B 12 11150 32 01860195 09 If a 3 cc block has density of 2 g, then its density is 6 g/cc. A. True 9 B. False 0178025 A 12 11152 32 01860195 09 If a 2 cc block has a mass of 5 g, then its density is 2.5 g/cc. A. True 9 B. False 0178026 B 12 11154 32 01860195 09 If a 1.5 cc block has a mass of 4 g, then its density is 6 g/cc. A. True 9 B. False 0190001 A 12 11156 31 00398003 Gold may be found uncombined in nature A. True 9 B. False 09 2WVW 0190002 A 12 11157 31 0027023680039004 Zinc sulfide is a white precipitate A. True 9 B. False 2WVW 0190003 B 12 11158 31 14931468019209 Extensive properties characterize, chemically identify, a substance. 9 A. True B. False 0009 0190004 A 12 11160 51 14680037018609 In trying to identify a certain liquid compound "L", a student finds that its density, freezing and boiling points, absorption spectrum, and behavior in a chromatography column are indistinguishable from those of known compound "Z". The student can safely assume L and Z are one and the same compound. 9 A. True B. False 0009 0190005 B 12 11165 31 14860028018909 About 50% of the known elements are nonmetals. 9 A. True B. False 0040 0190006 A 12 11166 31 1149 Rubbing alcohol feels cooler on the skin than does water because water has a lower vapor pressure. 9 A. True B. False 0003 0190007 A 12 11168 31 01960498 Hydrogen has a very low normal boiling point because its molecules are symmetrical and have few electrons. 9 A. True B. False 0003 0190008 A 12 11170 31 01950114 The molar volume of a liquid changes very little with changing pressure. 9 A. True B. False 0003 0190009 B 12 11172 31 0008 Water in an open thermos bottle will usually be colder than water in an open drinking glass. 9 A. True B. False 0003 0190010 B 12 11174 31 0498 When a liquid is at its boiling point, all the molecules have the same kinetic energy. 9 A. True B. False 0003 0190011 A 12 11176 51 1701 Amorphous materials ordinary become less viscous as they are heated. 9 A. True B. False 0003 0190012 A 12 11178 31 1701 Amorphous materials cannot cleave to reveal crystal faces. 9 A. True B. False 0003 0190013 B 12 11180 31 01281149 A substance with a high molecular weight will always have a lower vapor pressure than will one with a lower molecular weight, at any given temperature. 9 A. True B. False 0003 0190014 A 12 11183 31 0498 The normal boiling point of a liquid can be changed by changing the pressure. 9 A. True B. False 0003 0190015 A 0003 12 11185 31 0183 5 + A ferric oxide (Fe O ) sol may be coagulated by adding H . 4 23 9 A. True B. False 0190016 A 12 11188 31 0485 A catalyst alters the rate of a reaction without taking part in it 9 A. True B. False 0003 0190017 A 12 11190 31 0494 The frequency of collision between reacting particles is increased by increasing the temperature. 9 A. True B. False 0003 0190019 A 12 11192 31 1548 Relaxation spectroscopy is used to study reactions in which the rate of mixing of reactants is ordinarily much faster than their rate of chemical combination. 9 A. True B. False 0003 0190020 B 12 11195 31 0490 The triple_point temperature of water is slightly less than tne normal freezing point. 9 A. True B. False 0003 0190021 A 12 11197 31 0555 Whenever a pure liquid freezes, the temperature remains constant. 9 A. True B. False 0003 0190022 A 12 11199 31 0558 The lines on a phase diagram represent equilibrium between two 0003 phases. 9 A. True B. False 0190023 A 12 11201 31 04090438 When a supercooled liquid freezes, some of the potential energy of the particles is converted into kinetic energy. 9 A. True B. False 0003 0190024 A 12 11203 31 1152 Spontaneous freezing of water at _10 degrees C and constant pressure is accompanied by a decrease in free energy, if the ice formed is kept at _10 degrees C. 9 A. True B. False 0003 0190025 B 12 11206 31 0490 If heat is continuously added to solid, liquid, and gaseous water, all in equilibrium at the triple point, the solid and liquid phases will disappear simultaneously if the pressure is kept constant. 9 A. True B. False 0003 0190026 B 12 11209 31 0490 If the pressure of a sample of carbon dioxide at the triple point is increased, the phase remaining will be solid if the temperature is held constant. 9 A. True B. False 0003 0190027 A 12 11212 31 0511 If heat is added to ice at _1 degrees C, the average kinetic energy of the molecules will always increase. 9 A. True B. False 0003 0190028 B 12 11214 31 0245 The temperature at which a liquid and a gas are at equilibrium is always the same if the pressure is the same. 9 A. True B. False 0003 0190029 A 12 11216 31 0409 Supercooled water may be frozen by adding a snowflake. 9 A. True B. False 0003 0190030 A 12 11218 31 0245 If a liquid and its vapor are at equilibrium and the pressure is increased, heat is evolved. 9 A. True B. False 0003 0190031 A 12 11220 31 0491 The rates of most reactions change as the reactions proceed, even if the temperature is held constant. 9 A. True B. False 0003 0190032 A 12 11222 31 0114 Increasing the total pressure in a gas phase reaction increases the fraction of the collisions which are effective in producing reaction. 9 A. True B. False 0003 0190033 A 12 11225 31 0407 In stepwise reactions the rate_determining step is the slow one. 9 A. True B. False 0003 0190034 A 12 11227 31 04850996 An enzyme is a biochemical catalyst. 9 A. True B. False 0003 0192001 A 12 11228 31 05041153019209 Changes in physical state, like melting and boiling, tend to resolve matter into pure component substances. 9 A. True B. False 0009 0192002 B 12 11230 32 01691149016109 For all solids and liquids, vapor pressure increases linearly with temperature. 9 A. True B. False 0009 0192003 B 12 11232 31 0652 The mean free path of molecules in a liquid is greater than that of molecules in a gas. 9 A. True B. False 0192004 A 12 11234 31 0524 The statement "gases are more compressible than liquids" means that it is easier to increase the pressure of a gas than that of a liquid. 9 A. True B. False 0003 0192005 A 12 11237 31 0153 Water in an open container will eventually evaporate. 9 A. True B. False 0003 0192006 A 12 11239 31 11740195 The molar volume of liquid water at 100 degrees C is less than that of gaseous water at the same temperature. 0003 0003 9 A. True B. False 0192007 A 12 11241 31 0423 The molecules in liquid water at 100 degrees C have a lower average potential energy than the molecules in gaseous water at the same temperature. 9 A. True B. False 0003 0192008 B 12 11244 51 11490498 The vapor pressure of chloroform at its normal boiling point is greater than that of water at its normal boiling point. 9 A. True B. False 0003 0192009 A 12 11246 31 14180300 A much smaller fraction of the space occupied by a liquid is "empty" than in the case of a gas. 9 A. True B. False 0003 0192010 B 12 11248 31 1412 It takes more time to hard_boil an egg on a high mountain than at sea level because the atmospheric pressure is lower on the mountain. 9 A. True B. False 0003 0192011 A 12 11251 31 0494 Liquids diffuse much more slowly than gases, because the molecules in a liquid collide less frequently. 9 A. True B. False 0003 0192012 B 12 11253 31 0161 Molecules in a gas move at the same average speed as the molecules in a liquid if the gas and the liquid are at the same temperature. 9 A. True B. False 0003 0192013 A 12 11256 31 04331149 A barometer measures the equilibrium vapor pressure of the air. 9 A. True B. False 0003 0192014 A 12 11258 31 11490161 The vapor pressure of a liquid increases as the temperature is raised. 9 A. True B. False 0003 0192015 C 13 11260 31 050405881427 Which of the following states of matter is characterized by the most random motion of molecules? 9 A. solid B. liquid C. gas 0192016 A 13 11262 31 050405881359 Which of the following states of matter is characterized by the most highly ordered array of molecules? 9 A. solid B. liquid C. gas 0192017 C 13 11264 31 044205880504 Which state of matter is characterized by the highest intermolecular forces of attraction? 9 A. solid B. liquid C. gas 0192018 A 13 11266 31 050405881427 Which state of matter is characterized by the lowest intermolecular forces of attraction? 9 A. gas B. liquid C. solid 0192019 C 13 11268 31 050405881427 Which state of matter has the longest range intermolecular forces? 9 A. gas B. liquid C. solid 0192020 A 13 11270 31 050405880524 Which state of matter is most easily compressed into a smaller volume? 9 A. gas B. liquid C. solid 0192021 C 13 11272 31 05040588 Which state of matter has the lowest fluidity? 9 A. gas B. liquid C. solid 0192022 B 13 11274 31 050405881418 Which state of matter is characterized by portions of high molecular order which quickly disperse forming new portions of order? 9 A. gas B. liquid C. solid 0192023 A 13 11277 51 08710558 A system consists of two phases and is composed of liquid water and liquid benzene. Which of the following is true? A. Water and benzene do not mix. B. The system is a homogeneous mixture. 9 C. Benzene dissolves in water. 0192201 CCBA 43 11281 MACROITEM STEM 52 033003318001169006 ETS2 OS 2After the number on the answer sheet which corresponds to 2that of each conclusion, blacken space 2 A. if the conclusion is the best answer to the problem 2 B. if the conclusion is the least satisfactory answer to the 2 problem 2 C. if the conclusion is neither the best answer nor the least 2 satisfactory answer to the problem. (Two conclusions 0 should receive this mark). MACRO SUB_ITEM # 1 The dark lines of the solar spectrum are due to the fact that The atoms of the sun's atmosphere absorb all of the light of certain 1 definite frequencies. MACRO SUB_ITEM # 2 The relatively dark lines of the solar spectrum are due to the fact that the atoms of the heated and rarefied gases of the sun's atmosphere both absorb and emit light of certain definite 2 frequencies. MACRO SUB_ITEM # 3 The atmosphere of the sun contains sodium atoms which absorb light of certain definite frequencies and emit light of the same 3 frequencies. MACRO SUB_ITEM # 4 The atoms of the surface of the sun are incandescent and emit light which gives a continuous spectrum, while the atoms of the sun's atmosphere are not incandescent and thus absorb 9 light of certain definite frequencies. 0192202 ACACCAB 73 11296 52 1 028602939019149506 MACROITEM STEM 2The following questions refer to Figure 19. 2A piston is pushed down in a cylinder of air as shown in the 2diagram. After each item number on the answer sheet, blacken 2space 2 A. if the statement is true and the reason given is true 2 B. if the statement is true, but the reason given is false 0 C. if the statement is itself false MACRO SUB_ITEM # 1 The gas heats up, because the average kinetic energy of the 1 molecule has been increased. MACRO SUB_ITEM # 2 2 The number of molecules is increased, because the gas heats up. MACRO SUB_ITEM # 3 The gas heats up, because energy is expended in pushing down 3 on the piston. MACRO SUB_ITEM # 4 4 The molecules slow down, because they are being pushed together. ETS2 OS MACRO SUB_ITEM # 5 The cylinder cools off, because the molecules absorb heat 5 from it. MACRO SUB_ITEM # 6 The pressure increases, because the air molecules collide more 6 frequently with the walls of the cylinder. MACRO SUB_ITEM # 7 The temperature of the gas increases, because the air molecules 9 lose energy as they collide with each other. 0192203 ACCAABCB 83 11308 52 049904720114119006 MACROITEM STEM 2To answer the following questions, consider the following 2statements to apply to the kinetic theory of an ideal gas. 2Mark space 2 A. if a statement is true without qualification 2 B. if a statement is false without qualification 2 C. if a statement may be either true or false depending 0 on some further conditions MACRO SUB_ITEM # 1 When a certain gas is made denser, the molecules are then closer 1 together. MACRO SUB_ITEM # 2 2 When a gas is heated it expands. MACRO SUB_ITEM # 3 3 When a gas is heated its pressure rises. MACRO SUB_ITEM # 4 When the temperature of a gas is raised, the average speed 4 of the molecules increases. MACRO SUB_ITEM # 5 When molecular collisions are more frequent but the speeds are 5 unchanged, the pressure is greater. MACRO SUB_ITEM # 6 When molecular collisions are more frequent but the speeds are 6 unchanged, the temperature is greater. MACRO SUB_ITEM # 7 When the molecules of a gas are crowded closer together, their 7 average speed increases. MACRO SUB_ITEM # 8 When a gas is compressed adiabatically, heat is generated by 9 friction between the molecules. 0192204 C 13 11321 52 0542800103401306 Two identical leak_proof balloons a and b are filled, a with hydrogen and b with helium, so that at room temperature and pressure their volumes are equal. When they are taken together to the top of ETS OS ETS2 OS a mountain A. 1 will become appreciably bigger than 2 B. 2 will become appreciably bigger than 1 9 C. 1 and 2 will have approximately equal volumes 0192205 AACBABB 73 11326 72 030702788001119006 MACROITEM STEM 2The following questions refer to the kinetic_molecular 2theory. After each item number on the answer sheet, 2blacken space 2 A. if the item refers to observational or experimental 2 evidence which supports the theory. 2 B. if the item refers to an hypothesis or an assumption 2 concerning the theory which was formulated long 2 before there was experimental evidence to test it, 2 or has not as yet been entirely proven to be true 2 experimentally. 2 C. if the item refers to something which has nothing to 0 do with the theory. MACRO SUB_ITEM # 1 The volume of a gas increases with an increase in temperature 1 when the pressure remains constant. MACRO SUB_ITEM # 2 2 A gas always exerts pressure no matter how much it expands. MACRO SUB_ITEM # 3 3 Most gases are colorless. MACRO SUB_ITEM # 4 Gases are composed of small particles called molecules 4 which are relatively far apart and in rapid motion. MACRO SUB_ITEM # 5 5 Gases diffuse readily. MACRO SUB_ITEM # 6 6 Molecular collisions are perfectly elastic. MACRO SUB_ITEM # 7 9 Molecules on colliding lose no energy. 0192206 C 13 11339 52 0542019680011306 Two identical balloons 1 and 2 are filled, 1 with hydrogen and 2 with helium, so that at room temperature and pressure their volumes are equal. When they are taken together to the top of a mountain, assuming that there is no leakage of gas from either balloon. A. 1 will become appreciably bigger than 2 B. 2 will become appreciably bigger than 1 9 C. 1 and 2 will have approximately equal volumes ETS2 OS ETS2 OS 0192207 A 12 11345 51 03750706077109 The activity of an ideal gas is always numerically equal to its partial pressure. 9 A. True B. false. 0043 0192208 B 12 11347 51 03751404077109 The activity of a real gas is always numerically less than its partial pressure. 9 A. True B. false. 0043 0192209 B 12 11349 32 10970192018609 Two separate samples of the same gaseous substance at the same pressure would have densities in the same ratio as their absolute temperatures. 9 A. True B. False 0009 0192210 B 12 11352 32 01131392016109 The fact that a sample of gas would not have zero volume at the absolute zero of temperature is a consequence of the fact that absolute zero cannot be reached. 9 A. True B. False 0009 0192211 A 12 11355 31 14860511049909 The kinetic energy of an H molecule is lower than that of an O 4 2 2 molecule traveling at the same speed. 9 A. True B. False 0192212 A 12 11358 31 14860511016109 The average kinetic energy of molecules of different gases is the same at a given temperature. 9 A. True B. False 0040 0192213 B 12 11360 31 14860186011309 A high density is a characteristic of gases. 9 A. True B. False 0040 0192214 B 12 11361 31 01130321034809 Of all the gases in the atmosphere, nitrogen is the least reactive. 9 A. True B. False 0009 0192215 A 12 11363 31 07060128 The molecular weight of a gas may be calculated from its density at a given pressure and temperature. 9 A. True B. False 0040 0003 0192216 B 12 11365 31 1429 Gases which have low critical temperatures often show near_ideal behavior. 9 A. True B. False 0003 0192217 B 12 11367 31 1429 Gases which have high critical pressures usually have low critical temperatures. 9 A. True B. False 0003 0192218 A 12 11369 31 0258 The rate of diffusion of a gas is inversely proportional to the square root of its density. 9 A. True B. False 0003 0192219 B 12 11371 31 0706 The perfect_gas law can be used only for 1 mole of gas. 9 A. True B. False 0003 0192220 A 12 11373 31 0710 The vapor pressure of water is essentially independent of the total pressure. 9 A. True B. False 0003 0192221 A 12 11375 31 0706 The ratio of PV to T is independent of the pressure for a given quantity of ideal gas. 9 A. True B. False 0003 0192222 B 12 11377 31 0706 Equal weights of different gases contain the same number of molecules at STP. 9 A. True B. False 0003 0192223 A 12 11379 31 0511 The most probable kinetic energy of the molecules in a gas increases as the temperature is increased. 9 A. True B. False 0003 0192224 A 12 11381 31 1392 An ideal gas would have no volume at absolute zero. 9 A. True B. False 0003 0192225 B 12 11383 31 0706 At low pressures the molecules of a gas are moving more slowly than at high pressures. 0003 9 A. True B. False 0192226 A 12 11385 31 0706 All gases, except hydrogen and helium, undergo cooling when they are allowed to expand freely at room temperature. 9 A. True B. False 0003 0192227 A 12 11387 31 0511 The molecules in liquid water at 100 degrees C have a lower average kinetic energy than the molecules in gaseous water at the same temperature 9 A. True B. False 0003 0192228 A 12 11390 31 11490128 At 25 degrees C the vapor pressure of chloroform, CHCl , is 4 3 higher than that of carbon tetrachloride, CCl , because CHCl has 4 4 3 a lower molecular weight. 9 A. True B. False 0192229 A 12 11394 31 1429 When a liquid is at the critical temperature, its vapor pressure is the same as the critical pressure. 9 A. True B. False 0192230 B 13 11396 32 06540884 0540 At standard temperature and pressure, how would the volume occupied by one mole each of diatomic chlorine and monatomic xenon compare ? ( atomic numbers Cl = 17 , Xe = 54 ) A. the chlorine volume is greater than that of xenon B. the chlorine volume is equal to that of xenon 9 C. the chlorine volume is less than that of xenon 0192231 C 13 11401 32 06540884 0540 At standard temperature and pressure, how would the volume occupied by one mole each of diatomic nitrogen and monatomic neon compare? (atomic numbers N = 7, Ne = 10) A. the nitrogen volume is less than that of neon B. the nitrogen volume is greater than that of neon 9 C. the nitrogen volume is equal to that of neon 0192232 A 13 11406 32 06540884 0540 At standard temperature and pressure, how would the volume occupied by one mole each of diatomic oxygen and monatomic krypton compare ? ( atomic numbers O = 8 , Kr = 36 ) A. the oxygen volume is equal to that of krypton 0003 0003 9 B. the oxygen volume is greater than that of krypton C. the oxygen volume is less than that of krypton 0192233 B 13 11411 32 06540884 0540 At standard temperature and pressure, how would the volume occupied by one mole each of monatomic helium and monatomic xenon compare ? ( atomic numbers He = 2 , Xe = 54 ) A. the helium volume is greater than that of xenon B. the helium volume is equal to that of xenon 9 C. the helium volume is less than that of xenon 0192234 C 13 11416 32 06540884 0540 At standard temperature and pressure, how would the volume occupied by one mole each of diatomic fluorine and monatomic argon compare ? ( atomic numbers F = 9 , Ar = 18 ) A. the fluorine volume is less than that of argon B. the fluorine volume is greater than that of argon 9 C. the fluorine volume is equal to that of argon 0192401 B 12 11421 32 03930293139409 Gasoline, whose molecules have symmetrical arrangements of positive and negative charge, is an example of a nonpolar liquid. 9 A. True B. False 0041 0192402 A 12 11423 31 04980192012809 Boiling points of molecular substances usually increase with molecular weight. 9 A. True B. False 0009 0192403 A 12 11425 31 0438 In a liquid the attractive forces between the molecules are opposed by the repulsive forces between the electron clouds of neighboring molecules. 9 A. True B. False 0003 0192404 A 12 11428 31 14860174141209 Water will boil at 20 degrees C provided the atmospheric pressure is equal to the vapor pressure of the water. 9 A. True B. False 0040 0192405 B 12 11430 31 14860498011409 The normal boiling point of a liquid varies with atmospheric pressure. 9 A. True B. False 0040 0192406 B 0040 12 11432 31 14860498051109 When a liquid is at its boiling point, all the molecules have the same kinetic energy. 9 A. True B. False 0192407 B 12 11434 31 14860505043809 At a given temperature, all molecules in a liquid are moving at the same speed. 9 A. True B. False 0040 0192408 A 12 11436 31 14860791043809 Evaporation of a liquid is a physical process. 9 A. True B. False 0040 0192409 B 12 11437 31 01140113024509 The pressure exerted by a sample of gaseous benzene in equilibrium with liquid benzene will depend on the container volume. 9 A. True B. False 0009 0192410 A 12 11440 31 016110400871 Higher temperatures would favor the production of more product in the following system: benzene(l) <=====> benzene(g). 9 A. True B. False 0192411 A 12 11442 31 04980177 An ordinary table top will serve as an effective hot plate for boiling liquid air. 9 A. True B. False 0009 0003 0192412 B 12 11444 31 04980008 The boiling point of water is always 100 degrees C. 9 A. True B. False 0003 0192413 A 12 11446 31 13590438 In a liquid there may be a temporary and localized ordering of neighbors around a molecule. 9 A. True B. False 0003 0192414 AA 22 11448 32 11490498043890 MACROITEM STEM At 50 degrees C, the vapor pressure of liquid A is found to be 50 0 mm Hg; that of liquid B, 125 mm Hg. MACRO SUB_ITEM # 1 One can be reasonably sure that liquid A has the higher normal boiling point. 1 A. True B. False MACRO SUB_ITEM # 2 0009 For these same two liquids, one can state that the liquid with the higher surface tension at 50 degrees C is probably A. 9 A. True B. False 0192415 B 13 11453 51 05240438 The compressibility of liquids is A. very great because the molecules of a liquid slide easily over one another B. very small because molecules of liquid are quite close together 9 C. extremely dependent on intermolecular forces 0192416 A 12 11457 31 0122 Brownian motion is more pronounced for small particles than for large ones. 9 A. True B. False 0192601 A 12 11459 31 02448004001909 04 The geometric form of crystals is the result of the orderly arrangement of molecules, atoms, and ions. A. True 9 B. False 0192602 A 12 11461 31 06651678027409 The phenomenon of interference makes possible the use of x_ray in crystal analysis. 9 A. True B. False 0003 2WVW 0041 0192603 B 12 11463 31 05891213024409 Diamond is an example of an ionic crystal. 9 A. True B. False 0041 0192604 A 12 11464 31 02370244029309 Covalent crystals consist of arrays of separate molecules. 9 A. True B. False 0041 0192605 A 12 11466 Are all solids crystalline? 9 A. Yes B. No 31 0192606 B 12 11467 31 Some solids may evaporate. 9 A. True B. False 01691161 09 14860169015309 0192607 A 12 11468 31 0173 Metallic solids have hardnesses which vary markedly from one metal to another. 0009 0040 0003 9 A. True B. False 0192608 A 12 11470 31 0169 X_ray diffraction shows that solids generally have a very ordered structure. 9 A. True B. False 0192609 A 12 11472 31 06160612 An x_ray diffraction photograph is a picture of the inside of a crystal. 9 A. True B. False 0192610 A 12 11474 31 0169 Lattice defects are quite common. 9 A. True B. False 0192611 A 12 11475 31 15931932 09 An isomorphous substance also can be crystalline. A. True 9 B. False 0192612 A 12 11477 31 15931933 09 A polymorphous substance also can be crystalline. A. True 9 B. False 0192613 B 12 11479 31 1701 09 Substances which are crystalline also can be amorphous. A. True 9 B. False 0192614 A 12 11481 31 15931933 09 Substances which are crystalline also can be polymorphous. A. True 9 B. False 0192615 B 12 11483 31 0715 09 The unit cell is that section of a crystal which contains one formula weight of the compound A. True 9 B. False 0192616 A 12 11485 31 0715 09 The unit cell is the smallest section of a crystal which describes the structure of the crystal. A. True 0003 0003 0003 9 B. False 0192617 B 12 11487 51 0715 09 The smallest section of a crystal which describes the structure of the whole crystal is called the formula unit. A. True 9 B. False 0192618 A 12 11489 51 0715 09 In a crystal, the smallest repetitive unit which has the full symmetry of the lattice is defined as the unit cell. A. True 9 B. False 0192619 B 12 11491 31 1701 09 Amorphous solids have a regular arrangement of atoms in space. A. True 9 B. False 0192620 B 12 11493 51 01790172 09 A pure crystalline solid characteristically melts over a wide temperature range. A. True 9 B. False 0192621 A 12 11495 31 01790172 Crystalline solids have a sharp melting point. A. True 9 B. False 09 0192622 B 12 11497 31 17010172 09 Amorphous solids melt at a sharply defined temperature. A. True 9 B. False 0192623 A 12 11499 31 1701 09 Amorphous solids have little or no regular arrangement of their constituent atoms. A. True 9 B. False 0192624 A 12 11501 31 0179 09 Crystalline solids have a regular arrangement of atoms in space. A. True 9 B. False 0192625 B 12 11503 32 1892 09 In a cubic closest_packed structure, the particles of the substance are of different size in alternate layers. A. True 9 B. False 0192626 B 12 11505 32 1892 09 In a cubic closest_packed structure, the particles of the substance are spheres of unequal size. A. True 9 B. False 0192627 B 12 11507 31 0728 09 The crystal coordination number is the number of ions in a crystal. A. True 9 B. False 0192628 B 12 11509 31 0728 09 The crystal coordination number is the number of ions in a unit cell. A. True 9 B. False 0192629 A 12 11511 31 0728 09 The crystal coordination number is the number of nearest neighbors to an ion in a crystal. A. True 9 B. False 0192630 B 12 11513 31 08230825 09 The radius ratio of ions in a crystal is the ratio of the number of positive ions to negative ions in the unit cell. A. True 9 B. False 0192631 A 12 11515 31 08230325 09 The radius ratio of ions in a crystal is the ratio of the radius of the positive ion to the radius of the negative ion. A. True 9 B. False 0192632 A 12 11517 52 08230325 09 Crystals of two different binary sodium compounds have different radius ratios. Thus the negative ions in the two crystals must be different. A. True 9 B. False 0192633 B 13 11520 51 11531595 When a solid melts, A. the crystal lattice breaks down and heat is liberated in the process. B. the crystal lattice breaks down and heat is absorbed in the process. C. ordering in the crystal lattice remains the same but heat is used to increase the kinetic energy of the 9 molecules. 0193001 B 12 11525 31 00660189800409 04 Compounds are more complex than elements A. True 9 B. False 2 OS 0193002 B 12 11526 32 03500189094309 Since silicon is the second most abundant element in the earth's crust, it must be one of the cheapest to buy from a chemicals supplier. 9 A. True B. False 0009 0193003 A 12 11529 31 10970588018509 Stable, bulk samples of samples of matter carry little or no electric charge, that is, they are electrically neutral. 9 A. True B. False 0009 0193004 B 12 11531 31 14860293035109 The limit of chemical subdivision is a molecule. 9 A. True B. False 0040 0193005 B 12 11533 31 14860087041109 A solution is an example of a homogeneous pure substance. 9 A. True B. False 0040 0193006 B 12 11535 31 14860193041109 All homogeneous matter is classified as pure substance. 9 A. True B. False 0040 0193007 A 12 11537 31 14861149016109 The vapor pressures of all substances increase as the temperature is increased. 0040 9 A. True B. False 0193008 B 12 11539 31 03030189 Phlogiston is the lightest element. 9 A. True B. False 0041 0193201 A 12 11540 32 01690808011009 Sodium chloride and potassium dichromate, both solids which are soluble in water, can probably be separated by taking advantage of differences in solubility. 9 A. True B. False 0009 0193202 B 12 11543 32 15110438017409 Whenever bubbles form within a sample of liquid, the liquid is said to be boiling. 9 A. True B. False 0009 0193203 A 12 11545 31 14860087143609 Solutions can be separated into component substances by physical means. 9 A. True B. False 0040 0193204 A 12 11547 31 14860193020409 Homogeneous matter can have a variable composition. 9 A. True B. False 0040 0193205 B 12 11549 31 10971605000809 When a sample of air is allowed to warm up without changing the total water content, the relative humidity usually increases. 9 A. True B. False 0009 0193206 A 12 11552 32 0168 09 The properties of a homogeneous mixture are uniform throughout any single sample of the mixture. A. True 9 B. False 0193207 A 12 11554 32 0168 09 A mixture is a material which can be separated by physical means into the substances from which it is made. A. True 9 B. False 0193208 B 12 11556 32 0168 09 A mixture is a material which can be separated only by chemical means into the substances out of which it is made. 9 A. True B. False 0193209 B 12 11558 32 0168 09 The properties of a heterogeneous mixture are uniform throughout any single sample of the mixture. A. True 9 B. False 0193210 A 12 11560 32 0087 09 The properties of a solution are uniform throughout any single sample of the solution. A. True 9 B. False 0193401 B 12 11562 31 14860411035109 The unique simplest unit of a pure substance is an atom. 9 A. True B. False 0040 0193402 A 12 11564 31 14860293018909 Molecules of elements are always homoatomic. 9 A. True B. False 0040 0193601 A 12 11565 31 00660649000509 Compounds formed by electron transfer are called ionic compounds. 9 A. True B. False 0041 0193602 B 12 11567 31 02930005035509 Most molecules are held toghther by ionic bonds. 9 A. True B. False 0041 0193603 B 12 11569 51 14861307065309 In order for matter to be heterogeneous at least two different pure substances must be present. 9 A. True B. False 0040 0193604 A 12 11571 31 14860066035109 A compound contains only one kind of atom. 9 A. True B. False 0040 0193605 A 12 11572 31 14860066041109 A compound is an example of a pure substance. 9 A. True B. False 0040 0193606 B 12 11573 31 000800870196 Water is a solution of hydrogen and oxygen. 0041 9 A. True B. False 0193607 B 12 11574 32 0037 09 A compound is a substance which can be separated by physical means into the elements out of which it is made. A. True 9 B. False 0193608 A 12 11576 32 0037 09 A compound is a substance which can be separated by chemical means into the elements out of which it is made. A. True 9 B. False 0193609 A 12 11578 32 0037 09 A compound is composed of two or more elements combined in definite proportions. A. True 9 B. False 0193610 B 12 11580 32 0037 09 A compound is any material with two or more elements in it. A. True 9 B. False 0193611 A 12 11582 32 0037 09 The properties of a compound are uniform throughout any single sample of the compound. A. True 9 B. False 0193612 A 12 11584 32 00370168 Compounds are homogeneous mixtures. A. True 9 B. False 09 0193613 B 12 11585 31 0067 09 A binary compound is one which contains only two atoms. A. True 9 B. False 0193614 A 12 11587 31 0067 09 A binary compound is one which contains two and only two different elements. A. True 9 B. False 0193615 B 13 11589 31 0067 05 A binary compound is one which contains A. two atoms of the same element B. two and only two different elements 9 C. two ions with the same electrical charge 0193701 B 13 11592 31 06790785 The chief outlet from the nitrogen pool is, in humans, A. tissue protein being sloughed off B. proteins lost in solid wastes 9 C. urinary nitrogen. 0026 0195001 A 12 11595 31 01351418 A chemical reaction always involves molecular changes. 9 A. True B. False 0041 0195201 B 12 11597 31 04070226094309 Most chemical reactions are reversible. 9 A. True B. False 0041 0195202 A 12 11598 51 04070196035509 Reactions with hydrogen are typically slow, because the H_H bond is quite strong. 9 A. True B. false. 0043 0195203 A 12 11600 51 00150554039209 Metals which dissolve appreciable quantities of hydrogen are used for hydrogenation catalysts. 9 A. True B. false. 0043 0195204 B 12 11602 31 14990135080609 The materials which are consumed, disappear, during a chemical reaction are called products. 9 A. True B. False 0009 0195205 A 12 11604 52 09620977040709 All of the following may be reasons why the actual product yield in a reaction is usually less than 100%: separation and purification result in losses; competing reactions form other products instead; the reaction hasn't stopped yet; not all the reactants are converted to desired product, even when the reaction has ceased. 9 A. True B. False 0009 0195206 B 0009 12 11609 31 01920172000809 For any pure substance, the melting point is always a little above the freezing point. For instance, water will melt at a temperature above 0 degrees C and freeze at a temperature a little below 0 degrees C. 9 A. True B. False 0195207 A 12 11613 32 14860087041109 Some pure substances may be decomposed into simpler pure substances by chemical change. 9 A. True B. False 0040 0195208 B 12 11615 31 14860588035109 An atom is the smallest unit possible from physical subdivision of matter. 9 A. True B. False 0040 0195401 A 12 11617 31 03510293169709 At any instant, all atoms and molecules have asymmetric charge distributions. 9 A. True B. False 0041 0195402 A 12 11619 31 14140513117809 The following statement is probably consistent with modern atomic theory: A positively charged sodium ion is smaller than a neutral sodium atom. 9 A. True B. False 0009 0195403 B 12 11622 31 14861402034109 The chemical properties of elements are very dependent on the number of nuclear neutrons. 9 A. True B. False 0040 0196201 B 12 11624 32 04700189026409 One difference between an element and a compound is that compounds do not always follow the law of conservation of matter and energy while elements do. A. True 9 B. False 0196202 B 12 11627 32 0264 09 The law of conservation of matter and energy is generally, but not always, followed. A. True 9 B. False 0196203 B 12 11629 32 02640470 09 The burning of a candle is one of those rare exceptions to the law of conservation of matter and energy. A. True 9 B. False 0196204 A 12 11631 32 02640470 09 During a chemical reaction, matter and energy are always conserved. A. True 9 B. False 0196205 B 12 11633 32 02640470 09 Nuclear explosions which directly convert matter into energy are examples of exceptions to the law of conservation of matter and energy. A. True 9 B. False 0196206 B 12 11636 32 02640470 09 An exothermic reaction loses heat to its surroundings. This is a violation of the law of conservation of matter and energy. A. True 9 B. False 0196207 B 12 11639 32 02640470013509 Some energy is always destroyed when a chemical reaction occurs. A. True 9 B. False 0196208 A 12 11641 32 0470 09 The law of conservation of energy implies that energy is not destroyed during a chemical reaction. A. True 9 B. False 0196209 B 12 11643 32 0470 09 The law of conservation of energy states that matter cannot be converted into energy. A. True 9 B. False 0196210 A 12 11645 32 0364 09 Matter and energy can be considered interrelated because one can be converted into the other. 9 A. True B. False 0196211 A 12 11647 32 0364 09 The amount of energy into which matter can be converted is 5 2 governed by the equation E = mc . A. True 9 B. False 0196212 B 12 11650 32 04700264 09 The law of conservation of matter and energy states that matter can be created but not destroyed. A. True 9 B. False 0196213 B 12 11652 32 0264 09 An exception to the law of conservation of matter and energy occurs in the explosion of a hydrogen bomb. A. True 9 B. False 0196401 A 12 11654 31 02950345149609 In the light of current knowledge, we must view the law of constant composition as only a good approximation to observed behavior. 9 A. True B. False 0009 0196402 B 12 11657 31 14860513026509 The law of definite composition is an exception to the atomic theory. 9 A. True B. False 0040 0198001 A 12 11659 31 80040089008709 04 When molecules of an electrolyte are broken up in solution into their constituent radicals, each is charged, and these are called ions A. True 9 B. False 2WVW 0198002 A 12 11662 31 07310351015909 The ionization energy of an atom is the energy needed to remove its outermost electron. 9 A. True B. False 0041 0199001 A 2WVW 12 11664 31 02938004800309 04 Molecules are always in motion. A. True 9 B. False 0200001 ABABBBBA 83 11665 52 035103428001119006 MACROITEM STEM 2Evaluate the statements according to the key. 2 A. The statement is true. 2 B. The statement is false. 0 C. The statement is neither true nor false in all cases. MACRO SUB_ITEM # 1 1 All atoms must have at least one electron in the nucleus. MACRO SUB_ITEM # 2 2 All atoms must have at least one neutron in the nucleus. MACRO SUB_ITEM # 3 3 Nuclei of all atoms carry a positive charge. MACRO SUB_ITEM # 4 4 All nuclei contain more neutrons than protons. MACRO SUB_ITEM # 5 The isotopes of uranium cannot be separated by means of chemical 5 processes. MACRO SUB_ITEM # 6 When an atom disintegrates all of its mass is accounted for 6 in the particles and lighter atoms that are released. MACRO SUB_ITEM # 7 In the disintegration of uranium, the barium atoms are the 7 product that continues the chain reaction. MACRO SUB_ITEM # 8 Chemically speaking all but the nucleus of an atom can be 9 disregarded. 0200002 A 12 11675 51 0438 The x_ray diffraction pattern produced by a liquid shows a series of concentric rings. 9 A. True B. False 0210001 BAAAABAAC93 11677 31 027602638001119006 ETS2WVW MACROITEM STEM 2To answer the following questions, use the key below 2 A. a scientific fact well supported by evidence. 2 B. A highly probable theory. 0 C. A mere guess. MACRO SUB_ITEM # 1 An electron revolving around a positive nucleus is subjected to a centrifugal force equal and opposite to ETS2 OS 0003 1 the electrostatic force attracting it by the nucleus. MACRO SUB_ITEM # 2 The atom for the most part is made up of a nucleus of protons and neutrons with the same number of electrons revolving around the nucleus as protons contained 2 in the nucleus. MACRO SUB_ITEM # 3 A useful element has been formed by merely projecting 3 a neutron into the nucleus of an atom. MACRO SUB_ITEM # 4 Researchers have been able to form many isotopes 4 that have never been discovered as natural particles. MACRO SUB_ITEM # 5 The electron is considered by scientists as the 5 smallest particle of matter. MACRO SUB_ITEM # 6 The atom is a tiny solar system with a nucleus of positive charges of electricity at its center and electrons 6 revolving around it. MACRO SUB_ITEM # 7 Robert Millikan discovered the value of the electrical 7 charge carried by the electron. MACRO SUB_ITEM # 8 8 The atom has locked in its nucleus a tremendous amount of energy. MACRO SUB_ITEM # 9 9 A fuel in all the larger electrical power plants. 0210002 B 12 11692 31 16830495034109 A nucleon is a composite particle consisting of a neutron and a proton. 9 A. True B. False 0041 0210003 A 12 11694 31 00970341026309 The proton, neutron, and electron are stable particles that do not decay in free space. 9 A. True B. False 0041 0210004 B 12 11696 51 07970097146609 The old name for proton is positron. 9 A. True B. False 0041 0210005 B 12 11697 51 03411686168709 The antiparticle of the neutron is the neutrino. 9 A. True B. False 0041 0210006 B 0041 12 11699 51 16860343000909 Neutrinos are readily absorbed by lead and iron. 9 A. True B. False 0210007 B 12 11701 51 16880449 09 The distinction between mesons and hyperons is that mesons are unstable while hyperons are stable. 9 A. True B. False 0041 0210008 A 12 11703 31 00971486044509 Neutrons and protons weigh approximately the same. 9 A. True B. False 0040 0210009 A 12 11705 31 03421486018509 All nuclei are positively charged. 9 A. True B. False 0040 0210010 A 12 11706 31 14860445026309 The weight of 2000 electrons is less than that of 2000 protons. 9 A. True B. False 0040 0210011 A 12 11708 32 15711285035809 The extent of deflection in an electrostatic field is greater for a beta_particle than for an alpha_particle. 9 A. True B. False 0009 0210012 A 12 11710 31 05131486 Goldstein's experiments with discharge tubes proved that atoms contain positrons as well as electrons. 9 A. True B. False 0003 0210013 A 12 11712 31 03571486 Rutherford's experiments showed that the nucleus of an atom is extremely small. 9 A. True B. False 0003 0210014 B 12 11714 31 00701486 In the process of losing an electron from its outer shell, a neutral (uncharged) atom acquires a negative charge. 9 A. True B. False 0003 0210015 A 12 11716 31 026314860097 The mass_to_charge ratio of an electron is lower than that of a proton. 9 A. True B. False 0210016 B 12 11718 31 03851486 0003 0003 The positive particles formed in a Goldstein discharge tube are all alpha particles. 9 A. True B. False 0211001 B 14 11720 31 02630027800111 06 When electrons are emitted from a clean zinc plate illuminated by ultra_violet light the kinetic energy of an emitted electron is A. directly proportional to the intensity of the illumination B. dependent only on the frequency of the incident light C. independent of the frequency of the incident light D. directly proportional to the absolute temperature of 9 metal 0211002 A 12 11726 51 02760263168909 The theory of the electron was developed by Dirac. 9 A. True B. False 0211003 B 12 11728 32 02630097 09 In relation to the proton, the electron is about the same mass and of opposite charge. A. True 9 B. False 0211004 A 12 11730 31 02630097 09 In relation to the proton, the electron is many times lighter and of opposite charge. A. True 9 B. False 0211005 B 12 11732 31 02630097 09 In relation to the proton, the electron is many times heavier and of opposite charge. A. True 9 B. False 0211006 B 12 11734 31 02630341 09 In relation to the electron, the neutron is many times heavier and of opposite charge. A. True 9 B. False 0211007 B 12 11736 31 02630341 09 In relation to the electron, the neutron is many times lighter and negative in charge. A. True ETS2WVW 0041 9 B. False 0211008 B 12 11738 31 00970341 09 In relation to the proton, the neutron is many times heavier and negative in charge. A. True 9 B. False 0211009 A 12 11740 31 03410097 09 In relation to the neutron, the proton is about the same mass and positively charged. A. True 9 B. False 0211010 A 12 11742 31 02630097 09 The charges on the electron and proton are equal but opposite in sign. A. True 9 B. False 0211011 B 12 11744 31 00970341 09 The charges on the proton and neutron are equal but opposite in sign. A. True 9 B. False 0211013 B 12 11746 31 02630341 09 The charges on the electron and neutron are not equal but they have the same electrical sign. A. True 9 B. False 0211101 A 13 11748 31 05900571 Whether or not a given beam of radiation can eject electrons from a metal surface is determined solely by 9 A. its frequency B. its intensity C. its speed. 0026 0211102 A 12 11751 31 057103280263 The photoelectric effect is the emission of electrons when light is shined on a metal surface. 9 A. True B. False 0041 0213001 A 12 11753 31 03370189034209 The atomic number of an element is equal to the number of protons in its nucleus. 9 A. True B. False 0041 0213002 B 12 11755 31 03420351009709 The nuclei of all hydrogen atoms consist of single protons. 9 A. True B. False 0041 0213003 A 12 11757 All atoms contain protons. 9 A. True B. False 0040 31 14860097035109 0213004 B 12 11758 32 00970341 09 The number of protons in an atom is always equal to the number of neutrons. A. True 9 B. False 0213005 A 12 11760 32 00970263 09 The number of protons in a atom is always equal to the number of electrons. A. True 9 B. False 0215001 B 12 11762 31 03410353009709 The neutron is an isotope of the proton. 9 A. True B. False 0215002 B 12 11763 51 06200341 09 The half_life of the free neutron is 1,600 years. 9 A. True B. False 0041 0041 0215003 B 12 11765 32 03410263 09 The number of neutrons in a atom is always equal to the number of electrons. A. True 9 B. False 0215004 B 12 11767 32 00970263034109 All atoms of the same element must contain the same number of protons, neutrons, and electrons. A. True 9 B. False 0220001 A 13 11769 31 14020351018509 The chemical properties of an atom are determined by its nuclear charge. 9 A. True B. False 0009 0220002 A 0009 12 11771 31 03510189026309 All neutral atoms of a given element have the same number of electrons. 9 A. True B. False 0220003 A 12 11773 31 01950351026309 The volume of an atom is essentially that volume occupied by the electrons. 9 A. True B. False 0009 0220004 B 12 11775 31 01850351034209 All the electrical charge in an atom is confined to the nucleus. 9 A. True B. False 0009 0220005 B 12 11777 31 03371291026309 The atomic number is always equal to the number of electrons in a particular atom. 9 A. True B. False 0009 0220006 B 12 11779 31 08230185117809 The radius of a negatively charged monatomic ion is always smaller than the radius of the parent neutral atom. 9 A. True B. False 0009 0220007 B 12 11781 31 03420351148609 The nucleus occupies about 1/2 the volume of an atom. 9 A. True B. False 0040 0221001 B 12 11783 51 03640606154009 Einstein discovered that the line spectrum of an element contains specific wavelengths which are characteristic of the element alone. 9 A. True B. False 0041 0221002 B 12 11786 51 13450351 09 The Bohr theory of the atom is now known to be correct in all respects. 9 A. True B. False 0041 0221003 A 12 11788 51 0351026309 According to the Bohr model of the atom, atoms emit light when their electrons jump from outer to inner orbits. 9 A. True B. False 0041 0221004 B 12 11790 51 02630351134009 Electrons moving in circular paths outside of atoms emit electromagnetic radiation continuously. 0041 9 A. True B. False 0221005 A 13 11792 31 033001961345 The Bohr theory of the hydrogen atom A. successfully predicts its spectrum B. proves that light is a form of radiant energy 9 C. contradicts planck's quantum hypothesis. 0026 0221006 A 12 11795 31 06541486018509 Cathode rays possess a negative charge. 9 A. True B. False 0040 0221007 A 12 11796 32 0189 09 An atom and an ion which contain the same number of protons but which have different masses are both of the same element. A. True 9 B. False 0221008 A 12 11799 32 0189 09 Two atoms or ions with the same number of protons and the same mass are both of the same element. A. True 9 B. False 0221009 A 12 11801 32 0189 09 Two neutral atoms which contain the same number of electrons and which have the same mass are both atoms of the same element. A. True 9 B. False 0221010 B 12 11804 32 0189 09 Two atoms or ions with the same number of neutrons and the same mass must both be of the same element. A. True 9 B. False 0221011 B 12 11806 32 0189 09 Two isotopes of the same element differ in the number of protons their atoms contain. A. True 9 B. False 0221012 A 12 11808 32 0189 09 Two isotopes of the same element differ in the number of neutrons their atoms contain. A. True 9 B. False 0221013 B 12 11810 32 0342 09 The nucleus of an atom is composed of protons and electrons. A. True 9 B. False 0221014 B 12 11812 32 1110 09 Almost all the mass of an atom is contained in its protons and electrons. A. True 9 B. False 0221015 B 12 11814 32 1110 09 Almost all the mass of an atom is contained in its protons. A. True 9 B. False 0221016 A 12 11816 32 1110 09 Almost all the mass of an atom is contained in its protons and neutrons. A. True 9 B. False 0221017 A 12 11818 32 0342 09 The nucleus of an atom is composed of neutrons and protons. A. True 9 B. False 0230001 B 12 11820 31 03510445035109 All atoms have weights which are exactly integral multiples of the weight of the hydrogen atom. 9 A. True B. False 0230002 B 13 11822 31 5 235 In the symbol U , 235 means 4 92 A. the mass defect B. the isotope mass 9 C. the atomic number. 03531461 0230003 B 12 11824 31 00651413035309 The atomic weight is an average number that takes into account all known isotopes of an element, including those prepared 0041 0026 0009 artificially in the laboratory. 9 A. True B. False 0230004 A 12 11827 32 1110 09 The mass number of an element is determined by the number of protons and neutrons. A. True 9 B. False 0230005 B 12 11829 32 1110 09 The mass number of an element is determined by the number of protons and electrons. A. True 9 B. False 0230006 A 12 11831 32 1313 09 All atomic weights are based ultimately on carbon_12 having a weight of exactly 12.0000. A. True 9 B. False 0230007 B 12 11833 32 1313 09 All atomic weights are based ultimately on oxygen_16 having a weight of exactly 16.0000. A. True 9 B. False 0230008 A 12 11835 32 0065 09 An element with a higher atomic number than carbon will always have a greater number of protons in its nucleus than carbon does. A. True 9 B. False 0230009 A 12 11838 32 0065 09 An element with a lower atomic number than carbon will always have a lower number of protons in its nucleus than carbon does. A. True 9 B. False 0230010 B 12 11841 32 00650337 09 If atom X has a greater mass than atom Y, then its atomic number is surely greater also. A. True 9 B. False 0230011 A 12 11843 32 00650337 09 If element X has a greater number of protons in its nucleus than element Y, then its atomic number is surely greater also. A. True 9 B. False 0230012 B 12 11846 32 03370263 09 If an atom and an ion have the same number of electrons, then they are of the same element. A. True 9 B. False 0231001 A 12 11848 31 03530189009709 The isotopes of an element have the same number of protons in the nuclei of their atoms but different numbers of neutrons. 9 A. True B. False 0041 0231002 A 12 11850 31 07880847035309 Deuterium and tritium are isotopes of hydrogen. 9 A. True B. False 0041 0231003 B 12 11852 32 02930008 09 A molecule of deuterium oxide weighs twice as much as a molecule of ordinary H O. 4 2 9 A. True B. False 0043 0231004 B 12 11854 31 03531055033709 An isotope is one of two or more atomic species having the same atomic number but different numbers of electrons. 9 A. True B. False 0009 0231005 A 12 11856 31 03371486035309 Isotopes of an element have the same atomic number. 9 A. True B. False 0040 0231006 B 12 11858 31 14860353034109 Two isotopes can contain the same number of neutrons. 9 A. True B. False 0040 0231007 A 12 11860 31 03531486 Different isotopes of an element always have different numbers of neutrons in their nuclei. 9 A. True B. False 0003 0231008 A 12 11862 31 01891486 Atoms of a given element always have the same number of protons. 9 A. True B. False 0231009 A 12 11864 31 06601486 An atom can raise its neutron_proton ratio by ejecting a positron 9 A. True B. False 0003 0231010 A 12 11866 31 06541486 Cathode rays are streams of electrons. 9 A. True B. False 0003 0231011 B 12 11867 31 12021486 When exposed to a magnetic field, gamma rays exhibit no appreciable deflection. 9 A. True B. False 0003 0231012 B 12 11869 51 120906621070 Carbon 14 may be detected because of its distinctive color. 9 A. True B. False 0041 0231013 B 12 11871 32 03530263 09 Neutral atoms of isotopes of the same element differ in the number of electrons they contain. A. True 9 B. False 0231014 C 13 11873 32 0353 05 To change one atom into another nuclide of the same element, add or subtract 9 A. electrons B. protons C. neutrons 0231015 B 13 11875 32 0353 05 For two atoms or ions of the same mass to be the same element, they must contain the same number of 9 A. electrons B. protons C. neutrons 0231016 B 12 11878 32 01890353 09 Atoms of two different elements with the same number of neutrons are isotopes. A. True 9 B. False 0233001 B 12 11880 31 14520189148609 All of the 105 elements known today occur in nature. 9 A. True B. False 0040 0233002 B 12 11882 31 14860415018909 The known elements do not occur in exactly equal abundance but 3 _______ their abundances are very close to being equal. 9 A. True B. False 0040 0233003 B 12 11885 31 03531486041509 All of the elements occur in nature in two isotopic forms. 9 A. True B. False 0040 0233004 A 12 11887 31 14860415018909 More than 90% of the earth's crust, water, and atmosphere is composed of only ten elements. 9 A. True B. False 0040 0233005 B 12 11889 31 019603210189 There is little hydrogen in the earth's atmosphere because this element is rare everywhere in the universe. 9 A. True B. False 0041 0250001 A 13 11891 31 03370189800111 06 The atomic number of an element is numerically equal to A. the number of protons in the nucleus of the atom B. the number of neutrons in the nucleus of the atom 9 C. the whole number nearest to its atomic weight 0250002 A 12 11894 31 14020189168409 The chemical properties of an element are determined almost wholly by the electron clouds of its atoms. 9 A. True B. False 0250003 A 12 11896 31 07771486 The largest number of electrons which can populate an isolated atom's valence shell is eight. 9 A. True B. False 0250004 A 12 11898 32 01890097033709 The atomic number of an element is determined by the number of protons in its atoms. A. True 9 B. False 0250005 B 12 11900 32 01890097033709 The atomic number of an element is determined by the number of neutrons in its atoms. ETS2WVW 0041 0003 9 A. True B. False 0250006 B 12 11902 32 00370097026309 The atomic number of an element is determined by the total number of protons plus neutrons in an atom of the element. A. True 9 B. False 0251001 A 12 11904 52 11781423 09 The manganous ion contains five unpaired 3d electrons. 9 A. True B. False 0043 0251002 A 12 11906 51 07681178 The mercurous ion is not paramagnetic. 9 A. True B. False 0043 09 0251003 B 12 11907 51 0016 033809 5 3+ 3+ Al and Cr have similar electronic configurations in their outermost shells. 9 A. True B. False 0251004 A 12 11909 31 14860338035409 The electronic configuration of argon (Ar) is 5 2 2 6 2 6 1s 2s 2p 3s 3p 9 A. True B. False 0043 0040 0251005 A 12 11911 32 07771486 The ground_state electronic population of a sodium (Z = 11) ion is 5 2 2 6 1s 2s 2p 9 A. True B. False 0003 0251006 A 12 11913 31 11281486 The ground_state electronic configuration of a potassium (Z=19) ion is the same as that of a calcium (Z = 20) ion. 9 A. True B. False 0003 0251007 A 12 11915 31 09291486 The ground state of an atom is the one in which all electrons are in the lowest energy levels available to them. 9 A. True B. False 0003 0251008 C 13 11917 32 0189 05 An atom and an ion of the same element differ only in the number of 9 A. protons B. neutrons C. electrons 0251009 B 12 11919 32 01890353 09 Atoms of two different elements with the same mass number are isotopes. A. True 9 B. False 0251010 A 12 11921 32 01890263 09 A positive ion of a certain element can be formed by removal of an electron from an atom of that element. A. True 9 B. False 0251011 B 12 11923 32 01891178 09 5 + The number of electrons in an ion such as K is greater than the number of protons. A. True 9 B. False 0251012 B 12 11926 32 01891178 09 A negative ion of a certain element can be formed by removal of a proton from an atom of that element. A. True 9 B. False 0251013 B 12 11928 32 01891178 09 A negative ion of a certain element can be formed by removal of an electron from an atom of that element. A. True 9 B. False 0251014 B 12 11930 32 01891178 09 A positive ion of a certain element can be formed by addition of a proton to the nucleus of that element. A. True 9 B. False 0251015 A 12 11932 32 01891178 09 A negative ion of a certain element can be formed by addition of an electron to an atom of that element. A. True 9 B. False 0253001 B 12 11934 51 1540 09 Emission spectra consist of bright lines on a dark background. 9 A. True B. False 0041 0253002 A 12 11936 51 03510054032909 Atoms emit and absorb light of the same frequencies. 9 A. True B. False 0041 0253003 B 12 11938 51 03510907042909 An atom in an excited state has a high velocity. 9 A. True B. False 0041 0253004 A 12 11940 51 13620159 09 The 4d and 5s subshells are very close in energy. 9 A. True B. False 0043 0253005 A 13 11942 31 03800909 When an electron in a hydrogen atom undergoes a change in its principal quantum number from 3 to 8, its energy is 9 A. increased B. decreased C. unchanged. 0026 0253006 A 12 11945 31 01590263090909 The energy associated with an electron in a given atom is almost fully described by specifying its value of the quantum number n. 9 A. True B. False 0009 0253007 A 12 11948 31 14861362034709 A subshell is a collection of orbitals that have the same energy. 9 A. True B. False 0040 0253008 A 12 11950 31 14861362015909 Electrons in the 3d subshell would have more energy than those in the 3p subshell. 9 A. True B. False 0040 0270001 B 12 11952 51 05720351039209 The quantum_mechanical theory of the atom restricts itself to physical quantities that can be measured. 9 A. True B. False 0041 0270002 A 12 11954 51 16930351 09 Quantum mechanics is an extension of Newtonian mechanics to the atom. 0041 9 A. True B. False 0270003 B 12 11956 51 16930270026309 Because quantum mechanics does not make definite predictions about the position and velocity of each electron in an atom, its correctness cannot be verified by experiment. 9 A. True B. False 0041 0270004 B 13 11959 31 019603300572 The hydrogen atomic spectrum requires that the hydrogen atom gain or lose energy A. only in a vacuum tube B. in discrete amounts 9 C. as required by its environment. 0026 0270005 A 13 11962 31 06120628 A characteristic feature of waves is 9 A. diffraction B. internal friction C. typical mass 0026 0270006 B 12 11964 52 05720067060609 Without quantum theory, there probably would be no way of predicting the properties of element 110, yet to be discovered. 9 A. True B. False 0009 0273001 A 13 11966 31 146914700572 The Heisenberg uncertainty principle is based upon the fact that A. photons of high energy can disturb small pieces of matter B. the present state of precision of measuring atomic positions can be refined to an unlimited extent 9 C. actual experimental work always contains slight errors. 0026 0273002 A 12 11970 31 14860909147009 The larger the number (n) of a shell, the greater is the distance between the nucleus and the most probable position of a contained electron. 9 A. True B. False 0040 0273003 A 12 11973 31 1211 0417 It is impossible simultaneously to determine the position and velocity of an electron. 9 A. True B. False 0275001 B 12 11975 51 03470914150509 An orbital diagram is a geometrical representation of the shape of an orbital. 9 A. True B. False 0041 0009 0275002 B 12 11977 31 14860347136209 An orbital is a collection of subshells. 9 A. True B. False 0040 0275003 A 12 11978 31 14860347038009 An orbital has a definite size and shape which are related to the energy of the electrons it could contain. 9 A. True B. False 0040 0275004 A 12 11980 31 14861362034709 A 2p and a 3p subshell contain the same number of orbitals. 9 A. True B. False 0040 0275005 B 12 11982 31 14860915091409 An s orbital is shaped something like a four leaf clover. 9 A. True B. False 0040 0275006 B 12 11984 51 14860347136209 The maximum number of electrons possible in a d orbital is 10. 9 A. True B. False 0040 0275007 A 12 11986 31 11281486 If two electrons in an atom have the same spin and are both in p orbitals oriented in the same direction in space, they must be in different shells. 9 A. True B. False 0003 0275008 B 12 11989 31 05861486 Each electron in an atom revolves in an orbit around the nucleus, according to present_day theory. 9 A. True B. False 0003 0277001 A 12 11991 51 0909 026309 Four quantum numbers are required to characterize each electron in a complex atom. 9 A. True B. False 0041 0277002 B 12 11993 51 16920263058609 Electron spin refers to the motion of electrons in their orbits. 9 A. True B. False 0041 0277003 A 12 11995 51 02630909035109 No more than one electron in an atom can have the same set of quantum numbers. 9 A. True B. False 0041 0277004 A 12 11997 51 05301497026309 Both the direction and the magnitude of the angular momentum of an atomic electron are quantized. 9 A. True B. False 0041 0277005 B 12 11999 31 14860909026309 The maximum number of electrons in a shell with N = 3 is 10. 9 A. True B. False 0040 0279001 B 12 12001 31 11280244019509 The exclusion principle explains why crystals do not collapse into smaller volumes. 9 A. True B. False 0041 0279002 A 12 12003 31 14860347026309 The maximum number of electrons an orbital may contain does not vary with the type of orbital. 9 A. True B. False 0040 0290001 CABCCBCC 83 12005 31 1 057390159016959006 MACROITEM STEM 2The following questions refer to Figures 15 and 16. 2all atoms are made from the same three pieces in Figure 15. Every 2tiny atom is like a solar system. Its central "sun" has one or 2more protons, generally neutrons, too. The revolving "planets" 2are the electrons, one for each proton in the nucleus, because 2plus and minus must balance in the atom. 2The opposite charges attract but high speed keeps the electrons 2in their circular paths. All the weight of the atom may be 2considered to be in the nucleus since the electron weighs only 21/1850 of the proton. 2The atom is mostly empty space. If the nucleus were enlarged 2to the size of a baseball, the electron would be a mere speck 22000 feet away. Electrons supply the energy for chemical reactions 2like burning coal or the explosion of tnt. The nucleus 2evades all ordinary chemical reactons. Its energy can be 2released only by direct hits on the nucleus to break the bonds 2that hold the protons and neutrons in a tight bundle. 2Uranium is nature's heaviest atom called U_238. It is not 2directly usable for energy release, but an element may have 2several isotopes__alternate forms with the same number of 2protons but slightly different numbers of neutrons. The material 2needed for direct atomic energy release is U_235 which consists 2of only .7 per cent of natural uranium. The separation of the 2uranium isotopes is difficult since they are chemically the same ETS2WVW 2element. 2Relatively slow neutron bullets can split U_235 into lighter 2atoms and give several neutrons to split other U_235 atoms 2setting up a chain of explosions that may sweep through a block 2of U_235 releasing energy equivalent to 11,400,000 kilowatt_hours 2per pound. 2We now have a man_made new element, number 94 with 145 2neutrons, called plutonium which can also be split like u_235. 2in an elementary way the principle of atomic explosion can 2be shown by Figure 16. 2To answer the following questions, select from the key the 2most appropriate response. 2 A. The first part of the statement is true, and its truth 2 is supported by the reason given in the statement. 2 B. The first part of the statement is true, but its truth is 2 not supported by the reason given in the statement. 0 C. The first part of the statement is false. MACRO SUB_ITEM # 1 The atoms of all elements are neutral because the neutron 1 has no electrical charge. MACRO SUB_ITEM # 2 Splitting uranium into other elements produces elements of slightly different atomic weights because some neutrons 2 are given off in the action. MACRO SUB_ITEM # 3 3 Plutonium is listed as element 94 because it has 94 electrons. MACRO SUB_ITEM # 4 U_238 has the same atomic weight as U_234 because 4 U_234 is an isotope of U_238. MACRO SUB_ITEM # 5 electrons have no electrical attraction for the nucleus 5 because atoms are neutral in charge. MACRO SUB_ITEM # 6 Plutonium is heavier than U_238 as evidenced by its 6 greater atomic weight. MACRO SUB_ITEM # 7 The chance of a direct hit on the nucleus by an electron 7 bullet is good because the atom is mostly empty space. MACRO SUB_ITEM # 8 Centripetal force keeps electrons in their orbits because 9 electrons travel at high speed around the nucleus. 0290002 ABBBBBAAB92 12045 31 063106388001909004 ETS2WVW MACROITEM STEM 2The items to which you will respond have been 2selected from various sources. Mark space 2 A. if you believe that a statement is a scientific fact 2 B. if you believe a statement is an opinion 2For example statement of fact 1. growth is a characteristic of 3 _________ __ ____ 2cancer tissue. 2Statement of opinion 2. the cause of cancer will never be 3_________ __ _______ 0 discovered. MACRO SUB_ITEM # 1 1 Uranium_235 has less mass than U_238. MACRO SUB_ITEM # 2 The search for uranium in the united states 2 will result in an adequate supply of the ore. MACRO SUB_ITEM # 3 The atomic bomb does not make all methods 3 of warfare obsolete. MACRO SUB_ITEM # 4 An atomic bomb raid is no more damaging than a saturation bombing with fire bombs or block 4 busters. MACRO SUB_ITEM # 5 The hydrogen bomb is the most potent 5 weapon of war that science will ever produce. MACRO SUB_ITEM # 6 Sonar and radar diminish the effectiveness of 6 large navies. MACRO SUB_ITEM # 7 There are safety measures to be taken against 7 the atomic bomb. MACRO SUB_ITEM # 8 8 Uranium is a source of power. MACRO SUB_ITEM # 9 9 Radioactivity is the least of the atomic bomb's threats. 0290003 BBAACACAA93 12058 31 063102788001119006 ETS2WVW MACROITEM STEM 2To answer the following questions, use the key below 2 A. The statement is a fact. 2 B. The statement is an hypothesis. 0 C. The statement is a mere guess. MACRO SUB_ITEM # 1 If fission occurs in any heavy element, a chain 1 reaction will result. MACRO SUB_ITEM # 2 The scientist knew that if hahn had produced barium by neutron bombardment of uranium that he 2 had split the atom. MACRO SUB_ITEM # 3 Slow neutrons will cause fission of U_235 but not 3 of the other U_238. MACRO SUB_ITEM # 4 The capsule of beryllium at The center of a plutonium bomb (Greenglass version) furnishes additional 4 neutrons to those caused by the fission of the plutonium. MACRO SUB_ITEM # 5 The "tamper" (the force that holds the bomb together until a chain reaction is well under way) is an auxiliary explosion directed from all directions toward 5 the center of the bomb. MACRO SUB_ITEM # 6 The atomic bomb has the shape of a cigar but it 6 weighs thousands of pounds. MACRO SUB_ITEM # 7 The H bomb weighs less than the atomic bomb 7 but it is thousands of times more powerful. MACRO SUB_ITEM # 8 From theoretical considerations the H bomb should 8 be many times as powerful as an a bomb. MACRO SUB_ITEM # 9 9 Amount of energy. 0290005 C 13 12072 31 0661 The term that best describes the device which accelerates nuclear particles in a straight line until they have very high energies is 9 A. cyclotron B. atom_smasher C. linear accelerator. 0026 0290006 B 12 12075 31 0661 09 No useful applications (besides weapons) have been made using nuclear reactions. 9 A. True B. False 0290007 B 12 12077 31 0518 09 Nuclear fusion is now used to produce electicity. 9 A. True B. False 0040 0290008 B 12 12079 31 0353 09 Radioactive isotopes find little use in medicine. 9 A. True B. False 0040 0290009 B 12 12081 51 03180590133109 0040 0009 The most serious effect of low level radiation on the body is that it produces severe skin burns. 9 A. True B. False 0291001 A 12 12083 51 0342037909 The beta decay of a radioactive nucleus corresponds to the conversion of one of its neutrons into a proton and an electron. 9 A. True B. False 0041 0291002 A 12 12085 51 12020627032909 Gamma rays are electromagnetic waves of very high frequency. 9 A. True B. False 0041 0291003 A 12 12087 51 13470358037909 Luminous watch and clock dials glow because the alpha particles emitted by radioactive materials radiate light. 9 A. True B. False 0041 0291004 B 12 12089 51 03580379019209 The alpha particles emitted by radioactive substances form the gas radon. 9 A. True B. False 0041 0291005 A 12 12091 52 06200351037909 After a time span equal to three half_lives, seven_eighths of the original number of atoms of a radioactive substance will have decayed. 9 A. True B. False 0041 0291006 A 12 12094 51 03791202033709 When a radioactive element emits a gamma ray, its atomic number changes. 9 A. True B. False 0041 0291007 B 12 12096 51 03791499049109 Heating a radioactive material increases its rate of decay. 9 A. True B. False 0041 0291008 A 12 12098 31 03211209 09 The carbon_14 involved in dating is produced by naturally occurring reactions in the upper atmosphere. 9 A. True B. False 0040 0291009 B 12 12100 31 03580660 09 In radioactive decay involving alpha emission, the atomic number of the reacting isotope increases. 0040 9 A. True B. False 0291010 B 12 12102 32 1209 09 514 C (t = 5000 years) could conveniently be used to date a 46 1/2 1.5 million_year_old artifact. 9 A. True B. False 0040 0291011 B 12 12104 31 06171486 As atomic number increases, the neutron_proton ratio decreases for stable nuclei. 9 A. True B. False 0003 0291012 A 12 12106 31 06171486 Induced radioactivity is always a more energetic process than natural radioactivity. 9 A. True B. False 0003 0291013 A 12 12108 31 14661486 The magnitude of charge on a positron is the same as that on an electron. 9 A. True B. False 0003 0291014 B 12 12110 31 06321486 Alpha emission is usually considered to be an example of nuclear fission. 9 A. True B. False 0003 0291015 B 12 12112 31 06321486 Fission of light nuclei generally tends to release more energy than fission of heavy nuclei. 9 A. True B. False 0003 0291016 A 12 12114 32 06201486 If the number of grams of a radioactive isotope is found to be reduced from 12 to 1.5 in a time interval of 600 hr, then the half_life of that isotope is 200 hr. 9 A. True B. False 0003 0291017 B 12 12117 32 03531486 5 32 The number of neutrons in a P nucleus is 32. 4 15 0003 9 A. True B. False 0293002 A 12 12119 31 03420398049509 Atomic nuclei always weigh less than the sum of the individual masses of their constituent particles. 9 A. True B. False 0041 0293003 A 12 12121 31 16850342044909 The greater the binding energy of a nucleus, the more stable it is. 9 A. True B. False 0041 0293004 B 12 12123 31 01590632 09 5 235 Stars obtain their energy from the nuclear fission of U . 9 A. True B. False 0041 0293005 A 12 12125 51 01891110037909 Several elements whose atomic masses are less than that of lead are radioactive. 9 A. True B. False 0041 0293006 B 12 12127 31 039803420340 The mass of a helium nucleus is slightly more than the combined mass of four hydrogen nuclei. 9 A. True B. False 0041 0295001 B 12 12129 31 06321499 5 235 U is the only known fissionable material. 9 A. True B. False 0041 09 0295002 A 12 12131 31 06611218015909 The nuclear reaction that gives the hydrogen bomb its immense destructive capability is similar to that which supplies the sun with energy. 9 A. True B. False 0041 0295003 B 12 12134 51 12201221034109 The moderator in a nuclear reactor controls the rate at which power is produced by absorbing some neutrons. 9 A. True B. False 0041 0295004 B 12 12136 51 08470806120609 Tritium is one of the products of radium decay. 9 A. True B. False 0041 0295005 A 12 12138 51 16880342120609 All mesons are unstable outside of atomic nuclei and decay in a small fraction of a second. 9 A. True B. False 0041 0295006 A 12 12140 51 16901206169109 Charged p_ions decay into charged mions. 9 A. True B. False 0041 0295007 B 12 12141 51 00991690034109 Neutral p_ions decay into neutrons. 9 A. True B. False 0041 0295008 B 13 45003 31 066112160632 The term critical mass applies to A. atomic fusion B. atomic fission C. the manufacture of balance weights D. molecular mass 9 E. the equilibrium between gases and liquids 0026 0295009 B 12 12144 31 12161486 09 A nuclear explosion results only when a critical mass is accumulated. 9 A. True B. False 0040 0295010 B 12 12146 31 1212 Neutrons can be accelerated in a cyclotron. 9 A. True B. False 09 0040 0295011 A 09 0040 12 12147 31 0661 514 4 17 N reacts with alpha and produces O. The other particle 47 2 8 5 1 produced is H. 4 1 9 A. True B. False 0295012 B 12 12150 31 03281285033709 The emission of a beta_particle leaves the atomic number unchanged but increases the mass number by one unit. 9 A. True B. False 0009 0295013 A 0009 12 12152 31 03281466034209 Emission of a positron is equivalent to the conversion of a proton to a neutron in the nucleus. 9 A. True B. False 0295014 B 12 12154 31 06200379035309 The longer the half life of a radioactive isotope, the more rapidly it decays. 9 A. True B. False 0009 0295015 B 12 12156 51 12230337034109 The very heavy transuranium elements, atomic number 101 or greater, are most readily prepared by neutron bombardment. 9 A. True B. False 0009 0295016 B 12 12158 31 15751576157709 Probably the most important hazard associated with a nuclear power plant is the possibility of a nuclear explosion. 9 A. True B. False 0009 0295017 A 12 12160 31 07741486 A very high temperature is required in order to initiate a nuclear_fusion reaction. 9 A. True B. False 0003 0295018 B 12 12162 32 12851486 5 210 Emission of a beta particle from a Pb nucleus yields a 4 82 nucleus with a mass number of 211. 9 A. True B. False 0003 0295019 A 12 12165 31 06321486 High_energy neutrons are rarely produced in nuclear_fission reactions. 9 A. True B. False 0003 0295021 A 12 12170 31 12021486 Gamma radiation is not accompanied by a change in either atomic or mass number. 9 A. True B. False 0003 0295022 B 12 12172 31 15380787 A plausible way to achieve the high temperatures required for nuclear fusion is to operate the process in the upper atmosphere. 9 A. True B. False 0009 0297001 A 12 12175 31 05180331 09 A nuclear fusion reaction is responsible for the output of energy by the sun. 9 A. True B. False 0040 0299001 A 12 12177 32 01591447166909 5 16 The amount of energy equivalent to 1 kg of mass is 9 x 10 joules. 9 A. True B. False 0041 0299002 A 12 12180 51 02631466120209 When an electron and a positron come together, their mass and charge disappear and two gamma rays are created. 9 A. True B. False 0041 0299003 B 12 12182 31 06320518 09 Nuclear fission reactions produce more energy per weight of reactant than fusion reactions. 9 A. True B. False 0299004 B 12 12184 32 03641368051809 5 2 According to the einstein relation (E = mc ), the fusion 5 20 of one gram of deuterium would liberate 9.00 x 10 ergs or 5 10 2.15 x 10 kcal of energy. 9 A. True B. False 0040 0009 0311001 B 12 12188 51 13660367 09 Mendeleev's periodic law becomes exact with no exceptions when the elements are arranged in the order of their atomic numbers rather than of their atomic weights. 9 A. True B. False 0041 0312001 B 12 12191 31 03700189 09 There are still many gaps in the periodic table into which no known elements fit. 9 A. True B. False 0041 0312101 C 13 12193 31 122314610362 Uranium has an atomic number of 92. The transuranium elements all have atomic numbers. 9 A. greater than 94 B. less than 92 C. greater than 92. 0026 0312201 A 12 12196 31 07940370 09 There are eight major groups in the periodic table. 9 A. True B. False 0041 0312301 A 12 12198 31 01960015 09 Hydrogen behaves like a metal in certain respects. 9 A. True B. False 0041 0312302 A 12 12200 31 01890015 The majority of the elements are metals. 9 A. True B. False 0041 09 0312303 B 12 12201 31 14860015037009 Metals are found to the far right of the periodic table. 9 A. True B. False 0040 0312304 B 12 12203 31 03620722 09 Elements which are most metallic are found in the lower right area of the periodic table. A. True 9 B. False 0312305 B 12 12205 32 03620722 09 Elements which are the most metallic are found in the upper left area of the periodic table. A. True 9 B. False 0312306 B 12 12207 31 03620722 09 Elements which are the least metallic are found in the upper left area of the periodic table. A. True 9 B. False 0312307 A 12 12209 31 03620722 09 Elements which are the least metallic are found in the upper right area of the periodic table. A. True 9 B. False 0321001 A 12 12211 31 01890463800409 04 Elements with similar chemical properties have the same number of electrons in the outer shell A. True 9 B. False 2WVW 0321002 A 12 12213 31 0009033809 The magnetic behavior of iron, nickel, and cobalt is a consequence of their electron structures. 9 A. True B. False 0041 0321003 B 12 12215 31 01890020 An element can have only one valence. 9 A. True B. False 0041 09 0322001 B 12 12216 31 01890820037009 All the elements in each period of the periodic table have closely similar properties. 9 A. True B. False 0041 0322201 B 12 12218 51 00150104031509 Metals are good conductors of both electricity and heat. 9 A. True B. False 0041 0322202 B 12 12220 31 00150169150309 All metals are solids at room temperature. 9 A. True B. False 0041 0322203 A 12 12221 31 Metals have positive valences. 9 A. True B. False 0041 00150020058309 0322301 B 12 12222 31 00280351026309 Nonmetal atoms tend to lose their outer electrons when they combine chemically. 9 A. True B. False 0323001 B 12 12224 31 00821486 The hydroxy compounds of elements at the right of the periodic table are usually basic. 9 A. True B. False 0041 0003 0323101 A 12 12226 31 00020263035109 Sodium is more active than magnesium because the outer electrons of its atoms are less tightly bound than the outer electrons of magnesium atoms. 9 A. True B. False 0041 0323102 B 12 12229 31 01890449006609 Inactive elements form stable compounds. 9 A. True B. False 0041 0323104 B 12 12230 31 03750003 09 The activity of the alkali metals decreases with their size. 9 A. True B. False 0041 0323105 B 12 12232 31 00030554006109 An alkali metal is one that dissolves in a strongly basic solution only. 9 A. True B. False 0041 0323106 B 12 12234 31 01890845007509 Except for boron the elements of group III form amphoteric hydroxides. 9 A. True B. False 0043 0323107 B 12 12236 32 08080077008709 Bi O is not appreciably soluble in acid solutions. 4 23 9 A. True B. False 0043 0323108 A 12 12238 51 00030075160109 All alkali_metal (periodic group 1) hydroxides are strong bases. 9 A. True B. false. 0043 0323109 B 12 12240 31 03440025011309 Potassium metal reacts with oxygen gas to form potassium peroxide. 9 A. True B. false. 0043 0323110 B 12 12242 51 01700003079409 The sublimation energies of the alkali metals show a sharp increase in going down the group. 9 A. True B. False 0043 0323111 A 12 12244 51 00030172001509 Alkali metals have melting points which are rather low compared to many other metals. 9 A. True B. False 0043 0323112 A 12 12246 31 11780191000209 The sodium ion does not hydrolyze appreciably. 9 A. True B. False 0043 0323113 A 12 12247 31 13700794041609 The first ionization potential of lithium is the lowest in the group. 9 A. True B. False 0043 0323114 B 12 12249 31 00030008002509 Alkali metals are usually stored under water to protect them from the oxygen of the air. 9 A. True B. False 0043 0323115 B 12 12251 31 11780348105509 The sodium ion is a highly reactive species. 9 A. True B. False 0043 0323116 B 12 12252 31 16270113145209 5 + The disproportionation of Mg occurs only in the gas phase. 9 A. True B. False 0043 0323117 B 12 12254 51 01720900000309 The melting points of the alkaline_earth metals are generally lower than those of the alkali metals. 9 A. True B. False 0043 0323118 B 13 12256 51 017000030159 The sublimation energies of the alkali metals_____ in going down the group. 9 A. increase B. decrease C. remain constant 0019 0323119 B 13 12258 31 017200030015 As a class, the melting points of the alkali metals are ________ most other metals. 9 A. higher than B. lower than C. comparable to 0019 0323120 B 12 12260 31 148603690015 Representative elements contain partially filled d subshells. 9 A. True B. False 0040 0323121 A 12 12262 31 040700151331 5 2_ 2_ The reaction of oxygen with a 1A metal may produce O , O 4 2 5 _ O ions. 42 9 A. True B. False 0009 0323201 C 13 12266 31 The element Br will oxidize 4 2 01890045 or 0019 5 _ _ _ 9 A. F B. Cl C. I 0323202 A 13 12268 52 137101890516 The element with the lowest Van Der Waals attractive forces is A. F B. Cl C. Br 94 2 2 2 0019 0323203 A 13 12270 31 043809581097 In which liquid sample are the hydrogen bonds the strongest? A. H O B. H S C. H Se 94 2 2 2 0019 0323204 A 13 12272 52 11390293 The most polar molecule of those listed is A. NH B. PH C. AsH D. SbH E. BiH 94 3 3 3 3 3 0323205 B 12 12274 31 14860028007609 The element with atomic number 34 will probably form a positive ion. 9 A. True B. False 0323206 B 12 12276 32 03381486 A halogen atom has eight valence electrons. 9 A. True B. False 0323301 A 12 12277 51 00350189036909 Great variability in oxidation state is common for elements near the middle of a transition_metal series. 9 A. True B. False 0323302 B 12 12279 51 03690351088509 All transition element atoms have two valence electrons. 9 A. True B. False 0323303 A 12 12281 51 00350560 09 The highest oxidation state exhibited by manganese is +7. 9 A. True B. False 0019 0040 0003 0043 0043 0043 0323304 B 12 12283 51 03690793016909 Transition elements are likely to be brittle because of ionic bonding in the solid. 9 A. True B. False 0043 0323305 A 12 12285 51 01860614001509 The densities of all of the platinum metals are greater than 0043 5 3 that of lead (11.3 g/cm ). 9 A. True B. False 0323306 A 12 12287 32 01890943003209 Of the two elements, calcium and copper, the more likely to form coordination compounds is copper. 9 A. True B. False 0009 0323401 B 12 12289 51 03500062094309 Silicon is strongly metallic in its chemical behavior. 9 A. True B. False 0041 0323402 B 12 12291 32 01890845132309 The only element of group v which forms an amphoteric oxide is arsenic. 9 A. True B. False 0043 0323403 A 12 12293 31 01960321128409 Hydrogen is commonly found in combined form in the atmosphere. 9 A. True B. False 0043 0323501 A 12 12295 31 0567 09 The rare_earth metals resemble one another very closely. 9 A. True B. False 0323502 B 12 12297 51 17570067 09 As a result of the lanthanide contraction, lanthanum and yttrium are very similar in properties. 9 A. True B. False 0041 0043 0323801 A 12 12299 31 03510449034609 Atoms are most stable when their electron shells and subshells are closed. 9 A. True B. False 0041 0323802 A 12 12301 32 05810263034209 Chemical bonds form because one or more electrons are attracted simultaneously by two or more nuclei. 9 A. True B. False 0009 0323803 B 13 12303 52 011300370830 The first rare gas compound synthesized is ______. A. XeF B. XePtF C. XeOF 94 2 6 4 0324001 A 13 12305 71 8003 0019 2WVW Trans_1,2_dimethylethylene is more stable than cis_1,2_dimethylethylene because A. the repulsion of the methyl groups is greater in cis B. the product of hydrogenation of cis is more stable 9 C. the statement is correct, but A and B are incorrect 0331001 B 13 12309 71 800306 Which of the following is most reactive to anionic reagents? A. CF B. NF C. CH D. C H E. CCl 94 4 3 4 26 4 2WVW 0331002 A 15 12312 71 8003 06 Which will be most easily hydrogenated? A. cis_2_butene D. cyclohexane B. methane E. 1,2_dichloroethane 9 C. trans_2_butene 2WVW 0331003 C 13 12315 71 8003 Which will be most easily hydrogenated? A. cyclohexane B. cyclopropane 9 C. propylene (propene) 2WVW 06 0331004 B 12 12317 31 14860824072209 The most electronegative elements will be found on the left of the periodic table. 9 A. True B. False 0040 0332001 B 12 12319 31 00640731011309 The inert gases have the lowest ionization energies. 9 A. True B. False 0041 0334001 A 12 12321 51 03510032034409 An atom of Cu is considerably smaller than an atom of K. 9 A. True B. False 0043 0334002 A 12 12323 32 00261486 A chlorine atom (Z = 17) is smaller than an atom of sulfur (Z=16) because the chlorine atom has a higher nuclear charge. 9 A. True B. False 0003 0335001 B 12 12325 31 Chlorine is the heaviest gas. 9 A. True B. False 00060113 0041 0335002 B 08080373045809 12 12326 51 09 0043 The least soluble of the group II sulfates is BeSO . 4 4 9 A. True B. False 0335003 A 12 12328 31 0730 5 2+ 3+ Mg and Al are isoelectronic. 9 A. True B. False 09 0043 0335004 B 12 12330 52 08081526117809 MgSO is more soluble than BaSO because the charge density of 4 4 4 the ions is higher. 9 A. True B. False 0009 0335005 A 12 12332 52 15261435080809 Using the 'charge density rule,' we would expect CaF to be less 4 2 soluble than CaCl . 4 2 9 A. True B. False 0009 0335006 B 12 12335 32 00081486049809 Water has lower boiling point than prediced by the periodic law. 9 A. True B. False 0040 0335007 A 12 12337 32 07681486 Atoms of the noble gases in their ground states are never paramagnetic. 9 A. True B. False 0003 0337001 A 12 12339 31 08850351 09 The valence electrons of an atom are readily lost. 9 A. True B. False 0041 0337002 A 12 12341 31 00640020 The inert gases all have valences of zero. 9 A. True B. False 0041 09 0337003 B 12 12342 51 00350189003709 The only oxidation state exhibited by the group III elements in their compounds is +3. 9 A. True B. False 0043 0337004 B 12 12344 31 137100350369 The lowest oxidation state exhibited by a transition metal is +2. 0043 9 A. True B. False 0339001 A 12 12346 31 14020189006209 The chemical properties of the elements in each column of the periodic table change from top to bottom in the direction of increased metallic activity. 9 A. True B. False 0041 0339002 B 12 12349 31 00250028002309 Oxygen is a more active nonmetal than fluorine. 9 A. True B. False 0041 0339003 A 12 12351 31 00390071001509 Gold is a less active metal than iron. 9 A. True B. False 0041 0339004 A 12 12352 31 00281284 09 Nonmetals sometimes combine with one another. 9 A. True B. False 0041 0339005 B 12 12353 51 00390015007109 Gold is the most active common metal, sodium the least active. 9 A. True B. False 0041 0339006 A 12 12355 51 00230375009409 Fluorine is the most active common nonmetal, sulfur the least active. 9 A. True B. False 0041 0339007 A 12 12357 51 036900660035 In going down a transition_metal subgroup, compounds with higher oxidation states tend to become more stable. 9 A. True B. False 0043 0352001 B 12 12359 31 14860885096709 There are five valence electrons in boron (B). 9 A. True B. False 0040 0412001 B 12 12360 31 08120189079709 The symbol for an element is always derived from the first one or two letters in its English name. 9 A. True B. False 0009 0412002 B 12 12362 31 08121486018909 The first letter of an element's symbol always begins with the same letter as does the element's name. 0040 9 A. True B. False 0414001 A 12 12364 31 07260066 09 The sum of the oxidation numbers in a compound is 0. 9 A. True B. False 0041 0414002 B 12 12366 31 12540293019609 The molecular formula for hydrogen peroxide, H O , indicates that 4 22 one molecule of hydrogen (H ) is bonded to one molecule of 4 2 oxygen (O ). 4 2 9 A. True B. False 0009 0414003 B 12 12370 31 022401960445 The formula H S means that two parts of hydrogen by weight 4 2 are combined with one part of sulfur by weight. 9 A. True B. False 0041 0416001 B 12 12372 31 00310020 09 The equation H S + O _____> H O + SO is balanced. 4 2 2 2 2 9 A. True B. False 0041 0416002 A 12 12374 31 00311076 09 The equation C H + 11 O _____> 7 CO + 8 H O is balanced. 4 7 16 2 2 2 9 A. True B. False 0041 0416003 A 12 12376 32 08180031132409 The coefficient of boron, B , in the equation for the reaction of 4 5 boron with oxygen, can be predicted from the electronic structures of boron and of oxygen. 9 A. True B. False 0416004 C 15 12379 32 0704 22 The equation for the reaction of phosgene gas with sodium hydroxide is COCl + 4NaOH = Na CO + 2NaCl 4 2 2 3 + 2H O. If 3 moles of COCl react, how many moles of 4 2 2 sodium chloride are formed? 9 A. 2 B. 4 C. 6 D. 8 E. 10 0009 0416201 A 12 12383 51 02611173 09 Carbon dioxide may be prepared by heating MgCO . 4 3 9 A. True B. False 0043 0416202 B 12 12385 31 016101951167 At the same temperature and pressure, two volumes of hydrogen react with one volume of oxygen to give three volumes of water vapor. 9 A. True B. False 0041 0416401 A 12 12388 32 12010977102009 The calculation of theoretical yield is based on the assumption that all of the limiting reactant is consumed according to the equation for the reaction. 9 A. True B. False 0009 0416402 B 12 12391 31 01350553102009 In an ordinary chemical reaction, the number of moles of reactants always equals the number of moles of products. 9 A. True B. False 0009 0416403 A 12 12393 51 14190553024509 A chemical equation describes the relative changes in the numbers of moles of reactants and products as equilibrium is approached. 9 A. True B. False 0009 0420001 A 12 12396 31 05530066053409 A mole of any compound has a mass equal to the formula mass of that compound expressed in grams. 9 A. True B. False 0041 0420002 A 12 12398 31 02240553019209 The number of formula units is the same in a mole of any substance. 9 A. True B. False 0041 0420003 A 12 12400 51 05531339070309 The chemical mole is defined as being Avogadro's number of formula units (molecules, ions, atoms, electrons...). 9 A. True B. False 0009 0420004 A 12 12402 31 07030727 09 Avogadro's number of molecules is a mole of the substance. A. True 9 B. False 0420005 B 12 12404 31 1702 09 A mole of hydrogen atoms is equivalent in mass to a mole of hydrogen molecules (H ) 4 2 9 A. True B. False 0420006 A 12 12406 31 1702 09 A mole of hydrogen molecules (h ) and a gram_atom of helium 4 2 (He) contain the same number of particles A. True 9 B. False 0420007 A 12 12409 31 1702 09 A gram_atom of helium (He) and a mole of neon (Ne) contain the same number of particles. A. True 9 B. False 0420008 B 12 12411 31 1702 09 A mole of hydrogen (H ) and a mole of helium (He) have 4 2 the same mass. A. True 9 B. False 0420009 B 12 12413 31 1702 09 The mole is a convenient unit of measurement because a mole of one substance has the same mass as a mole of any other substance. A. True 9 B. False 0422001 B 12 12416 31 07031316079509 Avogadro's number is the number of amu in a gram. 9 A. True B. False 0422002 B 12 12418 31 0703 5 24 One mole of NaCl consists of 1.20 x 10 ions. 9 A. True B. False 0422003 A 12 12420 31 07030727 09 Avogadro's number of atoms is a mole of atoms. 0041 0003 9 A. True B. False 0422004 A 12 12422 31 07030727 09 5 23 A sample containing 6.02 x 10 atoms contains a mole of atoms. A. True 9 B. False 0422005 A 12 12424 31 07030727 09 5 12 The number of atoms in exactly 12.0000 grams of pure C is one mole. A. True 9 B. False 0422006 A 12 12427 31 07030727 09 5 12 A sample which contains 12.0000 grams of pure C contains 5 23 6.02 x 10 atoms of carbon. A. True 9 B. False 0422007 B 12 12430 31 07030727 09 5 16 A sample which contains 12.0000 grams of pure O contains Avogadro's number of atoms. A. True 9 B. False 0422008 B 15 12433 52 5 23 12 Avogadro's number is defined as 6.02 x 10 moles of pure C. 9 A. True B. False 0422009 A 12 12435 31 07030727 0940 The number of atoms present in 12.0000 grams of carbon_12 is called Avogadro's number. A. True 9 B. False 0422010 A 12 12437 31 07030727 0940 The number of atoms present in 16.0000 grams of oxygen_16 is called Avogadro's number. 9 A. True B. False 0422011 B 12 12439 31 07030727 0940 The number of atoms present in 6.0000 grams of carbon_12 is called Avogadro's number. A. True 9 B. False 0422012 B 12 12441 31 07030727 0940 The number of atoms present in 8.0000 grams of oxygen_16 is called Avogadro's number. A. True 9 B. False 0422013 A 12 12443 31 07030727 0940 The number of atoms present in 12.0000 grams of carbon_12 or 16.0000 grams of oxygen_16 is called Avogadro's number. A. True 9 B. False 0422014 A 12 12445 31 07030727 09 Avogadro's number of atoms is sometimes called a gram_atom. A. True 9 B. False 0424001 A 13 12447 52 146207270025 Which would require more oxygen for complete oxidation? A. 12 grams of charcoal (carbon) B. 12 grams of a compound C H O 4 5 10 2 C. 12 grams of a compound C H O N . 94 5 12 3 2 0026 0424002 A 12 12451 32 07950351029609 In 50 grams of calcium carbonate, CaCO (FW = 100), there are: 4 3 5 23 3 x 10 Ca atoms, 0.5 mole of C, and 3/2 gram atomic weights of oxygen. 9 A. True B. False 0009 0426001 A 12 12454 31 14860065035209 Atomic weights are relative weights. 9 A. True B. False 0040 0428001 A 12 12455 31 01280192029309 The molecular weight of a substance is a number which tells how heavy a molecule is when compared to a chosen reference 9 A. True B. False 0009 0428002 B 12 12458 31 03511097044509 Since three_fourths of the atoms in a sample of ScCl are 4 3 chlorine atoms, 75% of the weight of the sample is due to chlorine. 9 A. True B. False 0009 0428003 B 13 12461 32 006501890128 If the atomic weights of the constituent elements and the percentage composition by weight of a compound are known, it A. is always possible to determine the molecular weight of the gas B. may be possible to determine the molecular weight of the gas 9 C. is impossible to determine the molecular weight of the gas 0035 0428201 B 12 12466 32 03050196029309 A gram molecular weight of hydrogen (two atoms in a molecule) is a gram of hydrogen. 9 A. True B. False 0009 0428202 B 12 12468 32 02930305035109 The number of molecules in a gram molecular weight of water, 18 grams, is eighteen times the number of atoms in a gram atomic weight of hydrogen, 1 gram. 9 A. True B. False 0009 0434001 B 12 12471 32 02240037 09 A reasonable formula for a compound of aluminum and bromine would be Al Br. 4 3 9 A. True B. False 0009 0434201 A 12 12473 32 019513060293 Two volumes of hydrogen peroxide vapor may be decomposed into two volumes of water vapor plus one volume of oxygen; therefore hydrogen peroxide molecules have the formula H O . 4 22 9 A. True B. False 0041 0436001 A 12 12477 31 11100025170209 The atomic mass of oxygen is 16.00 amu, and so a gram atom of 0041 oxygen has a mass of 16.00 g. 9 A. True B. False 0436002 A 12 12479 32 0186 23 A box of salt ( NaCl ) weighs 1 lb. Approximately how many moles of salt does this box contain? ( atomic weights Na = 9 23 , Cl = 35.5 , 1lb = 454 grams ) 0436003 A 12 12482 32 0186 23 An empty aluminum soft drink can weighs 50 grams. How many moles of aluminum does the can contain? (Atomic weight Al=27) 9 A. 1.9 B. 0.5 C. 1350 D. 50 0436004 A 12 12485 32 0186 23 A 12oz soft drink can filled with water contains how many moles 9 of water. ( Atomic weights H = 1 , O = 16 , 1oz = 30mls ) 0436005 A 12 12487 32 0186 23 A nickle ( made from the element nickel ) weighs approximately 5 grams. If you had nickles equivalent in mass to one mole of nickel, approximately how much money would you 9 have. ( Atomic weight Ni = 60 ) 0439001 B 12 12490 32 00651486002509 An oxygen atom weighs 16 grams. 9 A. True B. False 0040 0439002 B 12 12491 32 14860065019609 Hydrogen has an atomic weight of 1, therfore one hydrogen atom weighs 1 g. 9 A. True B. False 0040 0440001 A 12 12493 32 00320182800209 04 Copper oxide is heated with charcoal. The reaction is an example of both oxidation and reduction A. True 9 B. False 2 OS 0441001 B 12 12495 31 07260351018909 The oxidation number of an atom in the elemental state is + if it is a metal, _if it is a nonmetal. 9 A. True B. False 0041 0441002 A 12 12497 31 15370007026309 In a redox reaction, the oxidizing agent gains electrons. 9 A. True B. False 0009 0442001 B 12 12499 31 08340474800309 04 Burning is an example of a physical change. A. True 9 B. False 2WVW 0442002 B 12 12500 31 00490286002109 Hydrogen is seldom used as a fuel because the heat liberated by its oxidation is small. 9 A. True B. False 0041 0443001 A 12 12502 31 00150196037509 The metals above hydrogen in the order of activity of the metals dissolve in acids, while those below hydrogen do not. 9 A. True B. False 0041 0443002 A 12 12504 51 00010027001609 Metallic aluminum is a stronger reducing agent than metallic zinc 9 A. True B. False 0043 0443003 B 12 12506 32 00871450145109 True or false? A solution of AgNO can safely be stored in a 4 3 copper bottle. 9 A. True B. False 0019 0444001 B 12 12508 31 00090189072609 Iron is the only element that has two different oxidation numbers in its compounds. 9 A. True B. False 0041 0444101 B 12 12510 51 035100700263 5 2+ When a vanadium atom (Z = 23) becomes ionized to form V , the electrons are removed from the 3d subshell. 9 A. True B. False 0043 0444201 B 12 12513 31 00200006040809 The oxidation state of chlorine is +1 in NaCl. 9 A. True B. False 0041 0444202 A 12 12514 31 00200413 The oxidation state of mercury is +2 in HgO. 9 A. True B. False 0444203 B 12 12515 32 09 00871296117809 0041 0041 A solution of copper sulfate, CuSO , contains copper, sulfur, and 4 4 oxygen ions. 9 A. True B. False 0444204 B 12 12517 32 10550189003509 The stable species of the element nitrogen in the +3 oxidation state in acidic solution is HNO . 4 3 9 A. True B. False 0444205 A 12 12520 31 00350189 09 The lowest oxidation state of a 5a element is _3. 9 A. True B. False 0444206 B 12 12522 31 0726 09 The sum of the oxidation states of all the atoms in an ion must equal zero. A. True 9 B. False 0444207 A 12 12524 31 0726 09 The sum of the oxidation states of all the atoms in a neutral molecule must equal zero. A. True 9 B. False 0444208 A 12 12526 31 0726 09 The charge on an ion is equal to the sum of the oxidation numbers of all the atoms in the ion. A. True 9 B. False 0444209 A 12 12528 31 0726 09 The oxidation state of an element can be different in two different compounds of that element. A. True 9 B. False 0444210 A 12 12530 31 0726 09 The oxidation state of an element bonded only to itself is always zero. A. True 9 B. False 0444211 A 12 12532 31 0726 09 0009 0009 The sum of the oxidation states of all the atoms in an ion equals the charge on the ion. A. True 9 B. False 0444212 A 12 12534 31 0726 09 The oxidation state of a given element is always the same in all samples of any particular compound which contains that element. A. True 9 B. False 0444301 BACBAACA 83 12537 52 034404048001169006 MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the statement is true and its truth is supported by the 2 reason given 2 B. if the statement is true but its truth is not supported by 2 the reason given 0 C. if the statement is False MACRO SUB_ITEM # 1 Potassium reacts more vigorously than sodium, because its valence 1 electron is closer to the nucleus of the atom. MACRO SUB_ITEM # 2 Chlorine reacts more vigorously than iodine, because its atomic 2 radius is smaller than that of iodine. MACRO SUB_ITEM # 3 Non_metals lose electrons more readily than metals, because they 3 have more electrons in their outermost shells. MACRO SUB_ITEM # 4 Acetic acid is a weaker acid than hydrochloric acid, because each 4 molecule of acetic acid can release only one hydrogen ion. MACRO SUB_ITEM # 5 When zinc reacts with hydrochloric acid, zinc atoms become zinc ions. The hydrogen ions of the acid act as the oxidizing agent, 5 because they gain electrons from the zinc atoms. MACRO SUB_ITEM # 6 When hydrogen ions acquire electrons, the change is reduction, 6 because electrons have been gained. MACRO SUB_ITEM # 7 Only an electric current can be used to reduce aluminum to the metallic state, because no other reducing agent is sufficiently 7 vigorous. MACRO SUB_ITEM # 8 The gases of group O of the periodic table do not react chemically with other elements, because they do not gain or lose electrons ETS2 OS 9 under chemical conditions. 0444303 B 12 12554 31 035111781402 Sodium atoms and sodium ions differ in that the latter are positively charged, but their chemical properties are identical. 9 A. True B. False 0041 0444304 A 12 12556 31 00660449 09 Ferric compounds tend to be more stable on the earth's surface, and ferrous compounds in the interior. 9 A. True B. False 0444305 B 12 12558 31 00160109002109 Aluminum disintegrates rapidly in air because of oxidation. 9 A. True B. False 0041 0041 0444306 B 12 12560 51 11780045001509 The vanadous ion will oxidize zinc metal. 9 A. True B. False 0043 0444307 A 12 12561 51 00450037036909 It is easier to oxidize compounds of the transition elements in basic solution than in acidic media. 9 A. True B. False 0043 0444308 A 12 12563 51 00121178 H O will reduce the manganic ion. 42 9 A. True B. False 09 0043 0444309 A 12 12564 51 13180191117809 One would expect a high percent hydrolysis for an ion with a high charge and a small radius. 9 A. True B. False 0043 0444310 A 12 12566 31 11731167002509 Li O can be prepared by reacting lithium metal with oxygen gas. 4 2 9 A. True B. False 0043 0444311 A 12 12568 31 09000189 09 None of the alkaline_earth elements is found uncombined in nature. 9 A. True B. False 0043 0444312 B 12 12570 31 00150726059509 Metals frequently show negative oxidation numbers. 0009 9 A. True B. False 0445001 B 12 12572 32 01621076007709 A redox equation balanced in acidic solution can be converted to apply in basic solution by adding the proper number of H O 4 2 molecules to both sides. 9 A. True B. False 0447001 B 12 12576 51 0007 09 Manganous hydroxide is a good oxidizing agent. 9 A. True B. False 0447002 B 12 12577 31 14860025 09 Liquid rocket propellant systems use oxygen as a fuel. 9 A. True B. False 0009 0043 0040 0447101 A 12 12579 31 17051473001009 Gangue is the valueless material mixed with an ore. 9 A. True B. False 0041 0447102 A 12 12581 31 00160013147309 Commercial aluminum is always produced by electrolysis. 9 A. True B. False 0041 0447103 B 12 12583 31 FeS is an important iron ore. 4 2 9 A. True B. False 00090010 09 0043 0447104 A 12 12584 51 17591323008609 In the basic open_hearth process limestone is added to remove acidic oxides. 9 A. True B. False 0043 0447105 B 12 12586 51 00151581000909 Chromium is a good metal for use in cathodic protection of iron. 9 A. True B. False 0043 0447106 A 12 12588 31 14860013147309 Electrolysis is used in the manufacture of some metals. 9 A. True B. False 0040 0447107 A 12 12590 31 14860461084409 Nickel is an important constituent of stainless steel. 9 A. True B. False 0040 0447108 A 12 12592 31 14860461002509 Oxygen is used in elemental form in steel production. 9 A. True B. False 0040 0447109 A 12 12594 Steel is an alloy. 9 A. True B. False 14860194046109 0040 0447110 B 12 12595 31 14860194003909 Fifteen carat gold is actually 50% gold. 9 A. True B. False 0040 0447111 B 12 12596 31 14860461136909 A steel with high tensile strength also has a high ductility. 9 A. True B. False 0040 0447201 C 13 12598 31 005500210125 Photography is based primarily upon the chemistry of 9 A. dyes B. developing agents C. silver compounds. 0026 0447202 C 13 12600 51 005505290125 A film is rendered panchromatic by the presence of A. a small amount of developer B. larger_than normal grains C. dyes, sensitive to certain regions of the spectrum which impart energy to silver halide grains 9 D. sulfide compounds. 0026 0447203 B 13 12604 51 005505290125 In typical color film, which light sensitive layer is hit first by the incoming light? A. The green sensitive layer B. The blue sensitive layer 9 C. The red sensitive layer. 0026 0447204 B 13 12607 51 005500540125 If a piece of photographic film is exposed, developed bleached, reexposed, redeveloped, washed, and then treated with hypo, a 9 A. negative results B. positive results C. print results. 0026 0447205 B 12 12610 31 14860055 09 A finished photograph contains silver halide compounds. 9 A. True B. False 0040 0447206 A 12 12612 31 31 14860125005509 0040 The dark parts of a photograph negative contain silver metal. 9 A. True B. False 0447301 A 12 12614 31 06140015117109 Platinum metal is essentially insoluble in HNO . 4 3 9 A. True B. False 0043 0447302 A 12 12616 51 00210209133109 5 2+ Oxidation of iron by dilute hydrochloric acid produces Fe . 9 A. True B. False 0043 0447303 A 12 12618 51 15801514009109 The oxidizing strength of oxyanions is ordinarily greatest at low pH. 9 A. True B. False 0009 0447401 A 12 12620 51 00160062001309 Metallic aluminum is not produced by electrolyzing an aqueous solution of an aluminum salt, because water has a much lower oxidation potential than aluminum. 9 A. True B. False 0043 0447402 B 12 12623 51 00130196078809 If water is electrolyzed, the hydrogen produced is richer in deuterium than usual. 9 A. True B. False 0043 0447403 A 12 12625 51 01961331001309 Hydrogen can be produced by electrolyzing a solution of NaOH in water. 9 A. True B. False 0043 0447404 A 12 12627 51 15861587001309 Cryolite is added in the Hall process for making aluminum so that the electrolysis can be carried out at a lower temperature. 9 A. True B. False 0009 0447405 B 12 12630 51 15881589013809 5 _ Complexing agents such as CN are used in many electroplating processes to increase the concentration of metal ions. 9 A. True B. False 0009 0447601 B 0043 12 12633 31 11681773023609 Hard water can be softened by adding graham's salt, which 5 2+ precipitates the unwanted Ca . 9 A. True B. False 0447602 A 12 12635 31 00081168148609 5 2+ A common ion present in hard water is Ca . 9 A. True B. False 0040 0447603 A 12 12637 31 00081486116809 Water can be made chemically pure by distillation. 9 A. True B. False 0040 0447604 B 12 12639 31 00081486095809 H O is the only substance which may form hydrogen bonds. 42 9 A. True B. False 0040 0447605 B 12 12641 31 00081486116809 Distillation is often used to soften water in the home. 9 A. True B. False 0040 0447606 B 12 12643 31 00081168148609 In order for water to be soft all positive ions must be removed from it. 9 A. True B. False 0040 0447607 A 12 12645 31 07871614116809 5 2+ In the lime_soda process of water softening, Ca ions in the 5 + hard water are replaced eventually by Na ions. 9 A. True B. False 0009 0447608 B 12 12649 51 16151616008709 A zeolite column used to soften water could be regenerated by flushing with a concentrated solution of CaCl . 4 2 9 A. True B. False 0009 0447609 B 12 12652 51 16170471048809 Salt water can be converted to pure water by the process of osmosis. 9 A. True B. False 0009 0510001 B 12 12654 51 8003 09 Kinetics is concerned chiefly with the energetics of a reaction. A. True 9 B. False 2WVW 0510002 A 12 12656 51 8003 09 Kinetics is concerned chiefly with the pathway of a reaction. A. True 9 B. False 2WVW 0511001 A 12 12658 31 8003 09 When two species collide, but do not react chemically, there may be transfer of energy from one to the other. A. True 9 B. False 2WVW 0511002 B 12 12660 52 04071609049409 Any reaction for which the rate determining step involves a collision between two molecules must be second order. 9 A. True B. False 0009 0513001 A 12 12662 51 04071192 09 In general, very fast reactions have small activation energies. 9 A. True B. False 0009 0515001 A 12 12664 51 10041609 09 In stepwise mechanisms the rate_determing step is the slowest one 9 A. True B. False. 0043 0515002 B 12 12666 51 01380440117909 The derivative of a concentration with respect to time is the instantaneous value of the concentration at a certain time. 9 A. True B. False. 0043 0515003 A 12 12668 52 04070138102009 In general, as a reaction proceeds not only will a reactant concentration change, but dc/dt also changes. 9 A. True B. False. 0043 0515004 B 12 12670 51 04071004161209 The reaction: H (g) + I (g) _____> 2 HI(g) is first order in 4 2 2 both H and I . consequently, the mechanism must involve a 4 2 2 simple bimolecular collision between H and I molecules. 4 2 2 0009 9 A. True B. False 0517002 B 12 12674 31 8003 09 Reaction orders are identical to the coefficients of the reactants in the overall equation for the reaction. A. True 9 B. False 0517003 A 12 12676 52 14410494049509 2WVW 0043 5 2 If the rate law for a single step is rate = k[Q] , that step consists of the collision (and reaction) of two particles of Q. 9 A. True B. False. 0517004 A 12 12679 51 06201808013809 The half_life of a first_order chemical reaction is independent of reactant concentration. 9 A. True B. False. 0043 0517005 B 12 12681 51 06201808016109 The half_life of a first_order chemical reaction is independent of temperature. 9 A. True B. False. 0043 0517006 B 12 12683 51 09180138180809 Plotting reciprocal concentration against time yields a straight line for a first_order reaction. 9 A. True B. False. 0043 0517007 A 12 12685 32 04070491013809 If the rate of reaction doubles when the concentration is doubled, the reaction must be first order. 9 A. True B. False 0009 0517008 B 12 12687 31 04071522038509 For a zero order reaction the rate constant k could have the 5 _1 units sec . 9 A. True B. False 0009 0517009 B 12 12689 51 04070138091809 In a first order reaction a plot of concentration vs time is a straight line. 9 A. True B. False 0009 0517010 A 12 12691 51 16100539013809 The order of reactions occuring at solid surfaces frequently changes with concentration. 9 A. True B. False 0519001 A 12 12693 51 00640193024509 The addition of an inert gas without change in volume to a homogeneous, gaseous system at equilibrium will not affect equilibrium concentrations of reacatants or products. 9 A. True B. False. 0009 0519101 B 12 12696 31 04910407013809 The rate of a chemical reaction is directly proportional to the concentration of each reacting substance. 9 A. True B. False 0041 0519102 A 12 12698 51 04910407016109 The rates of most reactions change as the reactions proceed, even if the temperature is held constant. 9 A. True B. False. 0043 0519103 B 12 12700 51 01140407049409 Increasing the total pressure in a gas_phase reaction increases the fraction of the collisions which are effective in producing reaction. 9 A. True B. False. 0043 0519104 A 12 12703 31 04910407044009 The rate of reaction ordinarily decreases with time. 9 A. True B. False 0009 0043 0519301 B 12 12705 51 8003 04 A reaction that is overall exergonic cannot be slow kinetically. A. True 9 B. False 2WVW 0519302 A 12 12707 51 8003 04 A reaction that is overall endergonic can be very rapid kinetically. A. True 9 B. False 2WVW 0519303 A 12 12709 31 1192 Reactions with high activation energies are usually endothermic. 9 A. True B. False 0003 0519304 B 12 12711 51 08010683040709 The distinction between exothermic and endothermic reactions is 0041 that the latter requre activation energy in order to occur while the former do not. 9 A. True B. False 0519305 B 12 12714 31 04070161049109 Reaction rates are normally independent of temperature. 9 A. True B. False 0041 0519306 B 12 12716 51 04071192068309 Reactions with high activation energies are usually endothermic. 9 A. True B. False. 0043 0519307 A 12 12718 51 15220407016109 It is possible to change the value of the specific rate constant for a reaction by changing the temperature. 9 A. True B. False. 0043 0519308 A 12 12720 51 03290494016109 The frequency of collision between reacting particles is increased by increasing the temperature. 9 A. True B. False. 0043 0519309 B 12 12722 51 13680161117209 _E/RT In the relation K = Ae , as the temperature increases, the value of e also increases. 9 A. True B. False. 0043 0519310 B 12 12724 52 04071192049109 Reactions with small activation energies show a greater increase in rate as the temperature is raised than do reactions with large activation energies. 9 A. True B. False. 0043 0519311 A 12 12727 51 01490491016109 Measurement of the rate of a given reaction at a series of different temperatures provides data for the computation of the activation energy of the reaction. 9 A. True B. False. 0043 0519312 A 12 12730 51 04070801022709 If a reaction were neither exothermic nor endothermic, its equilibrium constant would be independent of temperature. 9 A. True B. False. 0043 0519313 B 12 12732 51 01381233016109 In order to reduce the concentration of NO in automobile exhaust, 0009 it is desirable to increase the temperature at which the fuel is burned. 9 A. True B. False 0519314 B 12 12735 31 14861192049109 The rate of a reaction increases when activation energy increases. 9 A. True B. False 0040 0519315 B 12 12737 31 14860161013609 The rate of a reaction is usually doubled by a 25 degrees C increase in temperature. 9 A. True B. False 0040 0519316 B 12 12739 51 11920407102009 The activation energy for a reaction can be obtained by taking the difference in energy between reactants and products. 9 A. True B. False 0009 0519317 A 12 12741 51 13501192074509 It is possible for the activation energy, as calculated from the Arrhenius equation, to be negative. 9 A. True B. False 0009 0519318 A 12 12743 31 1522 It is possible to change the specific rate constant for a reaction by changing the temperature. 9 A. True B. False 0003 0519501 A 12 12745 31 04850491040709 A catalyst changes the rate of a chemical reaction without itself being consumed. 9 A. True B. False 0041 0519502 A 12 12747 31 02570407019209 Catalysis refers to the effect on reaction speed of a substance that does not enter into the reaction directly. 9 A. True B. False 0041 0519503 B 12 12749 51 04850407100409 A catalyst alters the rate of a reaction without being involved in the mechanism. 9 A. True B. False. 0043 0519504 A 12 12751 31 09960785048509 An enzyme is a biochemical catalyst. 0043 9 A. True B. False. 0519505 B 12 12752 51 04910485040709 The rate of a catalyzed reaction is always independent of the concentration of the catalyst. 9 A. True B. False. 0043 0519506 A 12 12754 51 04910192048509 The rate at which substances reach equilibrium may be increased by adding a catalyst. 9 A. True B. False. 0043 0519507 A 12 12756 31 14860485119209 Catalyst act by lowering activation energy. 9 A. True B. False 0040 0519508 B 12 12757 31 14860485024509 Catalysts determine the position of equilibrium in a reaction. 9 A. True B. False 0040 0519509 A 12 12759 51 16081001100809 An enzyme_catalyzed reaction may be inhibited by adding a substance with a structure very similar to that of the substrate. 9 A. True B. False 0009 0519701 B 12 12761 51 18240407102009 An autocatalytic reaction is one in which a reactant catalyzes the reaction. 9 A. True B. False. 0043 0530001 B 12 12763 31 02450407143909 It is normally very difficult to establish a chemical equilibrium since most chemical reactions tend to proceed to completion. 9 A. True B. False 0041 0530002 B 12 12766 51 01930245019209 A homogeneous equilibrium is one involving only one substance. 9 A. True B. False. 0043 0530003 A 12 12768 31 14860136024509 The term equilibrium implies equal rates for opposing process. 9 A. True B. False 0040 0530004 A 12 12770 31 0245 A condition in which two opposing processes occur at exactly the same rate is known as dynamic equilibrium. 0003 9 A. True B. False 0531101 B 12 12772 51 01140245087109 Increasing the pressure on an equilibrium system always causes the system to adjust so as to relieve the stress. 9 A. True B. False. 0043 0531301 A 12 12774 51 02450407049109 In a chemical equilibrium two opposite reactions occur simultaneously at the same rate. 9 A. True B. False 0041 0531302 B 12 12776 51 18220227040709 The mass_action expression is always equal to the equilibrium constant for a reaction. 9 A. True B. False. 0043 0531303 B 12 12778 51 04910407024509 The rate of the forward reaction is equal to the rate of the reverse reaction at equilibrium only if both reactions have single_step mechanisms. 9 A. True B. False. 0043 0531304 A 12 12781 51 08710245068309 For a system at equilibrium the endothermic reaction always has a higher activation energy than the exothermic reaction does. 9 A. True B. False. 0043 0531305 A 12 12784 51 18221319024509 The mass_action expression is strictly constant at equilibrium only if chemical activities are used in the expression. 9 A. True B. False. 0043 0531306 B 12 12786 51 03250138022709 The ratio of O to O concentration in the upper atmosphere can be 4 3 calculated knowing the concentration of O and the equilibrium 4 2 constant for the reaction: O <=====> O + O. 4 3 2 9 A. True B. False 0009 0531307 B 12 12790 51 02451076015909 Equilibrium can be considered as a balance struck between two opposing tendencies: A system will tend to move toward a state of maximum energy; a system will tend to move toward a state of 0009 minimum entropy. 9 A. True B. False 0531501 B 12 12794 51 02270801040709 The equilibrium constant for an exothermic reaction is negative. 9 A. True B. False. 0531502 B 12 12796 31 02270407 09 The equilibrium constant for the reaction: CO(g) + Hem.O (aq) <=====> O (g) + Hem.CO(aq) 4 2 2 is less than one. 9 A. True B. False 0043 0009 0531503 A 12 12799 31 13190227105509 The expression for K always shows all gaseous or dissolved 4 c species, never pure solid or liquid species. 9 A. True B. False 0009 0531504 B 12 12802 32 01131167022709 Gaseous hydrogen and oxygen are allowed to react to form liquid water. The value of K for the reaction: C 0009 2 H (g) + O (g) <=====> 2 H O(l) will depend upon the initial 4 2 2 2 relative amounts of H and O . 4 2 2 9 A. True B. False 0531701 A 12 12807 52 05530537024509 One mole of HI(g) and one mole of H (g) are placed in an 4 2 evacuated container at 100 degrees C and allowed to come to equilibrium. As equilibrium is approached, one can be sure that the H concentration will increase. (The reaction: 4 2 2 HI(g) <=====> H (g) + I (g)) 4 2 2 9 A. True B. False 0009 0533101 B 12 12812 51 01921171000809 Some substances are completely insoluble in water. 9 A. True B. False. 0043 0533102 A 12 12814 31 14860245079109 When a liquid is placed in a closed container evaporation continues for a time and then stops. 9 A. True B. False 0533501 B 12 12816 31 01100008 09 The solubility of AgCl in 0.10 m NaCl is greater than it is in water. 9 A. True B. False 0040 0009 0533901 A 12 12818 51 01910100008709 5 3+ The hydrolysis of Fe may be repressed by adding concentrated HNO to the solution. 4 3 9 A. True B. False 0043 0533902 A 12 12820 51 11691446023609 5 2+ Addition of a strong acid to Cu(NH ) can precipitate cupric 4 34 hydroxide. 9 A. True B. False 0043 0533903 B 12 12823 52 11970254094309 The smaller the value of the dissociation constant for a complex, the weaker the coordinate bonds in the complex. 9 A. True B. False 0009 0533904 A 12 12825 52 02541531092309 The dissociation constant for a complex ordinarily increases as the strength of the ligands as bases decreases. 9 A. True B. False 0009 0535001 A 12 12827 51 02270407023909 The equilibrium constant for the reaction of a weak acid with a strong base is smaller than that for a strong acid_strong base reaction. 9 A. True B. False 0009 0535002 A 12 12830 52 02270407025409 5 _ + The equilibrium constant for the reaction of C H O with H is 4 232 equal to 1/K , where K is the dissociation constant for HC H O . 4 a a 232 0009 9 A. True B. False 0535101 B 12 12835 32 00910087 A pH of 0 signifies a neutral solution. 9 A. True B. False 09 0041 0535102 A 12 12836 32 00910077008709 A pH of 3.4 signifies an acid solution. 9 A. True B. False 0041 0535103 A 12 12837 32 00910061008709 A pH of 7.7 signifies a basic solution. 9 A. True B. False 0041 0535104 B 12 12838 52 00720087009109 When NH in solution is titrated with a solution of HCl, the pH 4 3 at the equivalence point is greater than 7. 9 A. True B. False. 0043 0535501 A 12 12840 52 00870061013809 A solution of Na HPO is more basic than one of the same 4 2 4 concentration of NaH PO . 4 2 4 9 A. True B. False 0043 0535701 A 12 12843 32 01681444020909 A mixture of 100 ml of 1.0 M HCl with 100 ml of 2.0 M NaC H O 4 232 would act as a buffer. 9 A. True B. False 0009 0535702 B 12 12846 52 01681444020909 A mixture of 100 ml of 1.0 M HCl with 100 ml of 1.0 M NaC H O 4 232 would serve as a buffer. 9 A. True B. False 0009 0535901 A 12 12849 32 00080138117409 5 + _ In pure water the H and OH concentrations are both 5 _7 10 mole/liter. 9 A. True B. False 0041 0535902 A 12 12851 32 00770087013809 5 + _7 In an acid solution the H concentration exceeds 10 mole/liter. 9 A. True B. False 0041 0535903 A 12 12853 31 00770087006609 It is possible for an acid solution to result when certain compounds that contain no hydrogen are dissolved in water. 9 A. True B. False 0041 0535904 A 12 12855 51 01911376000809 5 3+ Because of hydrolysis the simple boron ion, B , cannot exist to any appreciable extent in water. 9 A. True B. False 0043 0535905 A 12 12858 51 01380293008709 The concentration of water molecules is practically the same in all dilute solutions. 9 A. True B. False. 0043 0535906 A 12 12860 52 00770018019109 The weaker an acid is, the more strongly its salts hydrolyze. 9 A. True B. False. 0043 0535907 B 12 12862 52 00870075117809 Adding NH to a solution decreases the hydroxide_ion 4 3 concentration. 9 A. True B. False. 0043 0535908 B 12 12864 31 00080087006109 5 + _7 In a basic water solution, (H ) > 10 . 9 A. True B. False 0009 0535909 B 12 12866 31 08981446160109 The conjugate anions of strong acids are strong bases. 9 A. True B. False 0009 0537001 B 12 12868 31 01681537120109 5 o For a certain mixture, positive E values are calculated for two different redox reactions. We can be confident that the 0009 5 0 one with the higher e value will occur first. 9 A. True B. False 0551001 A 12 12872 51 05530169052809 The number of moles of BaSO per liter of solid BaSO is 4 4 4 essentially constant. 9 A. True B. False. 0043 0551002 A 12 12875 51 01100018016109 If the solubility of a salt increases with increasing temperature the K also increases as temperature is increased. 4 sp 9 A. True B. False. 0043 0551003 A 12 12878 51 00890808000809 Many strong electrolytes are not very soluble in water. 9 A. True B. False. 0043 0551004 B 12 12880 52 15270554009109 Because the K for ZnS is larger than that for CuS, ZnS will sp 0043 9 dissolve in a solution of lower pH than CuS will. A. True B. False. 0551005 B 12 12883 32 00181527011009 Any two salts that have the same K value will have the same sp solubility. 9 A. True B. False 0009 0551006 B 12 12885 32 00870236152709 5 + _ When equal volumes of 0.1 M solutions of M and X are mixed, a precipitate forms if K of MX is less than 0.01. sp 9 A. True B. False 0009 0553001 B 12 12888 32 02360087013809 5 _ A precipitate will form when enough Cl is added to a solution 5 2+ _ 0.10 M in Pb to make conc Cl = 0.010 M 5 _5 (K PbCl = 1.7 x 10 ). 0009 4 sp 2 9 A. True B. False 0553002 A 12 12892 31 00181173040709 A salt MNO can be prepared by a precipitation reaction which 4 3 involves adding AgNO to a solution of MCl. 4 3 9 A. True B. False 0009 0555001 A 12 12895 32 01141172109609 An increase in pressure increases the stability of diamond relative to graphite. 9 A. True B. False 0009 0555002 B 12 12897 52 04900169137609 Below the triple point temperature, only solid can exist. 9 A. True B. False 0009 0555003 B 12 12899 52 00081376043809 Pure water cannot exist as a liquid below 0 degrees C. 9 A. True B. False 0009 0555004 A 12 12901 32 00080130008709 If water saturated with nitrogen at 1 atm is exposed to air, N 4 2 will come out of solution. 9 A. True B. False 0009 0555005 A 13 12904 52 019504380172 The volume of a liquid sample decreases on freezing. An increase in pressure would therefore A. increase the melting point B. decrease the melting point 9 C. produce NO change in melting point 0019 0555006 B 13 12907 31 049811490008 The normal boiling points of water and ethyl alcohol are 100 degrees C and 78.5 degrees C respectively. The vapor pressure of water at its normal boiling point is ________ that of ethyl alcohol at its normal boiling point. 9 A. greater than B. equal to C. less than 0019 0555007 AB 22 12911 32 11490498 MACROITEM STEM The vapor pressures of ether and chloroform at 0 degrees C are 0019 18.5 and 6.2 cm Hg respectively. The boiling point of chloroform 0 should be ______ the boiling point of ether. MACRO SUB_ITEM # 1 1 A. lower than B. higher than MACRO SUB_ITEM # 2 The rate of evaporation of ether at 0 degrees C will be _________ the rate of evaporation of chloroform at 0 degrees C. 9 A. slower than B. faster than C. the same as 0555008 B 13 12916 32 000801740161 Where would water boil at the lowest temperature? A. Miami, Fla. (Elev 0) B. Columbus, Ohio (elev 600 ft) 9 C. Denver, Colo. Elev 500 ft) 0019 0555009 B 12 12918 32 14861437 09 The greater the pressure of a gas on the surface of a liquid, the less the solubility of the gas. 9 A. True B. False 0040 0555010 A 12 12920 32 14861437106409 The bends of a deep sea diver and the sparkle of soda pop are due to the same process. 9 A. True B. False 0610001 B 12 12922 31 14860087 09 In any mixture of water and alcohol the alcohol is always properly referred to as the solvent. 9 A. True B. False 0040 0040 0611001 B 12 12924 32 00871291013409 In a solution containing equal numbers of grams of benzene (MW = 78) and toluene (MW = 92), the mole fractions are each 0.50 9 A. True B. False 0009 0611002 A 12 12926 31 01341436008709 The mole fractions of all the components of a solution add to unity. 9 A. True B. False 0009 0612001 A 12 12928 51 00910077006109 The pH of an acid being titrated with a base rises sharply at the equivalence point. 9 A. True B. False. 0043 0612501 A 0040 12 12930 31 14860089001809 Salts are usually strong electrolytes. 9 A. True B. False 0613001 A 12 12931 51 00910087009909 The pH of a neutral solution is 7.0 at 25 degrees C. 9 A. True B. False. 0043 0613002 A 12 12933 51 00910099008709 The pH of a neutral solution is not 7.0 at 50 degrees C. 9 A. True B. False. 0043 0613003 B 12 12935 51 12110091 It is impossible to have a pH less than zero. 9 A. True B. False. 09 0043 0613004 B 12 12936 31 12110087009109 It is impossible to have a solution with a negative ph. 9 A. True B. False 0009 0613005 B 12 12938 32 00910087117309 5 _9 The pH of a solution prepared by dissolving 1 x 10 moles of HCl in a liter of water is 9. 9 A. True B. False 0009 0621001 B 12 12941 31 08450192117109 An amphoteric substance is one that is insoluble. 9 A. True B. False 0041 0621101 A 12 12943 31 00610097026309 04 A base is a proton acceptor and an electron donor. A. True 9 B. False 2 OS 0621102 B 12 12945 31 14430189037009 Hydronium is the element following hydrogen in the periodic table. 9 A. True B. False 0041 0621103 A 12 12947 31 00770192007009 An acid is a substance containing hydrogen which is partially or completely ionized when dissolved in water. 9 A. True B. False 0041 0621104 A 12 12949 31 00930087006109 An alkaline solution is the same thing as a basic solution. 0041 9 A. True B. False 0621105 A 12 12951 31 14860018006609 The compound CuCl would be classified as a salt. 4 2 9 A. True B. False 0040 0621106 B 12 12953 31 14860077000609 The substance ClO (OH) could not possibly be an acid. 4 2 9 A. True B. False 0040 0621201 A 12 12955 51 00870105116709 A solution of HCl will react with a solution of NaC H O . 4 232 9 A. True B. False. 0043 0621202 B 12 12957 51 00721173144609 Ammonia can be prepared by heating a solution of ammonium chloride with a strong acid. 9 A. True B. False 0009 0621203 A 12 12959 31 00871511007709 A solution which gives off bubbles when Na CO is added is 4 2 3 acidic. 9 A. True B. False 0009 0621301 A 12 12961 51 11730130008709 Sodium hydrogen carbonate could be prepared by saturating a solution of NaOH with CO and evaporating. 4 2 9 A. True B. False 0009 0621401 A 12 12964 31 00770104031509 Pure acids are poor conductors of electricity. 9 A. True B. False 0041 0621402 B 12 12965 32 00770196029309 The weaker an acid, the weaker is the attachment of hydrogen in its molecules. 9 A. True B. False 0041 0621403 A 12 12967 H PO is a diprotic acid. 43 3 31 00770077 09 0043 9 A. True B. False 0621405 A 12 12968 51 00871760052209 As a solution of a weak base is diluted, the number of moles of 5 _ OH per liter decreases. 9 A. True B. False. 0043 0621406 A 12 12970 51 00810087023909 As a solution of a weak acid is diluted, the percent dissociation of the acid increases. 9 A. True B. False. 0043 0621407 B 12 12972 51 00660061 All hydroxy compounds are bases. 9 A. True B. False. 09 0043 0621408 A 12 12973 51 14460056008109 Although H SO is a strong acid, the second step in its 4 2 4 dissociation is partial. 9 A. True B. False. 0043 0621409 B 12 12975 51 01960138008709 If the hydrogen_ion concentration in a solution of HCl is gradually decreased by progressive addition of water, the solution will eventually turn basic. 9 A. True B. False. 0043 0621410 C 13 12978 51 00771455 The strongest acid of those listed is A. HClO B. HClO C. HClO 94 2 3 0019 0621411 A 12 12980 31 14860018116709 A salt is produced when an acid reacts with a base. 9 A. True B. False 0621412 A 12 12982 31 02391446 There are more weak acids than strong acids. 9 A. True B. False 0621413 A 12 12983 51 09 00871178006109 5 _ Solutions containing CN ion are expected to be basic. 0040 0009 0009 9 A. True B. False 0621414 A 12 12985 32 00771446 09 5 _4 _4 HF (K = 7 x 10 ) is a stronger acid than HNO (K = 4 x 10 ). 4 a 2 a 9 A. True B. False 0009 0621501 B 12 12988 32 00870408035109 A solution of sodium chloride contains neutral sodium and chlorine atoms. 9 A. True B. False 0041 0621502 A 12 12990 31 00180808 All salts are soluble to some extent. 9 A. True B. False 0041 09 0621503 A 12 12991 51 00871173055409 A solution prepared by dissolving KAl(SO ) .12H O in water is 4 42 2 acidic. 9 A. True B. False 0043 0621504 A 12 12993 31 00870077085009 A solution of NH NO is acidic, because the ammonium ion 4 4 3 undergoes dissociation in water. 9 A. True B. False 0043 0621505 A 12 12995 51 00870008009909 A solution of KNO in water is practically neutral. 4 3 9 A. True B. False. 0043 0621506 A 12 12997 51 00870061 09 One would expect a solution of NaC H O to be basic. 4 232 9 A. True B. False. 0043 0621507 A 12 12999 51 00870077 09 One would expect a solution of NaHSO to be acidic. 4 4 9 A. True B. False. 0043 0621508 B 12 13001 51 00870061 09 One would expect a solution of NH Cl to be basic. 0043 4 9 A. True B. False. 4 0621509 A 12 13003 51 00870099 09 One would expect a solution of NH C H O to be neutral. 4 4232 9 A. True B. False. 0043 0621510 B 12 13005 31 14860408001809 Sodium chloride is the only true salt. 9 A. True B. False 0040 0621511 B 12 13006 31 A solution of NH Cl is basic. 4 4 9 A. True B. False 0009 00870061025209 0622001 A 12 13008 31 00801446160109 The neutralization of a strong acid by a strong base in a water solution is essentially the reaction of hydrogen and hydroxide ions to form water. 9 A. True B. False 0041 0622002 A 12 13011 31 13230061008009 A basic oxide can neutralize an acid solution even though it 5 _ contains no OH ions. 9 A. True B. False 0041 0622003 A 12 13013 31 14860080001809 The products of an acid_base neutralization are a salt and water. 9 A. True B. False 0040 0622004 A 12 13015 31 14860080001809 The reaction HNO + NaOH _____> NaNO + H O can be classified as 4 3 3 2 a neutralization. 9 A. True B. False 0040 0622301 B 12 13018 52 01030215009909 When 100 ml of 0.10 M HC H O is added to 100 ml of 0.10 M NaOH, 4 232 a neutral solution is produced. 9 A. True B. False 0009 0622302 A 0009 12 13021 52 00870099020909 When 100 ml of 0.10 M HCl is added to 100 ml of 0.10 M NaOH, a neutral solution is formed. 9 A. True B. False 0622303 A 12 13023 51 15290103030509 The gram equivalent weight of acetic acid, HC H O , in an 4 232 acid_base titration, is always equal to its gram molecular weight 9 A. True B. False 0009 0622304 B 12 13026 51 15301183009109 At the equivalence point of the titration of a strong acid with a weak base, the pH is greater than 7. 9 A. True B. False 0009 0623001 B 12 13028 31 02440153008709 NH OH crystals can be formed by evaporating a solution of 4 4 ammonia in water. 9 A. True B. False 0041 0623201 A 12 13030 32 01130072008709 When the gas ammonia is dissolved in water, the resulting solution is basic. 9 A. True B. False 0041 0623202 B 12 13032 32 0085133109 Carbonic acid can produce severe wounds. 9 A. True B. False 0041 0630001 B 12 13033 32 08080237079009 All soluble covalent compounds are nonelectrolytes. 9 A. True B. False 0041 0630002 A 12 13035 32 00080112113909 Water is an excellent solvent because of its polar nature. 9 A. True B. False 0041 0630003 B 12 13037 31 11391394019209 Polar liquids dissolve nonpolar substances readily and vice versa. 9 A. True B. False 0041 0630004 A 12 13039 31 14860136055409 The rate of dissolving of a solute is increased by heating. 9 A. True B. False 0040 0631001 B 12 13041 52 10500808053509 DDT should be more soluble in alcohol than in carbon tetrachloride. 9 A. True B. False 0009 0631002 B 12 13043 31 14861139011009 The solubility of a polar solute in a polar solvent tends to be low. 9 A. True B. False 0040 0632001 A 12 13045 32 0351 159109 Because of the larger size of the arsenic atom, one would expect arsenic acid to be weaker than phosphoric acid. 9 A. True B. False 0043 0632002 A 12 13047 51 05541026006109 Be(OH) will dissolve in excess base. 4 2 9 A. True B. False 0043 0632003 B 13 13049 32 143508080008 CsCl would be expected to be: A. more soluble in carbon tetrachloride than in water B. more soluble in water than in carbon tetrachloride 9 C. equally soluble in both solvents 0019 0632004 B 12 13052 32 14860110039409 Gasoline does not dissolve readily in water because polar substances tend not to dissolve in each other. 9 A. True B. False 0632005 A 12 13054 31 14860008 09 A nonpolar solute would be relatively insoluble in water. 9 A. True B. False 0040 0040 0632006 A 12 13056 31 0453 One would expect charcoal to adsorb chlorine (Cl ) more strongly 4 2 than hydrogen sulfide (H S). 4 2 9 A. True B. False 0003 0632007 B 12 13059 31 0182 A charcoal gas mask is more efficient at the south pole than at the equator. 9 A. True B. False 0003 0633001 A 12 13061 52 011000080215 The solubility of Ca(OH) in water can be decreased by adding 4 2 NaOH to the solution. 9 A. True B. False. 0043 0634001 B 12 13063 31 00870112013009 A solution that contains the maximum amount of solvent is called a saturated solution. 9 A. True B. False 0041 0634002 A 12 13065 32 11780554113909 Ionic compounds dissolve only in highly polar liquids. 9 A. True B. False 0041 0634003 B 12 13067 31 01100113016109 The solubilities of gases and solids increase with temperature. 9 A. True B. False 0041 0634004 B 12 13069 31 11710008 Potassium nitrate is insoluble in water. 9 A. True B. False 0634005 A 12 13070 51 0808 The most soluble of the silver halides is AgF. 9 A. True B. False 09 09 0634006 A 12 13071 51 0408080809 Silver chloride is more soluble in very concentrated NaCl than in pure water. 9 A. True B. False 0041 0043 0043 0634007 B 12 13073 32 15131173010909 A supersaturated solution of air in water could be prepared by bubbling air through water at 60 degrees C and cooling to 25 degrees C. 9 A. True B. False 0009 0634008 B 12 13076 31 01100161016909 The solubility of a solid in a liquid is ordinarily directly proportional to the absolute temperature. 9 A. True B. False 0009 0634009 B 13 13078 32 028605540087 Heat is evolved when a certain salt dissolves. Heating the 0019 solution will therefore ______ the solubility of the salt. 9 A. increase B. decrease C. not change 0634010 B 12 13081 31 01100130148609 For a substance to form a saturated solution, it must be very insoluble. 9 A. True B. False 0040 0634011 A 12 13083 31 14860110016109 In certain cases the solubility of a substance in water decreases with temperature. 9 A. True B. False 0040 0634012 A 12 13085 31 14860087049109 The solution process can be speeded up in an exothermic reaction by heating. 9 A. True B. False 0040 0636001 A 12 13087 31 01100008 09 The solubility of AgCl in 0.10 M NaNO is greater than it is in 4 3 water 9 A. True B. False 0009 0640001 B 12 13089 32 14860736 09 The molecular weight of water is a colligative property. 9 A. True B. False 0040 0641001 B 12 13091 51 04980087053609 The boiling point of a 1 M solution of a nonelectrolyte will be 100.52 degrees C, provided the solution is ideal. 9 A. True B. False 0009 0641002 A 12 13093 32 14860132073609 Salt water boils at a higher temperature than pure water. 9 A. True B. False 0040 0642001 B 12 13095 52 01110087 09 The freezing point of a 1 M solution of K SO would be about the 4 2 4 same as that of a 1 M solution of urea. 9 A. True B. False 0642003 A 12 13098 31 14860127073609 The freezing point of water is lowered by the addition of a solute. 0009 0040 9 A. True B. False 0644001 A 12 13100 51 01330112008709 Raoult's Law often applies to the solvent in a solution but not to the solute. 9 A. True B. False 0009 0644002 A 12 13102 51 01270132051909 Freezing point lowering, boiling point elevation, and osmotic pressure can all be explained in terms of vapor pressure lowering 9 A. True B. False 0009 0644003 A 12 13105 32 14860131073609 The solvent vapor pressure of salt water is less than that of pure water. 9 A. True B. False 0040 0644004 B 12 13107 32 14860131073609 The vapor pressure of water can be raised by adding a small amount of sugar. 9 A. True B. False 0040 0660001 A 12 13109 31 0130 Even a very tall cylinder containing a solution of sugar in water shows no settling of sugar molecules. 9 A. True B. False 0660002 A 12 13111 31 In a typical gel, both solid and liquid phases are continuous. 9 A. True B. False 0003 0003 0660003 A 12 13113 31 0118 Information about the charge on colloidal particles can be obtained from electrophoretic measurements. 9 A. True B. False 0003 0660004 B 12 13115 31 0122 The Tyndall effect becomes more pronounced at higher temperatures 9 A. True B. False 0003 0660005 B 12 13117 31 0118 If a liquid appears perfectly transparent when viewed in front of a bright light, it cannot be a colloid. 9 A. True B. False 0003 0662001 A 0003 12 13119 31 0118 Some molecules are so large they will produce a Tyndall effect 9 A. True B. False 0700001 B 12 13121 31 05810347 09 Chemical bonds almost never form unless half_filled orbitals are available. 9 A. True B. False 0009 0700002 B 12 13123 31 05890336 Diamond is an example of a glass. 9 A. True B. False 0003 0710001 A 12 13124 31 03510237019209 The atoms of covalent substances are joined by shared electron pairs. 9 A. True B. False 0041 0710002 B 12 13126 31 02370015006609 Covalent compounds invariably contain a metal. 9 A. True B. False 0041 0710003 B 12 13127 31 14860927092609 No more than one pair of electrons can be shared to form covalent bonds between atoms. 9 A. True B. False 0040 0710004 A 12 13129 52 14860926033709 A compound between elements with atomic numbers of 7 and 8 will contain covalent bonds. 9 A. True B. False 0040 0711301 A 12 13131 31 07820355034709 Molecular orbitals can be bonding or antibonding in character. 9 A. True B. False 0041 0711302 A 12 13133 31 07820263 09 A molecular orbital can contain at most two electrons. 9 A. True B. False 0712001 B 12 13135 31 13210781026309 In structural formulas, each dash represents a single shared electron. 9 A. True B. False 0712002 A 12 13137 31 0926 In order to define a "molecule" of a covalent solid, one would 0041 0041 0003 have to specify the entire crystal. 9 A. True B. False 0712101 B 12 13139 31 00140781029309 Carbon atoms may be joined by one, two, three, or four bonds in a molecule. 9 A. True B. False 0041 0712102 A 12 13141 52 07760037077709 Knowing that a Lewis structure can be written for the compound XY , where Y corresponds to an element in group 7a of the 4 2 periodic table, and that the octet rule is obeyed, you can be reasonably sure that the neutral atom of element X has two unpaired "valence" electrons. 9 A. True B. False 0009 0712104 A 12 13145 32 09451486 The ammonia molecule has two lone_pair electrons. 9 A. True B. False 0003 0712105 A 12 13147 32 07771486 The octet rule is violated in the compound NO . 4 2 9 A. True B. False 0003 0712301 B 12 13149 51 09850355035109 The formation of multiple bonds is exhibited more readily by large atoms than by small ones. 9 A. True B. False 0043 0712302 B 12 13151 51 15140527093909 The strength of the attractive force between two bonded atoms increases, and the length of the bond increases, in the order: single bond _ double bond _ triple bond. 9 A. True B. False 0009 0712303 A 12 13154 32 07451486 The energy required to break the bond in N should be greater 4 2 than that required for O . 4 2 9 A. True B. False 0003 0712304 B 12 13157 31 09351486 Each electron of a pair spends its time in only one of the two 0003 lobes of a pi bonding orbital. 9 A. True B. False 0712501 B 12 13159 51 12271509123009 The double bonds in benzene and other aromatic hydrocarbons behave chemically in the same way as those in ethylene. 9 A. True B. False 0009 0712701 A 12 13161 31 09190347115909 Hybrid orbitals are formed from combinations of s and p orbitals. 9 A. True B. False 0041 0712702 A 12 13163 32 12130919 An example of hybrid orbital occurs in H O. 4 2 9 A. True B. False 09 0041 0714001 A 12 13167 31 13210351029309 The structural formula of a compound indicates the arrangement of the atoms in its molecules. 9 A. True B. False 0041 0714002 B 12 13169 52 15960293093009 Experimental results support the idea that a certain molecule, AB , is linear (that is, all three nuclei lie along a straight 4 2 line). this must mean that there are only two pairs of electrons about the central atom. 9 A. True B. False 0009 0714101 B 12 13173 31 03510293 09 The H atoms in an H O molecule are 180 degrees apart on opposite 4 2 sides of the O atom. 9 A. True B. False 0041 0714102 A 12 13175 32 10290875087909 The nitrate ion has a planar, triangular structure. 9 A. True B. False 0043 0714103 A 12 13177 32 08500874087909 The ammonium ion has a tetrahedral structure. 9 A. True B. False 0043 0714104 A 12 13178 32 07791486 The carbon tetrachloride, CCl , molecule has a tetrahedral shape. 0003 4 9 A. True B. False 4 0714301 B 12 13180 32 09391486 In the ammonium ion one N_H bond is of different length from the other three. 9 A. True B. False 0003 0714701 B 12 13182 52 08791178 09 The structure of the metaphosphate ion is similar to that of the dichromate ion. 9 A. True B. False 0043 0714801 A 13 13184 51 16580898 05 A mirror image represents which symmetry operation? A. Reflection in a plane B. Rotation about an axis of symmetry 9 C. Inversion through a center 0714802 A 12 13187 32 0579 A rectangle contains a center of symmetry. A. True 9 B. False 09 0715001 A 13 13188 32 00661403077809 What of the following compounds should have the highest dipole moment? A. H O B. H S C. H Te 94 2 2 2 0019 0715002 B 12 13190 51 15930192092609 The physical properties of molecular substances are directly related to the strengths of the covalent bonds holding the molecule together. 9 A. True B. False 0009 0715003 B 12 13193 32 16971486 The electronic charge distribution in a diatomic molecule is symmetrical between the two nuclei. 9 A. True B. False 0715101 B 12 13195 72 142302631756 Each unpaired electron in an atom contributes 1.73 Bohr magnetons to the magnetic moment if the orbital moment is quenched. 9 A. True B. False 0003 0043 0715301 A 12 13198 51 03550351029309 Strong bonds between atoms in a molecule mean great stability. 9 A. True B. False 0715302 B 12 13200 32 07451486 The energy required to break the H_F bond is less than that required to break either the H_H of F_F bond. 9 A. True B. False 0041 0003 0715501 A 12 13202 31 11390293018509 Polar molecules behave as though they were negatively charged at one end and positively charged at the other. 9 A. True B. False 0041 0715502 B 12 13204 31 The water molecule is nonpolar. 9 A. True B. False 0040 00081486113909 0715503 A 12 13205 32 07781486 A polar diatomic molecule always contains a polar covalent bond. 9 A. True B. False 0003 0715504 B 12 13207 32 The methane molecule is polar. 9 A. True B. False 07781486 0003 0715701 A 12 13208 52 5 2+ Ti (g) should be paramagnetic. 9 A. True B. False 0768 09 0715702 B 12 13209 51 0768 09 5 + Paramagnetism would not be expected of Cr(NH ) Cl . 4 34 2 9 A. True B. False 0715703 B 12 13212 51 01890009175809 All the elements of the iron subgroup are ferromagnetic. 9 A. True B. False 0715704 B 12 13214 51 0037076809 Except for ferric compounds, all of the common compounds of the iron triad elements are paramagnetic. 9 A. True B. False 0043 0043 0043 0043 0715705 A 12 13216 32 076814861423 No matter what its structure is, a molecule with an odd number of electrons must be paramagnetic. 9 A. True B. False 0003 0715706 B 12 13218 32 07681486 Any molecule which has an even number of electrons cannot be paramagnetic. 9 A. True B. False 0003 0715801 A 12 13220 31 09391486 The four carbon_hydrogen bonds in the methane molecule are all the same length. 9 A. True B. False 0003 0716001 A 12 13222 31 14860716016909 The building units of crystalline solids may be atoms, ions, or molecules. 9 A. True B. False 0040 0716101 A 12 13224 51 02240695089509 5 _ The formula CoCl (NH ) represents a pair of cis_trans isomers. 4 4 32 9 A. True B. False 0043 0716102 A 12 13226 51 06950874153109 Cis_trans isomerism is not possible in tetrahedral complexes. 9 A. True B. False 0043 0716103 B 12 13228 51 15311659087309 5 2_ The square_planar PtCl F complex shows optical isomerism. 4 22 9 A. True B. False 0043 0716104 A 12 13230 71 11781531 09 5 3+ Only three oxalate ions are necessary to complex one Fe . 9 A. True B. False 0716105 A 12 13232 51 15311178093009 5 + Ag forms many linear complex ions. 9 A. True B. False 0043 0043 0716106 A 12 13233 51 15320351 09 A complex ion always contains more than one atom. 9 A. True B. False. 0043 0716107 B 12 13235 51 07280874153209 Any complex ion with a coordination number of four for the central atom has a tetrahedral structure. 9 A. True B. False 0009 0716108 A 12 13237 51 06950874153109 Geometric (cis_, trans_)isomerism is not observed in tetrahedral complexes. 9 A. True B. False 0009 0716201 B 0009 12 13239 52 11780767117809 _ 2_ Of the two ions, CN and SO , the more likely to be found in 4 4 metal complexes is the sulfate ion, the weaker base. 9 A. True B. False 0716202 A 12 13242 51 012611781841 5 _ The cyanide ion, CN , exhibits a strong ligand_field effect. 9 A. True B. False 0043 0716401 A 12 13247 52 08741531 5 2_ CrO is a tetrahedral complex. 4 4 9 A. True B. False 0043 09 0716502 B 13 13253 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. K (Cr)O (potassium chromate) 4 2 4 A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716503 A 13 13257 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. K (Fe)(CN) (potassium 4 3 6 2WVW hexacyanoferrate(III) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 0716504 B 13 13261 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. K (Pt)(C=N) 4 2 6 (potassium hexacyanoplatinate(IV) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716505 B 13 13265 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. Ni(CO) (CO is carbon monoxide, 4 4 Ni is nickel) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716506 A 13 13269 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. (Fe)(HOH) (NO ) (hexaaquoiron(II) 4 6 32 nitrate). A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716507 A 13 13273 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. (Fe)(HOH) (NO ) (hexaaquoiron(III 4 6 33 nitrate) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716508 B 13 13277 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. K (CO)(C=N) (potassium 4 3 6 hexacyanocobaltate(III)) 2WVW 9 A. paramagnetic B. diamagnetic C. insufficient data to tell 0716509 A 13 13281 52 8003 06 Use crystal field splitting to predict whether the following compound would be paramagnetic. K (Cr)(C=N) (potassium 4 3 6 hexacyanochromate(III)) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716510 B 13 13285 52 8003 06 Use crystal field splitting to predict the magnetic properties of K [Fe(CN) ], potassium hexacyanoferrate(II). 44 6 9 A. paramagnetic B. diamagnetic C. insufficient data to tell 2WVW 0716511 B 13 13289 52 8003 06 Use cystal field splitting to predict whether the following compound would be paramagnetic. (Co)(NH ) (NO ) 4 33 23 (trinitrotriamminecobalt(III)) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716512 B 13 13293 52 8003 06 Use crystal field splitting to predict whethr the following compound would be paramagnetic. (Rh)(NH ) (Cl) 4 36 3 (hexaamminerhodium(III) chloride) A. paramagnetic B. diamagnetic 9 C. insufficient data to tell 2WVW 0716513 B 12 13297 51 06620874153109 5 2+ Cr(NH ) is a deep blue, tetrahedral complex. 4 34 9 A. True B. False 0043 0716514 A 12 13299 51 01100008008709 The solubility of AgCl in water can be increased by adding NH 4 3 0043 to the solution. 9 A. True B. False. 0716515 A 12 13302 52 13240808000809 One would predict that (Pt(NH ) )Cl is more soluble in water 4 34 2 than is (Pt(NH ) Cl ). 4 32 2 9 A. True B. False 0009 0716516 B 12 13305 51 15321533044909 For a complex ion, labile means exactly the opposite of stable. 9 A. True B. False 0009 0720001 B 12 13309 31 14861425092709 Ionic bond formation involves sharing of electron pairs. 9 A. True B. False 0040 0721001 B 12 13311 31 14861425002809 An ionic bond often forms when two nonmetals react. 9 A. True B. False 0040 0723001 B 12 13313 52 15140958016909 The difference in strength between the hydrogen bonds in H O and 4 2 those in HF explains why the solid phases of these compounds have very different structures. 9 A. True B. False 0009 0723002 A 12 13317 32 01860290087909 The maximum density of water at 4 degrees C can be explained by assuming that the molecular structure of ice does not completely disappear when it melts. 9 A. True B. False 0009 0725001 B 12 13320 51 1453 09 The lattice energy of KCl is greater than that of AgCl. 9 A. True B. False 0043 0728001 A 12 13322 31 00200066 09 Positive and negative valences are equal in simple compounds. 9 A. True B. False 0041 0728002 A 12 13324 31 11781296 09 5 3_ One would expect Na N to contain the N ion. 0043 4 3 9 A. True B. False 0728003 B 12 13326 31 01040462153409 Molten BaCl is not a good electrical conductor. 4 2 9 A. True B. False 0728004 A 12 13328 CaO is very refractory. 9 A. True B. False 51 1834 09 0043 0043 0728005 B 12 13329 51 01040293046209 NaOH(s) is a poor electrical conductor because it is made up of molecules. 9 A. True B. False 0009 0728006 B 12 13331 31 13260189137009 A binary compound consisting of an element having a low ionization potential and a second element having a high electronegativity is likely to possess covalent bonds. 9 A. True B. False 0009 0728007 B 12 13334 31 0169 Molecular solids generally have high melting points. 9 A. True B. False 0003 0728008 A 12 13336 31 0160 Ionic crystals are good electric conductors, because the particles at the lattice points are electrically charged. 9 A. True B. False 0003 0728009 B 12 13338 31 07030005 Crystals of calcium chloride (CaCl ) are molecular. 4 2 9 A. True B. False 0003 0730001 A 12 13340 31 00620926 09 The metallic bond can be regarded as a kind of covalent bond. 9 A. True B. False 0041 0730002 B 12 13342 31 02630015 09 The electrons in a metal are tightly bound in place and cannot move about readily. 9 A. True B. False 0041 0731001 A 12 13344 31 00150244087909 Metals are weaker than ionic crystals with perfect crystal structures. 9 A. True B. False 0041 0731002 A 12 13346 31 01041700005409 Conductors are opaque to visible light. 9 A. True B. False 0041 0731003 B 12 13347 31 00151701087909 Metallic elements are amorphous in structure, unlike crystalline solids. 9 A. True B. False 0041 0731004 B 12 13349 31 00151369 09 Metals are ductile because they lack dislocations. 9 A. True B. False 0041 0733001 A 12 13351 31 03800015035109 Metal atoms have energy bands in place of energy levels. 9 A. True B. False 0041 0733002 B 12 13353 31 01590924169909 When energy bands overlap, the overlapping portion is known as a forbidden band. 9 A. True B. False 0041 0733003 A 12 13355 31 16761699015909 Electrical insulators have wide forbidden bands separating filled energy bands from higher empty bands. 9 A. True B. False 0041 0740001 A 12 13357 31 16980293 09 Van der Waals bonds hold water molecules together to form ice. 9 A. True B. False 0741001 A 12 13359 31 0516 Van der Waals forces exist in all matter. 9 A. True B. False 0743001 A 12 13360 52 09581149016109 Because of hydrogen bonding the vapor pressure of H O is less 4 2 than that of H S at the same temperature. 4 2 9 A. True B. False. 0041 0003 0043 0743002 A 12 13363 51 09580351018909 Hydrogen bonds can be formed between two atoms of different elements. 9 A. True B. False. 0043 0743003 C 13 13365 31 053504980959 Which alcohol should be the highest boiling? A. C H O B. C H O C. C H O . 94 38 262 383 0026 0743004 A 12 13367 52 11940958 09 Ethyl alcohol, C H OH, would be expected to show hydrogen bonding 4 25 9 A. True B. False 0743005 A 12 13369 52 11780186 09 5 + It is believed that the (C H ) N ion promotes the formation of 4 254 "flichering clusters" of water molecules. Consequently, one would expect the maximum density of solutions containing this ion to be above 4 degrees C. 9 A. True B. False 0009 0009 0743006 A 12 13374 31 00081486095909 Hydrogen bonding causes water to have a lower density than expected at its freezing point. 9 A. True B. False 0040 0743007 B 12 13376 31 00081486095909 The molecular weight of water depends upon hydrogen bonding. 9 A. True B. False 0040 0743008 A 12 13378 31 00080959148609 The anomalous properties of water can be attributed to hydrogen bonding. 9 A. True B. False 0040 0743009 A 12 13380 31 00080958148609 Water is an example of a hydrogen bonded substance. 9 A. True B. False 0040 0743010 A 12 13382 31 00081486049809 Because of hydrogen bonding water has higher boiling point than would be expected for such a substance. 9 A. True B. False 0040 0810001 A 12 13384 51 8003 09 Thermodynamics is concerned chiefly with the energetics of a reaction. 9 A. True B. False 2WVW 0810002 B 12 13386 51 8003 09 Thermodynamics is concerned chiefly with the pathway of a reaction. A. True 9 B. False 2WVW 0810003 B 12 13388 51 065516710265 The laws of thermodynamics apply only to internal combustion engines. 9 A. True B. False 0041 0811002 A 12 13390 51 In an adiabiatic system q = 0. 9 A. True B. False. 0043 05380871028609 0811003 B 12 13391 51 08710159159809 If a system is carried through a series of steps, each of which involves an energy transfer into or out the system, but finally ends up being identical in every way to the initial system, the total thermal energy transfer must be zero. 9 A. True B. False 0811004 A 12 13395 51 09840470 The first law of thermodynamics is the law of conservation of energy. 9 A. True B. False 0811005 AC 23 13397 31 01610286 119006 MACROITEM STEM 2For the following questions, evaluate the statements according to 2the key 2 A. An increase of the first will produce An increase in the 2 second. 2 B. An increase of the first will produce a decrease in the 2 second. 2 C. One will remain practically constant regardless of how the 0 other changes. MACRO SUB_ITEM # 1 1 Temperature of a liquid__rate of evaporation MACRO SUB_ITEM # 2 Amount of heat being applied to the liquid__temperature of a 0009 0041 ETS2WVW 9 boiling liquid 0811103 CBCBAAC 73 13403 51 038704168001119006 MACROITEM STEM 2Blacken space 2 A. if the item at the left is of greater magnitude than that 2 at the right 2 B. if the item at the right is of greater magnitude than that 2 at the left 0 C. if they are approximately of the same magnitude MACRO SUB_ITEM # 1 The work represented The work represented 1 by a dyne centimeter by an erg MACRO SUB_ITEM # 2 work required to raise potential energy of the a 10 lb. Object through 10 lb. Object at a vertical 2 a vertical distance of 30 feet height of 300 feet MACRO SUB_ITEM # 3 potential energy of an kinetic energy of the object at a height of 30 feet same object the instant before 3 it strikes the earth MACRO SUB_ITEM # 4 the mechanical advantage the mechanical advantage of an inclined plane 40 feet of an inclined plane 60 feet long with a vertical height of long with a vertical height 4 2 feet of 2 feet MACRO SUB_ITEM # 5 force necessary to move force necessary to move the a 3000 lb. Car up an inclined same car up an inclined plane 40 feet long with plane 60 feet long with 5 a vertical height of 2 feet a vertical height of 2 feet MACRO SUB_ITEM # 6 useful work performed useful work performed in in pulling a coaster pushing on a stalled 6 wagon 30 feet car which you do not move MACRO SUB_ITEM # 7 the amount of energy the work accomplished required to move an object in moving the object a given distance the same distance with with a crowbar, neglecting the crowbar, neglecting 9 friction friction 0811104 BAACCCBCB93 13425 31 1 042903879004119506 MACROITEM STEM 2Figure 4 represents two hills of different slopes. Neglect 2friction and air resistance and assume that potential energy ETS2 OS ETS2 OS 2is measured from the level of the horizontal line xy. The hill 2on which point m is located is referred to as the upper hill 2and the hill on which points N and O are located is referred to as the lower hill. Assume for the items in which a sled slides 2down either of these hills that it starts from rest at point z. 2Potential energy is equal to mgh and kinetic energy is equal to 3 ___ 21/2 Mv**2. force is equal to Ma, work is equal to force times 2distance, and power is equal to work done per unit of time. 2Mechanical advantage of a frictionless inclined plane is equal to 2the length of the plane divided by the vertical height. 2After the answer sheet number corresponding to that of each 2of the following paired items, blacken space 2 A. if the item at the left is greater than the item at the right 2 B. if the item at the right is greater than the item at the left 0 C. if the two items are of the same magnitude MACRO SUB_ITEM # 1 velocity of a person velocity of the same sliding down the upper person when sliding hill on a sled when passing down the lower hill 1 point M when passing point N MACRO SUB_ITEM # 2 velocity of a sled while velocity of the same sliding down the lower sled while sliding down hill when it passes point the lower hill when it 2O passes point N MACRO SUB_ITEM # 3 force required to raise force required to pull a sled from y to z the same sled along 3 either hill from x to z MACRO SUB_ITEM # 4 work done on a sled in work done on the pulling it along the upper same sled in raising it 4 hill from x to z from y to z MACRO SUB_ITEM # 5 work done on a sled in work done on the pulling it along the upper same sled in pulling it hill from x to z along the lower hill 5 from x to z MACRO SUB_ITEM # 6 force required to stop a force required to stop sled at point x after the the same sled at point sled has coasted down X after the sled has 6 the upper hill coasted down the lower hill MACRO SUB_ITEM # 7 the power required to the power required to pull a sled 10 feet up pull the same sled 10 feet the lower hill near point up the lower hill O and in a given amount near point N and in 7 of time the same amount of time MACRO SUB_ITEM # 8 the power required to the power required to pull a sled from x to z pull a sled from x to along the upper hill in z along the lower hill 8 three minutes in three minutes MACRO SUB_ITEM # 9 9 minutes in five minutes 0811105 B 12 13463 51 01690438040709 When solids and liquids alone are involved in a reaction, the work done by the reacting system is generally very small. 9 A. True B. False. 0043 0811106 B 12 13465 31 14860423044209 Energy a particle possesses by virtue of its motion is called potential energy. 9 A. True B. False 0040 0811107 B 12 13467 31 14860511050509 Doubling the speed of a particle doubles its kinetic energy. 9 A. True B. False 0040 0811108 B 12 13469 31 14860511042309 Kinetic energy cannot be converted into potential energy. 9 A. True B. False 0040 0811109 B 12 13471 31 14860423051109 A rolling bowling ball possesses mainly potential energy. 9 A. True B. False 0040 0811110 B 12 13473 31 14860511042309 A wound up watchspring represents kinetic energy. 9 A. True B. False 0040 0811111 B 12 13475 31 14860511016109 The kinetic energy of molecules in hot water is less than that of cold water. 9 A. True B. False 0040 0811112 B 12 13477 31 14860423051109 The potential energy increases when two positively charged particles are separated. 9 A. True B. False 0040 0811113 B 12 13479 51 03870317 Work is done whenever a force is applied. 9 A. True B. False 0811114 ABACAC 63 13480 51 038703170420119006 MACROITEM STEM 2Blacken space 2 A. if the item at the left is of greater magnitude than that 2 at the right 2 B. if the item at the right is of greater magnitude than 2 that at the left 0 C. if they are approximately of the same magnitude MACRO SUB_ITEM # 1 the work represented the work represented 1 by one joule by one erg MACRO SUB_ITEM # 2 the effort force required the resistance force of to move an object the object being moved 2 with a crowbar by the crowbar MACRO SUB_ITEM # 3 the distance traveled by the distance traveled the effort force in moving by the resisting force the object with the in being moved by the 3 crowbar crowbar MACRO SUB_ITEM # 4 energy required in energy required in climbing a steep hill climbing the same hill along a longer and less 4 steep path MACRO SUB_ITEM # 5 force required to raise force required to raise a piano directly up to a the piano to the window window 6 feet above the along an inclined plane 5 ground 12 feet long MACRO SUB_ITEM # 6 work done in raising work done in raising the piano directly up, the piano along the plane, 9 neglecting friction neglecting friction 0811115 CACCBCC 73 13498 31 1 9004 119506 MACROITEM STEM 2Figure 4 represents two hills of different slopes. Neglect friction 2and air resistance and assume that potential energy is measured 2from the level of the horizontal line xy. The hill on which point 2m is located is referred to as the upper hill and the hill 0041 ETS2 OS ETS2 OS 2on which points N and O are located is referred to as the lower 2hill. Assume for the items in which a sled slides down either of 2these hills that it starts from rest at point z. Potential energy 5 2 is equal to mgh and kinetic energy is equal to 1/2 mv . force 2is equal to ma, work is equal to force times distance, and power 2is equal to work done per unit of time. Mechanical advantage of a 2frictionless inclined plane is equal to the length of the plane 2divided by the vertical height. 2After the answer sheet number corresponding to that of each of 2the following paired items, blacken space 2 A. if the item at the left is greater than the item at the right 2 B. if the item at the right is greater than the item at the left 0 C. if the two items are of the same magnitude MACRO SUB_ITEM # 1 potential energy acquired potential energy acquired by a person climbing by the same person climbing 1 the upper hill from x to z the lower hill from x to z MACRO SUB_ITEM # 2 potential energy of a potential energy of the person climbing the upper same person climbing 2 hill from x to point M the lower hill from x to N MACRO SUB_ITEM # 3 loss of potential energy loss of potential energy of the sled in coasting of the sled in coasting from z to x along the from z to x along the 3 upper hill lower hill MACRO SUB_ITEM # 4 loss of potential energy gain in kinetic energy of a sled in sliding from of the same sled in falling 4 z to x along the upper hill freely from z to y MACRO SUB_ITEM # 5 kinetic energy of a person kinetic energy of the and sled when coasting same person and sled when past point M on the upper coasting past point N on 5 hill the lower hill MACRO SUB_ITEM # 6 kinetic energy of the kinetic energy of the sled when it has coasted sled when it has coasted down the upper hill and down the lower hill 6 is passing point x and is passing point x MACRO SUB_ITEM # 7 velocity of a person velocity of the same sliding down the upper person sliding down hill when passing point x the lower hill when passing 9 point x 0813001 A 12 13532 51 07290192016109 The enthalpy of a substance always increases with an increase in temperature. 9 A. True B. False. 0813101 CCAABCAB 83 13534 32 020780018003119006 MACROITEM STEM 2The following paragraphs concern the action of 2a geyser. Read the passage carefully and answer the items by 2using the key. 2A geyser is a hot spring that erupts at intervals. It is made up 2of a more or less crooked, or constricted, tubular fissure that 2extends into the earth and is filled with water. A source of heat 2near the bottom of the fissure heats the water. 2After an eruption the tube fills with water from an underground 2source. The water throughout most of the length of the tube, 2and especially in the lower part, becomes heated to a point 2above the normal boiling temperature (212 degrees F.) of water but 2does not become quite hot enough to turn to steam. However, 2sooner or later, some of the water in the lower part of the tube at 2the source of heat reaches the boiling point and turns to steam. 2The steam raises the whole column of water above it and causes 2some water to overflow from the geyser pool at the surface. 2This overflow acts as a trigger, permitting the whole column 2of water in the tube to flash into steam which blows from the 2fissure in an eruption. 2 A. Statement is true and pertains directly to the action 2 of the geyser. 2 B. Statement is true but is not directly concerned with 2 the action of the geyser. 2 C. Statement is false. 0 _____ MACRO SUB_ITEM # 1 1 Water has one of the lowest specific heats of any common substance. MACRO SUB_ITEM # 2 The boiling point of water in the bottom of the tube is 2 lower than that at the top. MACRO SUB_ITEM # 3 The water in the tube does not turn to steam although it is above the normal boiling point because of the 3 pressure of the overlying water. MACRO SUB_ITEM # 4 More heat is necessary to turn the water to steam at the 4 bottom of the tube than at the top. 0043 ETS2WVW MACRO SUB_ITEM # 5 Water vapor at the top of the tube (at the surface of the geyser pool) can be raised above its boiling point soley by the application of more heat after the water has 5 been made to boil. MACRO SUB_ITEM # 6 If salt were added to the water the boiling point of 6 the water would be lowered. MACRO SUB_ITEM # 7 The geyser erupts because the overflow of water releases pressure throughout the whole tube, lowering the boiling point at all levels sufficiently to allow the water to turn 7 to steam. MACRO SUB_ITEM # 8 Air pressure on a fine day is usually higher than on a stormy day. Thus the geyser will erupt more often during 9 stormy weather. 0813102 B 13 13564 32 04580596800111 06 Cerrous sulfate is more soluble in cold water than in hot water. Therefore, when this compound is dissolved in water, it is likely that heat will be A. absorbed from the surroundings B. given up to the surroundings C. neither absorbed nor given up since there is ordinarily NO 9 connection between heat effect and solubility 0813103 B 12 13569 31 14860504015909 For a pure substance, the gas state represents a lower energy state than the liquid. 9 A. True B. False 0813104 A 12 13571 31 06530387 The work done by 1 mole of water is greater when the water boils than when it freezes. 9 A. True B. False ETS2WVW 0040 0003 0813105 B 12 13573 31 1151 When equal masses of ice and liquid water are at equilibrium with each other, their heat contents are the same. 9 A. True B. False 0003 0813106 A 12 13575 31 1151 /\H of fusion is always a positive quantity. 3__ 9 A. True B. False 0003 0813107 D 14 13577 32 1151 Since the molar heat of fusion of water is 1.44 kcal per mole, 1 kcal of heat will melt: A. 0.0799 g of water B. 0.799 g of water 9 C. 7.99 g of water D. 12.5 g water 0813201 B 12 13580 31 04071501080109 In carrying out a reaction in a test tube, a student observes that the test tube becomes cold. He should call the reaction exothermic. 9 A. True B. False 0003 0813202 B 12 13583 32 0729 The enthalpy of water remains constant as the water is heated from its melting point to its boiling point. 9 A. True B. False 0003 0813203 C 14 13585 31 1546 The axes on a cooling curve are: A. pressure and temperature B. pressure and heat 9 C. temperature and time D. pressure and time 0003 0813204 BA 22 13587 32 00310286015390 MACROITEM STEM Given the thermochemical equation: UF (l) _____> UF (g), delta H = +7.2 kcal, 04 6 6 MACRO SUB_ITEM # 1 one can be sure that at least 7.2 kcal of heat must be produced or evolved when one mole of liquid UF is evaporated. 4 6 1 A. True B. False MACRO SUB_ITEM # 2 Another way of writing the thermochemical equation of question in the question above would be: UF (l) + 7.2 kcal _____> UF (g). 4 6 6 9 A. True B. False 0813205 A 12 13594 51 06480161028609 Two objects at different temperatures in a perfectly insulated container are brought into contact but do not react with each other. The final temperature of the objects inside the container can never be lower than the cooler object nor higher than the hotter object. A. True 0009 0009 9 B. False 0813206 B 12 13598 51 06480161028609 Assume that a hot block of metal is dropped into an insulated beaker containing a cooler liquid. Whether the heat lost by the metal equals the heat gained by the liquid depends upon the masses and specific heats of the metal and liquid. A. True 9 B. False 0813207 A 12 13602 51 06480161028609 When a block of solid is dropped into an insulated beaker of liquid, the heat lost by the substance originally at the higher temperature is always exactly equal to the heat gained by the substance initially at the lower temperature. A. True 9 B. False 0813208 A 12 13606 31 0648 09 If an exothermic reaction takes place in an insulated container, the temperature of the contents will be higher at the end of the reaction than it was at the start. A. True 9 B. False 0813209 B 12 13609 31 0648 09 If an endothemic reaction takes place in an insulated container, then the temperature of the contents will be higher at the end of the reaction than it was at the beginning. A. True 9 B. False 0813210 B 12 13612 32 0648 09 If an exothermic reaction takes place in an insulated container, the temperature of the contents will be lower at the end of the reaction than it was at the start. A. True 9 B. False 0813211 A 12 13615 32 0648 09 If an endothermic reaction takes place in an insulated container, then the temperature of the contents will be lower at the end of the reaction than at the beginning. 9 A. True B. False 0813501 A 12 13618 31 08010407028609 All exothermic reactions liberate heat. 9 A. True B. False 0041 0813502 B 12 13619 51 04070801040709 If a certain reaction is exothermic, the reverse reaction will be exothermic also. 9 A. True B. False 0041 0813503 A 12 13621 51 01921306015909 Substances whose decompositions absorb energy are usually stable. 9 A. True B. False 0041 0813504 B 12 13623 52 14350286040709 You would expect that the heat produced in the following reactions would have one and the same numerical value: 9 A. True B. False 0009 0813505 A 12 13625 52 07291291150209 The difference in enthalpy between one mole of Cl and two moles 4 2 of atomic chlorine, Cl, both at one atmosphere pressure and 25 degrees C is equal in magnitude to the heat of bond formation for one mole of Cl . 4 2 9 A. True B. False 0009 0813506 B 12 13630 31 12130407065109 Considering the example reaction: C(s) + O (g) _____> CO (g), 4 2 2 one can always say that the heat of combustion for any substance is the same thing as the so_called heat of formation of that substance. 9 A. True B. False 0009 0813507 B 12 13634 32 14350407073309 One would expect that /\H for the following reaction would be 3 __ smaller (i.e., less negative) than the molar heat of formation of liquid water: 2 H(g) + O(g) _____> H O(l) 4 2 9 A. True B. False 0009 0813508 A 12 13638 31 14860791068309 Evaporation is an endothermic process. 9 A. True B. False 0040 0813509 B 12 13639 31 14860170080109 Sublimation is an exothermic process. 9 A. True B. False 0040 0813510 A 12 13640 51 04070482072909 Reactions which tend to occur of their own accord, proceeding "naturally" or spontaneously, usually involve a decrease in enthalpy. 9 A. True B. False 0009 0813601 B 12 13643 51 02270161040709 The value of K is expected to increase with temperature for any 4 c reaction that has a negative value of delta H. 9 A. True B. False 0009 0815001 B 12 13646 51 07350037098509 Free energies of formation of compounds are positive numbers in most cases. 9 A. True B. False 0009 0815002 B 12 13648 51 04070161072909 If delta H and delta S for a reaction are both negative, we expect delta G to be negative at all temperatures. 9 A. True B. False 0009 0815101 B 12 13650 51 04070735049109 Reactions for which delta G is highly positive have rapid rates. 9 A. True B. False. 0043 0815102 B 12 13652 51 04070735016109 If delta G for a reaction is positive, it is impossible to carry out the reaction unless either the temperature or the pressure is changed. 9 A. True B. False 0009 0815103 A 12 13655 51 08010407048209 Exothermic reactions always become spontaneous as we approach absolute zero. 9 A. True B. False 0009 0815104 A 12 13657 52 07350985150309 The free energies of formation O? Cu O and CuO at 25 degrees C 4 2 and 1 atm are _35 and _30 kcal/mole respectively. This means that Cu O, exposed to oxygen at room temperature, will convert 4 2 spontaneously to CuO. 9 A. True B. False 0009 0815105 A 12 13661 51 04071520016109 Reactions for which delta H and delta S have the same sign will tend to reverse at high temperatures. 9 A. True B. False 0009 0815106 A 12 13663 52 04070482 09 True or false? The following reaction is spontaneous as written 5 2+ 3+ _ 2Fe + Br ___> 2 Fe + 2Br 4 2 9 A. True B. False 0019 0815107 A 12 13666 32 04070482 Which is the best reducing agent listed? 5 2+ _ A. Ni B. Ni C. F D. F 4 2 True or false? The following reaction is spontaneous as written. 5 3+ _ 2+ 2 Fe + 2 I ___> I + 2 Fe 4 2 9 A. True B. False 0019 0815108 A 12 13671 31 14860482087009 A process will be spontaneous if the energy decreases and the entropy increases. 9 A. True B. False 0040 0815109 B 12 13673 51 01140407048209 At 25 degrees C and 1 atmosphere pressure, the reaction between N and O is spontaneous. 42 2 9 A. True B. False 0009 0815110 B 12 13675 32 0735 Delta G of freezing ice at 0 degrees C is equal to zero. 9 A. True B. False 0003 0815111 B 12 13677 32 0735 Delta G of freezing ice at 10 degrees C is less than zero. 9 A. True B. False 0815301 A 12 13679 51 02270407068309 If the equilibrium constant for a reaction increases as the temperature is increased, the reaction must be endothermic. 9 A. True B. False. 0815302 B 12 13681 5 o At equilibrium /\G = 0. 3 __ 9 A. True B. False. 51 0245 09 0003 0043 0043 0815303 B 12 13683 51 08710245073509 5 o For a system at equilibrium delta G = delta G . 9 A. True B. False. 0043 0815304 A 12 13685 52 06000189040709 For the decomposition of water to the elements at 25 degrees C and 1 atm, delta G = +56.7 kcal. This means that at least 56.7 kcal of work has to be supplied to make this reaction go. 9 A. True B. False 0009 0815305 A 12 13688 31 07350490 At the triple point of water, the solid, liquid, and gaseous phases all have the same free energy. 9 A. True B. False 0003 0815306 B 12 13690 31 0490 The triple_point temperature of water is: A. 100.01 degrees C B. _0.01 degrees C 9 C. 0.01 degrees C D. 99.99 degrees C 0003 0815307 A 14 13692 51 0490 The normal melting point of CO is: 4 2 A. below the triple_point temperature B. above the triple_point temperature C. above the critical temperature 9 D. nonexistent 0003 0817001 A 13 13695 31 040708708003 06 2WVW If the chemical reaction below proceeds from left to right, there will be ______ in the entropy of the reaction system. 2 HOH (gas) = 2 H (gas) + O (gas) 2 2 A. an increase B. a decrease 9 C. no appreciable change 0817002 B 13 13699 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. 2 NO + O = 2 NO 4 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817003 A 13 13703 31 040708708003 06 The change in entropy for the reaction P(Cl) = P(Cl) + (Cl) 4 5 3 2 should be A. positive B. negative 9 C. zero 2WVW 0817004 B 13 13706 31 040708708003 (Cu)SO + H O = (Cu)SO (H O) should be 4 4 2 4 2 A. positive B. negative 9 C. zero 2WVW 06 0817005 C 13 13708 31 040708708003 06 The reaction 2 SO + O = 2 SO should proceed from left to right 4 2 2 3 with________in entropy. A. no change B. an increase 9 C. a decrease 2WVW 0817006 B 13 13711 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be________in the entropy of the reaction system. N + 3 H = 2 NH 4 2 2 3 A. an increase 2WVW 9 B. a decrease C. no appreciable change 0817007 A 13 13715 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. N O = 2 NO 4 24 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817008 B 13 13719 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be________in the entropy of the reaction system. 2 CO + O = 2 CO 4 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817009 A 13 13723 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. 2NO=2N +O 4 2 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817010 B 13 13727 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. (Cl) + 3 F = 2 (Cl)F 4 2 2 3 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817011 B 13 13731 31 040708708003 06 If the chemical reaction proceeds from left to right, there will be ________ in the entropy of the reaction system. HCl(g) + NH (g) = NH (+)Cl(_) (s) 4 3 4 A. an increase B. a decrease 2WVW 9 C. no appreciable change 0817012 A 13 13735 31 087007878003 06 The change in entropy for the process H O(s) = H O(l) will be 4 2 2 A. positive B. negative 9 C. zero 2WVW 0817013 B 13 13738 31 087080030407 06 Given that the reaction shown below proceeds from left to right, there will be _____________in the entropy of the reaction system. 2WVW P (g) + 5O (g) = P O (s) 4 4 2 4 10 9 A. an increase B. a decrease C. no appreciable change 0817014 B 13 13742 31 040708708003 06 If the chemical reaction proceeds from left to right, there will be ________ in the entropy of the reaction system. 2 Na (s) + Cl (g) = 2 Na(+)Cl(_) (s) 4 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817015 A 13 13746 31 064707878003 06 The change in entropy for the process, S (g) = 6 S(g), will be 4 6 A. positive B. negative 9 C. zero 2WVW 0817016 C 13 13749 31 065580030870 06 The second law of thermodynamics states that for any real process the entropy of the ________ increases. A. system B. surroundings 9 C. universe 2WVW 0817017 C 13 13752 51 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. PF (trigonal bypyramid) = pF (square pyramid) 4 5 5 A. an increase 2WVW 9 B. a decrease C. no appreciable change 0817018 C 13 13756 51 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. Cis_2_butene (C H ) _ trans_2_butene (C H ) 4 46 46 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817019 A 13 13760 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ______ in the entropy of the reaction system. 2 HOH (gas) = 2 H (gas) + O (gas) 4 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817020 B 13 13764 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. 2 NO + O = 2 NO 4 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817021 A 13 13768 31 040708708003 06 The change in entropy for the reaction P(Cl) = P(Cl) + (Cl) 4 5 3 2 should be A. positive B. negative 9 C. zero 2WVW 0817022 B 13 13771 31 040708708003 The change in entropy for the reaction (Cu)SO + H O = (Cu)SO (H O) should be 4 4 2 4 2 A. positive B. negative 9 C. zero 2WVW 06 0817023 C 13 13774 31 040708708003 06 The reaction 2 SO + O = 2 SO should proceed from left to right 4 2 2 3 with________in entropy. A. no change B. an increase 9 C. a decrease 2WVW 0817024 B 13 13777 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be________in the entropy of the reaction system. N + 3 H = 2 NH 4 2 2 3 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817025 A 13 13781 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. N O = 2 NO 4 24 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817026 B 13 13785 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be________in the entropy of the reaction system. 2 CO + O = 2 CO 4 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817027 A 13 13789 31 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. 2NO=2N +O 4 2 2 2 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817028 B 13 13793 31 040708708003 06 If the chemical reaction below proceeds from left to right, there 2WVW will be ________ in the entropy of the reaction system. (Cl) + 3 F = 2 (Cl)F 4 2 2 3 A. an increase B. a decrease 9 C. no appreciable change 0817029 B 13 13797 31 040708708003 06 If the chemical reaction proceeds from left to right, there will be ________ in the entropy of the reaction system. HCl(g) + NH (g) = NH (+)Cl(_) (s) 4 3 4 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817030 A 13 13801 31 087007878003 06 The change in entropy for the process H o(s) = H o(l) will be 4 2 2 A. positive B. negative 9 C. zero 2WVW 0817031 B 13 13804 31 087080030407 06 If the chemical reaction proceeds from left to right, there will be ________ in the entropy of the reaction system. P (s) + 5O (g) = P O (s) 4 4 2 4 10 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817032 B 13 13808 31 040708708003 06 If the chemical reaction proceeds from left to right, there will be ________ in the entropy of the reaction system. 2 Na (s) + Cl (g) = 2 Na(+)Cl(_) (s) 4 2 A. an increase B. a decrease 9 C. no appreciable change 0817033 A 13 13812 31 064707878003 06 The change in entropy for the process, S (g) = 6 S(g), will be 4 6 A. positive B. negative 9 C. zero 2WVW 2WVW 0817035 C 13 13815 51 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. PF (trigonal bypyramid) = PF (square pyramid) 4 5 5 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817036 C 13 13819 51 040708708003 06 If the chemical reaction below proceeds from left to right, there will be ________ in the entropy of the reaction system. Cis_2_butene (C H ) _ trans_2_butene (C H ) 4 46 46 A. an increase B. a decrease 9 C. no appreciable change 2WVW 0817037 B 12 13823 51 01920482087009 When any substance undergoes a spontaneous change, its entropy increases. 9 A. True B. False. 0043 0817038 A 12 13825 51 01920870 09 When any substance melts, its entropy increases. 9 A. True B. False. 0817039 A 12 13827 51 0870 09 The entropy of a martini is greater than the total entropy of the gin and vermouth out of which it was made. 9 A. True B. False. 0817040 A 12 13829 51 04070870058309 For the reaction: PCl (g) _____> PCl (g) + Cl (g), delta S is 4 5 3 2 positive. 9 A. True B. False 0817041 A 12 13831 31 11110870 Automobiles increase in entropy with age. 9 A. True B. False 09 0817042 A 12 13832 51 07871435072909 For the process CO (s) _____> CO (g), we expect both delta H and 4 2 2 0043 0043 0009 0009 0009 delta S to be positive. 9 A. True B. False 0817043 B 12 13834 52 08700407059509 The sign of the entropy change for the reaction: 5 2+ Ni (aq) + dimethylglyoxime _____> chelate(s) is expected to be negative. 9 A. True B. False 0009 0817044 B 12 13837 31 14860870135909 A high entropy corresponds to a high degree of order for a system. 9 A. True B. False 0040 0817045 A 12 13839 31 14860870135909 The entropy of a coed class is greater than one containing men only. 9 A. True B. False 0040 0817046 A 12 13841 31 0870 Delta S of freezing is always a negative quantity. 9 A. True B. False 0003 0817047 A 12 13843 32 0870 The entropy of a disordered pile of bricks on the ground would be greater than the entropy of the same bricks in a wall 9 A. True B. False 0003 0820001 A 12 13845 31 00870089031509 All solutions of electrolytes conduct electricity. 9 A. True B. False 0041 0820002 B 12 13847 31 14860013008709 Electrolysis can only be performed on solutions. 9 A. True B. False 0040 0821001 B 12 13849 31 14860013002109 In electrolysis, the process occurring at the cathode is oxidation. 9 A. True B. False 0040 0821002 B 12 13851 31 00290574059709 In any cell, electrolytic or voltaic, the cathode is the negative electrode. 9 A. True B. False 0009 0821003 A 12 13853 31 00300597 An anode is a positive electrode. 9 A. True B. False 0041 0822001 B 12 13854 31 01890438017809 The liberation of free elements from liquids by the passage of an electric current is called neutralization. 9 A. True B. False 0041 0822002 A 12 13856 31 00130018008709 Electrolysis can be carried out in molten salts as well as in water solutions. 9 A. True B. False 0041 0822003 B 12 13858 51 15890013 Electroplating is the reverse of electrolysis. 9 A. True B. False 09 0041 0822004 A 12 13859 31 07430385018509 The Faraday is essentially a unit of electric charge. 9 A. True B. False 0041 0822005 A 12 13861 32 00870013006109 If a solution of KBr is electrolyzed, it becomes more basic. 9 A. True B. False. 0043 0822006 A 12 13863 32 012505970574 You wish to silver plate a spoon. Which electrode do you make the spoon? 9 A. cathode B. anode 0019 0822007 B 12 13865 51 15810597158209 The phrase "cathodic protection" refers to the common practice of enclosing fragile metal electrodes in plexiglass to prevent them from being broken. 9 A. True B. False 0822008 A 12 13868 32 00130087055309 5 _ In the electrolysis of a water solution of Nacl, one mole of OH 5 _ is produced for every mole of cl consumed. 9 A. True B. False 0009 0822009 B 5 0009 12 13872 52 00130087074309 3_ 0009 In the electrolysis of a solution of Ag(S O ) , three Faradays 4 232 of electricity are required to form one mole of silver. 9 A. True B. False 0823001 B 12 13876 52 14860013085709 Platinum cannot be plated from solution by electrolysis. 9 A. True B. False 0040 0823101 B 12 13878 31 10551448000709 A species with a large positive standard oxidation potential will be a strong oxidizing agent. 9 A. True B. False 0009 0823102 B 12 13880 31 11910029040709 The voltage of a cell in which the reaction: 5 + 2+ Cu(s) + 2 Ag (aq) _____> Cu (aq) + 2 Ag(s) occurs will be, at 5 + standard concentrations: s.o.p. Cu + 2 x s.r.p. Ag 9 A. True B. False 0009 0823301 A 12 13884 51 04070138157909 Reactions which are readily reversed by a small change in concentration are ones in which E is close to zero. 9 A. True B. False 0009 0823501 B 12 13886 31 01890021041609 Any element with an oxidation potential less than that of zinc will liberate H from water. 4 2 9 A. True B. False. 0043 0823502 B 12 13888 51 153600010015 5 + The standard reduction potentials of F and Ag are +2.87v and 4 2 5 _ +0.80v respectively. We conClude that F is a better reducing agent than Ag metal. 9 A. True B. False 0009 0826001 A 12 13892 32 14860751059709 The container serves as an electrode in some cells. 9 A. True B. False 0040 0826002 B 12 13894 51 15841585117809 The purpose of the iron screen in the downs cell is to prevent 5 + _ Na and Cl ions from coming in contact with each other. 9 A. True B. False 0009 0826101 B 12 13897 31 03330178016209 Batteries produce electric current by means of oxidation reduction reactions. 9 A. True B. False 0041 0826102 A 12 13899 51 01541193024709 The chemical changes that occur in a lead_acid storage battery when it is charged by an external current are the opposite of those that occur when it is discharged. 9 A. True B. False 0041 0826103 A 12 13902 31 14860333034309 In the lead_acid battery used in automobiles, a single electrolyte is employed. 9 A. True B. False 0040 0826104 B 12 13904 31 14860333034309 The lead_acid battery used in automobiles is in reality made up of a single cell. 9 A. True B. False 0040 0826105 A 12 13906 31 0333 0159 A battery is a device for converting chemical energy into electrical energy.00 9 A. True B. False 0041 0826301 B 12 13908 51 15830196 A fuel cell is a storage chamber for hydrogen. 9 A. True B. False 0826302 B 12 13909 31 14860751 Fuel cells are quite efficient. 9 A. True B. False 09 0041 09 0040 0910001 B 13 13910 31 019910580552 The most common simple sugar is 9 A. sucrose B. d_glucose C. sucrose molecules. 0026 0910002 B 12 13912 31 03941486 09 Low molecular weight hydrocarbons are usually solids. 9 A. True B. False 0040 0910003 B 12 13914 31 08901486 An alkyne contains at least one double bond. 9 A. True B. False 09 0040 0910004 A 12 13915 31 06950882148609 Isomers are substances that have the same structure but different formulas. 9 A. True B. False 0040 0910005 B 12 13917 31 06780394148609 Ethane and ethene are both unsatureated hydrocarbons. 9 A. True B. False 0040 0910006 B 12 13919 31 08880889148609 Alkenes always contain more carbon atoms than alkanes. 9 A. True B. False 0040 0910007 B 12 13921 31 14861509 Cyclohexane is an aromatic compound. 9 A. True B. False 09 0040 0910008 B 12 13922 31 14860889 The general formula for alkanes is C H . 4 n 2n 9 A. True B. False 09 0040 0911001 B 12 13924 Nitroglycerin is an ester. 9 A. True B. False 32 10001661170609 0041 0911002 A 12 13925 31 05350394124809 Alcohols are hydrocarbon derivatives in which one or more H atoms in a hydrocarbon molecule have been replaced by OH groups 9 A. True B. False 0041 0911003 B 12 13927 51 00660678011009 Unsaturated compounds are unlimited in their solubility in water. 9 A. True B. False 0041 0911004 A 12 13929 51 06951254132109 Isomers have the same molecular formulas but different structural ones. 9 A. True B. False 0041 0911005 B 12 13931 31 00660393 09 0041 Octane is the name of a compound added to gasoline to prevent it from freezing in cold weather. 9 A. True B. False 0911006 B 12 13933 51 17070394016909 The paraffin hydrocarbons are all waxy solids. 9 A. True B. False 0041 0911007 B 12 13934 51 03820701007709 Organic acids, like inorganic acids, are often strong acids. 9 A. True B. False 0041 0911008 B 12 13936 52 00140351085309 The carbon atoms in the ring structures of benzene hydrocarbons are actually joined to one another with alternate single and double bonds 9 A. True B. False 0041 0911009 B 12 13939 51 10000382008909 Esters are the organic analogs of salts and therefore are electrolytes. 9 A. True B. False 0041 0911011 A 12 13942 51 17070394013009 The paraffin hydrocarbons are saturated because their structures contain only single bonds. 9 A. True B. False 0041 0911012 B 13 13944 51 07661244 How many optically active tartaric acids are there? 9 A. one B. two C. three 0019 0911013 A 13 13946 51 124500660407 The enantiomer of a compound produced by reaction of a d acid with an l base is _______. A. d acid _ d base B. l acid_ l base 9 C. l acid _ d base 0019 0911014 B 12 13949 31 12540889 09 The molecular formula C H represents an alkane. 4 5 10 9 A. True B. False 0009 0911015 B 12 13951 32 15080695 09 The hydrocarbon C H shows cis_trans isomerism. 0009 4 4 10 9 A. True B. False 0911016 B 12 13953 31 06950067 Isomers have identical properties. 9 A. True B. False 0043 0913001 B 12 13954 51 06740394048509 Polymerization is the heating of heavy hydrocarbons under pressure in the presence of catalysts in order to break them down into simpler molecules. 9 A. True B. False 0041 0913002 C 13 13957 31 070011440674 Which is the monomer unit in (_CH _CH _CH _CH _), polyethylene? 4 2 2 2 2 A. _H _ B. _CH _ C. _CH _CH _ D. _C_ E. _CH _CH _CH _ 94 2 2 2 2 2 2 2 0026 0913101 B 12 13961 31 11440196039809 In polyethylene, (CH ) , hydrogen accounts for 2/3 of the mass. 4 2n 9 A. True B. False 0009 0913701 B 13 13963 51 019101990401 The complete hydrolysis of amylopectin yields 9 A. dextrins B. d_glucose C. sucrose molecules. 0026 0913702 B 13 13965 31 07851068 Essential amino acids are: A. those that contain sulfur B. those that the body cannot manufacture in sufficient amounts 9 C. those that contain complex ring structures in the molecule. 0026 0913703 B 13 13968 31 06790785 The fibrous protein found in mammalian tissue is: 9 A. d_deoxyribose B. collagen C. hemoglobin. 0026 0920001 B 13 13970 31 00180785 Meat can be preserved by generous amounts of salt. This is due to the fact that, A. microorganisms can not eat salt B. the salt forms a hypertonic solution which dehydrates a microorganism C. the salt creates an aneorobic situation in the meat, SO 9 bacteria can not grow. 0026 0920002 B 13 13974 51 125712561258 The iodine number of a triglyceride consisting only of oleic acid is ________ one consisting of only linolenic acid. 9 A. larger than B. smaller than C. the same as 0920003 E 15 13977 51 1266 Lycopene is a ___________. A. monoterpene B. diterpene C. triterpene 9 D. sesquiterpene E. tetraterpene 0920004 C 13 13979 51 126709760988 Adenine is contained in _________. 9 A. DNA only B. RNA only C. DNA and RNA 0920005 B 13 13981 51 09730988 Uracil is contained in _____________. 9 A. DNA only B. RNA only C. DNA and RNA 0019 0019 0019 0019 0920006 A 13 13983 51 126709751268 Adenine forms a base pair with 9 A. thymine B. cytosine C. guanine 0019 0920007 A 12 13985 31 14861035103409 Some antibiotics do not themselves kill bacteria. 9 A. True B. False 0040 0920008 A 12 13987 31 14861035103409 A number of antibiotics are produced by soil organisms. 9 A. True B. False 0040 0920009 A 12 13989 31 14861027052909 The original sulfa drug was related to a chemical dye. 9 A. True B. False 0040 0920010 A 12 13991 51 14861027 09 The illegal drug heroin is closely related in structure to codeine and morphine. 9 A. True B. False 0040 0920011 A 12 13993 31 14861735173609 Penicillin was originally isolated from a mold. 9 A. True B. False 0040 0920012 B 12 13995 31 14861027173009 Tranquilizers are mild analgesics. 0040 9 A. True B. False 0920013 A 12 13996 31 14861027 09 Sedatives relax a patient while producing drowsiness. 9 A. True B. False 0040 0920014 B 12 13998 31 14861082 09 The path followed by a nerve impulse from the brain to an organ is continuous. 9 A. True B. False 0040 0920015 B 12 14000 31 14861082 09 All sympathetic nerves originate in the same part of the spinal cord. 9 A. True B. False 0040 0920016 B 12 14002 31 14861027 09 In normal surgical operations today, a single drug is used to produce sleep and anesthesia. 9 A. True B. False 0040 0921001 B 12 14004 31 10721115011709 Hemoglobin is a valuable nutrient found in milk. 9 A. True B. False 0041 0921002 A 12 14006 51 04010014019609 All carbohydrates contain only carbon, hydrogen, and oxygen. 9 A. True B. False 0041 0921003 B 12 14008 51 06980401 09 Chlorophyll is the most important carbohydrate found in plants. 9 A. True B. False 0041 0921004 A 12 14010 51 01590796 Plants store energy in the form of starch. 9 A. True B. False 0041 0921005 A 12 14011 51 0401 Lobster shells are largely carbohydrate. 9 A. True B. False 09 09 0921006 A 12 14012 Fats are lipids. 9 A. True B. False 51 08401710 0921007 B 51 06790293106809 12 14013 09 0041 0041 0041 A protein molecule consists of 23 amino acid units joined together. 9 A. True B. False 0921008 A 12 14015 51 11710679129609 Skin, muscles, hair, and nails contain insoluble proteins. 9 A. True B. False 0921009 B 12 14017 52 06790952 Heating a protein turns it into a nucleic acid. 9 A. True B. False 0921010 B 12 14019 9 A. True B. False 52 09 08650679129609 0041 0041 0041 0921011 B 12 14020 51 10021711097609 The sequence of nitrogen bases in a DNA molecule determines the properties of the cell in which it is located. 9 A. True B. False 0041 0921012 A 13 14022 51 098001911248 Treatment of gly_leu_val with 2,4_dinitrofluorobenzene followed by complete hydrolysis will yield a derivative of 9 A. glycine B. leucine C. valine 0019 0921013 C 13 14025 51 098012490977 Treatment of gly_leu_val with hydrazine will yield hydrazides of A. glycine and leucine B. leucine and valine 9 C. glycine, leucine and valine 0921014 B 13 14028 51 084012600675 Fats become rancid _______ oils. 9 A. faster than B. slower than C. at the same rate as 0019 0921015 B 13 14030 51 127612770128 Pepsin is of ________ molecular mass as/than pepsinogen. 9 A. larger B. smaller C. same 0019 0921016 B 12 14032 31 Cholesterol is a sex hormone. 9 A. True B. False 14861723107809 0040 0921017 A 12 14033 51 14861726084009 Waxes and fats are chemically both esters. 9 A. True B. False 0040 0921018 A 0040 12 14034 31 14860191172209 0019 The hydrolysis of disaccharides yields other sugars. 9 A. True B. False 0921019 B 12 14036 31 14860996019109 Cows possess the enzyme necessary to hydrolyze cellulose. 9 A. True B. False 0040 0921020 A 12 14038 31 Cellulose is a polysaccharide. 9 A. True B. False 0040 14861053164309 0921021 A 12 14039 31 14860675084009 Solid cooking shortening can be made from vegetable oils. 9 A. True B. False 0040 0921022 A 12 14041 31 14861710067509 Waxes and oils are both classes of lipids. 9 A. True B. False 0040 0921023 B 12 14042 Starch is a lipid. 9 A. True B. False 31 14860796171009 0040 0921024 A 12 14043 31 The sugar glucose is a hexone. 9 A. True B. False 14860199172209 0040 0921025 B 12 14044 31 14860840126009 Fats and oils go rancid due to the formation of steroids. 9 A. True B. False 0040 0921026 B 12 14046 31 14860840017209 Fats usually have lower melting points than oils. 9 A. True B. False 0040 0921027 A 12 14048 31 14860840013009 The fats obtained from animal sources contain high percentages of saturated fatty acids. 9 A. True B. False 0040 0921028 A 12 14050 31 14860675019109 Complete hydrolysis of an oil will always yield glycerol. 9 A. True B. False 0040 0921029 A 12 14052 31 14861009019109 Saponification is a hydrolysis reaction involving carbohydrates 0040 and a strong base. 9 A. True B. False 0921030 A 12 14054 31 14860675067009 Liquid vegetable oil may be solidified using a hydrogenation reaction. 9 A. True B. False 0040 0921031 A 15 14056 31 14860679110709 The permanent waving of hair involves reversible protein denaturation. 9 A. True B. False 0040 0921032 A 12 14058 31 Protein is a natural polymer. 9 A. True B. False 0040 14860679067409 0921033 B 12 14059 31 14861489067909 The helical arrangement of protein chains is an example of primary structure. 9 A. True B. False 0040 0921034 B 12 14061 31 06791486095909 Hydrogen bonding is involved in the primary structure of a protein. 9 A. True B. False 0040 0921035 B 12 14063 31 14860679040109 Proteins and carbohydrates are stored in the body as energy reserves. 9 A. True B. False 0040 0921036 B 12 14065 31 14861073106809 Vitamins are amino acids that the body cannot manufacture. 9 A. True B. False 0040 0921037 B 12 14067 31 14861107067909 Denaturation of a protein involves the rupturing of peptide linkages. 9 A. True B. False 0040 0921038 B 12 14069 31 14861068156409 The sequence of amin acids in a polypeptide is called the secondary structure. 9 A. True B. False 0040 0921039 A 12 14071 31 14860979097809 More than one type of RNA is known. 9 A. True B. False 0040 0921040 B 12 14072 31 14861068126909 Only one codon exists for each amino acid. 9 A. True B. False 0040 0921041 A 12 14073 31 14861727019109 The most common reaction of digestion is hydrolysis. 9 A. True B. False 0040 0921042 B 12 14075 31 14861727019109 Saliva initiates the digestive hydrolysis of starch. 9 A. True B. False 0040 0921043 B 12 14077 31 14860952048509 Nucleic acids are specific catalysts for chemical reactions occurring within a cell. 9 A. True B. False 0040 0921044 B 12 14079 31 14860976067909 DNA supplies directly to the cell the information necessary to 3 ________ synthesize proteins. 9 A. True B. False 0921045 B 12 14081 31 14860976098809 The backbone of an RNA molecule is identical to that of a DNA molecule. 9 A. True B. False 0040 0921046 A 12 14083 31 14860261007709 CO is important in normal acid_base balance of the body. 4 2 9 A. True B. False 0040 0921047 B 12 14085 31 14860988098609 RNA is the compound of which genes are composed. 9 A. True B. False 0040 0921048 A 12 14087 31 14861729098109 Ribosomes are the site where protein synthesis takes place. 9 A. True B. False 0040 0921049 B 12 14089 31 14861268097309 The bases thymine and uracil can be found in the same nucleic 0040 0040 acid. 9 A. True B. False 0921050 A 12 14091 31 14861088067909 Some antiseptics attack infectious organisms by denaturing their protein. 9 A. True B. False 0040 0921051 A 12 14093 31 14860996040009 Enzyme inhibition is a mode of action for some poisons. 9 A. True B. False 0040 0921052 B 12 14095 51 04010674037809 Carbohydrate polymers are synthesized only by plants. 9 A. True B. False 0009 0921053 A 12 14097 51 01910679109809 The hydrolysis of proteins (breakage of the peptide links with insertion of water molecules) will always result in the formation of equal numbers of _NH and _CO H groups. 4 2 2 9 A. True B. False 0009 0921054 B 12 14101 51 09880976156909 Cellular RNA can be thought of as an exact copy of DNA. 9 A. True B. False 0009 0922001 A 12 14103 51 00211710015909 The oxidation of lipids yields more energy than the oxidation of carbohydrates. 9 A. True B. False 0041 0922002 A 12 14105 51 04610194 Vanadium is used in steel alloys. 9 A. True B. False 09 0043 0923001 B 12 14106 51 09960401048509 Enzymes are specialized carbohydrates that act as biochemical catalysts. 9 A. True B. False 0041 0923002 B 13 14108 51 127801911098 Trypsin is necessary to hydrolyze ___________. 9 A. carboxydrates B. peptides C. acid esters 0019 0923003 A 0040 12 14110 31 14860996048509 Enzymes are biological catalysts. 9 A. True B. False 0923004 A 12 14111 31 14861007164109 Apoenzymes need coenzymes in order to function properly. 9 A. True B. False 0040 0924001 B 12 14113 51 04010261069809 Plants manufacture carbohydrates from carbon dioxide and chlorophyll. 9 A. True B. False 0041 0924002 B 12 14115 51 00210159020009 The oxidation of glucose in living matter to yield energy is an example of photosynthesis. 9 A. True B. False 0041 0924003 B 12 14117 52 10680830040109 Amino acids are synthesized in the human body from carbohydrates. 9 A. True B. False 0041 0924004 A 12 14119 51 0616 086509 X_rays can change the heredity of an organism by altering the structure of its DNA molecules. 9 A. True B. False 0041 0924005 C 13 14121 51 012611300400 Cyanide ion acts primarily by, A. precipitating valuable iron as Fe(CN) 4 2 B. blocking aconitase enzyme 9 C. by tying up oxidative enzymes. 0026 0924006 A 13 14124 51 127912800159 The aerobic metabolism of pyruvic acid yields _____ energy as/than the anaerobic metabolism. 9 A. more B. less C. the same 0019 0924007 A 12 14126 31 14860091078509 The pH of the stomach is quite high. 9 A. True B. False 0040 0924008 B 12 14127 51 10380679015909 In animals, proteins serve primarily to store energy. 9 A. True B. False 0009 0924009 A 12 14129 52 02000407001709 The net photosynthetic reaction, CO +HO _____> glucose +O , involves a reduction 4 2(g) 2 (g) (s) 2(g) of carbon. 9 A. True B. False 0009 0924010 A 12 14132 51 10680946001509 The alpha_amino acids might generally be expected to form chelates with metal atoms. 9 A. True B. False 0009 0924011 B 12 14134 52 00871068009109 The water solution of any amino acid which contains only one basic functional group and one acidic group is expected to have a pH of 7. 9 A. true B. False 0009 0924012 B 12 14137 52 07350830065509 The formation of an enzyme from amino acids has a positive free energy change. The fact that the synthesis of enzymes occurs in a living organism is a contradiction of the laws of thermodynamics. 9 A. True B. False 0009 0930001 B 12 14140 31 14860032 09 Copper is used in greater quantities than any other metal. 9 A. True B. False 0040 0931001 B 12 14142 51 05980001147309 Chromium plating is durable because chromium is a very poor reducing agent. 9 A. True B. False 0043 0931002 B 12 14144 51 11670161021809 Nitrogen reacts with hydrogen more rapidly at moderate temperatures than at high ones. 9 A. True B. False 0043 0931003 B 12 14146 31 00360468019609 Water gas consists of a mixture of steam and hydrogen. 9 A. True B. false. 0043 0931004 B 12 14148 31 14860056104009 Sulfuric acid is produced in greater quantity than any other chemical. 0040 9 A. True B. False 0931005 B 12 14150 31 14860006 09 Cl is used extensively in fertilizer production. 4 2 9 A. True B. False 0040 0931006 A 12 14152 31 14860164039409 Chlorination of hydrocarbons is the main market for chlorine. 9 A. True B. False 0040 0931007 B 12 14154 31 14860215046109 Steel_making is the dominant consumer of NaOH. 9 A. True B. False 0040 0933001 CABB 43 14155 52 033602300335149006 MACROITEM STEM 2Glass is a solid material of great hardness and amazing stability 2that is made by fusing a batch of dry, powdered, or granular 2inorganic chemical compounds. Usually, 60% or more of sand with 2various percentages of two or more oxides of Na, Ca, K, Pb, Mg, and 2Al is heated in a refractory container, until a bubbling syrup 2is formed at a blinding white heat by the mutual solution of the 2metal oxides. Heating is continued at a lower temperature until 2the bubbles disappear and the syrup becomes homogeneous. Then, 2if the formula is a good one, if the melting or fusing has been 2correct, and if the cooling is done properly, the syrup will 2stiffen continuously from its liquid or molten state at about 22700 degrees F. to a hard, rigid solid at room temperature without 2any crystallization taking place. 2Soda_lime glasses are used for 90 per cent of all glassware. Their 2raw materials are the least expensive and they are among the 2easiest to melt and shape. 2Lead oxide is a good fluxing agent and in percentages of 20 and 40 2it can replace most or all of the lime and some of the soda or 2alkali content. This gives glasses greater sparkle and makes 2them easier to cut and engrave. They are used to make fine 2tableware and art_glass. About 1758, John Colland realized that the 2higher index of refraction of a lead glass, that accounts for its 2higher sparkle and luster, makes possible compound lenses that are achromatic. 2Fused quartz or fused silica glass (99.8% silica) can be made by 2fusing a batch consisting solely of quartz crystals or of sand 2(impure crystals of quartz). in this type, unfortunately, the 2fusing or melting temperature is as high (about 3150 degrees F.) 2as that of the crystalline raw materials. This requires special ETS2 OS 2melting methods and the molten glass is so viscous that it is 2difficult to make it homogeneous and free of bubbles. 2Borosilicate glasses are a type in which the melting point of 2the silica is lowered by the addition of boric oxide, b2o3, and in smaller amount alumina, Al O , with only the smallest possible 4 23 2amount of alkali. It is intrinsically superior to corrosion and to 2breakage from heat shock, but is more difficult to manufacture and 2work. Borosilicates have ample margin of heat shock resistance, 2some of which can be sacrificed in making articles that are 2thicker walled and thus mechanically stronger. 296% Silica glasses were developed by corning in 1939. first, the 2article is formed from a conventional borosilicate glass. Then a 2heat treatment causes the glass to separate into two 2intermingled glassy phases. One phase contains nearly all of the 2alkalies and can be leached out by hot acids to leave a sponge_like 2glass containing 96% silica and 3% B O . The leached glass is so 3 23 2refractory that subsequent heating can close the pores completely 2without any change of the shape of the article even though there is 2a linear shrinkage of about 14%. These glasses can be used at a red 2heat and plunged into ice water repeatedly without cracking. 2The following questions are to be answered after reading the above 2paragraphs and in reference to the following key. 2 A. The statement is true and the reason supports the truth of it. 2 B. The statement is true but the reason does not support the 2 truth of it. 0 C. The statement is false. MACRO SUB_ITEM # 1 Glass is a chemical compound because, at a blinding white heat, any two substances react to form a compound. At ordinary temperature, glass could be called a solid_liquid 1 because its molecules are scattered about as in liquids. MACRO SUB_ITEM # 2 2 In the manufacture of glass, the batch is heated to 2700 degrees F. MACRO SUB_ITEM # 3 Lead glass lenses are used in optical instruments because 3 of their high sparkle. MACRO SUB_ITEM # 4 Borosilicate glasses are used for most heat_resistant glass ware (such as pyrex ovenware) because they are the only heat_resistant glasses that can be produced by conventional mass production 9 into two intermingled glassy phases by heat treatment. 0933002 B 12 14207 31 17031704115909 0041 TNT is a form of gunpowder. 9 A. True B. False 0933003 A 12 14208 31 14860218104409 Explosives very commonly contain nitrogen. 9 A. True B. False 0040 0933004 B 12 14209 31 09640066001409 Dynamite is a compound of carbon, nitrogen, and oxygen. 9 A. True B. False 0041 0933005 B 12 14211 31 13341604026109 Carbon dioxide is obtained commercially by fractional distillation of air. 9 A. True B. False 0009 0935001 C 13 14213 31 0635 An optical brightener works to brighten clothes by A. bleaching them B. reflecting visible light 9 C. absorbing UV light and reemitting visible light. 0026 0941001 A 12 14216 51 03500066002009 Silicon tends to form compounds in which its valence is 4. 9 A. True B. False 0041 0941002 A 12 14218 51 06850879078109 In silicate structures, each silicon atom is linked to four oxygen atoms. 9 A. True B. False 0041 0941003 A 12 14220 52 0350008609 The only common rock in which silicon is not an important constituent is limestone. 9 A. True B. False 0041 0941004 A 12 14222 51 06851171 Most silicates are relatively insoluble. 9 A. True B. False 0041 09 0941005 B 12 14223 51 00160010068509 The most important aluminum ores are complex aluminum silicates such as felspar. 9 A. True B. False 0941006 A 12 14225 31 1798 0043 0003 The face_centered cubic unit cell consists of 14 points. 9 A. True B. False 0943001 A 12 14227 51 056606870590 Ozone is an excellent absorber of ultraviolet radiation. 9 A. True B. False 0041 0950001 A 13 14229 31 00251118 What happens to the bod of a stream as the temperature of the water goes up? 9 A. increases B. decreases C. no change. 0026 0950002 B 13 14231 31 05540025 What happens to the amount of dissolved oxygen as the temperature of a stream increases? 9 A. increases B. decreases C. NO change. 0026 0950003 C 13 14233 31 00230008 The mechanism by which fluoridation of water is affective appears to be, A. killing of bacteria B. the adjustment of pH SO that enzymes may work better in oxidation of organic wastes 5 _ C. incorporation of F ions into tooth structures such as 9 calcium hydroxyphosphate. 0026 0950004 B 13 14238 31 063205180672 Which has the greatest potential as a fuel for man's needs? 9 A. petroleum B. atomic fusion C. atomic fission. 0026 0950005 B 12 14240 31 00080541148609 Bodies of water tend to moderate climatic temperatures. 9 A. True B. False 0040 0950006 B 12 14242 31 Natural waters are often pure. 9 A. True B. False 00081486 0950007 B 12 14243 The pH of pure water is 8. 9 A. True B. False 14860091000809 31 09 0950008 A 12 14244 31 14860261064609 In the CO cycle in nature, plants use CO and give up O . 4 2 2 2 0040 0040 0040 9 A. True B. False 0950009 A 12 14246 31 03210325117209 As one moves up in the atmosphere, the ratio [O]/[O ] 4 2 increases. 9 A. True B. False 0951001 A 13 14248 31 11250343 The formula for tetraethyllead is A. (CH ) Pb B. (C H ) Pb C. Pb(CO) . 94 34 254 4 0009 0026 0951002 A 12 14250 51 14740008151509 A high B.O.D. suggests that a water supply is contaminated with organic wastes. 9 A. True B. False 0009 0951003 B 12 14252 31 14861104039309 Pb compounds in gasoline give rise to the greenhouse effect. 9 A. True B. False 0040 0951004 A 12 14254 31 14861099018709 The NO photolytic cycle results in the production of secondary 4 2 pollutants. 9 A. True B. False 0040 0951005 B 12 14256 31 14860187021809 Nitrogen_containing fertilizer is the main source of NO 4 x 0040 9 pollution. A. True B. False 0951006 A 12 14259 31 14860214026109 Thermal exhaust reactors convert CO to CO . 4 2 9 A. True B. False 0040 0951007 B 12 14261 31 Ozone is a primary pollutant. 9 A. True B. False 0040 14860566099909 0951008 B 12 14262 31 14860999021809 No natural mechanisms exist to get rid of any air pollutants. 0040 9 A. True B. False 0951009 A 12 14264 51 14861478109909 PAN is both a secondary air pollutant and a photochemical oxidant. 9 A. True B. False 0040 0951010 A 12 14266 31 14860214103409 CO is removed from the air by soil microorganisms. 9 A. True B. False 0040 0951011 A 12 14268 31 14860057041409 The burning of coal is the leading source of SO emissions. 4 2 9 A. True B. False 0040 0951012 A 12 14270 31 14861717008609 Limestone is attacked by certain particulate pollutants. 9 A. True B. False 0040 0951013 B 12 14272 31 14860214099909 CO is the most toxic of the common air pollutants. 9 A. True B. False 0040 0951014 B 12 14274 31 14861112061709 Thermal pollution is involved with radioactive ("hot") atoms. 9 A. True B. False 0040 0951015 B 12 14276 31 14861050025109 NTA has undergone extensive study as a replacement for DDT. 9 A. True B. False 0040 0951016 B 12 14278 31 14861050007309 The effects of DDT on birds relates to eggs with shells so thick that they do not hatch. 9 A. True B. False 0040 0951017 B 12 14280 31 14861119105009 Eutrophication is the process by which substances like DDT and Hg are concentrated in the food chain. 9 A. True B. False 0040 0951018 A 12 14282 31 14860025171809 The BOD content of sewage would be expected to be relatively high. 9 A. True B. False 0040 0951019 B 12 14284 31 14861112002509 The two plant nutrients of prime importance in water pollution are P (phosphorus) and O (oxygen). 9 A. True B. False 0040 0951020 A 12 14286 31 14860675111209 Oil pollution has serious long_term effects. 3 _________ 9 A. True B. False 0040 0951021 B 12 14288 31 14861116103309 Coliform bacteria are the main disease_causing agents in water. 9 A. True B. False 0040 0951022 B 12 14290 31 14860008059009 Radiation levels in water are increasing. 9 A. True B. False 0040 0951023 A 12 14291 31 14860018070109 Some inorganic pollutants cause salinity problems. 9 A. True B. False 0040 0951024 A 12 14293 31 14860488001809 Salt can kill growing plants because of the osmosis process. 9 A. True B. False 0040 0951025 B 12 14295 31 03400064032109 Helium is the most abundant noble gas in the atmosphere. 9 A. True B. False 0009 0953001 A 12 14297 51 10131516151709 Branched_chain detergents are more readily broken down in nature than those with straight chains. 9 A. True B. False 0009 0962001 B 12 14299 51 1677 0286 A thermocouple is a device for conducting heat from one location to another. 9 A. True B. False 0962003 A 12 14301 51 10761930 09 The sensitivity of an equal arm balance depends upon the masses suspended from the beam. A. True 9 B. False 0041 0962004 A 12 14303 51 10761930 09 The sensitivity of an analytical balance does not depend upon the position of the zero adjust dial of the balance. A. True 9 B. False 0962005 B 12 14305 51 10761930 09 The sensitivity of a single pan analytical balance depends upon the mass of the sample being weighed. A. True 9 B. False 0962006 A 12 14307 51 10761930 09 The single pan analytical balance has constant sensitivity because the same mass is suspended from the balance beam in all weighings. A. True 9 B. False 0962007 B 12 14310 51 10761930 09 When a weight is dialed on a single pan analytical balance, that number of grams is added to the balance beam on the side opposite the sample pan. A. True 9 B. False 0962008 A 12 14313 51 10761930 09 When a weight is dialed on a single pan analytical balance, that number of grams is removed from the balance beam on the side from which the sample pan hangs. A. True 9 B. False 0962009 B 12 14316 51 10761930 09 When an object is weighed on a double pan balance, one removes weights from the weight pan equal to the weight of the object. The beam is then balanced at zero. A. True 9 B. False 0962010 A 12 14319 51 10761930 09 When an object is weighed on a double pan balance, one adds weights to the weight pan until the beam arm is balanced at zero. A. True 9 B. False 0962011 B 12 14322 51 10761930 09 On a double pan balance, one can perform two weighings at the same time, one in each pan. A. True 9 B. False 0962013 A 12 14324 51 10761930 09 The single pan balance is so designed that the same mass (within 0.1 g) is suspended from the balance beam in all weighings. A. True 9 B. False 0962014 B 12 14327 51 10761930 09 When you make a weighing on a single pan analytical balance, the recommended procedure is to dial the smallest weights first and the largest weights last. A. True 9 B. False 0962015 B 12 14330 51 10761930 09 When a single pan analytical balance is used to make a weighing, the balance is set in full release, the sample is then placed on the sample pan, and weights are dialed. A. True 9 B. False 0962016 A 12 14333 51 10761930 09 When a single pan analytical balance is used to make a weighing, weights of 0.1 gram or larger are dialed with the beam in partial release. A. True 9 B. False 0962017 A 12 14336 51 10761930 09 When an analytical balance is in full release, the beam from which the pan is suspended is fully able to swing freely. A. True 9 B. False 0962018 A 12 14338 51 10761930 09 When a single pan analytical balance is used, weights of 1 gram or larger should never be dialed with the beam in full release. A. True 9 B. False 0962019 B 12 14341 51 10761930 09 When a sample is weighed on a single pan analytical balance, weights of 1 gram or larger should never be dialed with the beam in partial release. A. True 9 B. False 0962020 B 12 14344 51 10761930 09 When a single pan analytical balance has all dials set at zero, the beam has NO weights suspended from it. A. True 9 B. False 0962021 A 12 14346 51 10791930 09 When an equal arm double pan analytical balance is zeroed, the difference in masses suspended from the two arms of the beam is zero. A. True 9 B. False 0962022 A 12 14349 51 10791930 09 Before beginning a weighing, an analytical balance must be zeroed with the zero adjust knob. Before this is done, the weight dials must be set at zero. 9 A. True B. False 0962023 A 12 14352 51 1079 09 The mass of an object is measured by comparing the force of gravity on it to the force of gravity on an object of known mass. A. True 9 B. False 0962024 A 12 14355 51 10791930 09 Beam arm error is A. present only in the equal arm double pan balance. B. present only in the single pan analytical balance. C. present in all types of balances. 9 D. not present in any balance. 0962025 B 12 14358 51 10791930 09 5 _4 To weigh an object to a precision of 10 gram, one could use a triple beam balance. 9 A. True B. False 0962026 A 12 14361 51 10791930 09 4 _4 To weigh an object to a precision of 10 gram, one could use a single pan analytical balance. A. True 9 B. False 0970001 B 12 14364 32 00081486095909 Water has its maximum density at 0 degrees C. 9 A. True B. False 0970002 A 12 14365 31 14860125 Silver metal is a good conductor of electricity. 9 A. True B. False 09 0040 0040 0970003 B 12 14367 31 14860125079909 The tarnish on silverware is a thin coating of black Ag O. 4 2 9 A. True B. False 0040 0970004 A 12 14369 31 14860125079909 Silver tarnish is a chemical compound. 9 A. True B. False 0040 0970005 B 12 14370 31 14860039 09 Gold is generally found in nature in compounds with other elements. 9 A. True B. False 0040 0970006 B 12 14372 31 Pure gold is a very hard metal. 9 A. True B. False 0040 14860039 09 0971001 A 12 14373 51 00161323145409 Rubies are composed principally of aluminum oxide. 9 A. True B. False 0971002 B 12 14375 51 084609 The simplest of the known boron hydrides is BH . 4 3 9 A. True B. False 0043 0043 0971003 B 12 14377 51 01610218029309 Only at very high temperatures does nitrogen form an N molecule. 4 4 9 A. True B. False 0043 0971004 A 12 14379 31 05540806159109 When P O is dissolved in (excess) water, the final product 4 4 10 is H PO . 4 3 4 9 A. True B. False 0971005 B 12 14381 31 0293 09 NO , N O , and NO are all odd molecules. 4 2 24 9 A. True B. False 0043 0043 0971006 A 12 14383 31 00771627 09 Nitrous acid undergoes slow disproportionation. 9 A. True B. False 0043 0971007 B 12 14385 31 1774116709 White phosphorus is sometimes stored under kerosene, in order to prevent it from reacting with air. 9 A. True B. False 0043 0971008 A 12 14387 51 0674019209 Red phosphorus is a polymeric substance. 9 A. True B. False 0043 0971009 A 12 14388 31 00350196 09 The +1 oxidation state is more common than the _1 state for hydrogen. 9 A. True B. false. 0043 0971010 A 12 14390 31 0808040809 Silver chloride is less soluble in water than sodium chloride. 9 A. True B. false. 0043 0971011 A 12 14392 31 13940192080809 Nonpolar substances are not very soluble in water. 9 A. True B. false. 0043 0971012 A 12 14394 31 01650351019609 In ice every oxygen atom is bound to four hydrogen atoms. 9 A. True B. false. 0043 0971013 B 12 14396 Ozone is paramagnetic. 9 A. True B. false. 31 05660768 09 0971014 B 12 14397 31 04980025021809 The normal boiling point of oxygen is lower than that of nitrogen. 9 A. True B. false. 0043 0043 0971015 B 12 14399 31 00070566 09 Although O is a more powerful oxidizing agent than O , it is 4 3 2 a slower_acting one. 9 A. True B. false. 0043 0971016 A 12 14402 31 Hydrogen peroxide is an acid. 9 A. True B. false. 0043 10750077 09 0971017 A 12 14403 31 10751367162709 Hydrogen peroxide exhibits disproportionation. 9 A. True B. false. 0971018 B 12 14405 31 01690237 Sodium oxide is a covalent solid. 9 A. True B. false. 09 0043 0043 0971019 A 12 14406 31 08080008 09 One would not expect FePO to be very soluble in water. 4 4 9 A. True B. false. 0043 0971020 A 12 14408 31 SO is an acidic anhydride. 4 2 9 A. True B. false. 0043 00770804 09 0971021 A 12 14409 31 00750808000809 Many hydroxides are not very soluble in water. 9 A. True B. false. 0043 0971022 A 12 14411 31 00080045000209 Water is capable of oxidizing sodium metal. 9 A. True B. False 0043 0971023 A 0043 12 14412 31 00660344080809 Most compounds of potassium are quite soluble in water. 9 A. True B. False 0971024 A 12 14414 51 00870002 09 A solution prepared by adding sodium to liquid ammonia contains negative ions which are apparently solvated electrons. 9 A. True B. False 0043 0971025 B 12 14416 31 00870138132309 A solution prepared by adding K O to water contains a high 4 2 concentration of oxide ions. 9 A. True B. False 0043 0971026 B 12 14418 51 18321173183309 Plaster of paris may be prepared by adding water to gypsum. 9 A. True B. False 0043 0971027 B 12 14420 31 01730008 09 Permanent hardness may be removed by adding Ca(OH) to the water 4 2 9 A. True B. False 0043 0971028 A 12 14422 31 14860787005609 The conversion of SO to SO is a step in the production of 4 2 3 H SO . 42 4 9 A. True B. False 0040 0971029 B 12 14424 31 14860787005609 The S used as a starting material for H SO production is usually 4 2 4 obtained from H S in the atmosphere. 4 2 9 A. True B. False 0040 0971030 A 12 14427 31 14860109002509 Use of pure O instead of air results in a five_fold increase in 4 2 oxygen concentration. 9 A. True B. False 0040 0971031 B 12 14429 31 14860025 09 Commercial production of O involves electrolysis of H O. 4 2 2 0040 9 A. True B. False 0971032 A 12 14431 31 NH is a form of fixed nitrogen. 4 3 9 A. True B. False 14860218 09 0040 0971033 B 12 14432 31 14861525007209 The Haber process is used to produce Cl . 4 2 9 A. True B. False 0040 0971034 B 12 14434 31 14860072117009 The source of H needed for ammonia manufacture is sea water. 4 2 9 A. True B. False 0040 0971035 A 12 14436 31 14860215041309 Sodium hydroxide production often involves the use of mercury. 9 A. True B. False 0040 0971036 A 12 14438 31 14861330084809 5 _ The active ingredient in a bottle of bleach is the OCl ion. 9 A. True B. False 0040 0971037 A 12 14440 31 14860852081709 At least one allotrope of carbon conducts electricity. 9 A. True B. False 0040 0971038 B 12 14442 31 14860817002409 The allotropic form of phosphorus called red phosphorus is very toxic. 9 A. True B. False 0040 0971039 B 12 14444 31 14860817035009 Silicon shows the property of allotropy. 9 A. True B. False 0040 0971040 A 12 14445 31 14860817028409 Allotropes are different forms of the same element. 9 A. True B. False 0040 0971041 B 12 14447 31 14860024 All forms of phosphorus are poisonous. 9 A. True B. False 09 0040 0971042 A 12 14448 31 14860024081709 Phosphorus exists in at least two allotropic forms. 9 A. True B. False 0040 0971043 B 12 14450 31 14860350033609 No substance is known which will dissolve or react with glass. 9 A. True B. False 0040 0971044 B 12 14452 31 14860589001409 The main use of diamonds (by weight) is in jewerly. 9 A. True B. False 0040 0971045 B 12 14454 31 14860024 09 The bones of animals are unhealthy if they contain any phosphorus. 9 A. True B. False 0971046 A 12 14456 31 14860817001409 Carbon possesses the property of allotropy. 9 A. True B. False 0973001 A 12 14457 51 11780087 09 The ferric ion may be detected in solution by adding potassium thiocyanate. 9 A. True B. False 0040 0040 0043 0973002 A 12 14459 51 00370844000709 Compounds of +3 nickel are powerful oxidizing agents. 9 A. True B. False 0043 0973003 A 12 14461 51 17600061007509 Cobaltous hydroxide is a basic hydroxide. 9 A. True B. False 0043 0973004 B 12 14462 51 00320017008709 5 2+ Copper metal will reduce Fe in solution. 9 A. True B. False 0043 0973005 B 12 14464 51 11780012 The cobaltic ion will reduce H O. 4 2 9 A. True B. False 09 0043 0973006 A 09 0043 12 14466 51 11710008 AgCl and CuCl are both rather insoluble in water. 9 A. True B. False 0973007 B 12 14468 51 14480039117809 The oxidation potential of gold (to form the aurous ion) is highly positive. 9 A. True B. False 0043 0973008 B 12 14470 51 05541578002109 When HgS is dissolved in aqua regia, the mercury becomes 5 _ oxidized by the NO in the aqua regia. 4 3 9 A. True B. False 0043 0973009 A 12 14473 51 00870215055409 5 2+ Adding a solution of NaOH to a solution containing Zn produces a precipitate, which redissolves upon addition of excess NaOH. 9 A. True B. False 0043 0973010 B 12 14476 51 11690087023609 5 + Addition of NH to a solution containing Ag produces a black 4 3 precipitate. 9 A. True B. False 0043 0973011 A 12 14479 51 00890089 Mercuric chloride is a weak electrolyte. 9 A. True B. False 09 0043 0973301 B 12 14480 51 05040560006109 The +6 state of manganese is not stable in basic solution. 9 A. True B. False 004 0973302 A 12 14482 51 13310087001209 5 _ 2+ When MnO is reduced in acidic solution, Mn is produced. 4 4 9 A. True B. False 0043 0973303 A 12 14484 51 00450077008709 5 +3 2_ Cr may be oxidized to Cr O by H O in acid solution. 0043 4 9 A. True B. False 27 22 0983001 B 12 14487 51 15731574037909 The technique of activation analysis is limited to those elements that have naturally radioactive isotopes. 9 A. True. B. False. 0983002 A 12 14489 31 05781486 A mass spectrometer can be used to determine the charge_to_mass ratio of positively charged particles. 9 A. True B. False 1000002 ACAABA 64 14491 32 0272027880011290 MACROITEM STEM 2To answer the following questions, mark space 2 A. if the statement has been proved by experiment or observation 2 B. if the statement is theoretical or hypothetical 2 C. if the statement is a definition 2 D. if the statement has been proved false by experiment or 0 observation MACRO SUB_ITEM # 1 1 Heat is the kinetic energy of rapidly moving molecules. MACRO SUB_ITEM # 2 The acceleration of a body is equal to the time rate of change of 2 velocity. MACRO SUB_ITEM # 3 3 The mass of a hydrogen atom is 100 times that of an electron. MACRO SUB_ITEM # 4 An electric current may be produced in a coil of wire by moving 4 a magnet into the coil. MACRO SUB_ITEM # 5 The number of molecules in a liter of any gas is the same as the 5 number in a liter of any other gas under the same conditions. MACRO SUB_ITEM # 6 9 Wave motion transmits energy. 1000003 ABAD 44 14501 52 0021008180011190 MACROITEM STEM 2To answer the following items, select the most appropriate response 2from the key. 2 A. The second cannot occur unless the first has occured or is 2 occuring. 2 B. The first usually but not necessarily occurred before the 2 second. 2 C. The second usually but not necessarily occured before the 0009 0003 ETS2 OS ETS2 OS 2 first. 2 D. There is NO relationship between the occurence of the first 0 and the second. MACRO SUB_ITEM # 1 1 Oxidation_spontaneous combustion MACRO SUB_ITEM # 2 2 Solution in water_dissociation of ions MACRO SUB_ITEM # 3 3 Gaseous ions_discharge of an electroscope MACRO SUB_ITEM # 4 9 Rubbing with silk or fur_magnetization 1000004 CABBA 54 14509 32 0272027802811290 MACROITEM STEM 2To answer the following questions, mark space 2 A. if the statement has been proved by experiment or observation 2 B. if the statement is theoretical or hypothetical 2 C. if the statement is a definition 2 D. if the statement has been proved false by experiment or 0 observation MACRO SUB_ITEM # 1 1 The mass of 1 cc of water at 4 degrees C is one gram. MACRO SUB_ITEM # 2 2 The pressure of a gas is due to the motion of the molecules. MACRO SUB_ITEM # 3 The gravitational attraction is the same at all places on the 3 surface of the earth. MACRO SUB_ITEM # 4 4 The number of different kinds of atoms is limited. MACRO SUB_ITEM # 5 9 The earth's diameter is greater at the equator than at the poles. 1100001 BDA 35 14517 31 0257025880011290 MACROITEM STEM 2To answer the following questions, choose from the key list the 2term most closely related to the statements. 2 A. catalysis 2 B. hydrolysis 2 C. electrolysis 2 D. diffusion 0 E. dialysis MACRO SUB_ITEM # 1 A reaction in which a normal salt reacts with water to form 1 either an acidic or basic solution MACRO SUB_ITEM # 2 2 Mixing of two substances by molecular motion ETS2 OS ETS2 OS MACRO SUB_ITEM # 3 Changing the rate of a reaction by using a substance that remains 9 unchanged after completion of the reaction 1110001 D 15 14523 31 096109620963 Which of the following is not considered a valid reason for studying chemistry? A. The need to be aware of the effect of chemistry on each citizen and his environment B. The need to consider changes that may result as new chemical knowledge is obtained C. The need to know some of the important products that have resulted from chemical explorations D. The realization that chemistry is the answer to all the world's problems 9 E. The need to think rigorously and with logic 0018 1110002 C 14 14530 31 1702 One formula_unit of Na SO contains: 4 2 4 A. 1 mole of Na SO B. 1 gram_atom of sulfur 4 2 4 9 C. one atom of sulfur D. 1 mole of sodium 0003 1110003 B 14 14533 31 One molecule of HCl: A. contains 1 g of H 5 _23 B. weighs 6.06 x 10 g C. weighs 36.461 g 9 D. contains 1 mole of Cl 0003 0703 1110004 B 14 14536 31 0706 The product of the pressure and the volume of a fixed weight of ideal gas is: A. constant B. directly proportional to the temperature C. inversely proportional to the temperature 9 D. approximately constant 1110005 D 14 14539 52 07060186 The density of methane (CH ) at 2.00 atm pressure and 248 K is: 4 4 is: A. 26.0 g/liter B. 0.260 g/liter 9 C. 0.130 g/liter D. 1.30 g/liter 0003 0003 1110006 B 14 14542 31 0498 At a given pressure the boiling point is the same as the A. freezing point B. liquefaction point 9 C. critical temperature D. triple_point temperature 0003 1111101 C 15 14545 32 8003 Multiplying 75 x 273 x 600 gives 3 ___ ___ 300 750 9 A. 91 B. 91/125 C. 273/5 D. 273 2WVW E. none of these 1111102 A 15 14548 32 8003 What percent of $12.50 is 25 cents? 9 A. 2 B. 1/5 C. 5 D. 20 E. 200 2WVW 1111103 C 15 14550 32 8003 x divided by x equals 9 A. 0 B. x C. 1 D. 0.5x E. 2x 2WVW 1111104 E 15 14551 32 y_y equals 9 A. _2y B. 2y C. 1 D. y 8003 2WVW 1111105 E 15 14552 6 _ r equals 3_ _ n n A. 6r 3 __ 5 2 N B. 6n _ rn C. 6_r 3 ___ 2n D. 6 _ r 3 _____ 5 2 N 9 E. none of these 32 8003 2WVW 1111106 A 32 8003 2WVW _2 2 10 x 10 15 14555 E. 0 3__________ equals 4 _3 10 x 10 5 3 3 9 A. 1/10 B. 1/10 C. 10 _8 D. 1/10 E. 1/3 1111107 D 15 14558 32 The product of _7 and zero is A. _7 B. 7 C. _1 D. 0 9 E. none of these 8003 2WVW 1111108 C 8003 2WVW 15 14560 32 5 2 3 4 Multiplying x , x and x gives 5 24 9 A. x 24 B. 3x 9 C. x 9 D. 3x E. 9x 1111109 B 15 14562 32 8003 On a given map, one_fourth of an inch represents a distance of one mile. How long is a line which represents 12 miles (in inches)? 9 A. 1/3 B. 3 C. 36 D. 48 E. None of these 2WVW 1111110 E 15 14565 32 8003 The amount of money that will buy d dozen eggs at c cents per dozen will buy how many pounds of potatoes at e cents per pound. 9 A. dce B. ce/d C. de/c D. d(c+e) E. None of these 2WVW 1111111 A 15 14568 32 8003 How many kilograms are there in 242 pounds (1 kilogram = 2.2 pounds) 9 A. 110 B. 11 C. 0.009 D. 532.4 E. None of these 2WVW 1111112 B 15 14570 32 5 1/2 Simplifying 2 + 12 gives 3 ___________ 2 2 1/2 A. 1 + 2 x (3 ) 2WVW 1/2 B. 1 + 3 8003 1/2 C. 6 9 1/2 D. 12 E. none of these 1111113 D 15 14574 32 8003 A store advertised that the price of an article had been reduced 30% and the new selling price was 98 cents. What was the original price? A. $0.69 B. $1.27 C. $1.31 D. $1.40 9 E. none of these 2WVW 1111114 C 15 14577 32 8003 The number of cubic feet in a rectangular tank 8 inches by 15 inches by 10 feet is 9 A. 1200 B. 100 C. 25/3 D. 25/36 E. None of these 2WVW 1111115 D 2WVW 15 14579 32 8003 5 2 2 What is the value of x _ y if x = 3 and y = 1 3 _______ 2y _ 3x 9 A. _2 B. _64/7 C. 8/3 D. _8/7 E. 64/3 1111116 E 15 14582 32 8003 The outer diameter of a pipe is 3.257 inches and the inner diameter is 2.635 inches. What is the thickness of the pipe wall, in inches? A. 2.946 B. 0.301 C. 0.622 D. 1.882 9 E. none of these 2WVW 1111117 A 15 14585 32 8003 7 1/2 is 3/4 of 5/6 of what number? 9 A. 12 B. 1/12 C. 75/16 D. 16/75 2WVW 1111118 D 15 14587 32 8003 When y is 9% of x and y = 18, then x equals E. 75/9 2WVW 9 A. 162 B. 1.62 C. 2 D. 200 E. none of these 1111119 C 15 14589 32 8003 From a rectangle of length a and width b, squares of side x are cut out at the four corners. Find the area remaining 2WVW 5 2 2 A. (a_2x ) (b_2x ) B. (a_2x) (b_2x) 5 2 C. ab _ 4x 5 2 D. 4x _ ab 9 E. none of these 1111120 D 15 14593 32 Given a = p + prt, then r equals A. a _ p _ pt B. a _ p 3 __ pt C. a 3 __ p+pt D. a _ p 3 _____ pt E. a _ pt 3 _ 9 p 8003 2WVW 1111121 B 15 14596 5 _1/3 Simplifying _27 gives A. 1 3 _ 3 B. _ 1 3 _ 3 C. 9 8003 2WVW 32 5 3 D. _27 E. 1 3 _____ 5 9 3 27 1111122 A 15 14599 32 8003 A mixture is to be made of two substances a and b in the proportion seven parts of a to 13 parts of b. What percent of the mixture is b? A. 65 B. 54 C. 35 D. 19 9 E. none of these 2WVW 1111123 D 15 14602 32 8003 If a number, when divided by d, gives quotient q and remainder r, then the number is A. d + rq B. q + r 3 _ d C. q + rd D. dq + r 9 E. qrd 2WVW 1111124 C 15 14605 32 8003 How many cents are there in d dollars, q quarters, and t dimes? A. d + q + t B. d + q + t 3 ___ __ __ 100 25 10 C. 100d + 25q + 10t D. dqt 9 E. none of these 2WVW 1111125 A 15 14608 32 8003 When the simultaneous equations 3x + 5y = 9 2x _ y = _7 are solved, the value of y is A. 3 B. _2 C. _ 3 2WVW 3 _ 7 D. _ 3 3 __ 13 E. 25 9 13 1111126 C 15 14612 32 8003 The surface area of a cube is 294. Find the length of one edge. 5 1/3 A. 294 5 3 B. (294) C. 7 5 1/2 D. 294 9 E. None of these 2WVW 1111127 B 15 14615 32 8003 A diagonal of a square is 50. Find the length of a side. A. 25 5 1/2 B. 25 X 2 5 1/2 C. 25 x 3 5 1/2 D. 25 x 5 9 E. none of these 2WVW 1111128 D 15 14618 32 8003 If the weight of a box containing n apples is a, and the weight of the empty box is b, what is the average weight of six apples? A. 6n (a_b) 5 a B. (6_b)/n C. 6na _ b D. 6 (a _ b) 3 _ n 9 E. none of these 2WVW 1111129 D 15 14622 32 8003 The radius of a circle is r inches. By how many inches would the circumference be increased if the radius were increased 3 inches? A. 6 2WVW 9 B. 6 pi r C. 6r D. 6 pi E. none of these 1111130 D 15 14625 32 8003 5 2 The surface area S of a sphere is given by the formula S=4 pi r where r is the radius. What is the effect on S if r is reduced by 50%? A. reduced by 25% B. reduced by 50% C. reduced by 75% D. reduced by 200% 9 E. none of these 2WVW 1111131 E 15 14630 32 8003 If y = a sin 0 and x = b cos 0,then it is necessarily true that 3 / / 2WVW 5 2 2 2 2 A. x + y = a + b 5 2 2 B. x + y __ __ = 1 5 2 2 a b C. xy = ab D. y = tan 0 3 _ / x 9 E. none of these is necessarily true 1111132 C 15 14635 32 If py _ rq = y (r + p), then p = 3 _______ qx A. (qr + xy)/y B. 2qr/x C. qr(xy + 1) 3 __________ y _ qxy D. qr(1 _ xy) 3 __________ y (1 _ qx) 8003 2WVW 9 E. none of these is correct 1111133 C 15 14638 32 90 2In the study of the physical sciences it is frequently necessary 2to proceed from a verbal statement to a symbolic representation of 2this statement. Show that you can do this with the following statements (assume k and k' to be constants). under certain conditions, the product of the pressure (P) and volume (V) is proportional to the absolute temperature (T). A. PV = T B. P + V = T C. PV = kT D. PVT = 1 9 E. PV = kT + k' 2WVW 1111134 B 15 14644 32 8003 The effective wavelength, w, of a beam of electrons is inversely proportional to the square root of the mean kinetic energy of the electrons, E. 5 1/2 A. (wE) =k 5 1/2 B. w x E =k C. w = 1 3 ______ 5 1/2 E 5 9 1/2 D. w =k+1 _____ E E. none of these is correct 1111135 B 15 14650 32 8003 The atomic number of an atom is equal to A. the charge on the atom B. the number of protons in the nucleus C. half the atomic weight of the atom D. the number of electrons in the valence shell 9 E. the number of neutrons in the atom 1111136 E 15 14654 32 An aqueous sodium chloride solution conducts electricity better 2WVW 2WVW than does a solution containing an equal concentration of acetic acid because A. acetic acid reduces the dissociation of water markedly B. all acids are poor conductors in aqueous solution C. concentrated solutions conduct better than dilute solutions D. organic compounds never ionize at all 9 E. many more ions are present in the salt solution 1111137 B 15 14660 32 8003 Isotopes of nitrogen differ in the number of A. protons C. charged particles E. electrons 9 B. neutrons D. deuterons 2WVW 1111138 B 15 14663 32 8003 The fact that sulfur is a non_metal implies that it is A. monatomic B. a poor conductor of electricity C. malleable D. easily oxidized 9 E. able to displace hydrogen from an acid solution 2WVW 1111139 D 15 14666 32 8003 The term "acid" is used chemically to refer to A. anything which tastes sour B. any compound which contains hydrogen atoms C. any substance which has or can furnish hydrogen atoms D. any substance which has or can furnish hydrogen ions 9 E. any substance which can accept hydrogen ions 2WVW 1120001 D 14 14670 51 15100317 The strongest of the four fundamental interactions is the A. gravitational B. weak nuclear 9 C. electromagnetic D. strong nuclear 0041 1120002 A 14 14672 51 15100317 The weakest of the four fundamental interactions is the A. gravitational B. weak nuclear 9 C. electromagnetic D. strong nuclear 0041 1120003 C 14 14674 51 151009850627 The interaction primarily responsible for the formation of atoms from nuclei and electrons is the A. gravitational B. weak nuclear 9 C. electromagnetic D. strong nuclear 0041 1120004 C 0042 15 14677 32 180504451646 Considering significant figures, what is the total weight of a series of beakers which weigh 125.2 gm, 90.3 gm, 56.2 gm, and 20.237 gm respectively? 5 2 A. 2.91 x 10 gm, B. 292 gm, C. 291.9 gm, D. 291.937 gm, 9 E. 291.23 gm. 1120005 D 15 14681 32 18050288 Pay attention to significant figures and solve the problem: 35.00 + 1.02 4 ________________ = ? 5 2 (3.0) 9 A. 4 B. 4.002 C. 0.120 D. 4.0 0042 E. 12 1120006 B 15 14684 32 01950150 What is the volume of a box which is 200 mm x 10.0 cm x 0.400 m? 0028 A. 10.0 liters B. 8.00 liters C. 800 milliliters 9 D. 1000 milliliters E. 2000 milliliters 1120007 E 15 14687 31 096112870588 A study of chemistry can include a study of A. matter B. pesticides C. dyes D. photography 9 E. all of these 0020 1120008 C 15 14689 31 096103820014 Organic chemistry is A. the study of organisms B. the study of metallic compounds C. a study of compounds containing carbon D. a branch of quantitative analysis 9 E. a minor branch of biology 1120009 B 15 14692 31 026902040961 The science dealing with the composition of materials and the changes in composition which these materials undergo is A. biology B. chemistry C. physics D. mathematics 9 E. all of these 0020 0020 1120010 B 15 14695 32 1301 0020 5 _7 The number 1.23 x 10 is A. 00.12300 B. 0.000 000 123 C. 0.000 000 0012 23 D. 0.000 001 23 9 E. 0.000 012 3 1120011 D 15 14698 32 5 _2 8.80 cm plus 1.36 x 10 cm is 9 A. 8.94 cm B. 10.16 cm C. 8.93 cm 0020 D. 8.81 cm E. 8.8136 cm 1120012 E 15 14700 32 5 _7 5 3.80 X 10 times 5.60 x 10 is 5 1 2 A. 2.13 x 10 B. 0.00213 C. 0.0213 D. 2.13 x 10 9 E. none of these 1120013 C 15 14703 32 1302 5 _8 8 5.60 X 10 divided by 2.80 x 10 is 5 16 _16 0 A. 2.0 B. 2.0 x 10 C. 2.0 x 10 D. 2.0 x 10 9 E. none of these 1120014 E 15 14706 32 13031302 5 5 _5 _3 The results of (1.0 x 10 )(2.0 x 10 ) divided by 2.0 x 10 is 5 _3 3 _3 A. 100 B. 2.0 x 10 C. 2.0 x 10 D. 1.0 x 10 5 3 9 E. 1.0 x 10 1120015 C 15 14710 31 054501140798 The inflation of an automobile tire to a pressure of "20 pounds" means: 5 2 A. the pressure exerted by the air in the tire is 20 lb/in B. the weight of the air in the tire is 20 pounds 5 2 C. the pressure of the air in the tire is 20 lb/in higher than the air pressure outside the tire 0020 0020 0020 0009 5 9 2 D. the pressure of the air inside the tire is about 5 lb/in E. the mass of the air is 20 lb. 1120016 B 14 14718 5 2.699 10 equals A. log 2.699 B. 500 C. 2.699 log 10 9 D. 699. 52 19441827 0055 1120017 D 14 14720 52 19441805 The number of significant figures in 0.002060 is A. six B. two C. three 9 D. four 0055 1120018 A 14 14722 52 19441950 By experiment, a student found 39.08% of oxygen in KClO . The 4 3 theoretical percentage is 39.17%. The percent of experimental error is calculated as follows: A. (39.08 _ 39.17)100/39.17 B. (39.08 _ 39.17)100/39.08 C. (39.08 _ 39.17)100 9 D. (39.17 _ 39.08)100 0055 1120019 B 14 14727 52 194416540398 The weight of an object w, is equal to the product of its mass m, and the acceleration due to gravity a, (w = ma). if w is in dynes 5 _2 and a is in cm sec , then m is in 5 _2 A. dyne cm sec 5 2 _1 B. dyne sec cm 5 _1 2 _1 C. dyne sec cm 5 _1 _2 9 D. dyne sec cm 0055 1120020 C 14 14732 52 19441328 5 _6 The multiple 10 is denoted by the prefix A. mega B. milli C. micro 9 D. nano 0055 1120021 B 14 14734 52 1944 The number of chirps per minute made by a cricket is temperature dependent as follows: deg F = 0.25 (chirps/min) + 39.0. If a cricket chirps 144 times per minute the Fahrenheit temperature is 9 A. 36 B. 75 C. 105 D. 114 0055 1120022 D 15 14738 72 1955 A solid lead sphere is 1 cm in diameter. A second solid lead sphere is 2 cm in diameter. The mass of the second sphere is how many times that of the first? 9 A. 2 B. 3.14 C. 4 D. 8 E. 16 0062 1122001 C 15 14741 52 The number 134537.5, expressed to three significant figures is: 5 5 5 9 A. 134. B. 135. C. 1.35x10 D. 1.34x10 1122002 BDA 35 14744 52 MACROITEM STEM Maria says to Gwenda, "I have four experimental values for the atomic weight of chlorine. They are: 36.7665, 33.7762, 34.9112 and 35.8726." Gwenda determines the average and says to Maria, "Your precision 0 is much better than your accuracy. MACRO SUB_ITEM # 1 On the basis of this information, it can be concluded that A. Gwenda is correct in her assessment of Maria's data. B. Gwenda is incorrect in her assessment of Maria's data because Maria's accuracy is better than her precision. C. Gwenda is incorrect in her assessment of Maria's data because 1 Maria's precision is just about equal to her accuracy. MACRO SUB_ITEM # 2 Maria's average deviation for these four results is (in atomic mass units) 2 A. 0.1 B. 0.3 C. 0.5 D. 1 E. 2 MACRO SUB_ITEM # 3 OS OS Maria would be justified in reporting her average atomic weight to how many significant figures? 9 A. 2 B. 3 C. 4 D. 5 E. 6 1122003 BDE 35 14756 52 MACROITEM STEM The atomic weight of aluminum is determined five times. The results of these trials are shown below: Trial 1 26.872 Trial 2 26.849 Trial 3 26.867 Trial 4 26.844 Trial 5 26.853 OS83 0 If the accepted value of the atomic weight of Al is 26.982, then MACRO SUB_ITEM # 1 it can be concluded from these data that A. the accuracy of these determinations is significantly greater than the precision. B. the precision of these determinations is significantly greater than the accuracy. C. the precision and accuracy are about the same. D. the precision and accuracy are not the same, but one is not 1 significantly greater than the other. MACRO SUB_ITEM # 2 Based on the precision of these measurements, the experimental value for the atomic weight of aluminum should be reported to ____________ significant figures. 2 A. 1 B. 2 C. 3 D. 4 E. 5 MACRO SUB_ITEM # 3 Of the five experimental values, the one which seems to deviate from the mean because of an effect other than random experimental error is A. 26.872 B. 26.849 C. 26.867 D. 26.844 9 E. none of them. They seem to be fairly evenly distributed. 1122004 B 15 14771 52 071101 A mixture is prepared by mixing 7.65 g of A and 6.95 g of B. The total weight of the mixture can be reported to ______ significant figures. The ratio, wt of A/wt of B, in the mixture can be reported to ______significant figures. The difference, A _ B, can be reported to _____significant figures. The numbers required to fill the blanks are, respectively, 0064 9 A. 3,3,3 B. 4,3,2 C. 4,3,3 D. 4,4,3 E. none of these 1122005 D 15 14777 52 071101 Two samples were weighed using different balances sample (1) = 3.529 g and sample (2) = 0.40 g. How should the total weight of the samples be reported? 9 A. 3.929 g B. 3 g C. 3.9 g D. 3.93 g E. 4 g 0064 1122006 C 15 14780 52 071101 A 0.060_g sample of Al wire was found to weigh 56.0 mg after treatment with hydrochloric acid. How should the percent weight loss be reported? 9 A. 6.7% B. 15% C. 7% D. 6.67% E. 10% 0064 1122007 D 15 14783 52 071101 Which of the following contains 4 significant figures? A. 0.0005 g B. 0.0050 mL C. 0.0500 m D. 0.5000 cm 9 E. all of these 0064 1122008 C 15 14785 52 071101 Add 5.17 g, 0.251 g and 0.0023 g. The answer to the correct number of digits after the decimal point is 9 A. 5.4233 g B. 5.423 g C. 5.42 g D. 5.4 g E. 5 g 0064 1122009 D 15 14788 52 071101 Two samples were weighed using different balances sample (1) = 3.529 g and sample (2) = 0.40 g. How should the total weight of the samples be reported? 9 A. 3.929 g B. 3 g C. 3.9 g D. 3.93 g E. 4 g 0064 1122010 D 15 14791 52 071101 Which of the following masses is reported to four significant figures? 5 _4 A. 2.0110 mg B. 17.4 x 10 g C. 0.0020 g 5 4 9 D. 3.030 kg E. 3 x 10 g 0064 1122011 B 15 14794 52 071101 A mixture of X and Y weighing 14.00 g is found to contain 13.50 g of X. The percentage of Y (by weight) in this mixture should be reported to ____significant figure(s). 9 A. one B. two C. three D. four E. eight 0064 1122012 E 15 14797 52 071101 The density of the element gold, Au, is to be calculated from the 0064 following data Mass of a golden coin = 13.512 g Volume of the coin and water = 25.1 ml Volume of the water alone = 24.4 ml The density of the metal in the coin should be reported as A. 19.303 g/ml B. 19.30 g/ml C. 19.3 g/ml D. 19 g/ml 5 1 9 E. 2 x 10 g/ml 1122013 B 13 44559 31 Maria says to Gwenda, "I have four experimental values for the atomic weight of chlorine. They are: 36.7665, 33.7762, 34.9112 and 35.8726." Gwenda determines the average and says to Maria, "Your precision is much better than your accuracy." On the basis of this information, it can be concluded that A. Gwenda is correct in her assessment of Maria's data. B. Gwenda is incorrect in her assessment of Maria's data because Maria's accuracy is better than her precision. C. Gwenda is incorrect in her assessment of Maria's data because 9 Maria's precision is just about equal to her accuracy. 1122014 B 15 45148 71 How many significant figures are there in the value 2,100,100? 9 A. 7 B. 5 C. 4 D. 3 E. 2 1122015 D 15 45150 71 What is the best answer to report for the following: 2.521 x 13.51 _____________ + 0.31 2.78 4 9 A. 12.5613 B. 12.561 C. 12.56 12.6 E. 13 1122016 B 15 45154 71 The age of a wooden artifact was determined by carbon_14 dating. Three different measurements gave values of 6295, 4815, and 5485 years. Its age would best be reported as (in years): 9 A. 5531.7 B. 5532 C. 5530 D. 5500 E. 5000 1123001 E 15 14802 52 071101 If you could count individual atoms at the rate of one atom per second, about how many years would be required to count 0064 5 23 6.02 x 10 atoms? 5 2 3 9 A. 10 B. 10 9 C. 10 12 D. 10 16 E. 10 1124001 C 15 45158 51 Which of the following is NOT an SI unit? 9 A. meter B. kilogram C. angstrom D. pascal E. joule 1128001 ADE 35 14806 72 1977 90 MACROITEM STEM A determination of the atomic weight of chlorine is carried out five times. The values obtained are 35.436,35.440,35.445,35.458 0 and 35.493. MACRO SUB_ITEM # 1 If the accepted atomic weight of chlorine is 35.453, A. the accuracy of this series of trials is significantly greater than the precision. B. the precision of this series of trials is significantly greater than the accuracy. C. the accuracy and the precision of this series of trials are about the same. D. no judgment regarding the accuracy or precision of this series of trials can be made, as the mean of the measurements is much too low. E. no judgment regarding the accuracy and precision of this series of trials can be made, as the mean of the measurements is 1 much too high. MACRO SUB_ITEM # 2 The experimental value from this series of measurements should be reported to _____ significant figures. 2 A. 1 B. 2 C. 3 D. 4 E. 5 MACRO SUB_ITEM # 3 Of the five experimental values, the one which appears to deviate from the mean because of an effect other than random experimental error is 9 A. 35.436 B. 35.440 C. 35.445 D. 35.458 E. 35.493 1128002 D 15 14821 52 Michele asks Ivan, "Did you weigh our sample yet?" Ivan replies, "Yes, I weighed it on each of three top loading Mettler balances. Here are my results." Balance 1 2 3 Mass of sample 1.206 g 1.237 g 1.285 g OS OS82 Michele says, "Do you mind if I weigh it once again?" From this brief conversation, one could conclude that the MOST reasonable explanation for Michele's request is that A. the Mettler balances have scales accurate only to 0.1 g, so Ivan could not have achieved his reported results. B. Only with four weighings can one safely assume that accurate results will be achieved. C. Ivan should have used the Centogram balance, because it would have produced more precise results. D. The agreement between the three values should be better than it is, even if one uses separate Mettler balances. 9 E. Only one balance should have been used for this weighing. 1128003 DBCA 45 45743 51 MACROITEM STEM A solution is known to have a concentration of 0.1126+0.0002 M HCl 3 _ Five students carry out a standardization of the solution using Na CO and report the following values: 4 2 3 Student Sample 1 Sample 2 Sample 3 A. Juliet 0.1129 M 0.1184 M 0.1106 M B. Brian 0.1120 M 0.1118 M 0.1124 M C. Michael 0.1104 M 0.1109 M 0.1116 M D. Shelley 0.1100 M 0.1115 M 0.1163 M E. Tramy 0.1118 M 0.1123 M 0.1130 M 0 Of these five reports, which exhibits MACRO SUB_ITEM # 1 1 the highest accuracy? MACRO SUB_ITEM # 2 2 the highest precision? MACRO SUB_ITEM # 3 3 the lowest accuracy? MACRO SUB_ITEM # 4 9 the lowest precision? 1200001 B 15 14834 31 02790269028011 Galileo considered his sciences to be "new" in the sense that they A. take into account the facts of nature B. deal with phenomena never before investigated C. avoid abstractions and adhere to inductions from observations D. involve novel and original uses of mathematical proof E. rest upon application of mathematical methods to physical 9 principles heretofore unknown ETS2 OS 1200002 E 15 14840 52 02920293800111 Avogadro's suggestion that in some elements molecules might be identical with atoms but that in other elements as well as in compounds, each molecule might consist of several atoms, is a good example of A. a conceptual scheme which could not be directly tested or proved B. a hypotheses that had some truth in it but, in general, had little consequence C. a conceptual scheme that had an immediate application D. a concept that had no practical use 9 E. a hypothesis that led directly to new knowledge 1200003 DDAEDCDDA95 14847 32 0271027380011190 MACROITEM STEM 2The following questions should be answered in accordance with the 0 opinions and point of view expressed by Conant. MACRO SUB_ITEM # 1 The significance of Toricelli's experiment for those studying the methods of science lies in the fact that A. it can be easily and quickly duplicated in any laboratory B. it can be readily verified C. it is a broad hypothesis or conceptual scheme D. it is simple evidence of one consequence of a broad hypothesis or conceptual scheme to a pressing problem of 1 the day MACRO SUB_ITEM # 2 One of the reasons why the phlogiston hypothesis was not accepted for over a hundred years was that A. scientists of that day were less intelligent than modern scientists B. gases were commonly believed to have zero or negative weight C. scientists of that day were not really good observers D. men were too set in their ways to accept the theory of oxidation E. a better theory could not have been formulated until Dalton's 2 atomic theory became known MACRO SUB_ITEM # 3 According to Conant, the rebirth of the idea of air as an elastic medium is an example of A. a concept arising from an experiment B. a limited working hypothesis C. an experiment giving rise to deduced consequences D. a limited working hypothesis arising from a concept 3 E. none of these MACRO SUB_ITEM # 4 ETS2 OS ETS2 OS 4 5 6 7 8 Conant believes that A. few if any hypotheses on a grand scale can be directly tested B. unlike hypotheses, conceptual schemes can be directly tested C. unlike conceptual schemes, most hypotheses on a grand scale can usually be tested directly D. hypotheses on a grand scale are tests of conceptual schemes E. both hypotheses on a grand scale and conceptual schemes can usually be tested directly MACRO SUB_ITEM # 5 According to Conant, the idea that Galileo used to explain the failure of pumps to raise water more than 34 feet was that A. nature abhors a vacuum B. mechanical defects existed in all pumps C. water is incompressible D. a water column, like a long wire, breaks under a stress E. atmospheric pressure was a causal factor MACRO SUB_ITEM # 6 select the one condition which contributes least toward the development of a conceptual scheme. A. The time must be ripe for scientific discovery to be effective. B. Scientific variables must be controlled. C. A previous accepted conceptual scheme which already explains the phenomena. D. The adoption of ad hoc (special or for this purpose only) assumptions to support theories. E. The use of deductive experimentation or tests. MACRO SUB_ITEM # 7 Avogadro's hypothesis concerning the relationship between volumes of gases and the number of particles or molecules they contain is now considered a A. generalization B. conceptual scheme C. discarded hypothesis D. law E. fruitful hypothesis MACRO SUB_ITEM # 8 The concept of atmospheric pressure A. was proved by the simple process of deductive reasoning B. depended upon the presence of a funiculus C. could never have arisen without a knowledge of Gay Lussac's law D. led Boyle into a series of fruitful experiments dealing with vacuums E. proves that nature abhors a vacuum 9 MACRO SUB_ITEM # 9 their contemporaries 1200004 D 15 14889 32 01530281800112 The lowering of the temperature of a liquid by evaporation was probably first discovered by A. deducing the consequences of the kinetic theory B. controlled experimentation C. speculation D. observation 9 E. inductive reasoning 1200005 CECA 45 14893 52 0304007780011290 MACROITEM STEM 2The following questions refer to Lavoisier's experiments with 0 muriatic acid. MACRO SUB_ITEM # 1 Of the following methods, Lavoisier would best support his contention that the acidity of muriatic acid is due to the presence of oxygen by A. showing that oxygenated muriatic acid is stronger than muriatic acid itself B. showing that all other oxygen_containing substances are acidic C. showing that other substances are capable of uniting with a sufficient amount of oxygen to form acids D. preparing muriatic acid by combining a non_acidic or weakly_ acidic substance with oxygen 1 E. isolating oxygen as a decomposition product of muriatic acid MACRO SUB_ITEM # 2 The subsequent discovery that muriatic acid contains no oxygen A. invalidates the criteria by which Lavoisier identified acids B. excludes muriatic acid from the class of acids C. necessitates postulating another element as the cause of acidity D. makes this one exception necessary to the theory that oxygen is the cause of acidity E. invalidates the oxygen theory of acidity but retains the 2 criteria by which acids are recognized MACRO SUB_ITEM # 3 Lavoisier states, we cannot have the slightest doubt that it (muriatic acid), like all other acids is composed by the union of oxygen with an acidifiable base. This statement may be best characterized as A. a tentative hypothesis designed to guide further investigation B. a redefinition of the term "acid" in terms of observables ETS2 OS ETS2 OS C. a conclusion arising from similarity of properties of muriatic acid and oxygen_containing acids D. an inference from experimental data on muriatic acid E. a necessary consequence of the theory that all substances 3 containing a maximum amount of oxygen are acids MACRO SUB_ITEM # 4 In view of the subsequent finding that muriatic acid contains no oxygen, which of the following comments is best justified? A. Lavoisier erred in basing conclusions on qualitative rather than quantitative data. B. Lavoisier violated his own precepts by making hypotheses. C. Lavoisier's error demonstrates the need of an atomic theory as a guiding principle. D. To the extent that a scientist may feel it unnecessary to prove all highly probably conclusions, Lavoisier was justified. E. Lavoisier's entire scheme of classification is invalid, since 9 it contains a false assumption. 1200006 BBCE 45 14925 32 0304010980011290 MACROITEM STEM 2The following items refer to Lavoisier's experiments with 0 mercury to determine the composition of air. MACRO SUB_ITEM # 1 In Lavoisier's determination of the composition of air, the experiment in which mercury was calcined in the presence of a restricted amount of air is best considered to be A. a complete analysis of the air B. a step in an analysis of the air C. a step in a synthesis of the air D. a complete synthesis of the air 1 E. simultaneous analysis and synthesis of the air MACRO SUB_ITEM # 2 The subsequent experiment in which the red calx of mercury was heated in the absence of air is best considered to be A. a complete analysis of the air B. the final step in a partial analysis of air C. the final step in a partial synthesis of air D. the final step in a complete synthesis of the air 2 E. none of the above MACRO SUB_ITEM # 3 The heating of the red calx of mercury can also be looked on as A. an analysis of the mercury B. a synthesis of the mercury C. an analysis of the mercuric calx D. a synthesis of the mercuric calx ETS2 OS 3 E. a part of the synthesis of the mercuric oxide MACRO SUB_ITEM # 4 In terms of Lavoisier's criteria for adequate chemical evidence, proof that ordinary air is composed of the two parts, "mephitis" and "highly" respirable air, requires that Lavoisier A. use no more than the results of the experiments mentioned in the previous questions B. prove that "mephitis" and "highly" respirable air cannot themselves be separated into any more substances C. show that no substance other than air is composed of "mephitis" and "highly" respirable air. D. show that "mephitis" and "highly" respirable air can each be obtained from other compound substances, although not necessarily from the same compound substances E. show that when "mephitis" and "highly" respirable air only are combined in the proportions in which they were obtained 9 from air, the mixture behaves in all ways as air 1200007 C 14 14951 31 056106168004 In some cases Moseley found that the variation in the wave lengths of x_rays between two successive elements was twice as great as his conclusions justified. He concluded that A. the atomic weight of the first element was incorrect B. the atomic weights of the second element was incorrect C. the element was misplaced in the periodic table 9 D. the existence of an inert gas was indicated 1200008 CBE 35 14957 52 0323032480011390 MACROITEM STEM 2Davy found that the combining volumes of oxygen with 100 volumes of 0 nitrogen are 49.5, 108.9 and 204.7. MACRO SUB_ITEM # 1 From these results Gay_Lussac concluded that the volume ratios are 2:1, 1:1, and 1:2. What justification did Gay_Lussac have for such a conclusion? A. The measured values are closer to these simple ratios than to any others. B. Combination in definite proportions had already been established; simple volume ratios are, therefore, to be expected. C. The other gas reactions studied showed similar clusterings of data around simple ratios. D. Although subsequent measurements justified the conclusion, these data do not justify it. 1 E. Natural laws take the simplest possible forms. MACRO SUB_ITEM # 2 2 OS ETS2 OS Rayleigh found that the density of nitrogen isolated from air is about 0.47% greater than that of nitrogen prepared by chemical means. May this difference be regarded as significant? A. Only if two kinds of nitrogen gas are assumed to exist B. Only if this difference is much larger than the experimental error involved C. Only if the experimental error is considered to be zero D. Any discrepancy among related data must be regarded as significant 2 E. This difference is too small to have any real significance MACRO SUB_ITEM # 3 In view of your answers to the preceding two items, what general statement may be made as to the criteria for significance of deviations in experimental data? A. The point at which deviations are great enough to be considered significant are arbitrarily decided by each investigator concerned. B. Deviations of less than 1% may be attributed to experimental error but greater deviations are real. C. Deviations may be considered significant only if they reappear in a great many similar measurements. D. The only criterion is whether or not the best theory available can account for such deviations. E. The significance of deviations is determined by the precision 9 of measurement. 1200009 D 15 14984 52 02650312800111 In order to help determine the existence of a degree of order and organization in a constantly changing environment, certain methods of investigation have been emphasized especially in connection with the studies on physical and chemical changes and the derivation of two of the gas laws. These methods are A. obtaining data, classifying the data, and then placing it on graphs B. identification, recognition and classification of dynamic relationships between quantities C. identification of all variables involved, then keeping one variable fixed while others are varied one after another D. direct and inverse comparisons of observed differences E. application of external agents, careful observation of results, and formulation of hypotheses leading to fruitful 9 investigations ETS2 OS 1200010 D 15 14995 31 04830293800111 The Brownian movement was so named because a man named Brown noticed that finely divided solid particles suspended in a ETS2 OS liquid moved about continuously. He attributed this to A. convection currents in the liquid B. electrical forces of attraction and repulsion C. chemical activity between the substances D. molecular movement of liquid particles 9 E. Newton's law of universal gravitation 1200011 C 15 15001 71 0189 05 Which of the following elements was NOT named for a geographical area? 9 A. Francium B. Thulium C. Samarium D. Copper E. Ruthenium 1200012 B 14 15003 31 018906638004 An element discovered by the use of the spectroscope is A. lithium B. cesium C. potassium 9 D. sodium 2 OS 1200013 B 14 44866 31 019501138004 The statement, "Equal volumes of all gases, under the same conditions of temperature and pressure, contain the same number of molecules, is credited to A. Gay_Lussac C. Berthollet E. Dalton 9 B. Avogadro D. Proust 2 OS 1200014 D 14 45640 31 018906068004 An element whose discovery was not predicted by Mendeleev is A. scandium C. gallium E. they were all predicted by 9 B. germanium D. helium Mendeleev 2 OS 1200015 C 15 15010 31 018502630580 The charge on the electron was originally determined by A. using Avogadro's principle. B. measuring the equivalent conductance of ions. C. Millikan's oil_drop experiment. D. hysteresis measurements. 9 E. alpha_particle bombardment. 0042 1200016 C 15 15014 31 079702680757 Which name_idea association is incorrect? A. Mendeleev_periodic table B. Moseley_atomic number C. De Broglie_uncertainty principle D. Pauli_exclusion principle 9 E. Rutherford_alpha particle scattering. 0042 1200017 E 15 15017 51 141402680272 Each of the following statements describes the significance of a certain key experiment or idea. Which one is not correct? 3 ___ A. J. J. Thomson used a primitive mass spectrometer to measure the charge_to_mass ratio of the electron. Subsequently R. A. Millikan's oil drop experiment provided a value for the electronic charge. B. The solution to the Schroedinger wave equation for the hydrogen atom does not exactly specify the electron's position but only the probability of finding the electron in a given region of space. C. Einstein explained the photoelectric effect by applying Planck's idea of the quantization of radiant energy to the ionization of atoms. D. Rutherford's experiment on the scattering of alpha particles showed that the mass of the nucleus is concentrated in a very small volume. E. Roentgen discovered x_rays and noted that they were deflected by electric and magnetic fields and therefore 9 were beams of charged particles. 0044 1200018 D 15 15032 51 036103510357 Bohr proposed a theory of atomic structure for the hydrogen atom that was influenced by Rutherford's nuclear model of the atom, the quantum hypothesis and the experimental results of atomic spectroscopy. Which of the below statements is not a correct 3 ___ statement of some aspect of Bohr's theory? A. The energy of the electron in the hydrogen atom depends on only one quantum number, the principle quantum number, n. B. The radius of the hydrogen atom in the ground state (n=1) is 0.529 angstrom. C. The energy of the electron in the hydrogen atom is restricted to certain quantized values, given by 5 2 E = _k/n (n=1,2,3,4,...), where k is a constant D. Although the theory worked well for hydrogen and other atoms of low atomic number, it failed to explain the spectra 5 + 2+ of ions such as He or Li . E. The Rydberg constant used to calculate the frequencies of the lines in the hydrogen spectrum could be precisely calculated from independently determined physical constants (Planck's constant, mass of electron, and 9 charge of electron). 0044 1200019 D 15 15049 31 060609640965 Who was responsible for the discovery of dynamite? 9 A. Dalton B. Kekule C. Meyer D. Nobel E. Curie 0018 1200020 C 15 15051 31 018906060440 In which of the following time periods were the greatest number of elements discovered? A. 1600_1700 B. 1700_1800 C. 1800_1900 D. 1900_1930 9 E. 1930_1975 0040 1200021 D 15 15054 31 Alchemy probably began in the A. 4th century B.C. B. 1st century B.C. C. 1st century A.D. D. 4th century A.D. 9 E. 8th century A.D. 1650 0034 1200022 D 15 15057 31 1651 0474 The first generally accepted scheme of our physical and biological world was formulated by A. Plato. B. Thales of Miletos C. Socrates 9 D. Aristotle E. Democritus 0034 1200023 C 15 15060 31 16501472 To the alchemists, the transmutation of metals into gold was a process that required A. changing the basic composition of the metal B. changing the properties of the metal C. changing the aristotelian qualities of the metal D. purifying the metal 9 E. changing the atomic structure of the metal 0034 1200024 E 15 15065 31 1652 0008 The concept that the primary basis of all nature was water was announced by A. Aristotle B. Lavoisier C. Priestly D. Plato 9 E. Thales of Miletos 0034 1200025 C 15 15068 31 0513 The 17th century (A.D.) saw the rise of A. deductive logic B. inductive logic C. the atomic theory 9 D. the law of conservation of mass E. all of the above 1200026 B 15 15071 31 030302900043 0034 0034 The Phlogiston theory failed in its inability to explain A. the qualitative changes which occurred on combustion B. the weight changes that occurred during combustion C. the phenomenon of respiration D. the "improvement" in the quality of the air when mercury oxide is heated E. the "reduction" of metal oxides to the metal on heating with 9 charcoal 1200027 A 15 15076 31 03030304 The overthrow of the Phlogiston theory is due primarily to 9 A. Lavoisier B. Priestly C. Cavendish D. Franklin E. Dalton 1200028 A 15 15078 31 0114 The inability to pull apart the Magdeburg hemispheres was due to A. the external pressure exerted on the hemispheres B. the fact that nature abhors a vacuum C. the vacuum in the hemispheres holds them together D. the hemispheres were too large 9 E. all of the above 1200029 B 15 15082 31 04330114 The column of mercury in a Torricelli barometer is held up by A. the upward pull of the vacuum in the space above the mercury B. the downward pressure of the air on the pool of mercury C. the attraction between the mercury and the glass tubing wall D. all of the above play a role in holding up the mercury column 9 E. none of the above 0034 0034 0034 1200030 D 15 15087 31 04330321 A mercury barometer placed on the moon would A. be higher than on earth because of the lower gravity B. be lower than on earth because of the lower gravity C. be higher because of the absence of a gaseous atmosphere D. be lower because of the absence of a gaseous atmosphere 9 E. be the same as on earth 0034 1200031 A 15 15092 31 02920113 Avogadro realized that events involving gases at the macroscopic level (gas laws, combining volumes, etc.) could be interpreted in terms of A. events at the molecular level B. collisions between the molecules in the gas C. the sizes of the individual molecules 5 23 D. the number 1.06 x 10 0034 9 E. the kinetic molecular theory 1200032 C 14 15097 31 16500039 The alchemists were: A. early physicians B. French chemists at the time of the revolution C. primarily interested in making gold from base metals 9 D. the men who first developed the scientific method 0041 1200033 B 15 15100 71 1966 Which of the following elements was not named for a 3 ___ geographical location? 9 A. Lutetium B. Indium C. Erbium D. Magnesium OS E. Holmium 1200034 D 15 15103 71 1966 Each option below contains three elements. All elements in one set are named for objects in space. That set is ______. A. Uranium, Selenium, Cesium B. Thorium, Mercury, Krypton C. Cerium, Neptunium, Promethium D. Phosphorus, Palladium, Tellurium 9 E. Plutonium, Helium, Thorium OS 1200035 E 15 15107 71 1966 Each option below is followed by a set of three elements. One set contains elements all of which are named for geographical areas. Which set is that? A. Thulium, Osmium, Lutetium B. Iodine, Holmium, Europium C. Yttrium, Gallium, Lanthanum D. Samarium, Francium, Magnesium 9 E. Americium, Copper, Hafnium OS 1200036 B 15 15112 31 19661469 ________ hypothesized that it is impossible to know both the exact location and the exact momentum of an object at the same time. 9 A. Planck B. Heisenberg C. Pauli D. Bohr 1200037 D 15 15115 51 Which element is not named after a person? 9 A. Fermium B. Gadolinium C. Curium D. Tellurium E. Nobelium 1220001 BB 25 15117 MACROITEM STEM 32 0304030380011390 NGLS MSU ETS2 OS 2Answer the following questions concerned with the Phlogiston 0 theory MACRO SUB_ITEM # 1 A theory widely held in Lavoisier's time was that combustion consisted in the escape of a material substance, Phlogiston, from a burning material into the surrounding atmosphere. By which of the following assumptions can the Phlogiston theory best account for the fact that a wax candle burns only for a short time in a closed jar, but can be burned again if the jar is opened? A. The amount of Phlogiston in the wax is limited. B. The atmosphere can become saturated with Phlogiston. C. Part of the Phlogiston is in stable combination with the wax. D. Phlogiston is repelled by the atmosphere under certain conditions. E. The pressure of the surrounding atmosphere is necessary in 1 order to expel the Phlogiston. MACRO SUB_ITEM # 2 Which of the following observations is most difficult to explain on the basis of the statements given above about the Phlogiston theory? A. Air in which mercury is heated decreases in volume. B. Combustion of some substances results in an increase in weight; combustion of others, in a decrease. C. Air in which mercury is heated is rendered unfit for breathing. D. Air in which the red calx of mercury is strongly heated supports combustion more vigorously than does ordinary air. E. If a candle is burned in a closed vessel, the total weight 9 of the contents does not change. 1220002 E 15 15136 32 03220304800113 On mixing the mephitic air with vital air in the proportion of 73 to 27, Lavoisier obtained a gas precisely similar to atmospheric air in all its properties, how can this result, taken by itself, be reconciled with the Phlogiston theory? A. By postulating an excess of Phlogiston in mephitic air and a deficiency in vital air. B. By identifying vital air as Phlogiston and mephitic air as dephlogisticated air. C. By postulating that mephitic air is pure Phlogiston. D. No reconciliation is necessary since the rival theories agree on the interpretation of this result. E. No reconciliation is possible; this result is incompatible 9 with the Phlogiston theory. ETS2 OS 1220003 A ETS2 OS 15 15146 32 03010302800114 According to the Phlogiston theory, when wood burns its ashes weigh less than the original wood, and the decrease in weight may be reasonably interpreted as the weight of the Phlogiston which has escaped. When a metal is heated, however, the resulting powder weighs more than the original metal. In terms of the Phlogiston theory, this would seem to indicate that A. Phlogiston could also have a negative weight, so that its escape would therefore make a substance heavier B. Burning is a different chemical process than that which is involved in the heating of a metal until it changes into a powder C. While burning liberates Phlogiston, heating a metal attracts Phlogiston D. In burning a substance some of the Phlogiston which is present is consumed as the product of combustion, while in heating a metal Phlogiston combines with the metal to form scale 9 E. More than one of these could account for the results 1220004 B 15 15159 32 00590303800112 When a large jar is placed over a lighted candle, the candle burns for a few minutes and then goes out. On the basis of the Phlogiston theory, this would suggest that A. all the Phlogiston in the air was consumed by the burning candle B. the air in the jar became saturated with Phlogiston C. the air in the jar becaue too hot to receive Phlogiston D. carbon dioxide produced by the burning candle extinguished the flame E. this is a phenomenon that could not be explained by the 9 Phlogiston theory ETS2 OS 1220005 C 15 15167 52 03038001001514 We no longer accept the Phlogiston hypothesis of combustion because prediction does not agree with observation in one of the 3 ___ following instances. A. Combustion of a substance results in a new substance being formed. B. New properties may appear when a substance is burned. C. When a metal is burned Phlogiston is expelled from it, resulting in a loss of weight. D. Metals can be recovered from their ores by heating with charcoal. E. A substance heated in a limited amount of air is only 9 partially burned. ETS2 OS 1300001 B 14 15175 31 A hydrated proton is called a A. deuterium B. hydronium ion C. hydroxide ion 9 D. hydrogen ion 019080040255 2 OS 1300002 B 14 15177 31 007001928004 The term ionization is correctly used with substances which A. are electrovalent B. form polar molecules C. are hygroscopic 9 D. form macromolecules 2 OS 1300003 D 14 15180 31 010905158004 On exposure to air a deliquescent substance A. oxidizes B. crystallizes C. loses water of hydration 9 D. becomes moist 2 OS 1300004 C 14 15182 31 040708068004 A reaction in which the products possess more energy than the reactants is A. an isothermic reaction B. reversible reaction C. endothermic reaction 9 D. exothermic reaction 2 OS 1300005 C 14 15185 31 022400668004 The simplest formula for a compound is A. the correct formula B. the molecular formula C. the empirical formula 9 D. the atomic formula 2 OS 1300006 B 14 44453 31 007300948004 When calcium metal reacts with elemental sulfur, the compound formed is calcium A. sulfate B. sulfide C. sulfite D. thiosulfate 9 E. persulfate 2 OS 1300007 B 14 15190 31 006601891296 Which of the following compounds contains only two elements? A. sodium sulfate B. potassium chloride 9 C. potassium nitrate D. magnesium carbonate 0041 1300008 E 15 15193 32 081217951507 In which case is the symbol of the nuclide accurately described? 0042 5 1 A. H is isotopic with hydrogen_1, 4 1 5 65 B. Cu is an isobar of copper_65 4 29 5 19 F has Z=19, 4 9 5 80 D. Br will have 36 electrons when ionized so as to possess 2 4 35 negative charges, C. 5 E. 4 9 37 Cl when mixed with 77% of chlorine_35 will provide an 17 average atomic weight of 35.45 for the mixture. 1300009 A 15 15200 31 079701920705 What is the name of a substance whose empirical formula is LiH? A. lithium hydride B. lithium hydrate C. lithium amide 9 D. lithium hydroxide E. none of these is correct. 1300010 D 15 15203 31 02241178 Write the formula of the hydrogen carbonate ion. 5 2_ _ _ 2_ A. H CO , B. HCO , C. H CO , D. HCO , E. HCO 94 2 3 3 2 4 3 3 1300011 B 15 15206 31 0224 The correct formula of calcium hydroxide is: A. Ca(OH) B. Ca(OH) C. Ca (OH) D. CaOH 94 2 2 2 0042 0042 . 0042 E. Ca(OH) . 3 1300012 A 15 15209 31 132803510094 The "thio" prefix indicates that an atom of sulfur has replaced 0042 an atom of 9 A. oxygen B. chlorine C. hydrogen D. nitrogen E. carbon 1300013 D 14 15211 51 17611178 The ferricyanide ion is: 5 6_ 4_ 6_ A. Fe(CN) B. Fe(CN) C. Fe(CN) 94 4 6 3 0043 3_ D. Fe(CN) 6 1300014 D 14 15214 51 0457 The following is not an alum: A. KAl(SO ) .12H O B. NH Al(SO ) .12H O 4 42 2 4 42 2 C. NH Cr(SO ) .12H O D. Al (SO ) .18H O 94 4 42 2 2 43 2 0043 1300015 D 14 15217 31 1769 Carborundum is: A. CaC B. Fe C C. CaCO D. SiC. 94 2 3 3 0043 1300016 A 14 15219 31 019212540695 Compounds with the same molecular formula but different structures are called: 9 A. isomers B. polymers C. esters D. isotopes E. allotropes 1300017 D 14 15221 31 08790094 Although the details of the structure of monoclinic sulfur are not all known, it probably consists of: A. S chains B. S molecules C. S rings D. S rings. 94 8 2 4 8 0043 0043 1300018 D 14 15224 31 0094 It is known that rhombic sulfur consists of: A. S chains B. S molecules C. S rings D. S rings. 94 8 2 4 8 0043 1300019 A 14 15227 51 0077 Hypobromous acid is: A. HOBr B. HOBrO C. HOBrO D. HOBrO 94 2 3 0043 1300020 C 15 15229 31 0115 Sodium stearate is a component of 9 A. table salt B. sand C. soap D. margarine E. detergent 0047 1300021 D 14 15231 32 0081 The number of syllables in the word dissociation is: 9 A. 8 B. 7 C. 6 D. 5 1300022 D 14 15233 31 022408130176 The formula of anhydrous copper sulfate is: A. CuSO .5H O B. Cu(H O) SO .H O C. Cu(H O) SO 94 4 2 2 4 4 2 2 4 4 0043 0043 D. CuSO 4 1300023 A 15 15236 31 07970037 Select the proper set of names for the following four compounds: 1. Cu(CN) 2. Sn(ClO ) 3. Fe (SO ) 4. AgCl 4 2 34 2 33 2 A. 1. copper(II) cyanide 2. tin(IV) chlorate 3. iron(III) sulfite 4. silver(II) chloride B. 1. curium(II) cyanide 2. tin(IV) chlorate 3. iron(III) sulfate 4. gold(II) chloride C. 1. copper(II) cyanide 2. tin(IV) perchlorate 3. iron(III) sulfite 4. silver(II) chloride D. 1. curium(II) cyanide 2. tin(IV) chlorate 3. iron(III) sulfite 4. silver(II) chloride. 9 E. None of the above. 0044 1300024 B 15 15245 31 07970037 Which of the following four compounds is incorrectly named? 3 ___________ A. TiSe B. Na C O C. V(ClO ) D. AlPO 4 2 224 33 4 A. titanium(IV) selenide B. sodium acetate C. vanadium(III) chlorate D. aluminum phosphate 9 E. none of the above. 0044 1300025 C 15 15250 31 07970037 Select the proper set of names for the following four compounds: 1. Au(MnO ) 2. NiS 3. Cu(CrO ) 4. Zn(NO ) 4 43 4 32 A. 1. gold(III) permanganate 2. niobium(II) sulfide 3. copper(I) chromate 4. zinc nitrite B. 1. gold(III) permanganate 2. nickel(II) sulfide 3. copper(II) chromate 4. zinc nitrite C. 1. gold(III) permanganate 2. nickel(II) sulfide 3. copper(II) chromate 4. zinc nitrate D. 1. gold(III) manganate 2. nickel(II) sulfide 3. copper(II) chromate 4. zinc nitrate 9 E. none of the above. 0044 1300026 C 15 15259 31 07970037 Which of the following four compounds is incorrectly named? 3 ___________ A) Cu(CrO ) B) Al(NO ) C) Bi (C O ) D) Ag Se 4 4 23 2 243 2 A. copper(II) chromate B. aluminum nitrite C. bismuth(III) acetate D. silver(I) selenide 9 E. none of the above. 0044 1300027 E 15 15264 31 00350797 The correct name for NaClO is 4 4 A. sodium hypochlorite B. sodium chlorite C. sodium perchlorite D. sodium chlorate 9 E. sodium perchlorate 0028 1300028 B 15 15267 Slaked lime is A. calcium carbonate B. calcium hydroxide C. calcium oxide D. calcium phosphate 9 E. none of these 31 1166 1300029 E 15 15269 51 128912900943 The publication that is the key to the world's chemical literature is A. the A.C.S. B. Chemical Reviews C. J. Chemical Education D. Chemistry Today 9 E. Chemical Abstracts 0020 0020 1300030 E 15 15272 31 07971325 A better name for stannous nitrate is A. stannic nitrate B. tin(IV)nitrate C. tin(III) nitrate D. stannous nitrite 9 E. tin(II) nitrate 0020 1300031 E 15 15275 31 00661326 Which of the following compounds is not a binary compound? A. sodium hydride B. lead dioxide C. phosphorus pentachloride 0020 9 D. calcium iodide E. all are binary 1300032 A 15 15278 31 The Greek prefix for seven is A. hepta B. hexa C. septa D. nona 9 E. none of these 13271328 0020 1300033 D 15 15280 31 00661329 The compound PCl can correctly be called 4 3 A. phosphorus trichloride B. monophosphorus trichloride C. phosphorus(III) chloride D. all of the above 9 E. none of the above 0020 1300034 E 15 15283 31 0224 The formula for aluminum sulfate is A. AlSO B. Al SO C. Al(SO ) D. Al (SO ) 94 4 2 4 42 3 42 0020 E. Al (SO ) 2 43 1300035 A 15 15286 31 006607971326 A compound whose name has an _ide ending even though it is not a binary compound is A. KCN B. HNO (aq) C. KMnO D. KClO E. H CO 94 3 4 3 2 3 0020 1300036 D 15 15289 31 02600083 NaHCO is called 4 3 A. baking soda B. sodium hydrogen carbonate C. sodium bicarbonate D. all of these 9 E. none of these 0020 1300037 D 15 15291 31 11781330 5 _ The ClO ion is called A. perchlorate B. hypochlorate C. perchlorite 9 D. hypochlorite E. chlorite 0020 1300038 A 15 15293 51 032813470161 The emission of light from matter at low temperatures is called A. luminescence B. radium emission C. gamma radiation D. symbiosis 9 E. none of these 0020 1300039 C 15 15296 52 134706651348 Which of the following is not a luminescent phenomenon? A. bioluminescence B. television pictures C. light from flashlight D. phosphorescence 9 E. luminous watch dial 0020 1300040 E 15 15299 51 006602240355 The compound nitric oxide has A. the formula NO 4 2 5 3 B. sp hybrid bonds C. 90 degree bond angles D. 8 electrons around each atom 9 E. none of these 0020 1300041 C 15 15302 31 117814610025 Which of the following polyatomic ions does not contain oxygen? 3 ________ A. sulfate B. acetate C. cyanide 9 D. peroxide E. permanganate. 0040 1300042 B 15 15305 51 117801850851 Which of the following polyatomic ions has a negative two charge associated with it? A. phosphate B. carbonate C. chlorate 9 D. both A and B E. both B and C. 0040 1300043 B 15 15308 31 021814610066 The name of the compound Mg N is 4 32 A. manganese nitride B. magnesium nitride C. magnesium nitrate D. manganese nitrate 9 E. magnesium nitrate 0040 1300044 D 0040 15 15311 31 146107260006 Which of the following groups of compounds would be named by using Roman numerals to represent oxidation numbers? A. NO , N O , N O B. KCl, KBr, KI 4 2 24 25 C. H SO , H SO D. CoCl , CoCl 4 2 3 2 4 2 3 9 E. both B and C. 1300045 D 15 15315 31 146102180025 The compound N O can correctly be called 4 25 A. nitrogen pentoxide B. dinitrogen tetroxide C. nitrogen trioxide D. dinitrogen pentoxide 9 E. dinitro pentoxide. 0040 1300046 B 15 15318 31 146101000077 HNO is called nitric acid. Therefore, the name of HNO is 4 3 2 A. pernitric acid B. nitrous acid C. hyponitrous acid D. hydronitric acid 9 E. no correct response is given. 0040 1300047 A 15 15322 31 146100770056 Which formula is followed by its correct name? A. H SO __sulfurous acid B. HClO __chlorous acid 4 2 3 3 C. H S__sulfuric acid D. HNO _ nitric acid 4 2 2 9 E. both A and B. 0040 1300048 C 15 15326 31 001814610066 Which of the following compounds has a name ending in the suffix_ate? A. KCN B. H SO C. KClO D. H S 4 2 3 3 2 9 E. both A and C. 0040 1300049 B 15 15329 32 003500570025 The name for the oxide of sulfur in which the sulfur has an oxidation number of +4 is A. sulfur monoxide B. sulfur dioxide C. sulfur trioxide D. disulfur monoxide 9 E. sulfurous oxide. 0040 1300050 E 15 15332 31 00640354 Which of the following is an inert gas? 0035 9 A. Mg B. Si C. C D. P E. Ar 1300051 D 15 15334 31 166109610066 Organic chemistry may be defined as that branch of chemistry that includes A. molecules that contain only the element carbon B. molecules that are synthesized only in living systems C. substances that are endowed with a "vital force" D. compounds of carbon and other elements 9 E. molecules capable of forming long chains 1300052 E 15 15339 32 1461 The compound Fe O is named 4 23 A. iron(II) oxide D. ferrous oxide B. iron dioxide E. iron(III) oxide 9 C. ferric oxalate 0034 05 1300053 A 14 15342 32 1461 0540 The compound Na S is named 4 2 A. sodium sulfide C. sodium sulfite 9 B. sodium sulfate D. sodium sulfone 1300054 A 14 15344 32 1461 The compound K SO is named 4 2 4 A. potassium sulfate C. potassium sulfite 9 B. sodium sulfate D. sodium sulfite 1300055 C 14 15347 52 1948 The formula of gallium (III) perchlorate is: A. GaClO B. Ga ClO C. Ga(ClO ) 94 4 3 4 43 1300056 A 14 15350 52 1948 The formula of tin (II) sulfate is: A. SnSO B. Sn SO C. Sn(SO ) 94 4 2 4 42 0540 E. potassium sulfide 0059 D. GaClO 3 0059 D. Sn (SO ) 2 43 1300057 C 14 15352 52 19470224 The formula for lithium orthophosphate is: A. LiPO B. LiPO C. Li PO D. Li(PO ) 94 4 3 3 4 33 1300058 A 14 15354 52 1949 0058 0060 The formula of hypophosphorous acid is: A. H PO B. H P O C. H P O D. H P O 94 3 2 425 426 427 1300059 D 14 15356 52 1949 The anhydride of H VO is: 4 3 4 A. VO B. VO C. V O D. V O 94 3 4 23 25 0060 1300060 EDD 35 15358 52 MACROITEM STEM 0 Match the name to the formula: MACRO SUB_ITEM # 1 bicarbonate 5 = _ = = A. C O B. HC O C. H CO D. CO E. HCO 14 24 24 2 3 3 3 MACRO SUB_ITEM # 2 bromate 5 _ _ _ _ _ A. Br B. BrO C. BrO D. BrO E. BrO 24 2 3 4 MACRO SUB_ITEM # 3 phosphite 5 3_ 3_ 3_ 3_ 3_ A. P B. PO C. PO D. PO E. PO 94 2 3 4 OS 1300061 D 14 15366 31 029300728004 A difference between a molecule of ammonia and an ammonium ion is one A. electron B. neutron C. positron 9 D. proton 1300062 A 15 45181 31 Choose the pair of names and formulas that do not match. A. sodium sulfite, Na S D. aluminum bromide, AlBr 4 2 3 B. calcium fluoride CaF E. iron(III) oxide Fe O 4 2 23 C. potassium permanganate, KMnO 94 4 2 OS 1300063 B 15 45186 71 The oxoanion which comes from nitrous acid is: 5 _ _ _ A. NO B. NO C. NO D. N O E. HNO 94 2 3 23 3 1600001 C 15 15368 31 02670266800111 Inductive reasoning is a phase of logic concerned primarily with A. solving problems by formula B. classification and systematic organization of facts C. developing laws from a study of assembled facts D. observing natural phenomena 9 E. the statement of a theory ETS2 OS 1600002 A 15 15372 32 02690268800111 One of the baffling features of the advance of science lies in the A. unpredictable way in which revolutionary ideas have developed B. reluctance of famous scientists to accept new ideas or concepts C. slow development of new ideas by logical thought D. reluctance of professors and scientists to mingle with artisans E. reluctance with which new ideas have been applied to 9 everyday events ETS2 OS 1600003 C 14 15378 32 02760277800111 A theory is A. used interchangeably with the word "principle" B. the method of applying some principle to the solution of a problem C. a generalization standing midway between a hypothesis and law D. a generalization standing midway between a hypothesis and 9 principle ETS2 OS 1600004 A 14 15383 31 02810282800111 The process in which one systematically observes and builds up piecemeal scientific principles is called A. deduction B. induction C. intuition 9 D. hypothesis ETS2 OS 1600005 B 15 15386 52 02100277800111 Proust's Law of definite proportions which states that the elements which make up a chemical compound are combined in a ETS2 OS definite proportion by weight, is a A. concept which arose out of abstract thinking B. generalization which was developed as a means of integrating many observed facts C. hypothesis which stemmed from a concept by means of a chain of reasoning D. conceptual scheme which was theorized from a set of proven hypotheses E. general unsubstantiated belief becoming accepted as law as a 9 result of the passage of time 1600006 A 14 15394 32 02850031800111 F=k x m x m is an expression of 4 1 2 3 _______ 5 2 d A. a natural law B. an hypothesis C. a theory 9 D. an assumption ETS2 OS 1600007 D 15 15397 32 02868001028811 A statement such as "The heats of formation between the halogens and carbon were checked and they increase from iodine to fluorine," represents A. a hypothesis B. a problem C. the specification of a problem D. data used in the solution of a problem 9 E. none of these ETS2 OS 1600008 B 15 15401 52 02890283800111 From the general principle that "To every action there is always an equal reaction," it may be concluded that a rocket ship will travel out in space moving forward by reaction from the materials ejected. This best illustrates A. inductive reasoning B. deductive reasoning C. testing an hypothesis experimentally D. discovering a scientific law 9 E. utilization of common sense ETS2 OS 1600009 C 15 15407 52 02900278800111 When one evolves a new explanation of why a certain cause produces a certain effect with the idea of testing the ETS2 OS explanation observationally or experimentally, it is MoSt appropriate to call the explanation A. a deduction B. a scientific law C. an hypothesis D. a general theory 9 E. an example of inductive reasoning 1600010 B 15 15412 31 00870089800111 In solution, all electrolytes break down into atoms or groups of atoms carrying positive or negative charges. This is classified as a/an A. hypothesis B. theory C. definition D. natural law 9 E. unverifiable hypothesis ETS2 OS 1600011 C 15 15416 32 03260054800114 A photoelectric cell for measuring intensities of light has been constructed on the theory that electrons exist. Calculations based on this theory give correct values for the intensity of light falling on the cell for all values of the current through the cell. If in the future scientists find evidence against the existence of electrons, A. we should stop using the cell B. we should have to reconstruct the cell C. we could use the cell but not the electron theory for calculating the intensity of light D. we could continue using the electron theory for calculating the intensity of light 9 E. none of the above is true ETS2 OS 1600012 CE 25 15425 52 0284027680011190 MACROITEM STEM 2The following questions involve terms used in science. Select from 2the key the most closely related term for each item. 2 A. definition 2 B. observation 2 C. theory 2 D. verification of hypothesis 0 E. natural law MACRO SUB_ITEM # 1 The atom consists of a positive nucleus with one or more planetary 1 electrons revolving around it in orbital motion. MACRO SUB_ITEM # 2 ETS2 OS In every sample of any compound substance, formed or decomposed, the proportion by weight of the constituent elements is always 9 the same. 1600014 AEC 35 15432 52 0284027680011190 MACROITEM STEM 2The following questions involve terms used in science. Select 2from the key the most closely related term for each item. 2 A. definition 2 B. observation 2 C. theory 2 D. verification of hypothesis 0 E. natural law MACRO SUB_ITEM # 1 About 1887 congress passed a law making the yard 3600/3937 of the 1 standard meter. MACRO SUB_ITEM # 2 In every sample of any compound substance, formed or decomposed, the proportion by weight of the constituent elements is always 2 the same. MACRO SUB_ITEM # 3 The molecules of an electrolyte are broken up in solution into 9 their constituent radicals, each being charged 1600015 DAACDEBAB95 15440 52 0296029780011190 MACROITEM STEM 2Read the following selection carefully. 2The northwestern tip of Quebec just south of Baffin Island, is 2flat, sodden tundra sprinkled thickly with little lakes. Most of 2them are irregularly shaped. But prospector Fred W. Chubb noticed, 2while poring over an aerial photograph, that one lake was almost 2round and surrounded by a wall of rock. This week Dr. V. B. Meen, 2field geologist Ontario Department of Mines, returned from a quick 2air visit to the lake and reported that it was almost certainly a 2meteorite crater (there was no lava or other sign of volcanic 2activity), and the biggest yet discovered. The lake in the crater 2is two and one_half miles across compared with Arizona's famed 2meteorite crater, which is four_fifths of a mile across. Its 2level is about 90 feet above that of other small lakes in the 2vicinity, and around it is a ring of shattered granite that rises 2550 feet above the tundra. The rim is lowest on the north_west 2side, which suggests that the meteorite came from that direction and hit the ground obliquely. 2Dr. Meen found no meteoric iron, only a reddish rock that might 2prove to be the peculiar stony material of which some meteorites 2are made. But there was plenty of other evidence that some enormous 2body had buried itself in the earth shattered blocks of stone from ETS2 OS ETS2 OS 2football to freight_car size, and concentric circles in the granite 2around the crater, like ripples stirred up by a pebble dropped 2into still water. Dr. Meen estimated that the meteorite must have 2fallen at least 3,000 years ago, since there are no Indian or 2Eskimo legends about it. He named it Chubb crater after the 2sharp_eyed prospector, and promised that a full_dress expedition 2would report on it within a year. Time, August 14, 1950. by permission. Copyright Time, Inc., 1950. 2Directions: For each of the following questions select the best 0 answer, then mark the corresponding space on the answer sheet. MACRO SUB_ITEM # 1 The basic problem which faces a scientist in the case of this lake is the A. the shape of the lake B. size of the lake C. high elevation of the lake D. origin of the lake 1 E. depth of the lake MACRO SUB_ITEM # 2 This problem was suggested by the A. shape of the lake B. size of the lake C. high elevation of the lake D. origin of the lake 2 E. depth of the lake MACRO SUB_ITEM # 3 Which one of the following statements is least related to the 3 _____ basic problem? A. The northernwestern tip of Quebec...is flat, sodden tundra, sprinkled thickly with little lakes. B. ..one lake was almost round, and surrounded by a wall of rock. C. There was no lava or other sign of volcanic acitivity. D. Its level is about 80 feet above that of other small lakes in the vicinity, and around it is a ring of shattered granite that rises 550 feet above the tundra. E. (there were) concentric circles in the granite around the crater, like ripples stirred up by a pebble dropped into 3 still water. MACRO SUB_ITEM # 4 Which one of the following statements would represent the attitude of a scientist? A. He would not say that the lake was of meteoric origin unless he had seen the meteor fall. B. He would say that the lake was of meteoric origin if he had 4 5 6 7 any evidence that pointed in that direction. C. He would say that the lake was probably of meteoric origin if evidence from many different sources pointed in that direction. D. He would state that the lake was of meteoric origin and then would attempt to prove it. E. The economic conditions of the regions would influence his interest in the origin of the lake. MACRO SUB_ITEM # 5 The statement "It was almost certainly a meteorite crater" is A. a scientific fact B. evidence in support of a scientific fact C. an unfounded assumption D. a reasonable hypothesis E. a chance guess MACRO SUB_ITEM # 6 Which one of the following lines of study would probably furnish the most conclusive means of testing the idea of meteoric origin of the lake? A. Compare the lake with other lakes in the immediate vicinity. B. Accurately survey the lake and territory immediately around it. C. Look for other lakes like this lake in other parts of Quebec and Baffin Island. D. Compare the lake in detail with known meteoric craters. E. Determine the structure and composition of the rock found in the vicinity of the lake. MACRO SUB_ITEM # 7 Which one of the following statements is the best example of an hypotheses? A. Dr. Meen found no meteoric iron, only a reddish rock that might prove to be the peculiar stony material of which some meteorites are made. B. The rim is lowest on the northwest side, which suggests that the meteorite came from that direction and hit the ground obliquely. C. Prospector Fred W. Chubb noticed... that one lake was almost round and surrounded by a wall of rock. D. The lake in the crater is two and one_half miles across, compared with Arizona's famed meteorite crater, which is four_fifths of a mile across. E. Dr. Meen promised that a full_dress expedition would report on it within a year MACRO SUB_ITEM # 8 The face of the moon shows many craters similar to the Chubb and Arizona craters, most of which are larger than either of these. If these craters on the moon were formed by meteorites, why are there fewer of them on the earth? A. The moon has no atmosphere, and therefore there is no erosion working on the moon to destroy the craters. B. More meteorites strike the moon than the earth because the moon is located out in space where the meteorites can reach it more easily. C. The moon is smaller than the earth and therefore the moon is more susceptible to being buffeted by meteorites. D. The natural laws that operate on the earth do not operate on the moon. E. The moon is older than the earth, and therefore has had more 8 time for meteorites to strike it. MACRO SUB_ITEM # 9 9 Uninhabited places 1600016 DDEAAE 65 15518 52 0299029380011690 MACROITEM STEM 2Read the following selection carefully. 2At a temperature of 0 degrees centigrade and standard barometric 2pressure there are about 27,000,000,000,000,000,000 molecules 2in one cubic centimeter of air. These molecules are in constant 2motion, and have an average velocity of about one_quarter of a 2mile per second. This is slightly greater than the speed of 2sound. Under these conditions the average distance traveled by 2a molecule before it strikes another is eight millionths of a centimeter. 2In interstellar space a molecule is believed to travel about 50 2billion miles before it collides with another. Each molecule in 2space collides with another on the average of about once a year. 2For each of the following questions, select the best answer and 0 mark the corresponding space on the answer sheet. MACRO SUB_ITEM # 1 The statements in the selection are A. wild guesses B. true, because they are based on statements in a reputable textbook C. incredible, because no one can even see molecules, much less measure their speeds and number of collisions D. probably close to the truth because they are the results of calculations based on a well_established theory E. incredible, because no one has ever been able to travel to 1 interstellar space MACRO SUB_ITEM # 2 The statements in the selection are A. observed facts ETS2 OS B. generalized presentations of fact C. hypotheses D. reasoning based on a theory 2 E. experimental data upholding or disproving an hypothesis MACRO SUB_ITEM # 3 The statements in the selection are obtained by the process of A. experimentation B. generalization C. observation D. reasoning from specific data to a principle 3 E. applying a general principle to a specific case MACRO SUB_ITEM # 4 The statements in the selection are A. impossible to prove or disprove because one cannot see or handle individual molecules B. impossible to prove or disprove because no instruments are available to measure such distances or speeds C. possible to check experimentally by direct methods D. possible to check experimentally by indirect methods E. impossible to check because of the very large and very 4 small numbers involved MACRO SUB_ITEM # 5 If the statements about molecules are true A. the average distance a molecule travels between collisions is large in comparison to its diameter B. there is much more space occupied by molecules than between molecules in the air C. when one molecule strikes another, the first one is destroyed D. the distances between molecules are small compared to their diameters 5 E. each molecule always travels at the same speed MACRO SUB_ITEM # 6 if the statements in the selections are true, which one of the following is inconsistent with them? 3 ____________ A. Matter must be evenly distributed in interstellar space. B. Man can build a machine which will travel as fast as an average air molecule. C. Probably in air few molecules travel as far as one centimeter before colliding with others. D. In interstellar space, molecules travel an average distance of 50,000,000,000 miles before changing directions. 9 E. Interstellar space is a complete vacuum. 1600017 B 14 15560 31 02810320028712 The observation of data without allowing one's personal motives to ETS2 OS "color" the observations is known to social science A. intuition B. objectivity C. subjectivity 9 D. bias 1600020 E 15 15570 52 02760272800111 A scientific theory is usually established when A. it agrees with about half of the observed experimental facts B. it is based on plain common sense C. almost every person believes it D. about half of the leading scientists accept it E. it accounts for every bit of experimental evidence known at 9 the time ETS2 OS 1600021 C 15 15575 32 03080276800111 A geologist, in attempting to prove a theory A. looks only for evidence that supports the theory B. limits his evidence to observations in easily accessible localities C. records any observations that prove or disprove the theory D. builds on previous concepts despite new evidence 9 E. supports and correlates all evidence with a geologic map ETS2 OS 1600022 E 15 15580 32 02720299800111 The earliest investigator in this field observed after one experiment that water boiled at 100 degrees centigrade (212 degrees F). He concluded that water would always boil at this temperature. His conclusion may be classified as A. a proven fact B. a scientific law C. a deliberate lie D. a haphazard guess 9 E. an invalid assumption ETS2 OS 1600023 B 15 15585 32 02780310800111 A satisfactory scientific hypothesis A. is a collection of accurate observations relating to the same phenomenon B. is an educated guess which explains a large number of observations or a scientific law and can be subjected to further experimental test C. is a summary, often in the form of an equation, of a series of related measurements D. is the name given to a theory which has survived a large number of experimental tests ETS2 OS 9 E. is necessary before any accurate scientific measurement can be made 1600024 A 15 15593 32 03110278800111 The scientific method A. begins with the formation of reasonable hypotheses B. is applied only to the natural sciences C. deduces facts only on the basis of the laws which have been discovered D. evolves laws to fit the theories which have been established E. proceeds in the following order; fact, law, hypothesis, 9 theory ETS2 OS 1600025 B 15 15598 32 02660267800111 Logic, both inductive and deductive, is a necessary part of scientific thinking; but its conclusion must A. be accepted beyond question B. always be tested by experiment C. be based upon a few observations D. never be used today E. be accepted whenever the scientist presenting the theory is an 9 authority in his field ETS2 OS 1600026 A 15 15603 32 02910318800112 A scientist thinks that he understands why a certain cause produces a certain effect, but he refuses to more than tentatively accept his explanation until he has collected adequate data. It is evident from the above alone that this scientist possesses A. scientific attitude B. common sense C. scientific knowledge D. the correct solution to his problem 9 E. a willingness to rationalize ETS2 OS 1600027 D 15 15609 32 02720319800112 A scientific observation A. deals only with living things B. is peculiar to the field of investigation C. provides no possibility of bein duplicated D. can be challenged on the basis of reproducibility 9 E. is conducted only in a laboratory ETS2 OS 1600028 B 14 15613 31 02940295800111 By obtaining knowledge through the logical processes of reason, we are using A. authoritarianism ETS2 OS 9 B. rationalism C. intuitionalism D. experimentalism 1600029 EABACBBDE95 15616 52 80018002 1490 MACROITEM STEM 2The following exercise follows the general pattern of scientific 2thinking. A scientist on observation of a given phenomenon 2formulates an hypothesis or several hypotheses, which are 2tentative explanations of the phenomenon. He then thinks about the 2hypothesis or hypotheses in terms of his data. Finally, he derives 2from his data and his thinking about the hypothesis or hypotheses 2a general conclusion, which is his best answer to the problem 2presented by the phenomenon. Be sure to read the directions 2carefully and to follow them explicitly. Base your judgments 2wholly on the information given in the selection. You may refer 2back to the selection as often as you wish. 2As the words imply, a continuous spectrum is a spectrum in which 2there is a continuous band of colors from one end to the other. 2This necessarily means that the light source is emitting all 2frequencies of light between the spectral limits. A bright_line 2spectrum is a spectrum in which there are one or more vertical lines 2of light in certain specific positions. This means that the light 2source is emitting light waves of certain specific frequencies. 2In the isolated atom the electrons have certain definite and 2characteristic motions, which are related to the emission or 2absorption of light waves of certain specific frequencies. Hence, 2when atoms are sufficiently far apart, as in a rarefied gas, and 2are heated to incandescence, the light waves emitted from them 2produce the bright_line spectrum characteristic of the elements 2of the luminous source. However, when the natural motions of 2electrons of each atom are altered by force due to the presence 2of nearby atoms, as in the case of a condensed gas, liquid, or 2solid, the light waves emitted, instead of being of certain 2specific frequencies, are of numerous different frequencies. 2Therefore, incandescent solids, liquids, and dense gases produce continuous spectra. Rarefied gases produce bright_line spectra. 2As previously stated, because of the forces exerted upon them by 2their neighbors, atoms of solids and liquids have their emitting 2frequency ranges greatly widened. For the same reason their 2absorbing frequency ranges are likewise widened. On the other 2hand, since the atoms of vapors and gases at ordinary or low 2pressures are comparatively free to emit waves of their own 2natural frequencies, they can absorb waves of those particular 2frequencies. Consequently, the absorption spectrum of a vapor is 2a spectrum in which there are dark lines corresponding to the ETS2 OS 2bright lines in the bright_line spectrum that the vapor would yield if it were incandescent. 2The spectrum obtained from the glowing carbon of a carbon arc is 2continuous and has no vertical lines. When sodium metal is heated 2in a metal spoon held over the flame of a bunsen burner placed 2below the arc, sodium vapor is produced, which surrounds and to 2some extent obscures the arc. A dark line then appears in the 2spectrum of the arc. If the burner and spoon are removed and a tiny 2piece of sodium is inserted between the terminals of the arc, a 2bright yellow line instantly appears in the exact position 2previously occupied by the dark line. 2When light from the sun is observed by means of a spectroscope, the 2continuous spectrum contains a number of vertical lines, which 2appear dark by contrast with the rest of the spectrum. 2 2Problem: What causes the relatively dark lines of the solar 2spectrum? 2Below are given a series of hypotheses, each of which is followed 2by numbered statements. After the answer sheet number corresponding 2to that of each statement, blacken space 2 A. if the statement supports the hypothesis, and this statement 2 B. if the statement supports the hypotheses, but this statement 2 is not justified by the information given 2 C. if the statement contradicts the hypothesis, and this 2 statement is justified by the information given 2 D. if the statement contradicts the hypothesis, but this 2 statement is not justified by the information given 2 E. if the statement is not relevant to the hypothesis, or the 2 statement neither supports nor contradicts the hypothesis. 2Hypothesis I. Sodium atoms, when vaporized but not heated to 0 incandescence, absorb light waves of a definite frequency. MACRO SUB_ITEM # 1 Sodium is a metal which ignites easily when vaporized in air. 1 (Refer to hypothesis I). MACRO SUB_ITEM # 2 When sodium vapor surrounds a carbon arc, a dark line appears in 2 the spectrum of the arc. (Refer to hypothesis I). MACRO SUB_ITEM # 3 Sodium vapor under the conditions described absorbs light of a definite frequency, because the natural motions of the electrons of each of its atoms are altered by forces due to the presence of 3 nearby atoms. (Refer to hypothesis I). MACRO SUB_ITEM # 4 Blacken space A if hypothesis I is true, or space B if it is false. 4 (Refer to hypotheses I). MACRO SUB_ITEM # 5 Hypothesis II. Incandescent solids yield bright_line spectra. The atoms of a solid are SO closely packed together that the 5 natural motions of the electrons of its atoms are altered. MACRO SUB_ITEM # 6 Atoms of incandescent solids are far enough apart that the motions of the electrons are unaltered by atomic forces; hence, such atoms 6 yield bright_line spectra. (Refer to hypothesis ii). MACRO SUB_ITEM # 7 blacken space a if hypothesis ii is true, or space b if it is false. 7 (Refer to hypothesis ii). MACRO SUB_ITEM # 8 hypothesis III. The atmosphere of the sun contains atoms less incandescent than the atoms on the surface of the sun. A brilliant corona is observed during a total eclipse of the sun by the moon; hence the atmosphere of the sun is more incandescent 8 than its surface. MACRO SUB_ITEM # 9 9 Cooler than the rest of the surface. (Refer to hypothesis III). 1600030 D 15 15689 32 05560048800114 A glowing splint placed in oxygen will burst into flame. Assume that if placed in other gases lacking in oxygen, the glowing splint is extinguished. A jar of oxygen and a jar of nitrogen were placed with their mouths separated by a glass plate. The plate was removed for a few seconds, then a glowing splint was placed in each jar. The splint burst into flame in both containers. This provides direct evidence that 3 ______ ________ A. the two gases intermingled B. the oxygen diffused into the nitrogen C. the nitrogen diffused into the oxygen D. oxygen is present in both jars 9 E. none of the above is correct 1600032 BACBABD 74 15698 51 0513049980011190 MACROITEM STEM 2The following questions relate to one of the four theories listed 2below. After each item blacken the space 2 A. if the statement belongs to the atomic theory 2 B. if the statement belongs to the kinetic theory 2 C. if the statement belongs to the theory of ionization 0 D. if the statement belongs to the theory of isostacy MACRO SUB_ITEM # 1 1 The molecules of a substance attract one anoTher. MACRO SUB_ITEM # 2 2 Matter is discontinuous. ETS2 OS ETS2 OS MACRO SUB_ITEM # 3 3 The charge of an ion is proportional to its valence. MACRO SUB_ITEM # 4 The distance between the molecules of a gas is extremely 4 great in comparison to their diameters. MACRO SUB_ITEM # 5 5 Compounds are formed by the union of atoms in simple ratios. MACRO SUB_ITEM # 6 6 Heat is molecular motion. MACRO SUB_ITEM # 7 There has been progressive subsidence in the Mississippi 9 deltaic region through long intervals of geologic time. 1600033 CDBCDB 64 15708 52 0272060880011690 MACROITEM STEM 2The following questions are to be answered in accordance with the 2key 2 A. The statement has been proved by experiment or observation. 2 B. The statement is theoretical or hypothetical. 2 C. The statement is a definition. 2 D. The statement has been proved false by experiment or 0 observation. MACRO SUB_ITEM # 1 1 The mass of 1 cc. of water at 4 degrees C. is one gram. MACRO SUB_ITEM # 2 The gravitational attraction is the same at all places on the 2 surface of the earth. MACRO SUB_ITEM # 3 3 The number of different kinds of atoms is limited. MACRO SUB_ITEM # 4 The acceleration of a body is equal to the time rate of change 4 of velocity. MACRO SUB_ITEM # 5 5 The mass of a hydrogen atom is 100 times that of an electron. MACRO SUB_ITEM # 6 The number of molecules in a liter of a gas at 0 degrees C. and 76 cm. of mercury pressure is the same as the number of molecules in 9 a liter of any other gas at the same pressure and temperature. 1600034 A 14 15719 31 026905888003 The science that deals with the study of matter is A. chemistry B. zoology C. botany 9 D. physics 1600037 CCDCADBC 85 15721 52 0278027680011190 ETS2 OS 2WVW ETS2 OS MACROITEM STEM 2The following questions involve terms used in science. Select 2from the key the most closely related term for each of the items. 2 Key 2 A. deduction 2 B. theory 2 C. natural law 2 D. definition 0 E. none of these MACRO SUB_ITEM # 1 1 Our senses observe and interpret within certain limitations. MACRO SUB_ITEM # 2 2 The atom is composed of electrons, protons, and usually neutrons. MACRO SUB_ITEM # 3 Natural philosophy is concerned with fundamental concepts of time and space, matter and energy, and their relationship with 3 each other. MACRO SUB_ITEM # 4 F=kxm xm 4 1 2 _______ 5 2 4 d MACRO SUB_ITEM # 5 One of the explanations of the origin of the solar system is 5 known as the planetesimal. MACRO SUB_ITEM # 6 A conclusion drawn from many particular observations is known 6 as a special type of reasoning. MACRO SUB_ITEM # 7 Science frequently uses statements agreeing with all observations made so far or a tentative principle which is plausible on the 7 basis of observations. MACRO SUB_ITEM # 8 In every sample of any compound substance formed or decomposed the proportion by weight of the constituent elements is always the 9 same. 1600038 A 14 15735 31 80038004 Three of the following constitute advantages that may arise from the use of symbolism. Which one is a disadvantage? A. The symbol may become completely dissociated from the object it represents. B. Under certain conditions the symbol makes unnecessary the manipulation of the object it represents. C. Information can be stored. 9 D. Experience can be gained vicariously. 2WVW 1600039 C 14 15741 31 80038004 A symbol, if it is to have value as a means of communication between one person or group and another, must possess which one of the following characteristics? A. It must suggest to the person using it some characteristic of the object or concept that it represents. B. It must suggest to the person using it as wide a variety of objects or concepts as possible. C. It must suggest the same object or concept to all persons using it in the same way. 9 D. It must have only one meaning regardless of how it is used. 1600040 D 15 15749 31 027802650279 Which of the following sequences for the scientific theory is correct? A. facts_experiments_hypothesis_theory_laws B. hypothesis_facts_experiments_laws_theory C. facts_hypothesis_experiments_theory_laws D. facts_hypothesis_experiments_laws theory 9 E. none of the above 1600041 C 14 15753 31 0311 A goal of chemistry is to be able to explain phenomena of matter on the basis of its 9 A. laws B. facts C. structure D. macroscopic properties. 2WVW 0018 0026 1600042 A 14 15756 31 02650269 A summarization of a large body of related facts is a(n) A. law B. theory C. example of deductive thinking 9 D. synthetic hypothesis. 0026 1600043 D 14 15758 31 11570269 All of the following are true of submicroscopic models except one A. could be mathematical B. could be pictorial C. use macroscopic phenomena to portray or explain ideas about parts of matter too small to be seen 9 D. become laws with sufficient passage of time. 0026 1600044 E 15 15762 32 027606311288 A sample of metal has a density of 6.75 g/cc. Its specific gravity is A. 6.75 g/cc B. 0.148 C. 1.48 g/cc D. 0.675 g/ml 0020 9 E. 6.75 1600045 D 15 15765 52 031102761402 The correct scientific reaction to a situation involving different theories concerning the same chemical and physical properties should be A. Always reject out of hand any new theory by young upstarts. B. When several cases of agreement of two theories with experiment are found, one may conclude that both theories are always equally valid. C. Always accept the word of a professor as gospel and not subject to change__since he makes out grades and gives the degrees. D. Seek to find an experimental measurement for a case which has differing predictions according to which theory is used. E. Form a hybrid of the two theories so that a given answer 9 is either 100% correct or at least 50% correct. 0019 1652001 C 14 15776 31 000808198004 Water extinguishes a fire mainly by A. lowering the kindling temperature B. raising the kindling temperature C. lowering the temperature 9 D. removing the combustible material 2 OS 1700001 B 15 15779 31 04360186800111 An instrument which is used to measure liquid density is a A. hygrometer B. hydrometer C. pyrometer D. barometer 9 E. none of these ETS2 OS 1700002 D 15 15782 31 01490158800111 A device for the direct measurement of the specific gravity of a liquid is the A. burette B. optical pyrometer C. barometer D. hydrometer 9 E. hygrometer ETS2 OS 1700003 D 15 15785 51 04400439800111 Time is involved in all of these except 3 ______ ETS2 OS 9 A. watts B. horsepower C. rate of working D. calories E. power 1700004 EAD 35 15788 31 0149065080011490 MACROITEM STEM 2The key presents brief references to experiments 2and demonstrations of traditional significance in physical 2science. Recall the observations and conclusions of the total 2experiment and indicate which activity yields the most 2information toward explaining the situations described in the 2statement. 2 A. A pycnometer was filled with water and carefully weighed. 2 B. The extension produced in a spring by the rotation 2 of an attached weight was recorded. 2 C. A weight was suspended and then allowed to fall 2 in such a way as to leave equal time intervals marks 2 on sensitive paper. 2 D. The weight and temperature of a cup of water was 2 recorded before and after a known amount of electricty 2 had flowed through a resistance immersed in the water. 2 E. The weight and temperature of a cup of water was 2 recorded before and after a cube of ice was melted 0 in it. MACRO SUB_ITEM # 1 Farmers sometimes place a tube of water in cellars where 1 potatoes are stored. MACRO SUB_ITEM # 2 A hydrometer can be used to estimate the freezing temperature 2 of the coolant in an automobile radiator. MACRO SUB_ITEM # 3 The temperture of a mass of water will rise if placed in a 9 container and agitated. 1700005 C 15 15804 A unit of work is the A. poundal B. coulomb C. erg D. esu 9 E. dyne 31 ETS2 OS 03850387800111 ETS2 OS 1700006 D 15 15806 31 01590387800111 Energy may be defined as capacity for ETS2 OS 9 A. exerting force B. action C. great power D. doing work E. producing motion 1700007 A 15 15808 An erg is equal to a A. dyne_centimeter B. dyne C. gram_centimeter D. foot_pound 9 E. poundal 31 03880389080011 ETS2 OS 1700008 C 15 15810 31 03920385800111 Measurement of which of the following quantities cannot be 3 ______ expressed in the units indicated? A. electricity__coulombs B. force__dynes C. work__horsepower D. pressure__millibars 9 E. acceleration__feet per day per hour ETS2 OS 1700009 D 14 15814 Energy is A. work B. a force C. power 9 D. ability to do work 31 01590387800111 ETS2 OS 1700010 D 15 15816 Kinetic energy is A. energy of position B. weight times height C. force times distance 5 2 D. (1/2) mv 5 2 9 E. (mv )/r 31 04190159800111 ETS2 OS 1700011 D 15 15819 31 Power may be measured in A. ergs B. dynes C. foot_pounds 03840418800111 ETS2WVW 9 D. horse power E. b.t.u. 1700012 CDBACCE 75 15821 31 0385014903911190 MACROITEM STEM 2The following questions refer to various units of physical 2measurement in the metric system which have their counterpart in 2the english system of units. For each question select from the 2key the analogous unit or concept involved. 2 A. poundal 2 B. foot_pound per second 2 C. foot_pound 2 D. cubic inch 0 E. pound per cubic foot MACRO SUB_ITEM # 1 1 joule MACRO SUB_ITEM # 2 2 liter MACRO SUB_ITEM # 3 3 watt MACRO SUB_ITEM # 4 4 dyne MACRO SUB_ITEM # 5 5 erg MACRO SUB_ITEM # 6 6 kilogram_meter MACRO SUB_ITEM # 7 5 3 9 gm./cm. 1700013 DBDC 45 15827 31 0385039101491190 MACROITEM STEM 2The following questions refer to various units of physical 2measurement in the English system. For each question select from 2the key the analogous unit or concept involved. 2 A. ergs 2 B. dynes 2 C. liters 2 D. watts 0 E. none of these MACRO SUB_ITEM # 1 1 foot_pound per second MACRO SUB_ITEM # 2 2 poundal MACRO SUB_ITEM # 3 3 horsepower ETS2 OS ETS2 OS MACRO SUB_ITEM # 4 9 cubic inches 1700014 BDBBCDA 75 15832 31 0385014903921190 MACROITEM STEM 2The following questions refer to units of measurement of fundamental 2quantities in physical science. For each question select from the 2key the term which relates to it. 2 A. mass 2 B. work 2 C. force 2 D. power 0 E. two of the above MACRO SUB_ITEM # 1 1 joule MACRO SUB_ITEM # 2 2 ft. lb./sec. MACRO SUB_ITEM # 3 3 erg MACRO SUB_ITEM # 4 4 k.w.h. MACRO SUB_ITEM # 5 5 poundal MACRO SUB_ITEM # 6 6 watts MACRO SUB_ITEM # 7 9 gram 1700015 C 15 44510 31 The metric unit which is analagous to the cubic inch is the 9 A. joule B. newton C. liter D. watt E. pascal 1700016 C 15 15837 31 03840385800111 A unit of power is the A. dyne B. erg C. watt D. foot_pound 9 E. gram_centimeter 1700017 B 15 15839 31 01140113800111 Which of the following is a good definition of the pressure of a gas? A. The pressure of a gas is the force exerted by the gas against its containing walls B. The pressure of a gas is the force exerted by the gas against a unit area of its containing walls ETS2 OS ETS2 OS ETS2 OS 9 C. The pressure of a gas is the force exerted upon the gas by its containing walls D. Each of the above is a good definition of the pressure of a gas E. None of the above is a good definition of the pressure of a gas 1700018 B 15 15846 31 03850159800111 Suitable units for expressing energy are 9 A. watts B. joules C. meters D. newtons E. hours ETS2 OS 1700019 B 15 15848 52 8003 Colorado River water contains 700 ppm of dissolved solids. If half of this is chloride ion, one liter of Colorado River water contains 5 _ ______ grams of Cl . A. 0.7 g B. 0.35 g 5 _6 C. 3.5 x 10 g 5 _3 D. 1 x 10 g 2WVW 5 _4 9 E. 7 x 10 g 1700020 C 15 15853 31 075507568003 5 +1 A krypton ion (Kr ) gas laser emits light of several different wavelengths in the visible region. If the energy of the electronic transition associated with one of these wavelengths is 5 _19 3.82 x 10 Joule, what color would you expect the beam of light emerging from the laser to be? The wavelength ranges for the different colors in the visible spectrum are shown in the figure below. 5 8 _1 _34 (c = 3.00 x 10 m sec , h = 6.62 x 10 J sec) wavelength (nm) 400 500 600 700 : : : : : : : : :______________________________: :v : : : y: : : :i : : : e: : : :o :blue : green : l:orange:red: :l : : : l: : : :e : : : o: : : 2WVW :t : : : w: : : ________________________________ 9 A. violet B. blue C. green D. yellow E. orange 1700021 D 15 15868 31 033007318003 5 _1 If the first ionization energy of neon is 500 kcal mole , what type of electromagnetic radiation would you need to ionize a neon atom? (refer to the figure below, which shows the electromagnetic spectrum as a function of wave number, n) 5 _1 _14 _1 (1.00 kcal mole = 6.95 x 10 erg atom ; 2WVW 10 _1 _27 c = 3.00 x 10 cm. sec. ; h = 6.62 x 10 erg sec.) 5 _1 2 3 4 5 6 7 8 9 cm 1 10 10 10 10 10 10 10 10 10 | | | | | | | | | | ____________________________________________________________________ : : :: : : radio : : :: : : gamma waves : MW : IR :V: UV : : rays : : :: : : ____________________________________________________________________ A. microwave (MW) B. x rays C. infrared (IR) D. ultraviolet (UV) 9 E. visible (V) 1700022 B 15 15883 52 030603281233 The 1970 standard established by the United States government for carbon monoxide emission for automobiles limits exhaust to 23.0 grams CO per vehicle mile. Assume that in a typical metropolitan area of 565,000 people there are 90,400 automobiles, driven an average of 15.6 miles per 24 hour period. How much CO (in tons) is (legally) discharged into the area's atmosphere per day? (1 ton = 2000 x 454 gr.) A. 0.0677 tons/day B. 35.8 tons/day 5 _9 C. 4.38 x 10 tons/day D. 0.146 tons/day 5 13 9 E. 2.95 x 10 tons/day. 0044 1700023 A 0044 15 15891 52 030603281233 The 1970 standard established by the United States government for carbon monoxide emission for automobiles limits exhaust to 23.0 grams CO per vehicle_mile. Assume that in a typical metropolitan area of 571,000 people there are 91,300 automobiles, driven an average of 15.6 miles per 24 hour period. How much CO (in tons) is (legally) discharged into the area's atmosphere per day? (1 ton = 2000 x 454 grams) 5 _2 36.1 tons 6.83 x 10 tons 0.414 tons A. _________ B. ________________ C. __________ day day day 5 _9 13 4.33 x 10 tons 2.98 x 10 tons D. ________________ E. ________________. 9 day day 1700024 A 15 15901 32 015007950288 Convert 2270 g to lb. 9 A. 5.00 lb B. 50.0 lb C. 10.0 lb D. 1,040,000 lb E. 2.27 lb 0028 1700025 B 15 15903 32 087101490440 All the systems of measurement use the same units for A. mass B. time C. force D. volume 9 E. length 0020 1700026 E 15 15905 A foot equals A. 0.472 m B. 4.72 m C. 30.5 m D. 0.135 m 9 E. none of these 32 129412910144 0020 1700027 C 15 15907 A 50 mg pill has a mass of A. 0.00731 oz B. 0.0563 oz C. 0.00176 oz D. 0.00563 oz 9 E. none of these 32 039812951077 0020 1700028 A 15 15909 32 A fifth of whiskey contains 129612970546 0020 9 A. 0.75 liters B. 0.84 liters C. 1.32 liters D. 1.06 liters E. none of these 1700029 E 15 15911 31 043304180114 A barometer measures A. volume of a gas B. density of mercury C. molecular motion D. temperature of the atmosphere 9 E. pressure of the atmosphere 0020 1700030 A 15 15914 31 139001141391 An apparatus for measuring the pressure of a gas in a vessel is a A. manometer B. gasometer C. Boyle's apparatus D. gas meter 9 E. none of these 0020 1700031 A 15 15917 31 019203980067 Which of the following is an intrinsic property of a substance? A. mass B. temperature C. volume D. pressure 9 E. none of these 1700032 C 15 15919 32 If there are 10 globs in a blot, and I have 20 blots, how many globs do I have? 9 A. 2 B. 0.50 C. 200 D. 30 E. none of these 0019 1700033 B 14 15921 31 0615 09 The wavelength of a wave is the wave velocity divided by the A. wave number C. wave amplitude 9 B. wave frequency D. value of the node 1700034 B 14 15924 31 0615 09 The frequency of any wave is A. the time it takes a whole wave to pass a particular point B. the number of crests which pass a stationary point in one second C. the number of wave nodes present in a given distance 9 D. the distance between two successive wave crests 0019 1720001 C 15 15928 31 014901500151 The metric system is superior to the English system of measurement in that A. measurements can be made more accurately with it B. 1000 cubic centimeters of water at 40 degrees C. weighs exactly 1000 grams C. multiples of the fundamental units are related by the factor 10 or a multiple of ten D. it includes familiar units of time E. one can get more kilometers per gallon of gasoline than 9 miles per gallon with any automobile ETS2 OS 1720002 B 14 15935 31 03510019800111 When two atoms react to form an ionic compound, we assume in accordance with the atomic theory that A. one or more pairs of electrons are shared in common between the two atom B. one or more electrons are transferred from one atom to the other C. the atoms are held together by the electrostatic force between protons and neutrons 9 D. the atoms are held together by the force of gravity ETS2WVW 1720003 D 15 15941 31 80018002 Which one of the following is not correct? 3 ___ A. there are 1000 milligrams in a gram B. there are 1000 milliliters in a liter C. there are 100 centimeters in a meter D. there are 100 millimeters in a centimeter 9 E. there are 1000 grams in a kilogram 11 ETS2 OS 1720004 B 14 15945 31 046308698004 A chemical balance is calibrated in A. cubic centimeters B. grams C. liters 9 D. inches 2WVW 1720005 A 15 15947 31 088601500385 Which of the following is a standard unit of length in the metric system? A. meter B. liter C. gram D. Celsius degree 9 E. none of these 0018 1720006 D 15 15949 31 01450150 0028 The prefix meaning 1/1000 of a unit is: A. kilo_ B. deci_ C. centi_ D. milli_ 9 E. none of these 1720007 D 15 15951 Weight units are A. mass units B. grams C. metric units D. force units 9 E. size units 31 044503850317 1720008 D A Joule is a 5 _2 9 A. kg m s 31 0388 15 15953 _1 B. newton m C. force unit 0020 0020 2 _2 D. kg m s 1720009 B 14 15955 32 019514001401 What is the volume in cubic centimeters of a cube which is 100 mm along each edge? 5 2 3 2 3 9 A. 10 B. 10 C. 100 D. 100 1720010 B 14 15958 52 19441956 One microlitre equals 5 _3 A. 10 litre B. 1 cubic millimetre C. 1 millilitre 5 _6 9 D. 10 cubic metre E. erg 0019 0055 1730001 C 15 15960 32 01430144800111 A liter is to a cubic centimeter as a meter is to a A. centimeter B. dekameter C. millimeter D. decimeter 9 E. micron ETS2 OS 1730002 B 15 15962 52 01880143800111 One cubic inch is equivalent to approximately A. .048 cubic centimeters B. 2.54 cubic centimeters ETS2 OS 9 C. 6.5 cubic centimeters C. 6.5 cubic centimeters D. 16 cubic centimeters E. 1000 cubic centimeters 1730003 C 15 15965 32 00390479800213 Gold can be beaten so thin that a square piece of leaf 10 cm 5 3 on a side weighs 0.0193 g. The density of gold is 19.3 g/cm , so the thickness of the leaf must be 5 _7 A. less than 10 cm. 5 _3 B. greater than 10 cm. 5 _6 _3 C. between 10 cm. and 10 cm 5 _4 _3 D. between 5 x 10 and 10 cm. 5 3 6 9 E. between 10 and 10 cm. 1730004 BCC 35 15972 72 02030186 1390 MACROITEM STEM 2The following items refer to the experimental use of a pycnometer 2(specific gravity bottle). In this case the object was to determine 2the density of an unknown solid in the form of small shot 2which could be poured into the bottle. Assume that the density of 5 3 water is 1 gm./cm. . The following data were collected 2Weight of empty bottle................................18.3 gm. 2Weight of bottle when filled with water...............43.3 gm. 2Weight of bottle when partly filled with shot.........67.2 gm. 2Weight of bottle with shot and water to fill 2the crevices..........................................77.3 gm. 0 Using the information given, answer the following questions. MACRO SUB_ITEM # 1 The volume of shot used was (in cc) A. 25.0 B. 14.9 C. 48.9 D. 10.1 1 E. none of these MACRO SUB_ITEM # 2 5 3 The density of the unknown shot in gm./cm. was calculated by A. 49.9/25 ETS2 OS ETS2 OS B. 48.9/10.1 C. 48.9/14.9 D. 67.2/14.9 2 E. none of these MACRO SUB_ITEM # 3 The best explanation of the use of a bottle stopper with a hole through the center is A. it helps to prevent breakage if hot water is used B. it allows for expansion when the temperature changes C. it permits complete filling of the bottle D. it helps to remind the student to keep the bottle upright while weighing 9 E. it admits air to the top of the water surface while weighing 1730005 C 14 15991 32 1944 One metric ton of molten sulfur is loaded on a barge at the rate of 1200 tons per hour. The loading rate in kg per minute is 9 A. 20 B. 100 C. 20000 D. 10000 E. 2000 1730006 B 15 15994 31 030614471804 One United State "standard" pound (avoirdupois) is equivalent to A. 543.6 grams B. 453.6 grams C. 354.6 grams 9 D. 534.6 grams E. 654.3 grams. 1730007 B 14 15997 31 18231291 One liter_atmosphere equals: 9 A. 19.2 Joules B. 101 Joules C. 4.18 Joules D. 8.31 Joules. 1730008 B 15 15999 32 04200144 The distance from the earth to the moon is 236,000 miles. What is the distance in meters? (1 km = 0.625 mile) 5 10 8 8 A. 3.78 x 10 m B. 3.78 x 10 m C. 2.36 x 10 m 5 5 8 9 D. 3.78 x 10 m E. 1.48 x 10 1730009 D 15 16003 32 How many significant digits are in the number 0.00754? 9 A. six B. five C. four D. three E. none of these 0055 0042 0043 0018 0028 1730010 A 15 16005 32 015004450441 Convert 65 mg to kilograms A. 0.000065 kg B. 0.0000065 kg C. 65 kg 9 D. 65,000 kg E. 65,000,000 kg 0028 1730011 C 15 16007 Convert 0.41 dg to cg 0028 32 015004450441 9 A. 0.041 cg B. 0.0041 cg C. 4.1 cg D. 41 cg E. 410 cg 1730012 D 15 16009 32 015004450441 Add the following masses: 2.000000 kg, 450 mg, 30.0 cg, 0.21 dg. What is the total mass in grams? A. 2000.690 g B. 2000.501 g C. 2001.160 g 9 D. 2000.771 g E. 2.771 g 0028 1730014 A 15 16014 32 01500445 Convert 20.0 inches to meters 9 A. 0.508 m B. 0.254 m C. 2.54 m D. 5.08 m E. 50.8 m 0028 1730015 D 15 16016 32 04710150 Convert 21.2 quarts to mL 9 A. 20.0 mL B. 200 mL C. 2000 mL D. 20,000 mL E. 21.2 mL 0028 1730016 E 15 16018 32 015005050391 Convert 0.00500 mile/hr to cm/min. A. 1.13 cm/min B. 1340 cm/min C. 2.23 cm/min 9 D. 0.223 cm/min E. 13.4 cm/min 0028 1730017 E 15 16020 32 079501500288 Convert 26.0 mg to grams. 9 A. 260 g B. 26.0 g C. 2.60 g D. 0.260 g E. 0.0260 g 0028 1730018 B 14 16022 32 044504710288 Approximately how many grams in 4 pounds? 9 A. 1816 B. 4000 C. 114 D. 0.0088 0026 1730019 C 15 16024 32 01430546 500 cc equals 9 A. 50 L B. 0.05 L C. 0.500 L D. 5.00 L 1730020 E 15 16026 293 mg equals A. 2930 g B. 293 000 kg C. 2.93 g D. 0.0293 g 9 E. 0.000 293 kg 32 0020 E. 500 L 079512911292 0020 1730021 E 15 16028 32 042003901293 A distance of 100 cm is approximately A. 12 inches B. 3 yards C. 1/10 of a mile 0020 9 D. 254 inches E. 1 yard 1730022 D 15 16030 One meter is equal to A. 10 decimeters B. 1000 mm C. 100 centimeters D. all of the above 9 E. none of the above 32 014412910390 0020 1730023 C 15 16032 32 129812990195 A box has the following dimensions: 50.0 cm by 0.100 m by 600 mm. The volume of the box is A. 30.0 ml B. 3000 cc C. 30.0 liters D. 300 liters 9 E. none of these 0020 1730024 D 15 16035 32 053503980186 80.0 ml of alcohol has a mass of 63.3 g. Its density is A. 1.26 g/cc B. 0.126 g/ml C. 0.802 g/cc D. 0.791 g/ml 9 E. none of these 0020 1730025 B 15 16037 32 139613970390 5 3 Given that 10 microns = 1 mm 5 8 10 Angstroms = 1 cm how many microns are in one Angstrom? 5 4 _4 5 _5 11 9 A. 10 B. 10 C. 10 C. 10 E. 10 0019 1730026 D 15 16040 52 00140589 A 10_carat diamond would weigh A. 200 mg B. 10 mg C. 10 g D. 2 g 9 E. no correct response is given. 1730027 A 14 16042 One btu/lb deg F equals A. 1 cal/g deg C B. 252 cal 52 194419510439 0040 0055 9 C. 252 cal x 454 g/lb D. 252 cal/454g/lb 1730028 E 15 16044 52 071101 A car is rated with a highway mileage of 41 miles per gallon of gasoline. Given that 1 mile = 1.6093 kilometers, how many liters of gasoline will be needed for a highway trip of 500 kilometers? 5 3 9 A. 74 B. 3.0 x 10 C. 2.0 D. 2.0 E. 29 0064 1730029 C 15 16048 52 071101 A soft drink bottler distributes its product in 2.00_liter bottles. What is the volume in quarts? 9 A. 1.89 B. 2.00 C. 2.11 D. 8.00 E. 9.39 0064 1730030 D 15 16051 52 071101 A typical freshman chemistry exam consists of pages measuring 8 and 1/2 by 11 inches. What is the approximate area (reported to one significant figure) of one side such a page in square meters? 9 A. 0.001 B. 2 C. 0.01 D. 0.06 E. 0.0006 0064 1730031 B 15 16055 52 071101 The density of lead, 11.2 g/cubic centimeter, when expressed 5 3 in lb/ft is: 9 A. 2.60 B. 699 C. 11.2 D. 0.179 E. 0.753 0064 1730032 C 15 16057 52 071101 A latex semigloss enamel paint is advertised as having a coverage 5 2 of 450 ft /gal when used on sealed surfaces. What is the average thickness of the coat of paint in millimeters? 9 A. 10.1 B. 188 C. 0.0905 D. 0.378 E. 1.01 0064 1730033 E 15 16061 one cm is the same as A. 100 mm B. 2.54 in 9 E. none of these 0064 52 C. 1 mL 071101 D. 0.1 m 1730034 A 15 16063 52 071101 Suppose that a standard snail's pace is measured to be 0.040 ft/min. The snail's pace measured in cm/sec would be: 9 A. 0.020 B. 0.010 C. 0.079 D. 0.19 E. 0.60 0064 1730035 A 15 16066 52 071101 A velocity of 98 ft/sec corresponds (in units of km/sec) to 5 _2 A. about 3 x 10 B. about 2 C. about 0.005 5 2 9 D. about 5 x 10 E. about 0.8 0064 1730036 A 15 16069 52 071101 In order to convert square feet into square centimeters the area in square feet should be multiplied by 9 A. 929 B. 30.5 C. 77.4 D. 366 E. 22.3 0064 1730037 B 15 16072 52 071101 5 3 A metallic sphere (V=4/3 pi r ) has a diameter of 0.200 inches and weighs 0.0066 oz. What is the density of the metal in g/cc? 9 A. 18 B. 2.7 C. 0.18 D. 3.6 E. 5.6 1730038 B 15 16075 52 071101 One cubic centimeter is the same as 5 3 A. 100 mm B. 1 ml C. 0.4 in D. 1 liter 9 E. none of these 0064 0064 1731001 B 15 16078 52 The base units of the International System of Units (S.I.) refer to length, mass, time, temperature, electric current, amount of substance and luminous intensity. Which of the following DERIVED quantities can be gotten from mass and length only? 9 A. pressure B. density C. force D. concentration E. volume OS82 1732001 E 15 16083 52 A nanometer is to a millimeter as a meter is to a _____meter. 9 A. centi B. deci C. deka D. kilo E. mega OS82 1740001 DCE 35 16085 31 0286800180031290 MACROITEM STEM 2Choose from the key list the device or mechanism 2that is most dependent upon the principle as stated. 2 A. Photoelectric cell 2 B. Photographic light meter 2 C. Optical pyrometer 2 D. Thermostat 0 E. Thermocouple MACRO SUB_ITEM # 1 ETS2WVW Two metals of different coefficients of linear expansion riveted or welded together will warp or bend under 1 changes in temperature. MACRO SUB_ITEM # 2 The color and intensity of light emitted from a heated 2 object depends on the temperature of the object. MACRO SUB_ITEM # 3 An electric current will flow through two wires of dissimilar metal if the junctions are kept at different 9 temperatures. 1740002 E 15 16093 52 01618001800312 A room thermometer graduated in the Fahrenheit scale reads 40 degrees. Outside the window a Centigrade thermometer reads 1.8 degrees. The temperature difference in Fahrenheit degrees between the inside and outside is 9 A. 38.2 B. 35.2 C. 33.0 D. 12.2 E. 4.8 ETS2WVW 1740003 A 15 16097 52 01618001800312 Using the appropriate formula, what is the Centigrade equivalent of 23 deg. F? A. _5 deg. C B. 30 5/9 deg. C. C. 73 2/5 deg. C. D. 99 deg. C. 9 E. _19 2/9 Deg. C. ETS2WVW 1740004 E 15 16100 52 01618001800312 A pilot takes the temperature in the cockpit of his plane and finds it to be 50 degrees Fahrenheit. He reads the outside air 3 __________ temperature on the Centigrade scale and finds it to be 10 degrees 3 __________ Centigrade. The temperature difference in degrees Fahrenheit between 3__________ __________ the inside and outside is A. 75.6 B. 23.3 C. 37.6 D. 12.3 9 E. there is no difference ETS2WVW 1740005 A 15 16107 32 01618001800312 One could take a bath comfortably in water at a temperature of 5 o o 9 A. 303 K B. 75 C C. 95 K D. 150 F E. 250 K ETS2WVW 1740006 AE 25 16110 52 0161 5290 MACROITEM STEM 2Answer the questions below according to the diagram below 2 I I 2 I I 2 100 degrees _ _ _ _ _ b.p. _ _ _ _ _ 185 degrees 2 I I 2 I I 2 I I 2 t" _ _ _ _ _ _ _ _ _ _ _ _ 145 degrees 2 I I 2 I I 2 I I 2 I I 2 I I 2 I I 2 C I I X 2 I I 2 I I 2 I I 2 I I 2 I I 2 20 degrees _ _ _ _ _ _ _ _ _ _ _ _ t 2 I I 2 I I 2 I I 2 0 _ _ _ _ _ f.p. _ _ _ _ _ 25 degrees 2 I I 2 I I 2C represents a centigrade thermometer and X a thermometer 2on which the boiling point of water at 76 cms. pressure has 0 been marked 185 degrees and the freezing point 25 degrees. MACRO SUB_ITEM # 1 When the Centigrade thermometer reads 20 degrees the corresponding reading t on the X thermometer is A. 32 degrees B. 37 degrees C. 57 degrees D. 67 degrees 1 E. 52 degrees MACRO SUB_ITEM # 2 When the X thermometer reads 145 degrees, the corresponding reading t on the Centigrade thermometer is A. 50 degrees B. 64 degrees ETS2WVW 9 C. 72 degrees D. 75 degrees E. 90 degrees 1740007 AC 25 16136 31 02860649 1390 MACROITEM STEM 2A householder is interested in increasing the effiency of 2his heating system, consisting of a gas burner used in conjunction 2with a circulating hot water system. He knows that 2the combustion of the fuel used is approximated closely by the equation CH _ 2O ___> CO + 2H O in which 4 4 2 2 2 CH is methane gas. The methane and air (20% oxygen) are forced 4 4 0 into the furnace from separate pipes. MACRO SUB_ITEM # 1 Some liquids heat more quickly than water; that is, they require less heat for the same temperature rise. Is there a great advantage in circulating such liquids? A. No; they would also release less heat on cooling. B. No; they would produce excessive heat throughout the house. C. No; they would boil at too low a temperature. D. Yes; less fuel would be needed for the same heating effect. E. Yes; they would retain their heat better and reduce 1 the amount of insulation needed. MACRO SUB_ITEM # 2 For most efficient transfer of heat, water pipes in a furnace should A. be coated with a white heat_resisting enamel B. be covered with asbestos C. have a rough blackened surface D. have a bright polished surface 9 E. be blacked inside and brightly polished outside 1740008 ECDAB 55 16152 52 MACROITEM STEM Use the key below to match the appropriate property to each of the units of measurement listed beyond the key. 0 A. mass B. length C. time D. temperature E. volume MACRO SUB_ITEM # 1 1 cubic centimeter MACRO SUB_ITEM # 2 2 second MACRO SUB_ITEM # 3 5o ETS2WVW OS 3 C MACRO SUB_ITEM # 4 4 gram MACRO SUB_ITEM # 5 9 kilometer 1740009 B 15 16156 52 The boiling and freezing points of water were determined and marked on the glass of a new, and as yet "blank" thermometer. If these two points are 9 cm apart, how far apart would the degree marking be if it were desired to make a Celsius thermometer? 9 A. 9/180 cm B. 0.09 cm C. 0.90 cm D. 0.562 cm E. 0.286 cm OS86 1740010 C 15 16161 31 01610008800111 The temperature at which water boils may be increased by A. decreasing the area of exposed surface B. insulating the container C. adding salt D. raising the gas flame 9 E. dissolving alcohol in the water ETS2 OS 1740011 C 15 16164 31 01610159800111 The temperature in a medium refers to A. the quantity of molecules present B. the total potential energy of the molecules C. the average kinetic energy of the molecules D. the total caloric content of the individual molecules 9 E. the average potential energy of the molecules ETS2 OS 1740012 E 15 16168 31 04860114800131 The absolute zero is considered to be _273 degrees C. because A. all gases liquefy before that temperature is reached B. that is the lowest temperature that has ever been reached experimentally C. the Centigrade and Fahrenheit scales come together at that point D. Dulong and Petit's law holds at this point E. the pressure of a constant volume of gas at 0 degrees decreases 1/273 for every degree C of temperature 9 decrease ETS2 OS 1740013 C 15 16175 51 04870161800111 The critical temperature of a substance is A. the temperature required to liquefy the gas at one atmosphere pressure B. the temperature at which the substance begins to decompose ETS2 OS 9 C. the highest temperature at which the sustance can be a liquid D. the temperature at which the liquid evaporates E. the lowest temperature at which the substance may be liquefied 1740014 A 15 16181 31 01618001800311 5 o o o The freezing point is 32 F, or 0 C. The boiling point is 212 F, 5 o or 100 C. By which one of the following formulas could a 5 o o temperature reading in F be converted to its equivalent C reading? A. C = (5/9)(F _ 32) C. C = (9/5)F + 32 E. C = (5/9)F _ 32 9 B. F = (9/5)C _ 32 D. F = (5/9)C _ 32 1740015 C 15 16187 32 01618001800312 What Fahrenheit temperature is equivalent to 373 degrees Kelvin? A. 32 degrees Fahrenheit B. 122 degrees Fahrenheit C. 212 degrees Fahrenheit D. 0 degrees Fahrenheit 9 E. 273 degrees Fahrenheit 1740016 C 15 16190 31 06548001800312 If a sample of gas is heated in a rigid container A. it may change its weight B. it may increase in volume C. it must increase its pressure D. it must increase its density 9 E. it must increase its volume ETS2WVW ETS2WVW ETS2WVW 1740017 B 14 16193 31 083608378003 Identify the thermometer scale on which the zero level is 273 degrees above the point of no molecular motion of matter A. Reamur B. Celsius C. Kelvin 9 D. Fahrenheit 2WVW 1740018 B 15 16196 32 029901610441 Convert 35.0 degrees C to degrees F A. 121 degrees F B. 95.0 degrees F C. 1.67 degrees F 9 D. 37.2 degrees F E. 51.4 degrees F 0028 1740019 C 15 16198 32 029901610441 Convert 900 degrees K to degrees C A. 673 degrees C B. 527 degrees C C. 627 degrees C 0028 9 D. 1190 degrees C E. 1173 degrees C 1740020 D 15 16200 32 015001610288 Convert 35.0 degrees C to degrees F. A. 121 degrees F B. 1.67 degrees F C. 37.2 degrees F 9 D. 95.0 degrees F E. 63.0 degrees F 0028 1740021 A 15 16202 _22 degrees F equals A. _30 degrees C B. _97 degrees C C. _29.9 degrees C D. 6.6 degrees C 9 E. none of these 32 054412910299 0020 1740022 C 15 16204 5 degrees C equals A. _21 degrees F B. 15.4 degrees F C. 41 degrees F D. 278 degrees F 9 E. none of these 32 054402991304 0020 1740023 A 15 16206 32 043804981315 Liquid hydrogen boils at 20 degrees K. What is the boiling temperature on the Fahrenheit scale? 9 A. _423 B. _253 C. _293 D. 293 E. _901 0019 1740024 D 15 16208 32 016114471304 5 o A temperature reading of _10 C is equivalent to 5 o o o 9 A. _10 F B. 283 K C. 483 R D. 14 F 0035 E. 273 K 1740025 B 15 16211 51 0161 1653 The belief that an absolute zero of temperature exists depends on the fact that A. most gases cannot be cooled to below that temperature B. extrapolation of the V vs. T curve for all gases gives the same T at V = 0 C. at the absolute zero, all motion ceases D. all gases liquify before reaching the absolute zero 9 E. all of the above contribute to the belief 1740026 C 5 14 16217 72 1944 o 0034 0055 The freezing point of mercury is _39 C and the freezing point of 5 o cadmium is 321 C. If you devised a temperature scale using the 5 o freezing point of mercury as 0 N and the freezing point of cad_ 5 o mium as 100 N, what would be the Celsius temperature correspond_ 5 o ing to 90 N? 5 o A. _6.6 C 5 o B. 254 C 5 o C. 285 C 5 o 9 D. 324 C 1740027 A 15 16224 52 071101 100.0 g of liquid water at 95.0 degrees C is mixed with l35.0 g of liquid water at 13.6 degrees C. Assuming that no heat is lost to the surroundings, what would be the resultant temperature of the mixture? 5 o o o o o 9 A. 48.2 C B. 42.4 C C. 38.7 C D. 35.5 C E. 54.3 C 0064 1740028 C 15 16229 52 071101 An increase in temperature of 15 degrees C corresponds to an increase in temperature of ____degrees F. 9 A. 15 B. 8.3 C. 27 D. 59 E. 32 0064 1740029 A 15 16232 52 071101 Experimentally it is found that 163 kJ of thermal energy (heat) is evolved when 10.0 g of Al O is formed from the elements. To what 4 23 5 o final temperature would 4.00 kg of water at 20 C be heated by absorbing this quantity of heat? 5 o (specific heat of water = 4.18 J/g_ C) 5 o o o o o 9 A. 29.5 C B. 10.8 C C. 28.7 C D. 28.5 C E. 20.02 C 0064 1740030 D 15 45141 52 071101 5 o A 10.0_kg piece of iron at 50.0 C is placed in 1.00 kg water at 0064 5 o 10.0 C. The iron and water will come to the same temperature. What is that temperature, assuming that no heat is lost to the 5 _1 o outside? (The specific heat of iron is 0.481 J g C) 5 o o o o o 9 A. 13.4 C B. 25.0 C C. 30.0 C D. 31.4 C E. 43.1 C 1760001 B 14 16245 72 02050206800113 Six hundred grams of substance A at 50 degrees C was mixed with 600 grams of substance B at 30 degrees C in a calorimeter. The equilibrium temperature was 43 degrees C. Disregarding any heat change in the calorimeter, the specific heat of substance A can be calculated to be A. equal to that of substance B B. higher than that of substance B C. lower than that of substance B D. a comparison of the specific heats cannot be made from this 9 data 1760002 ADBCA 54 16252 51 0286800180031490 MACROITEM STEM 2The following passage concerns the caloric theory 2of heat. The items concern an evaluation of the theory. 2Read the passage carefully before answering. 2The caloric theory of heat was the most widely accepted theory 2of heat in the early 19th century. It was recognized by a large 2majority of the leading men of science, many of whom contributed 2greatly to the advance of science in their time. It stated 2 A. heat was a fluid, caloric, which was made up of 2 particles or corpuscles. 2 B. the corpuscles were able to push their way between 2 the particles (molecules) of matter. 2 C. the corpuscles were mutually repellent (much as 2 the electrons of negative electricty). 2 D. all matter attracted the corpuscles but some matter 2 more strongly than other matter. 2 E. the fluid was indestructible and could not be created. 3 _____ ___ __ _______ 2Select from the key the most appropriate phrase. (Assume the 2caloric theory to postulate only the points given above.) 2 A. The statement is true and can be explained by both 3 ____ ___ 2 the caloric theory and the kinetic theory. 2 B. The statement is true and can be explained by the 3 ____ ___ ETS2 OS ETS2WVW 2 kinetic theory but not by the caloric theory. 2 C. The statement is false and can be shown to be false 3 _____ 2 by either the kinetic or caloric theories. 3 ______ 2 D. The statement is false but if true would be a point 3 _____ 0 in favor of the caloric theory. MACRO SUB_ITEM # 1 When two substances of unequal temperature are placed 1 in contact the colder one is warmed and the warmer one cooled. MACRO SUB_ITEM # 2 Only a certain amount of heat may be obtained from a body by friction, when that body is rubbed, even though the friction does not continue long enough to wear the 2 body away. MACRO SUB_ITEM # 3 3 Iron expands when it is heated. MACRO SUB_ITEM # 4 Two cakes of ice may be melted by friction if they are rubbed together rapidly even though the temperature 4 of the surroundings is below 32 degrees F. MACRO SUB_ITEM # 5 9 Milk when churned will rise in temperature. 1760003 B 14 16280 31 02860161800111 Regions near large bodies of water are much less subject to wide variations of temperature than inland regions because of the A. low heat capacity of water B. high heat capacity of water C. low heat conductivity of water 9 D. high heat conductivity of water ETS2WVW 1760004 D 15 16284 31 02868001800311 Heat transfer by convection requires A. differences in thermal conductivity B. temperatures above freezing C. a change of state D. differences in density within the medium 9 E. that the medium be in the form of a gas ETS2WVW 1760005 B 15 16288 32 043902860161 How many calories of heat are required to raise the temperature of 20.0 g of water from 40 degrees to 60 degrees C? A. 40 cal B. 400 cal 0020 9 C. 20 cal D. 200 cal E. none of these 1760006 B 15 16291 52 071101 A coffee cup containing 100 cc of liquid water at 100 degrees F is heated to a final temperature of 180 degrees F. The number of joules absorbed by the water is 5 4 4 _10 A. 6.0 x 10 B. 1.9 x 10 C. 6.0 x 10 5 3 _10 9 D. 1.1 x 10 E. 1.9 x 10 0064 1760007 B 15 16296 52 071101 A 200 g metal bar requires 1.200 kcal to change its temperature from 0 degrees C to 100 degrees C. What is the specific heat of the metal in J/g_degree C? 9 A. 69.9 B. 0.251 C. 10.0 D. 0.0837 E. none of these 0064 1760008 A 15 16299 52 071101 200 g of copper shot at 25.0 degree C is added to 200 ml of water at 80.0 degree C. The final temperature of the mixture is 75.3 degree C. Assuming that the specific heat of water is 1.0 cal/ g_degree C and that no heat is lost to or gained from the surroundings, what is the specific heat of copper metal in cal/g_degree C? 9 A. 0.093 B. 0.10 C. 1.0 D. 10 E. none of these 0064 1770001 E 15 16305 31 06630054800111 The spectroscope A. is most useful to the chemist in studying the light emitted by incandescent solids B. is used for the analysis of x_rays C. is only useful for the analysis of molecules D. makes use of the tyndall effect E. causes light of different wave_lengths to follow 9 different paths through a prism ETS2 OS 1770002 D 15 16310 31 03300627800111 In the electromagnetic spectrum A. ultra_violet has longer wave lengths than the infra_red B. blue light is of higher frequency than x_rays C. radio waves have shorter wave lengths than gamma rays D. gamma rays have higher frequency than infra_red ETS2 OS 9 E. cosmic rays are low_frequency radio waves 1770003 B 14 16315 31 033006638003 The characteristic color spectrum for an element is readily identified through the use of one of the following devices A. electroscope B. spectroscope C. microscope 9 D. optical bench 1770004 C 15 16318 51 00540615 Small objects in a microscope can be observed with better resolution with blue light rather than red because: A. many men are red_green colorblind. B. blue light is more intense than red light. C. the wavelength of blue light is shorter than the wavelength of red light. D. the wavelength of red light is shorter than the wavelength of blue light. 9 E. blue light is dispersed more easily than red light. 1770005 C 14 16324 31 Loudness in sound corresponds in light to A. color B. doppler effect C. brightness 9 D. frequency 12 2WVW 0047 ETS2JPB 1770006 D 14 16326 31 050504290054 The speed of light in space always has the value A. 1000 kilometers per hour B. 32 feet per second 5 2 C. 3.4 x 10 meters per second 5 8 D. 3 x 10 m/sec. 9 E. 650 miles per hour 0026 1770007 B 15 16329 31 042900541322 The velocity of light in a vacuum is 5 8 10 A. 299 792.5 cm/s B. 3 x 10 m/s C. 3 x 10 km/s 5 10 8 9 D. 3 x 10 m/s E. 3 x 10 cm/s 0020 1770008 E 0020 15 16332 31 005413400159 Light is A. a form of energy B. electromagnetic radiation C. photons D. A, B and C 9 E. none of these 1770009 C 15 16334 51 134101591202 Which of the following has the greatest amount of energy per photon? A. x_rays B. ultraviolet light C. gamma rays D. infraredlight 9 E. visible light 0020 1770010 A 15 16337 51 015913421291 Energy equals Planck's constant times A. c/lamda B. mc 5 2 C. mc D. c/lambda 9 E. none of these 0020 1770011 E 15 16339 51 Photons are A. the same as quanta B. particles of light C. have energy=hc/lambda 5 2 D. have energy = mc 9 E. all of these 0020 062403650054 1770012 A 15 16342 51 043606250663 An instrument used to separate and display, in the order of increasing wavelengths, the component parts of light coming from a radiation source is A. a spectroscope B. an electromagnetic spectrum C. prism meter D. mass spectrograph 9 E. none of these 0020 1770013 D 15 16346 51 134306641344 When sunlight passes through a glass prism one sees a 0020 9 A. line spectrum B. absorption spectrum C. mercury spectrum D. continuous spectrum E. emission spectrum 1770014 C 15 16349 31 059001590627 Electromagnetic radiation increases in energy in the order 3 ______ A. ultraviolet < visible < infrared < x_ray B. x_ray < ultraviolet < visible < infrared C. visible < ultraviolet < x_ray < gamma ray D. ultraviolet < visible < x_ray < gamma ray 9 E. all electromagnetic radiation is of the same energy 0034 1770015 B 14 16354 31 0615 05 The wavelength of any wave is A. the length of time it takes one wave to travel a set distance B. the distance between two successive crests of the wave C. the distance between two successive nodes of a wave 9 D. the point of zero amplitude on a wave 1770016 C 14 16358 31 0615 05 The wavelength of any wave is A. the wave frequency times the wave velocity B. the wave frequency divided by the wave velocity C. the wave velocity divided by the wave frequency 9 D. the wave frequency plus the wave velocity 1770017 B 14 16362 31 0615 The accepted symbol for wavelength is A. nu C. theta B. lambda D. psi 9 E. alpha 05 1780001 C 15 16364 52 01950158800112 The volume of 50 grams of sulfuric acid, specific gravity, 1.86 is A. 83 ml. B. 1.86 times the molecular weight C. 26.9 ml. D. 26.9 g. 9 E. none of these values ETS2 OS 1780002 BC 25 16367 MACROITEM STEM ETS2 OS 52 01580015 1390 2A piece of metal weighs 100 gm. in air, 60 gm. in water, and 70 gm. 5 3 when immersed in gasoline. (The density of water is 1 gm./cm. ) 0 Using this information, answer the following questions. MACRO SUB_ITEM # 1 The specific gravity of the above metal is A. 0.6 B. 2.5 C. 3.3 D. 10.0 1 E. none of these MACRO SUB_ITEM # 2 the volume of gasoline displaced by the above piece of metal is 5 3 A. 10 cm. 3 B. 3/ cm. 5 3 C. 40 cm. 5 3 D. 50 cm. 9 E. none of these 1780003 C 14 16375 32 One cubic foot of water weighs A. 33_1/3 lbs. B. 64.2 lbs. C. 62.4 lbs. 9 D. 8 lbs. 00088001800211 1780004 BBBDC 55 16377 52 0445019501581390 MACROITEM STEM 2A piece of rock weighs 100 gm. in air. When it is immersed in 2water, the buoyancy force is 40 gm. and when it is immersed in an 2unknown liquid it weighs only 70 gm. 0 Based on this information, answer the following questions. MACRO SUB_ITEM # 1 The weight in gm. of the water displaced is equal to A. 30 B. 40 C. 60 D. 70 1 E. none of these MACRO SUB_ITEM # 2 5 3 The volume in cm. Of the unknown liquid displaced is equal to ETS2 OS ETS2 OS A. 30 B. 40 C. 60 D. 70 2 E. none of these MACRO SUB_ITEM # 3 5 3 The volume of rock in cm. A. 30 B. 40 C. 60 D. 70 3 E. None of these MACRO SUB_ITEM # 4 The specific gravity of the unknown liquid is A. 30 B. 57 C. 70 D. 75 4 E. some other value MACRO SUB_ITEM # 5 The density of the rock is 5 3 A. less than 62.4 lb./ft. 5 3 B. 1.75 gm./cm. 5 3 C. 2.50 gm./cm. 5 3 D. 1.67 gm./cm. 9 E. some other value 1780005 CB 25 16390 52 0446047801861390 MACROITEM STEM 2Some boys playing with a floating rectangular raft noticed that it 2projected 1/10 ft. out of water, but when they got on it, the raft 2just barely floated. The combined weight of the boys was 187.5 lbs. 2The density of the water is 62.5 pounds per cubic foot. 0 Using this information, answer the following questions. MACRO SUB_ITEM # 1 When the boys got on the raft, the additional volume of water displaced was A. 18.75 cu. ft. B. .30 cu. ft. C. 3.0 cu. ft. D. 30 cu. ft. ETS2 OS 1 E. none of these MACRO SUB_ITEM # 2 The area of cross section of the raft must have been A. 3 sq. ft. B. 30 sq. ft. C. 6.25 ft. D. 18.75 sq. ft. 9 E. None of these 1780006 C 15 16399 31 01860435800111 Which one of these is true concerning density? 5 3 A. The density of water in lb./per ft. has the same value 5 3 numerically when measured in gm./per cm. . B. Density and specific gravity have the same meaning. C. In metric units of measurement, density and specific gravity have the same numerical value. D. The density of water is greater than that of any other liquid. 9 E. Density is a ratio number. ETS2 OS 1780007 C 15 16406 31 04338001800211 Four of these are related in some way. Which one is not? 3 ___ A. hydrometer B. Archimedes C. barometer D. density 9 E. specific gravity ETS2 OS 1780008 B 15 16409 32 04130008800112 Comparing equal volumes of mercury and water, one cubic foot of mercury weighs A. 848.64 lbs. B. 968 lbs. C. 13.6 lbs. D. 462 lbs. 9 E. 1204 lbs. ETS2 OS 1780009 B 14 16412 32 00088001800311 50 cubic centimeters of water weighs 9 A. 62.4 g B. 50 g C. 25 g D. 88 g ETS2 OS 1780010 C 14 16414 32 04140186800112 If coal has a specific gravity of 1.3, a cubic foot of coal weighs ETS2 OS 9 A. 62.4 lbs. B. 72 lbs. C. 81.12 lbs. D. 2184.24 lbs. 1780011 A 14 16416 32 01860165800112 If ice has a density of .9 then a cubic foot of ice weighs A. 56.16 lbs. B. 60.2 Lbs. C. 71.3 Lbs. 9 D. 43.08 Lbs. ETS2 OS 1780012 C 14 16418 32 013800188001 To standardize the concentration of a salt solution by adding salt until the solution will float an egg is based on the assumption that A. all eggs have equal volume B. all eggs have equal weight C. all eggs have equal density 9 D. all eggs are about the same shape ETS2 OS 1780013 A 14 16422 32 01960478800113 A paper bag is fully inflated with hydrogen and so weighted that it will float half way between the floor and ceiling of a high auditorium of still air. If the average air temperature of the auditorium is raised 10 degrees F., the bag will A. float lower B. float higher C. remain at the same height D. the bag cannot be made to float half way to the ceiling. It 9 will either rise all of the way or not rise at all. ETS2 OS 1780014 B 15 16428 32 00390158800113 Gold has a specific gravity of 19.3. What is the weight, in grams, of 10 cubic centimeters of gold? A. 19.3 B. 193 C. 393 D. 493 9 E. 593 ETS2 OS 1780015 C 15 16431 32 01950158800113 If an object floats in water with exactly one_half its volume submerged, the specific gravity of the object A. cannot be determined unless the total volume is known B. cannot be determined unless the weight is known ETS2 OS 9 C. is one_half D. is one E. is two 1780016 A 15 16435 32 00080186800212 Water has a density of 62.4 lbs. per cubic foot. If the specific gravity of a piece of cork is .25, a cubic foot of cork weighs A. 15.6 lbs. B. 46.8 lbs. C. 62.15 lbs. D. 78 lbs. 9 E. None of these answers ETS2 OS 1780017 E 15 16438 52 00080186800112 Water has a density of 62.4 lbs. per cubic foot. A certain sample of ore has a specific gravity of 2.5. Therefore its density is A. 2.5 lbs. per cu. Ft. B. 2.5 grams per cu. ft. C. 24.76 lbs. per cu. ft. D. 64.9 lbs. per cu. ft. 9 E. 156 lbs. per cu. ft. ETS2 OS 1780018 B 15 16442 32 01860158800112 If the density of a substance is 9 grams per cu. cm., its specific gravity is (density of water is 62.4 lb. per cu. ft.) 5 3 A. 9 gm. per cm. B. 9 C. 9 lb. per cu. ft. D. 561.6 9 E. 561.5 lb. per cu. ft. 2 OS 1780019 A 15 16446 32 01580016800112 The specific gravity of aluminum is 2.6. The weight of 5 cu. ft. of aluminum is about A. 812.5 lbs. B. 5 lbs. C. 130 lbs. D. 13 lbs. 9 E. 32.5 lbs. 2 OS 1780020 D 15 16449 32 80010186019512 A certain mineral has a density of 300 lbs/cu. ft. The volume of a block of it which weighs 450 lbs. is A. 450 cu. ft. B. 0.5 cu. ft. 2 OS 9 C. 2/3 cu. ft. D. 1.5 cu. ft. E. 4.5 cu. ft. 1780021 CE 25 16452 52 0477019501861390 MACROITEM STEM Using this information, answer the following questions. A mineral specimen weighs 300 gm. in air, 180 gm. when submerged 0 in water, and 210 gm. in gasoline. MACRO SUB_ITEM # 1 The volume of gasoline displaced by the mineral is 5 3 A. 30 cm. 5 3 B. 90 cm. 5 3 C. 120 cm. 5 3 D. 150 cm. 1 E. None of these MACRO SUB_ITEM # 2 The density of the specimen in the preceding question is 5 3 A. 1.67 gm./cm. 5 3 B. 3.33 gm./cm 5 3 C. 0.40 gm./cm. 5 3 D. 1.0 gm./cm. 5 3 9 E. 1.50 gm./cm. ETS2 OS 1780022 D 14 16460 31 An ice cube will float highest in A. alcohol B. gasoline C. fresh water 9 D. salt water 2WVW 80038004 1780023 D 14 16462 31 011301868004 The property of a gas usually expressed in the units, grams _ per _ liter, is the A. specific gravity B. mole C. molar volume 2 OS 9 D. density 1780024 E 15 16465 32 018610970015 What is the density of a sample of metal that weighed 50.0 grams and which, on immersion, raised the water level in a graduated cylinder from 10.3 ml to 16.2 ml? 9 A. .12 g/ml B. 8 g/ml C. 85 g/ml D. 5.5 g/ml E. 8.47 g/ml. 0042 1780025 C 15 16469 31 01860284 The density of a substance divided by the density of some substance taken as a standard is the definition of: A. specific heat B. a calorie C. specific gravity 9 D. density E. none of these 0028 1780026 E 15 16472 32 01860158 Calculate the volume in milliliters at 18 degrees C occupied by 75 g of sulfuric acid. 5 o 5 18 C d = 1.83 g/ml 9 A. 140 ml B. 14 ml C. 0.024 ml D. 4.1 ml E. 41 ml 0028 1780027 C 15 16475 32 01860158 An experiment calls for 252 ml glycerol 5 o 5 20 C/4 sp gr = 1.26 . How many grams would be required? 9 A. 200 g B. 300 g C. 318 g D. 342 g E. 252 g 0028 1780028 A 15 16478 32 01860158 Calculate the number of milliliters at 25 degrees C in 0.0355 5 o 5 25 C/4 kg of ethyl ether. Sp gr = 0.71 9 A. 50 ml B. 25 ml C. 5.0 ml D. 2.5 ml E. 71 ml 0028 1780029 C 15 16482 52 018601500288 Carbon tetrachloride has a density of 1.59 g/ml. How many milliliters will 0.282 lb occupy? 9 A. 890 ml B. 390 ml C. 80.5 ml D. 17.8 ml E. 101 ml 1780030 C 15 16485 31 01860008 The density of water is A. less than that of ice at 0 degrees C B. constant at all temperatures C. a maximum at 3.98 degrees C 0028 0020 9 D. a minimum at 3.98 degrees C E. none of these 1780031 A 15 16488 32 018601940195 What is the density of a metal alloy, 1500 g of which has a volume of 300 cc? A. 5.00 g/ml B. 0.450 g/ml C. 0.500 g/cc D. 4.50 g/cc 9 E. none of these 1780032 C 15 16491 32 Expressed with an accuracy of three significant figures, the number 345689.7 is 5 6 5 5 4 6 9 A. 3.46x10 B. 3.45x10 C. 3.46x10 D. 3.45x10 E. 3.45x10 0020 0020 1780033 B 15 16494 32 018613981399 A piece of nickel weighing 44.5 g displaces 5.0 ml of water when submerged. The density of nickel is __________g/ml. 9 A. 0.11 B. 8.9 C. 4.45 D. 5.0 E. 1.1 0019 1780034 C 14 16497 32 019201860398 A substance X has a density of 3 g/ml. Substance Y has a density of 2 g/ml. If you had 250 g of X and 125 ml of Y, then it follows that you have A. a greater mass of X than Y B. a greater mass of Y than X C. equal masses of both substances 9 D. no way of telling how to compare the masses of the two 0019 1780035 A 15 16502 32 043801860195 A liquid has a density of 2.5 g/ml. What volume in ml would 500 mg of this substance occupy? 9 A. 0.20 B. 1.25 C. 2.5 D. 5.0 E. none of these 0019 1780036 D 15 16505 32 047701860195 A certain mineral has a density of 300 lbs/cu. ft. The volume of a block of it which weighs 450 lbs. is A. 450 cu. ft. B. 0.5 cu. ft. C. 2/3 cu. ft. 9 D. 1.5 cu. ft. E. 4.5 cu. ft. 0035 1780037 B 14 16508 32 01860195 05 What is the volume of a cube which has a density of 4 g/cc and a mass of 5 grams? 9 A. 0.8 cc's B. 1.25 cc's C. 20.0 cc's D. 9 cc's 1780038 A 15 16510 32 01860195 05 5 3 What is the volume (in cm ) of a block of manganese which has a 5 3 density of 7.0 g/cm and a mass of 3.5 g? 9 A. 0.50 B. 2.0 C. 10.5 D. 24.5 E. 49.0 1780039 D 14 16513 32 01860195 05 The density of a 3 cc piece of boron is 4.0 g/cc. What is its mass? A. 0.75 g C. 7.0 g 9 B. 1.33 g D. 12.0 g 1780040 D 14 16515 32 01860195 05 An 8 cc block has a density of 2 g/cc. What is its mass A. 0.25 g C. 6.0 g 9 B. 4.0 g D. 16.0 g 1780041 B 14 16517 32 01860195 05 The density of a 2 cc block of metal is 6.0 g/cc. What is the density of a 4 cc block of this same metal 9 A. 3.0 g/cc B. 6.0 g/cc C. 8.0 g/cc D. 12.0 g/cc 1780042 B 14 16520 32 01860195 05 The volume of a 6 g block of metal is 2 cc's. What is the density? 9 A. 0.33 g/cc B. 3.0 g/cc C. 4.0 g/cc D. 12.0 g/cc 1780043 A 14 16522 32 01860195 05 The mass of a 5 cc block is 2 g. What is the density of this block? 9 A. 0.4 g/cc B. 2.5 g/cc C. 4.0 g/cc D. 10.0 g/cc 1780044 D 14 16524 52 1944 5 3 3 A 100 cm graduated cylinder has water to the 35.0 cm mark; 5 _3 20.0g of sand (density = 2.65 g cm ) are added. What is the new level of water in the cylinder? 5 3 A. 88.0 cm 5 3 B. 55.0 cm 5 3 0055 C. 53.0 cm 5 3 9 D. 42.5 cm 1780045 A 14 16529 52 1944 Aluminum has a density of 2.7 g/cc. Copper has a density of 8.9 g/cc. An alloy made from 270 g Al and 89 g Cu has a density of 5 _3 A. 3.3 g cm 5 _3 B. 5.5 g cm 5 _3 C. 5.8 g cm 5 _3 9 D. 7.6 g cm 0055 1780046 B 14 16533 52 19550138 5 3 The volume of one mole of AgCl, the density of which is 5.56 g/cm : 9 A. 1/(5.56 x 143) B. 0.143/5.56 C. 5.5/14.0 D. 5.56 x 143 0062 1780047 D 15 16536 52 071101 A sulfuric acid solution has a density of 1.84 g/cc and contains 98% sulfuric acid, H SO by weight. How many milliliters of this 4 2 4 solution should be taken in order to supply 1000 g of H SO ? 4 2 4 5 3 3 2 A. 1.8 x 10 B. 1.9 x 10 C. 7.5 x 10 5 2 9 D. 5.5 x 10 E. none of these 0064 1780048 C 15 16542 52 071101 A solution prepared by dissolving 26.0 g of a substance in 101 ml of pure water has a density of 1.14 g/cc. What is the volume of this solution? 9 A. 89 ml B. 101 ml C. 111 ml D. 127 ml E. 145 ml 0064 1780049 A 15 16545 72 071101 How many grams of KOH are contained in 50.00 ml of a KOH solution that has a density of 1.46 g/cc and contains 45% KOH by weight? 5 2 9 A. 33 B. 15 C. 1.6 x 10 D. 1.6 E. 56 0064 1780050 A 0064 15 16548 52 071101 A solution is prepared by dissolving 25 g of substance X in 100 ml of pure water. The resulting solution has a density of 1.136 g/cc. How many milliliters of this solution should be taken in order to provide 2 g of X? 9 A. 9 B. 4.0 C. 7 D. 8 E. 0.8 1780051 B 15 16552 52 071101 At one time gold sold for $400/Troy ounce. If the density of gold is 19.3 g/cc, calculate the cost of 4.54 ml of gold at that price. (1 Troy pound = 12 Troy ounces = 373 g.) 9 A. $0.353 B. $1130 C. $33.4 D. $980 E. $3.03 0064 1780052 E 15 16556 52 071101 5 21 The planet Earth has a volume of 1.1 x 10 cubic meters and an average density of 5.5 g/cubic centimeter. What is the mass of the earth in kilograms? 5 20 30 A. 5.0 Mg B. 5.5 x 10 kg C. 4.2 x 10 kg 5 23 24 9 D. 2.0 x 10 kg E. 6.1 x 10 kg 0064 1780053 B 15 16561 52 071101 Mercury has a density of 13.6 g/ml. What volume, in cubic inches, would 34.0 pounds of mercury occupy? 9 A. 46.2 B. 69.3 C. 227 D. 448 E. 1160 0064 1780054 B 15 44506 31 5 3 3 If a cube with a density of 6.0 g/cm has a volume of 3.0 cm , then its mass is 5 2 9 A. 2.0 g B. 18 g C. 0.50 g D. 1.6 x 10 g E. 0.22 g 1780055 B 15 44755 31 If a 2 cc block has a mass of 5 g, then its density is 9 A. 10 g/cc B. 2.5 g/cc C. 0.5 g/cc D. 5.0 g/cc E. variable 1780056 A 15 44853 51 If a 3 cc block has a mass of 2 g, then its density is ___ g/cc. 9 A. 0.67 B. 1.5 C. 3 D. 6 E. 2 1780057 D 15 45165 51 Calculate the mass of copper which occupies the same volume as 5 3 75.0 g of magnesium. The density of Cu = 8.96 g/cm and 5 3 and Mg = 1.74 g/cm . 9 A. 14.56 g B. 14.6 g C. 15 g D. 386 g E. 386.2 g 1900001 A 15 16564 31 03980067800111 The mass of a substance is A. described as a property of a substance by virtue of which it possesses inertia B. the density of its particles C. dependent upon the gravitational pull of the earth or some other body D. a force which accelerates a body 9 E. its weight in any set of weight units ETS2 OS 1900002 D 15 16569 51 00140066800114 Which of the following is characteristic of carbon compounds? A. carbon atoms join other carbon atoms only in such manner as to form chain compounds. B. once a carbon compound is formed it cannot be chemically changed unless some atoms are removed. C. once a carbon compound is formed it cannot be chemically changed unless some atoms are added. D. many carbon compounds are soluble in water. E. carbon atoms may share from one to eight valence 9 bonds with other carbon atoms. ETS2 OS 1900003 C 15 16576 32 04750504800111 The particles of which all matter is composed are believed to be A. moving at the same rate regardless of the mass or physical state of the matter B. moving at different rates, the differences depending on the quantity or mass of the matter C. moving at different rates, the differences depending on the physical state and temperature of the matter D. moving at different rates, the differences depending on the weight of the matter observed 9 E. stationary and immovable ETS2 OS 1900004 E 15 16583 31 01610195800111 At constant temperatures, volume varies inversely with pressure for enclosed A. solids, liquid, and gases B. solids and liquids C. solids and gases, but not liquids D. liquids ETS2 OS 9 E. gases 1900005 A 15 16586 31 03170293800111 The attractive forces between molecules becomes less when A. temperature is raised at constant pressure B. temperature is lowered at constant pressure C. pressure is raised at constant temperature D. volume is decreased at constant temperature 9 E. volume is decreased at constant pressure ETS2 OS 1900006 D 15 16590 31 04930494800111 One can infer that the cooling of any substance results in a decrease in A. weight of the molecules B. decomposition of the molecules C. volume of the molecules D. number of collisions between the molecules 9 E. attractive forces between the molecules ETS2 OS 1900007 ECAB 45 16594 31 0258052580011290 MACROITEM STEM 2Select from the key the term that is best described in the 2questions below. 2 A. Diffusion 2 B. Immiscibility 2 C. Viscosity 2 D. Compressibility 0 E. Surface tension MACRO SUB_ITEM # 1 It is almost as if the water were covered wIth a thin, stretched sheet of rubber, which must be ruptured before the water can make 1 contact with metal or glass. MACRO SUB_ITEM # 2 Observations suggest that the liquid moves by the sliding of one 2 layer over the other. MACRO SUB_ITEM # 3 If a heavy gas, like carbon dioxide, is placed in the bottom of a container, and a light gas, such as hydrogen, is placed on top of 3 the heavy gas, within a few hours the two will be completely mixed. MACRO SUB_ITEM # 4 Two liquids shaken together give a cloudy mixture with tiny globules of one liquid suspended in the other; when the shaking stops the globules coalesce, and the liquids separate into 9 distinct layers. 1900008 CDEA 45 16605 31 800405170803 90 ETS2 OS 2 OS MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches. 2 A. Boyle's law 2 B. Charles' law 2 C. Resonance 2 D. Adsorption 0 E. Absorption MACRO SUB_ITEM # 1 The property of an atom or molecule of shifting its electronic 1 structure between two or more different patterns MACRO SUB_ITEM # 2 2 A soaking up of one substance through the entire mass of another MACRO SUB_ITEM # 3 3 The accumulation of one substance on the surface of another MACRO SUB_ITEM # 4 The volume of a certain amount of dry gas is inversely proportional to the pressure, provided the temperature remains 9 constant 1900009 EDAB 45 16613 32 001905638004 90 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches. 2 A. Valence 2 B. Allotrope 2 C. Ion 2 D. Radical 0 E. Ionic bonding MACRO SUB_ITEM # 1 Bonding in which one or more electrons are transferred from one 1 atom to another MACRO SUB_ITEM # 2 A group of atoms which usually behaves as if it were a single 2 atom MACRO SUB_ITEM # 3 The number of electrons gained, lost, or shared by an atom in 3 bonding with one or more atoms MACRO SUB_ITEM # 4 9 One of the two or more different forms of an element 1900010 C 14 16620 31 019601138004 Hydrogen is a gas which is A. colorless and quite soluble B. odorless and a supporter of combustion C. combustible and a reducing agent 2 OS 2 OS 9 D. both a catalytic and an oxidizing agent 1900011 BDAC 45 16623 31 023708208004 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches A. covalent bond 2 B. period 2 C. radical 2 D. shell 0 E. chemical bond MACRO SUB_ITEM # 1 1 A horizontal row of elements in the periodic table MACRO SUB_ITEM # 2 2 A region about the nucleus of an atom in which electrons move MACRO SUB_ITEM # 3 3 Bonding in which atoms share a pair of electrons MACRO SUB_ITEM # 4 9 An atom or group of atoms with an unpaired electron 2 OS 1900012 D 14 16629 31 01540159 Energy added to matter may cause A. an increase in temperature B. a change of state C. a chemical reaction 9 D. any of the preceding answers depending upon the conditions. 0026 1900013 E 15 16632 31 140203481426 In which of the following pairs are both properties classified as chemical? A. odor, flammability B. melting point, color C. hardness, explodes upon heating D. odor, density 9 E. flammability, explodes upon heating 0040 1900014 E 15 16636 31 159301720186 Which of the following is not a property of both liquids and 3 ______ solids? A. density B. small degree of compressibility C. small degree of thermal expansion D. vapor pressure 9 E. melting point. 0040 1900015 B 14 16640 52 19470415 The element found in the largest number of known compounds is: 9 A. C B. H C. N D. O 0058 1920001 B 15 16642 51 00940172800111 When sulfur is heated A. the monoclinic variety changes to the rhombic B. at the melting point, the liquid is dark brown in color and very viscous C. monoclinic crystals are formed by allowing liquid sulfur, not heated much above its melting point, to freeze D. various isotopes of sulfur are formed as the temperature rises E. plastic sulfur is a mixture of the monoclinic and rhombic 9 varieties ETS2 OS 1920002 A 15 16648 52 04990169800111 All of the following would be contradictory to the kinetic theory except A. a gas that liquefies at 300 degrees below zero centigrade B. two solids that diffuse into each other C. a greater force of attraction between two molecules of steam at 212 degrees F. than between two molecules of water at the same temperature D. a material in which all molecular motion stops at 0 degrees C. 9 E. a solid which evolves heat as it changes to a liquid ETS2 OS 1920003 E 15 16655 31 01130195800111 When a given mass of gas is heated while its volume is held constant A. the gas condenses to a liquid B. the pressure of the gas decreases C. the pressure of the gas remains the same D. the kinetic energy of the molecules will decrease 9 E. the molecules will move faster ETS2 OS 1920004 B 15 16659 31 01130438800111 Indicate which of the following statements is most nearly correct with respect to the difference between a gas and a liquid. A. Gases are invisible, liquids are visible. B. Gases can be greatly compressed, liquids cannot. C. Molecules of a gas are smaller than molecules of a liquid. D. Molecules of a gas will diffuse, molecules of a liquid will not. E. Molecules of a gas have a higher kinetic energy than the 9 molecules of a liquid at the same temperature. ETS2 OS 1920005 B 15 16666 31 03960397800111 Great resistance to compression is a property of all A. solids, liquids, and gases B. solids, liquids, but not gases C. solids only D. solids and gases, but not liquids 9 E. liquids only ETS2 OS 1920006 D 15 16669 31 02930113800111 When the molecules of a confined gas are made to move faster, A. the volume of the gas decreases B. the temperature of the gas decreases C. the temperature of the gas remains constant D. the temperature of the gas increases 9 E. the gas condenses to a liquid ETS2 OS 1920007 B 15 16673 52 02780113800111 The hypothesis that gases expand and contract because the molecules expand and contract while remaining in contact is best refuted by A. the observation that all gases are transparent B. the observation that gases interdiffuse rapidly C. the theory that molecular diameters are constant D. the observation that the fog tracks of alpha particles through hydrogen are long and straight 9 E. the theory that gases are mostly empty space ETS2 OS 1920008 C 15 16679 31 01130438800111 The individual molecules of a substance which changes from a gas to a liquid to a solid, experience the greatest change in their A. kinetic energy B. mass C. potential energy D. volume 9 E. coefficient of expansion ETS2 OS 1920009 D 15 16683 32 05370161800112 A given amount of gas in a closed container is heated from room temperature to 100 degrees F.; disregarding the possible expansion of the container, according to the kinetic theory A. the gas has increased in weight B. the individual molecules of the gas have expanded C. the average distance between molecules has increased D. the average velocity of the molecules has increased ETS2 OS 9 E. the pressure on the sides of the container has decreased 1920010 A 15 16689 31 04380169800111 Which one of the following is true in the comparison of a liquid and a solid at the same temperature? A. Liquid molecules have a greater degree of freedom. B. Heat must be applied to make the molecules of a solid move. C. Liquid molecules vibrate about a fixed position. D. There is less space between the molecules of a liquid. 9 E. Liquid molecules are more dense. ETS2 OS 1920011 E 15 16694 31 01130195800111 When a given mass of gas is heated while its volume is held constant A. the gas condenses to a liquid B. the pressure of the gas decreases C. the pressure of the gas remains the same D. the kinetic energy of the molecules will decrease 9 E. the molecules will move faster ETS2 OS 1920012 D 14 16698 31 025804388004 Three of the following statements about diffusion are true. Which one is false? A. Substances diffuse from regions of their greater concentration to regions of their lesser concentration. B. Small particles will difuse for more readily than large particles. C. Diffusion occurs more readily in a gas than in a liquid. 9 D. Diffusion is more readily visible in a liquid than in a gas. 2 OS 1920013 B 15 16704 31 041305040588 Mercury is an example of which one of the following states of matter at room temperature and atmospheric pressure: A. solid B. liquid C. gas 9 D. liquid and gas E. none of these 0028 1920014 A 14 16707 31 02930113 Molecules are, in general, farthest apart from one another in A. gases B. liquids 9 C. crystalline solids D. amorphous solids 1920015 D 14 16709 31 16550871 A portion of the universe isolated for study is called a A. phase C. heterogeneous mixture 9 B. homogeneous mixture D. system 1920016 D 15 16711 31 08710588 0041 How many phases are present in the following system: a vessel containing water, pure copper, carbon tetrachloride, and air. Note: water and carbon tetrachloride do not mix. 9 A. 1 B. 2 C. 3 D. 4 E. 5 1920017 C 14 16714 51 189704900748 The triple point on the phase diagram for a substance A. is the only set of conditions under which none of the three phases of the substance can exist in equilibrium B. is the point above which three separate phases of the substance are in equilibrium C. is the intersection of the three two_phase equilibrium lines D. is the point below which the three phases of the substance 9 are in equilibrium 1920018 D 14 16720 51 1897 On a phase diagram of a substance, the areas between lines represent A. the conditions under which all three phases can exist in equilibrium with one another B. the conditions under which none of the three phases of the substance is present C. areas in which two phases exist 9 D. conditions under which only one phase exists 1920019 B 14 44658 51 189702450114 On a pressure_temperature phase diagram, the conditions under which two phases can exist in equilibrium with one another are indicated by A. the area delineated by two or more lines B. points on a line in the diagram C. the intersection of two lines D. the intersection of three lines 9 E. the horizontal axis 1920020 B 14 16729 51 189704900245 The triple point in a phase diagram represents A. the temperature at which the solid and liquid coexist in equilibrium with the vapor when the pressure is 1 atm. B. the temperature and pressure at which the solid, liquid, and vapor coexist in equilibrium. C. the region in a phase diagram in which one pure phase exists. D. the temperature of the normal boiling point of the 9 substance. 1920021 B 14 16735 51 18970558 Where, on a phase diagram, can you locate conditions where one phase only exists? A. on a line B. in an area bounded by lines C. at an intersection of two lines 9 D. at an intersection of three lines 1920022 A 14 16738 51 189705580245 Where, on a phase diagram, can you locate conditions where two phases coexist in equilibrium? A. on a line B. in an area bounded by lines C. at an intersection of two lines 9 D. at an intersection of three lines 1920023 D 14 16742 51 18970245 Where, on a phase diagram, can you locate conditions where all three phases may coexist in equilibrium? A. on a line B. in an area bounded by lines C. at an intersection of two lines 9 D. at an intersection of three lines 1920024 C 14 16746 51 189714090558 On a phase diagram of a substance, the lines represent conditions where how many phases may exist? 9 A. 0 B. 1 C. 2 D. 3 1920025 C 14 44481 31 1429 The temperature above which a gas cannot be liquefied, no matter how great the applied pressure, is called the A. triple point C. critical temperature E. dew point 9 B. normal boiling point D. condensation point 1920026 BA 25 16751 52 MACROITEM STEM Draw smooth curves through the points in the diagram below: | . | . | . | . | . | . |. OS82 0 |_______________________ MACRO SUB_ITEM # 1 This diagram describes phenomena associated with the behavior of A. acid_base equilibria C. ideal gases B. phase equilibria D. ideal solutions 1 E. heat transfer across a boundary MACRO SUB_ITEM # 2 The correct labels for the axes of this diagram are 9 A. B. C. D. E. x temperature pressure volume temperature enthalpy change y pressure temperature temperature solubility concentration 1922001 A 15 16762 52 01950114800112 A gas occupies 3 liters at S.T.P. Its volume at +546 degrees C. and at 380 mm. pressure will be A. 18 liters B. 3 liters C. 1.5 liters D. 4.5 liters 9 E. none of these answers ETS2 OS 1922002 B 15 16765 72 02180025800113 If the atomic weights of nitrogen and oxygen are 14 and 16 5 o respectively, the volume of 4.6g NO at 0 C and 4 2 0.5 atm pressure is A. 2.24 liters C. 8.96 liters E. 44.8 liters 9 B. 4.48 liters D. 224 ml ETS2 OS 1922003 C 15 16769 31 06548001800312 If the temperature of a fixed volume of gas is 0 deg. C., the temperature to which the gas must be raised to approximately double the pressure is 5 o o o o 9 A. 2 C B. 100 C C. 273 C D. 273 K E. 546 C ETS2WVW 1922004 C 15 16773 31 03170113800111 The force exerted on the walls of a vessel by a contained gas is caused by A. the repulsive forces between the molecules B. slight loss in average speed suffered by the molecules ETS2 OS 9 at the walls C. changes in the momentum which the molecules experience at the walls D. attraction between the walls and the gas E. elastic collisions between molecules of the gas 1922005 E 15 16779 31 01140113800111 The pressure exerted on the walls of a vessel by a confined gas arises from A. the repulsion between molecules B. a loss in speed when the molecules hit the walls C. the attraction of the walls for the gas molecules D. the stored_up energy of the molecules 9 E. the kinetic energy of the molecules ETS2 OS 1922006 E 15 16784 32 01950161800111 To state that the volume of a gas changes by 1/273 for each degree centigrade change in temperature can be true only if A. the volume is expressed in metric units B. the gas consists of only one element or compound C. the change in temperature is decreasing D. the temperature is expressed in absolute rather than in centigrade degrees 9 E. no chemical reaction is caused ETS2 OS 1922007 E 15 16790 52 04990379800111 The kinetic theory can be used to explain all of the following phenomena except A. the difference in riding quality between a flat and a properly inflated tire B. the presence of cooking odors in rooms adjacent to a kitchen C. Boyle's law D. Charles' law 9 E. artificially induced radioactivity ETS2 OS 1922008 C 15 16795 31 01950113800111 That the volume of an ideal gas is directly proportional to the absolute temperature is A. an inaccurate expression B. true if the centigrade scale of temperatures is used C. true if the pressure is held constant D. true if the volume is held constant 9 E. true without qualification ETS2 OS 1922009 A ETS2 OS 15 16799 32 01950113800111 Which one of the following would not affect the volume of a single gas in a rubber balloon? A. chemical composition of the gas B. temperature of the gas C. pressure of the gas D. altitude of the balloon 9 E. more than one of the above 1922010 E 15 16803 31 04998001800211 Of the following statements concerning the kinetic theory the one which is incorrect is A. matter is comprised of small discrete particles called molecules B. molecules are in motion in all substances except at the temperature of absolute zero C. for gases it is assumed that molecules are very far apart in relation to the size of the molecules D. for gases it is assumed that molecules exert practically no attraction on each other 9 E. all of the above statements are incorrect ETS2 OS 1922011 C 15 16810 31 01130293800111 Which one of these is not a characteristic of a gas molecule in motion? A. very high velocities B. a vast number of collisions per second C. a speed directly proportional to the mass of the molecule D. motion in straight lines between collisions 9 E. erratic motion as exemplified in the brownian movement ETS2 OS 1922012 C 15 16815 51 00670509800111 Which of the following is not a general property of gases? 3 ___ A. They mix homogeneously unless they react. B. When molecules collide with each other, there is no loss of energy in the gas. C. They are always clear and colorless. D. The molecular attraction between the molecules is less than it is for liquids and solids. E. The temperature of a gas is a measure of the average 9 kinetic energy of its molecules. ETS2 OS 1922013 E 15 16822 31 01610113800111 At a constant temperature, the volume of a constant mass of gas A. increases as the pressure increases ETS2 OS 9 B. decreases as the pressure increases C. is inversely proportional to the pressure D. is directly proportional to the pressure E. two of the above are correct 1922014 B 15 16826 31 05100161800111 Boyle's law which states that, at a constant temperature, pressure is inversely proportional to volume, can be applied A. to all liquids B. to all gases C. only to combinations of liquids and gases D. to any combination of liquids, gases, and solids 9 E. to all of these ETS2 OS 1922015 D 15 16830 52 80010290051211 For which one of the following does the kinetic theory offer the least satisfactory explanation? A. the growth of crystals B. the elasticity of solids C. heat as a form of molecular motion D. the magnetization of a magnet 9 E. the near incompressibility of liquids and solids ETS2 OS 1922016 D 15 16834 51 04990517800111 The kinetic_molecular theory A. is based on the law of constant proportions B. was originally derived from observations on crystals C. explains why large molecules exert a greater pressure than do the same number of small molecules at the same temperature in the same volume D. gives a satisfactory explanation of charles"law 9 E. explains the law of dulong and petit ETS2 OS 1922017 A 15 16840 51 01130397800111 Gases, in general, show abnormally large compressibilities A. at ordinary temperatures upon moderate increases in pressure B. at very large increases in pressure C. because the molecules occupy a definite volume D. because of the tendency of molecules to repel each other 9 E. because of Boyle's law ETS2 OS 1922018 C 15 16845 51 01138001047211 According to the gas laws, A. every gas, at constant pressure, expands to twice its former volume when the centigrade temperature is doubled. B. gases, at constant temperature, diffuse with speeds ETS2 OS 9 directly proportional to the square roots of their densities. C. The volume of a gas is not changed if it is heated from 0 degrees C to 273 degrees C,and at the same time the pressure is increased from 760 mm to 1520 mm. D. if gases are mixed, the pressure of each lowers the pressure of the other. E. if the law of Boyle is to hold, the gas must be kept at constant pressure. 1922019 A 15 16854 52 02650499800111 Deviations from the gas laws A. are not explained by the kinetic_molecular theory B. appear only when gases are exposed to very high pressures C. indicate that the molecules themselves occupy NO space D. result in gases being slightly more compressible under moderate increases than is in accordance with the law of Boyle 9 E. are present only in the conduct of the hypothetical perfect gas ETS2 OS 1922020 D 15 16860 51 02180400800111 Nitrogen is least significantly associated with A. the explosive industry B. dyes and the dyeing industry C. soil fertility D. poison war gases 9 E. proteins ETS2 OS 1922021 E 15 16863 51 04110412000811 Which one of the following pure compounds contains water vapor? A. dry ice B. hydrogen peroxide C. ammonia D. hydrogen chloride 9 E. none of these ETS2 OS 1922022 A 15 16866 32 01130195018612 A given mass of gas is enclosed in a suitable container so that it may be maintained at constant volume. This procedure necessarily implies that there can be no change in A. density B. pressure C. molecular kinetic energy D. total heat content 9 E. temperature ETS2 OS 1922023 A 15 16870 51 02180449045111 Nitrogen A. forms one of the most stable diatomic molecules known B. is used in the space above the mercury in thermometers because it liquefies at a very low temperature C. forms nitrites when heated with nearly all metals D. forms ammonia when heated to an extremely high temperature in the presence of platinum E. is used in electric light bulbs to eliminate oxidation of 9 the tungsten filament ETS2 OS 1922024 A 15 16876 31 02120454044811 Methane A. is the principal constituent of natural gas B. is formed when hydrogen is discharged at a graphite cathode C. requires three times its own volume of oxygen for complete combustion D. is the simplest branched_chain hydrocarbon 9 E. mixed with steam constitutes water gas ETS2 OS 1922025 B 15 16880 51 01140113016111 When the pressure on a given mass of gas is decreased A. the molecules of the gas will gain kinetic energy B. the temperature of the gas will decrease C. more collisions between gas molecules will occur D. the volume will decrease 9 E. the molecules will move more rapidly ETS2 OS 1922026 D 15 16884 31 01130161800111 A gas in a closed container is heated from room temperature to 5 o 100 C. Assume that the volume of the container remains unchanged. According to the kinetic molecular theory, the A. gas has increased in weight B. individual molecules of the gas have increased in size C. average distance between molecules has increased D. average velocity of the molecules has increased 9 E. pressure on the sides of the container has decreased ETS2 OS 1922027 B 15 16890 31 01618001019511 Increasing the temperature of a confined gas would A. decrease the pressure if the volume is also decreased B. increase the pressure if the volume were held constant C. increase the pressure if the volume were also increased D. increase the volume if the pressure were also increased 9 E. decrease the volume if the pressure were also decreased ETS2 OS 1922028 E 15 16895 31 01130286800111 When a given mass of gas is heated while its volume is held constant, A. the gas condenses to a liquid B. the pressure of the gas decreases C. the pressure of the gas remains the same D. the kinetic energy of the molecules will be reduced 9 E. the molecules will move faster ETS2 OS 1922029 B 15 16899 32 02720113800111 In a laboratory experiment in which the weight of 22.4 liters of oxygen was determined by collecting the gas over water A. 22.4 liters of oxygen were collected B. the vapor pressure of water was subtracted from the existing atmospheric pressure C. the collected oxygen was dried and weighed D. it was necessary to decompose all the potassium chlorate originally in the ignition tube 9 E. no pressure or temperature corrections were required ETS2 OS 1922030 D 15 16906 31 02930113800111 When the molecules of a confined gas are made to move faster, the A. volume of the gas decreases B. temperature of the gas decreases C. temperature of the gas remains the same D. temperature of the gas increases 9 E. molecular motion has no effect on the temperature ETS2 OS 1922031 B 15 16910 51 01090397800112 When air from a compressed air tank expands, the air is reduced in temperature mainly because A. convection takes place B. work is done at the expense of heat energy C. air is a good conductor of heat D. expansion increases the degree of molecular freedom E. the pressure of a gas is inversely proportional to the 9 absolute temperature ETS2 OS 1922032 C 15 16915 31 02728001029312 The experimental observation that the volume of a gas may be greatly decreased by applying pressure is best explained by the assumption that A. the average kinetic energy of gas molecules is directly proportional to the absolute temperature B. gas molecules collide without loss of kinetic energy ETS2 OS 9 C. gas molecules are small compared to the distance between them D. gas molecules exert almost no attraction on one another E. none of the above explains the assumption 1922033 D 15 16922 31 02860195800112 If, in heating a particular type of gas, the volume is maintained at a constant value, then the net result will be A. a fall in temperature of the contained gas B. inability of the gas to take on more heat C. a drop in the pressure of the contained gas D. an increase in the pressure of the contained gas 9 E. none of the above ETS2 OS 1922034 B 15 16927 31 02728001025812 Indicate the experimental or observational study giving best support for the statement "Molecules of a gas are in constant motion." A. winds exert pressure. B. Two gases interdiffuse quickly. C. Warm air rises. D. Heat is necessary to vaporize a substance. 9 E. Gases are highly compressible. ETS2 OS 1922035 B 15 16932 52 01920351800113 If we had a substance made up of atoms which had no attraction for one another, which of the following would be most nearly correct? A. Ten million atoms of this substance as a gas would occupy a much larger volume than 10 million molecules of the gas O , at the same temperature and pressure. 4 2 B. This substance would be a gas which could not be liquefied or changed to a solid. C. This substance could never exist as a gas at all but would be a solid or a liquid. D. If this substance were contained in a stoppered bottle and the temperature were increased, the pressure the substance exerts on the sides of the bottle would decrease. E. As a gas it would behave like any other gas since all gases 9 are of this type. ETS2 OS 1922036 D 15 16943 52 80010114032113 One liter each of four gases, W, X, Y, and Z, at standard conditions are passed into a one_liter container, where they combine to form a new gas (compound Q). The pressure of gas Q is found to be one atmosphere at 0 degrees C. What conclusions may be drawn? ETS2 OS 9 A. The number of molecules of Q formed is greater than the number of molecules in any one of the reactants. B. The number of molecules of Q formed equals the number of molecules of all the reactants. C. The number of molecules of Q formed is less than the number of molecules in any one of the reactants. D. The number of molecules of Q formed equals the number of molecules in any one of the reactants. E. One mole of Q was formed. 1922037 A 14 16953 32 02728001018714 Experimental evidence that a gas consists mostly of empty space is the fact that A. the density of a gas becomes greater when it is liquefied. B. gases exert pressure on the walls of their containers. C. gases are transparent 9 D. heating a gas increases molecular motion ETS2 OS 1922038 C 15 16957 31 04450293800114 The weight of a molecule of oxygen is 16 times as much as the weight of a molecule of hydrogen. One balloon is to be inflated with two liters of oxygen and another balloon of the same size with two liters of hydrogen. If both are kept at the same temperature, the pressure of the oxygen in the first balloon necessary to attain the same volume as the second balloon will be A. sixteen times as great as in the second B. one_sixteenth as great as in the second C. equal to that in the second D. four times as great as in the second 9 E. one_fourth as great as in the second ETS2 OS 1922039 CD 25 16965 52 0196011480011390 MACROITEM STEM 0 Answer the following questions. MACRO SUB_ITEM # 1 A liter of hydrogen gas at 0 degrees C. and a pressure of one atmosphere weighs 0.09 gram. If hydrogen is placed in a rigid container and the temperature is raised from 0 degrees C. to 273 degrees c., the weight of the liter of gas will A. become 1/273 as great B. be reduced by one_half C. remain the same D. become twice as great 1 E. become 273 times as great MACRO SUB_ITEM # 2 The pressure of the gas on the walls of the container will ETS2 OS 9 A. become 1/273 as great B. be reduced by one_half C. remain the same D. become twice as great E. become 273 times as great 1922040 B 14 16973 51 087101930548 A system consists of nothing but gaseous H and gaseous N . 4 2 2 Which of the following is true? A. H and N do not mix 4 2 2 B. H and N form a homogenous mixture 4 2 2 C. H and N form a heterogenous mixture 4 2 2 D. H and N form two phases 94 2 2 1922041 A 15 16978 32 01130195800112 A given mass of gas is enclosed in a suitable container so that it may be maintained at constant volume. This procedure necessarily implies that there can be no change in A. density B. pressure C. molecular kinetic energy D. total heat content 9 E. temperature ETS2 OS 1922042 D 15 16982 31 01140438800111 The vapor pressure of a liquid A. is the pressure at which its pressure is equal to that of the atmosphere B. decreases more rapidly with temperature as the temperature falls C. is the pressure necessary to cause bubble formation at atmospheric pressure D. is the pressure at which the rate of evaporation is equal to the rate of condensation 9 E. is normally large for electrovalent than for covalent compounds ETS2 OS 1922043 B 15 16988 51 01090472800111 When air from a compressed air tank expands, the air is reduced in temperature mainly because A. convection takes place B. work is done at the expense of heat energy ETS2 OS 9 C. air is a good conductor of heat D. expansion increases the degree of molecular freedom E. the pressure of a gas is inversely proportional to the absolute temperature 1922044 B 15 16993 31 01130114800111 When air is let out of a tire, the temperature of the air is reduced because A. the pressure of a gas is inversely proportional to the absolute temperature B. expansion increases the degree of molecular freedom C. work is done at the expense of heat energy D. air is a good conductor of heat 9 E. convection takes place ETS2WVW 1922045 B 15 16998 31 02930195800111 The number of molecules in equal volumes of all gases under the same conditions of temperature and pressure are A. widely different B. equal C. numerous D. comparatively few 9 E. unknown ETS2 OS 1922046 D 15 17001 52 02760025800111 According to theory, in a given mixture of oxygen and nitrogen, of uniform temperature throughout, A. all the molecules are moving at the same speed. B. all the molecules possess the same kinetic energy. C. the average speed of the nitrogen molecules is the same as the average speed of the oxygen molecules. D. the averrage kinetic energy of all the molecules in this mixture is the same as that of any other gas at the same temperature. E. the average kinetic energy of all the molecules in this mixture is the same as that of any other gas at 9 the same pressure. ETS2 OS 1922047 C 15 17010 51 80010511029311 Select the true statement or statements. 1. If a gas expands against an external pressure, without absorbing heat from the enviroment, then the average kinetic energy of the gas molecules is increased. 2. If a gas is compressed, without losing heat to the environment, then the average kinetic energy of the gas molecules is unchanged 3. If the volume of a gas remains constant while the gas ETS2 OS absorbs a certain quantity of heat, then the average kinetic energy of the gas molecules is increased. The correct selection includes only A. 1 B. 2 C. 3 D. 1 and 2 9 E. 2 and 3 1922048 D 15 17018 71 80010186016111 Which of the following is the best statement of the reason for defining the term "pressure" as we do? A. The expansive force of a gas is its most characteristic property. B. The "elasticity" of a gas can be measured by observing the amount of force necessary to keep it confined in its volume. C. A gas of a given kind (e.g., hydrogen), at a specified density and temperature, always exerts the same force against its containing walls regardless of the shape or volume of that container. D. A gas of a given kind (e.g., hydrogen), at a specified density and temperature, exerts against a plane portion of its containing walls a force proportional to the area of that portion. E. A term can be defined in any way one pleases, the only admissible question is whether the term as defined 9 can be applied to anything. ETS2 OS 1922049 B 15 17030 31 01610195800112 When the temperature and the volume are held constant, the pressure of a gas remains unchanged. Which one of the following principles is most closely associated with the explanation of this? A. The addition of heat increases the speed of the molecules. B. Molecules collide without loss of kinetic energy. C. In an adiabatic change work is done at the expense of internal energy. D. At a given temperature, the pressure exerted by a confined gas is proportional to the number of molecules it contains. 9 E. The volume coefficient of expansion for gases is a constant. ETS2 OS 1922050 C 15 17039 52 01140493800112 The reduction in pressure as a gas is cooled in a container of ETS2 OS constant volume is best explained on the basis that the molecules A. hit each wall of the vessel less often B. hit each wall of the vessel with less force C. hit each wall of the vessel with less force and less often D. contract 9 E. get closer together 1922051 B 14 17044 32 05330109800112 When pumping air into an automobile tire, we notice the wall of the pump becomes quite warm to the touch. This is because A. the air being taken in is warmer than the air in the tire B. some of the mechanical energy of pumping is converted to heat C. the air molecules have increased their frictional drag 9 D. warm air rushes back into the pump from the tire 1922053 BBD 35 17050 31 0025034580011290 MACROITEM STEM 2Read the following paragraph to answer the questions below. 2Chemists using oxygen, atomic weight 16 and molecular weight 32, 2as standard, and the known weight under standard conditions of 21 liter of oxygen 1.429 gms., show that the volume occupied by 232 gms. of oxygen equals 32/1.429 or 22.4 liters. When nitrogen 2is used, the weight of 22.4 liters is 28 instead of 32. the two 2numbers, 28 and 32, must be the relative weights of an equal number 2of molecules of the gases. In numbers, the molecular weight of any 2gaseous element or compound is the same as the weight in grams of 0 22.4 liters of the gas. MACRO SUB_ITEM # 1 The above paragraph makes particular use of the A. law of definite proportions B. law of Avogadro C. law of conservation of mass D. law of multiple proportions 1 E. law of Gay Lussac MACRO SUB_ITEM # 2 If the density of hydrogen is .08987 gm./liter under standard conditions, 22.4 liters of hydrogen should weigh A. 1.008 gms. B. 2.016 gms. C. 4.064 gms. D. 32/.08987 gms. 2 E. None of these MACRO SUB_ITEM # 3 ETS2 OS ETS2 OS If the atomic weight of chlorine is 35.5, 22.4 liters under standard conditions A. weigh 1.58 gm. B. weigh 35.5 gm. C. weigh 32 gm. D. weigh 71 gm. E. weigh an amount which cannot be determined without knowing 9 the weight of 1 liter 1922054 A 15 17067 31 01610114800111 Which of the following statements is not correct? 3 ___ A. At constant temperature the pressure of a certain amount of gas increases with increasing volume. B. At constant volume the pressure of a certain amount of gas increases with increasing temperature. C. At constant pressure the volume of a certain amount of gas increases with increasing temperature. D. In dealing with gas laws the most convenient scale of temperature to use is the absolute or Kelvin. E. Equal numbers of molecules of all gases exert about the 9 same pressure at a certain temperature and volume. 1922056 D 15 17076 52 07078003 According to the kinetic molecular theory, for an equimolar mixture of two ideal gases, A and B, (where the molecular weights of A and B are different) A. all molecules have the same velocity B. the average molecular kinetic energy is greater for the lighter gas C. the average molecular kinetic energy is greater for the heavier gas D. the average molecular velocity is greater for the lighter gas E. the partial pressure exerted by the heavier gas is greater 9 than that exerted by the lighter gas 1922057 A 15 17084 52 070807098003 The effusion of different gases from a pinhole can be compared under the same conditions. Compared to oxygen (O ), the time 4 2 A. 4 times shorter C. 16 times shorter C. 16 times shorter D. 16 times longer 9 E. none of the above is correct ETS2 OS 2WVW 2WVW 1922058 BDC 35 17089 31 8001019501611190 MACROITEM STEM 2Mark the following questions according to the key below. (Assume 2an ideal gas.) 2 A. True without qualification 2 B. False 2 C. True if the temperature is constant 2 D. True if the volume is constant 0 E. True if the pressure is constant MACRO SUB_ITEM # 1 1 The pressure of a gas varies directly as the volume MACRO SUB_ITEM # 2 2 The pressure of a gas varies directly as the absolute temperature MACRO SUB_ITEM # 3 9 The volume of a gas varies inversely as the pressure ETS2 OS 1922060 A 14 17095 31 80038004 Which of the following is a physical property which determines the method of collection of a gas? A. solubility in water B. color C. ease of liquefaction 9 D. state 2WVW 1922061 B 14 17098 32 011304968002 The gas which diffuses more rapidly than other bases under similar conditions is A. oxygen B. hydrogen C. nitrogen 9 D. chlorine 2 OS 1922062 D 14 17100 31 011305388002 When an ideal gas expands adiabatically against a resisting pressure A. the temperatue remains constant B. energy is liberated C. the pressure increases 9 D. the environment remains unchanged 2 OS 1922063 A 14 17103 32 05990884039851 An unknown gas occupies a volume of 725 ml at STP and has a mass of 1.036 g. This gas could be 9 A. oxygen B. nitrogen C. carbon dioxide D. chlorine. 9000 1922064 C 5 9000 14 17106 32 01141543054651 o A 10_liter tank contains argon at 1.0 atm pressure and 25 C. What pressure will be exhibited by the argon if the tank is 5 o heated to 250 C? 9 A. 10 atm B. 2.01 atm C. 1.75 atm D. 1.08 atm. 1922065 B 14 17110 32 01950114 51 A balloon containing hydrogen gas at STP has a volume of 45 liters. What is its volume at 77 degrees C and 0.2 atm pressure? 9 A. 11.5 liters B. 57.7 liters C. 77 liters D. 288 liters. 1922066 A 14 17113 32 05530546088451 How many moles of nitrogen gas are there in 4.42 liters volume at STP? 9 A. 0.197 B. 1.07 C. 4.4 D. 8.8 1922067 A 14 17115 32 05531097011351 How many moles are present in a sample of gas which occupies 15.8 liters at 20 degrees C and 0.4 atm pressure? 9 A. 0.26 B. 3.9 C. 3.1 D. 0.32 9000 9000 9000 1922068 C 14 17118 32 12010114016851 Calculate the total pressure exerted by a mixture of gases composed of 7.0 g N , 20 g Ar, and 0.5 g H . the mixture is 4 2 2 5 o contained in a 5.0 liter vessel at 127 C. 9 A. 0.48 atm B. 2.08 atm C. 6.56 atm D. 10.0 atm. 9000 1922069 A 15 17123 32 018606540288 Calculate the density of carbon dioxide in grams per liter at 2.00 atmospheres and 0 degrees C. A. 3.92 g/l B. 0.880 g/l C. 0.509 g/l D. 1.96 g/l 9 E. 1.02 g/l 0028 1922070 D 14 17126 31 01130707 All of the following are a part of the kinetic molecular theory of gases except A. a gas is composed of molecules in ceaseless motion, colliding in perfectly elastic collisions. B. As the temperature is increased, the molecules move faster. C. The molecules of a gas are very small compared to the space they occupy. D. The pressure of a gas results from the close packing of the molecules in the container like the pressure exerted by 9 oranges packed tightly in a crate. 0026 1922071 C 14 17133 31 070706540802 The pressure_volume relationship expressed by Boyle's law can be explained by the kinetic molecular theory as follows A. When more pressure is applied to a gas, a greater volume of the gas dissolves in a liquid. B. The volume of a gas decreases as the pressure on the gas increases. C. When the volume of a gas is decreased the molecules are closer together causing more frequent collisions with the walls of the container. D. When the volume is decreased, the increased temperature causes the molecules to move faster and to hit the walls 9 of the container harder and more often. 1922072 A 14 17142 31 01810707 According to the kinetic molecular theory, the heat of vaporization is used primarily A. to speed up the molecular motion B. to increase the potential energy of the molecules C. to move the molecules closer together 9 D. to melt a solid. 0026 0026 1922073 B 14 17146 32 152401340321 In a synthetic atmosphere made up of He and O , the mole fraction 4 2 of He is 0.80. The weight % of He is: 9 A. 80 B. less than 80 C. greater than 80 D. cannot tell 0009 1922074 E 15 17149 31 030614090884 Which of the following represents standard conditions of temperature and pressure(STP)? A. 0 degrees F, 1 inch Hg B. 0 degrees K, 1 atm C. 0 degrees K, 1 mm Hg D. 0 degrees C, 1 mm Hg 9 E. none of the above 0019 1922075 D 15 17152 31 14121291 Atmospheric pressure is equal to A. the reciprocal of the volume times the gas constant B. the weight of a column of mercury at sea level C. the height of mercury in an inverted tube supported by weight of air above the surface of the mercury D. 760 mm 9 E. 760 atm 0019 1922076 D 15 17156 31 011303400451 Of the following gases the only one which does not consist of 3 ________ diatomic molecules at room temperature is B. nitrogen B. carbon monoxide C. oxygen D. helium 9 E. both B and D. 0040 1922077 B 15 17160 31 080201130528 Boyle's law, which states that at a constant temperature, pressure is inversely proportional to volume, can be applied to A. all liquids B. all ideal gases C. combinations of liquids and gases only D. any combination of liquids, gases, and solids. 9 E. to all of these. 0035 1922078 B 14 17164 51 011404330113 When the pressure of a sample of gas is increased, the mercury level in a barometer which is measuring this pressure will A. drop C. remain constant 9 B. rise D. depend on yet other variables 1922079 A 14 17167 52 011404130321 A pressure of 760 mm of Hg equals A. 1 atmosphere C. 760 atmospheres 9 B. 273 torr D. 1 torr 1922080 D 14 17169 52 032101141790 A pressure of one atmosphere is equal to A. 1 torr C. 14.7 mm Hg per square inch 9 B. 1 cm Hg D. 760 torr 1922081 C 14 17171 51 139101140413 A U_tube manometer is open on the right arm and connected to a gas sample at the other arm. If the pressure of the gas increases A. the mercury level in the right arm drops B. there is no change in the levels of Hg C. the mercury level in the left arm drops 9 D. difference in mercury levels in the two arms decreases 1922082 B 14 17176 51 139104130114 A U_tube manometer is open on the left arm and connected to a gas sample on the other arm. If the mercury level in the left arm is higher than in the right, which of the following is true? 9 A. The pressure of the gas is less than the prevailing atmospheric pressure B. The pressure of the gas is greater than the prevailing atmospheric pressure C. The pressure of the gas is equal to the prevailing atmospheric pressure D. One can derive nOne of the above information about the gas sample pressure unless a torricellian barometer is used. 1922083 A 14 17184 51 139104130114 A U_tube manometer is open on the left and connected to a gas sample on the other arm. If the mercury level in the right arm is higher than in the left, which of the following is true? A. The pressure of the gas is less than the prevailing atmospheric pressure. B. The pressure of the gas is greater than the prevailing atmospheric pressure. C. The pressure of the gas is equal to the prevailing atmospheric pressure. D. One can derive none of the above information about the gas sample pressure unless a Torricellian barometer 9 is used. 1922084 C 15 17192 31 0706 Which of the following gases is the most nearly ideal? A. CO B. NO C. O D. ICl 94 2 1922085 B 14 17195 31 0706 Which of the following gases would you expect to deviate most from ideality? A. N B. NO C. O D. CO 94 2 2 2 1922086 C 15 17198 31 13900706 Which of the following factors causes a gas to deviate the most from ideal behavior? A. Polarity of the bonds in the molecule B. Mass of the molecules C. Polarity of the molecule overall structure D. Nonspherical shape of the molecules 9 E. Molecular electronic 1922087 D 14 17202 31 11390706 E. NH 3 Carbon monoxide and nitrogen are both gases at room temperature. Which one of them is more ideal and why? A. Carbon monoxide because the bond is stronger B. Nitrogen because its mass is less C. Carbon monoxide because the bond is more polar 9 D. Nitrogen because the molecule is less polar 1922088 D 14 17207 31 11390706 CH and NH are both gasses, and CH is the more ideal gas 4 4 3 4 because A. the N_H bonds in NH are less polar than C_H bonds in CH 4 3 4 B. the NH molecules have greater mass than CH molecules 4 3 4 C. carbon is more electronegative than nitrogen D. CH molecules are less polar than NH molecules 94 4 3 1922089 D 14 17214 31 1429 Which of the following gases has the highest critical temperature? A. N B. H C. CH D. H O 94 2 2 4 2 1922090 B 14 17217 31 1429 Which of the following gases has the highest critical temperature? A. O B. HF C. CO D. He 94 2 2 1922091 D 14 17220 31 1429 Which of the following gases has the highest critical temperature? A. SO B. H C. O D. H O 94 2 2 2 2 1922092 A 14 17223 31 1429 Which of the following gases has the lowest critical temperature? A. H B. NH C. SO D. HCl 94 2 3 2 1922093 A 14 17226 31 1429 Which of the following gases has the lowest critical temperature? A. CH 94 4 B. NH 3 C. H O 2 D. HF 1922094 D 14 17229 31 1429 Which of the following gases has the lowest critical temperature? A. NH B. H O C. HCl D. He E. O 94 3 2 3 1922095 B 14 17232 31 14271430 A gas can be most easily liquefied if it has A. low forces of intermolecular attraction B. high forces of intermolecular attraction C. molecules of large size 9 D. molecules of small size 1922096 B 14 17235 31 14300502 Which of the following properties has no effect on whether or not a gas can be liquefied? A. The temperature of the gas. B. The surface tension of the liquid phase. C. The pressure applied to the gas sample. 9 D. The intermolecular forces among gas molecules. 1922201 C 15 17239 32 01130305038001 It is found that 2.00 liters of a gas at standard conditions weigh 4.50 grams. The gram_molecular weight of the gas (in grams) is 9 A. 4.50 B. 2.25 C. 50.4 D. 25.2 E. 9.0 ETS2 OS 1922203 B 15 17242 52 012800370113 Determine the molecular weight of a compound given the following gas phase data: mass = 3.42 grams; temperature = 31.1 degrees C; pressure = 862 torr; and volume = 1.83 liters. 5 _3 9 A. 54.1 B. 41.1 C. 42.6 D. 420 E. 5.53 X 10 . 0044 1922204 B 15 17246 32 070601280288 If 2.00 g of a gas occupy 1.12 liters at STP, what is its molecular mass? 9 A. 4.00 amu B. 40.0 amu C. 10.0 amu D. 100 amu E. 400 amu 0028 1922205 E 15 17248 32 070601280288 Calculate the molecular mass of a gas if 1.00 g has a volume of 550 ml at 27 degrees C and 760 torr. 9 A. 33.6 amu B. 56.0 amu C. 40.7 amu D. 22.4 amu E. 44.8 amu 0028 1922206 C 15 17251 32 012801130114 What is the molecular mass of a gas if 10 grams of the gas occupies 82 liters at a pressure of 1 atmosphere and 25 degrees C? 9 A. 33.3 B. 3.3 C. 2.98 D. 29.8 E. 164 0019 1922207 C 15 17254 32 088401130398 At STP, 3.50 g of an unknown gas were found to occupy 2.24 liters. What is the mass of a mole of this gas? 9 A. 0.350 g B. 7.94 g C. 35.0 g D. 79.4 g E. none is correct 0019 1922208 D 15 17257 52 022401131649 In order to decide whether the formula of a gas is NO , or N O , 4 2 24 or N O , the best procedure is to find: 4 36 A. the structure of the N and O atoms B. the percentage composition of the compound C. the relative volumes of oxygen and nitrogen in the compound D. the weight of a fixed volume of the gas at a known pressure and temperature E. the nature of the acid produced when the gas reacts with 9 water 0038 1922209 C 14 17264 32 07060128 The molecular weight of a gas, 7.98 g of which occupies 4.48 liters at STP, is: 9 A. 4.00 amu B. 20.2 amu C. 39.9 amu D. 83.8 amu 0003 1922210 B 14 17266 32 07060128 The molecular weight of a gas, 44.3 g of which occupies 16.8 liters at 0 degrees C and 700 torr, is: 9 A. 46.7 amu B. 64.2 amu C. 79.3 amu D. 84.0 amu 0003 1922211 A 15 17269 52 0128 What is the molecular weight of a gas if 11.2 grams occupy 11.2 liters at 380 torr and 0 degrees C? A. 45 g/mole C. 90 g/mole E. 5.6 g/mole 9 B. 22.5 g mole D. 11.2 g/mole 1922212 D 15 17272 52 0128 A 2240 ml container confines 10.0 grams of gas at 2.00 atm and 273 degrees C. What is the molecular weight of this gas? A. 4.00 g/mole C. 50.0 g/mole E. 10.0g/mole 9 B. 25.0 g/mole D. 100 g/mole 1922213 B 15 17275 52 0128 Exactly 25.0 grams of a 5.6 liter sample of an unknown gas at 278 degrees C is found to exert a pressure of 2.02 atm. The molecular weight of the gas is A. 0.020 g/mole C. 51.0 g/mole E. 4.00 g/mole 9 B. 100 g/mole D. 10.0 g/mole 1922214 C 15 17279 52 0128 A 3.60 liter flask contains 10.0 grams of an unknown gas at a pressure of 1.02 atm and 87 degrees C. what is the molecular weight of the gas? A. 980 g/mole C. 80 g/mole E. 8.0 g/mole 9 B. 240 g/mole D. 19 g/mole 1922215 B 14 17283 52 0128 An 11 ml sample bulb at a temperature of 57 degrees C is filled with a 0.020 g gas sample whose pressure is found to be 82 torr. The molecular weight of the gas is 9 A. 79 g/mole B. 456 g/mole C. 1260 g/mole D. 790 g/mole 1922216 D 14 17287 52 0128 A 0.20 gram sample of an unknown gas confined in a 160 ml container at a temperature of 47 degrees C is found to exert a pressure of 0.55 atm. What is the molecular weight of the gas? 9 A. 227 g/mole B. 8.7 g/mole C. 298 g/mole D. 60 g/mole 1922217 D 14 17291 52 0128 At a temperature of 277 degrees C, a 0.200 gram sample of a compound is found to exert a pressure of 380 torr when it is confined in a volume of 820 ml. What is the molecular weight of the compound? 9 A. 550 g/mole B. 290 g/mole C. 3.40 g/mole D. 22.0 g/mole 1922401 B 15 17295 51 80010189006612 Suppose 2 liters of a gaseous element X combine with 3 liters of a gaseous element Y to form 3 liters of a gaseous compound. If one assumes that the separate and independent particles of elementary gases are atoms, what conclusion necessarily follows? A. gases X and Y do not have the same number of atoms in equal volumes. B. There are more atoms of gas X than gas Y per liter. C. There are fewer atoms of gas X than gas Y per liter. D. Equal volumes of gases contain the same number of atoms. 9 E. None of these is a necessary conclusion. ETS2 OS 1922402 A 15 17303 51 80010293039811 In computing the kinetic energy of a gas molecule, it is necessary to consider both the velocity of the molecule as well as A. its mass B. the number of atoms in the gas molecule C. the kinds of atoms in the gas molecule D. its physical properties 9 E. all of the above ETS2 OS 1922403 A 15 17307 52 80010161011413 If both the volume and the absolute temperature of a gas under standard conditions were tripled, the pressure would be A. unchanged B. three times as great C. six times as great D. nine times as great 9 E. one_ninth as great ETS2 OS 1922404 E 15 17311 52 01950161800113 If the volume and the absolute temperature of a given mass of gas were both reduced to one_half their former value, the pressure exerted by the gas would be A. one_half as great B. one_fourth as great C. twice as great D. four times as great 9 E. unchanged ETS2 OS 1922405 C 15 17315 52 01950445800113 To triple the volume of a given weight of gas at 27 degrees C, keeping pressure constant, raise the temperature to A. 81 degrees C. B. 273 degrees C. C. 900 degrees absolute D. 627 degrees absolute 9 E. 546 degrees absolute ETS2 OS 1922407 B 15 17319 52 01140113800113 To halve the pressure on a given mass of gas at 27 degrees C, keeping its volume constant, change the temperature to A. 54 degrees C. B. 150 degrees absolute C. 13.5 degrees C. D. 600 degrees absolute 9 E. _27 degrees C. ETS2 OS 1922408 E 15 17323 72 04290025800113 The mean velocity of oxygen molecules at 0 degrees C is 460 m/s. If the molecular weight of oxygen is 32 and the molecular weight of helium is 4, then the mean velocity of a helium molecule at 0 degrees C is (in m/s) 9 A. 230 B. 326 C. 650 D. 920 E. 1300 1922409 A 15 17327 72 01138001054613 5 o One liter of a gas has a pressure of 1 atmosphere at 0 C. What will be the volume of the same quantity of gas at 570 mm Hg 5 o and 27 C (in liters) 9 A. 1.47 B. 1.21 C. 1 D. 0.68 E. 0.825 ETS2 OS 1922410 A 15 17331 72 01138001016113 A gas in a 200 cc container has a pressure of 60 torr at 27 deg C. If the temperature is raised to 127 deg C and the container expands to 250 cc, what will be the pressure of the gas? 9 A. 64 torr B. 100 torr C. 36 torr D. 56 torr E. 226 torr ETS2 OS 1922411 D 15 17335 52 05490161800113 A certain mass of gas is confined in a cylinder and occupies a volume of 5 cubic feet when the absolute temperature (K degrees) is 1000 degrees. If the applied pressure on the piston is kept constant and the absolute temperature of the gas is lowered to 800 degrees (F degrees), the volume occupied by the gas is, in cubic feet, A. 1 B. 2 C. 4.3 D. 4 9 E. 6.2 ETS2 OS 1922412 C 15 17340 52 01860025800113 The density of oxygen at 273 degrees C and a pressure of 2 atmospheres is 5 3 A. 0.002 gm/cm 5 3 B. 0.007 gm/cm 5 3 C. 0.0014 gm/cm 5 3 D. 0.0056 gm/cm 5 3 9 E. 0.0098 gm/cm ETS2 OS ETS2 OS 1922413 AB 25 17344 52 0113032180011390 MACROITEM STEM 0 Answer the following questions. MACRO SUB_ITEM # 1 A certain specimen of gas has a volume of 1.5 liters, at 0 degrees C and atmospheric pressure. At 0 degrees C. and a pressure of 3 atmospheres, this specimen of gas will occupy a volume of A. 0.5 liter B. 1.0 liter C. 1.5 liters D. 3.0 liters 1 E. 4.5 liters MACRO SUB_ITEM # 2 The same specimen of gas, at 273 degrees C. (=546 degrees absolute) and a pressure of 3 atmospheres, will occupy a volume of A. 3.5 liter B. 1.0 liter C. 1.5 liters D. 3.0 liters 9 e 4.5 liters ETS2 OS 1922414 C 15 17351 32 01140300800112 Assuming that the pressure remains constant in both cases, if a particular type of gas occupies 273 cc of space at 0 degrees C, at a temperature of 10 degrees C it will occupy a space of A. 263 cc. B. 273 cc C. 283 cc. D. 278 cc. 9 E. 293 cc. ETS2 OS 1922415 E 15 17355 32 01950161800112 If the volume and the absolute temperature of a certain mass of gas were both doubled, the pressure would be A. one_half as great B. twice as great C. one_fourth as great D. four times as great 9 E. unchanged ETS2 OS 1922416 E 15 17358 32 01950012800112 If the volume and absolute temperature of a given mass of gas were both reduced to one_half their former value, the pressure would be ETS2 OS 9 A. one_half as great B. one_fourth as great C. twice as great D. four times as great E. unchanged 1922417 C 15 17362 32 01140526800112 If the pressure is constant and a gas has a volume of 10 liters 5 o o at 20 C, its volume at 20 C will be (in liters) 9 A. 5 B. 20 C. 10.7 D. 9.36 E. 8.24 ETS2 OS 1922418 C 15 17365 32 01610195800112 If the temperature of a fixed volume of gas is 0 degrees C, the temperature to which the gas must be raised to approximately double the pressure is A. 2 degrees C. B. 100 degrees C. C. 273 degrees C. D. 273 degrees A. 9 E. none of these ETS2 OS 1922419 A 15 17369 32 04860114800112 If the volume and the absolute temperature of a given mass of gas under standard conditions were each tripled, the pressure would be A. unchanged B. three times as great C. six times as great D. nine times as great 9 E. changed by some quantity other than the above three ETS2 OS 1922420 B 15 17373 32 01610195800112 If the temperature of a gas is 0 degrees C, the temperature to which the gas must be raised to approximately double the volume while maintaining the pressure constant is A. 273 K B. 273 degrees C. C. 2 degrees C. D. 100 degrees C. 9 E. none of these ETS2 OS 1922421 B 15 17377 31 03980195800112 A certain mass of gas has a volume of 200 cc under a barometric pressure of 76 cm of mercury. If this gas is subjected to an additional pressure of 4 cm of ETS2 OS mercury, without changing its temperature, its volume will be approximately A. 280 cc B. 190 cc C. 3800 cc D. 120 cc 9 E. none of these 1922422 D 15 17382 52 07068003 What is the volume occupied by 0.200 mole of an ideal gas at 380 torr and 300 deg K? 5 _1 _1 (R=0.0820 liter atm mole deg ) A. 1.73 liters B. 3.67 liters C. 8.20 liters D. 9.84 liters 9 E. 16.4 liters 2WVW 1922423 A 15 17386 31 06548003 A gas in volume V at a pressure P is allowed to expand at 4 1 1 constant temperature, so that its new volume V is 3(V ). 4 2 1 its new pressure is A. P /3 B. P x V C. P x V /V D. P E. 3(P ) 94 1 1 1 1 2 1 1 1 2WVW 1922424 D 15 17391 52 8003 What is the volume occupied by 0.200 mole of an ideal gas at 380 torr and 300 deg. K? A. 1.73 liters B. 3.67 liters C. 8.20 liters D. 9.84 liters 9 E. 16.4 liters 2WVW 1922425 D 15 17394 52 8003 A sample containing 1.6 gram of O and 2.02 gram of Ne are placed in 4 2 an 8.2 liter flask. What is the total pressure of the gas mixture at 27 deg. C.? A. 0.15 atm. B. 0.30 atm. C. 0.40 atm. D. 0.45 atm. 2WVW 9 E. 0.60 atm. 1922426 B 14 17398 32 019501138002 If the volume which a certain number of gas molecules occupies remains constant as the temperature is lowered, then the pressure exerted by this number of molecules A. remains constant B. steadily decreases C. steadily increrase 9 D. first increases and then decreases 1922427 A 14 17402 52 0706 At 380 torr and 0 degrees C, an 11.2_liter container will hold how many moles of an ideal gas? 9 A. 0.25 B. 0.50 C. 1.00 D. 2.00 E. 11.2 2 OS 0003 1922428 B 14 17405 32 019500258002 The volume of 16 grams of oxygen at standard temperature and pressure is A. 1 liter B. 11.2 liters C. 16 liters 9 D. 22.4 liters 2 OS 1922429 D 14 17407 32 019500258002 The volume occupied by 3 moles of oxygen at standard temperatures and pressure is A. 1 liter B. 22.4 liters C. 3 liters 9 D. 67.2 liters 2 OS 1922430 C 14 17410 31 011401138002 Doubling the pressure of a gas at the same time that its Kelvin temperature is doubled, causes its volume to A. increase B. decrease C. remain the same 9 D. increase by 100 per cent 2 OS 1922431 B 15 17413 52 072706548003 A sample of pure argon gas (Ar) occupies a volume of 0.082 liter at 0.30 atm when the temperature is 27 deg C. how many moles of Ar are there in the sample? 5 _1 _1 (At. Wt Ar=40; R=0.082 liter atm mole deg ) 2WVW 5 _3 _5 A. (1.0 x 10 )/40 = 2.5 x 10 5 _3 B. 1.0 x 10 5 _2 C. 1/90 (about 1.1 x 10 ) 5 _2 D. 4.0 x 10 9 E. 22.4 1922432 B 15 17420 52 070607278003 In an 18_liter mixture of gases whose temperature and pressure were 825 deg C and 1520 torr the partial pressure of helium was 76 torr. Calculate the number of moles of helium in the mixture. 5 _1 _1 (R=0.082 liter atm mole deg ) A. 0.0050 B. 0.020 C. 0.080 D. 0.32 9 E. 0.80 2WVW 1922433 B 14 17425 31 07950113141209 One gram of any gas at 0 degrees C and atmospheric pressure occupies 22.4 liters. 9 A. True B. False 0041 1922434 D 14 17427 31 141205530113 At 0 degrees C and atmospheric pressure, 1 mole of any gas occupies a volume A. that depends upon the mass of its molecule B. that depends upon its formula mass C. of Avogadro's number of liters 9 D. of 22.4 liters 0041 1922435 D 15 17431 32 019507061790 What is the volume occupied by 0.200 mole of an ideal gas at 380 torr and 300 degrees K? A. 1.73 liters B. 3.67 liters C. 8.20 liters 9 D. 9.84 liters E. 16.4 liters 0042 1922436 D 15 17434 32 109714070114 A sample containing 1.6 gram of O and 2.02 gram of Ne are placed 4 2 in an 8.2 liter flask. What is the total pressure of the gas 0042 mixture at 27 degrees C? 9 A. 0.15 atm B. 0.30 atm C. 0.40 atm D. 0.45 atm E. 0.60 atm 1922437 E 15 17438 32 021801141201 Nitrogen gas was placed in a 22.4_liter container at 273 degrees absolute. The resulting pressure of the nitrogen was 2 atmospheres. Calculate the number of grams of nitrogen in the container. 9 A. 5.6 B. 2.8 C. 28 D. 1.4 E. None of these. 0042 1922438 C 15 17442 32 120101860114 Calculate the density, in grams per liter, of oxygen at 546 degrees C. and 760 mm. pressure A. 0.715 B. 0.357 C. 0.476 D. 16 9 E. can not be calculated from this data. 0042 1922439 D 15 17445 32 044501130161 Given a constant mass of an ideal gas, if both the Kelvin temperature and the volume are halved, what will be the new pressure relative to the original pressure? 9 A. 3/2 B. 2/3 C. 5/1 D. 6/1 E. the same. 0042 1922440 C 15 17448 32 019507060161 The volume of an ideal gas is reduced by one half at constant temperature. Which of the following statements is true? A. The average speed of the molecules increase. B. The average speed of the molecules decrease. C. The number of collision of molecules with unit area of the wall increase by a factor of two. D. The number of collisions of molecules with unit area of the wall remains constant. 9 E. None of the above. 0047 1922441 C 15 17454 52 01140195 At the upper level of the troposphere (the atmosphere closest to the earth) about 7 miles above sea level, the air pressure is 190 mm of Hg and the temperature about _55 degrees C. What would be the volume of one mole of air? The average molecular weight of air is 29 and the gas constant is 0.082 1 atm 5 _1 _1 deg mole . A. 7.15 liters B. 22.4 liters C. 71.5 liters 9 D. 142.0 liters E. 73.0 liters. 1922442 A 14 17460 51 141204130433 When the atmospheric pressure decreases, the mercury level 0047 in a barometer measuring it will A. drop C. remain constant 9 B. rise D. depend on yet other variables 1922443 A 15 17463 52 070606540288 A gas occupies a volume of 200 ml at 400 torr. To what pressure must the gas be subjected in order to change the volume to 20.0 ml? The temperature remains constant. A. 4000 torr B. 400 torr C. 40.0 torr D. 800 torr 9 E. 1600 torr 0028 1922444 A 15 17467 32 088406540288 A given mass of gas occupies a volume of 200 ml at 273 degrees C and 3.00 atmospheres. What volume would the gas occupy at standard temperature and pressure? 9 A. 300 ml B. 1200 ml C. 333 ml 600 ml E. 100 ml 0028 1922445 D 15 17470 32 06540288 At 27 degrees C the volume of a given gas is 600 ml. Holding the pressure constant, what would be the volume of the gas if placed in a room at 0 degrees C? 9 A. 660 ml B. 819 ml C. 300 ml D. 546 ml E. 136 ml 1922446 C 15 17473 52 088406540288 If 2.00 g of a gas occupy 1.12 liters at STP, what is the molecular mass of the gas? 9 0028 0028 A. 100 amu B. 4.00 amu C. 40.0 amu D. 10.0 amu E. 1.00 amu 1922447 D 15 17476 52 019501960161 A volume of hydrogen was measured to be 1.00 liter at a temperature of 80 degrees C and a pressure of 700 torr. What volume will the gas occupy at STP? A. 0.812 liters B. 1.19 liters C. 1.34 liters D. 0.713 liters 9 E. none of these 0020 1922448 C 15 17480 52 088401610113 Given 10.0 liters of a gas at STP, what would the temperature of the gas be if the pressure is increased to 3.00 atmospheres and the volume is decreased to 5.00 liters? A. 290 degrees K B. 186 degrees C C. 410 degrees K 0020 9 D. no change in temperature E. not enough information is available to solve the problem 1922449 D 15 44407 52 0224 Which of the following formulas does NOT describe the behavior of one mole of an ideal gas? A. V =(P /P )x(T /T )x V 4 2 1 2 2 1 1 B. P V = P V at constant T 4 11 22 C. PV/T = a constant D. none of these 9 E. all of these 0020 1922450 C 15 17488 31 011413890317 Pressure can be expressed in A. grams per unit area B. atmosphere per liter C. force per unit area D. mass of mercury per unit area 9 E. all of these 0020 1922451 D 15 17491 32 019501130161 The volume of a gas is 100 ml at a temperature of 25 degrees C and a pressure of 760 torr. Its volume at the same temperature but at a pressure of 500 torr is 9 A. 200 ml B. 100 ml C. 66.0 ml D. 152 ml E. none of these 0020 1922452 C 15 17495 32 011301140195 1.00 liter of a gas is initially at one atmosphere pressure and room temperature. What is the new volume if the pressure is increased to 2 atmospheres and the temperature remains constant? A. 2 liters B. 50 ml C. 500 ml D. the same 9 E. none of these 0020 1922453 E 15 17499 32 016101130195 If the temperature of a gas is decreased but the volume is held constant A. the average kinetic energy increases B. the density of the gas decreases C. the average velocity of the molecules increases D. the gas molecules make more collisions with the walls of the vessel 0020 9 E. none of the above 1922454 E 15 17504 32 039801130114 A mass of oxygen gas occupies 10.0 liters under a pressure of 800 torr. What volume will this same mass of gas occupy at a pressure of one atmosphere? assume the temperature to remain constant. A. 80.0 liters B. 100 liters C. 95.0 liters D. 105 liters 9 E. none of these 0020 1922455 A 15 17508 32 053701140113 Two three_liter containers are connected by a closed valve. One container has a pressure of 600 torr of hydrogen and the other a pressure of 1200 torr of hydrogen. Both gas samples are at the same temperature. What is the final pressure in both containers when the valve is opened? A. 900 torr B. 1800 torr C. 1200 torr D. 1000 torr 9 E. none of these 0020 1922456 C 14 17513 32 053201140195 A certain mountain rises to 14,100 feet above sea level. The pressure at the top is about 17.7 inches (of mercury). If you blew up a balloon at sea level, where the pressure happened to be 29.7 inches, and carried it to the top of the mountain, by what factor would its volume change? A. there would be no change B. 29.7 _ 17.7 9 C. 29.7/17.7 D. 17.7/29.7 0009 1922457 D 15 17518 52 055301130321 There are_____________moles of a gas in 3.5 liters at 5 atmospheres and 182 degrees C. A. 3.5/22.4 B. (3.5)(5)/22.4 C. (3.5)(8/5)(5) D. (3.5)(3/5)(5)/22.4 9 E. 22.4/35 1922458 A 15 17521 32 011310970553 A gas sample occupies a volume of 16.4 liters at 27 degrees C and 0.30 atm. How many moles of the gas are present? 9 A. 0.20 B. 0.45 C. 3.5 D. 5.0 E. none is correct 0019 0019 1922459 B 15 17524 32 109701130195 A sample of gas occupies 8 liters. If the pressure increases by a factor of 4 and the absolute temperature is doubled, what will be the new volume in liters? 9 A. 1 B. 4 C. 16 D. 64 E. none is correct 0019 1922460 A 14 17527 32 011301860884 A gas has a density of 5.4 g/liter at 0 degrees C and 2 atm of pressure. What will be its density at STP? A. 2.7 g/liter B. 5.4 g/liter C. 10.9 g/liter 9 D. none is correct 0019 1922461 D 15 17530 32 027214080195 During an experiment, 350 ml of oxygen were collected over water at 22 degrees C and a barometric pressure of 749 mm. Which of the following will give the volume of dry oxygen at STP? (Vapor pressure of water at 22 degrees C = 20 mm.) 0019 273 degrees K 749 mm A. 350 ml x _____________ x ______ 295 degrees K 760 mm 295 degrees K 760 mm B. 350 ml x _____________ x ______ 273 degrees K 729 mm 273 degrees K 729 mm C. 350 ml x _____________ x ______ 293 degrees K 760 mm 273 degrees K 729 mm D. 350 ml x _____________ x ______ 295 degrees K 749 mm 9 E. none of the above is correct 1922462 B 15 17540 32 011401611097 At a pressure of 2.0 atm, 0.30 moles of hydrogen was found to occupy a volume of 3.7 liters. What was the temperature in degrees centigrade of the sample? 9 A. 17 B. 27 C. 37 D. 67 E. none is correct 0019 1922463 C 15 17543 32 016107060553 At what temperature would two moles of a perfect gas occupy 82 liters and exert a pressure of 1 atmosphere? 0019 9 A. 5 degrees K B. 50 degrees K C. 500 degrees K D. 1000 degrees K E. none of these 1922464 E 15 17546 32 019501610398 If the volume and the absolute temperature of a certain mass of gas were both doubled, the pressure would be A. one_half as great B. twice as great C. one_fourth as great 9 D. four times as great E. unchanged 0035 1922465 D 15 17549 32 019501140161 To triple the volume of a given weight of gas at 27 degrees C, keeping pressure constant, raise the temperature to A. 81 degrees C B. 273 degrees C C. 546 degrees K 9 D. 900 degrees K E. 627 degrees K 0035 1922466 E 15 17552 32 119905530114 A one liter vessel contains three moles of a gas at 273 degrees C. The pressure in the cylinder expressed in atmospheres is A. 33.6 atm. B. 100.8 atm C. 145.6 atm. 9 D. 67.2 atm. E. 134.4 atm. 0035 1922467 D 15 17555 32 054201140195 A balloon occupies 1000 ml under a pressure of 1 atmosphere and a temperature of 0.0 degrees C. Calculate the volume it will occupy under a pressure of 2 atmospheres and at a temperature of 273 degrees C. 9 A. 500 ml B. 2000 ml C. none of these D. 1000 ml E. 4000 ml 0035 1922468 B 15 17559 32 016103920113 If the temperature of a given quantity of gas is held constant and its pressure is doubled, its volume will B. double B. be reduced to one half the orginal volume C. not be affected D. be divided by 1/2 9 E. reduced to one fourth the original volume 0034 1922469 C 15 17563 32 019503920113 If the volume of a given quantity of gas is held constant and its temperature is raised, the pressure will A. double B. be reduced C. be increased D. be reduced to one half the original pressure 9 E. impossible to tell from the facts given 0034 1922470 D 15 17567 32 011401130161 If the pressure of a given quantity of gas is held constant and its temperature is lowered from 300 degrees K to 200 degrees K, the volume will 0034 9 A. be reduced to one half the original volume B. be raised to three halves the orginal volume C. be doubled D. be reduced to two thirds the original volume E. be reduced by an amount that cannot be predicted from the data given 1922471 B 14 17573 32 1429 The critical temperature of H O is higher than that of O because 4 2 2 the H O molecule has: 4 2 A. fewer electrons than O B. a dipole moment 4 2 9 C. two covalent bonds D. a linear shape 1922472 A 14 17577 52 07060884 The volume occupied at STP by 1.00 g of C H (g) is: 4 38 9 A. 0.508 liter B. 0.988 liter C. 1.01 liters D. 22.4 liters 0003 0003 1922473 B 14 17580 32 0706 The volume occupied by 0.100 mole of an ideal gas at 0 degrees C and 0.250 atm pressure is (in liters): 9 A. 0.448 B. 0.560 C. 4.48 D. 8.96 E. 2.24 0003 1922474 C 14 17583 32 0706 The volume occupied by 0.500 mole of an ideal gas at 273 degrees C and 1.00 atm pressure is: 9 A. 5.60 liters B. 11.2 liters C. 22.4 liters D. 44.8 liters 0003 1922475 C 14 17586 32 0706 A sample of Cl gas having a volume of 0.750 liter at 20 degrees 4 2 C and 725 torr has a weight equal to: 0003 5 3 9 A. 1.60 x 10 g B. 10.6 g C. 2.11 g D. 0.320 g 1922476 C 14 17589 32 0706 The molar volume of acetylene (C H ) at 300 degrees K and 0.450 4 22 atm pressure is: 9 A. 22.4 liters B. 26.2 liters C. 54.7 liters D. 105 liters 0003 1922477 A 0003 14 17592 32 0706 The density of carbon monoxide at STP is: A. 1.25 g/liter B. 0.800 g/liter 9 C. 22.4 g/liter D. 28.0 g/liter 1922478 A 14 17594 51 06160612 The x_ray diffraction picture of a liquid shows: A. a concentric_ring pattern B. a regular spot pattern 9 C. parallel straight lines D. lines radiating from a point 1922479 C 14 17597 52 07060884 0540 What is the volume at standard temperature and pressure of 45 grams of nitrogen(II) oxide gas, which has the molecular formula NO ? ( atomic weights N = 14 , O = 16 ) A. 22.4 liters C. 33.6 liters 9 B. 11.2 liters D. 44.8 liters 1922480 A 14 17601 52 07060884 0540 What is the volume at standard temperature and pressure of 18 grams of gaseous oxygen diflouride , OF ? 4 2 A. 7.5 liters C. 22.4 liters 9 B. 11.2 liters D. 33.6 liters 1922481 A 14 17605 52 07060884 0540 What is the volume at standard temperature and pressure of 8.8 grams of carbon dioxide gas, CO ? ( atomic weights C = 4 2 12, O = 16) A. 4.5 liters C. 7.1 liters 9 B. 2.2 liters D. 7.1 liters 1922482 B 14 17609 52 07060884 0540 What is the volume at standard temperature and pressure of 8 grams of methane gas, CH ? ( atomic weights C = 12 , H = 4 4 1.0) A. 5.6 liters C. 16.8 liters 9 B. 11.2 liters D. 22.4 liters 1922483 C 14 17613 52 07060884 0540 What is the volume at standard temperature and pressure of 16 grams of gaseous sulfur dioxide, SO ? ( atomic weights O 4 2 = 16, S = 32) A. 22.4 liters C. 5.6 liters 9 B. 11.2 liters D. 16.8 liters 0003 1922484 D 14 17617 52 07060884 0540 What is the volume at standard temperature and pressure of 10 grams of gaseous hydrogen fluoride, HF ? ( atomic weights H = 1.0, F = 19) A. 22.4 liters C. 33.6 liters 9 B. 44.8 liters D. 11.2 liters 1922485 A 14 17620 52 07060884 0540 What is the volume at standard temperature and pressure of 7.3 grams of gaseous hydrogen chloride, HCl? ( atomic weights H = 1.0 , Cl = 35.5 ) A. 4.5 liters C. 11.2 liters 9 B. 5.6 liters D. 22.4 liters 1922486 D 14 17623 52 07060884 0540 What is the volume at standard temperature and pressure of 8.1 grams of gaseous hydrogen bromide, HBr? ( atomic weights H = 1.0 , Br = 80 ) A. 22.4 liters C. 5.6 liters 9 B. 11.2 liters D. 2.2 liters 1922487 A 14 17626 52 07060884 0540 What is the volume, in liters, at STP of 9.2 g gaseous nitrogen(IV) oxide, NO ? 4 2 9 A. 4.5 B. 5.6 C. 6.9 D. 10.1 E. 112 1922488 D 15 17630 52 07060884 0540 What is the volume at standard temperature and pressure of 14 grams of nitrogen gas, N ? ( atomic weight N = 14 ) 4 2 A. 22.4 liters C. 33.6 liters E. 5.6 liters 9 B. 44.2 liters D. 11.2 liters 1922489 A 15 17634 52 07060884 0540 At standard temperature and pressure, what volume will 28 grams of nitrogen gas, N , occupy? ( Atomic weight N = 14 ) 4 2 A. 22.4 liters C. 33.6 liters E. 5.6 liters 9 B. 44.2 liters D. 11.2 liters 1922490 C 15 17638 52 0706 0540 A sample of oxygen gas, O , has a volume of 33.6 liters at 4 2 standard temperature and pressure. How many grams are present? A. 24 grams C. 48 grams E. 12 grams 9 B. 32 grams D. 64 grams 1922491 A 15 17642 52 0706 0540 A sample of nitrogen gas, N , has a volume of 22.4 liters at 4 2 standard temperature and pressure. How many grams does it weigh? ( atomic weight N = 14 ) A. 28 grams C. 7 grams E. 42 grams 9 B. 14 grams D. 56 grams 1922492 B 15 17646 52 0706 0540 A sample of fluorine gas, F , has a volume of 11.2 liters at 4 2 standard temperature and pressure. How many grams does it weigh? ( Atomic weight F = 19 ) A. 38 grams C. 9.5 grams E. 28.5 grams 9 B. 19 grams D. 57 grams 1922493 C 15 17650 52 0706 0540 Which of the following quantities of matter contains the same number of particles (atoms, molecules, or ions) as 0.1 mole of He atoms ? A. 0.8 gram of O molecules 4 2 B. Avogadro's number of marbles 5 22 C. 6.02 x 10 atoms of Na D. 0.05 gram_atom of H molecules 4 2 5 +2 9 E. 2.0 grams of Ca ions 1922494 C 14 17656 51 05490317 The pressure of a gas is a measure of A. the speed of a gas molecule B. the number of gas molecules in a sample C. the force exerted by a gas on a specified area D. the total energy of a gas sample which is dependent on 9 the temperature of that sample 1922495 B 15 17660 52 0549 An 8.2 liter sample of Cl gas is found to contain 0.10 mole 4 2 of the gas at a temperature of 27 degrees C. The pressure of the gas is A. 3.3 atm C. 0.027 atm E. 3.0 atm OS85 9 B. 0.30 atm D. 37.0 atm 1922496 D 15 17664 52 0549 A 4.10 liter sample of NO gas confined at a temperature of 127 degrees C is found to contain 0.333 mole of the gas. The pressure of the sample is A. 0.0420 atm C. 0.847 atm E. 1.18 atm 9 B. 0.370 atm D. 2.66 atm 1922497 C 15 17668 52 0549 A 0.60 mole sample of NH gas is found to occupy a volume of 4 3 16.4 liters at a temperature of 77 degrees C. The pressure of the gas is A. 0.34 atm C. 1.05 atm E. 0.0023 atm 9 B. 0.23 atm D. 0.95 atm 1922498 A 14 17672 52 0114 What is the pressure exerted by a 10 mole sample of H at 4 2 0 degrees C which is confined in a 22.4 liter vessel? 9 A. 10 atm B. 5.0 atm C. 3.0 atm D. 1.0 atm 1922499 B 14 17676 52 0114 Calculate the pressure in a cylinder of argon gas if the cylinder has a volume of 15.0 liters and contains 12.5 moles of the gas at a temperature of 27 degrees C. 9 A. 40.0 atm B. 20.5 atm C. 10.1 atm D. 1.00 atm 1922501 B 15 17679 32 19660884 The volume of 16 grams of oxygen at STP is: A. 1 liter B. 11.2 liters C. 16 liters D. 160 liters 9 E. insufficient information to do the calculation 1922502 A 15 17682 31 01610114019511 Which of the following statements is not correct? 3 ___ A. At constant temperature the pressure of a certain amount of gas increases with increasing volume. B. At constant volume the pressure of a certain amount of gas increases with increasing temperature. C. At constant pressure the volume of a certain amount of gas increases with increasing temperature. BRHM ETS2 OS 9 D. In dealing with gas laws the most convenient scale of temperature to use is the absolute or kelvin. E. Equal numbers of molecules of all gases exert about the same pressure at a certain temperature and volume. 1922601 D 15 17691 52 04100711 A sample containing 1.6 g of O and 2.02 g of Ne are placed 4 2 in a 8.2_liter flask. What is the total pressure of the gas mixture at 27 deg C? 5 _1 (At. Wt O=16.0, Ne=20.2; R=0.082 liter atm mole A. 0.15 atm B. 0.30 atm C. 0.40 atm D. 0.45 atm 9 E. 0.60 atm 2WVW _1 deg ) 1922602 E 15 17696 32 077101130168 What is the partial pressure in torr of the gas B H in a 4 26 mixture of gases containing 7.0 g B H , 4.0 g CH and 7.0 g C H 4 26 4 24 at standard conditions? 3 9 A. 190 B. 380 C. 25.3 D. 570 E. 253 0042 1922603 C 15 17701 52 129107710445 When equal weights of helium gas and methane gas are added to an empty container at 25 degrees C, the fraction of the pressure exerted by the helium is: A. 1/2 total pressure B. 1/5 total pressure C. 4/5 total pressure D. 1/2 total pressure x 273/298 9 E. 4/5 total pressure x 273/298 0042 1922604 B 15 17705 52 109713060771 A 7.20 g sample of pure Cu(NO ) was placed in an evacuated 4 32 container and heated until it completely decomposed as follows: 2 Cu(NO ) _____> 2 CuO +O + 4 NO 4 32 (s) 2(g) 2(g) If the total pressure in the container is now 930 torr, what is the partial pressure of O ? 4 2 A. 35.7 torr B. 186 torr C. 133 torr 0044 9 D. 159 torr E. 310 torr. 1922605 B 15 17711 52 011301680771 A gas mixture contains an equal number of CO molecules and CO 4 2 molecules, and no others. Assuming ideal gas behavior, which of the following statements is true? A. The total mass of CO is the same as the CO. 4 2 B. Since CO molecules have more mass, they have more inertia 4 2 and contribute more to the pressure. C. The average velocity is the same for CO and CO . 4 2 9 D. None of the above. 0044 1922606 C 15 17719 52 011417900168 The total pressure of a mixture of gases is 1420 torr. The mixture is analyzed and found to contain only 3.47 moles of H S, 2.22 moles of O , and 4.80 moles of N . What is 42 2 2 the partial pressure of O in torr? 4 2 5 4 4 _2 9 A. .142 x 10 B. .315 x 10 C. 301 D. .332 x 10 E. 639. 0044 1922607 C 15 17725 52 011401811790 Suppose 4.60 grams of CH OH and 5.20 grams of CH O are injected 4 3 2 into a large evacuated container maintained at 25 degrees C. After all the CH OH and CH O have vaporized, the total pressure 4 3 2 is found to be 329 torr. What is the partial pressure of CH O? 4 2 (MW's: CH OH _ 32.0, CH O _ 30.0 g/mole) 4 3 2 A. 382 torr B. 0.056 torr C. 177 torr 9 D. 283 torr E. 152 torr. 0044 1922608 C 15 17733 52 109711491408 A sample of O was collected over water at 47.2 degrees C when 4 2 the barometric pressure was 783 torr. The volume of the gas as it was collected was 2.67 liters. What would the volume of dry O be at STP? (The vapor pressure of H O at 47.2 is 81.8 torr) 42 2 0044 9 A. 3.04 liters B. 2.21 liters C. 2.10 liters D. 14.2 liters E. 3.22 liters. 1922609 C 15 17739 52 179001610114 A 1.91 liter tank containing O at 320 torr is connected to a 4 2 2.11 liter tank containing O at 199 torr, and the contents 4 2 allowed to mix, at constant temperature. The final pressure in torr is: 9 A. 488 B. 103 C. 257 D. 520 E. 2.74 0044 1922610 A 15 17744 52 140717900134 A 2.69 liter flask contained He at 711 torr. A 3.60 liter flask contained ar at 790 torr. The contents of the two flasks were mixed by opening a stopcock connecting them. What is the mole fraction of He in the mixture? (assume constant temperature, ideal gas behavior, and neglect the volume of the connecting stopcock.) 9 A. .402 B. .526 C. .598 D. .474 E. 1.28 0044 1922611 E 15 17749 52 109713060771 A .800 g sample of pure (NH ) CO was placed in an evacuated 4 42 3 container and heated until it completely decomposed as follows: (NH ) CO _____> 2 NH + CO +HO 4 42 3 3(g) 2(g) 2 (g) If the total pressure in the container is now 652 torr, what is the partial pressure of H O? 4 2 A. 6.33 torr B. 130 torr C. 239 torr 9 D. 5.43 torr E. 163 torr. 1922612 A 15 17755 52 011301680771 A gas mixture contains an equal number of CO molecules and CO 4 2 molecules, and no others. Assuming ideal gas behavior, which of the following statements is true? A. The partial pressures of CO and CO are the same. 4 2 B. The total mass of CO is the same as the CO. 4 2 C. If the temperature is increased at constant volume, the pressure due to CO will rise more rapidly than that of 4 2 co. D. Since CO molecules have less mass, they have higher 0044 0044 9 velocity, make more frequent impacts, and hence contribute more pressure. E. None of the above. 1922613 C 15 17765 52 088407710654 Exactly 380 ml of oxygen are collected over water at 27 degrees C and 627 torr. Compute the volume of dry oxygen at STP. Vapor 3 ___ pressure of water at 27 degrees C is 27 torr. 9 A. 546 Ml B. 286 ml C. 273 ml D. 1090 ml E. 137 ml 0028 1922614 C 15 17769 31 011401680771 The total pressure of a mixture of gases is A. always constant B. increased as the temperature is lowered C. equal to the sum of the partial pressures of the individual gases D. inversely propotional to the square of the vapor pressures 9 E. none of the above 0020 1922615 B 15 17773 52 109714070771 A 100 ml sample of nitrogen at 0.5 atm and 50 degrees C is placed in an evacuated 200 ml flask at 50 degrees C. Helium at 50 degrees C is then added until the total pressure is 750 mm of Hg. The partial pressure of nitrogen in the mixture is _____ mm Hg. 9 A. 380 B. 190 C. 750_380 D. 750_190 E. 760 0019 1922616 C 15 17778 32 016807710134 In a gas mixture, the partial pressure of gas A is 380 mm Hg, when the total pressure is equal to 1140 mm Hg. What is the mole fraction of gas A? 9 A. 3.0 B. 0.30 C. 0.33 D. 3.3 E. 0.432 0019 1922617 D 14 17781 31 129105530114 When equal numbers of moles of two gases at the same temperature are mixed in a container, the pressure of the gaseous mixture is A. given by Gay_Lussac's law of combining volumes B. the product of the pressures each gas would have if alone C. the difference of the pressures each gas would have if alone in the container 9 D. the sum of the pressures each would have if alone 0009 1922618 A 15 17787 32 002508840114 If 200 ml of oxygen and 400 ml of nitrogen, measured at STP, are forced into a 100 milliliter container at 25 degrees C, the total pressure will be 0035 9 A. 6 atm. B. 3 atm C. 5 atm. D. 2 atm. E. 4 atm. 1922619 D 15 17790 52 016801130771 A mixture of gases contains 4.0 g each of SO , O and CH . 4 2 2 4 5 o At 27 C the total pressure is 644 mm Hg. The partial pressure in mm Hg of the CH is 4 4 9 A. 161 B. 184 C. 92 D. 368 E. 215 1922620 A 14 17794 52 1947 A mixture of O (g) and O (g) had a volume of 1 liter at STP. The 4 3 2 O (g) was completely converted to O (g) and the volume expanded to 43 2 1.10 liters at STP. Calculate the % volume of O (g) in the ori_ 4 3 ginal mixture. 9 A. 20 B. 15 C. 10 D. 5 1922621 C 15 17799 52 0771 What is the partial pressure of helium when 8.0 grams of He and 16 grams of oxygen are in a container with a total pressure of 2.00 atm? 9 A. 1.33 atm B. 0.67 atm C. 1.60 atm D. 1.0 atm E. 1.7 atm 1922622 B 15 17802 52 07710445 What weight of hydrogen gas (in grams) would give a partial pressure of 0.67 atm when confined in a container with 8.0 g of helium at 2.0 atm total pressure of both gasses? 9 A. 2.67 B. 2.0 C. 1.0 D. 5.33 E. 1.33 1922623 E 15 17805 52 0771 The total pressure exerted by oxygen and nitrogen in a container is 4 atm and the partial pressure of the oxygen is 0.5 atm. What is the partial pressure of nitrogen? 9 A. 2.0 atm B. 4.5 atm C. 2.5 atm D. 8 atm E. 3.5 atm 1922624 B 15 17809 52 0771 A 2.0 liter vessel contains nitrogen at 2.2 atm and has a total internal pressure of 4.4 atm. What is the partial pressure of the remaining gas? 9 A. 1.1 atm B. 2.2 atm C. 6.6 atm D. 2.0 atm E. 1.2 atm 1922625 E 15 17812 52 0771 0042 0058 When 3.0 liters of argon at 2.0 atm is mixed with 2.0 liters of xenon at 1 atm and the final volume is 5.0 liters, what are the partial pressures of the gasses? A. 0.4 atm Xe 3.3 atm Ar D. 3.3 atm Ar 2.5 atm Xe B. 1.2 atm Xe 0.4 atm Ar E. 1.2 atm Ar 0.4 atm Xe 9 C. 1.2 atm Ar 2.5 atm Xe 1922626 D 15 17816 52 0771 A 4.0 liter container of N at 2.5 atm and a 3.0 liter 4 2 container of Ne at 4.0 atm are allowed to mix at constant temperature without any change in total volume. What are the respective partial pressures? A. 2.5 atm N , 4.0 atm Ne B. 4.4 atm N , 9.3 atm Ne 4 2 2 C. 3.3 atm N , 3.0 atm Ne D. 1.4 atm N , 1.7 atm Ne 4 2 2 E. 0.83 atm N , 1.3 atm Ne 94 2 1922627 B 15 17823 52 0771 A 2.0 liter vessel contains a 1.0 liter bulb of N at 1.0 4 2 atm and the rest of the space is occupied by Cl gas also at 4 2 1.0 atm. If the bulb breaks, what is the resulting partial pressure of the N in the vessel? 4 2 9 A. 1.0 atm B. 0.5 atm C. 2.0 atm D. 0.7 atm E. 1.5 atm 1922628 E 15 17829 52 0771 The original pressures of helium and methane are each 760 torr when in separate 2 liter compartments of a box. When the partition is removed, what is the partial pressure of the methane in the box? A. 760 torr C. 1520 torr E. 380 torr 9 B. 1140 torr D. 330 torr 1922701 C 14 17833 31 119707061410 The value of the ideal_gas constant R in joules per mole_degree is: 9 A. 101 B. 19.2 C. 8.31 D. 4.18 0043 1922702 D 15 17835 52 019507061790 What is the volume occupied by .277 mole of an ideal gas at 0044 5 o 764 torr and 14.1 C? A. 0.154 liters B. 0.319 liters C. 3.13 liters 9 D. 6.49 liters E. 0.00854 liters. 1922703 C 15 17838 52 011401130161 The pressure of a gas in a 25.0 liter tank is 709 torr. If the gas is transferred to a 43.9 liter container at the same temperature, what is the final pressure of the gas (in torr)? A. 709 torr B. 0.00495 torr C. 404 torr 9 D. 0.531 torr E. more information is required. 0044 1922704 A 15 17842 52 011407060128 5 o What is the pressure on 2.85 grams of an ideal gas at 10.8 C occupying 7.71 liters? (The molecular weight of the hypothetical gas is 20.1 grams per mole.) A. 326 torr B. 2.33 torr C. 0.0162 torr D. 0.429 torr 9 E. 61.6 torr. 0044 1922705 C 15 17846 72 018601130287 Determine the density (g/liter) of a gas, given the following data: 5 _1 o MW = 53.2 grams mole ; pressure = 782 torr; temperature = 42.5 C A. 15.7 B. .473 C. 2.11 D. 1610 9 E. more information is required 1922706 A 15 17851 52 139201611097 Absolute zero is defined as the temperature at which: A. a straight line graph of P vs. T for a confined sample of an ideal gas intersects the T axis. B. The density of a liquid equals that of its vapor. C. Mercury freezes solid. D. A straight line graph of V vs. 1/P intersects the 1/P axis. 9 E. None of the above. 0044 1922707 A 15 17856 52 011401130161 The pressure of a gas in a 25.0 liter tank is 720 torr. If the gas is transferred to a 47.4 liter container at the same temperature, what is the final pressure of the gas (in torr)? 5 2 _3 _1 A. 3.80 x 10 B. 2.63 x 10 C. 5.00 x 10 5 2 9 D. 7.20 x 10 E. more information is required. 0044 0044 1922708 B 15 17861 52 011301610195 A 46.4 liter vessel containing hydrogen gas at a fixed temperature and pressure and a 23.2 liter vessel containing oxygen gas at the same temperature and pressure are mixed in a reaction chamber and sparked. After the temperature and pressure of the resulting gas(es) are returned to the initial temperature and pressure, what is the total volume (in liters) of the gas(es)? (assume all the water is present as water vapor.) A. 23.2 B. 46.4 C. 92.8 D. 2.07 9 E. more information is required. 0044 1922709 D 15 17868 52 016107061790 At what temperature will 0.171 mole of an ideal gas at 501 torr occupy 6.78 liters? 5 2 _2 A. 3.19 x 10 degrees C B. 2.16 x 10 degrees C 5 _3 1 C. 1.36 x 10 degrees C D. 4.63 x 10 degrees C 5 5 9 E. 2.42 x 10 degrees C. 0044 1922710 C 15 17873 52 070606470114 A fixed amount of an ideal gas undergoes the following changes: Initial conditions Final conditions P = 782 torr P = ? torr 41 2 T = 40.5 degrees C T = 6.8 degrees C 41 2 V = 47.2 liters V = 17.3 liters 41 2 what is the value of P ? 4 2 47.2 (40.5 + 273) 47.2 6.80 A. 782 x ____ x ____________ B. 782 x ____ x ____ 17.3 (6.80 + 273) 17.3 40.5 0044 47.2 (6.80 + 273) 17.3 (40.5 + 273) C. 782 x ____ x ____________ D. 782 x ____ x ____________ 17.3 (40.5 + 273) 47.2 (6.80 + 273) 17.3 (6.80 + 273) E. 782 x ____ x ____________. 47.2 (40.5 + 273) 9 1922711 B 15 17885 52 019507061790 0044 What is the volume occupied by 15.6 grams of an ideal gas at 701 torr and 31.8 degrees C? The molecular weight of the hypothetical gas is 62.1 grams per mole. 5 _3 A. 8.97 X 10 liters B. 6.82 liters C. 0.712 liters 9 D. 1.41 liters E. 0.147 liters. 1922712 D 15 17889 52 132202930706 Using modern vacuum techniques, a 3.02 liter flask was evacuated 5 _9 to 2.27 x 10 torr at 15.4 degrees C. How many molecules of an ideal gas would be present under these conditions? 5 _9 17 32 A. 5.44 x 10 B. 8.94 x 10 C. 1.11 x 10 5 11 12 9 D. 2.29 x 10 E. 4.31 x 10 . 0044 1922713 A 15 17894 52 018601130287 Determine the density of a gas given the following data: molecular weight = 65.9 grams per mole; pressure = 821 torr; temperature = 45.8 degrees C. 5 3 A. 2.72 g/liter B. 19.0 g/liter C. 2.07 x 10 g/liter 5 _1 9 D. 3.67 x 10 g/liter E. more information is required. 0044 1922714 A 15 17899 52 018601131790 The density of a gas is 3.31 grams per liter at 36.6 degrees C and 792 torr. What is the density of the gas at STP? A. 3.61 g/l B. 0.425 g/l C. 0.462 g/l 9 D. 23.7 g/l E. 3.31 g/l. 0044 1922715 C 15 17902 52 139201611097 Absolute zero is defined as the temperature at which: A. a straight line graph of V vs. 1/P intersects the 1/P axis. B. All gases must liquify. C. A straight line graph of P vs. T for a confined sample of an ideal gas intersects the T axis. D. A straight line graph of P vs. 1/V intersects the 1/V axis. 9 E. None of the above. 0044 1922716 E 15 17907 52 070602650706 Which one of the following statements is a required postulate for the theoretical derivation of the ideal gas law? A. When a molecule penetrates the wall and sticks there, all its kinetic energy gets transferred to the wall. 0044 9 B. The mass of the molecules is so small that it can be neglected. C. Molecules are spherical in shape and incompressible. D. Because of Van Der Waal's forces all molecules are attracted to each other, especially at short distances. E. The average kinetic energy of the molecules is proportional to the absolute temperature. 1922717 B 15 17915 32 0706 0288 Calculate the mass in grams of 5.60 liters of O gas at STP. 4 2 9 A. 16.0 G B. 8.00 g C. 4.00 g D. 56.0 g E. 32.0 g 0028 1922718 B 15 17918 31 051701950161 The law that relates the volume of a gas to the temperature at constant pressure is A. Boyle's law B. Charles's law C. Gay_Lussac's law D. Dalton's law 9 E. Avogadro's law 0020 1922719 D 15 17921 52 019505420161 The initial volume of a balloon is 6.00 liters at a temperature 5 o of 270 C and 760 torr. What is its volume in liters if the 5 o temperature is increased to 400 C with no change in pressure? 9 A. 3.81 B. 4.05 C. 4.87 D. 7.44 E. 8.89 0020 1922720 A 15 17925 Charles' Law states A. V /T = V /T 4 1 1 2 2 B. V T = V T 4 11 22 C. P V = P V 4 11 22 D. V T = a constant 4 11 9 E. none of these 51 0517 1922721 D 15 17928 31 114501131146 Avogadro's law states A. all gases contain the same number of molecules B. equal volumes of gases at the same pressure have the same 0020 0020 9 temperature C. equal volumes of gases at the same pressure contain equal numbers of molecules D. equal volumes of gases at the same temperature and pressure contain equal numbers of molecules E. none of these 1922722 C 15 17934 52 011308840351 A 2_liter cylinder of oxygen gas at STP contains A. more molecules than a 2_liter cylinder of hydrogen at STP B. fewer molecules than a 2_liter cylinder of carbon dioxide at STP C. the same number of atoms as a 2_liter cylinder of argon at STP D. all of the above 9 E. none of the above 0020 1922723 A 15 17939 51 011305360114 Gases approach ideal behavior when A. the pressure is low and the temperature is high B. the temperature is low and the pressure is high C. when both the temperature and the pressure are low C. when both the temperature and the pressure are high 9 E. none of these 1922724 E 15 17943 31 080201130114 Boyle's law states A. gases are in constant random motion B. the pressure of a gas is proportional to the temperature if the volume remains constant C. the volume of a gas is directly proportional to the pressure if the temperature remains constant D. all of the above 9 E. none of the above 0020 1922725 C 15 17948 Boyle's law says A. P/V=k B. V/P=k C. V=k/P D. V=kP 9 E. none of these 31 0802 1922726 D 14 44962 31 019505531504 The volume of a mole of gas is A. 22.4 L, regardless of T and P. B. directly proportional to pressure and absolute temperature 0020 0020 0009 9 C. directly proportional to pressure, inversely proportional to absolute temperature D. inversely proportional to pressure, directly proportional to absolute temperature E. inversely proportional to pressure, inversely proportional to absolute temperature 1922727 E 15 17955 31 016101130195 If the temperature of a gas sample is decreased but the volume is held constant A. the density of the gas decreases B. the average kinetic energy increases C. the average velocity of the molecules increases D. the number of collisions of the molecules with the walls increases 9 E. none of the above is correct 0019 1922728 B 13 17960 32 034001141406 A welder has a cylinder of helium. The cylinder has a volume of 32 liters and the gas is under a pressure of 110 atm at 27 degrees C. The cylinder will burst if the pressure reaches 200 atm. Which of the following is false? A. The pressure of the gas is 8360 cm of mercury B. The welder can safely heat the cylinder to 327 degrees C C. The helium could fill a 3500 liter balloon at 27 degrees C 9 and 1 atm of pressure 0019 1922729 C 15 17966 52 131912010113 Which expression is best suited for the calculation of the temperature when the pressure, volume, and amount of gas are known? A. T = PV/nRT B. PV/T = constant C. PV/nR = T D. V is proportional to T 9 E. none of the above 0019 1922730 E 15 17970 31 119714101174 The value of the molar gas constant R A. is 0.08203 under all circumstances B. is dependent on the units used for the pressure and the volume but not dependent on the units used for moles and temperature C. changes as the temperature changes D. is dependent upon the particular gas being studied 9 E. none of the above is correct 0019 1922731 D 15 17975 32 129901131201 When the universal gas constant, R, has the value 0.082, it is expressed in units of A. proportional quantities 0019 5 liters K B. ___________ 4 atm mole 5 liters mole C. ___________ 4 atm K 5 liters atm D. __________ 4 K mole 9 E. R is a dimensionless quantity 1922732 C 15 17980 31 143307061434 The factor PV/nRT for an ideal gas will show A. a negative deviation from unity at low pressures B. a positive deviation from unity at high pressures C. no deviation at any pressure D. a positive deviation from unity at low pressures 9 E. a negative deviation from unity at high pressures 0019 1922733 D 15 17984 31 019507061388 That the volume of a given mass of an ideal gas is directly proportional to the absolute temperature is A. an inaccurate expression. B. true if the centigrade scale of temperature is used. C. true if the volume is held constant. D. true if the pressure is held constant. 9 E. true without qualification. 0035 1922734 B 14 17989 32 06540706 When an ideal gas undergoes unrestrained expansion, no cooling occurs, because the molecules: A. are below the inversion temperature B. exert no attractive forces on each other C. do work equal to the loss in kinetic energy 9 D. collide without loss of energy 0003 1922735 C 0003 14 17993 31 07060161 The absolute temperature of an ideal gas: A. is proportional to the average potential energy of the molecules B. is proportional to the average speed of the molecules C. is proportional to the average kinetic energy of the molecules 9 D. is inversely proportional to the partial pressure 1922736 D 14 17998 32 0161 One way to increase the average speed of the molecules of an ideal gas is to: A. decrease the temperature B. expand the gas against a piston C. expand the gas into a vacuum 9 D. add heat, holding v and p constant 0003 1922737 D 14 18001 31 01611429 The critical temperature is: A. the temperature below which a gas undergoes cooling when expanded into a vacuum B. the temperature at which a gas liquefies at 1 atm pressure C. the temperature at which the average kinetic energy of the molecules is a maximum D. the temperature above which it is impossible to liquefy a 9 gas 0003 1922738 B 14 18006 31 01610706 The behavior of a real gas approaches that of an ideal gas when: A. the temperature is low B. the temperature is high 9 C. the pressure is high D. the volume is low 0003 1922739 A 14 18009 31 011301950114 When a gas is forced into a smaller volume without a change in temperature, its pressure increases because its molecules A. strike each square centimeter of the container walls more often B. strike each square centimeter of the container walls at higher speeds C. strike each square centimeter of the container walls with greater force 9 D. have more energy 1922740 B 15 18015 52 1966 5 _2 Stated with appropriate units, the number 4.46 x 10 is A. the gas constant, R. 0041 GRHL 9 B. the number of liters per mole of an ideal gas at STP. C. the number of moles per liter of an ideal gas at STP. D. degrees Fahrenheit at STP E. none of the above. 1922741 E 15 45329 51 Absolute zero is the temperature at which: A. gaseous helium liquefies. B. a straight_line graph of P versus 1/V intersects the 1/V axis. C. a straight_line graph of V versus 1/P intersects the 1/P axis. D. a graph of P versus V at constant T intersects the V axis. 9 E. a straight_line graph of P versus T intersects the T axis. 1922742 C 15 45334 71 The pressure of 4.0 L of nitrogen in a flexible container is decreased to one_third of its original pressure, and its absolute temperature is decreased by one_half. The volume is now: 9 A. 1.0 L B. 4.0 L C. 6.0 L D. 8.0 L E. 24 L 1922801 C 15 18020 32 02930025800113 The weight of a molecule of oxygen is 16 times as much as the weight of a molecule of hydrogen. One balloon is to be inflated with 2 liters of oxygen and another balloon of the same size with 2 liters of hydrogen measured under standard conditions. If both are kept at the same temperature, the pressure in the first balloon necessary to attain the same volume as the second balloon is A. sixteen times as great as in the second B. one_sixteenth that in the second C. equal to that in the second D. four times as great as in the second 9 E. one_fourth as great as in the second ETS2 OS 1922802 A 15 18028 51 04990114800112 On the basis of the kinetic theory, gas pressure is explained by the A. change in momentum when the molecules collide with the walls of the container B. change in kinetic energy with changes in the temperature of the gas C. assumption that the molecules exert little or no attractive force on one another D. assumption that the molecules collide without loss in kinetic energy E. assumption that the distances between molecules are large 9 compared to their diameters ETS2 OS 1922803 E ETS2 OS 15 18035 51 02930196800112 If the molecules in a tank of hydrogen have the same average speed as the heavier molecules in a tank of oxygen, we may be sure that A. the pressure is the same in the two cases B. the hydrogen is at the higher temperature C. the hydrogen exerts the greater pressure D. the temperature is the same in the two cases 9 E. the oxygen is at the higher temperature 1922804 A 15 18040 32 01610293800112 From the generalization that "all gases at the same temperature have the same average molecular kinetic energy," it is possible to deduce that at the same temperature A. heavy molecules should move more slowly than light molecules B. light molecules should move more slowly than heavy molecules C. light molecules move at the same speed as heavy molecules D. the relative speeds of light and heavy molecules have no relation to the molecular kinetic energies 9 E. more than one of the above could be considered correct 1922805 B 15 18048 72 01090511800113 When the temperature of the air is increased from 20 degrees C to 30 degrees C., the approximate increase in the average kinetic energy of the molecules according to the kinetic molecular theory would be A. 0.34 percent B. 3.4 percent C. 10 percent D. 50 percent 9 E. none of these ETS2 OS ETS2 OS 1922806 E 15 18052 52 01610398800113 Two gases, X and Y, at the same temperature are in containers of different sizes. The mass of an X molecule is greater than that of a Y molecule. It follows, therefore, that A. Y molecules have a higher average speed than X molecules B. the average kinetic energy of X molecules is greater than that of Y molecules C. the pressure exerted by the gas in the smaller container is greater than the pressure of the other gas D. the molecules are closer together in the smaller container E. the information given does not warrant any of the above 9 statements ETS2 OS 1922807 A 14 18060 52 05430168800113 An unglazed pottery jug has walls that are porous. If such a jug were corked and placed in a room containing equal parts of several ETS2 OS gases, after a reasonable time the jug would contain a mixture of the gases. The gas that would represent the greatest component of the mixture would be the one with the A. lowest density B. lowest temperature C. highest specific heat D. highest molecular weight 9 E. highest valence 1922808 B 14 18066 52 01610544800113 To raise the temperature of 1 gm. of gas 1 degree C. would require A. more heat if the gas were not allowed to expand on heating B. more heat if the gas were allowed to expand on heating C. the same amount of heat regardless of the above conditions of confinement D. the answer depends upon the kind of gas employed and thus 9 cannot be answered with the above data ETS2 OS 1922809 E 15 18072 32 01610114800114 If the temperature of a confined gas were kept constant, then A. the volume would increase as the pressure increased B. the pressure would decrease as the volume increased C. the volume and the pressure would be directly proportional D. the volume would decrease as the pressure increased 9 E. more than one of the above are correct ETS2 OS 1922810 B 14 18077 31 011304048003 At the same temperature and pressure, the gas which has the highest density is 3_______ A. carbon monoxide B. chlorine C. sulfur dioxide 9 D. hyrogen sulfide 1922811 CA 25 18080 52 0541054201091390 MACROITEM STEM 2A meteorologic balloon, inflated with helium when the air 2temperature is 20 degrees C. and the barometric pressure is 1000 5 3 millibars, has a volume of 10 m . 0 Using this information, answer the following questions. MACRO SUB_ITEM # 1 5 o If the air temperature should decrease to 0 C, (pressure 5 3 2WVW ETS2 OS remaining constant) the volume of the balloon (in m ) would be A. 1/0.7 B. 10.0 C. 9.30 D. 0.00 E. Some value appreciably different than any of the preceding 1 choices MACRO SUB_ITEM # 2 If the balloon should be allowed to rise until it reached a height 5 o of 3,048 m, where the air temperature is 0 C and the barometric 5 3 pressure is 700 millibars, the volume of the balloon (in m ) would be 9 A. 13.3 B. 14.6 C. 15.0 D. 6.5 E. 7.0 1922812 CAD 35 18093 51 0527052801131290 MACROITEM STEM Van Der Waals' equation states (for one mole of gas) 5 2 [P + (a/V )]x(V_b) = RT 0 Using this information, answer the following questions. MACRO SUB_ITEM # 1 ETS2 OS 5 2 The term (a/V ) represents A. the volume occupied by the gas molecules B. the mean velocity of the gas molecules C. the attractive force between molecules D. the universal gas constant 1 E. none of these MACRO SUB_ITEM # 2 The constant "b" represents A. the volume occupied by the gas molecules B. the mean velocity of the gas molecules C. the attractive force between molecules D. the universal gas constant 2 E. none of these MACRO SUB_ITEM # 3 The constant "R" represents A. the volume occupied by the gas molecules B. the mean velocity of the gas molecules C. the attractive force between molecules D. the universal gas constant 9 E. none of these 1922813 B 15 18104 31 01130265800112 From the generalization that, "The pressure of a gas approaches zero as its temperature approaches _273 degrees C," it is ETS2WVW possible to deduce that A. at a temperature of _273 degrees C. all gases would become solids. B. at a temperature of _273 degrees C. the gas molecules would lose their kinetic energies completely. C. at a temperature of _273 degrees C. the gas would have absolutely no weight. D. at a temperature of _273 degrees C. the gas would have absolutely no volume. 9 E. More than one of the above could be correct. 1922814 B 14 18112 31 019602618003 If a container is filled with hydrogen and another container of the same size is filled with carbon dioxide, both containers will, at the same temperature and pressure, contain the same A. number of atoms B. number of molecules C. weight of gas 9 D. number of neutrons 2WVW 1922815 B 14 18116 52 044500258003 The weight of two liters of oxygen gas at standard temperature and pressure is about A. 1.43 grams B. 2.86 grams C. 16.0 grams 9 D. 32.0 grams 2WVW 1922816 C 14 18119 52 018605698003 The density of krypton gas (atomic weight = 83.8) in grams per liter is A. 1.28 B. 1.88 C. 3.7 9 D. 7.5 2WVW 1922817 D 14 18121 32 044502188003 The weight in grams of 22.4 liters of nitrogen (atomic weight = 14) is A. 3 B. 7 C. 14 9 D. 28 2WVW 1922818 C 5 15 18123 72 0161010980011390 o ETS2 OS o When the temperature of the air is increased from 20 C to 30 C, the approximate increase in the average kinetic energy of the molecules will increase by the approximate factor 9 A. 1.0003 B. 1.003 C. 1.03 D. 1.50 E. 1.10 1922819 C 14 18134 72 1885 The mean free path of the molecules in a gas at 1 atm pressure and 5 o 25 C is A. directly proportional to the square of their diameters. B. the same as at 10 atm pressure. C. inversely proportional to their collision frequencies. 9 D. independent of their diameters. 1922820 C 14 18138 52 According to the Kinetic Molecular Theory, the average kinetic energy of gaseous molecules A. depends on the kind of molecules and the temperature. B. depends on the kind of molecules and is independent of the temperature. C. depends on the temperature and is independent of the kind of molecules. D. is proportional to the first power of the average velocity 9 of the molecules. 1922821 B 14 18144 31 011301148002 Real gases will approach the behavior of an ideal gas at A. low temperatures and high pressures B. high temperatures and low pressures C. low temperatures and low pressures 9 D. high temperatues and high pressures 2 OS 1922822 C 15 18147 52 051107068003 5 _1 _1 Given, R=1.98 cal mole deg , calculate the average kinetic energy in two moles of an ideal gas at 300 deg K. A. 594 cal B. 1190 cal C. 1780 cal D. 2500 cal 9 E. 3560 cal 2WVW 1922823 A 15 18150 72 19741975 How does the average speed of the molecules of a given gas at constant temperature compare with their most probable speed? The average speed 9 A. is greater. B. is less. C. is the same. D. may be greater, equal, or less, depending on the temperature. E. is constant 1922824 D 15 18154 52 025804911314 What is the relative rate of diffusion of O as compared to CH ? 4 2 4 5 1/2 1/2 9 A. 2/1 B. 1/2 C. 2 /1 D. 1/2 E. the same. 0042 1922825 A 15 18157 52 070816480113 According to Graham's law of gas effusion, helium gas will effuse x times as fast as SO . What is the value of x? 4 2 9 A. 4.00 B. 16.0 C. 0.250 D. 256 E. 0.0624 0044 1922826 B 15 18160 52 1648 0161 If 90.0 liters of H effuse through a porous partition in 30.0 4 2 min., what volume of C F will effuse through the same partition 4 24 at the same temperature and pressure in 20.0 min? (MW's: H = 2.02, C F = 100) 4 2 24 9 A. 1.21 B. 8.53 C. 422 D. 2970 E. 46.9 0044 1922827 D 15 18165 52 011301281648 Given: Gas MW (grams/mole) CH 26.0 4 22 H 2.02 4 2 What is the rate of effusion of C H compared to H ? 4 22 2 9 A. 3.59 B. 0.0777 C. 12.9 D. 0.279 E. 0.928 0044 1922828 C 15 18169 52 070816480113 According to Graham's law of gas effusion, helium gas will effuse x times as fast as C H . What is the value of x? 4 24 9 A. .143 B. .378 C. 2.65 D. 112 E. 7.00 0044 1922829 E Given: Gas O 4 2 0044 15 18172 52 011301281648 MW(grams/mole) 32.0 Ne 20.2 What is the rate of effusion of O compared to Ne? 4 2 9 A. 1.26 B. .613 C. 1.58 D. .631 E. .795 1922830 C 15 18176 52 1648 0161 If 42.0 liters of Ar effuse through a porous partition in 21.0 min., what volume of HCl will effuse through the same partition at the same temperature and pressure in 10.0 min? (MW: Ar _ 39.9, HCl _ 36.5) 9 A. 19.1 B. 21.9 C. 20.9 D. 18.3 E. 4.78 0044 1922831 A 15 18180 72 164801131458 Two hypothetical gases effuse into a glass tube 120 cm long. Gas A (MW=9.00) enters at the end marked 0 cm; gas B (MW=25.0) enters the end marked 120. The point at which the gases meet is marked by a white deposit. How far from the end marked 0 cm is the deposit located? 9 A. 75.0 cm B. 31.8 cm C. 45.0 cm D. 3.53 cm E. 88.2 cm. 0044 1922832 C 15 18185 52 042902931791 5 o The root mean square velocity of SO molecules at 25 C is 736 4 2 miles per hour. What is the rms velocity in miles per hour of 5 o HBr molecules at 25 C? 5 ___ 7 (hint: v = /3RT R = 8.314 x 10 erg/(deg mole)). rms V 3 _____ m 9 A. 2920 mph B. 827 mph C. 655 mph D. 583 mph E. 736 mph 0044 1922833 C 15 18192 52 019501140161 Two rigid vessels of equal volume are at the same temperature and pressure. One contains H (gas) and the other contains He(gas). 4 2 Which of the following statements is correct? A. A rise in temperature will decrease the density in both cases to the same extent, but the increased molecular velocity will compensate and lead to the pressure remaining constant. B. The two vessels contain the same mass of gas. C. The helium vessel is reduced to half its volume by pushing in the walls. As a result, the helium pressure 0044 9 is doubled and the helium makes more impacts per unit wall area than the hydrogen. D. If both vessels are cooled, the helium, because it is denser, will condense at a higher temperature. E. The average momentum transferred per molecule per impact is the same for both gases. 1922834 C 15 18204 52 049102580113 5 235 The relative rates of diffusion of the two gases UF and 4 6 5238 UF are 4 6 A. 352/349 B. square root of 349/square root of 352 C. square root of 352/square root of 349 D. 1.43 9 E. 1.86 0020 1922835 B 15 18209 51 138513950293 A person is able to smell perfume because perfume molecules A. are small B. are in constant random motion C. do not collide with other molecules D. travel faster than other molecules 9 E. none of these 0020 1922836 E 15 18212 51 138602930429 The kinetic_molecular theory says A. gas molecules are widely separated from one another B. the velocity of gas molecules increases with increasing temperature C. gas molecules move at different speeds D. gases contain molecules or atoms 9 E. all of these 0020 1922837 C 15 18216 51 029304941387 Molecular collisions are A. rare 5 2 B. equal to (1/2)mv C. perfectly elastic D. more frequent at lower pressures 9 E. all of these 0020 1922838 B 15 18219 52 051113880429 Kinetic energy is A. the same as heat energy B. proportional to the square of the average velocity C. inversely proportional to the temperature D. constant at all temperatures 9 E. none of these 0020 1922839 B 15 18222 51 042902930161 The average velocity of molecules A. is proportional to kinetic energy B. increases with an increase in temperature C. is the same for H and O at the same temperature 4 2 2 D. all of these 9 E. none of these 0020 1922840 A 15 18226 52 042902930161 The velocity of a hydrogen molecule at 25 degrees C is A. approximately 4 times the velocity of oxygen molecules at the same temperature B. equals the velocity of oxygen molecules at the same temperature C. the same at all temperatures 5 _2 D. is approximately 4.6 x 10 m/s 9 E. decreases at higher temperatures 0020 1922841 C 14 18231 51 139201610299 At the absolute zero of temperature A. molecular motion ceases B. the kinetic energy of molecules is zero 5 o C. the temperature is _273.15 C 9 D. all the above 0020 1922842 B 13 18234 52 011301611395 Your lecturer opens a bottle of hydrogen sulfide gas, H S, and a 4 2 bottle of gaseous diethyl ether, C H O, at the same time. Both 4 4 10 gases are at the same temperature and pressure. Which of the two should you be able to smell first? (Both have characteristic odors.) A. the ether B. H S C. both at the same time 4 2 0009 9 D. neither gas would escape into the room 1922843 D 15 18241 31 138601610113 According to the kinetic molecular theory, the absolute temperature of any gas is proportional to: A. the mass of the molecules only B. the potential energy of the molecules C. the randomness of the molecules D. the kinetic energy of the molecules 9 E. none of the above is correct 1922844 C 15 18245 31 011301610494 When a definite amount of gas is enclosed in a vessel at constant temperature, the pressure exerted by it remains constant for any length of time. This fact leads to the postulate of the kinetic molecular theory that: A. the molecules of the gas are constantly colliding with one another and with the wall of the container B. the collisions between molecules and the wall of the container are inelastic C. the collisions between molecules and the wall of the container are elastic D. the molecules of the gas move in straight lines 9 E. none of the above is correct 0019 0019 1922845 A 15 18253 51 140505940588 It is observed experimentally that gases are almost infinitely expansible. From this one can reasonably postulate that A. matter is discontinuous, i.e. composed of discrete particles B. molecules are too small to be seen C. molecules have energy which increases with temperature D. molecular collisions are inelastic E. matter is continuous, i.e. Composed of units which are 9 linked together in chains or sheets 0019 1922846 C 15 18259 52 016101130500 If the temperature of a certain gas sample is increased from 273 degrees K to 819 degrees K, the average momentum of the molecules is expected to A. double B. triple C. increase by a factor of square root of 3 D. increase by a factor of 546 9 E. remain unchanged 0019 1922847 C 15 18263 52 012812910429 The molecular masses of X and Y are equal. The average velocity 0019 of X at 200 degrees K is _____ that of Y at 400 degrees K. A. One half B. square root of 2 times faster than C. 1/square root of 2 times D. twice 9 E. the same as 1922848 D 15 18267 52 011301280429 Two gases A and B are compared at 0 degrees C. The molecular mass of A is 25 times that of B. The average velocity of A is ________ that of the average velocity of B. 9 A. 25 times B. 1/25 C. 5 times D. 1/5 E. none is correct 0019 1922849 D 15 18271 52 011314110398 Two gases, X and Y, are examined at 20 degrees C. It is found that the velocity of X is three times that of Y. It may be concluded that the mass of X is ________ times that of Y. A. Square root of 3 B. 1/square root of 3 C. 9 D. 1/9 9 E. none correct 0019 1922850 E 15 18275 32 14130511 The average kinetic energy of H at 10 degrees C is ________ 4 2 the average kinetic energy of 0 at 50 degrees C. 4 2 A. higher than B. the same as C. 32/2 smaller than D. 50/10 larger than 9 E. 283/323 smaller than 0019 1922851 B 15 18279 52 141613860423 According to the kinetic molecular theory, the heat of vaporization goes primarily to A. speed up molecular motion B. increase the potential energy of the molecules C. move the molecules closer together D. melt the substance 9 E. both A and B. 0040 1922852 B 15 18283 31 070701130511 Which of the following is not a basic part of the kinetic theory 3 ______ 0040 of gases? A. Gas particles are in constant motion. B. Large gas particles have more average kinetic energy than small ones at the same temperature. C. The collisions of gas particles with the container walls result in NO loss of energy. D. Frequent collisions occur between the particles making up the gas. 9 E. Both C and D. 1922853 D 15 18290 31 049901130438 Which of the following statements is correct for both gases and liquids according to the kinetic theory of matter? A. Constituent particles are in constant motion. B. Constituent particles move in straight lines between collisions. C. The speed of the constituent particles increases with temperature. D. More than one response is correct. 9 E. Energy is gained when molecules collide. 0040 1922854 A 15 18296 31 049901130438 According to kinetic theory, a difference between liquids and gases is A. distance between molecules B. average kinetic energy at a given temperature C. the molecules of one are in constant motion 9 D. both A and B E. both B and C. 0040 1922855 B 15 18300 31 138611470442 According to the kinetic molecular theory, in most solids A. there is no motion of the molecules B. there is generally some vibrational movement of the molecules C. the molecules generally revolve around each other and the lattice points D. the molecules are packed together in a rather haphazard fashion 9 E. both B and C. 0040 1922856 D 15 18305 31 051104420113 The kinetic energy of the following gas molecules is the same. Which one is moving the fastest? A. CO B. O C. NH D. H 4 2 2 3 2 9 E. all move the same speed. 0040 1922857 A 15 18308 31 049905110161 If the temperature of object A is higher than that of object B it is true that A. the average kinetic energy of the molecules in object A is greater than that of the molecules in object B B. the average kinetic energy of the molecules in object A is less than that of the molecules in object B C. the average kinetic energy of the molecules in objects A and B is the same D. it is impossible to predict which set of molecules has the greatest kinetic energy 9 E. no correct response is given. 0040 1922858 D 15 18316 31 138604420317 Which of the following is not a postulate of the kinetic 3 ______ molecular theory? A. Matter is composed of molecules in constant motion. B. As the temperature is increased, the molecules move faster. C. All molecules exert an attractive force on one another. D. The molecules of a gas or vapor are quite close together. 9 E. Both A and B. 0040 1922859 B 15 18321 31 049901130494 Which of the following statements concerning gases is not 3 ______ consistent with the kinetic theory? A. The molecules are in constant motion. B. The molecules collide infrequently because of great distances between them. C. Any molecular collisions are perfectly elastic. D. The speed of the molecules increases with increasing temperature. 9 E. Both A and D. 0040 1922860 E 15 18327 31 049904420494 In a sample of liquid at constant temperature, the kinetic theory 3 ____________________ tells us that A. all molecules are moving with the same speed B. the molecules are separated by relatively long distances C. the average speed and energy of the molecules is independent of the temperature D. the molecules are arranged orderly E. constituent particles move in straight lines between 0040 9 collisions. 1922861 C 15 18333 51 016105110293 The temperature in a medium refers to A. the quantity of molecules present. B. the total potential energy of the molecules. C. the average kinetic energy of the molecules. D. the total caloric content of the individual molecules. 9 E. the average potential energy of the molecules. 0035 1922862 D 15 18337 31 029301130161 When the molecules of a confined gas are made to move faster, A. the volume of the gas decreases. B. the temperature of the gas decreases. C. the temperature of the gas remains constant. D. the temperature of the gas increases. 9 E. the gas condenses to a liquid. 0035 1922863 C 15 18341 31 031701130500 The force exerted on the walls of a vessel by a contained gas is caused by A. the repulsive forces between the molecules. B. slight loss in average speed suffered by the molecules at the walls. C. changes in the momentum which the molecules experience at the walls. D. attraction between the walls and the gas. 9 E. elastic collisions between molecules of the gas. 0035 1922864 A 15 44968 51 051102930398 In computing the kinetic energy of a gas molecule, it is necessary to consider both the velocity of the molecule as well as A. its mass. B. the number of atoms in the gas molecule. C. the kinds of atoms in the gas molecule. D. its physical properties. 9 E. the types of chemical bonds in the molecule 0035 1922865 D 15 18351 31 027601680511 According to theory, in a given mixture of oxygen and nitrogen, of uniform temperature throughout A. all the molecules are moving at the same speed. B. all the molecules possess the same kinetic energy C. the average speed of the nitrogen molecules is the same as the average speed of the oxygen molecules. 0035 9 D. the average kinetic energy of all the molecules in this mixture is the same as that of any other gas at the same temperatures. E. the average kinetic energy of all the molecules in this mixture is the same as that of any other gas at the same pressure. 1922866 C 15 18360 31 144501131388 Which one of these is not a characteristic of a gas molecule in motion? A. Very high velocities. B. A vast number of collisions per second. C. A speed directly proportional to the mass of the molecule. D. motion in straight lines between collisions. 9 E. Erratic motion as exemplified in the brownian movement. 0035 1922867 E 15 18365 32 042902930128 The mean velocity of an oxygen molecule at 0 degrees C is 460 meters/sec. If the molecular weight of helium is 4, then the mean speed of a helium atom (molecule) at 0 degrees C is A. 230 m/sec. B. 326 m/sec. C. 650 m/sec. 9 D. 920 m/sec. E. 1300 m/sec. 0035 1922868 B 15 18369 31 030913860511 Which one of the following is NOT an assumption of the kinetic theory of gases? A. Gas particles are negligibly small. B. Gas particles undergo a decrease in kinetic energy when passed from a region of high pressure to a region of lower pressure. C. Gas particles are in constant motion. D. Gas particles exert NO attraction for each other. 9 E. Gas particles undergo elastic collisions. 0035 1922869 D 15 18375 52 164814090491 SO effuses through a small hole (under prescribed conditions of 4 2 temperature and pressure) at the rate of 4 ml/min. The rate (in ml/min.) at which helium effuses through the same hole under the same conditions is: A. 2 B. 1 C. 64 D. 16 E. none of these 9 Atomic weights: S = 32, O = 16, He = 4 0035 1922870 D 15 18380 52 016101140258 At any given temperature and pressure the relative diffusion rates of CH and CS are (h = 1, C = 12, O = 16, S = 32) 0035 4 4 2 9 A. 1 to 2 B. 2 to 5 C. 4 to 1. D. 2 to 1 E. 1 to 4 1922871 D 15 18383 32 011305370429 A given amount of gas in a closed container is heated from room temperature to 100 degrees F; disregarding the possible expansion of the container, according to the kinetic theory A. the gas has increased in weight. B. the individual molecules of the gas have expanded. C. the average distance between molecules has increased. D. the average velocity of the molecules has increased. 9 E. the pressure on the sides of the container has decreased. 0035 1922872 A 15 18389 32 019501140113 At constant volume the pressure of gas Y increases with increasing temperature because as the temperature increases A. molecules of Y move faster. B. the molecular volume of Y increases. C. the mass of Y molecules increases. D. molecular collisions are more elastic. 9 E. molecules are closer together. 0035 1922873 E 15 18394 31 059413860189 Which of the following is not a basic postulate of the kinetic 3 ___ molecular theory A. The molecules of a gas are in a state of perpetual random motion B. Gases consist of discrete particles of matter called molecules C. The temperature of a gas is a measure of average kinetic energy of the molecules D. The collisions between molecules of a gas are perfectly elastic 9 E. Most gaseous elements consist of diatomic molecules 0034 1922874 D 15 18401 51 029013860113 Which of the following is explained by the kinetic_molecular theory of gases? A. The combustibility of gases B. The color of gases C. The chemical activity of gases D. The high compressibility of gases 9 E. The molecular weights of gases 0038 1922875 A 14 18405 52 01130258 0038 Which will require the longer time for one liter of the gas to diffuse through a small opening? (Chlorine: GMW = 71; ammonia: GMW = 17) A. Chlorine, because of its greater density B. Chlorine, because its molecule Cl has fewer atoms than 4 2 ammonia, NH 4 3 9 D. there should be no difference 1922876 D 14 18410 72 1974 At the same temperature, the molecules of which gas have the highest average velocity? A. O B. CCl C. CO D. C H E. C H 94 2 4 2 24 26 1922877 A 14 18413 72 0708 An equimolar mixture of CH and CO is allowed to effuse through a 4 4 2 small hole into a vacuum. At a later time the gas remaining will contain A. more CO than CH . C. an equimolar mixture of CH and CO . 4 2 4 4 2 B. more CH than CO . D. pure CH . 94 4 2 4 1922878 C 14 18419 72 197519769033 The figure below illustrates the distribution of molecular velocities as predicted by the Maxwell distribution law. | | fraction | of | molecules | that have | T(1) = 1000 K a | 1 velocity | 11 =c | 1 122 | 1 221 2 T(2) = 2000 K | 12 1 2 | 1 2 1 22 | 12 1 2 | 12 1 22 | 12 1 22 | 12 1 22 |12 11 22 | 122 11 2222 |12 1111 _____________________________________________ c(velocity) The abscissa value corresponding to the peak of each curve represents A. the mean velocity of the molecules. B. the temperatures at which molecules have greatest velocities. C. the velocity possessed by more molecules than any other velocity. 9 D. the root mean square velocity. 1922879 C 14 18433 72 1885 In the design (or construction) of a vacuum system, large diameter tubing is essential for the main manifold. The property of gas molecules being considered in this instance is A. collision diameter. B. root mean square velocity. C. mean free path. 9 D. average molecular weight. 1922880 C 14 18437 72 Methane, CH , has a higher thermal conductivity than O , Ar, CO 4 4 2 2 or Cl under the same conditions of temperature and pressure because of 4 2 its low molecular weight and consequent A. lower vibrational energy. B. lower heat capacity. C. higher molecular velocity. 9 D. smaller molecular diameter. 1922881 B 14 18442 52 04290708138605 5 4 If the velocity of an oxygen molecule is 4.24 x 10 cm/sec 5 o at 0 C, what is the average velocity of CO molecules at 4 2 the same temperature_pressure conditions (in cm/sec). 5 4 4 4 4 9 A. 3.10 x 10 B. 3.62 x 10 C. 4.66 x 10 D. 5.81 x 10 1922882 D 15 18448 51 19660708 Graham's Law states the relationship between the _______ of a gas and its diffusion rate at a constant temperature. A. volume C. number of molecules CWHS NGLS 9 B. pressure D. molecular mass 1922883 B 15 45343 71 What is the ratio of the average kinetic energy of O to that of 4 2 CH at 298 K? 4 4 5 1/2 1/2 1/2 1/2 9 A. 2:1 B. 1:1 C. 1:2 D. (32) :(16) E. (16) :(32) 1922901 D 14 18451 31 070601130293 The fact that the ideal gas law only approximately describes the behavior of a gas can be partly explained by the idea that A. R is not really a constant B. gas molecules really do have zero volume C. the kinetic energy of gas molecules is not really directly proportional to the absolute temperature 9 D. gas molecules really do interact with each other 0009 1922902 A 14 18456 31 140407060161 Real gases behave most nearly like the ideal gas law says they do at A. high temperatures, low pressures B. low temperatures, high pressures C. high temperatures, high pressures 9 D. low temperatures, low pressures 0009 1922903 B 15 45073 51 143214310706 5 2 The van der Waals equation, P = RT/(V_b) _ a/V , incorporates the following correction(s) to the ideal gas law in order to account for the properties of real gases: A. the possibility of chemical reaction between molecules B. the finite volume of molecules C. the quantum behavior of molecules D. average kinetic energy is inversely proportional to temperature 9 E. the infrared absorption spectra of gases 0009 1922904 B 15 18466 31 140407060114 Real gases approach perfect gas behavior at A. low pressures and temperatures B. low pressures and high temperatures C. high pressures and low temperatures D. high pressures and high temperatures 9 E. temperatures just above the boiling points of their liquids 0019 1922905 B 14 18470 31 08020114 Boyle's law if least likely to be obeyed at A. high temperatures B. high pressures C. in small samples 9 D. none of the above is correct 0019 1922906 E 15 18473 32 14260706 Which of the following would be most likely to behave as an ideal gas? A. HCl B. SO C. H O (vapor) D. NH E. O 94 2 2 3 2 0019 1922907 E 15 18476 52 14291430 The critical temperature of nitrogen is _147 degrees C and that of oxygen is _119 degrees C. At _100 degrees C ________ can be liquefied. 9 A. nitrogen B. oxygen C. both D. all gases E. neither 0019 1922908 A 15 18479 51 143103091386 Certain corrections are made on the assumptions of the kinetic molecular theory to explain the deviations of the real gases from ideal behavior. These corrections are: A. pressure and volume corrections only B. pressure, volume and temperature corrections C. pressure corrections only 9 D. volume and temperature corrections only 0019 1922909 B 15 18484 51 143213361427 The term a in the van der waals equation is: A. a measure of the diameters of the molecules of the gas B. a measure of intermolecular attractions between molecules C. a measure of density of the gas D. a measure of velocities of molecules of the gas 9 E. none of the above is correct 0019 1922910 A 5 0035 15 18488 52 143205400195 2 na Van Der Waal's equation states (P + ____)(V_nb) = nRT. Using 5 2 V this information, indicate what the term nb represents. A. The volume occupied by the gas molecules. B. The mean velocity of the gas molecules. C. The attractive force between molecules. 9 D. The universal gas constant. E. None of these. 1922911 A 14 18495 31 1430 The liquefaction temperature of a gas increases as the pressure is increased because at higher pressures: A. the average speed of the molecules is higher B. the average speed of the molecules is lower C. the average intermolecular distance is higher 9 D. the average intermolecular distance is lower 0003 1922912 C 14 18500 72 1432 The constant b in the van der Waals' equation is proportional to A. the radius of one molecule. B. the force of attraction between two molecules. C. the excluded volume per mole. 9 D. the temperature. 1922913 DA 25 18503 52 MACROITEM STEM Draw a smooth curve through the points in the diagram below: |. | . | . | . | . | . |. 0 |__________________ MACRO SUB_ITEM # 1 This diagram describes phenomena associated with A. reaction kinetics D. the critical point B. acid_base equilibria E. Raoult's Law 1 C. solubility MACRO SUB_ITEM # 2 The correct labels for the axes of this diagram are x y A. temperature density B. volume density C. temperature pressure D. pressure mole fraction 9 E. density pressure 1922914 A 15 45347 71 In the van der Waals equation of state for 1 mol of gas, OS82 5 a (P + __ )(V _ b) = RT 4 2 4 V the effect of intermolecular forces is accounted for by: 5 2 2 9 A. P + a/V B. P C. V _ b D. b E. (P + a/V )(V _ b) 1923001 B 14 18513 31 04110192 According to the chemical definition of a pure substance, which of the following could be a pure substance? 9 A. milk B. quartz C. chalk D. air 0026 1924001 C 15 18516 31 01530008800111 The rate of evaporation of water into the air of a room may be decreased by A. increasing the temperature B. placing the water in a pan of larger diameter C. increasing the humidity of the room D. decreasing the pressure over the water surface 9 E. increasing the molecular motion of the water ETS2 OS 1924002 E 15 18521 31 05010502800111 The best explanation for the nearly spherical shape of raindrops is based on A. evaporation B. gravity C. capillary action D. the brownian movement 9 E. surface tension ETS2 OS 1924003 C 15 18524 51 04120397800111 If a saturated vapor is compressed at constant temperature, A. the pressure rises B. the vapor density increases C. the vapor begins to condense D. the pressure falls 9 E. the system obeys boyle"s law ETS2 OS 1924004 E 15 18527 31 04470444800111 The hydraulic press A. does more work than is done upon it B. must make use of water as the liquid C. gives better results when the atmospheric pressure is high D. shows an application of Charles' law ETS2 OS 9 E. shows an application of Pascal's principle 1924005 C 15 18531 52 04910153800111 The rate of evaporation of water may be increased by all of these steps except A. increasing the temperature B. placing the water in a pan of larger diameter C. increasing the humidity of the room D. decreasing the pressure over the water surface 9 E. increasing the molecular motion of the water ETS2 OS 1924006 D 14 18536 51 01140130800111 The pressure of a given saturated vapor depends on A. the volume of the space to be filled B. the amount of liquid to be vaporized C. the density of the liquid only 9 D. the temperature only ETS2 OS 1924007 D 15 18539 31 05350493800112 An alcohol rub cools the skin. This cooling effect A. is an illusion arising from the effect of wetness B. occurs because the skin is too dry C. occurs because the alcohol is at a lower temperature D. is the result of rapid evaporation of the alcohol 9 E. is the same for any liquid ETS2 OS 1924008 C 15 18543 51 04120161800113 A pure liquid and its vapor, maintained at a constant temperature, are contained in a tall cylinder fitted with a piston which exerts a pressure just equal to the vapor pressure of the liquid. If the pressure on the piston is doubled, the piston will A. drop until the volume of the vapor is half its original volume B. not change its position C. drop until it touches the surface of the liquid, condensing all the vapor D. drop until the volume of the vapor and the volume of the liquid are each one_half of their original volumes 9 E. none of the above ETS2 OS 1924009 A 15 18551 52 01530505800111 Evaporation from a liquid results in A. a decrease in the average speed of the molecules of the liquid B. an increase in the temperature of the liquid C. an increase in the rate of collision between molecules of the liquid D. an increase in the average speed of the molecules of the ETS2 OS 9 liquid E. a decrease in the amount of vapor above the liquid 1924011 A 14 18556 31 04380433800111 Two liquids, a and b, are introduced into two barometer tubes, the temperature of each being the same. It is noticed (1) that in both cases a little of the liquid does not evaporate, and (2) that the mercury in the tube containing a is more depressed than that in the tube containing b. it follows from this that the vapor pressure of liquid a A. is greater than that of liquid b B. is less than that of liquid b C. the same as that of liquid b D. cannot be estimated relative to that of liquid b 9 from the information given above ETS2 OS 1924012 B 15 18564 31 04120293800112 The vapor collecting in the space above a liquid in a container is considered to saturate the space when A. the density of the vapor equals the density of the liquid B. molecules leave and enter the liquid at equal rates C. no more molecules leave the liquid D. the liquid boils 9 E. the vapor density is equal to 1 ETS2 OS 1924013 C 15 18569 31 04950483800112 The apparently aimless, continuous movement of very small particles which is known as the "Brownian movement" is caused by A. the influence of the earth's magnetic field B. the pull or attraction of the electron shell of the substance C. collision or jostling about by molecules D. the influence of an electric field E. repulsion between protons of the particles and the 9 electrons of the surrounding media ETS2 OS 1924014 C 15 18575 52 04930008800112 Water will keep cool in an unglazed earthenware jug because A. the jug absorbs cold air B. water vapor from the atmosphere condenses on the jug C. there is a large surface from which the water can evaporate D. the jug cools the water 9 E. earthenware material is always cool ETS2 OS 1924015 B 14 18579 31 015904380499 As a pure liquid is heated, its temperature increases and it becomes less dense. Therefore, A. its potential energy increases B. its kinetic energy increases C. both its potential energy and kinetic energy increase 9 D. it necessarily undergoes a chemical change. 0026 1924016 B 14 18583 31 047110970161 To convert a sample of air into a liquid, you would probably have to A. increase the temperature and pressure of the sample B. decrease the temperature and increase the pressure of the sample C. cool it to 0 degrees K 9 D. the task is an impossible one 0009 1924017 A 14 18587 52 019211491403 Which substance should have the highest vapor pressure at any given temperature? A. C H B. C H C. C H D. C H E. C H 94 26 38 4 10 5 12 66 0009 1924018 C 15 18590 52 051104230286 As a pure liquid is heated, its temperature increases and it becomes less dense. Therefore: A. its potential energy increases B. its kinetic energy increases C. both its potential and kinetic energy increase D. its potential energy increases while kinetic energy decreases 9 E. its potential energy remains constant. 0040 1924019 B 14 18595 31 04380652 Liquids have A. stronger intermolecular forces than solids B. more random molecular motion than solids C. more molecular order than solids D. very long range molecular attractive forces 9 E. symmetry 1924020 B 14 18598 31 13590438 Ordering of molecules in a liquid phase is A. greater than in the solid phase of the same substance B. short range and limited C. nonexistent 9 D. high in some liquids and random in others 1924021 B 14 18601 31 0438 The molecules in a liquid are A. in constant random motion, unconfined by any molecular order or attraction. B. in constant random motion, but are attracted to neighboring molecules. C. are held in a rigid spatial array, and only vibrate within that array. 9 D. motionless. 1924022 C 14 18606 51 14270438 Intermolecular forces in liquids are A. the greatest of any phase because of the fluidity of liquids B. the least of any phase because the molecules in a liquid are always in constant random motion C. intermediate between those of gases and solids 9 D. equal to zero 1924023 D 14 18610 51 07610438 The molecular theory for gases was at one time thought to apply to liquids. Which of the following assumptions about gases is least applicable to liquids? A. the phase is fluid. B. molecules in the phase exhibit random motion. C. molecules in the phase have a large distribution of energies. D. molecules in the phase have negligible attraction for 9 one another. 1924024 B 14 18616 51 04380524 What property of a liquid explains the fact that a liquid may be used to measure air pressure as in a barometer? A. random molecular motion C. intermolecular attraction 9 B. low compressibility D. portions of the phase are ordered 1924025 C 14 18620 51 04380067 What property of a liquid explains the fact that liquids have a vapor pressure associated with them? A. low compressibility B. fluidity of the phase C. some molecules have energies high enough to overcome molecular attractions 9 D. the phase conforms to the shape of its container 1924026 D 14 18625 31 05020438 The phenomenon of surface tension in a liquid is caused by A. the regions of short range molecular order which are found in liquids B. the high kinetic energy of some molecules in the liquid C. the small compressibility of liquids D. the imbalance of attractive forces on molecules at the 9 surface 1924027 D 14 18630 51 0502 Surface tension accounts for which of the following observations? A. Liquids can be used in hydraulic brakes. B. A drop of ink diffuses slowly through water. C. Water has a definite vapor pressure at 25 deg C. D. The top of a column of liquid mercury is rounded 9 instead of flat. 1924028 C 14 18635 51 15460555 The horizontal plateau on the cooling curve of a liquid represents A. the cooling of the liquid to its freezing point. B. a period of time when no heat is gained or lost from the substance. C. the freezing of the liquid at constant temperature. 9 D. the warming of the solid to its melting point. 1924029 D 15 18640 51 Draw a smooth curve through the points in the diagram below: | . | | | . | | | . |. |__________________ This curve could possibly describe which of the following phenomena? A. The behavior of an ideal gas at constant temperature. B. The behavior of an ideal gas at constant pressure. C. The reactant concentration (y_axis) for a first_order reaction with respect to time. OS82 9 D. The vapor pressure (y_axis) of a liquid with respect to temperature. E. The function (PV)/(nRT) for an ideal gas (y_axis) with respect to pressure. 1924030 E 15 18649 51 11490438 The vapor pressure of a liquid depends on A. only the temperature of the liquid. B. only the volume of the liquid. C. only the intermolecular forces in the liquid. D. both the temperature and the volume of the liquid. E. both the temperature and the intermolecular forces of 9 the liquid. 1924031 B 14 18654 51 05110438 When a liquid in an insulated vessel vaporizes A. the average kinetic energy of molecules in the liquid phase increases B. the average kinetic energy of molecules in the liquid phase decreases C. the intermolecular forces are increased in the liquid 9 D. the surface tension of the liquid is decreased 1924032 B 14 18659 51 05110438 When a liquid evaporates from an insulated container, the average kinetic energy of molecules remaining in the liquid phase A. increases until it equals the kinetic energy of the molecules in the vapor B. decreases steadily C. decreases until it equals the kinetic energy of the molecules in the vapor 9 D. remains the same 1924201 D 14 18664 31 00080130 Pure water is not 9 A. polar B. a good solvent C. a compound D. saturated 1924202 A 15 18666 52 024511490161 A sealed container partly filled with water is allowed to come to equilibrium. The vapor pressure in the space above the water depends upon which of the following? A. The value listed in The vapor pressure tables as a function of temperature. B. The nature of the interior wall of the vapor space. C. The volume of water. D. The nature of the other gases in the vapor space. 0041 0044 9 E. None of the above. 1924203 D 15 18672 31 025804380652 Diffusion in liquids is explained by A. surface tension B. capillary attraction C. vibrations of atoms D. molecular motion 9 E. all of these 0020 1924204 A 15 18675 31 000811480336 Water rises in a capillary tube because A. water wets the glass B. water has a low vapor pressure C. water has a high boiling point D. glass is an extremely pure substance 9 E. none of these 0020 1924205 A 15 18678 31 043801530293 A liquid evaporates A. because of the motion of the molecules B. when a vessel containing the liquid is exposed to the atmosphere C. when molecules escape from the surface of the liquid D. all of these 9 E. none of these 0020 1924206 E 15 18682 31 11490161 The vapor pressure of water A. is constant at a given temperature B. increases with temperature C. decreases with temperature D. is due to the pressure of water molecules in the gas phase 9 E. all of these 0020 1924207 B 15 18685 51 019211490165 Which of the following substances has the lowest vapor pressure? A. water at 25 degrees C B. ice at 0 degrees C C. ether at room temperature D. water at 100 degrees C 9 E. chloroform at room temperature 0020 1924208 D 15 18688 52 114904380161 The vapor pressure of a given liquid is constant at a given temperature and does not depend on the size or shape of the 0020 container A. as long as some liquid is present B. because a dynamic equilibrium is established C. because pressure is a per_unit_area phenomenon D. all of the above 9 E. none of the above 1924209 B 15 18693 31 114904380498 When the vapor pressure of a liquid equals the atmospheric pressure A. no more liquid remains B. the liquid boils C. sublimation occurs D. condensation occurs 9 E. none of these 0020 1924210 C 15 18696 32 083911500114 Foods can be cooked faster by A. using less water in the pan B. adding heat more rapidly C. increasing the pressure above the food D. decreasing the pressure above the food 9 E. none of these 0020 1924211 C 14 18699 31 049804381149 The boiling point of any liquid is: A. 100 degrees C B. the temperature at which as many molecules leave the liquid as return to it C. the temperature at which the vapor pressure is equal to the external pressure D. the temperature at which NO molecules can return to the bulk 9 of the liquid 0009 1924212 D 14 18704 31 049001610114 The triple point is A. the temperature above which the liquid phase cannot exist B. usually found at a temperature very close to the normal boiling point C. the temperature at which the vapor pressure of a liquid is three times the value at 25 degrees C D. the value of temperature and pressure at which solid, liquid 9 and gas may exist in equilibrium 0009 1924213 B 15 18710 31 049804381149 The boiling temperature of a liquid is 0019 9 A. the temperature at which the molecules leaving the liquid is the same as the rate of molecules returning B. the temperature at which the vapor pressure is equal to the atmospheric pressure C. 100 degrees C D. the temperature at which the vapor pressure is greater than atmospheric pressure E. the temperature at which NO molecules of the liquid can return to the body of the liquid 1924214 E 15 18717 52 141414370087 Which of the following statements is true of Henry's law? A. valid for dilute solutions B. valid for solvent C. is expressed by P = kx D. A, B and C are true 9 E. A and C are true 0019 1924215 C 15 18720 31 008702041307 Which of the following is characteristic of solutions? A. heterogeneous B. constant composition C. variable composition D. both A and B 9 E. both A and C 0040 1924216 D 15 18723 31 159314020662 Which of the following could best be called a physical property of some substance? A. color B. flammability C. density D. both A and C 9 E. both B and C. 0040 1924217 C 15 18726 31 049815930161 The boiling point of a liquid is best described as a particular A. vapor pressure B. vapor pressure at a specific temperature C. temperature D. vapor pressure at a specific altitude 9 E. both A and D. 0040 1924218 A 15 18729 31 114901611593 The vapor pressure of a liquid depends upon A. the temperature of the liquid B. the volume of the liquid C. the container of the liquid D. the boiling point of the liquid 0040 9 E. the altitude of the liquid. 1924219 D 15 18732 51 114915930317 The magnitude of the vapor pressure of a liquid at constant temperature depends on A. the size of the container B. the atmospheric pressure C. the boiling point of the liquid D. the nature of the forces between liquid molecules 9 E. the surface area of the liquid 0040 1924220 C 15 18736 31 049815930161 The normal boiling point of any liquid is defined as A. the temperature at which the liquid boils B. 100 degrees C C. the temperature at which the vapor pressure equals one atmosphere of pressure D. the temperature at which there is equilibrium 9 E. both B and C. 0040 1924221 C 15 18740 31 043815930786 Which of the following is a liquid at room temperature? A. I B. Cl C. Br D. S 4 2 2 2 9 E. both B and C. 0040 1924222 C 14 18742 51 006716191416 The property of water that is most critical to the regulation of body temperature is A. high specific heat B. high boiling point 9 C. high heat of vaporization D. high surface tension 0009 1924223 C 15 18745 51 142901920438 The critical temperature of a substance is A. the temperature required to liquefy the gas at one atmosphere pressure. B. the temperature at which the substance begins to decompose. C. the highest temperature at which the substance can be a liquid. D. the temperature at which the liquid evaporates. E. the lowest temperature at which the substance may be 9 liquefied. 0035 1924224 C 15 18751 31 051614300237 Van Der Waals' forces A. cause the high melting point of most salts 0035 9 B. hold together the atoms in a diamond crystal. C. are responsible for the liquifaction of covalent compounds. D. disappear when gases are liquified. E. promote the supercooling of liquids. 1924225 B 15 18755 32 043802860160 When a liquid is heated in an open vessel, its temperature rises until A. it is completely vaporized. B. its vapor pressure equals atmospheric pressure. C. the latent heat is all absorbed. D. the kindling temperature is reached. 9 E. the air is saturated with vapor. 0035 1924226 B 14 18759 32 011408100171 When atmospheric pressure in the laboratory is 752 torr, distilled water in an open vessel will boil: A. at 100 degrees C B. at less than 100 degrees C C. at more than 100 degrees C 9 D. when its vapor pressure reaches 760 mm. 0038 1924227 A 14 18763 52 195401770498 When liquid air evaporates, the order of increasing boiling point 3 __________ (order of evaporation) for O , N , and Ar is: 4 2 2 A. N , Ar, O B. Ar, N , O C. O , N , Ar D. Ar, O , N 94 2 2 2 2 2 2 2 2 0061 1924228 D 14 18768 72 1890 The force opposing the motion of a spherical particle of radius r moving at a speed of v through a viscous medium with a coefficient f viscosity (eta) is approximately f=6 (pi)(eta)rv. This is called A. Graham's Law of Effusion. B. Fick's First Law of Diffusion. C. The barometric formula. D. Stokes' Law. 9 E. Boyle's Law. 1924229 A 14 18773 31 00080186 At about 4 degrees centigrade, water has its maximum A. density B. vapor pressure C. specific heat 2 OS 9 D. volume 1926001 B 15 18775 31 05070169800111 The expansion of a solid on heating is due to A. an increase in the size of the particles of the solid B. an increase in the agitation of the particles of the solid C. the addition of caloric to the solid D. application of the kinetic_molecular theory 9 E. none of the above ETS2 OS 1926002 D 15 18779 31 01900128800111 A hydrate A. is a moist compound B. is a liquified element C. is usually an organic compound D. loses mass if heated sufficiently 9 E. is produced when an hydroxide and an acid react ETS2 OS 1926003 B 14 18782 31 04810416800114 The center of gravity of any mass seeks the lowest point. The potential energy of any system tends toward a minimum. These statements are A. equivalent B. closely related, but not equivalent C. both correct, but unrelated 9 D. mutually contradictory ETS2 OS 1926004 D 15 18786 31 8001 13 The diagram represents a rectangular annealed brass plate in which there is cut a rectangular hole, of dimensions (at 0 degrees C.) as indicated. If now the temperature of the plate is raised to 150 degrees C, I_______________________________________I I I I I I I I I___________________I I I I bI I I I a I I I I___________________I I I I I I I I i_______________________________________i A. a will increase, while b decreases. B. Both a and b will decrease. ETS2WVW C. b will increase while a decreases D. both a and b will increase. E. The new dimensions of the hole will depend upon the original outside dimensions of the plate itself. 93 _____ ______ 1926005 C 15 18802 51 05880244800111 Concerning matter in the crystalline state A. a high electrical conductivity is evidence of an electrovalent compound B. the density is always higher than that of the same substance in the liquid state C. low melting point is usually characteristic of molecular crystal D. all elements fall in the category of atomic crystals with covalent bindings 9 E. the vapor pressure is equal to 760 torr. At the melting point ETS2 OS 1926006 C 15 18809 51 01140407800111 Changes in pressure have only a slight effect on reactions between solids. The best explanation of this is that A. molecules of solids move very slowly B. solids are not appreciably reactive C. solids are not appreciably compressible D. in solids molecular freedom is limited 9 E. none of the above is a satisfactory explanation ETS2 OS 1926007 E 15 18814 72 071507168003 Zinc metal crystallizes with a unit cell very close to a hexagonal close packed array of hard spheres. Predict the density in g/cc if the distance between the centers of the neighboring zinc atoms is 0.266 nanometers. (At. Wt Zn=65.4; number of zinc atoms effectively located inside the hexagonal close packed unit cell=6; volume of hexagonal close 5 3 packed unit cell containing atoms of radius r equals 34.0 (r ) 9 A. 1.0 B. 1.6 C. 4.2 D. 5.0 E. 8.2 2WVW 1926008 B 15 18823 72 071907188003 A variety of stoichiometric compounds, known as interstitial 3 ____________ compounds, can be produced by atoms of nonmetals such as hydrogen, 3_________ boron, carbon, and nitrogen occupying some or all of the vacant holes in the close packed structures of certain metals. Zirconium metal (Zr, Z=40) forms interstitial compounds, particularly with 2WVW nitrogen. If zirconium metal adopts a face_centered cubic close packed structure, what is the simplest stoichiometric formula of the interstitial compound formed with nitrogen, if the nitrogen atoms two thirds of the available tetrahedral holes? A. ZrN B. Zr N C. ZrN D. Zr N E. Zr N 94 34 2 32 43 1926009 E 15 18833 51 1 071607289020 95 The crystal structure of fluorite, CaF , is shown in the Figure 20. 4 2 if sodium monoxide, Na O, adopts an antifluorite structure, which 4 2 3 ____________ of the following sets of coordination numbers for the Na(+1) and O(_2) ions in sodium monoxide is correct? 3 _______ Na(+1) O(_2) 3 ______ _____ A. 3 6 B. 4 4 C. 8 4 D. 6 6 9 E. 4 8 2WVW 1926010 C 15 18841 52 071607178003 Strontium metal exists in three different crystalline forms known as alpha, beta, and gamma strontium. The alpha form, which exists at 25 deg. C., has a face centered cubic unit cell with an edge of 4.2 Angstrom. What is the density of alpha_strontium? (At.Wt. Sr=88) 5 _3 A. 0.42 g cm 5 _3 B. 2.0 g cm 5 _3 C. 8.0 g cm 5 _3 D. 28 g cm 5 _3 9 E. 88 g cm 2WVW 1926011 D 15 18847 51 8003 In the band theory for solids, a large band gap implies the material is A. a conductor B. an intrinsic semiconductor C. an impurity semiconductor 2WVW 9 D. an insulator E. both answers B and C 1926012 E 15 18850 51 8003 A one_fold rotation axis means that we should rotate ______ degrees to obtain a view similar to the original view. A. 60 B. 90 C. 120 D. 180 9 E. 360 2WVW 1926013 D 15 18853 51 8003 A two_fold rotation axis means that we should rotate ______ degrees to obtain a view similar to the original view. 9 A. 60 B. 90 C. 120 D. 180 E. 360 2WVW 1926014 C 15 18856 51 8003 A three_fold rotation axis means that we should rotate _____ degrees to obtain a view similar to the original view. A. 60 B. 90 C. 120 D. 180 9 E. 630 2WVW 1926015 B 15 18859 51 8003 A four_fold rotation axis means that we should rotate ______ degrees to obtain a view similar to the original view. A. 60 B. 90 C. 120 D. 180 9 E. 360 2WVW 1926016 A 15 18862 51 8003 A six_fold rotation axis means that we should rotate ______ degrees to obtain a view similar to the original view. A. 60 B. 90 C. 120 D. 180 9 E. 360 2WVW 1926017 E 15 18865 51 8003 A center of symmetry means that if we rotate _____ degrees and 2WVW reflect through the mirror plane perpendicular to the rotation we obtain a view similar to the original view. A. 30 B. 45 C. 60 D. 90 9 E. 180 1926018 D 15 18868 51 8003 A four_fold inversion axis means that if we rotate _____ degrees and reflect through the mirror plane perpendicular to the rotation axis, we obtain a view similar to the original view. A. 30 B. 45 C. 60 D. 90 9 E. 120 2WVW 1926019 E 15 18872 51 8003 A three_fold inversion axis means that if we rotate ______ degrees and reflect through the mirror plane perpendicular to the rotation axis, we obtain a view similar to the original view. A. 30 B. 45 C. 60 D. 90 9 E. 120 1926020 C 15 18876 51 8003 A six_fold inversion axis means that if we rotate ______ degrees and reflect through the mirror plane perpendicular to the rotation axis, we obtain a view similar to the original view. A. 30 B. 45 C. 60 D. 90 9 E. 120 2WVW 1926021 B 15 18880 51 8003 Electron diffraction experiments can provide all necessary information regarding the symmetry, bond ______, and bond ______ of a molecule. A. Orders _ lengths B. lengths _ angles C. strengths _ angles D. distances _ strengths 9 E. displacements _ geometry 2WVW 2WVW 1926022 C 14 18884 31 050405888002 The state of matter characterized by both a definite shape and a definite volume is A. fluid B. liquid C. solid 9 D. gas 1926024 D 14 18886 31 15931932 05 Isomorphism is defined as a condition in which A. one compound has two different amorphous structures B. one compound has two different crystalline structures C. two different compounds have the same amorphous structure D. two different compounds have the same crystalline 9 structure 1926025 B 14 18891 31 15931933 05 Polymorphism is defined as a condition in which A. one compound has more than one amorphous structure B. one compound has more than one crystalline structure C. two different compounds have the same amorphous structure D. two different compounds have the same crystalline 9 structure 1926026 B 14 18896 51 0715 0524 The unit cell is defined as the smallest portion of a crystal which A. contains one formula unit of the compound B. is repeated throughout the crystal C. shows the coordination number of one ion 9 D. contains a complete molecule 1926027 B 14 44521 51 0715 0524 The unit cell is defined as that portion of a crystal lattice which A. contains one formula unit of the compound B. is the smallest repetitive unit with the full symmetry of the lattice C. shows the maximum coordination number for every ion D. contains at least one of every kind of atom in the formula unit 5 3 9 E. one cm of the substance 2 OS 1926028 C 14 18905 52 1949 Orthorhombic S and monoclinic S are: 9 A. isomeric B. homologous C. allotropic 0060 D. allelomorphic 1926029 C 14 18907 52 0172 Heat is supplied at a constant rate to a solid sample initially at 0 degrees C. The temperature of the system after ten minutes is 25 deg C. After 12 minutes the temperature is 30 deg C and ceases to rise with further heat input. After fifteen minutes, the temperature begins to rise again and reaches 55 at twenty minutes. What is the melting point of the initial solid? ( in deg C) 9 A. 0 B. 25 C. 30 D. 55 1926030 C 15 18913 52 044511530286 A block of ice requires 33,356 J of heat to melt it at its melting point. What is the weight of the ice? (/\H for water = 333.2 J/g) 4 __ f 9 A. 10 g B. 18 g C. 100 g D. 148 g E. 36 g 1926031 D 14 18916 52 04451151 A piece of ice required 159.6 calories of heat to melt it at its melting point. How much does the ice weigh? 9 A. 18 g B. 15.9 g C. 5.0 g D. 2.0 g 1926201 D 14 18919 31 017201691698 The lowest melting points are usually found in solids held together by A. covalent bonds C. metallic bonds E. polar bonds 9 C. ionic bonds D. Van Der Waals bonds 1926202 C 14 18922 31 085205890067 Graphite and diamond are different in physical properties because A. they are composed of different elements B. diamond is pure carbon while graphite contains traces of other substances C. their crystal structures are different 9 D. their atomic weights are different 1926203 A 14 18926 52 01691178 The following solid consists of ions: A. CaB O B. BI C. B H D. BF 94 24 3 26 3 1926204 C 15 18928 52 016914180172 Solids can be divided into four categories: 0041 0041 0043 0044 molecular, such as SO (solid), H O (ice, iodine, CCl (solid); 4 2 2 4 network, or covalent; such as diamond (carbon), silicon, silicon carbide; metallic, such as copper, iron, sodium; ionic, such as table salt (NaCl), potassium iodide(KI), calcium carbonate(CaCO ). 4 3 Which of the following statements about the properties, structures, etc., of these different categories of solids is incorrect? 3_________ A. The bonding between atoms in a metal is ascribed to the sharing of an electron 'sea" by a positive ion lattice. B. The bonding between carbon atoms in diamond is similar to that between carbon atoms in the ethane molecule. C. Silicon carbide, like most covalent solids, has a low melting point. D. Molecular crystals are usually soft whereas metals range from soft to hard. E. Solid benzene, like most molecular solids, has a low melting 9 point. 1926205 B 15 18942 31 078701690170 The process in which a solid goes directly to a gas is called A. effusion B. sublimation C. fusion D. melting 9 E. condensation 0020 1926206 A 15 18944 31 115100080439 The heat of fusion for water is A. 80 cal/g B. 540 cal/g C. the same as the heat of vaporization D. the same as the heat of liquefaction 9 E. none of these 0020 1926207 A 15 18947 51 023701690355 Covalent solids A. are very hard B. are very soft C. are good conductors of electricity D. have molecules as structural units 9 E. have very low melting points 0020 1926208 E 15 18950 32 000502441159 Which of the following forms an ionic crystal? 9 A. Fe B. SiO C. N D. CO E. AgBr 0020 1926209 B 15 18952 32 006202441160 Metallic crystals conduct an electric current because of A. the covalent bonding B. the sea of electrons C. the high boiling points D. the ionic attraction between atoms 9 E. tne movement of ions 0020 1926210 E 15 18955 52 001602071415 The specific heat of aluminum (atomic mass = 27.0) is expected by the law of Dulong and Petit to be about A. 27.0 cal/gram deg B. 0.29 cal/gram deg C. 3.1 cal/gram deg D. 6.4 cal/gram deg 9 E. none of the above is correct 0019 1926211 C 14 18959 31 055501701417 A wet towel hung out at _5 degrees C freezes solid but then becomes soft and dry. This is an example of 9 A. fusion B. liquefaction C. sublimation D. disintegration 0019 1926212 E 15 18962 31 159301860172 Which of the following is not a physical property of matter 3 ______ A. melting point B. density C. color D. odor 9 E. all are physical properties 0040 1926213 B 14 18965 51 161104980114 A chemistry handbook normally gives the pressure at which the boiling point of a pure substance is measured but generally does not indicate the pressure for the melting point. Why? A. both melting point and boiling point are always measured at the same pressure B. the melting point is usually nearly independent of pressure C. solids are more often impure and therefore have variable melting points 9 D. all melting points are measured at one atmosphere 0009 1926214 A 14 18972 31 0169 One would expect a low molar heat of fusion for: A. a molecular solid B. a covalent solid 0003 9 C. an ionic solid D. a metallic solid 1926215 B 14 18974 51 1701 05 A substance which melts over a wide temperature range is A. Crystalline C. cubic closest_packed 9 B. amorphous D. hexagonal closest_packed 1926216 A 14 18977 51 17010336 05 Window glass is an example of which kind of solid? A. amorphous C. hexagonal closest_packed 9 B. crystalline D. face_centered cubic closest_packed 1926217 B 14 18980 52 19441952 The gram atomic weight of potassium is 39.1 grams. The density of 5 _3 potassium is 0.861 g cm . the gram atomic volume of potassium is then calculated as follows: 5 _3 A. (39.1 g/g At. Wt)x 0.861 g cm 5 _3 B. (39.1 g/g At. Wt)/ 0.861 g cm 5 _3 C. (0.861 g cm )/(39.1 g/g At wt) 5 _3 9 D. (1/39.1 g/g At. Wt) x (1/0.861 g cm ) 0055 1926401 B 14 18987 31 135917010169 Short_range order is never present in A. crystalline solids B. amorphous solids 9 C. liquids B. gases 0041 1926402 A 14 45643 31 170101690879 An amorphous solid is closest in structure to A. a liquid C. an ionic crystal E. an insulator 9 B. a covalent crystal D. a semiconductor 0041 1926403 D 14 18991 31 071610041698 Defects in crystal structure are not involved in A. the flow of electrons in a semiconductor B. the flow of holes in a semiconductor C. the mechanical strength of a solid 9 D. the mechanism of van der waals bonding 0041 1926404 C 14 18994 31 049502441178 The individual particles in an ionic crystal are 9 A. atoms B. molecules C. ions D. electrons 0041 1926405 A 14 18996 31 049502440351 The individual particles in a covalent crystal are 9 A. atoms B. molecules C. ions D. electrons 0041 1926406 B 14 18998 31 049500660293 The individual particles in the Van Der Waals crystal of a compound are 9 A. atoms B. molecules C. ions D. electrons 0041 1926407 C 15 19000 52 001511611798 Strontium metal exists in three different crystalline forms known as alpha _, beta_, and gamma_strontium. The alpha form, which exists at 25 degrees C, has a face centered cubic unit cell with an edge of 4.2 Angstrom. What is the density of alpha_strontium? (At. Wt. Sr = 88) 5 _3 _3 _3 A. 0.42 g cm B. 2.0 g cm C. 8.0 g cm 0042 5 _3 _3 9 D. 28 g cm E. 88 g cm 1926408 C 15 19006 52 024414540767 A crystal of anhydrous KNO is composed of: 4 3 A. molecules of KNO , 4 3 B. atoms of potassium, nitrogen and 3 atoms of oxygen alternately spaced in the crystal C. a geometrical pattern of potassium ions and nitrate ions in the crystal D. potassium nitrate molecules alternately spaced with water molecules E. molecules of KNO and water combined into larger molecules. 94 3 1926409 C 15 19013 52 109714090224 A sample of iron oxide prepared under certain laboratory conditions has the formula Fe O. This is due to some of the 4 .97 5 ++ lattice sites of Fe not being occupied. Electrical neutrality 5 ++ is conserved by an appropriate nuber of Fe ions being converted 5 3+ to Fe . Let us consider a portion of the iron oxide that 0042 0047 contains 16 g of oxygen atoms. What would be the number of 5 2+ 3+ moles of Fe and Fe in this portion if the oxygen ions has a charge of _2. 5 2+ 3+ 2+ 3+ A. 0.5 Fe ; 0.5 Fe B. 0.97 Fe ; 0.03 Fe 5 2+ 3+ 2+ 3+ C. 0.91 Fe ; 0.06 Fe D. 1.0 Fe ; 0.0 Fe 5 2+ 3+ 9 E. 0.0 Fe ; 1.0 Fe 1926410 B 14 19025 51 The activity of a pure solid is: 9 A. 0 B. 1 C. _1 D. _2. 03750169 0043 1926411 B 15 19026 72 001515950026 Cu metal crystallizes in a face centered cubic unit cell with the length of an edge equal to 3.62 Angstroms. Assuming the atoms are identical hard spheres, calculate the atomic radius of the metal. 5 .5 .5 .5 .5 A. 3.62 B. 2 x 3.62 C. 2 x 3.62 D. 3 x 3.62 E. 1.5 x 3.62 4 ____ _________ _________ _________ 94 2 4 2 2 0044 1926412 B 15 19033 72 001515950026 Cs metal crystallizes in a body centered cubic lattice with the unit cell edge length equal to 6.17 angstroms. Assuming the atoms are identical hard spheres, calculate the atomic radius of the metal. (Hint: the square roots of 2 and 3 are 1.414 and 1.732 respectively.) 0044 (1.732)(6.17) (1.732)(6.17) 6.17 (1.414)(6.17) A. _____________ B. _____________ C. ____ D. _____________ 2 4 2 4 9 E. none of the above. 1926413 C 15 19040 71 159507150026 Most metals crystallize in the body centered cubic (bcc), the face centered cubic (fcc), or the hexagonal closest packed (hcp) lattice. Select the one right statement below; where 3 _____ a = edge length of unit cell, and r = atomic radius A. in fcc there are 6 atoms per unit cell. B. In fcc, a times the square root of three = 2r. 0044 9 C. In bcc there are 8 nearest neighbors at a distance 2r. D. in fcc there are 10 nearest neighbors at distance 2r. E. In bcc there are 6 nearest neighbors at distance 2r. 1926414 A 15 19048 72 07150186 Pd metal crystallizes in a face centered cubic unit cell with the length of an edge equal to 0.387 nm. What is the density (g/cc) of Pd metal? (AW of Pd = 106.) 9 A. 12.1 B. 27.2 C. 90.9 D. 0.165 E. 6.06 1926415 B 15 19051 72 071501860351 The length of a unit cell of Ag metal is 4.07 Angstroms and its density is 5.31 grams/cc. How many atoms of Ag are present in 5 _8 the unit cell? (1 Angstrom = 10 cm) 9 A. 9 B. 2 C. 4 D. 14 E. 5 0044 0044 1926416 E 15 19055 72 01861595 TlBr crystallizes in the CsCl lattice with the length of an edge equal to 3.87 Angstroms. What is the density of TlBr? (MW of TlBr = 284.) A. 122 g/cc B. 488 g/cc C. 32.6 g/cc 9 D. .111 g/cc E. 8.16 g/cc. 0044 1926417 A 15 19058 72 07150186 NaI crystallizes into the NaCl unit cell. The density is equal to 4.14 g/cc. What is the length of an edge of the unit cell of NaI in nanometers (nm)? 5 7 9 A. 0.622 B. 0.117 C. 0.392 D. 5.25 x 10 E. 24.1 0044 1926418 A 15 19062 51 016902931147 In solids, the molecules can A. vibrate about fixed positions B. have any kind of motion C. move freely relative to other molecules D. have translational kinetic energy 9 E. none of these 1926419 CBAD 44 19065 52 07161593800290 MACROITEM STEM Choose the best answer in the key for each of the descriptions of a solid pure substance. 3 KEY ___ 0020 OS A. Covalent B. Molecular C. Ionic 0 D. Metallic MACRO SUB_ITEM # 1 1 High melting point, brittle, soluble in water. MACRO SUB_ITEM # 2 2 Low melting point, insoluble in water. MACRO SUB_ITEM # 3 Insoluble in water, high melting point, and the 3 solid is a non_conductor of electricity. MACRO SUB_ITEM # 4 Insoluble in water, the solid is a conductor of 9 electricity and it has a high melting point. 1926420 B 15 19072 31 087901690351 The lattice points in a solid A. are always occupied by molecules B. may be occupied by atoms C. cannot be occupied by atoms 9 D. are always occupied by single atoms E. are sharp. 0040 1926421 A 15 19075 31 078101730169 Which of the following types of solids is the hardest? A. atomic solids B. ionic solids C. nonpolar molecular solids D. polar molecular solids 9 E. cannot be determined from given information . 0040 1926422 D 15 19078 31 00140716 Each carbon atom in the diamond structure is located so that it has A. one nearest neighbor B. two nearest neighbors C. three nearest neighbors D. four nearest neighbors 9 E. six nearest neighbors 1926423 C 14 44582 72 001501790026 A certain metal crystallizes in a face_centered cubic unit cell. On the assumption that atoms are spherical, the relationship between the atomic radius (r) of the metal and the length (a) of one edge of the unit cell is: 5 1/2 A. 2r = a C. 4r = (2) x a E. r = a 5 1/2 1/2 9 B. 2r = (2) x a D. 4r = (3) xa 0040 0009 1926424 C 14 19086 51 130115721595 The number of closest neighbors in a body_centered cubic lattice is 9 A. 4 B. 6 C. 8 D. 12 0009 1926425 D 15 19088 31 141801690173 Molecular solids are usually: A. good electrical conductors B. quite hard C. quite brittle 9 D. volatile E. heavy 0035 1926426 A 15 19090 31 024403170351 In a molecular crystal the forces holding together the atoms within a given molecule are: A. covalent C. metallic bonds E. London forces 9 B. ionic bonds D. Van Der Waals' forces 0035 1926427 D 14 19093 31 000501690793 Ionic solids tend to be A. good electrical conductors C. volatile E. malleable 9 B. soft D. brittle 0035 1926428 E 15 19095 31 000500660237 One way that ionic compounds differ from covalent compounds is that ionic compounds A. usually form well_defined crystals, covalent usually do not. B. are all soluble in water, covalent are all insoluble. C. never contain carbon, covalent always contain carbon. D. are generally more volatile than covalent compounds. 9 E. none of these. 0035 1926429 B 14 19100 32 1894 05 Hexagonal closest packing in a crystal is found when the particles of the substance are A. six_sided C. nonequivalent spheres 9 B. equivalent spheres D. molecules composed of six atoms 1926430 A 14 19103 32 1892 05 Cubic closest packing in a crystal is found when the particles of the substance are A. equivalent spheres C. molecules composed of eight atoms 9 B. nonequivalent spheres D. eight_sided 1926431 C 14 19106 32 18921894 05 The basic difference between hexagonal closest packing and cubic closest packing is that A. the atoms are more closely packed in one of these 9 structures than in the other B. the coordination number of nearest neighbors is different C. the repetition of the layers is ordered differently D. the atoms are arranged in six_sided layers in the former and in squares in the latter 1926432 B 14 19112 51 0716 05 The type of packing that is assumed by atoms (or ions) in a crystal is determined by A. the oxidation states of the atoms B. the different sizes of the atoms C. the kind of compound that is formed 9 D. physical properties of the crystal 1926433 C 14 19116 52 194801860715 5 3 The density of diamond is 3.515 grams per cm . Diamond and Si possess the same structure. The unit cell edge lengths of diamond and Si are 3.567 A and 5.430 A respectively. Atomic weights are: C = 12.011 and Si = 28.086. density of Si may be calculated as follows: 5 3 (3.567) 12.011 A. 3.515 x ________ x ______; 5 3 (5.430) 28.086 5 3 (5.430) 12.011 B. 3.515 x ________ x ______; 5 3 (3.567) 28.086 5 3 (3.567) 28.086 C. 3.515 x ________ x ______; 5 3 (5.430) 12.011 0059 3 (5.430) 28.086 D. 3.515 x ________ x ______. 5 3 9 (3.567) 12.011 1926434 C 14 19128 Crystal system of ice: 72 195501651893 0062 9 A. isometric B. tetragonal C. hexagonal D. orthorhombic 1926435 A 14 19130 72 19551957 In which type of unit cell is the percentage of "empty" space the greatest? A. simple cubic B. body_centered cubic E. fluorite type 9 C. face_centered cubic D. hexagonal close packing 0062 1926436 D 14 19133 72 19550344 Which solid is relatively soft and a good electrical conductor? A. Cr B. NaCl C. P D. K 94 4 0062 1926437 A 14 19135 72 19550852 Which substance meets the requirements: hexagonal, soft, high melting point? 9 A. graphite B. quartz C. ice D. tungsten 0062 1926438 D 15 19137 52 If a metal forms a face_centered crystalline structure with unit cell edge length of x, the atomic radius of the metal may be calculated as follows: _ __ _ _ _ A. xV2 B. V2x C. xV2 D. xV2 E. /x 3 ___ ___ ___ _ 9 4 2 4 V2 1926439 B 14 19142 72 19550943 NaCl crystallizes in a face_centered cubic crystal lattice. The crystallographic coordination number of Na in NaCl is 9 A. 1 B. 6 C. 8 D. 4 E. 12 0062 1926440 C 15 19145 72 159507150725 NaBr crystallizes into a lattice structure equivalent to that of NaCl but with a unit cell edge length equal to 5.80 Angstroms. If the ionic radius of Br is 1.95 Angstroms, what is the ionic radius of Na? A. 3.07 Angstroms B. 2.90 Angstroms C. .950 Angstroms 9 D. 1.90 Angstroms E. 3.85 Angstroms. 0044 1926441 C 15 19150 72 159501860715 Cu metal crystallizes in a face centered cubic lattice with four atoms per unit cell. The density of Cu is 8.92 g/cc. What is the length of an edge of the unit cell of Cu metal (in nanometers)? 5 8 9 A. 0.0907 B. 3.06 x 10 C. 0.362 D. 0.474 E. 0.456 0044 1926442 B 15 19155 52 Identical spheres are arranged in three different patterns: simple cubic (SC), body centered cubic (BCC) and face centered cubic (FCC). The coordination number of each sphere (the number of nearest_neighbor spheres) is 9 A. B. C. D. E. SC 8 6 12 8 6 BCC 6 8 8 6 12 FCC 12 12 6 12 8 1926443 B 15 45469 71 How many atoms are there in a body_centered cubic unit cell of tungsten? 9 A. 1 B. 2 C. 4 D. 6 E. 8 1926444 D 15 45471 71 Calcium fluoride crystallizes in a face_centered cubic lattice. The fluoride ions occupy the interstitial sites in the unit cell, and the calcium ions occupy the faces and corners of the unit cell. The total number of ions in the unit cell is: 9 A. 2 B. 4 C. 6 D. 8 E. 12 1926445 B 15 45475 71 What is the simplest formula of a solid containing A, B, and C atoms in a cubic lattice in which the A atoms occupy the corners, the B atoms the body_center position, and the C atoms the faces of the unit cell? A. ABC B. ABC C. ABC D. A BC E. A BC 94 3 6 8 6 4 3 1926446 A 15 45480 71 5 o An atomic face_centered cubic crystal is 3.92 A on an edge and has 5 3 a density of 21.5 g/cm . What is its atomic weight? 9 A. 195 B. 207 C. 48.8 D. 108 E. 63.5 1926447 A 15 45484 71 Silver crystallizes in the face_centered cubic system. If the edge 5 o of the unit cell is 4.07 A, what is the radius of a silver atom in 5 o _8 OS83 angstroms (1 A = 10 cm)? 9 A. 1.44 B. 1.76 C. 2.04 D. 2.88 E. 3.52 1926448 DCBB 45 45488 71 MACROITEM STEM Answer the next four questions using the following information: Lithium chloride crystallizes in a face_centered cubic structure. 5 _8 The unit cell length is 5.14 x 10 cm. The chloride ions are touching each other along the face diagonal of the unit cell. The 0 lithium ions fit into the holes between the chloride ions. MACRO SUB_ITEM # 1 How many lithium ions are there in this unit cell? 1 A. 1 B. 2 C. 3 D. 4 E. 5 MACRO SUB_ITEM # 2 What is the mass of LiCl in a unit cell? 5 _23 _22 _22 A. 7.04 x 10 g C. 2.82 x 10 g E. 5.63 x 10 g 5 _22 _22 2 B. 1.41 x 10 g D. 4.22 x 10 g MACRO SUB_ITEM # 3 What is the density of the lithium chloride? A. 1.04 g/cc C. 2.42 g/cc E. 3.78 g/cc 3 B. 2.08 g/cc D. 3.11 g/cc MACRO SUB_ITEM # 4 What is the radius of the chloride ion? _8 _8 _8 A. 1.29 x 10 cm C. 2.23 x 10 cm E. 2.76 x 10 cm _8 _8 9 B. 1.82 x 10 cm D. 2.56 x 10 cm 1926449 E 15 45502 71 Which of the following as a solid has a crystal structure containing discrete (or separate) molecules? A. potassium C. quartz E. hydrogen chloride 9 B. glass D. carborundum, SiC 1930001 E 15 19161 52 01868001800211 Which of the following statements would tell you most about whether a given portion of matter is a pure substance or a mixture? A. It all dissolves in the same solvent. B. Solutions of different concentrations are found to possess different properties. C. When heated unevenly, the portion which is hottest melts first. D. The matter is observed, under a microscope, to be composed of ETS2 OS 9 particles of different sizes. E. The large particles are found to be of greater density than the small particles. 1930002 A 15 19169 72 01090187800111 Nitrogen and oxygen, the principle constituents of the air, are present in a practically constant ratio of 3.2 grams of nitrogen to every one gram of oxygen. The two elements can also be made to combine chemically, forming the compound nitric oxide, which contains seven grams of nitrogen to every eight grams of oxygen. Both air and nitric oxide are colorless gases. An experimental method for showing that one is a compound and the other is a mixture, would be to A. compress and cool a sample of each gas until liquefaction took place B. examine a sample of each gas under the microscope C. weigh equal volumes of each gas D. add a sample of one gas to a sample of the other, and let them stand overnight E. let them both stand undisturbed for a long period of time, and then to carefully remove samples from both the top and 9 bottom of the containers for examination 1930003 CAEBA 55 19181 52 0189006680011190 MACROITEM STEM 2For the following items, choose the best answer from the key 2below. 2 A. Element 2 B. Compound 2 C. Mixture 2 D. Solution 0 E. Two of the above MACRO SUB_ITEM # 1 1 Granite MACRO SUB_ITEM # 2 2 A noble metal MACRO SUB_ITEM # 3 3 Air MACRO SUB_ITEM # 4 4 Silica MACRO SUB_ITEM # 5 9 Graphite 1930004 A 15 19184 31 01920193800112 A substance may be considered to be homogeneous when A. every particle is like every other particle ETS2 OS ETS2 OS ETS2 OS 9 B. it is composed of particles whose properties may be quite different C. its density is 1 g/cc D. it is composed of two different elements E. its density approaches that of water 1930005 C 15 19189 All alloys can be termed A. isotopes B. elements C. mixtures D. compounds 9 E. polymers 31 01940168800111 1930006 CDABCAB 74 19191 52 0087017880011290 MACROITEM STEM 2Suppose that four samples of different materials in powdered form 2are subjected to the following treatments 2A. When heated, sample A melted at a relatively low temperature. 3 ______ 2When sample A was dissolved in water, no reaction took place with 3 ________ 2the water, and the solution thus obtained would not conduct an 2electric current. 2B. When an attempt was made to dissolve sample B in carbon 3 ________ 2disulfide, a solvent, a black residue remained undissolved. When 2the carbon disulfide was poured off from the black residue and 2allowed to evaporate, a yellow residue remained. 2C. When sample C was heated it melted at a much higher temperature 3 ________ 2than sample A. when sample C was dissolved in water, no reaction 2was observed to take place, but the solution thus obtained did 2conduct an electric current. 2D. Sample D was subjected to experimentation. Evidence was obtained 3 ________ 2which showed that all of the atoms of D have the same atomic 2number, although there was some variation in mass. 2After each item number on the answer sheet, blacken the one 3 ___ 2lettered space which designates the sample material to which the 0 item correctly refers. MACRO SUB_ITEM # 1 When in solid form, positive and negative ions of this sample are 1 held together by electrostatic forces. MACRO SUB_ITEM # 2 ETS2 OS ETS2 OS 2 All of the atoms in the sample are atoms of the same element. MACRO SUB_ITEM # 3 3 This sample evidently consists of a non_ionic or covalent compound. MACRO SUB_ITEM # 4 4 This sample is evidently a mixture. MACRO SUB_ITEM # 5 5 This sample is evidently an ionic or electrovalent compound. MACRO SUB_ITEM # 6 The molecules of this compound evidently have little attraction 6 for each other. MACRO SUB_ITEM # 7 9 The constituents of this sample are chemically uncombined. 1930007 EDAD 45 19214 51 0438018680011190 MACROITEM STEM 2The following questions involve properties of certain substances. 2Select from the key the substance which has the property indicated 2by each item. 2 A. Carbon dioxide 2 B. Water 2 C. Oil 2 D. Mercury 0 A. Ethyl alcohol MACRO SUB_ITEM # 1 1 A liquid which is miscible with water MACRO SUB_ITEM # 2 2 The listed substance having the greatest density MACRO SUB_ITEM # 3 3 The substance having the lowest boiling point MACRO SUB_ITEM # 4 A substance capable of floating an alloy whose specific gravity 9 Is 10 1930008 D 15 19220 31 01090025800111 Under normal conditions air and oxygen differ in A. state B. color C. odor D. density 9 E. taste 1930009 D 14 19222 31 019202868004 A pure substance Z can be separated into pure substances X and Y only by heating. Which of the following is true? A. X and Y must be elements; Z must have been an element. B. X and Y must be compounds; Z must have been a compoiund. ETS2 OS ETS2 OS 2WVW 9 C. X and Y must be elements; Z must have been a mixture. D. X and Y could be either elements or compounds, Z must have been a compound. 1930010 BCCDBABCC94 19228 31 0168018980011290 ETS2WVW MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the item is true only of mixtures 2 B. if the item is true only of elements 2 C. if the item is true only of compounds 0 D. if the item is true of both elements and compounds MACRO SUB_ITEM # 1 1 Consists of a single variety of atoms. MACRO SUB_ITEM # 2 2 Always have a definite and constant composition. MACRO SUB_ITEM # 3 Its formation from simpler materials is always accompanied 3 by a loss or gain of energy. MACRO SUB_ITEM # 4 Are identified by specific physical and chemical 4 properties. MACRO SUB_ITEM # 5 5 A planned arrangement results in the periodic classification. MACRO SUB_ITEM # 6 6 Properties of the components are retained in the material. MACRO SUB_ITEM # 7 7 Can be approximately classified as metals or non_metals. MACRO SUB_ITEM # 8 8 Can be approximately classified as covalent or ionic. MACRO SUB_ITEM # 9 9 Have a definite composition of unlike atoms. 1930011 ABCABBADC94 19238 31 0189006680011290 ETS2WVW MACROITEM STEM 2After each item on the answer sheet, blacken space 2 A. if the item is true only of elements 2 B. if the item is true only of compounds 2 C. if the item is true only of mixtures 0 D. if the item is true of both elements and compounds MACRO SUB_ITEM # 1 1 Consists of the same atomic species MACRO SUB_ITEM # 2 2 Have properties entirely different from those of the constituents MACRO SUB_ITEM # 3 Have properties, dependent on the ratios of the substances 3 present MACRO SUB_ITEM # 4 Are listed according to increasing atomic numbers on the 4 periodic chart MACRO SUB_ITEM # 5 Energy is gained or lost when formed from simpler 5 materials MACRO SUB_ITEM # 6 6 Usually classified as covalent or electrovalent MACRO SUB_ITEM # 7 7 Usually classified as metals, non_metals or inert gases MACRO SUB_ITEM # 8 8 Are homogeneous, that is, the same throughout MACRO SUB_ITEM # 9 9 Physical means 1930012 A 15 19248 31 04570458800111 An alum A. has the general formula M (SO ) 4 2 43 B. does not necessarily contain aluminum C. is an anhydrous salt D. gives off CO when heated with cream of tartar 4 2 E. one variety, commonly called alundum, is commonly used 9 as an abrasive ETS2 OS 1930013 D 15 19253 52 06900414800111 Select the true statement or statements. A. Bituminous coal contains fixed nitrogen. B. Anthracite coal is over 90% carbon C. When melted, coke becomes coal tar. The correct selection includes only A. A B. B C. C D. A and B 9 E. B and C ETS2 OS 1930014 B 14 19257 31 80038004 A chemical property of a substance is its A. color B. combustibility C. density 9 D. state 2WVW 1930015 CBE 35 19259 31 080106838004 90 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches. 2 A. Exothermic 2 B. Endothermic 2 C. Element 2 D. Catalyst 0 E. Molecule MACRO SUB_ITEM # 1 1 A substance which can't be decomposed by ordinary chemical means. MACRO SUB_ITEM # 2 2 Pertaining to a reaction which occurs with the absorption of heat. MACRO SUB_ITEM # 3 The smallest portion of a substance that can have a stable, 9 independent existence. 2 OS 1930016 CAEB 45 19265 31 058800668004 90 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches 2 A. matter 2 B. compound 2 C. density 2 D. element 0 E. atom MACRO SUB_ITEM # 1 1 The weight of a material per unit volume MACRO SUB_ITEM # 2 2 Anything which occupies space and has weight MACRO SUB_ITEM # 3 The smallest part of an element that can enter into combination 3 with other elements MACRO SUB_ITEM # 4 A substance which can be decomposed into two or more simpler 9 substances by ordinary chemical means 2 OS 1930017 CAEB 45 19271 31 078704388004 90 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches. 2 A. Precipitate 2 B. Reducing agent 2 C. Filtration 2 D. Distillation 2 OS 0 E. Specific gravity MACRO SUB_ITEM # 1 The process of removing suspended material from a liquid by allowing the liquid to pass through a material such as paper or 1 layers of sand MACRO SUB_ITEM # 2 An insoluble product formed by chemical action between the 2 solutions of two soluble substances MACRO SUB_ITEM # 3 The ratio of the density of a substance to the density of a 3 standard of reference such as water MACRO SUB_ITEM # 4 9 A substance which supplies electrons during a chemical reaction 1930018 D 14 19279 31 010901688004 A reason that air is a mixture is that A. it becomes warm as it is compressed B. it can be liquified C. it supports combustion 9 D. its compositon varies 2 OS 1930019 D 14 19282 31 04110154 The chemist attemps to purify matter because A. only by purifying matter can he precisely characterize the components of nature B. the behavior of matter in chemical changes would be unpredictable unless pure matter is involved C. he fundamentally opposes bacteria 9 D. two of the above answers. 0026 1930020 C 14 19287 31 01720192 Which one of the following properties may be used to specifically identify a given substance? 9 A. temperature B. mass C. melting point D. volume. 0026 1930021 E 15 19290 31 079800870193 Air, water, pure carbon, and a solution of sugar in water are similar in that they are all A. heterogeneous B. compounds C. in the same state of matter D. mixtures 9 E. homogeneous 0020 1930022 B 15 19293 31 058800870066 In which of the following sequences are the classifications of 0040 matter listed in order of decreasing complexity? A. homogeneous, element, solution B. homogeneous, solution, compound C. pure substance, compound, solution D. solution, element, compound 9 E. solution, homogeneous, compound 1930023 D 15 19297 31 008702040588 Which of the following classifications of matter may be associated with a variable composition? A. pure substance B. homogeneous matter C. solution D. both B and C 9 E. both A and B 0040 1930024 A 15 19300 31 130701650018 Which of the following is an example of heterogeneous matter? A. water containing crushed ice B. a sample of pure table salt C. a sample of salt water D. a pure sample of iron 9 E. an ice cube. 0040 1930025 E 15 19303 31 093700660588 Which of the following classifications of matter could not possibly contain heteroatomic molecules? A. pure substance B. homogeneous matter C. compound D. solution 9 E. no correct response is given. 0040 1930026 D 14 19306 31 144510970192 Of the following characteristics of a sample of a substance, the one that is not a physical property is its 9 A. color B. density C. hardness D. temperature 0041 1930027 B 15 44757 31 Choose the option in the key below which best matches the statement following the key: A. exothermic C. element E. molecule 9 B. endothermic D. catalyst 1932001 C 15 19309 32 00180152800111 For which one of the following reasons may we consider the dissolving of salt in water to be a physical change? A. The salt becomes invisible. ETS2 OS 9 B. The water combines with the salt. C. The residue from evaporation of the solution is unaltered. D. The residue from evaporation of the solution is not salt. E. None of the above; this is actually a chemical change, and the above are not applicable. 1932002 D 15 19315 52 00110153800112 A certain material on extraction with water left a solid residue. The water extract on evaporation also formed a solid residue. These facts definitely show that the original material was A. an electrolyte B. an element C. a compound D. a mixture 9 E. a salt ETS2 OS 1932003 A 15 19319 32 00080173800111 The hardness of water cannot be removed by which of the following? 3 ______ A. boiling B. addition of Na CO to precipitate CaCO 4 2 3 3 C. distillation D. addition of MgCl 4 2 9 E. use of ion_exchange minerals or resins ETS2 OS 1932004 C 15 19324 31 01770025800111 The fractional distillation of liquid air is used commercially to obtain A. dry ice B. ammonia C. oxygen D. carbon dioxide 9 E. hydrogen ETS2 OS 1932005 A 15 19327 32 00188001800211 A chalk and salt mixture could be separated into its component substances by A. adding water, stirring and filtering B. adding water and boiling C. adding water, and distilling D. adding water, boiling, and cooling 9 E. subliming the salt out of the mixture ETS2 OS 1932006 C 14 19331 31 018900668004 2WVW Elements and compounds found in the same area but not chemically combined form A. an amino acid B. a compound C. a mixture 9 D. a molecule 1932007 B 14 19334 31 032108228004 The atmosphere surrounding the earth is an example of A. a compound B. a mixture C. a molecule 9 D. an element 2WVW 1932008 B 14 19336 31 008700188004 A saturated solution of salt is an illustration of A. the law of definite composition B. a mixture C. a compound 9 D. a nonhomogeneous solution 2WVW 1932009 A 14 19339 31 019201688004 A substance was separated from a mixture. It was flammable, did not dissolve sugar, had a boiling point of 81 deg. C., had a density of less than 1, and had a definite odor. This substance was probably which of the following? A. alcohol B. sodium chloride C. water 9 D. ammonia and water 2WVW 1932010 C 14 19343 32 016904388004 Depending upon the situation, there are many ways of separating insoluble solids from liquids. Which of the following is not one of these ways A. pour the liquid off the top of the solid B. skim the solid off the top of the liquid C. use fractional crystallization 9 D. filter the substance 2 OS 1932011 B 15 19347 31 016801570504 Which one of the following is not an example of the formation of 3 ___ a mixture? A. mixing of hydrogen and oxygen B. igniting of hydrogen and oxygen to form water 0028 9 C. dissolving of sodium chloride in water D. dissolving of sugar in water E. dissolving ethyl alcohol in water 1932012 D 15 19351 31 117001930192 Sea water A. is a homogeneous mixture B. is a solution C. contains many dissolved substances D. all of these 9 E. none of these 0020 1932013 B 15 19353 31 008701690194 Solutions of solids in solids are called A. amalgams B. alloys C. heterogeneous mixtures D. brass 9 E. none of these 0020 1932014 D 15 19355 31 016800870169 Which of the following mixtures cannot be a solution? A. gases in gases B. solids in solids C. gases in liquids D. solids in liquids 9 E. solids in gases 0020 1932015 B 15 19358 31 008707900552 Which of the following solutions is a nonelectrolyte? A. salt in water B. sugar in water C. sea water D. ammonium chloride in water 9 E. none of these 0020 1932016 E 15 19361 31 016813070193 A mixture is A. always heterogeneous B. sometimes a single substance C. always a liquid D. never homogeneous 9 E. none of these 0020 1932017 B 15 19363 32 055200870168 If a sugar solution is mixed with a salt solution, the result is 0020 9 A. a pure substance B. a mixture C. heterogeneous D. a new compound E. none of these 1932018 B 14 19366 32 039301680192 One way to definitely show that gasoline is a mixture of substance would be to A. measure its density B. measure the temperature during boiling 9 C. burn it D. filter it 0009 1932019 B 14 19369 52 027401680714 The chemical analysis of a mixture of gases is most likely to involve A. density measurements B. mass spectroscopy 9 C. boiling point measurements D. fractional crystallization 0009 1932020 D 14 19372 31 078705880164 Which one of the following processes does not remove suspended matter from water? A. sedimentation B. coagulation 9 C. filtration D. chlorination 0009 1932021 C 15 19375 31 019305880087 Which of the following is an example of homogeneous matter? A. concrete B. muddy water C. salt water D. wood 9 E. water containing crushed ice. 0040 1932022 B 14 19378 52 152801681565 To separate a mixture of monosaccharides, you would probably use a(n): A. centrifuge B. column chromatograph 9 C. mass spectrometer D. electrolytic cell 0009 1932023 A 14 19381 32 19550087 A salt solution is: A. a homogeneous mixture B. heterogeneous and consists of one phase C. a compound 9 D. a heterogeneous mixture 1934001 C 15 19383 31 01920351800111 A substance composed of only one kind of atoms is A. a colloid C. an element E. a solution 0062 ETS2 OS 9 B. a complex D. a compound 1934002 C 15 19385 32 05660195800111 Ozone A. is an isotope of oxygen B. is an important constituent of the atmosphere C. has a volume two_thirds of that of the oxygen from which it was formed D. absorbs heat when it is decomposed 9 E. is used industrially in the production of high temperatures ETS2 OS 1934003 B 14 19389 31 049501898004 The smallest particle of an element is a/an A. molecule B. atom C. compound 9 D. amino acid 2WVW 1934004 B 14 19391 31 018901928004 An element may be defined as a substance, all the atoms of which have the same A. atomic weight B. atomic number C. radioactivity 9 D. number of neutrons 2WVW 1934005 B 14 19394 31 Tritium is a radioactive form of A. helium B. hydrogen C. nitrogen 9 D. carbon 80038004 1934006 C 14 19396 31 018903988004 The element with the lowest atomic mass is 9 A. oxygen B. aluminum C. hydrogen D. magnesium 1934007 D 14 19398 31 The symbol k+ represents one A. atom of krypton B. atom of potassium C. ion of krypton 9 D. ion of potassium 2WVW 2 OS E. boron 081200198004 1934008 B 14 19400 31 019602930926 Hydrogen atoms are held together to form hydrogen molecules by 2 OS 0041 9 A. ionic binding B. covalent binding C. electron spin D. polar molecules 1934009 A 14 19402 31 035101890066 Atoms of two different elements A. may form no compounds together. B. Can form only one compound together C. can always form more than one compound together D. must have the same valence if they are to form a compound 9 together 0041 1934010 C 14 19406 31 018900660014 The element contained in the greatest number of compounds is 9 A. hydrogen B. oxygen C. carbon D. sulfur 0041 1934011 A 14 19408 31 115900941503 The form of sulfur which is stable at room temperature and normal atmospheric pressure is: 9 A. orthorhombic B. hexagonal C. monoclinic D. amorphous. 0043 1934012 A 14 19411 51 00940114 When liquid sulfur at one atmosphere pressure is very slowly cooled, unless supercooling occurs, the first solid to appear is: A. monoclinic sulfur B. rhombic sulfur 9 C. hexagonal sulfur D. "metallic" sulfur. 1934013 D 15 19414 31 034103510263 Atoms of an elemet A. must be indentical to each other in all aspects. B. may differ in the number of electrons they contain C. may differ in the number of protons they contain D. may differ in the number of neutrons they contain 9 E. both D and B. 1934014 A 15 19418 32 071101 Which of the following represent elements: O, O , O , P, P , S, S 4 2 3 4 8 A. all are chemical elements B. only O, P, and S C. only O , P, and S D. only O , O , P , and S 4 2 2 3 4 8 E. only O , P , and S 94 2 4 8 1934015 C 14 19423 32 195404150064 The most abundant rare gas in earth's atmosphere is: 0043 0040 0064 0061 9 A. He B. Ne C. Ar D. Kr E. Xe 1936001 D 15 19425 32 80018002 11 When water is decomposed into its elements, the volume of hydrogen produced is twice as great as the volume of oxygen. The weight of the hydrogen is A. twice as much B. half as much C. one_quarter as much D. one_eighth as much 9 E. one_sixteenth as much ETS2 OS 1936002 A 15 19429 51 00660263800111 All of these terms apply to an important class of chemical compounds except 3 ______ A. pairs of shared electrons B. formation of ionized solutions C. atoms forming rings of various sizes D. formation of homologous series 9 E. atoms forming chains ETS2 OS 1936003 E 15 19433 31 04450087800111 The following are the common names of the materials indicated A. Ca(OH) is quick lime 4 2 B. a mixture of CaCO and CaO is mortar 4 3 C. CaCO is slaked lime 4 3 D. KHCO is baking powder 4 3 E. a solution of Ca(OH) is lime water 94 2 ETS2 OS 1936004 DCDEB 55 19438 52 1 012800429009129095 MACROITEM STEM 0 The following questions refer to Figure 9. MACRO SUB_ITEM # 1 the molecular weight of magnesium oxide is A. 20 B. 21 C. 22 D. 42 1 E. none of the above. MACRO SUB_ITEM # 2 ETS2 OS 2 3 4 9 The number of protons and neutrons in ion number four is A. 9p, 9n B. 7p, 10n C. 8p, 9n D. 8p, 10n E. 7p, 8n MACRO SUB_ITEM # 3 The atomic weight of atom number one is A. 12 B. 13 C. 24 D. 25 E. 26 MACRO SUB_ITEM # 4 Atom number two is A. of positive valency B. ionized C. inactive D. a reducing agent E. non_metallic in character MACRO SUB_ITEM # 5 Ion number three in the compound has been A. oxidized and is now a negative ion B. oxidized and is now a positive ion C. reduced and is now a negative ion D. reduced and is now a positive ion E. made neutral 1936006 D 15 19452 51 00080128800111 Water is not used as the standard 3 ___ A. of specific gravities B. of specific heats C. in calibrating thermometer scales D. of molecular weights 9 E. of the metric system of weights ETS2 OS 1936007 D 15 19455 31 00660189800111 A compound A. is any substance that can be obtained in crystalline state B. can only be obtained by the direct combination of its constituent elements C. varies slightly in composition according to the proportion of the two elements combined together D. is made up of two or more elements combined in unchangeable proportions by weight ETS2 OS 9 E. is always more stable at low temperature than high temperature 1936008 B 14 19461 31 018900668004 Two or more elements chemically combined form a/an A. amino acid B. compound C. enzyme 9 D. atom 2WVW 1936009 A 14 19463 31 018900668004 When active elements combine to form compounds, the compounds A. are very stable B. are very unstable C. form with great difficulty 9 D. reverse themselves 2WVW 1936010 B 14 19466 31 Which choice is a compound? A. carbon B. carbon dioxide C. hydrogen 9 D. nitrogen 2WVW 006302618004 1936011 D 14 44485 31 006603510945 In general, in a covalent compound, A. electrons are transferred from one atom to another B. only atoms with the same atomic number are present C. there must be at least one carbon atom D. adjacent atoms share electron pairs 9 E. electronegativity differences are quite large 0041 1936012 C 14 19471 31 040802441178 Sodium chloride crystals consist of NaCl molecules B. Na and Cl atoms 5 + _ _ + 9 C. Na and Cl ions D. Na and Cl ions 0041 1936013 B 14 19474 31 006609430020 Every simple chemical compound A. is either an acid or base B. contains the same number of positive and negative valences C. is a member of the periodic table 9 D. contains at least one hydrogen atom 0041 1936014 B 0018 15 19477 31 003701930192 Homogeneous substances composed of two or more simpler substances whose proportions are fixed and invariable by weight are called A. elements B. compounds C. mixtures 9 D. metals E. none of these 1936015 C 15 19480 31 00870504 Ammonia water would be classified according to which one of the following states of matter: A. solid in a gas B. gas in a solid C. gas in a liquid 9 D. liquid in a gas E. liquid in a liquid. 0028 1936016 B 15 19483 31 018901680037 Pure water is A. an element C. a mixture E. always heterogeneous 9 B. a compound D. a solution 0026 1936017 D 15 19485 31 006601920943 A compound is A. a pure substance that may be broken down into simpler substances by physical means B. a substance that cannot be broken down into simpler substances by chemical means C. a heterogeneous substance D. a pure substance that can be broken down into simpler substances by chemical means 9 E. the smallest part of a molecule 0020 1936018 D 15 19490 31 003701920943 A compound represents A. a heterogeneous substance B. a pure substance that may be broken down into simpler substances by physical means C. a substance that cannot be broken down into simpler substances by chemical means D. a pure substance that can be broken down into simpler substances by chemical means E. a homogeneous substance which is the smallest particle of an 9 element 0019 1936019 C 15 19496 31 006601890135 A pure substance a is found to change upon heating into two new pure substances b and C. from this we may conclude that A. A and B are both elements. B. B and C are both compounds. C. A is a compound, B and C may or may not be elements. 0040 9 D. A is an element, B and C are compounds. E. A is a diatomic element 1936020 B 15 19501 31 018909360937 Molecules of compounds have one characteristic that is different from molecules of elements. This characteristic is that A. only compound molecules are homoatomic. B. only compound molecules are heteroatomic. C. only compound molecules may be heteroatomic or homoatomic. D. compound molecules are always heavier than element molecules 9 E. element molecules are always heavier than compound molecules 0040 1936021 D 15 19507 31 019205880066 Which of the following statements relating to the various subclassifications of matter is incorrect? 3 ________ A. All elements are pure substances. B. All compounds are pure substances. C. All compounds have heteroatomic molecules. D. All pure substances are compounds. 9 E. All elements are homonyclear 0040 1936022 E 15 19512 31 132600660075 Which of the following is not a binary compound? 3 ______ A. sodium hydride B. lead dioxide C. phosphorus pentachloride D. calcium iodide 9 E. sodium cyanide 0040 1936023 C 14 19515 31 031702930462 The forces most suited to account for the fact that atoms often combine to form molecules are 9 A. nuclear B. magnetic C. electrical D. polar 0009 1938001 C 14 19517 31 005607978004 The common name for sulfuric acid is A. muriatic acid B. nitrose acid C. oil of vitriol 9 D. oil of sulfur 2 OS 1938002 D 14 19519 31 001801898004 Common table salt contains the elements A. hydrogen and oxygen B. carbon and oxygen C. aluminum and chloride 2 OS 9 D. sodium and chloride 1938003 A 14 19521 31 020980028004 Muriatic acid is the name for the technical grade of A. hydrochloric acid B. hydrofluoric acid C. hydrobromic acid 9 D. hydriodic acid 2 OS 1950001 B 15 19523 32 01540155800111 Which of the following alterations of a substance would indicate that this substance had undergone a chemical rather than a physical change? A. a change in density B. change in odor or taste C. change in volume D. change in viscosity 9 E. all of these indicate that the change was chemical ETS2 OS 1950002 E 15 19528 32 01578001800212 Which one of these represents a physical change rather than a chemical one? A. bleaching clothes B. destructive distillation C. roasting meat D. synthesis of nitrates 9 E. none of the above ETS2 OS 1950003 C 15 19531 31 01650166800112 Consider the following changes (a) the grinding of wheat to flour; (b) the drying of clothes; (c) the drying of paint; (d) the making of "burnt" toast; (e) the melting of ice. How many of these are strictly physical changes? A. 1 B. 2 C. 3 D. 4 9 E. 5 ETS2 OS 1950004 C 15 19535 31 01690113800111 When a solid is changed to a gas or back again without melting, the process is called A. osmosis B. electrolysis C. sublimation D. boiling ETS2 OS 9 E. dissociation 1950005 B 15 19538 31 00080171800111 Chemically pure water may be made by A. electrolysis B. distillation C. filtering D. boiling 9 E. catalysis ETS2 OS 1950006 D 15 19540 51 01548001800211 A chemical change is one in which A. the substances alter their state (gas, liquid solid) B. heat is always given off C. new substances are formed the total energy of which is the same as the total energy of the reactants D. the identities of the substances are changed E. new substances are formed the total weight of which is 9 always slightly less than the total weight of the reactants ETS2 OS 1950007 A 15 19546 31 00090094800111 Which one of the following is true concerning the heating of various substances in laboratory experiments? A. Iron and sulfur combined on heating. B. Halite remained unchanged on heating. C. Steel wool decreased in weight on heating. D. Sodium bicarbonate gained weight on heating. 9 E. Heat always produces a chemical change. ETS2 OS 1950008 E 15 19551 32 01780087800111 Which one of the following is the best example of a chemical change? A. Defrosting a refrigerator B. Filtering drinking water C. Liquefying air D. Adding anti_freeze to a car radiator 9 E. Passing an electric current through a solution ETS2 OS 1950009 D 15 19555 31 01790180800111 The combining of a substance with a definite amount of water during crystallization is called A. sublimation B. saturation C. evaporation D. hydration 9 E. ionization ETS2 OS 1950010 E 15 19558 51 01780089800111 A chemical change is always produced in A. changes of state of matter B. crystallization of salts from saturated solutions C. osmosis through a semi_permeable membrane D. solution of a solute in a liquid 9 E. passing an electric current through an electrolyte ETS2 OS 1950011 B 15 19562 31 01810171800111 The process of vaporizing a liquid and condensing the vapor is known as A. precipitation B. distillation C. sublimation D. extrapolation 9 E. interpolation ETS2 OS 1950012 CAACDBAD 84 19565 32 0162008080011190 MACROITEM STEM 2For each of the practices or observations indicate from the 2following list the kind of change involved. 2 A. Oxidation_reduction 2 B. Ionization 2 C. Neutralization 0 D. Physical change MACRO SUB_ITEM # 1 1 Use of baking soda in leavening dough MACRO SUB_ITEM # 2 2 Deterioration of rubber tires in storage MACRO SUB_ITEM # 3 3 Use of chlorine in purifying water MACRO SUB_ITEM # 4 4 Using ground limestone on certain kinds of soil MACRO SUB_ITEM # 5 5 Beating an egg until it becomes light and foamy MACRO SUB_ITEM # 6 6 The sour taste of vinegar MACRO SUB_ITEM # 7 7 Production of heat in a gas range MACRO SUB_ITEM # 8 9 Production of heat in an electric range ETS2 OS 1950013 BCADDDBB 84 19572 32 0162008080011190 MACROITEM STEM 2For each of the practices or observations indicate from the ETS2 OS 2following list the kind of change involved 2 A. OxidatIon_reductIon 2 B. ionization 2 C. Neutralization 0 D. Physical change MACRO SUB_ITEM # 1 1 The sour taste of old milk MACRO SUB_ITEM # 2 2 Use of soda to relieve distress after over_eating MACRO SUB_ITEM # 3 3 Discoloration of fruit which is left in open air MACRO SUB_ITEM # 4 Death or injury resulting from snapping an electric light switch 4 While standing in a tub of water MACRO SUB_ITEM # 5 5 Whipping cream with an electric beater MACRO SUB_ITEM # 6 6 Making maple sugar from sap MACRO SUB_ITEM # 7 7 Injury to skin caUsed by strong soaps and washing powders MACRO SUB_ITEM # 8 9 use of vinegar in removing hard water stains from glassware 1950014 BCEA 45 19580 52 0080016280011190 MACROITEM STEM Many chemical and physical changes are involved in daily 2activities. 2For the following items select from the key the type of change most 2closely related to the statement. 2 A. Ionization 2 B. Neutralization 2 C. Oxidation_reduction 2 D. Physical change 0 E. None of these MACRO SUB_ITEM # 1 1 Soil is often sweetened with lime. MACRO SUB_ITEM # 2 3 _________ 2 Many families burn gas. MACRO SUB_ITEM # 3 3 The fission of uranium led to the development of the atomic bomb. MACRO SUB_ITEM # 4 3 _______ During thunderstorms flashes of lightning occur. 93 _______ __ _________ _____ ETS2 OS 1950015 E 15 19588 31 00878001800211 Which of the following would yield the most reliable evidence in determining or distinguishing whether a substance had merely gone into solution, or had actually undergone a chemical change? A. a change in mass B. a change in viscosiy C. a change in miscibility D. whether or not the substances would separate upon boiling 9 E. none of the above. ETS2 OS 1950016 E 15 19593 31 00080190800111 Which of the following statements is not true? 3 ___ A. Water is a polar compound. B. Water molecules may form hydrogen bonds with other water molecules. C. Water will conduct electricity to a small extent. D. Water ionizes to form hydronium ions and hydroxide ions. E. Water combines with other compounds to form hydrates by a 9 process called hydrolysis ETS2 OS 1950017 BBD 35 19599 32 0009009480011190 MACROITEM STEM 2A mixture of iron and sulfur was heated until the reaction ceased. 2When the product was tested with a magnet it was found to be 2magnetic. A sample of pure iron sulfide was tested with the magnet 2and found to be non_magnetic. Using this information , answer the 0 following questions. MACRO SUB_ITEM # 1 Which of the following assumptions would explain the magnetic properties of the product? A. An excess of sulfur is present in the product. B. There was not enough sulfur in the reactants. C. There was not enough iron in the reactants. 1 D. The relative amounts of iron and sulfur are not important. MACRO SUB_ITEM # 2 The product obtained in the reaction was a A. compound B. mixture C. physical change D. chemical change 2 E. change of state MACRO SUB_ITEM # 3 The formation of the iron sulfide is an example of a A. compound B. mixture ETS2 OS 9 C. physical change D. chemical change E. change of state 1950018 BDCED 55 19611 31 06530286 1290 MACROITEM STEM 2For the following items select from the key that portion of the 2curve in the diagram which furnishes the desired information. 2The relationships between the addition or removal of heat and the 2consequent changes in the temperature and physical state of 210 grams of water may be represented schematically as follows 2 * 2 * g 2 * 2 | * 2 100 |___________________________**************** 2 t | *| e f| 2 e | *| | 2 m | * | | 2 p | * | | 2 | * | | 2 d | b c * | | 2 e 0 |___****************** | | 2 g | *| | | | 2 |*| | | | 2 C _10 |* | | | | 3 __________________________________________________ 2 a 50 850 1850 7250 2 heat (calories) ___________________________________________________________ 2 A. a b 2 B. b c 2 C. c e D. e f 0 E. f g MACRO SUB_ITEM # 1 1 The heat of fusion MACRO SUB_ITEM # 2 2 The heat of vaporization MACRO SUB_ITEM # 3 3 The specific heat equals 1 cal./gm./deg. C. MACRO SUB_ITEM # 4 4 The volume change is The greatest MACRO SUB_ITEM # 5 the vapor pressure and atmospheric pressure are approximately 9 equal ETS2WVW 1950019 C 15 19633 31 05030493800111 The principle of most direct significance in the operation of mechanical refrigeration is that A. evaporation is a cooling process B. it is impossible to convert heat wholly into work C. cooling results when a vapor expands against the attractive forces between the molecules D. the volume occupied by a given mass of gas is inversely proportional to the pressure applied 9 E. none of the above applies to refrigerators ETS2 OS 1950020 A 15 19639 51 05150412800111 Substances do not deliquesce unless A. the vapor pressure of their concentrated aqueous solutions is less than the pressure of the water vapor in the atmosphere B. their vapor pressure is less than the pressure of the atmosphere C. they form dilute solutions which are saturated D. they give off water of hydration E. they are present in an atmosphere the humidity of 9 which is 100 percent ETS2 OS 1950021 C 15 19645 52 03930394800111 Gasoline, a mixture of hydrocarbons, burns to carbon dioxide and water. In order to maintain a dirigible, or lighter_than_air airship, at a constant weight, the procedure used is to condense water vapor present in the exhaust gases from the engines and allow the co2 to escape. However, only about 70% of the water vapor need be condensed. Why? A. Water is denser than gasoline. B. Dirigibles filled with helium are heavier than those filled with hydrogen. C. The water contains oxygen from the atmosphere. D. Gasoline is about 70% carbon. 9 E. The gasoline is not completely burned in the engines. ETS2 OS 1950022 A 15 19654 51 01820113800111 Activated charcoal A. is used in gas masks because it absorbs gases with high critical temperatures B. catalyzes the oxidation of poison gas by air C. is used to improve the wearing qualities of tires D. is used to reduce iron ore to iron 9 E. is used in gunpowder ETS2 OS 1950023 D 15 19658 31 04820113800111 The spontaneous process whereby two gases intermingle so as to form a homogeneous mixture is known as A. cohesion B. sublimation C. condensation D. diffusion 9 E. osmosis ETS2 OS 1950024 B 15 19661 31 04880489800111 Osmosis is A. another name for dialysis B. the flow through a semipermeable membrane of solvent from dilute to concentrated solutions C. the flow, as above, from concentrated to dilute solutions D. the rise of liquids in tubes by capillary attraction 9 E. the flow of ions through the membrane of the primary cell ETS2 OS 1950025 ABCEDE 65 19666 31 0020022480011190 MACROITEM STEM 2To answer the following questions, select from the key the idea most 2closely related to that expressed by each question. 2 A. Valence 2 B. Radical 2 C. Compound formation 2 D. Formula of a compound 0 E. None of these MACRO SUB_ITEM # 1 1 The number of electrons lent, borrowed, or shared MACRO SUB_ITEM # 2 Certain atoms within a molecule are held together by 2 Sharing electrons and behave as a unit MACRO SUB_ITEM # 3 3 The number of electrons lent must equal The number borrowed MACRO SUB_ITEM # 4 4 A combination of two atoms of an element MACRO SUB_ITEM # 5 5 The total plus valence must equal The total negative valence MACRO SUB_ITEM # 6 9 A charged atom ETS2 OS 1950026 BDABCD 65 19674 32 0020019680011190 MACROITEM STEM 2Select from the key the most closely related description. 2 A. Valence of zero ETS2 OS 2 2 2 0 B. Acquires or has a positive valence C. Acquires or has a negative valence D. Shares electrons E. Shares electrons and may form chains MACRO SUB_ITEM # 1 1 The behavior of hydrogen in the formation of water MACRO SUB_ITEM # 2 2 Carbon MACRO SUB_ITEM # 3 3 Neon MACRO SUB_ITEM # 4 4 An element which lends electrons MACRO SUB_ITEM # 5 The SO radical 54 4 MACRO SUB_ITEM # 6 9 The formation of gas molecules 1950027 CBEE 45 19680 32 0020026380011190 MACROITEM STEM 2Select from the key the most closely related description. 2 A. Acquires or has a positive valence 2 B. Acquires or has a negative valence 2 C. Valence of zero 2 D. Shares electrons and may form chains 0 E. Shares electrons MACRO SUB_ITEM # 1 1 Argon MACRO SUB_ITEM # 2 2 An element which borrows electrons MACRO SUB_ITEM # 3 3 The formation of hydrogen molecules MACRO SUB_ITEM # 4 9 The formation of water molecules 1950028 EBCE 45 19685 31 MACROITEM STEM The following questions involve the highest oxidation state of the 3 _______ elements. For each element select the proper highest oxidation state. 0 A. +1 B. +2 C. +3 D. +4 E. +5 MACRO SUB_ITEM # 1 1 Phosphorus MACRO SUB_ITEM # 2 2 Calcium ETS2 OS OS85 MACRO SUB_ITEM # 3 3 Aluminum MACRO SUB_ITEM # 4 9 Vanadium 1950029 E 15 19689 51 03510293800111 A group of atoms within a molecule which are held together by sharing electrons and which behave as the unit during chemical reaction is termed A. a compound B. a mixture C. a salt D. an alloy 9 E. a radical ETS2 OS 1950030 D 15 19693 31 02930351800111 The formation of molecules through combination of atoms does not occur in 3 ___ A. oxygen B. hydrogen C. nitrogen D. helium 9 E. iodine ETS2 OS 1950031 ACBDAC 64 19696 32 0014048080011490 MACROITEM STEM 2The following questions contain pairs of statements which are 2either in agreement with other or not in agreement, and either 2one of the statements may be true or false. For each item select 2from the key the correct response. 2 A. Statement I and II are in agreement and both false. 2 B. Statement I and II are in agreement and both true. 2 C. Statement I and II are not in agreement; I true, II false. 0 D. Statement I and II are not in agreement; I false, II true. MACRO SUB_ITEM # 1 I. Carbon is always of positive valence. 1 II. Carbon always lends electrons in chemical reactions. MACRO SUB_ITEM # 2 I. the activity of rock folding in the lithosphere has never been observed. II. The deformation (rock folding) takes place too rapidly to be 2 observed. MACRO SUB_ITEM # 3 I. At absolute zero the molecules of a substance do not move with respect to each other. ETS2 OS 3 II. No heat energy is possessed by a substance at absolute zero. MACRO SUB_ITEM # 4 I. If an air mass expands isothermally, its temperature will rise. 4 II. Heat must be added in the isothermal expansion of air. MACRO SUB_ITEM # 5 I. If a metal is oxidized its valence is lowered. 5 II. An oxidizing agent lends electrons to the metal it oxidizes. MACRO SUB_ITEM # 6 I. Any body having mass possesses inertia. II. The gravitational pull of the earth determines the mass of a 9 body. 1950032 A 14 19713 31 040703518004 Chemical reactions occur in part because every atom A. tends to complete its outer electron shell B. contains an even number of electrons C. contains an odd number of protons 9 D. requires another atom 2WVW 1950033 D 14 19716 31 025805558004 Diffusion of one substance through another can usually be hastened by one or several of the following means. By which means, however, would diffusion tend to be retarded? A. Heating B. Agitation C. Rarefaction 9 D. Freezing 2WVW 1950034 A 14 44992 31 029302588004 Two groups of molecules are in a fluid state. One moves through the other. The process is called A. diffusion C. respiration E. separation 9 B. mitosis D. excretion 2WVW 1950035 B 15 44396 32 5 + A solution which contains K , when subjected to the Bunsen flame test produces a color which is 9 A. yellow B. violet C. crimson D. green E. orange 1950036 DABC 45 19724 31 0484025880011190 MACROITEM STEM 2To answer the following questions, indicate the most closely related 2word or phrase from the key below. 2 A. Condensation 2 B. Crystallization ETS2 OS 2 C. Diffusion 2 D. Distillation 0 E. Evaporation MACRO SUB_ITEM # 1 1 A process in which a liquid is changed to a gas and back again MACRO SUB_ITEM # 2 2 A change of state from a gas to a liquid MACRO SUB_ITEM # 3 The formation of a definite arrangement of molecules, atoms, 3 or ions MACRO SUB_ITEM # 4 The process by which a substance is equally distributed through 9 all parts of another substance 1950037 CA 25 44512 31 MACROITEM STEM For each of the practices or observations indicate from the following list the kind of change involved: A. oxidation_reduction B. ionization C. neutralization D. physical change 0 E. precipitation MACRO SUB_ITEM # 1 1 Use of soda to relieve distress after over_eating MACRO SUB_ITEM # 2 9 Discoloration of fruit which is left in open air 1950038 D 14 19731 31 80038004 When a lighted splint is placed in a tube of carbon dioxide, the splint A. glows brightly B. causes a loud pop C. remains the same 9 D. goes out 2WVW 1950040 B 14 19734 31 078703518004 The process by which two or more separate kinds of atoms or molecules mix because of their atomic or molecular motion is A. adsorption B. diffusion C. occusion 9 D. absorption 2 OS 1950041 A 14 19737 32 000900148004 A small sample of iron sulfide is changed to a powder and shaken 2 OS with carbon disulfide. This results in A. no change B. the solution of the sulfur C. the solution of the iron 9 D. the production of hydrogen sulfide 1950042 C 14 19741 31 009403028004 Burning sulfur produces a substance whose odor is A. like that of rotten eggs B. like that of boiled cabbage C. choking 9 D. bitter 2 OS 1950043 C 14 19743 31 The tarnish on silver is silver A. oxide B. hydroxide C. sulfide 9 D. sulfate 2 OS 079901258004 1950044 B 14 19745 31 003200948004 A piece of copper strip inserted into the hot vapors of sulfur reacts in a manner which shows sulfur A. burns B. supports combustion C. is a reducing agent 9 D. readily solidifies 2 OS 1950045 D 14 19748 31 009403518004 The type of sulfur composed of long chains of sulfur atoms is A. rhombic sulfur B. monoclinic sulfur C. lambda_sulfur 9 D. mu_sulfur 2 OS 1950046 B 14 19750 31 009408008004 Slow cooling of carefully melted sulfur produces A. rhombic sulfur B. monoclinic sulfur C. plastic sulfur 9 D. lac sulfur 2 OS 1950047 A 14 19752 31 001400948004 The form of sulfur prepared by evaporation from a carbon disulfide solution is A. rhombic 3 OS 9 B. monoclinic C. plastic D. amorphous 1950048 B 14 19754 31 040305358004 Solid iodine produces a solution with a deep brown color when dissolved in A. water B. alcohol C. carbon tetrachloride 9 D. carbon disulfide 2 OS 1950049 B 14 19757 31 018904038004 The element which may be collected as a solid on the bottom of a cooled dish is A. fluorine B. iodine C. bromine 9 D. chlorine 2 OS 1950050 D 14 19759 31 024400948004 Crystalline sulfur is readily soluble in A. cold water B. hot water C. alcohol 9 D. carbon disulfide 2 OS 1950051 C 14 19761 31 016100948004 The temperature at which melted sulfur becomes so thick that it hardly flows from an inverted tube is aproximately 5 o o o o 9 A. 96 C B. 115 C C. 250 C D. 445 C 2 OS 1950053 C 14 19764 31 019008138004 Any hydrate may be converted to the anhydrous form by A. recrystallization B. evaporation from solution C. heating 9 D. exposing it to air 2 OS 1950054 C 14 19767 31 003201098004 The black deposit formed when a piece of copper is heated in air is A. soot B. carbon C. cupric oxide 2 OS 9 D. cupric hydroxide 1950055 B 14 19769 31 045804458004 As blue cupric sulfate is heated its weight A. increases B. decreases C. remains the same 9 D. increases in direct proportion to the rising temperature 2 OS 1950056 C 14 19772 31 016901138004 When a solid is changed to a gas, without melting, the process is called A. diffusion B. boiling C. sublimation 9 D. osmosis 2 OS 1950057 C 14 19774 31 011301618004 In order for a gas to be liquefied it must be A. above its critical temperature and above its equilibrium vapor pressure B. above its critical temperature and below its equilibrium vapor pressure C. below its critical temperature and above its equilibrium vapor pressure D. below its critical temperature and below its equilibrium 9 vapor pressure 2 OS 1950058 B 14 19780 31 000804048004 A water solution of chlorine exposed to sunlight A. explodes B. liberates oxygen C. liberates hydrogen 9 D. forms a peroxide 2 OS 1950059 D 14 19782 31 019604048004 A jet of hydrogen will burn in chlorine and form A. water B. ammonia C. carbon dioxide 9 D. hydrogen chloride 2 OS 1950060 B 15 44654 31 000801748004 Water with temporary hardness A. will lather with soap after standing a while B. may be softened by boiling 2 OS 9 C. cannot be softened by washing soda D. regains its hardness quickly E. may be softened by thawing out 1950061 D 14 19787 31 006700778004 A property of a material determined by its behavior when heated with an acid is described as A. its melting point B. its boiling point C. a physical property 9 D. a chemical property 2 OS 1950062 A 14 19790 31 000802448004 The presence of water of crystallization in a compound may be detected by A. heating B. dissolving C. feeling 9 D. weighing 2 OS 1950063 D 14 19792 31 019600258004 When hydrogen is mixed with oxygen at ordinary temperatures, what happens A. an explosion occurs B. a hydride is formed C. water is formed 9 D. there is NO apparent reaction 2 OS 1950064 D 14 19795 31 082606688004 When a student introduced some barium chloride into the flame of his Bunsen burner, the flame became green in color. This result is best explained by the fact that A. chlorine is a green_colored gas B. chlorine is an oxidizing agent C. an atom of barium has more electrons than an atom of chlorine D. when electrons return to a lower energy level, radiant 9 energy may be emitted 2 OS 1950065 D 14 45028 31 010801968004 If an electric spark were passed through a tube filled only with hydrogen A. the hydrogen would explode B. the hydrogen would condense C. water vapor would form D. no chemical reaction would occur 2 OS 9 E. the hydrogen will decompose into simpler substances 1950066 B 14 19804 31 009400328004 When sulfur and copper are heated together A. copper sulfate is formed B. copper sulfide is formed C. copper sulfite is formed 9 D. no reaction occurs 2 OS 1950067 A 14 19807 31 002700168004 A solution of zinc chloride should not be stored in a tank made of A. aluminum B. silver C. copper 9 D. lead 2 OS 1950068 D 14 19809 32 025808328004 Which one of the following is an example of diffusion A. the flow of water in a river B. movement of traffic on a busy highway C. raindrops falling from clouds 9 D. apparent disappearance of smoke from a candle 2 OS 1950069 B 15 44858 32 029305298004 Molecules of dye can move at the rate of 200 miles per hour but they may actually require weeks to diffuse an inch up a tube of water. This phenomenon can be accounted for A. because the dye molecules move upward slowly due to the pull of gravity B. because other molecules impede upward movement of the dye molecules by colliding with them and changing the direction of their motion C. because the walls of the tube retard diffusion of the dye D. because of adhesion between dye molecules 9 E. because of the hydrophobic nature of dye molecules 2 OS 1950070 D 14 19819 32 019202588004 Of the following substances, the one least likely to enter a typical cell in significant amounts by the process of diffusion is A. oxygen B. glycerol C. nitrate ion 9 D. a protein 2 OS 1950071 D 14 19822 31 048801128004 Osmosis occurs whenever A. there is a solution involving two substances of different molecular weights B. one substance is dissolved in another, with a membrane between two parts of the solution C. a membrane separates two regions of a fluid D. a membrane permeable to solvent but not to solute separates 9 two differently concentrated regions of the solvent 2 OS 1950072 C 15 19828 32 012502488004 Silver tarnishes when it reacts with A. ammonia C. hydrogen sulfide E. water 9 B. carbon dioxide D. nitrogen 2 OS 1950073 A 14 19830 32 036401598004 According to einstein, the release in energy in a chemical reaction is accompanied by a decrease in mass. This loss in mass in the usual laboratory demonstration A. is much too small to be measured B. is readily measurable C. was satisfactorily explained prior to einstein's contribution 9 D. was found only after einstein's contribution 2 OS 1950074 B 15 19835 31 064704630154 Which one of the following is not an example of a chemical 3 ___ change? A. souring of milk B. dissolving of salt in water C. rusting of iron D. burning of oil 9 E. digestion of a candy bar 0028 1950075 A 15 19839 31 06470157 Which one of the following is not an example of a physical 3 ___ change? A. burning of coal B. removing coal from underneath the ground C. cutting of wood D. tearing a piece of paper 9 E. spilling a quart of milk 0028 1950076 C 0019 15 19843 31 01540302 Which one of the following describes a chemical change? A. boiling of water B. adding sugar to water C. burning of wood D. melting of lead 9 E. evaporation of sea water 1950077 C 15 19846 31 1044 An explosive is a substance which A. reacts with oxygen B. always contains chlorine C. decomposes almost instantaneously upon shock D. contains ammonia 9 E. no correct response is given. 0040 1952001 D 15 19849 51 01540164800112 Which one of the following is the best example of a chemical change? A. the disappearance of dry ice B. adding alcohol to water C. evaporating salt water D. chlorination of drinking water 9 E. distilling water ETS2 OS 1952002 E 15 19853 51 00060013800111 Chlorine A. unites with hydrogen to form the hydrogen halide of greatest stability B. can be made by electrolysis of its compounds with the nonmetallic elements C. unites with hydrogen by a chain reaction D. loses electrons more easily than bromine E. is often produced commercially by the electrolysis of 9 molten potassium chloride ETS2 OS 1952003 B 15 19858 51 00570043800111 Sulfur dioxide A. is a stable compound whose density is almost equal to that of oxygen B. is obtained by the combustion of iron pyrites C. yields a monoprotic acid when it dissolves in water D. is only liquefied with great difficulty 9 E. contains sulfur with an oxidation state of +2 ETS2 OS 1952004 C 15 19863 51 01820183800111 Charcoal is made by a process known as ETS2 OS 9 A. carbonation B. organic synthesis C. destructive distillation D. hydration E. oxidation 1952005 B 15 19865 51 01840185800111 The Cottrell process is A. a method of preparing colloids B. a method of imparting a charge to particles, suspended in the air, SO that they are driven to a plate of opposite charge C. a method of dialysis D. a method of increasing the humidity of the air E. an interesting theoretical method of precipitating colloids, 9 but one that has NO practical application 1952006 D 15 45022 51 Two different molecular forms of the same element are called A. isotopes C. different oxidation states E. compounds 9 B. isomers D. allotropes 1952007 B 15 19871 31 01090497800111 Moving air seems cooler to a person than still air, because A. moving the air gives it a lower temperature B. moisture from the body is evaporated more rapidly C. impact of air on the face give the impression of coolness D. moving air has the greater specific heat 9 E. still air has the greater specific heat 1952008 AEED 45 19876 51 1 045201099005119095 MACROITEM STEM 2The following questions refer to Figure 5. In the Linde 2process for making liquid air, the gas, thoroughly 2freed from water vapor, is first compressed to a high pressure 5 2 (some 2000 lbs./in. ) by a pump (p in Figure 5). It is then 2cooled in an ice_water bath w. The cool air then passes 2into an expansion chamber e, being driven through the inner of 2two tubes and escapes at the bottom through a small adjustable 2hole h. It is drawn back through the outer tube by the suction 2side of the double_acting pump. The expansion cools the air. 2Thus the incoming stream of air is cooled by the outgoing one, 2and this cooling process is progressive, so that, if heat is 2prevented from getting into the expansion chamber from outside, 2the expanding air eventually cools itself to a temperature 2below its boiling point, when drops of liquid form by condensation ETS2 OS ETS2 OS ETS2 OS 2and fall into the vacuum vessel at the bottom, where it is kept 2until needed. Using this information, answer the 0 following questions. MACRO SUB_ITEM # 1 Which of the following occurs when the incoming air is compressed? A. The temperature of the air increases. B. Power is produced to run generators. C. The air is immediately liquefied. D. The temperature of the air decreases. 1 E. Oxygen is separated from nitrogen. MACRO SUB_ITEM # 2 The cooling effect of the expansion of the air is a phenomenon which A. occurs only because the temperature is already at a low point. B. is a peculiarity of air. C. occurs because the gas was originally under a low pressure. D. is caused by a liquefaction of part of the air. 2 E. occurs when any gas expands. MACRO SUB_ITEM # 3 The principal reason for removing water vapor from the incoming air is to A. produce pure liquid air B. prevent formation of rust in the apparatus C. prevent formation of steam which would cause deterioration of the piston in p D. prevent formation of ice which would cause the water in w to change to ice 3 E. prevent formation of ice which would clog the air tubes MACRO SUB_ITEM # 4 The main purpose for the liquefaction of air is to A. produce nitrogen for commercial use B. produce oxygen for commercial use C. produce liquid air for commercial refrigeration D. attain extremely low temperatures 9 E. demonstrate that air can be liquefied 1952009 A 14 19906 31 081501898004 Lamps used for roadway illumination contain vapor of the element A. sodium B. potassium C. lithium 9 D. magnesium 2 OS 1952010 A 14 45025 31 019600238004 Electric light bulbs may be frosted by exposing the inside surface to 2 OS 9 A. hydrogen fluoride C. cryolite E. ice B. freon D. hydrogen iodide 1952011 B 15 19910 31 000800238004 Drinking water is subjected to fluoridation in order to A. destroy bacteria B. prevent tooth decay C. prevent goiter D. destroy portions of the enlarged thyroid 9 E. improve the taste 2 OS 1952012 B 14 19913 32 043801138004 The cooling effect of an electric refrigerator is due to the following change of state A. gas to liquid B. liquid to gas C. liquid to solid 9 D. solid to gas 2 OS 1952013 A 14 19916 31 128400150351 When they combine chemically with metal atoms, nonmetal atoms A. gain electrons to become negative ions B. lose electrons to become positive ions C. remain electrically neutral D. form van der Waals bonds 9 E. are reduced 0041 1952014 C 14 19920 51 015903510159 Chemical energy is stored within atoms, molecules, and ions as A. activation energy B. electron kinetic energy 9 C. electron potential energy D. thermal energy 0041 1952015 A 14 19923 31 009401091331 The combustion of sulfur produces predominately A. SO B. SO C. H SO D. S O E. H S 94 2 3 2 3 23 2 0043 1952016 B 15 19925 31 01540600 C H O + heat _____> 12 C + 11 H O 4 12 22 11 2 What type of ordinary chemical reaction is depicted by the above equation? A. combination B. decomposition C. replacement 9 D. halogenation E. neutralization 1952017 D 14 19929 31 015401570135 0028 0026 Which of the following is a chemical change? A. the purification of alcohol by distillation B. freezing of water C. dissolving of sodium chloride in water 9 D. tarnishing of silver dinnerware. 1952018 B 15 19932 32 016501540834 Which of the following involves a chemical change? A. melting ice B. burning paper C. magnetizing an iron bar D. sawing a piece of wood 9 E. extracting cream from milk 1952019 E 15 19935 32 01571213 An example of a physical change is A. souring of milk B. burning of paper C. digestion of food D. rusting of iron 9 E. none of these 0020 0020 1952020 C 15 19938 31 015401350834 Which of the following is not a chemical change? 3 ______ A. burning of magnesium B. exploding of some nitroglycerine C. pulverizing of some sulfur D. rusting of iron 9 E. neutralization of an acid 0040 1952021 D 15 19942 31 015702930407 When a substance undergoes a physical change it is always true that A. it melts. B. a new substance is produced. C. heat is evolved. D. the molecules of the substance remain unchanged. 9 E. gas is given off. 0040 1952022 D 15 19945 31 015701540653 Which of the following represents a physical change in matter? A. Ice melts. B. A solid is crushed. C. A substance burns. D. Both A and B 0040 9 E. both A and C 1952023 D 15 45203 51 All of the following reactions are described as decomposition reactions EXCEPT: A. 2KClO (s) ___> 2KCl(s) + 3O (g) 4 3 2 B. HCOOH(l) ___> H O(l) + CO(g) 4 2 C. 2HgO(s) ___> 2Hg(l) + O (g) 4 2 D. POCl (l) + 3H O(l) ___> H PO (aq) + 3HCl(aq) 4 3 2 3 4 E. Ni(CO) (l) ___> Ni(s) + 4CO(g) 94 4 1952024 A 15 45209 71 All of the following reactions are called combination reactions EXCEPT: A. Cl (g) + H O(l) ___> HOCl(aq) + HCl(aq) 4 2 2 B. MgO(s) + CO (g) ___> MgCO (s) 4 2 3 C. C H (g) + Br (l) ___> C H Br (l) 4 24 2 24 2 D. CuSO (s) + 5H O(l) ___> CuSO . 5H O(s) 4 4 2 4 2 E. 3H (g) + N (g) ___> 2NH (g) 94 2 2 3 1954001 A 14 19948 31 031703510527 The chief cause of the repulsive force that keeps atoms from meshing together despite any attractive forces that may be present is A. electrostatic repulsion between the electrons B. the uncertainty principle C. the exclusion principle 9 D. conservation of energy 0041 1954002 E 15 19952 31 018903511305 The smallest part of an element that can enter into combination with other elements is A. a molecule B. a gram C. a mole D. the electron 0020 9 E. an atom 1954003 E 15 19955 32 019213060413 A substance that cannot be decomposed by chemical means is A. sugar B. air C. water D. salt 9 E. mercury 0020 1954004 A 15 19957 31 049501890351 The smallest particle of an element that can enter into combination with other elements is A. an atom B. a crystal C. a solid D. a molecule 9 E. none of these 0020 1954005 E 15 19960 31 058305130293 Dalton's Atomic Theory, as modified by subsequent discoveries, says A. atoms unite to form molecules B. all matter is made up from atoms C. all atoms of the same element have a limited number of mass values D. an element is made up of similar atoms 9 E. all of above 0020 1954006 C 14 19964 31 018903510185 An element is: A. a collection of atoms with identical numbers of neutrons B. a collection of atoms with identical nuclear masses C. a collection of atoms with identical nuclear charges 9 D. one of the following: air, earth, fire, water 0009 1954007 C 14 19968 31 052714360462 What kind of force holds an electron in the vicinity of the nucleus of an atom? A. gravitational B. magnetic 9 C. electrical D. the chemical bond 0009 1954008 D 15 19971 31 03510342 The fundamental nature of the atom, that is, the factor or factors which seem(s) to distinguish it from all other kinds of atoms is A. the charge of the electrons in the electron cloud. 0035 9 B. the atomic weight of the atom. C. the charge of the neutrons within the atom. D. the positive charge on the nucleus of the atom. E. more than one of the above. 1954009 B 15 19976 32 035103420263 An atom has 3 protons and 4 neutrons in its nucleus. The number of electrons in its orbitals is 9 A. 4 B. 3 C. 7 D. 12 E. unpredictable. 0035 1954010 C 15 19978 31 035113010263 The chemical nature of the atom is determined by the A. atomic weight. B. number of neutrons. C. number of electrons. D. weight of the protons. 9 E. size of the neutrons. 0035 1954011 C 15 19981 31 141405130351 Which one of the following statements about atomic theory is incorrect? A. There are particles in the nucleus which add mass to the atom but do not affect the electrical charge. B. The volume of an atom is not determined by the space occupied by the nucleus. C. Each atom is composed of a negatively charged nucleus. D. Almost the entire mass of the atom is concentrated in the nucleus. E. The atomic number of an atom is the same numerically as the 9 number of protons in the nucleus. 0035 1954012 A 15 19988 31 033701890263 Given only the atomic number of an element, which of the following quantities could you find? A. The number of electrons. B. The atomic weight. C. The number of neutrons in the nucleus. D. The number of isotopes. 9 E. All of the above. 0035 1960001 C 15 19992 31 03510463800111 The chemical nature of the atom is determined by the A. atomic weight B. number of neutrons C. number of electrons D. weight of the protons ETS2 OS 9 E. size of the neutrons 1960002 A 15 19995 32 02920445800111 Avogadro's Law is of importance in the A. determination of the relative weights of molecules B. prediction of solar eclipses C. determination of the pressure of a gas when the temperature is known D. prediction of intensity of discharge of electrons across a spark gap E. determination of the rate of disintegration of radioactive 9 substances ETS2 OS 1960003 D 15 20001 31 03510097800113 If an atom containing 3 protons and 4 neutrons combines with a second atom with 9 protons and 10 neutrons, the ion of the second atom in the compound will have A. 12 protons B. 4 protons C. 10 protons D. 9 protons 9 E. none of these ETS2 OS 1960004 DACCBAE 75 20005 51 0513051180011290 MACROITEM STEM 2The following questions involve certain theoretical principles. 2Select from the key the most closely related principle. 2 A. Atomic theory 2 B. Kinetic Theory 2 C. First law of thermodynamics 2 D. Adiabatic change 0 E. Isothermal change MACRO SUB_ITEM # 1 An increase in volume of a gas without adding heat from An external 1 source. MACRO SUB_ITEM # 2 2 Atoms combine in simple ratios by weight. MACRO SUB_ITEM # 3 The heat from burning food could be transformed into mechanical 3 energy. MACRO SUB_ITEM # 4 The ratio of the work in joules to the heat in calories is a 4 constant. MACRO SUB_ITEM # 5 Molecules are perfectly elastic and rebound without energy loss 5 after collision. ETS2 OS MACRO SUB_ITEM # 6 6 The smallest particle of an element taking part in a reaction. MACRO SUB_ITEM # 7 A decrease in pressure of a gas with the addition of heat from an 9 external source so that PV = k. 1960005 E 15 20015 52 02920195800111 Avogadro's Law A. led to the discovery of the law of combining volumes B. states that at S.T.P. equal volumes of all gases contain equal numbers of atoms C. states that the product of the molecular weight and the specific heat of all gases at S.T.P. is approximately 6 D. states that the avogadro number is 22.4 E. explains why the volumes of reacting gases are in the ratio 9 of small whole numbers ETS2 OS 1960007 D 15 20021 52 00310407800112 In chemical equations where two gases combine to form a gaseous product, the relationship of the volumes of the reacting substances to that of the product formed is shown by the A. molecular weight B. subscripts C. equality between the sum of the volumes of reactants and the volume of the product D. ratios of the coefficients 9 E. valence of the substances ETS2 OS 1960008 C 15 20027 52 071101 Given two pure substances (I and II) containing elements A and B. Substance I has a mass of 2.25 g and contains 0.900 g of B. Substance II is analyzed as 40.0% B and 60.0% A by weight. These data A. illustrate the law of multiple proportions B. prove that either I or II is an element C. illustrate the Law of Definite Composition D. prove that either I or II is a mixture E. show that the formulas of I and II are AB and AB 94 3 1960009 E 15 20034 32 01960404800112 Since one volume of hydrogen reacts with one volume of chlorine to produce two volumes of hydrogen chloride A. one molecule of each of the reacting elements combine to form one molecule of hydrogen chloride B. each molecule of hydrogen chloride contains two atoms of 0064 ETS2 OS 9 hydrogen C. the volume of a gas produced in any reaction is equal to the sum of the volumes of the gaseous reactants D. the relation is an example of the law of combining weights E. one molecule of hydrogen reacts with one molecule of chlorine to form two molecules of hydrogen chloride 1960010 A 14 20042 32 082908068004 In double replacement, the reaction will go to completion if A. one of the products is a gas B. one of the products is soluble C. one of the products ionized 9 D. the products formed are highly ionized 2 OS 1960011 C 15 20045 31 051302650351 Atoms are generally believed in because of A. many direct observations of them B. one chemical law which indirectly verifies their existence C. several chemical laws which indirectly verify their existence D. the periodic table relationships 9 E. chemical reactions occur. 0040 1960012 D 15 20049 31 051313200345 Which of the following pieces of evidence support our belief in atoms? A. Law of multiple proportions B. Law of constant composition C. Law of conservation of matter D. both A and B 9 E. both B and C 0040 1960013 B 14 20052 52 1682 0961 Of the following natural laws, that with the least application to chemistry is the law of A. conservation of energy B. conservation of momentum 9 C. conservation of mass D. definite proportions 1962001 C 15 20055 32 02640265800111 At the present time, the law of conservation of mass is actually A. a theory B. a hypothesis C. a law in itself D. a special case of a more general law 9 E. none of these 0041 ETS2 OS 1962002 B 15 20058 32 00420031026411 The equation Mg + O ___> MgO is incorrect because 4 2 it is not in accord with A. Avogadro's law B. the law of conservation of mass C. the law of definite proportions D. the law of multiple proportions 9 E. Boyle's law ETS2 OS 1962003 E 15 20062 31 015904230284 The energy an object possesses due to its relative position is: A. radiant energy B. electrical energy C. chemical energy 9 D. kinetic energy E. potential energy 0028 1962004 A 14 20065 31 001500451323 When a piece of metal is oxidized, the resulting oxide is A. heavier than the original metal B. the same weight as the original metal C. lighter than the original metal D. sometimes heavier and at other times lighter, depending upon 9 the metal 0041 1964001 D 15 20069 52 01760066800111 CuSO . 5H O is considered a chemical compound because 4 4 2 A. it gives off water when heated B. when it is powdered it loses its characteristic blue color C. the water in the compound evaporates rapidly D. it always contains 5 molecules of water per molecule of CuSO 4 4 9 E. it becomes opaque when heated ETS2 OS 1964002 E 15 20075 51 01960025800112 An electric spark is passed through a mixture containing 16 grams of oxygen gas and 4 grams of hydrogen gas. After the explosion, there is in the container A. 16 grams of water and 4 grams of hydrogen B. 8 grams of water and 12 grams of oxygen C. 6 grams of water and 14 grams of oxygen D. 20 grams of water 9 E. 18 grams of water and 2 grams of hydrogen ETS2 OS 1964003 D 15 20080 51 01970198800112 In the formation of CaO, the relative combining weights are 5 gm. of Ca to 2 gm. of O. If 10 gm. of Ca and 6 gm. of O are taken ETS2 OS for the experiment, A. no reaction should occur B. the per cent of oxygen in the CaO would be greater C. CaO should be formed 4 2 D. some oxygen is left after CaO is formed 9 E. the extra oxygen acts as a catalyst 1964004 C 14 20085 31 026505688004 The Law of Definite Proportions applies to the definite compositon by weight of A. atoms B. elements C. compounds 9 D. mixtures 2 OS 1964005 E 15 20087 52 070401980288 Two compounds are formed from the elements A and B. One of the compounds is 25% A and 75% B by weight. The other compound is 50% A and 50% B by weight. For a fixed weight of A in the two compounds, the ratio of the weights of B in the two compounds is 9 A. 4:3 B. 1:1 C. 2:3 D. 1:2 E. 1:3 0026 1964006 B 15 20091 32 026113180345 Carbon dioxide is always found to contain 27.3 percent of carbon. This statement obeys the law of A. multiple proportions B. constant composition C. Einstein D. conservation of mass_energy 9 E. all of these 0020 1964007 C 15 20094 31 006601891320 The existence of two different compounds composed of the same two different elements is explained by A. the law of definite composition B. the law of constant composition C. the law of multiple proportions D. Avogadro's law 9 E. all of the above 0020 1964008 C 14 20098 31 026501891320 The law that relates the different weights of one element that combine with a fixed weight of another element is the law of A. conservation of matter B. constant composition 9 C. multiple proportions D. equivalent proportions 0009 1964009 C 15 20102 52 003200061284 Copper and chlorine combine in different ratios to yield more than one compound. In one, 1.792 g of copper combine with 1.000 g of chlorine. Which of the following might represent the mass of copper combining with 1.000 g of chlorine in another compound: 9 A. 2.792 g B. 1.000 g C. 0.896 g D. 0.792 g E. none of these 0019 1964010 B 15 20107 31 051313200307 The law of multiple proportions is an example of evidence supporting the atomic theory. This law provides what type of evidence? A. Direct evidence B. Indirect evidence C. Direct observation of atoms D. both A and C 9 E. both B and C 0040 1964011 C 15 20111 31 040803450513 Sodium chloride, NaCl, is 39% Na and 61% Cl everywhere pure NaCl is found. This means that NaCl obeys the law of A. multiple proportions B. conservation of matter C. constant composition 9 E. conservation of momentum 0040 1964012 C 15 20115 31 034505130568 Which law states that a particular substance always has the same elements present in the same proportions by weight? A. Law of multiple proportions B. Law of conservation of matter C. Law of constant composition D. Law of conservation of energy 9 E. Law of gravity. 0040 1964013 B 15 20119 32 034505131097 Which of the following would be most useful to you if you wanted to verify the law of constant composition? A. Analysis information about two compounds that contains the same elements in different proportions B. A number of samples of a pure compound collected from many locations in the world C. The total weights of the reactants and products of a reaction D. The percentage of each isotope contained in one sample of an element 0040 9 E. The total moles of the reactants and products of a reaction. 1964014 B 14 20127 32 016804070806 A mixture of iron and sulfur was heated until the reaction ceased. When the product was tested with a magnet it was found to be magnetic. A sample of pure iron sulfide was tested with the magnet and found to be non_magnetic. Using this information, state which of the following assumptions would explain the magnetic nature of the product. A. An excess of sulfur is present in the product. B. There was not enough sulfur in the reactants. C. There was not enough iron in the reactants. 9 D. The relative amounts of iron and sulfur are not important. 0035 1964015 C 14 20135 52 019604450189 If it is known that (1) 1.008 g hydrogen reacts with 8.000 g oxygen, (2) 12.15 g of element X reacts with 35.46 g chlorine, and (3) 1.008 g hydrogen reacts with 35.46 g chlorine, it is reasonable reasonable to assume that the weight of element X which will react with 8.000 g oxygen will be 9 A. 24.30 g. B. 1.008 g. C. 12.15 g. D. 35.46 g. 0038 1964016 B 14 20140 31 026501890066 The law that states that the elements making up a chemical compound are always combined in the same weight ratios is called A. The law of conservation of mass B. The law of definite proportions C. Avogadro's law D. the atomic theory 9 E. the Pauli Principle 0041 1964017 A 15 20144 52 071101 Which of the following pairs could be used to illustrate the Law of Multiple Proportions? A. Au O and Au O B. O and O C. Au O and Fe O 4 2 23 2 3 23 23 D. H O and OH E. Au O and AuCl 94 2 2 23 3 0064 1964018 A 15 20148 52 071101 Three different samples containing only elements A and B are analyzed: Sample #1 weighs 24.00 g and contains 3.00 g of B. Sample #2 is 12.5% B by weight. Sample #3 is composed of 11.375 pounds of A and 1.625 pounds 0064 of B. It is likely that: A. all three samples are identical compounds. B. only samples #1 and #2 are identical and #3 is a different compound. C. only samples #2 and #3 are identical and #1 is a different compound. D. each of the three samples is a different compound. 9 E. at least one of the samples is a mixture. 1980001 D 15 20156 32 03150316800112 Krauskopf states that, "electricity and magnetism, just in the fact of their existence, do violence to our intuitive ideas of matter, space, and the nature of force." In making this statement he probably had in mind the fact that A. we cannot formulate laws which can be used to make valid predictions B. they really exist only in our minds as scientific abstractions C. they have not been fruitful in extending research D. they act without contact across intervening space 9 E. they do not alter the space around them 1980002 C 15 20164 51 07148003 The equation governing the deflection of a positive ion under the influence of a magnetic field of strength H in a mass spectrometer is 5 2 m/e = ((Hr) )/2V where m is the mass of the positive ion, e its charge, r the radius of the circular path described by the ion, and V the accelerating electrical voltage. If all the following positive molybdenum ions have been accelerated by the same electrical voltage, V, which one of the ions would be deflected the most from its original line_of_flight under the influence of the magnetic field in a mass spectrometer? A. mass 94, charge +1 B. mass 99, charge +1 C. mass 99, charge +2 D. mass 100, charge +1 9 E. mass 100, charge +2 1980003 B 14 20174 31 001904638004 Ions are A. chemically stable and electrically neutral B. chemically stable and electrically charged C. chemically unstable and electrically charged ETS2 OS 2WVW 2 OS 9 D. chemically unstable and neutral 1980004 B 14 20177 32 001901858004 The ability of an ion to polarize or deform another ion with which it comes in contact will be greatest if it has A. high ionic charge and large radius B. high ionic charge and small radius C. low ionic charge and large radius 9 D. low ionic charge and small radius 2 OS 1980005 A 14 20181 31 035101858004 An atom or group of atoms with an unbalanced electrostatic charge is A. an ion B. a radical C. covalent 9 D. neutral 2 OS 1980006 B 14 20183 31 015902630731 The energy that must be expended in order to remove an electron from an atom is called A. electron affinity B. ionization energy 9 C. valence D. heat of vaporization 0041 1980007 B 14 20186 31 016004621367 Moderate electrical conductivity is exhibited by: A. SiO B. graphite C. diamond D. CO 94 2 2 0043 1980008 D 14 20188 31 09380041 If two objects repel each other A. they are probably unlike charged B. their potential energy increases as they are moved closer together C. their potential energy increases as they are moved further apart 9 D. they must necessarily be like charged. 1980009 D 15 20192 31 017801040192 Good conductors may be defined as substances that have A. high melting and boiling points B. high densities C. the ability to resist the flow of an electric current D. the ability to allow the flow of an electric current 9 E. all of the above 0026 0034 1980010 A 14 20196 52 1946 An ohm is the resistance of a column of mercury 106.3 cm long and 5 2 1 mm cross section at 0 degree C. The resistance of a column of 5 2 mercury 10.63 cm long and 1 cm cross section at 0 degree C is: 5 _3 9 A. 10 ohm B. 0.1 ohm C. 1 ohm D. 10 ohms 0057 2000001 E 15 20200 52 05730351800111 A uranium atom can be seen with A. an ordinary microscope B. a high power microscope C. a 200_in. Telescope D. an electron microscope 9 E. none of these instruments ETS2 OS 2000002 DCCDDACAC94 20203 31 0658066180011490 ETS2WVW MACROITEM STEM 2To answer the following questions, use the key below 2 A. The statement is true but the reason is false. 3 ____ _____ 2 B. The statement is false but the reason is true. 3 _____ ____ 2 C. The statement is true and the reason is true. 3 ____ ____ 2 D. The statement is false and the reason is false. 03 _____ _____ MACRO SUB_ITEM # 1 Low voltage x_rays are more dangerous than high voltage x_rays 1 because they carry more energy. MACRO SUB_ITEM # 2 High voltage x_rays have great penetrating power because they 2 are high energy rays. MACRO SUB_ITEM # 3 Scientists knew that if barium was produced by neutron bombardment of uranium that fission had been attained, because a lighter element 3 had been made from a heavier one. MACRO SUB_ITEM # 4 Scientists knew that in a fission reaction if one neutron caused the release of more than one neutron, a chain reaction would result, because the released neutrons certainly would bring about fission 4 in other atoms. MACRO SUB_ITEM # 5 It is known that under certain conditions of energy, neutrons will bring about fission in any element because the binding energy value 5 of all nuclei is the same. MACRO SUB_ITEM # 6 Gamma rays are more dangerous to the personnel of a nuclear reaction plant than are the beta rays because they are made up of 6 positively charged particles. MACRO SUB_ITEM # 7 The isotopes of an element cannot be separated from each other by chemical methods, because the atomic number of an element is somewhat responsible for an element's chemical behavior and all the 7 isotopes of an element have the same atomic number. MACRO SUB_ITEM # 8 When a neutron is projected into the nucleus of a U_238 atom, it causes the atom to change immediately into a plutonium atom because in a nuclear reactor plutonium is obtained from neutrons bombarding 8 U_238. MACRO SUB_ITEM # 9 Graphite is used as a moderator in a nuclear reactor because 9 graphite is an excellent absorber of neutrons. 2000003 C 15 20228 31 05131649 An important forward step in the development of atomic theory occurred with proof that the atom is mostly empty space. The experimental procedure involved A. the radioactive disintegration of certain substances. B. The Wilson cloud chamber. C. The use of alpha particles to bombard gold foil. D. Aston's mass spectrograph. 9 E. The use of a zinc sulfide fluorescent screen. 2000004 ADCBE 55 20234 52 MACROITEM STEM Match the idea to the person who first put forth the idea A. The mass of the products of a chemical reaction equals the mass of the reactants. B. The composition of natural copper carbonate is the same as that of copper carbonate synthesized in the laboratory. C. Elements are composed of indivisible particles called atoms. D. Electricity, like matter, consists of particles. 0 E. The atom consists of a dense, positively charged nucleus. MACRO SUB_ITEM # 1 1 Lomonosov MACRO SUB_ITEM # 2 2 Stoney MACRO SUB_ITEM # 3 3 Dalton 0035 OS83 MACRO SUB_ITEM # 4 4 Proust MACRO SUB_ITEM # 5 9 Rutherford 2100001 A 15 20241 32 00190066800112 The stability of an ionic compound such as potassium chloride is due to A. the electrostatic force of attraction between the ions B. the difficulty in ionizing further an already ionized atom C. its high energy D. the fact that the formation of the compound is accomplished by the absorption of a considerable quantity of radiation or heat E. the fact that the energy lost in the formation of the negative 9 ion far exceeds that gained in forming the positive ion 2100002 CAB 35 20248 31 0351026380011290 MACROITEM STEM 2A certain neutral atom is composed of 21 electrons, 21 protons, and 224 neutrons. Based on this information, answer the following 0 questions. MACRO SUB_ITEM # 1 What is the approximate relative weight? A. 21 B. 24 C. 45 D. 42 1 E. 66 MACRO SUB_ITEM # 2 What is the atomic number? A. 21 B. 24 C. 45 D. 42 2 E. 66 MACRO SUB_ITEM # 3 Of what element is it an isotope? A. calcium B. scandium C. chromium D. neon 9 E. zinc 2100003 BCBDDABEB95 20254 ETS2WVW MACROITEM STEM 31 0341026380011190 ETS2 OS ETS2 OS 2To answer the following questions, select from the key the correct 2particle. 2 A. neutron 2 B. electron 2 C. proton 2 D. atom 0 E. molecule MACRO SUB_ITEM # 1 1 A particle which travels in elliptical orbits MACRO SUB_ITEM # 2 2 Another name for the hydrogen ion MACRO SUB_ITEM # 3 3 A nearly weightless particle found in all elements MACRO SUB_ITEM # 4 4 The molecule of bromine contains only one of what other particle? MACRO SUB_ITEM # 5 5 A particle particularly important in the kinetic theory MACRO SUB_ITEM # 6 6 A particle not found in a certain one of the known elements MACRO SUB_ITEM # 7 3 ___ ___ 7 A particle discussed in the elementary theories of magnetism MACRO SUB_ITEM # 8 A particle for active gaseous elements, containing exactly 8 two other particles MACRO SUB_ITEM # 9 9 A particle important in the operation of a thermocouple 2100004 C 15 20264 31 03420097800111 The nucleus of an atom consists of A. electrons and protons B. electrons, protons, and neutrons C. protons and neutrons D. electrons and neutrons 9 E. protons only ETS2WVW 2100005 D 14 20267 31 03518001800311 The factor which seems to distinguish an atom of one element from an atom of any other element is A. the charge of the electrons in the electron cloud B. the atomic weight of the atom C. the charge of the neutrons within the atom 9 D. the positive charge on the nucleus of the atom ETS2WVW 2100006 A 15 20271 31 03510579800111 The most common, or so_called "classical method," by which ETS2WVW the inner structure of atoms has been studied, has been by A. bombardment of these atoms with small particles or with high_frequency electromagnetic radiation B. the use of these atoms as projectiles hurled into the nucleus of heavy molecules C. whirling these atoms again and again through an electric field in a cyclotron D. the bombardment of alpha particles from radium with a stream of these atoms E. speeding up these atoms by placing them between two electrodes in an evacuated tube, and giving the electrodes strong charges of opposite sides or 9 polarities 2100007 C 15 20281 31 034103518004 The number of neutrons in an atom whose atomic number is 4 and whose atomic mass is 9 is 9 A. 13 B. 9 C. 5 D. 4 2 OS 2100008 A 15 20283 31 05640342800111 A deuteron is A. the nucleus of heavy hydrogen B. a neutron C. an electron with a positive charge D. an atom of a recently discovered element 9 E. a type of large molecule ETS2WVW 2100009 A 15 20286 An alpha particle is A. a helium nucleus B. an electron C. a radioactive element D. a negative particle 9 E. a hydrogen atom 31 03580340800111 ETS2WVW 2100010 A 15 20288 Radiant energy consists of A. photons B. protons C. neutrons D. positrons 9 E. electrons 31 04640159800111 ETS2 OS 2100011 BDAAB 54 20290 31 80018003 1190 MACROITEM STEM 2After each item number on the answer sheet, blacken space ETS2WVW 2 2 2 0 A. if the item is true of cathode rays only B. if the item is true of positive rays only C. if the item is true of both cathode and positive rays D. if the item is true of neither MACRO SUB_ITEM # 1 Consist of the residue of molecules which have lost one or more 1 electrons MACRO SUB_ITEM # 2 Move toward the electrode which has the same charge as they 2 themselves bear MACRO SUB_ITEM # 3 3 Consist of a stream of electrons MACRO SUB_ITEM # 4 Are identical, irrespective of metal in the anode or cathode 4 or gas in the tube MACRO SUB_ITEM # 5 9 Vary with gas or material in the tube 2100012 CCBDA 55 20298 31 80018003 1190 MACROITEM STEM After each item number on the answer sheet, blacken space 2 A. if the item is true of cathode rays only 2 B. if the item is true of positive rays only 2 C. if the item is true of both cathode and positive rays 0 D. if the item is true of neither MACRO SUB_ITEM # 1 1 Are deflected by magnetic or electrical fields MACRO SUB_ITEM # 2 Magnitude of their charge is either equal to or a multiple 2 of the fundamental charge on the electron MACRO SUB_ITEM # 3 May have a mass equal to that of the proton if the gas in the 3 tube is hydrogen MACRO SUB_ITEM # 4 4 Are uncharged particles MACRO SUB_ITEM # 5 9 Mass is 1/1850 of that of the hydrogen atom 2100013 B 15 20306 31 03510097800112 An atom has 3 protons and 4 neutrons in its nucleus. The number of electrons in the neutral atom is A. 4 B. 3 C. 7 D. 12 9 E. unpredictable ETS2WVW ETS2WVW 2100014 CBADBB 65 20309 31 0351026380011190 MACROITEM STEM 2The following questions refer to particles of matter 2for each item select from the key the most 2appropriate response. 2 A. atom 2 B. electron 2 C. ion 2 D. neutron 0 E. proton MACRO SUB_ITEM # 1 1 A dissociated particle in a solution MACRO SUB_ITEM # 2 Particles which are paired to form valence bonds in carbon 2 compounds MACRO SUB_ITEM # 3 3 The inert gas molecules contain only one of these particles MACRO SUB_ITEM # 4 An uncharged particle which is undisturbed in ordinary 4 chemical reactions MACRO SUB_ITEM # 5 5 A particle causing an ammeter to give a reading MACRO SUB_ITEM # 6 9 The particle with the smallest weight ETS2WVW 2100015 DBCCB 55 20316 51 0185057480011190 MACROITEM STEM 2The following questions begin with a phrase specifying something 2to be measured, determined, or produced. After the exercise 2number on the answer sheet, blacken the one lettered space which 3 ___ 0 designates how this goal is to be accomplished. MACRO SUB_ITEM # 1 The amount of electric charge on a single electron A. Use an electroscope B. Use a cathode tube C. Use a fog_track apparatus D. Use Millikan's oil drop apparatus 1 E. Use the mass spectrograph of aston MACRO SUB_ITEM # 2 Whether the nucleus of an atom is small as compared with the total volume of the atom A. Use Millikan's oil drop appraratus. B. Shoot alpha particles through gold foil or use the fog_track apparatus. ETS2WVW 2 3 4 9 C. Use a zinc_sulfide fluorescent screen. D. Use the mass spectrograph of aston. E. Use the geiger counter. MACRO SUB_ITEM # 3 Whether or not a given element has isotopes A. Seek chemical reactions which will separate different forms. B. Use the fog_track appratus. C. Use the mass spectrograph of aston. D. Use a centrifuge SO that the heavier atoms will be separated from the lighter ones. E. Use a zinc_sulfide fluorescent screen. MACRO SUB_ITEM # 4 Whether or not a given particle, known to be an electron or a positron, is the latter rather than the former A. Observe its path in a zinc_sulfide fluorescent screen. B. Use the mass spectrograph of aston. C. Observe its path in a fog_track apparatus in the presence of a magnetic field. D. Pass the particle through beryllium foil and observe the result. E. Observe the direction in which it circles around the nucleus of the atom. MACRO SUB_ITEM # 5 Whether or not neutrons are present A. Use the Geiger counter. B. Look for evidence of collisions in which there is no fog_track up to the collision. C. Use the oil drop apparatus of Millikan. D. Use deuterons in the atom smashing experiment. E. Compare the observable path of the neutron with that of the electron and proton. 2100016 DBBAADAC 85 20342 31 80018003 1190 MACROITEM STEM 2The following questions refer to the particles which are important 2in our theories of matter. For each item select from the key the 2most appropriate response. 2 A. atom 2 B. electron 2 C. molecule 2 D. neutron 0 E. proton MACRO SUB_ITEM # 1 The particle most important in the continuance of chain 1 reactions in the fission of uranium. MACRO SUB_ITEM # 2 ETS2WVW The particle most responsible for the reading of a light meter 2 when exposed to suitable radiation. MACRO SUB_ITEM # 3 The particle of which there is a deficiency when a glass rod 3 is charged positively. MACRO SUB_ITEM # 4 A particle most frequently discussed in theories of 4 "states" of matter. MACRO SUB_ITEM # 5 5 A particle most helpful in explaining how a gas exerts pressure. MACRO SUB_ITEM # 6 A particle which accounts for chlorine and many other 6 elements being assigned an "average" atomic weight. MACRO SUB_ITEM # 7 7 A particle which exists in an ionized state in table salt. MACRO SUB_ITEM # 8 The smallest particle which can exist and still retain all of 9 the properties of the compound. 2100017 B 15 20354 31 03980263800111 Which one of these has the smallest mass? A. neutron B. electron C. ion D. proton 9 E. atom ETS2WVW 2100018 C 15 20356 31 04950351800111 The number of different fundamental particles which seem to have some part in the make_up of atoms is A. 4 B. 2 C. 3 D. 8 9 E. more than 10 ETS2WVW 2100019 A 15 20359 31 03510357800111 Rutherford developed his nuclear theory of atomic structure because A. most alpha particles passed through gold foil without serious deflection but a very few were violently deflected B. the atomic numbers of the elements were in the same order as their atomic weights C. of the enormous amounts of energy liberated by nuclear disintegration D. because radium condenses drops from supercooled water vapor ETS2WVW 9 E. because the frequency of x_rays was proportional to the square root of the atomic number 2100020 BCBDD 55 20367 31 0341026380011190 MACROITEM STEM 2To answer the following questions, select from the key 2the correct particle. 2 A. neutron 2 B. electron 2 C. proton 2 D. atom 0 E. molecule MACRO SUB_ITEM # 1 1 A particle which travels in elliptical orbits MACRO SUB_ITEM # 2 2 Another name for hydrogen ion MACRO SUB_ITEM # 3 3 A nearly weightless particle found in all elements MACRO SUB_ITEM # 4 4 The molecule of bromine contains only one of what other particle? MACRO SUB_ITEM # 5 9 A particle particularly important in the kinetic theory ETS2WVW 2100021 ABEDBA 65 20373 31 0341026380011190 MACROITEM STEM To answer the following questions, select from the key 2the correct particle. 2 A. neutron 2 B. electron 2 C. proton 2 D. atom 0 E. molecule MACRO SUB_ITEM # 1 A particle not found in a certain one of the known elements. 13 ___ MACRO SUB_ITEM # 2 2 A particle discussed in the elementary theories of magnetism. MACRO SUB_ITEM # 3 A particle, for active gaseous elements, containing 3 exactly two other particles. MACRO SUB_ITEM # 4 4 A particle which may be ionized in chemical reactions. MACRO SUB_ITEM # 5 5 A particle important in the operation of a thermocouple. MACRO SUB_ITEM # 6 9 A particle which helped explain discrepancies in atomic weights. ETS2WVW 2100023 C 14 20381 32 026303518004 The number of electrons in an atom whose atomic number is 3 and whose mass number is 7 is A. 10 B. 7 C. 3 D. 4 9 E. 2 2100024 CEBD 45 20383 31 034100978004 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches. 2 A. electron 2 B. proton 2 C. neutron 2 D. group 0 E. nucleus MACRO SUB_ITEM # 1 1 A neutral particle found in the nucleus of an atom MACRO SUB_ITEM # 2 2 the postively_charged, dense central part of an atom MACRO SUB_ITEM # 3 3 A positively_charged particle found in the nucleus of an atom MACRO SUB_ITEM # 4 9 A vertical volume of elements in the periodic table 2 OS 2 OS 2100025 D 14 44855 31 035180048002 The atom can be seen by means of A. a transmission electron microscope B. a Geiger counter C. a spectroscope D. a tunnelling electron microscope 9 E. magnetic resonance imaging 2 OS 2100026 C 14 20390 31 034203518004 The nucleus of an atom is composed of A. neutrons and electrons B. protons and ions C. protons and neutrons 9 D. neutrons and ions 2100027 C 14 20392 32 035104048004 An atom of chlorine, atomic number 17, and atomic weight 35, contains in its nucleus A. 35 protons C. 17 protons E. 17 electrons 2 OS 2 OS 9 B. 17 neutrons D. 18 protons 2100028 B 14 20395 32 034203530341 5 27 The nucleus of the aluminum isotope Al contains 4 13 A. 13 neutrons B. 14 neutrons 9 C. 27 neutrons D. 40 neutrons 0041 2100029 C 14 20398 31 0358 0097 An alpha particle consists of A. two protons B. two protons and two electrons 9 C. two protons and two neutrons D. four protons 0041 2100030 A 14 20400 51 12850263 A beta particle is 9 A. an electron B. a photon C. a proton D. a neutron 0041 2100031 D 15 20402 51 04950358 Of the following, the one that is not an elementary particle is the A. electron B. proton C. neutron 9 D. alpha particle E. beta particle 0041 2100032 B 14 20405 31 034200970341 A tritium nucleus consists of: A. one proton and two electrons B. one proton and two neutrons C. one neutron and two protons 9 D. one proton and three neutrons. 0043 2100033 C 15 20408 52 035102630398 A neutral atom which has 53 electrons and an atomic mass of 111 has A. no other isotopes. B. an atomic number of 58 C. a nucleus containing 58 neutrons. D. a nucleus containing 53 neutrons. 9 E. a nucleus containing 58 protons. 0044 2100034 A 15 20412 52 026303980351 A neutral atom which has 58 electrons and an atomic mass of 121 has: A. a nucleus containing 63 neutrons. B. a nucleus containing 63 protons. C. no other isotopes. D. a nucleus containing 58 neutrons. 9 E. an atomic number of 63. 0044 2100035 A 14 20416 31 03510263009751 All neutral atoms contain equal numbers of A. electrons and protons B. protons and neutrons 9 C. positrons and electrons D. neutrons and electrons. 9000 2100036 B 15 20419 31 058703420351 The ____________ of an atom is the total number of neutrons plus protons in the nucleus. A. atomic number B. mass number 9 C. nuclear charge D. none of these 0018 2100037 E 15 20422 32 01850342 5 3+ The charge on the nucleus of Al is 9 A. +16 B. +10 C. +27 D. +3 E. +13 0018 2100038 E 15 20424 31 035703581127 In the Rutherford gold foil experiment the fact that most of the alpha particles were not deflected by the gold foil indicates that A. the nucleus is positively charged. B. the nucleus is negatively charged. C. atoms are solid spheres touching each other in the solid state. D. gold is very dense. 9 E. None of these 0018 2100039 B 15 20429 31 026300990337 The number of electrons in a neutral atom is equal to the A. atomic weight B. atomic number C. number of neutrons present D. atomic weight minus the number of protons 9 E. number of neutrons present plus the number of protons 0018 2100040 E 15 20433 31 035702720342 Rutherford's experiment demonstrated that A. atoms are mostly empty space B. nuclei are very small C. nuclei have positive charges D. the mass of the atom is mostly in the nucleus 9 E. all of these 0020 2100041 B 15 20436 The mass number is 0020 31 058700970341 9 A. the atomic mass B. sum of protons + neutrons in an atom C. sum of protons, electrons, and neutrons in an atom D. the molecular mass E. none of these 2100042 C 14 20439 51 149714980342 By about how many orders of magnitude (powers of ten) is the diameter of an atom larger than that of a nucleus? 9 A. 1 B. 2 C. 4 D. 10,000 0009 2100044 A 15 44832 32 035305780398 The e/m value for a certain isotope was found from mass 5 6 spectrometric measurements to be 2.5 x 10 coulombs/gram. If the 5 _19 charge on the isotopic ion were known to be 1.6 x 10 coulombs, the mass of the ion would be equal to 0019 5 _19 1.6 x 10 A. ___________ g 5 6 2.5 x 10 5 6 2.5 x 10 B. ___________ g 5 _19 1.6 x 10 5 6 _19 C. 2.5 x 10 x 1.6 x 10 g 5 D. 2.5 x 1.6 x 10 5 9 _24 g _24 2.5 x 10 E. ___________ g 1.6 2100045 D 15 20450 31 035703420513 Rutherford's gold_foil experiment was instrumental in establishing the concept of A. an atom B. a molecule C. subatomic particles 0040 9 D. a nucleus in an atom E. electrons in a atom. 2100046 E 15 20453 31 026300970398 Which of the following sequences gives a correct listing of the fundamental subatomic particles in order of increasing weight? A. proton, electron, neutron B. electron, neutron, proton C. neutron, electron, proton D. proton, neutron, electron 9 E. electron, proton, neutron. 0040 2100047 C 15 20457 31 034203510097 The nucleus of the atom consists of A. electrons and protons. B. electrons, protons, and neutrons. C. protons and neutrons. D. electrons and neutrons. 9 E. protons only. 0035 2100048 C 15 20460 32 079711780097 Another name for the positive ion of the hydrogen atom is 9 A. neutron. B. electron. C. proton. D. atom. E. molecule. 0035 2100049 A 15 20462 31 049503420358 Which particle is identical to a helium nucleus? A. alpha particle B. beta particle C. gamma ray D. proton 9 E. neutron 0034 2100050 C 15 20464 31 059115711202 Which of the following is undeflected by a magnetic field? A. alpha particle B. beta particle C. gamma ray D. proton 9 E. more than one of the above 0034 2100051 B 14 20467 31 026803570069 The basic idea of the Rutherford atomic model is that the positive charge in an atom is A. spread uniformly throughout its volume B. concentrated at its center C. readily deflected by an incoming alpha particle 9 D. the same for all atoms 0041 2100052 B 14 20471 72 19540342 A species containing two neutrons and one proton is: 5 2 3 3 7 A. H B. H C. He D. Li 0061 94 1 1 2 3 2110001 CACA 45 20474 31 0659026380011290 MACROITEM STEM 2In the early days of cathode_ray study, during the process of 2experimentation, the results listed below were noted. These results 2gave rise to certain inferences. From the key of inferences given 2below, select the one that would be most likely to arise as a result 3 ____ ______ 2of the evidence or experimental result described in each item. 2 A. Cathode rays possess considerable kinetic energy. 2 B. Cathode rays possess considerable potential energy. 2 C. Cathode radiation travels approximately in straight lines. 2 D. Cathode radiation carries a strong negative charge. 0 E. Cathode radiation carries a strong positive charge. MACRO SUB_ITEM # 1 Experiments showed that obstacle in the path of cathode rays 1 produced sharp shadows. MACRO SUB_ITEM # 2 Experiments showed that a piece of platinum placed at the point 2 where the rays converged, quickly become red_hot. MACRO SUB_ITEM # 3 Experiments showed that the rays can be focused on a point by using a cathode with a concave surface, somewhat as light is 3 focused, by a concave mirror MACRO SUB_ITEM # 4 Experiments showed that if a tiny paddle wheel is placed on a runway in the tube, with the vanes in the path of the rays__it will 9 move rapidly away from the cathode. ETS2WVW 2110002 A 15 20490 31 05760574800111 Perrin placed a pair of coaxial cylinders in the path of a stream of cathode rays in a tube, so that the rays passed through holes into the inner cylinder. He found that A. the inner cylinder received a negative charge B. the outer cylinder received a negative charge C. both cylinders received a negative charge D. one cylinder or the other (but not both) received a negative charge 9 E. one cylinder or the other or both received a negative charge ETS2WVW 2110003 D 15 20497 32 02630317800111 All of these present experimental evidence for the electron theory of matter except A. when a rubber rod is rubbed with fur, the rod becomes charged. ETS2 OS 9 B. hot filaments in radio tubes emit a stream of charged particles. C. radium disintegrates into other forms, the end product being lead. D. every body in the universe attracts every other body with a measurable force. E. certain substances dissociate in solution and become ions. 2110004 A 15 20504 31 05740113800111 Which of the following is not true of cathode rays? A. They change in character as the gas in the tube is changed. B. They travel in straight lines unless deflected by a magnetic or an electric field. C. They can be brought to a focus. D. They cause some materials to fluoresce. 9 E. They cast shadows of obstacles placed in their path. ETS2WVW 2110005 D 15 20509 31 06160015800111 X_rays emerge from a metal target when it is struck by A. radiation of long wave length B. high_velocity alpha particles C. high_velocity neutrons D. high_velocity electrons 9 E. cosmic rays ETS2WVW 2110006 D 14 20512 31 05740263800111 By the term "cathode rays" we refer to A. stream of positive ions B. electromagnetic waves of very short wave length C. a beam of x_rays 9 D. a stream of electrons ETS2WVW 2110007 D 15 20515 31 03980263800111 The mass of an electron is A. the same as the mass of the hydrogen atom B. dependent upon the atomic weight of the atom from which it was separated C. the same as the mass of a proton D. about one two_thousandth the mass of a hydrogen atom 9 E. about four times the mass of a hydrogen atom ETS2WVW 2110008 C 15 20520 31 05740595800111 Cathode rays are A. the most effective projectiles in the disintegration of atoms B. particles which go from cathode to anode in the electrolysis of aqueous solutions ETS2WVW 9 C. very light negatively charged particles which travel from cathode to anode in a crookes tube D. similar to the alpha particles of radium except for their speed E. differ from x_rays only in their wave_length 2110009 D 15 20526 31 Cathode rays are A. electromagnetic waves B. photons C. neutrons D. electrons 9 E. protons 05740626800111 ETS2WVW 2110010 D 15 20528 31 06160574800111 The basic difference between an x_ray tube and a cathode_ray tube is that A. the cathode ray tube contains a vacuum. B. the x_ray tube has both a cathode and an anode. C. the cathode_ray tube contains electrodes. D. the x_ray tube stops the flow of electrons. E. the x_ray tube produces a stream of electrons from the 9 cathode. ETS2WVW 2110011 A 15 20533 31 06160263800111 X_rays result from the bombardment of a suitable target by high speed A. electrons B. ions C. protons D. neutrons 9 E. atoms ETS2WVW 2110012 D 15 20535 31 06260330800111 Which of the following does not appear on the electromagnetic spectrum? A. cosmic rays B. hertzian waves C. x_rays D. seismic waves 9 E. ultra_violet rays ETS2 OS 2110013 B 15 20538 31 03980263800111 Which one of these has the smallest mass? A. neutron B. electron ETS2WVW 9 C. ion D. proton E. atom 2110014 D 15 20540 31 05740593800113 When a narrow beam of cathode rays is deflected in a magnetic field, it spreads out, according to Thomson, into a broad fan_shaped luminosity in the gas; thus the rays are not all equally deflected. The most probable explanation of this effect is that A. the magnetic field is not accurately homogeneous, but is stronger in some places than in others B. the magnetic field is not uniform in direction C. the mass and charge are not the same for all the particles in the beam, only the ratio m/e being constant 3 ___ D. the particles do not all have the same velocity E. minute variations in the density of the gas in the tube 9 produce a dispersion of the rays in the magnetic field ETS2WVW 2110015 B 15 20550 31 03510357800111 In 1911 Rutherford bombarded gold foil with alpha particles. This experiment helped to establish the electron theory by showing A. the mass of the atom B. that the atom is mostly empty space and the plus charge is concentrated C. the number of protons present in the mucleus D. the charge of an electron 9 E. the presence of charged particles derived from atoms ETS2WVW 2110016 C 15 20556 31 01850263800111 When the ratio of the charge to the mass (e/m) of the electron was calculated, which one of the following assumptions was made about the electron? A. The charge on the electron was positive. B. The electron was a material particle. C. The electron had no weight. D. The electron always moves with the velocity of light. 9 E. The charge on the electron was negative. ETS2WVW 2110017 A 15 20561 31 00020019800111 In relative weight, a sodium ion compared to a sodium atom A. is about the same B. is heavier C. is considerably lighter D. cannot be compared because an ion has NO weight 9 E. cannot be compared because an ion is an electrical charge ETS2WVW 2110018 D 14 20565 31 015901968004 The particle which occupies the first energy level in the hydrogen atom is known as the A. neutron B. nucleus C. electron 9 D. K electron 2 OS 2110019 A 15 20568 32 A positron has a mass number of 9 A. 0 B. 1 C. 3 D. 16 E. 1837 2110020 B 15 20570 31 109402630185 The particles making up canal rays are A. negatively charged and heavier than electrons B. positively charged and heavier than electrons C. negatively charged and lighter than electrons D. positively charged and lighter than electrons 9 E. NO correct response is given. 0040 2110021 B 15 20574 31 049501890263 A nearly weightless particle found in all elements is the 9 A. neutron. B. electron. C. proton. D. atom. E. molecule. 0035 2110022 D 15 20576 32 018502631390 When the charge on the electron was determined, which technique or apparatus was used? A. Electroscope. B. Cathode tube. C. Fog_track apparatus. D. Millikan's oil drop apparatus. 9 E. Mass spectrograph of Aston. 0035 2111001 A 15 20579 31 03260282800111 The principle underlying the operation of a photoelectric cell A. Radiation may cause some substances to emit electrons. B. Electrons may be emitted from certain substances at high temperatures. C. A changing magnetic or electro_magnetic field may produce a flow of electrons. D. Radiation may be re_radiated at different wave lengths. E. Electrons may cause radiations to be emitted from 9 some substances. 2111002 ABBBC 55 20585 31 0054034480011490 MACROITEM STEM 2To answer the following questions select from the key the most ETS2WVW ETS2WVW 2appropriate statement. 2 A. Statement true; reason true and bears directly on the statement 3 _________ ____ ______ ____ 2 B. Statement true; reason false. 3 ______________ ______ _____ 2 C. Statement true; reason true, but does not have any 3 _________ ____ ______ ____ 2 bearing on the statement. 2 D. Statement false; reason true but with no bearing on 3 _________ _____ ______ ____ 2 the statement. 2 E. Statement false; reason false 03 _________ _____ ______ _____ MACRO SUB_ITEM # 1 A current results when light falls on a photoelectric cell because certain substances emit electrons when light 3_______ 1 strikes them. MACRO SUB_ITEM # 2 2 Potassium is used in a photoelectric cell because it is a metal. MACRO SUB_ITEM # 3 3 _______ Photoelectric cells may be used as exposure meters in photographic work because the current in the cell is 3 _______ proportional to the amount of incident light and not to 3 the frequency of the vibration. MACRO SUB_ITEM # 4 A simple photoelectric cell has an uncoated plate charged negatively because such a plate is necessary to 3 _______ 4 attract the protons released by the incident light. MACRO SUB_ITEM # 5 Light striking a photoelectric cell sets up an electric current because light is a longitudinal vibration. 93 _______ 2111003 E 15 20603 51 05750572800111 Planck introduced the quantum postulate into the theory of radiation in order to account for A. discontinuous spectra B. interference C. the constitution of radiation out of finite, corpuscle_like "chunks" of energy, each of which is propagated with great speed in a straight line D. the ejection of electrons from matter by light, a ETS2WVW 9 phenomenon which indicates in rather direct fashion that the spatial distribution of energy in a light "wave" is discontinuous E. the distribution of energy in the spectrum of a black body, a phenomenon which does not involve any obvious discontinuity, but which can be accounted for quantitatively by the postulate 2111004 C 15 20613 31 05110630800111 The maximum kinetic energy of photoelectrons from an illuminated surface increases A. when the light intensity increases B. when the light intensity decreases C. when the light frequency increases D. when the light frequency decreases 9 E. independently of light intensity and frequency ETS2WVW 2111005 E 15 20617 31 03260263800111 In the photo_electric effect, the maximum speed of an electron ejected by a photon is determined A. entirely by the frequency of the light falling on the metal surface B. entirely by the number of photons falling on the metal surface C. entirely by the nature of the metal surface D. by the frequency of the light and the number of photons falling on the metal surface E. by the nature of the metal surface and the frequency 9 of light falling on the surface ETS2WVW 2111006 A 15 20624 31 03260590800111 The principle underlying the operation of a photoelectric cell is A. radiation may cause some substances to emit electrons. B. electrons may be emitted from certain substances at high temperatures. C. a changing magnetic or electro_magnetic field may produce a flow of electrons. D. radiation may be re_radiated at different wave lengths. E. electrons may cause radiations to be emitted from some 9 substances. ETS2WVW 2111007 A 14 20630 31 03260263800111 The photoelectric effect involves the A. emission of electrons from an illuminated metallic surface B. emission of light when radioactive material strikes a zinc ETS2WVW 9 sulfide screen C. process of developing photographs using the electric current D. emission of visible light by high voltage electricity 2111008 BABDCBAB 84 20635 31 80018003 1190 MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the item is true of the photoelectric effect 2 B. if the item is true of the Edison effect 2 C. if the item is true of both effects 0 D. if the item is true of neither effect MACRO SUB_ITEM # 1 1 Electrons are emitted from a heated filament. MACRO SUB_ITEM # 2 Electrons are emitted from a metal or compound when 2 exposed to light. MACRO SUB_ITEM # 3 The conductor which is to receive the electrons must be connected to the positive terminal of the battery or 3 direct current source. MACRO SUB_ITEM # 4 The metal which emits the electrons must be connected 4 to the positive terminal of the direct current source. MACRO SUB_ITEM # 5 5 The flow of electrons is unidirectional. MACRO SUB_ITEM # 6 6 Forms the basis of the radio tube. MACRO SUB_ITEM # 7 The effect is often used to operate a relay which in 7 turn may operate the electric switch on various devices. MACRO SUB_ITEM # 8 9 A grid may be employed to regulate the flow of electrons. 2111009 D 15 45404 71 Which of the following processes represents the ionization energy of iodine? 5 + _ A. I (s) ___> I (g) + e 4 2 2 5 + _ B. I (g) ___> I (g) + e 4 2 2 5 + _ C. I(s) ___> I (g) + e 5 + _ D. I(g) ___> I (g) + e ETS2WVW 5 + _ 9 E. I(l) ___> I (l) + e 2111010 B 15 20647 31 00150326800113 If a certain metal gives a photoelectric effect under visible light of a certain color C, one should expect the effect to occur, for that metal, A. under light of any color on the red side of C in the spectrum B. under light of any color on the violet side of C in the spectrum C. under light of any color whose wave length is an integral multiple of that of C D. under light of any color whose frequency is an integral multiple of that of C E. under any kind of light whose energy quanta are integral 9 multiples of h 2111011 ABEBAEA 75 20655 71 0571057280011190 MACROITEM STEM 2To answer the following questions, mark 2 A. if it states an observable or experimentally determinable 2 characteristic of the photoelectric effect, and is in 2 accordance with both the classical and the quantum theory 2 of light. 2 B. if it states an observable or experimentally determinable 2 characteristic of the photoelectric effect, and is in 2 accordance with the quantum theory of light but not with the 2 classical theory 2 C. if, while it is not experimentally testable in any fairly 2 direct way, it is a true statement about the photoelectric 2 effect according to both the classical and quantum theories 2 D. if, while it is not experimentally testable in any fairly 2 direct way, it is a true statement about the photoelectric 2 effect according to the quantum theory, though not 2 according to the classical theory of light. 2 E. if it is, according either to experimental results or to the 2 quantum theory, not a true statement about the photoelectric 0 effect. MACRO SUB_ITEM # 1 The average kinetic energy of the liberated electrons increases if 1 one increases the intensity of the light. MACRO SUB_ITEM # 2 When light falls upon a metal, it exerts an influence upon the electrons within the metal, and may succeed in ejecting them from 2 it. MACRO SUB_ITEM # 3 ETS2WVW ETS2WVW In light of very low intensity, the average amount of energy flowing across a square centimeter in a second may be so small that, considering a region of the size of an atom and assuming uniform distribution of the energy, years would be required for enough energy to flow through such a region to give an electron comparable with that measured in the photoelectric effect. Yet such light 3 falling upon a metal may instantly eject electrons from it. MACRO SUB_ITEM # 4 When light falls upon a metal, interactions with electrons occur only in the form of encounters between a single electron and a 4 definite, localized, and indivisible portion of the light. MACRO SUB_ITEM # 5 The speeds with which electrons leave a body in the photoelectric 5 effect may be increased by using light of shorter wave length. MACRO SUB_ITEM # 6 Electrons can be ejected from a metal only by light whose frequency 6 corresponds to a line in the bright line spectrum of that metal. MACRO SUB_ITEM # 7 Positive charges are never ejected from a body by the photoelectric 9 effect. 2111012 E 15 20688 72 05718003 If the kinetic energy of a photoelectric electron ejected from sodium by ultraviolet light of wavelength 300 nm is 5 _19 3.3 x 10 J, what is the critical wavelength for the photoelectric effect in sodium? 5 8 _1 _34 (c = 3.0 x 10 m sec , h = 6.6 x 10 J sec) 5 _6 _6 9 A. 6.0x10 nm B. 3.0x10 nm C. 300 nm D. 500 nm E. 600 nm 2111013 D 15 44377 52 02638001800313 Find the maximum velocity of a photoelectron which can be stopped by 5 17 3 volts negative potential. (Assume e = 5 x 10 e.s.u./gm for the 3 _ m electron and 1 volt = 1 e.s.u. Of potential). 3 ___ 300 5 9 8 7 A. 3 x 10 cm/sec C. 3 x 10 cm/sec E. 3 x 10 cm/sec 5 9 8 9 B. 1 x 10 cm/sec D. 1 x 10 cm/sec 2WVW ETS2WVW 2111014 D 15 20701 52 05718003 If the kinetic energy of a photoelectric electron ejected from 2WVW 5 _13 cesium metal by 5000 A light is 9.9 x 10 erg, what is the minimum energy required to eject an electron from the surface of 3_______ ______ cesium metal and leave the electron at rest? (note KE=h(f1 _ f2), where f1 is the incident light frequency, f2 is the minimum frequency for the photoelectric effect in cesium, and H is Planck's constant) 5 10 _1 (c = 3.0 x 10 cm. sec ; 5 _27 h = 6.6 x 10 5 erg sec.) _27 A. 6.6 x 10 5 erg _13 B. 3.0 x 10 5 erg _13 C. 9.9 x 10 5 erg _12 D. 3.0 x 10 erg 5 _12 9 E. 9.9 x 10 erg 2111015 D 14 20712 51 15400263038051 Emission spectra (line spectra) are produced when an electron A. reverses its spin B. escapes from the atom C. spirals into the nucleus 9 D. changes its atomic energy level 2111016 D 15 20715 52 The magnitude of the charge on an electron is A. 1 coulomb 5 19 B. 1.60 x 10 coulombs 5 _28 9000 OS83 C. 9.11 x 10 coulomb 5 _19 D. 1.60 x 10 coulomb _23:5 9 E. 6.02 x 10 coulomb 2111017 A 14 20719 31 051302630654 Experimental evidence to indicate that cathode rays have charge is A. that their path is curved in a magnetic field B. that they have no effect on an electroscope C. that they have been assigned a negative charge 9 D. that gravity affects their path. 0026 2111018 B 14 20723 31 051302630654 Regardless of the metals used as cathodes, the cathode rays had the same charge to mass ratio. This indicates that A. there is no difference between one metal and another B. electrons are a part of all matter C. the nucleus of an atom contains protons 9 D. electrons are negatively charged. 0026 2111019 C 14 20727 31 001901850513 A submicroscopic particle of +1 charge could be a(n) 9 A. electron B. neutron C. ion D. atom E. alpha particle. 0026 2111020 B 15 20729 31 12850263 Beta particles are A. particles with a _2 charge B. the same as electrons C. particles with NO mass or charge D. particles with a _1 charge and a mass of 1 9 E. larger than alpha particles 2111022 D 15 20732 An electron has a mass of A. 0.00054874 amu 5 _28 B. 9.11 x 10 g C. almost zero D. all of these 9 E. none of these 31 026303981316 2111023 D 15 20735 51 142002630185 Millikan's oil drop experiment is used to determine precisely A. the exact size of the oil drop 0020 0020 0019 9 B. the charge to mass ratio of the oil drop C. the magnitude of the gravitational force D. the minimum value of the charge of an electron E. none of the above 2111024 D 14 20739 51 027209970590 Which of the following experiments gives the conclusive proof of the quantum nature of radiation? A. Rutherford's scattering experiment B. Thomson's cathode ray experiment C. Einstein's experiment on the photo electric effect 9 D. none of the above 0019 2130001 C 14 20743 51 04950097 The particle that most closely resembles the proton is the A. positron B. neutron C. antiproton 9 D. positive sigma hyperon 0041 2130002 B 15 20745 31 01850342 5 _ The charge on the nucleus of O is 4 2 9 A. 6+ B. 8+ C. 2_ D. 2+ E. none of these 0018 2130003 D 15 20748 31 033701850342 The positive charge on the nucleus is called A. moseley's number B. the atomic weight C. the neutron concentration D. the atomic number 9 E. none of these 0020 2130004 C 15 20751 31 018900970342 Tin is element 50. This means that A. its mass is 50 amu B. its mass number is 50 C. it has 50 protons in its nucleus D. it has 50 neutrons in its nucleus 9 E. none of these 0020 2150001 D 15 20754 31 03410351800131 The loss of a neutron from an atom A. changes the chemical nature of the atom B. changes the charge on the atom C. changes the physical properties of the atom D. reduces the mass number of the atom ETS2WVW 9 E. causes the subsequent loss of an electron 2150002 C 15 20758 31 03410351800111 The loss of a neutron from an atom A. changes the chemical nature of the atom B. changes the charge of the atom C. changes the mass number of the atom D. reduces the atomic number of the atom 9 E. causes the subsequent loss of an electron ETS2WVW 2150003 A 15 20762 31 00650097034111 Which one of these is correct concerning the neutron? A. The atomic weight of an atom equals the sum of the weights of the protons and the neutrons. B. Every element contains one or more neutrons. C. The neutron prevents the attractive forces of the protons and electrons from causing them to come together. D. The neutron like the electron is of negligible weight relative to the total weight of the atom. E. The atomic number equals the number of neutroms present 9 in the atom. ETS2WVW 2150004 D 14 20769 32 03410342058751 The number of neutrons contained in the nucleus of a particular atom is equal to its A. atomic weight B. mass number C. atomic number 9 D. mass number minus the atomic number 9000 2150005 E 15 20772 31 039803410495 A subatomic particle that has an atomic mass of 1 and a charge of 0 is A. a beta particle B. an alpha particle C. an electron 9 D. a proton E. a neutron 2150006 C 15 20775 31 06570341 A neutral particle having a mass of approximately one atomic mass unit is A. an electron B. a proton C. a neutron 9 D. a meson E. none of these 2150007 A 15 20778 31 040713380341 The reaction which chadwick studied when he discovered neutrons was A. Be + alpha particles B. Be + protons C. boron + electrons 0018 0028 0020 9 D. boron + alpha particles E. beryllium + electrons 2150008 B 15 20781 31 034105910592 Which of the following fundamental particles is not affected by electric or magnetic fields? A. protons D. both A and B B. neutrons E. both A and C 9 C. electrons 0040 2150009 A 15 20784 31 049501890341 A particle not found in a certain one of the known elements is the 9 A. neutron. B. electron. C. proton. D. atom. E. molecule. 0035 2150010 D 14 20786 52 1944 Which particle has the largest rest mass? A. electron B. positron C. proton 9 D. neutron 0055 2200001 E 15 20788 52 03570358800112 According to Rutherford, "atoms of matter are not solid spheres, but empty structures consisting of extremely minute particles separated by relatively great distances." however, from cloud chamber observations, it was noted that fast_moving alpha particles passing through a gas may be slowed down and even stopped without ever hitting one of these minute particles in the center of the atoms of the gas! this can be explained by assuming that A. Rutherford was not exactly correct, and that there is really a thin sort of matter within the atom as well as the minute particles B. the alpha particles passing through the gas lost their initial kinetic energy, and therefore their slowing down was not due to any action of the gas C. while the atoms of the gas may consist of empty structures containing only minute particles separated by relatively great distances, nevertheless there is probably a tenuous membrane stretched between the outer surfaces of the atoms which acts to slow down and stop the alpha particles D. the alpha particles contain great quantities of static electricity charge which react with the minute particles within the atoms of the gas to slow down and stop these particles E. powerful electric fields exist within the atoms of the gas ETS2 OS 9 itself, and that it is these fields which may slow down or stop the particles 2200002 E 15 20807 31 03660351800112 Cannizzaro apparently considers that the most valid criterion for the correctness of an atomic theory is A. its degree of conformity to Avogadro's theory B. its degree of internal consistency C. that it provide a mechanical model understandable at the gross level, for phenomena occurring at a level too minute to be directly observed D. its consistency with all known chemical and physical phenomena 9 E. its degree of simplicity ETS2 OS 2200003 C 15 20814 31 03660065800112 How may the statement, "the atomic weight of nitrogen is 14," be interpreted in cannizzaro's sense? A. An atom of nitrogen weighs 14 units. B. In a compound of nitrogen and hydrogen, the nitrogen has 14 times the weight of the hydrogen. C. A liter of nitrogen has 14 times the weight of a liter of hydrogen. D. No smaller weight of nitrogen than 14 grams is ever found in a molecular weight (in grams) of any compound of nitrogen. E. A gram of nitrogen contains 14 times as many atoms as a gram 9 of hydrogen. ETS2 OS 2200004 D 15 20822 51 02760351800111 Which one of these is explained on the basis of atomic theory rather than on kinetic theory? A. The explanation of heat of fusion B. That the energy of particles may be expressed in terms of 5 2 (1/2) mv C. Changes in the state of matter D. Conservation of mass 9 E. The meaning of temperature ETS2WVW 2200005 C 15 20827 51 05130189800111 The atomic theory assumes all of these except A. the average mass of atoms of the same kind is definite, but different from that of any other kind of atom. B. the number of different kinds of elements is limited. C. atoms lose their identity in chemical reactions. D. atoms possess kinetic energy. ETS2WVW 9 E. all elements are composed of small discrete particles. 2200006 E 15 20833 51 05830513800113 Dalton's atomic theory offers a reasonably satisfactory explanation for one of the following statements. You are to 3 ___ determine which one this is. A. When hydrogen combines with oxygen, a large amount of energy is liberated. B. Forces holding the atoms together in a molecule of nitroglycerine are so small that the compound is explosive. C. The weight of carbon dioxide produced by burning a given amount of carbon can be accurately predicted. D. Hydrogen atoms combine with oxygen atoms more readily than with chlorine atoms. E. Four atoms of hydrogen combine with one atom of carbon, 9 but two atoms of hydrogen combine with one atom of oxygen. 2200007 CCBD 45 20843 31 1 80019012 119095 MACROITEM STEM 2The following questions refer to Figure 12. After each exercise 2number on the answer sheet, blacken the one lettered space which 0 designates the correct answer. MACRO SUB_ITEM # 1 This is an historically famous experiment performed by A. Moseley B. Thomson C. Rutherford D. Millikan 1 E. Urey MACRO SUB_ITEM # 2 Gold was used because it A. can be obtained as a nugget B. is a lightweight atom C. is malleable and can be prepared easily into a very thin sheet D. is yellow 2 E. was believed to be different from other atoms MACRO SUB_ITEM # 3 Particles used as projectiles in this experiment were A. electrons B. alpha particles C. beta particles D. gamma rays 3 E. neutrons MACRO SUB_ITEM # 4 ETS2WVW ETS2WVW The experiment gives excellent evidence that nuclei are A. very close together and positively charged B. very close together and neutral in character C. very far apart and neutral in character D. very far apart and charged positively 9 E. very far apart and charged negatively 2200008 E 15 20856 51 80018003 12 According to Rutherford's calculations, the deflection d of an alpha particle of mass m, initial speed v, and charge 2e moving initially so as to pass at a distance of p an atomic nucleus of charge ne, is given by the equation 5 2 2 cot (d/2)= v /(2ne ) The derivation of this equation is based upon the assumption A. that the probability of a given deflection is proportional to the target area presented by the region capable of producing such a deflection. B. that the probability of a given deflection is the same as the fraction of particles which experience that deflection. C. that multiple scattering does not occur. D. that the force on an alpha particle varies inversely as the square of its distance from an atomic center. E. that multiple scattering does not occur, and that the force on an alpha particle is inversely proportional to the 9 square of its distance from an atomic center. ETS2WVW 2200009 C 15 20869 51 80018003 12 Rutherford's formula for the probability p of a deflection between angles X and Y for an alpha particle traversing a metal foil of thickness t is 5 2 4 2 4 p = (4 x (3.14) x t x (n ) x(e )/(m ) x (u )) x 4 2 2 5 2 2 ((cot x/2) _ (cot y/2) ) the quantities t, N (number of atoms per cubic centimeter), e, m, and u can be determined independently. The quantity N can best be determined A. from the atomic weight of the metal B. by observing the fraction of particles deflected through angles between X and Y (for some given values of X and Y) C. by measuring the deflection of some one alpha particle D. from the value of the charge of an electron E. by dividing some interval (X and Y) into equal parts and calculating the probability of a deflection for each part ETS2WVW 9 of the interval, comparing these with the net probability for the interval as a whole 2200010 A 15 20883 31 05930357800114 Thomson and Rutherford, in discussing the constitution of atoms, assume that the elements out of which atoms are built are charged particles. Which of the following does not constitute part of the 3 ___ evidence for this view? A. Coulomb's law for the electrostatic force between point charges B. the fact that all conductors contain charges that are free to move C. the fact that the properties of dielectrics are accounted for by the hypothesis of their "polarization" in electric fields D. the ejection of alpha and beta particles in radioactive decay E. the identity of the properties of cathode rays derived from 9 various sources ETS2WVW 2200011 D 15 20893 31 05830513800116 Dalton's atomic theory is A. a good example of absolute truth B. a good example of the static view of science C. correct, and led to more scientific discoveries D. partially in error, but led to more scientific discoveries 9 E. neither correct nor in error. Nothing more was done about it. ETS2WVW 2200012 E 15 20897 31 06070287800116 A physicist, using the accumulated data concerning the nature of the atomic nucleus, constructed a model of the nucleus of a certain atom. In doing this, he used the physical laws known to describe the behavior of large_scale phenomena. He discovered, however, that the theoretical behavior of his model did not agree with the actual behavior of the atomic nucleus. After checking carefully his original data, checking carefully his mathematics, and trying models of the nuclei of the atoms of several different elements, the results still did not agree. If all of the statements in the above paragraph are accepted as true, the most acceptable conclusion would be that A. the physical laws describing the behavior of large_scale phenomena were incorrect. B. the atomic nucleus behaved independently of natural laws. C. he must have made a mistake in the way that he constructed his model. D. the accepted system of mathematics was incorrect. E. the physical laws operating in the case of the large_scale ETS2WVW 9 phenomena and the small_scale phenomena may not be entirely consistent with one another. 2200013 CAEDA 55 20912 31 0097034180011290 MACROITEM STEM 2The following questions refer to various processes related to 2atomic or molecular structure. For each item select from the key the 2changes involved in the process. 2 A. Only electron changes between atoms 2 B. Alteration in the number of protons and neutrons 2 C. Alteration only in the number of neutrons 2 D. Changes in arrangement of all particles in the atom 2 E. No change in relation to the number of electrons, protons, 0 or neutrons in the atom MACRO SUB_ITEM # 1 1 Differences between two isotopes of the same element MACRO SUB_ITEM # 2 2 Electrolytic conduction MACRO SUB_ITEM # 3 3 Fractional distillation MACRO SUB_ITEM # 4 4 Fission MACRO SUB_ITEM # 5 9 Rubbing a Rubber rod with a piece of wool 2200014 ADCABBE 75 20921 51 0357035100151490 MACROITEM STEM 2For each of the items, mark 2 A. if it should be regarded as supported by the agreement 2 of Rutherford's calculations with experimental data. 2 B. if it is a presupposition of Rutherford's calculations 2 which is in no need of support, since its validity is 3 _____________________ 2 guaranteed by purely mathematical considerations. 2 C. if it is presupposed either in Rutherford's calculations 2 or in his general considerations concerning the structure 2 of atoms and is in no need of support from Rutherford 3 _____________________________________ 2 because it is implied by physical considerations other 2 than Rutherford's 2 D. if it is implied by other considerations than Rutherford's 2 and must be regarded as true, but is hard to reconcile 3 _________________ 2 with Rutherford's results, and so points the way to further 3 _________________________ 2 investigation. ETS2WVW ETS2WVW 2 E. if it is a presupposition of Rutherford's calculations which 2 cannot be regarded as supported by any arguments set forth 2 by Rutherford or by other considerations understood at 2 the time, but is rather a pure assumption which remains 0 for further testing. MACRO SUB_ITEM # 1 The scattering of particles by thin foils of metal is produced in such a way that the observed deflection of any particle through a large angle must have been produced at a single encounter with an 1 atom. MACRO SUB_ITEM # 2 An atom must contain negative charges in the form of "electrons" 5 _8 or light particles, arranged within the atomic radius of 10 cm. 2 In such a way as to form a stable configuration. MACRO SUB_ITEM # 3 Atoms are composed of electrically charged particles, the negative charges occuring in corpuscles of very small mass and the atom as a 3 whole normally being electrically neutral. MACRO SUB_ITEM # 4 The mass and a large part of the positive or negative charge in an 4 atom is concentrated in a very minute volume at its center. MACRO SUB_ITEM # 5 The atoms in a metal foil can be regarded as practically fixed in 5 position during an interaction with an alpha particle. MACRO SUB_ITEM # 6 A body whose acceleration varies inversely as the square of its distance from a point and is always directed away from that point, 6 moves in a hyperbola with that point as a focus. MACRO SUB_ITEM # 7 The force between two point charges at distances of the order of 5 _12 magnitude of 10 cm. or more, is correctly predicted by 9 Coulomb's law. 2200015 B 15 20954 31 05830513800111 Four of the following five statements are assumptions which make up Dalton's atomic theory. You are to select the one which was not 3 ___ formulated as one of Dalton's assumptions, but which is the result of other research. A. Every element consists of tiny particles. B. The tiny particles in some elements consist of two or more atoms. C. The atoms of any one element are all exactly alike. D. In general, atoms combine in simple ratios. ETS2WVW 9 E. Atoms of one element may combine with atoms of another element to form a new substance or compound. 2200016 B 15 20963 31 03510185800111 In a neutral atom, the total positive charge on the nucleus is equal to the total A. positive charge of all electrons B. negative charge of all electrons C. charge, both positive and negative D. charge of all neutrons and protons 9 E. charge of all protons and electrons ETS2WVW 2200017 C 15 20967 31 05130351800111 Which one of the following statements about atomic structure is incorrect? 3_________ A. There are particles in the nucleus which add mass to the atom but do not affect the electrical charge. B. The volume of an atom is not determined by the space occupied by the nucleus. C. Each atom is composed of a negatively charged nucleus. D. Almost the entire mass of the atom is concentrated in the nucleus. E. The atomic number of an atom is the same numerically as the 9 number of protons in the nucleus. ETS2WVW 2200018 C 15 20975 31 03510263800111 According to our ideas of atomic structure, we say that it takes more electrical energy to remove an electron from a helium atom than from a hydrogen atom because A. helium initially has two electrons B. the helium nucleus has a greater mass C. the helium nucleus has a greater charge D. when hydrogen converts to helium (as in the stars) energy is released 9 E. helium has neutrons in its nucleus ETS2WVW 2200019 A 15 20981 31 03370351800111 In order to determine the atomic number of any atom, it is 3 ___ sufficient to know the number of A. protons in the nucleus B. neutrons in the nucleus C. protons minus the number of electrons D. protons minus the number of neutrons 9 E. neutrons plus the number of protons ETS2WVW 2200020 E 15 20986 51 04950592800112 The quantity u, the initial speed of the alpha particles, can best be measured by A. sending the same beam of alpha particles through metal foils of different thickness, and comparing the average deflection with the thickness in each case. B. sending the same beam of alpha particles through metal foils of different thickness, and comparing the various results for the fraction of particles deflected through a given angle. C. determining the minimum thickness of a given substance required to stop all of the alpha particles. D. determining the force exerted by the beam of alpha particles upon a static electric charge of known magnitude at a given distance from the beam, and the rise in temperature produced in a block of metal when the beam falls upon the block and is completely stopped. E. subjecting the beam of alpha particles to electric and magnetic fields at right angles to the beam, adjusting the intensities e and H until no deflection is produced, and applying the law that the electric force on a charge q 9 moving with speed u is eq, the magnetic force Hqu. ETS2WVW 2200022 A 15 21002 31 05930041800112 Thomson's concept of the arrangement of electric charges in the atom is derived chiefly from considerations concerning A. the spectra of elements B. the theory of multiple scattering of alpha and beta particles C. the periodic table D. the possible stable arrangements of charges 9 E. the photoelectric effect ETS2WVW 2200023 A 15 21007 31 03570272800112 Which of the following is a piece of evidence, not available to Rutherford at the time of his experiments on alpha particle scattering, which today provides overwhelming confirmation of the view that atoms are built of charged particles? A. The existence of an uncharged particle, the neutron, which can be scattered by atomic nuclei, but which follows a scattering law quite different from that of the alpha and beta particles. B. The identity of alpha particles with charged atoms of helium. C. The identity of beta particles with the particles composing cathode rays. D. The success of Bohr's theory of the atom in accounting for the periodic table of the elements. ETS2WVW 9 E. The formula for the wave lengths in the line spectrum of hydrogen. 2200024 C 15 21018 51 05830065800112 In order to determine the atomic weight of an element by Dalton's method, it is sufficient to know A. the composition by weight of a compound of the element B. whether compounds of the element are binary, ternary, etc. C. both the composition by weight of a compound of the element, and the class (i.e., binary, ternary, etc.) to which the compound belongs D. the composition by weight of a large number of compounds of the element E. the density of the element relative to that of the standard 9 element ETS2WVW 2200025 C 15 21026 51 05940292800112 Avogadro postulates that molecules are composed of more than one "elementary molecule" since A. the different gaseous elements have different specific densities. B. some gases apparently contract when combining. C. his postulate about number of molecules in a volume of gas would otherwise be inconsistent with the ratios between combining volumes of gases. D. his postulate about the number of molecules in a volume of gas would otherwise be inconsistent with the ratios between total volumes of component gases and the volumes of the compound gases. 9 E. this is the simplest hypothesis possible. ETS2WVW 2200026 A 15 21035 51 02920594800112 Avogadro postulates an equal number of molecules in equal volumes of gas under the same conditions primarily on the grounds that A. the laws of combining volumes of gases can be deduced directly from this postulate B. the laws involving temperature, pressure and volume of gases can be deduced directly from this postulate C. Dalton's observed atomic weights are inconsistent with Dalton's hypotheses about chemical combination D. this furnishes an adequate explanation of the simple combining ratios by volume observed in gas reactions E. correct molecular weights are obtainable by application of 9 the postulate ETS2WVW 2200027 BEAE 45 21044 31 0351039880011190 ETS2WVW MACROITEM STEM 2The following questions are concerned with the men or experiments 2which helped to establish the electron theory of matter. For each 2question select from the key the most closely related idea. 2 A. The mass of the atom. 2 B. That the atom is mostly empty space and the plus 2 charges concentrated. 2 C. Measure of the number of protons present in the nucleus. 2 D. Revealed the presence of charged particles derived 2 from atoms. 0 E. None of these. MACRO SUB_ITEM # 1 1 Rutherford bombarded gold foil with alpha particles in 1911 MACRO SUB_ITEM # 2 2 Moseley's experiments of 1914 MACRO SUB_ITEM # 3 3 Aston's spectrograph MACRO SUB_ITEM # 4 9 Millikan's oil drop experiment 2200028 DBEDAC 65 21052 31 0398058005741190 MACROITEM STEM 2The following questions refer to various features of atomic 2structure. For each item select from the key the experimental method 2that was most important in establishing it. 2 A. Measurements with the mass spectrograph. 2 B. Millikan's oil drop experiment. 2 C. Deflection of cathode rays in a magnetic field. 2 D. Measurements of the wave lengths of characteristic 2 lines in the x_ray spectra. 0 E. Deflection of alpha particles by foils of metals. MACRO SUB_ITEM # 1 The atomic number is equal to the number of extra_nuclear 1 electrons. MACRO SUB_ITEM # 2 5 _10 2 The charge on the electron is 4.802 x 10 esu. MACRO SUB_ITEM # 3 The positive charge of the atom is concentrated in a small, 3 compact nucleus. MACRO SUB_ITEM # 4 The electrons of an atom are arranged in energy levels about 4 the nucleus. MACRO SUB_ITEM # 5 5 Atoms of the same element may have different atomic weights. MACRO SUB_ITEM # 6 ETS2WVW 5 _28 9 The mass of the electron is 9 x 10 gm. 2200029 CB 24 21064 31 0263006580011190 MACROITEM STEM 2The following questions refer to comparisons which are frequently 2made in science. For each item select from the key the most 2appropriate response. 2 A. The first is greater than the second. 2 B. The first is equal to the second. 2 C. The first is less than the second. 0 D. More data is required to compare them. MACRO SUB_ITEM # 1 The number of electrons in a sodium ion compared to 1 the number of protons in its nucleus. MACRO SUB_ITEM # 2 9 The atomic weight of helium compared to its molecular weight. 2200030 D 15 21071 31 03510342800111 Basically the atom is generally conceived as A. a solid spherical mass which is neutral in charge B. a nucleus and electrons all traveling in the same plane but at various energy levels C. paired groups of electrons and protons, widely but uniformly distributed D. a nucleus of protons and generally neutrons with as many electrons as protons traveling in orbits around the nucleus E. having an atomic weight equal to the weight of the neutrons 9 and the electrons 2200031 AADADAEC 85 21078 51 0171020080011190 MACROITEM STEM 2The following questions refer to various processes related to 2atomic or molecular structure. For each item select from the key the 2changes involved in the operation of the process. 2 A. Electron changes between atoms 2 B. Alteration in the number of protons and neutrons 2 C. Alteration in the number of neutrons only 2 D. No change in the number of electrons, protons, or neutrons 2 in the atom 0 E. Changes in all particles MACRO SUB_ITEM # 1 1 Photosynthesis MACRO SUB_ITEM # 2 2 Rubbing a glass rod with a piece of silk MACRO SUB_ITEM # 3 ETS2WVW ETS2WVW 3 Distillation MACRO SUB_ITEM # 4 4 Ordinary chemical reaction MACRO SUB_ITEM # 5 5 Isomerism in carbon compounds MACRO SUB_ITEM # 6 6 Ionization MACRO SUB_ITEM # 7 7 Fission MACRO SUB_ITEM # 8 9 Changes in atomic weight without Change in atomic number 2200032 BADBCA 64 21087 51 0337058780011190 MACROITEM STEM 2After the number on the answer sheet which corresponds to that of 2each of the following items, blacken space 2 A. if the item is true of atomic number 2 B. if the item is true of mass number 2 C. if the item is true of atomic weight as given in the 2 periodic table 0 D. if the item is true of atomic size or volume MACRO SUB_ITEM # 1 The different isotopes of a given element differ in this respect, 1 for example U_235 and U_238. MACRO SUB_ITEM # 2 Determines the position of every element listed in the periodic 2 table. MACRO SUB_ITEM # 3 Is most closely related to the ease with which an element in any given group in the periodic table gains or loses electrons from 3 the highest energy level. MACRO SUB_ITEM # 4 Can be determined for each isotope of an element by deflection of gaseous ions of the element in electrostatic and electromagnetic 4 fields. MACRO SUB_ITEM # 5 None of the individual atoms of an element may have the value of this. It is a kind of average of the values pertaining to the 5 isotopes of the element. MACRO SUB_ITEM # 6 Equals the number of planetary electrons in the neutral atom of an 9 element. 2200033 BCE 35 21101 31 0293026380011190 MACROITEM STEM 2The following questions refer to the "building blocks" of matter. 2For each item select from the key the correct response. ETS2WVW ETS2WVW 2 2 2 2 0 A. Molecule B. Neutron C. Atom D. Electron E. Proton MACRO SUB_ITEM # 1 A particle which accounts for some elements having several atomic 1 weights MACRO SUB_ITEM # 2 The smallest particle of a pure substance that can exist and retain 2 all its properties MACRO SUB_ITEM # 3 9 The charged particle found only in the nucleus 2200034 B 15 21107 31 03510342800111 It is generally supposed that the atom is A. a solid but elastic sphere B. a positively charged mucleus and one or more planetary electrons C. a negatively charged nucleus and one or more planetary protons D. an equal number of positrons and electrons distributed in pairs E. a negatively charged nucleus and an equal amount 9 of positive charge distributed around it ETS2WVW 2200035 D 15 21113 31 04950189800111 The smallest particle of any chemical element that can exist by itself and retain the qualities that distinguish it as an element is the A. electron B. proton C. neutron D. atom 9 E. molecule ETS2WVW 2200036 B 15 21116 31 03510065800111 Numbers expressing how much heavier one kind of atom is than another kind of atom, are known as A. atomic numbers B. atomic weight C. symbols of the elements D. molecular weights 9 E. chemical formulae ETS2WVW 2200037 E ETS2WVW 15 21119 31 03510196800111 5 1 All atoms, with the exception of H, are composed of 4 1 4 1 A. ions, plutons and cathode rays B. molecules, geigers and electrons C. neutrons, electrons and alpha particles D. radioactivity, lead and protons 9 E. protons, electrons and neutrons 2200038 D 15 21124 52 051305720272 During the twentieth century classical atomic theory has been substantially revised by certain key experiments and by quantum theory. Which of the following statements is representative of classical atomic theory? A. All atoms have their mass concentrated in a very small fraction of their volume, called the nucleus. B. The atom is composed of protons, neutrons and electrons. C. Electrons in matter are more conveniently described as waves than as particles. D. All atoms of the same element have the same mass. 9 E. The atomic number is the number of protons in the nucleus. 0044 2200039 A 15 21132 31 05130342 The nucleus of an atom is: A. positively charged and has a high density. B. negatively charged and has a high density. C. positively charged and has a low density. D. negatively charged and has a low density. 9 E. none of these. 0028 2200040 C 15 21136 31 03510513 Atoms are best described as having A. protons and electrons in the nucleus, and electrons outside the nucleus with the number of electrons equal to the number of protons. B. protons, neutrons, and electrons in the nucleus, and also electrons outside the nucleus. C. protons and neutrons in the nucleus, and electrons outside the nucleus with the number of protons equal to the number of electrons. D. protons and neutrons in the nucleus, and electrons outside the nucleus with the number of protons equal to the number of neutrons. E. protons and neutrons in the nucleus and electrons outside the nucleus with the number of neutrons equal to the 9 number of electrons. 0028 2200041 D 14 21146 31 05130710 How would Dalton's atomic theory explain the law of conservation of matter? A. It is obvious by weighing the reactants and then the products that no matter is lost nor gained. B. The ratio of the weights of the atoms composing a molecule of a compound is the macroscopic ratio of weights of the elements in the compound. C. Molecules are composed of a definite ratio of whole atoms. D. In a chemical reaction, the atoms forming the molecules of the reactants are simply regrouped to form the molecules 9 of the products. 0026 2200042 B 14 21154 31 05130710 Each of the following is a part of Dalton's atomic theory except one. Which is it? A. All atoms of a given element are alike especially in weight B. Atoms contain a nucleus composed of protons and neutrons C. Atoms are indivisible D. Atoms unite in whole number ratios to form molecules of 9 compounds. 0026 2200043 B 14 21159 31 035305130710 Dalton's concept of the atom was considered insufficient because of all of the following discoveries but one. A. Cathode rays B. Isotopes C. Natural radioactivity 9 D. Law of constant composition. 2200045 C 14 21162 31 06170583 What part of Dalton's theory was shown to be wrong by the discovery of radioactivity? A. The ultimate particle of a compound in a molecule B. Atoms are permanent, unchanging bodies C. Atoms of a given element all weigh the same D. Two or more kinds of atoms may combine in different ways to 9 form more than one kind of molecule. 2200046 E 15 21167 31 0263 5 + H __> H + ___ A. alpha particle B. neon atom C. neutron D. proton 9 E. electron 2200047 D 14 21169 31 035104950244 0026 0026 0020 0009 Experimental support for the existence of atoms and subatomic particles includes all of the following except: A. radioactive decay B. electrical discharge through gases C. metal foil scattering of alpha particles 9 D. continuous mechanical subdivision of a single crystal 2200048 A 14 21173 52 057814140495 In a mass spectrometer, which of the following statements is true for positive ions in which one electron has been removed from the atom? A. The lightest particles are deflected the most B. The particles gain electrons C. The heaviest particles are deflected the most 9 D. All particles are deflected to the same extent 0019 2200049 B 15 21178 31 051303510342 Each of the following is a part of the postulates of atomic theory except one. Which is it? A. All atoms of a given element are similar to one another. B. Atoms contain a nucleus composed of protons and neutrons. C. Atoms are considered to be indestructible. D. Only whole atoms can participate in or result from a chemical reaction. 9 E. All atoms of a given element have similar chemical properties 0040 2200050 B 15 21184 32 035714650358 In the Rutherford gold_foil experiment, the fact that most of the alpha particles were not deflected by the gold foil indicates that A. the nucleus is positively charged B. the atom is mostly empty space C. atoms are solid spheres touching each other D. gold is very dense 9 E. gold is composed of many atoms. 0040 2200051 A 15 21189 31 058305130345 Dalton based his atomic theory partially on A. the law of definite composition B. the electrical conductivity of substances C. the law of combining volumes D. aristotle[s concepts of matter 9 E. the valences of the various elements 0034 2200052 D 15 21193 31 035706161373 Which of the following was not proposed by Ernest Rutherford? 0034 3 ___ A. the nature of alpha rays B. the nature of beta rays C. the nature of gamma rays D. the nature of x_rays 9 E. all of the above were proposed by Rutherford 2200053 A 15 21197 31 035703511571 Rutherford based his solar system model of the atom partly on the fact that A. deflections of alpha particles were extremely rare on passing through metal foils B. deflections of alpha particles were quite frequent but usually the deflections were by small angles C. occasionally alpha particles were captured by the atomic nucleus D. all of them passed through the metal foils undeflected 9 E. none of them passed througn the metal foils undeflected 0034 2200054 D 14 21204 52 018903531291 An element has an isotope containing the same number of protons and neutrons in its nucleus. Its mass number is 40. How many electrons will it have in its outermost shell? 3 _________ 9 A. eight B. six C. four D. two E. five 0038 2200055 C 14 21208 32 035403370065 Argon has a smaller atomic number, but a higher atomic weight than potassium. This inconsistency is due to: A. more protons in the argon nucleus B. more electrons in the outer shell of argon C. more neutrons in the argon nucleus 9 D. a larger number of electron shells in the K atom 0038 2200056 C 15 21212 32 034203410065 If the nucleus is composed only of protons and neutrons, how many neutrons are present in the nucleus of the element of atomic weight 119 and atomic number 50? 9 A. 119 B. 79 C. 69 D. none of these E. 65 0038 2210001 A 15 21215 32 03610351800112 According to the Bohr theory of the atom, the inert gases are most accurately characterized as elements whose atoms have A. the greatest possible number of electrons in the state with the highest principal quantum number occuring in the most stable configuration of the atom B. both very high ionization energy and very little ability to ETS2 OS 9 attract additional electrons C. no ability to lose electrons D. no ability to gain electrons E. no ability to gain or to lose electrons 2210002 D 15 21222 32 00150019800112 It was realized during the nineteenth century that the characteristic physical and chemical properties of the metallic elements can be explained as due to a tendency of their atoms to become positively charged. This tendency is accounted for in Bohr's theory of the atom as a direct result of metallic atoms having A. few electrons B. many electrons C. relatively low ionization energy in their most stable states D. electrons in the outermost electron shell 9 E. quantum numbers greater than those of non_metallic atoms ETS2 OS 2210005 C 15 21229 51 03610159800114 The principal reason for the existence of the problem attacked by Bohr was that A. while radiation is emitted by atoms in a discrete fashion as far as frequency is concerned (line spectra), the emission nevertheless appears to be continuous in time. B. the observed scattering of alpha particles, according to Rutherford, is compatible only with a nuclear model of the atom. C. radiation phenomena indicate that, since atoms emit light, they must lose energy, and thus cannot exist in "stationary" states of constant energy; on the other hand, stationary states are required to account for the stability of the atom. D. the Rutherford atom could not be stable if its electrons were at rest, nor, according to Maxwell's electrodynamics, if they were in motion; on the otherhand, the Planck_Einstein theory of radiation involved concepts different from and contradictory to those of Maxwell's theory. E. the fact that elements have characteristic spectra, exhibited by them both in the uncombined state and in compounds, indicates that these spectra are due to processes within 9 individual atoms. ETS2 OS 2210006 C 15 21245 51 03420351800111 1. The nucleus of an atom contains only protons and electrons as separate particles. 2. The number of electrons in an atom in the normal ETS2WVW state equals the number of protons. 3. The nucleus of an atom contains protons and neutrons. 4. The number of neutrons in an atom always gives the atomic number. 5. An atom may lose one or more electrons in ordinary chemical reactions. Which of the following choices lists all and only those statements above which are correct according to the theory of the Bohr atom? A. 1 and 3 B. 2 and 4 C. 2, 3 and 5 D. 2, 3, and 4 9 E. 1, 2, and 3 2210007 B 15 21253 51 0224035102631290 2The first set of relationships established by Bohr in his 2discussion of systems consisting of a single electron revolving 2about a nucleus is given by the formulae ETS2WVW 5 1/2 3/2 1/2 w = (2 ) x (u )/(p x e x e x m )/u 4 1 1 2 2 4 2 x r =(e x e )/u 1 2 2where w is the orbital frequency of an electron of charge e and 4 1 2a mass m moving about a nucleus of charge e in an orbit of radius r 4 2 and ionization energy u. The importance of these relationships in Bohr's theory lies in the fact that A. they give the radius of the orbit and the frequency of revolution as functions of the charge of the electron. B. they give the radius of the orbit and the frequency of revolution as functions of the charge of the nucleus. C. they give the radius of the orbit and the frequency of revolution as functions of the ionization energy. D. they express Bohr's hypothesis concerning the necessary and sufficient conditions for the existence of stationary states. 9 E. they determine the size of the atom. 2210008 AC 25 21298 52 0357035100391390 ETS2WVW MACROITEM STEM 0 Answer the following questions. MACRO SUB_ITEM # 1 In Rutherford's calculations, he assumes that the atom with which an alpha particle interacts is at rest during the interaction. The mass of a gold atom is approximately 50 times the mass of an 5 9 alpha particle. If a single alpha particle, moving at 2 x 10 cm./sec., meets a gold atom and is deflected through 180 degrees, emerging at the same speed with which it entered, and if the total momentum of the particle and the atom is the same before and after the encounter, the atom must have acquired a speed of A. zero 5 _2 B. 2 x 10 cm./sec. C. 1 cm./sec. 5 7 D. 8 x 10 cm./sec. 5 8 1 E. 5 x 10 cm./sec. MACRO SUB_ITEM # 2 In the light of the considerations given in the preceding item, which of the following remarks is justified concerning the status of Rutherford's assumption that the atoms are stationary? A. In the experiments cited by Rutherford, the speeds of the alpha 5 9 particles were only 1.7 and 1.8 x 10 cm./sec., so that the result of the calculation in the preceding item is not directly relevant. B. Rutherford is entitled to assume that the forces between the atoms, which give the metal its solidity, prevent any one atom from acquiring a high speed; the momentum imparted by the encounter is therefore not carried by a single atom, but shared among many. C. The considerations given in the preceding item bear out Rutherford's assumption that the velocity imparted to the atom is either zero or insignificant. D. The considerations given in the preceding item are not easily reconciled with Rutherford's assumption; hence, since that assumption is required to derive his results (which accord with experiment), some modification of classical mechanics__ possibly giving up the law of the conservation of momentum__ is indicated. E. Rutherford's assumption is not affected by the considerations given, since that assumption has the status of a working hypothesis which is justified as long as it leads to results 9 borne out by experiment. 2210009 B 14 21328 32 1110 05 Almost all the mass of an atom is due to A. its protons and electrons C. its protons B. its neutrons and protons D. its neutrons 9 E. its neutrons and electons 2210010 B 15 21331 31 01480357800114 The failure of classical physics, applied to the Rutherford atom model, to account for the stability of the atom leads Bohr to attempt to answer the question A. Do there exist other processes which classical physics is unable to explain? B. How can we explain the existence of stable atoms, in which electrons circulate around the nucleus but do not produce radiation? C. How can we determine which of the imaginable orbits of the electron in the atom are in fact stable (classical physics not withstanding)? D. If electrons circulating about nuclei do not emit radiation, then what becomes of the energy which, according to classical physics, should be emitted in this fashion? E. If the light emitted by atoms does not constitute 9 electromagnetic radiation, then what sort of process is it? ETS2WVW 2210011 E 15 21343 31 03420263800116 The attraction of the nucleus for electrons diminishes as the invervening space increases. Which of the following is the best experimental evidence for this statement? A. Alkali metals have many properties in common. B. Gas spectra consist of a series of sharp lines. C. Beta_ray emission does not change the atomic weight of the radioactive element. D. Iodine is chemically less active than is chlorine. 9 E. None of the above is good evidence. ETS2WVW 2210012 D 15 21350 31 03610351800111 The Bohr picture of the atom A. was devised to explain combining weights B. fails to explain why rapidly moving alpha particles ionize gases C. explains a negative electrovalence of one by setting up the 3 ___ electron configuration 2,8,9 D. explains the line spectrum of hydrogen ETS2WVW 9 E. explains the complete ionization of electrovalent compounds 2210013 E 15 21356 31 03610590800111 According to the Bohr theory, visible radiations of light from atoms or molecules are directly due to A. small particles ejected from the nuclei of the atoms B. photons absorbed by the atoms C. revolution of the electrons in their orbits D. electrons jumping from an inner to an outer orbit 9 E. electrons falling from an outer to an inner orbit ETS2WVW 2210014 D 14 21361 31 03510263 In the Bohr model of the atom, the electrons revolve around the nucleus of an atom so as to A. emit spectral lines B. produce x_rays C. form energy levels that depend upon their speeds only 9 D. keep from falling into the nucleus 0041 2210015 D 14 21365 31 03510263 According to the Bohr model of the atom, an electron in a stable orbit A. radiates electromagnetic energy continuously B. emits only spectral lines C. remains there forever 9 D. can jump to another orbit if given enough energy 0041 2210016 C 14 21369 31 026305860342 An electron can revolve in an orbit around an atomic nucleus without radiating energy provided that the orbit A. is far enough away from the nucleus B. is less than a de broglie wavelength in circumference C. is an integral number of de broglie wavelengths in circumference 9 D. is a perfect circle 0041 2210017 C 15 45649 32 059403610347 Which of the following is not a main postulate of the Bohr theory? 3 ___ A. The electron moves around a heavy positively charged nucleus in a circular orbit. B. Only certain orbits (energy levels) are allowed. C. An atomic orbital is a region in space where there is a 90% probability of finding an electron. D. Any loss or gain in the energy of the electron must come from transitions from one energy level to another. 9 E. All of the above ARE main postulates of the Bohr theory. 0018 2210018 A 15 21381 51 134502630586 According to the Bohr postulates of the atom A. electrons can have only certain allowed energies B. electrons must remain in fixed orbits C. orbits closest to the nucleus have the highest energy D. all electrons are the same distance from the nucleus 9 E. none of these 0020 2210019 E 15 21385 31 006902900330 Bohr's atomic model was built around an explanation of A. the ionization potentials of the elements B. the transition elements C. wave mechanics D. chemical bonding 9 E. the spectrum of hydrogen 0034 2300001 D 15 21388 31 00140306006511 Why is the weight of carbon_12 a good standard upon which to base the relative atomic weights of other elements? A. It is heavy. B. It is of relatively low density. C. It unites with many other elements. D. It is readily available. 9 E. It unites with no other elements. ETS2WVW 2300002 A 15 21392 31 03660065800111 In order to apply Cannizzaro's method for determining the atomic weight of an element, one must know, in addition to composition by weight of several of its compounds, A. the specific gravities of several compounds in the vapor state B. the specific heat of the element C. either the data in A or that in B D. the specific heats of several compounds of the element 9 E. all of the data in A, B, and D. ETS2WVW 2300003 C 15 21398 31 03980351800111 The mass of an atom is concentrated in a very small part of the total volume of the atom, that is, the nucleus. This statement is substantiated most by the observation that A. gases can be compressed into very small volumes. B. gases diffuse through one another. C. alpha particles penetrate thin sheets of gold. D. atoms neither gain nor lose mass during chemical reactions. 9 E. light passes through many substances. ETS2WVW 2300004 D ETS2WVW 15 21404 31 04450351800111 The relative weights of atoms may be determined most appropriately by the A. zinc_sulphate fluorescent screen B. Wilson cloud chamber C. Geiger counter D. mass spectrograph 9 E. electron microscope 2300005 D 15 21407 31 00650351800111 The atomic mass of most atoms depends almost entirely upon the mass of the A. electrons of the atom B. protons of the atom C. electrons and protons of the atom D. protons and neutrons of the atom 9 E. electrons and neutrons of the atom ETS2WVW 2300006 D 15 21411 31 00650351800111 The atomic weight of most atoms depends almost entirely upon 3 ______ the weight of the A. electrons of the atom B. protons of the atom C. electrons and protons of the atom D. protons and neutrons of the atom 9 E. electrons and neutrons of the atom ETS2WVW 2300007 BDCCA 55 21415 52 0158006680011390 MACROITEM STEM 2Gaseous element X has a specific gravity (relative to oxygen) of 20.94; gaseous element Y has a specific gravity of 3.75. they form 2three gaseous compounds with each other, the combining weights 2and specific gravities being tabulated below. 2 Specific 2 Combining weights gravities 2compound I 1g X+2g Y 2.8 2compound II 1g X+4g Y 1.2 2compound III 1g X+8g Y 4.2 2(the atomic weight of oxygen is 16.0; its molecule contains 2two atoms.) 0 Using this information, answer the following questions. MACRO SUB_ITEM # 1 Which of the compounds would be considered as binary according to Dalton's method for determining atomic weight? A. Compound I B. Compound II ETS2WVW 1 2 3 4 9 C. Compound III D. All of these are equally likely to be binary. E. None of these could be binary, since no ratio is 1:1. MACRO SUB_ITEM # 2 Using Dalton's method, the atomic weight of element Y is calculated to be A. two B. twice that of element X C. three D. four times that of element X E. eight MACRO SUB_ITEM # 3 How would the application of Cannizzaro's method for determining the atomic weight of element Y constitute an improvement over Dalton's method? A. By identifying the spatially separate particles of element Y as molecules instead of atoms B. By postulating that the molecules of element Y consist of two atoms C. By utilizing molecular weights calculated from the specific gravities listed D. By defining atomic weights in terms of oxygen as a standard instead of hydrogen E. By yielding absolute atomic weights rather than merely relative atomic weights MACRO SUB_ITEM # 4 What are the relative volumes of the gases involved in the formation of compound I? A. 1 of X and 1 of Y yield 2 of compound I. B. 1 Of X and 2 of Y yield 2 of compound I. C. 2 Of X and 1 of Y yield 2 of compound I. D. 1 Of X and 2 of Y yield 3 of compound I. E. The data give NO information on this matter. MACRO SUB_ITEM # 5 Division of the molecule of element Y must have occured in the formation of A. compound I only B. compound II only C. compounds I and II, but not III D. compound III only E. none of these compounds 2300008 C 15 21444 31 03980351800111 The mass of an atom is most closely related to the sum of the masses of its A. protons alone ETS2WVW 9 B. protons and electrons C. protons and neutrons D. neutrons alone E. electrons alone 2300009 D 15 21447 31 03510097800112 If an atom has 9 protons and 10 neutrons in its nucleus, and 9 planetary electrons, its atomic weight is probably A. 9 B. 10 C. 18 D. 19 9 E. 28 ETS2WVW 2300010 A 15 21450 31 00650189800111 In general, the atomic weight of an element is equal to A. the sum of the weights of the protons and neutrons in the nucleus B. twice the atomic number C. the molecular weight in grams D. the sum of the protons and the planetary electrons 9 E. the sum of the neutrons and the valence electrons ETS2WVW 2300011 C 15 21455 31 00650014800111 The present_day table of atomic weights is based upon an arbitrary weight assigned to A. hydrogen B. salt C. carbon D. water 9 E. oxygen ETS2WVW 2300012 B 15 21458 52 071101 If the atomic weight of carbon had been assigned exactly 100 amu, instead of 12 amu, the atomic weight of oxygen would have been 9 A. 104 B. 133 C. 16 D. 128 E. none of these 2300013 B 14 21461 31 111001890337 The atomic mass of an element in amu is A. always equal to or less than its atomic number B. always equal to or greater than its atomic number C. equal to its atomic number except in the case of isotopes D. sometimes greater and somtimes smaller than its atomic 9 number 2300014 B 15 21465 32 03510065 0064 0041 0047 5 21 In 0.37 g of X there are 3.01 x 10 atoms of X. The atomic weight of X is 5 _1 _1 _1 A. 37.0 g mole B. 74.0 g mole C. 142.0 g mole 5 _1 _1 9 D. 35.5 g mole E. 16.0 g mole 2300015 C 15 21469 52 141500650189 The principle of Dulong and Petit states that the product of the atomic weight of a solid element and its specific heat, measured at room temperature, is approximately 6.2 cal per g_atom per degree. A prospector has asked you to identify the most abundant element in a mineral sample he has found. You chemically separate the most abundant element and determine that its 5 _1 specific heat is 1.11 x 10 cal per gram per degree. What is the element? 9 A. Be B. Mg C. Fe D. Ni E. Cu. 0044 2300016 B 15 21476 32 111003530341 The atomic mass of an isotope of chlorine,Cl,having eighteen neutrons is 9 A. 18 B. 35 C. 36 D. 35.45 E. none of these 0018 2300017 E 15 21478 31 03510445 The weight of an atom depends on A. the number of electrons B. the number of protons and electrons C. the number of neutrons and electrons D. the number of protons 9 E. none of these 2300018 C 14 21481 31 006514130351 The atomic weight of chlorine is 35.5. This means that A. the actual weight of a Cl atom is not known more accurately than to three digits B. a variable number of electrons gives a fractional value C. on the average, an atom of Cl weighs almost three times as much as an atom of carbon 9 D. chlorine occurs with a variable number of protons 2300019 D 14 21486 32 006503981315 Suppose the atomic weight scale had been set up with calcium, Ca, chosen for a mass of exactly 10 units, rather than about 40 on the present scale. On such a scale, the atomic weight of oxygen would be about 0018 0009 0009 9 A. 64 B. 32 C. 16 D. 4 2300020 B 14 21490 31 006507140634 The most direct method for determining atomic weights is: A. gas density measurements B. mass spectroscopy 9 C. combining weights D. alpha_particle scattering 0009 2300021 D 15 21493 32 006503530189 Element A exists in three isotopic forms with weights of 21.0, 25.0, and 26.0 respectively. Element B also exists in three isotopic forms with weights of 22.0, 24.0, and 26.0 respectively. It is true that A. element A will have a higher atomic weight than B. B. element B will have a higher atomic weight than A. C. they will have identical atomic weights since the sum of their isotopic weights are equal. D. you cannot predict which atomic weight is greater from the data given. 9 E. no correct response is given. 0040 2300022 A 15 21501 32 033703530006 Chlorine consists of two naturally occurring isotopes with weights of 35.0 and 37.0 amu. The atomic weight of natural chlorine is 35.453 amu. It is true that A. chlorine_35 is present on the largest amount. B. chlorine_37 is present in the largest amount. C. chlorine_35 and chlorine_37 are present in exactly equal quantities. D. the two are present in about equal quantities. 3 _____ 9 E. it is impossible to determine from given information. 0040 2300023 C 15 21508 31 006501890353 The atomic weight of an element is: A. the weight of any single atom of that element B. the weight of a particular isotope of that element C. the average weight of atoms of that element compared to a standard D. the average weight of a particular isotope of that element compared to a standard 9 E. a multiple of the weight of carbon. 0040 2300024 D 15 21513 32 035103420065 If an atom has 9 protons and 10 neutrons in its nucleus, and 9 planetary electrons, its atomic weight is probably 9 A. 9 B. 10 C. 18 D. 19 E. 28 0035 2300025 C 14 21516 32 02070065 The specific heat of calcium is: A. 0.273 cal/g_deg B. 0.232 cal/g_deg C. 0.157 cal/g_deg 9 E. 0.102 cal/g_deg 0003 2300026 B 14 21518 32 02070065 If the specific heat of nickel is 0.105, the approximate atomic weight of this element is: 9 A. 34 B. 60 C. 120 D. 6.7 0003 2300027 B 14 21520 52 19451313 The present atomic weight scale is based on A. natural carbon 5 12 B. C C. natural oxygen 5 16 9 D. O 0056 2300028 A 15 21522 52 071101 Given the substances: nitrogen, manganese, nickel, silver, silicon, and magnesium. Arranged left to right in order of increasing atomic weight, the chemical symbols are: A. N, Mg, Si, Mn, Ni, Ag B. N, Mg, S, Mn, Ni, Si C. Ni, Mn, Si, Mg, N, Ag D. N, Mn, Sc, Mg, Ni, Si 9 E. N, Mg, Sc, Mn, Ni, Ag 0064 2300029 E 15 21527 52 071101 A compound of formula AB contains 40% A by weight. The atomic 4 3 weight of A must be A. one_half that of B. B. equal to that of B. C. three times that of B. D. one_third that of B. 9 E. twice that of B. 0064 2300030 D 15 21531 52 071101 Consider the compound X Y that is 60.0% X and 40.0% Y by weight. 4 25 From these data, it can be concluded that the ratio of the atomic weight of X to the atomic weight of Y is 9 A. 1.50 B. 0.667 C. 1.33 D. 3.75 E. 2.67 0064 2300031 C 15 21535 52 071101 Atom Z is found to be 12.0 times as heavy as a carbon atom. You wish to prepare a compound that contains 2 atoms of carbon for 0064 every 1 atom of Z. If 1.00 g of carbon is used, how many grams of Z are required? 9 A. 12.0 B. 48.0 C. 6.00 D. 3.00 E. 24.0 2300032 A 15 21539 52 071101 A 2.0000_gram sample of element X reacted with oxygen to form 2.5392 grams of the compound XO . Taking 16.00 amu for the atomic 4 2 weight of oxygen, determine the identity of element X. 9 A. Sn B. Si C. Co D. Ti E. C 0064 2310001 E 15 21543 51 03530351800111 An isotope is A. a new but unstable element B. a new compound C. a form of an element which has different chemical properties but the same weight as another form of that element D. an old previously_known compound with the same chemical characteristics but a new molecular weight E. an atom of an element which has the same chemical characteristics as another atom of the element but 9 different atomic weight ETS2WVW 2310002 B 15 21549 31 03530573800111 Separation of the isotopes of uranium requires a physical method rather than a chemical method because A. it is too dangerous to mix other chemicals with uranium. B. they are chemically the same element. C. they differ in number of neutrons. D. it is the heaviest element in nature. 9 E. natural uranium contains only 0.7% U_235. ETS2WVW 2310003 A 15 21554 31 05820591800111 In positive_ray analysis A. a combination of magnetic and electrical fields sorts out atoms according to their atomic number. B. cathode rays are separated into groups according to their ratio of mass to charge. C. positively charged atoms are split into groups according to their group number in the periodic table. D. atoms of the same mass and charge hit a photographic plate at the same point. E. isotopes of the same element converge to the same point 9 on a photographic plate. ETS2WVW 2310004 D ETS2WVW 15 21562 31 03530351800111 In which of the following ways did the discovery of isotopes change our ideas of the nature of atoms? A. it demonstrated that atoms can be broken down into smaller particles. B. it demonstrated that there is NO such thing as a pure atom. C. it has made the distinction between an atom and a molecule less clear. D. it indicated that the mass of the atom does not determine its chemical properties. E. it indicated that an element probably does not consist of 9 atoms. 2310005 C 15 21569 31 03390351800112 The atomic number of lithium is 3. Some atoms of lithium have 3 neutrons but most have 4 neutrons so that the atomic weight is 6.9. This shows that lithium A. has two valences B. is not a pure substance C. exists as two isotopes D. has a negative valence 9 E. has several distributions of its electrons ETS2WVW 2310006 A 15 21574 31 05640342800111 A deuteron is A. the nucleus of a heavy hydrogen atom B. a neutron with two positive charges C. an electron with a positive charge D. a type of large molecule 9 E. an atom of a recently discovered element ETS2WVW 2310007 E 15 21577 31 05640342800111 Isotopes are elements A. with two or more forms, like graphite and the diamond B. with the same atomic weight but different molecular weights C. which have both positive and negative valences D. which can exist in two or more states at the same temperature E. with the same atomic number but a different number of 9 neutrons ETS2WVW 2310008 B 15 21582 31 01890353800111 A chemical element is found to consist of serveral substances of different atomic weights but identical chemical properties. These substances are called A. allotropic forms B. isotypes C. electrons ETS2WVW 9 D. deuterons E. isobars 2310009 A 15 21586 31 03510189800111 The atoms of a given element may differ in atomic weight, have different physical characteristics and yet not vary chemically. This is because of a variation in the number of their A. neutrons B. electrons C. protons D. two of the above 9 E. all of the first three ETS2WVW 2310010 E 15 21590 31 03530189800111 An isotope is A. a new but unstable element B. a new compound C. a form of an element which has different chemical properties but the same weight as another form of that element D. an old previously known compound with the same chemical characteristics but a new molecular weight E. an atom of an element which has the same chemical characteristics as another atom of the element but 9 different atomic weight ETS2WVW 2310011 E 15 21597 31 04950189800111 A particle which accounts for some elements having several atomic weights is the A. molecule B. electron C. proton D. ion 9 E. neutron ETS2WVW 2310012 D 14 21600 31 Tritium has an atomic weight of A. 1 B. 2 C. 4 9 D. 3 084700658004 2310013 E 15 21601 31 03530189800111 Isotopes of a given element differ only in A. position in the periodic table 2WVW ETS2WVW 9 B. number of electrons outside the nucleus C. atomic numbers D. positive charge of the nucleus E. number of neutrons in the nucleus 2310014 D 14 21604 An isotope of hydrogen is A. neptunium B. plutonium C. thorium 9 D. tritium 31 035301968004 2310015 D 15 21606 31 03530351800111 Isotopes are A. atoms having the same nuclear charge and the same mass B. atoms having different nuclear charges and the same mass C. atoms having different nuclear charges and different masses D. atoms having the same nuclear charge and different masses 9 E. atoms having negative nuclear charges 2WVW ETS2WVW 2310016 B 14 21611 32 0353 05 Two isotopes of the same element contain different numbers of A. electrons C. protons 9 B. neutrons D. protons and electrons 2310017 A 14 21613 31 035301898004 Isotopes of a particular element differ in all of the following except A. chemical properties B. nuclear structures C. atomic masses 9 D. density 2 OS 2310018 C 14 21616 31 019603538004 The hydrogen atom isotope which consists of one proton, one neutron and one electron is known as A. hydronium B. plutonium C. deuterium D. tritium 9 E. the alpha particle 2 OS 2310019 B 14 21619 31 035301898004 Isotopes of a particular element have a different number of A. electrons 2 OS 9 B. neutrons C. protons D. energy levels 2310020 B 14 21621 31 035301898004 Isotopes of a particular element have a different number of A. electrons B. neutrons C. protons 9 D. energy levels 2 OS 2310021 A 14 21623 31 033703538004 The atomic number of the isotopes of hydrogen is A. always 1 B. sometimes 2 C. 3, since there are three isotopes 9 D. 1.0078 2 OS 2310022 B 14 21625 31 035103420097 Atoms whose nuclei contain the same numbers of protons but different numbers of neutrons are called 9 A. alpha particles B. isotopes C. radioactive D. positrons 0041 2310023 E 15 21628 32 035301890351 If two isotopes of a certain element are known, it follows that some of the atoms of that element: A. have different numbers of protons in their nuclei B. have different number of positrons in their nuclei C. have different chemical properties D. are naturally radioactive 9 E. have different numbers of neutrons in their nuclei. 0042 2310024 C 14 21633 32 02930445 The following two molecules have practically the same weight: A. H O and D O B. H O and HOT 4 2 2 2 C. D O and HOT D. DOT and HOD. 94 2 2310025 E 15 21636 52 018903530204 A hypothetical element has the following isotopic composition: isotope mass percent abundance 76 75.9217 27.6 78 77.9212 72.4 What is the atomic weight of the element? (75.9217 + 77.9212) 0043 0044 A. (27.6)(75.9217)+(72.4)(77.9212) B. ___________________ 2 9 (76 + 78) C. _________ D. 75.9217 + 77.9212 E. none of the above. 2 2310026 C 15 21643 52 018900650353 A hypothetical element has atomic weight 33.51 grams/gram_atom. It is composed of two isotopes of mass 33.92 and 32.93. What is the percentage of the heavier isotope? 9 A. 0.415 B. 1.41 C. 58.5 D. 41.5 E. 71.1. 0044 2310027 D 14 21646 31 10550669034051 5 3 4 5 The species He, He, and He represent three 4 2 2 2 9 A. allotropes B. isomers C. homologs D. isotopes E. conformers 9000 2310028 B 15 21649 51 039803530454 The mass of an isotope is ____________ the sum of the masses of the individual constitutents. A. greater than B. less than C. about the same as D. may be greater than or less than 9 E. cannot predict 0018 2310029 B 15 21652 32 006505130353 542 Ca has 420 A. 22 protons in the nucleus. B. 22 neutrons in the nucleus. C. 22 electrons outside the nucleus. D. 20 neutrons in the nucleus. 9 E. 20 electrons in the nucleus. 0028 2310030 B 15 21656 52 5 20 Element X was found to come in two forms: 90.0% 4 10 What is the atomic mass of element X? 9 A. 20.1 B. 20.2 C. 20.8 D. 21.2 E. 21.8 2310031 B 15 21660 32 006503530341 22 X and 10.0% 10 X. 0028 An isotope having an atomic number of 22 and a mass number of 49 would have A. 27 protons in the nucleus B. 27 neutrons in the nucleus C. 27 electrons outside the nucleus D. 22 neutrons in the nucleus 9 E. none of these 2310032 B 14 21664 31 051303530065 Two isotopes of the same element must necessarily differ in their A. atomic numbers B. atomic weights 9 C. number of electrons D. charge. 0026 2310033 B 14 21666 31 006503410353 An atom of an element has an atomic weight of 75 and an atomic number of 35. How many neutrons per atom? 9 A. 35 B. 40 C. 75 D. 110. 0026 2310034 D 15 21668 Heavy water contains A. deuterium oxide B. deutrium C. heavy hydrogen D. all of these 9 E. none of these 0020 31 116507880196 2310035 D 15 21670 31 035301960847 The hydrogen isotope with an atomic mass of 3.00 is A. deuterium B. deuterium oxide C. heavy water D. tritium 5 2 E. D 94 1 2310036 E 15 21672 31 122412251226 A major use for radioactive isotopes occurs in A. tracer experiments B. medicine C. agriculture research D. industry 9 E. all of these 2310037 D 15 21675 31 03530337 Isotopes A. must have the same mass B. have different nuclear charges C. contain the same number of neutrons D. must have the same atomic number 0020 0020 0020 9 E. none of these 2310038 E 15 21678 31 035303370342 5 84 The isotope Kr 4 36 A. has a mass number of 84 B. contains 48 neutrons C. has a nucleus with a +36 charge D. has an atomic number of 36 9 E. all of these 0020 2310039 E 15 21681 31 035313390189 An isotope is defined as A. elements with the same atomic mass B. elements with the same number of neutrons C. different compounds containing the same elements D. an element with atoms containing the same number of protons but slightly different numbers of electrons E. an element with atoms containing the same number of protons 9 but slightly different numbers of neutrons 0020 2310040 E 15 21687 31 081203420353 The symbol for the nucleus of an isotope of gallium, element number 31, atomic mass 69.72, is 5 31 101 31 69.72 70 A. Ga B. Ga C. Ga D. Ga E. Ga 4 70 31 69 31 31 9 0020 2310041 D 15 21691 52 018903530065 An element in its naturally occurring form is made up of 85% of an isotope of mass 24.0 amu and 15% of an isotope of mass 26.0 amu. The atomic mass of this element is 9 A. 24.85 B. 26.15 C. 24.7 D. 24.3 E. 25.0 0019 2310042 A 14 44638 31 035301890337 An isotope of an element A. has the same atomic number, but different mass number B. disintegrates to yield the radiation of energy and a new element C. has the same atomic mass but a different atomic number D. has an inequality in the number of protons and electrons 9 E. has a different arrangement of atoms 0019 2310043 A 0019 14 21698 31 084703420097 The tritium nucleus consists of ______. A. one proton and two neutrons B. one proton and one neutron C. one proton and two electrons 9 D. one proton and three neutrons 2310044 B 15 21701 31 035308120189 Which of the following pairs of symbols represent isotopes of one element? 5 2 5 10 11 10 10 A. X and X B. X and X C. X and X 4 1 2 4 4 5 4 5 5 5 D. X and X 4 1 2 9 E. both C and d 0040 2310045 C 15 21705 31 035308120341 5 65 The symbol Zn indicates that this isotope contains 4 30 0040 9 A. 35 protons and 35 neutrons B. 35 protons and 30 neutrons C. 30 protons and 35 neutrons E. 30 protons and 65 neutrons 2310046 B 15 21708 31 034200970353 Isotopes of the same element differ from each other in what way? A. They have different numbers of protons in the nucleus. B. They have different numbers of neutrons in the nucleus. C. They have different numbers of electrons outside the nucleus. D. Both A and C 9 E. both B and C. 2310047 B 15 21713 31 03530573 Which pair represents isotopes? 5 54 54 235 238 A. Cr and Fe B. U and U 4 24 26 92 92 5 116 116 239 239 C. Cd and Sn D. Np and Pu 4 48 50 93 94 5 4 3 E. He and Li 0040 0040 94 2 3 2310048 C 15 21718 31 018903530578 To determine whether or not a given element has isotopes, scientists A. seek chemical reactions which will separate different forms. B. use the fog_track apparatus. C. use the mass spectrograph of Aston. D. use a centrifuge so that the heavier atoms will be separated from the lighter ones. 9 E. use a zinc sulfide flourescent screen. 0035 2310049 C 15 21723 31 033703510065 The atomic number of lithium is 3. Some atoms of lithium have 3 neutrons but most have 4 neutrons so that the atomic weight is 6.9. This shows that lithium A. has two valences B. is not a pure substance. C. exists as two isotopes. D. has a negative valence. 9 E. has several distributions of its electrons. 0035 2310050 C 14 21728 31 035313760578 Which of the following is the best indication of the existence of isotopes? A. the fact that some elements are more reactive than others B. the deflection of alpha particles on passing through thin sheets of metals C. the appearance of more than one line in the mass spectrum of an element in the mass spectrometer D. the appearance of more than one line in the emission 9 spectrum of an incandescent element 0038 2310051 A 15 21734 32 035103420540 Two different atoms, X and y, have the same number of protons in the nucleus, but the atom of Y has two more neutrons in its nucleus than the atom of X. What may we infer from this information? A. both atoms have the same valence B. if the valence of X is 2, the valence of Y is 4 C. both atoms have the same atomic weight D. the atom of Y has two more electrons than an atom of Y E. the percentage of X in the oxide of X is the same as the 9 percentage of Y in the oxide of Y 0038 2310052 A 14 21741 52 1944 0055 Isotopes of the same element have A. different neutron numbers B. different atomic numbers C. the same atomic masses 9 D. the same mass numbers 2310053 B 14 21744 52 1944 Suppose that in nature three isotopes of element X occur as fol_ lows: Isotope Atomic mass % 1 110.0 60.0 2 105.0 30.0 3 100.0 10.0 The atomic mass (weight) of the naturally occurring mixture of X is A. 315.0 B. 107.5 C. 105.0 9 D. 102.5 0055 2310054 C 14 21750 52 1945 Suppose that in nature a certain element consists of two isotopes with masses of 24 U and 28 U occurring in percentages of 25% and 75%, respectively. Calculate the average mass of an atom of this element in nature. A. 25 U B. 26 U C. 27 U 9 D. 52 U 0056 2310055 A 14 21754 52 194708470097 5 3 The number of protons in a tritium atom ( H) is: 9 A. 1 B. 2 C. 3 D. 0 2330001 B 15 21756 52 80018003 13 The relative abundance of the two rubidium isotopes of atomic weights 85 and 87 are 75% and 25%, respectively. The average atomic weight of rubidium is A. 85 B. 85.5 C. 86 D. 86.5 9 E. 87 2330002 C 15 21759 32 018903530065 0058 ETS2WVW 0047 5 69 The element gallium consists of 60% Ga isotope, (mass=68.93amu) 5 71 and 40% Ga isotope (mass 70.93 amu). Calculate the atomic weight of normally occurring gallium. 9 A. 68.93 B. 69.10 C. 69.73 D. 70.93 E. 70.50 2330003 C 15 21763 31 011301950569 Which of the following gases is not one of the four that account for 99.997% by volume of clean dry air? A. nitrogen B. oxygen C. krypton D. carbon dioxide 9 E. none of these(i.e.,all are) 0018 2330004 D 15 21766 31 041501890025 The most abundant element on the earth's crust is A. carbon B. nitrogen C. iron D. oxygen 9 E. water 0020 2330005 B 15 21768 31 041501890196 The most abundant element in the universe is A. oxygen B. hydrogen C. nitrogen D. carbon 9 E. iron 0020 2330006 E 15 21770 31 130804150196 In the whole solar system the most abundant elements are A. oxygen an iron B. iron and oxygen C. carbon and oxygen D. silicon and oxygen 9 E. hydrogen and helium 0020 2330007 D 15 21773 32 018911590353 An element in its naturally occurring form is made up of 15 percent of an isotope of mass 26.0 amu and 85 percent of an isotope of mass 24.0 amu. The atomic mass of this element is 9 A. 25.0 B. 26.15 C. 24.7 D. 24.3 E. 24.85 0020 2330008 E 15 21777 31 041501891376 105 different elements are known to exist. Which of the following statements relating to these elements is correct? 3 _______ A. All of these elements are found in nature. B. The last of these elements was discovered prior to 1940. C. Although they do not occur in exactly equal abundance in nature, their abundances are very close to being equal. D. The first letter of the symbol of each element begins with the same letter as does the element[s name. 9 E. Some of the elements were man made. 0040 2330009 C 15 21785 31 041500250350 The two most abundant elements in nature are A. oxygen and hydrogen B. carbon and silicon C. silicon and oxygen D. nitrogen and oxygen 9 E. chlorine and fluorine 0040 2330010 B 15 21788 52 041503530065 The relative abundance of the two rubidium isotopes of atomic weights 85 and 87 are 75% and 25%, respectively. The average atomic weight of rubidium is 9 A. 85. B. 85.5 C. 86. D. 86.5 E. 87. 0035 2330011 B 15 21791 31 The most abundant element (by mass) in the human body is 9 A. hydrogen B. oxygen C. carbon D. nitrogen E. water 2500001 A 15 21793 31 03380353800112 The electron structure of a certain neutral isotope is specified as follows: 2 electrons in K level, 8 electrons in L level, and 7 electrons in M level. Of what element is the above an isotope? A. chlorine B. oxygen C. fluorine D. beryllium 9 E. nitrogen 2500002 A 15 21797 31 03510263 12 The diagram below symbolizes the structure of a particular atom. The symbols contained within multiple parenthesis represent the structure of the inner core, and the number in front of the right parenthesis represents the outer electrons. Which of the following choices best describes this diagram? OS86 ETS2 OS ETS2 OS (18p) (22n) 8) (10e) 9 A. an argon atom B. an argon ion C. a chlorine ion D. a potassium ion E. a potassium atom 2500003 E 15 21804 52 63038003301111 Which of the following is the best evidence that electrons are arranged in definite energy levels? A. Electrons in the beta_ray have a very high energy. B. All elements do not have identical properties. C. Electrons rotate about the nucleus. D. The penetrating power of cathode ray electrons depends on the voltage used to produce them. E. Atomic spectra consist of sharp lines, not continuous bands 9 of color. ETS2WVW 2500004 E 15 21810 31 00020351800111 A sodium atom (atomic number 11) which has lent an electron in a chemical reaction, that is, has become a sodium ion, contains (select the most complete answer) A. only completely filled electronic energy levels B. an incompletely filled electronic energy level C. a number of electrons greater than the number of protons D. a number of protons greater than the number of electrons 9 E. two of the above ETS2WVW 2500005 A 15 21816 31 03460351800111 The third shell (or principle energy level) of an atom of neon (atomic number 10) contains A. 0 electrons B. 2 electrons C. 8 electrons D. 10 electrons 9 E. 18 electrons ETS2WVW 2500006 A 15 21819 31 00650002800113 The atomic weight of sodium is 23. when we start with hydrogen and arrange the elements in the order of their increasing atomic numbers, sodium is 11th on the list. From this we may determine the number of neutrons in the nucleus of the sodium atom to be A. 12 ETS2WVW 9 B. 11 C. 34 D. equal to the total number of electrons in the orbits about the nucleus E. equal to the electrons in the outermost orbit or energy level 2500007 D 15 21825 31 01960028800111 Hydrogen combines easily with non_metals because A. it is the lightest of the elements B. it consists of two electrons C. it is a gas D. it has an unfilled electronic energy level 9 E. it has a completely filled electronic energy level ETS2WVW 2500008 A 15 21829 31 03370189800111 Given only the atomic number of an element, which of the following quantities could you find? A. the number of electrons B. the atomic weight C. the number of neutrons in the nucleus D. the number of isotopes 9 E. all of the above ETS2WVW 2500009 C 15 21833 31 03510263800111 The chemical nature of the atom is determined by the A. atomic weight B. number of neutrons C. electrons D. weight of the protons 9 E. kind of charge in the nucleus ETS2WVW 2500010 A 15 21836 31 03370189800111 The atomic number of an element A. is the number of electrons outside the nucleus B. is the number of neutrons in the nucleus C. is the number of atoms in 22.4 liters of the gas at S.T.P. D. follows, for all the elements, the same order as the atomic weights E. is the quotient obtained by dividing the atomic weight by the 9 valence ETS2WVW 2500011 E 15 21841 31 03510342800112 A certain atom is symbolized as shown below. The numbers in front of the right parenthesis represent the outer electrons. The symbol (12p, 13n) represents the nuclear structure. What is the element whose isotope is represented? ETS2 OS 9 (12p,13n) 2) 8) 2) A. manganese B. calcium C. carbon D. aluminum E. magnesium 2500012 C 15 21846 31 00660293800112 Two atoms are symbolized below. The symbols contained within multiple parenthesis represent the structure of the inner core, and the numbers in front of the right parenthesis represent the outer electrons. What compound is represented by the following two structures joined together? ( 11p) ( 17p) ( 12n) 2) 8) and ( 18n ) 2) 8) 8) A. nitrogen bromide (NBr) B. lithium chloride (LiCl) C. sodium chloride (NaCl) D. sodium bromide (NaBr) 9 E. potassium chloride (KCl) ETS2 OS 2500013 B 14 21854 31 035102638004 Since an atom is electrically neutral, the number of electrons equals the number of A. neutrons B. protons C. neutrons minus protons 9 D. protons minus neutrons 2 OS 2500014 A 14 21857 31 033701890342 The atomic number of an element is the number of A. protons in its nucleus B. neutrons in its nucleus C. electrons in its nucleus 9 D. protons and neutrons in its nucleus 0041 2500015 E 15 21860 31 033703420513 From the following statements, select the one which is not a 3 ___ correct statement about atomic numbers. A. The atomic number gives the number of electrons outside the nucleus of an atom. B. The atomic number gives the positive charge on the nucleus. C. The atomic number subtracted from the mass number gives the number of neutrons. D. The atomic number is equal to the number of protons in the nucleus. 0028 9 E. The atomic number equals the number of neutrons in the nucleus. 2500016 D 15 21868 31 033701890097 The atomic number of an element is identical to A. the atomic mass B. the number of electrons in the ion C. the number of neutrons in the nucleus D. the number of protons in the nucleus 9 E. more than one of the above 2500017 C 14 21872 52 1944 Which statement is incorrect? For any atom, the atomic number equals the number of A. protons in the nucleus B. electrons in the neutral atom C. neutrons in the nucleus 9 D. nucleons minus the number of neutrons 2500018 ADBC 45 21875 32 0338002003411290 MACROITEM STEM 2The diagram below symbolizes the electronic configuration of the 2atom of a particular element. The symbol (n) represents the 2nucleus, and the number in front of each right parenthesis 2represents the number of electrons contained in that shell. 2 (n) 2) 8) 8) 1) 0 Based on the diagram above, answer the following questions. MACRO SUB_ITEM # 1 The valence of this element is 1 A. 1 B. 3 C. 5 D. 7 E. 9 MACRO SUB_ITEM # 2 The atomic number of this element is 2 A. 2 B. 8 C. 16 D. 19 E. 21 MACRO SUB_ITEM # 3 If the nucleus contains 21 neutrons, the atomic weight of this element is 3 A. 2 B. 40 C. 16 D. 19 E. 21 MACRO SUB_ITEM # 4 This element can be characterized as A. an inert gas B. an oxidizing agent C. a reducing agent D. a non_metal 9 E. none of these 2510001 B 15 21885 31 03510339800113 0034 0055 ETS2 OS ETS2WVW If an atom of lithium containing 3 protons and 4 neutrons unites with an atom of fluorine containing 9 protons and 10 neutrons, the ion of lithium in the compound LiF will have A. 2 protons B. 3 protons C. 4 protons D. 12 protons 9 E. none of these 2510002 D 15 21889 31 06050263800114 The Pauli "exclusion principle", which asserts that no two electrons in an atom can agree in the values of all four of their quantum numbers, provides the theoretical basis for understanding A. the relation of spectral_line series to atomic structure in atoms more complex than that of hydrogen B. the forces which hold the components of molecules together C. the relation of the properties of an atom connected with radiation to its chemical behavior D. the periodic structure of electron shells 9 E. the possibility of Bohr's "stationary states" ETS2WVW 2510003 E 15 21897 31 00020351800111 A sodium atom (atomic number 11) which has lent an electron in a chemical reaction, that is, has become a sodium ion, contains A. only completely filled electronic energy levels B. an incompletely filled electronic energy level C. a number of electrons greater than the number of protons D. a number of protons greater than the number of electrons 9 E. two of the above ETS2WVW 2510004 D 15 21903 31 03378001026311 The atomic number of a certain element is 53. An atom of this element must contain A. 53 neutrons B. 26 neutrons and 27 protons C. 1 neutron, 26 protons and 26 electrons D. 56 electrons 9 E. 53 particles of all kinds ETS2WVW 2510005 E 15 21907 31 03518001035011 Atoms of the element silicon contain 14 protons. How many electrons are there in the outer valence electron shell of the silicon atom? A. This cannot be determined from the number of protons. B. 14 C. 12 D. 6 ETS2WVW 9 E. 4 2510006 C 15 21911 31 80010351009712 If the nucleus of a neutral atom is assumed to consist of 22 neutrons and 18 protons, the atomic number of the atom would be A. 40 B. 22 C. 18 D. 4 9 E. none of these ETS2WVW 2510007 B 15 21914 31 01920337800112 In chemical combination, a substance with an atomic number of 12 should A. acquire a valence of _1 B. acquire a valence of +2 C. acquire a valence of _2 D. acquire a valence of +4 9 E. be inert ETS2WVW 2510008 BCEBA 55 21917 31 0015018980011290 MACROITEM STEM 2Answer the following questions by referring to the key below. 2 Atomic atomic electronic number weight structure 2 A. 6 12 24 2 B. 11 23 281 C. 18 40 288 2 D. 12 24 282 2 E. 17 35 287 2(Electronic structure refers to the number of electrons in the 0 respective orbits.) MACRO SUB_ITEM # 1 1 The most active metal listed MACRO SUB_ITEM # 2 2 An inert element MACRO SUB_ITEM # 3 3 The element having exactly 18 neutrons in the nucleus MACRO SUB_ITEM # 4 4 The best reducing agent in the list MACRO SUB_ITEM # 5 9 An element forming compounds by sharing electrons ETS2WVW 2510009 C 14 21925 31 026301898004 The electronic configuration of the element xenon is A. 2_8_8 2WVW 9 B. 2_18_18_1 C. 2_8_18_18_8 D. 2_8_18_28_8_2 2510010 B 14 21927 31 034400198004 The potassium ion has the same arrangement of electrons as the element with atomic number A. 11 B. 18 C. 36 9 D. 37 2WVW 2510011 B 14 21929 31 026303468004 The maximum number of p electrons in any shell is A. 2 B. 6 C. 14 9 D. 8 2WVW 2510012 B 14 21931 31 026303468004 The maximum number of electrons found in the K shell of an atom is A. 8 B. 2 C. 18 9 D. 32 2WVW 2510013 A 14 21933 31 084600198004 The hydride ion has the same electron configuration as an atom of A. helium B. lithium C. beryllium 9 D. hydrogen 2WVW 2510014 D 14 21935 31 026301898004 The most probable electron configuration for element number 28 would be which one of the following? A. 2,8,18 B. 2,8,10,8 C. 2,8,8,8,2 9 D. 2,8,16,2 2WVW 2510015 ADBC 45 21938 32 8001002003411290 MACROITEM STEM 2The diagram below symbolizes the electronic configuration of the 2atom of a particular element. The symbol (n) represents the ETS2 OS 2nucleus, and the number in front of each right parenthesis 2represents the number of electrons contained in that shell. 2 (N) 2) 8) 8) 1) 0 Based on the diagram above, answer the following questions. MACRO SUB_ITEM # 1 The valence of this element is A. 1 B. 3 C. 5 D. 7 1 E. 9 MACRO SUB_ITEM # 2 The atomic number of this element is A. 2 B. 8 C. 16 D. 19 2 E. 21 MACRO SUB_ITEM # 3 If the nucleus contains 21 neutrons, the atomic weight of this element is A. 2 B. 40 C. 16 D. 19 3 E. 21 MACRO SUB_ITEM # 4 This element can be characterized as A. an inert gas B. an oxidizing agent C. a reducing agent D. a non_metal 9 E. none of these 2510016 C 15 21949 52 8003 How many electrons can be accomodated in the orbitals that comprise the fourth quantum shell? A. 8 B. 18 C. 32 D. 40 9 E. 72 2510017 A 14 21951 31 002380040263 Fluorine has an atomic number of 9 and a mass of 19. The number of electrons in the l shell of the atom is 2WVW 2 OS 9 A. 7 B. 2 C. 9 D. 10 2510018 A 14 21953 31 018902688004 An element having an octet of electrons has the atomic number A. 10 B. 3 C. 6 9 D. 4 2510019 D 15 21955 31 07238003 How many electrons can be accommodated in all the atomic orbitals that correspond to the principal quantum number 4? 9 A. 2 B. 8 C. 18 D. 32 E. 40 2 OS 2WVW 2510020 D 14 21958 31 058703421683 The mass number of a nucleus is equal to the number of its 9 A. electrons B. protons C. neutrons D. nucleons 0041 2510021 C 15 21960 31 026303470346 How many electrons can be accomodated in the orbitals that comprise the fourth quantum shell? 9 A. 8 B. 18 C. 32 D. 40 E. 72 0042 2510022 E 15 21962 52 091302631296 A "d" sub_shell can contain no more than: A. three pairs of electrons B. three orbitals C. seven pairs of electrons D. five electrons 9 E. five un_paired electrons. 0042 2510023 E 15 21965 52 03380189 The ground state electron configuration of gas phase titanium is 5 1 3 9 A. 3d 4s 2 2 B. 4s 4p 3 1 C. 3d 4s 4 D. 3d 0042 2 2 E. 3d 4s 2510024 A 15 21969 52 090901590263 Considering negative quantum numbers to be those of lowest energy, what are the four quantum numbers of the "last" electron to be added when the argon atom is formed? n l m s A. 3 1 1 +1/2 B. 3 0 1 _1/2 C. 3 1 _1 +1/2 0042 9 D. 3 E. 3 1 0 _1 0 _1/2 +1/2 2510025 A 15 21974 32 09091211 Which of the following pairs of quantum numbers represent impossible situations? A. n = 3 l = 3 B. n = 4 l = 2 C. n = 5 l = 0 D. l = 1 m = 1 E. l = 1 m = 0 94 l l 2510026 D 15 21977 52 0338 Which of the following electron configurations is incorrect? 5 2 A. alkaline earth metals: ns n>1 5 1 B. Rb: (Kr)5s 5 + 2 6 C. Na : (He)2s 2p 5 1 5 D. Cr : (Ar)4s 3d 9 E. all the above configurations are correct. 2510027 C 15 21982 52 09130263 How many unpaired electrons are there in p? 9 A. 1 B. 2 C. 3 D. 4 E. none, p is diamagnetic. 0047 0044 0044 2510028 D 15 21984 31 026303420097 Which statement is always true? A. The nucleus of an atom contains neutrons and electrons. B. The atomic number of an element is the number of neutrons in one atom. C. The atomic mass of an atom is the number of protons in the nucleus plus the number of electrons outside. D. The number of electrons outside the nucleus is the same as number of protons in the nucleus in a neutral atom. 9 E. None of these 0018 2510029 E 15 21990 52 033800640019 Which of the following ions does not have the electronic configuration of the inert gas krypton,Kr? 5 + 2+ _ 2_ A. Rb B. Sr C. Br D. Se E. none of these(i.e.,all of them have the electronic 9 configuration of Kr) 0018 2510030 A 0028 15 21994 31 072303380376 The correct representation of the electronic structure in 5 34 sublevels for S is: 4 16 5 2 2 6 2 4 2 2 6 2 6 2 A. 1s , 2s 2p , 3s 3p D. 1s , 2s 2p , 3s 3p , 4s 4p 4 5 2 2 6 6 B. 1s , 2s 2p , 3p 6 2 2 6 2 6 2 E. 1s , 2s 2p , 3s 3p , 4s 4p 5 2 2 6 2 5 9 C. 1s , 2s 2p , 3s 3p 2510031 C 15 22000 31 072303380376 5 31 3_ Write the electronic configuration in sublevels for P . 4 15 5 2 2 6 2 3 A. 1s , 2s 2p , 3s 3p 5 2 2 6 2 5 B. 1s , 2s 2p , 3s 3p 5 2 2 6 2 6 C. 1s , 2s 2p , 3s 3p 5 2 2 6 2 D. 1s , 2s 2p , 3s 9 E. none of these 0028 2510032 D 15 22006 51 123102630380 The total number of electrons that can theoretically be accommodated in the seventh energy level? 9 A. 72 B. 56 C. 32 D. 98 E. 196 0020 2510033 E 15 22008 51 13561357 5 3 The notation 4f designates A. 4 electrons in the f sublevel where l=3 B. 4 electrons in the n = 3 energy level, l = 3 C. 3 electrons in the n = 3 energy level, l = 3 D. 3 electrons in the l = 2, n = 3 level 9 E. none of these 2510034 D 15 22012 51 033808441358 The ground state electronic configuration of a nickel atom can be represented as 5 2 2 6 2 6 2 6 2 0020 0020 A. 1s 2s 2p 3s 3p 4s 4p 5s 5 2 2 6 2 6 2 2 6 B. 1s 2s 2p 3s 3p 3d 4s 4p 5 2 2 6 2 6 10 C. 1s 2s 2p 3s 3p 3d 5 2 2 6 2 6 8 2 D. 1s 2s 2p 3s 3p 3d 4s 9 E. none of these 2510035 E 15 22017 51 The f level can hold a total of A. 6 electrons B. 10 electrons C. 32 electrons D. 8 electrons 9 E. 14 electrons 136112310263 0020 2510036 B 15 22019 51 136313640263 The rule of Hund says A. electrons in the outer energy level cannot pair B. no pairing of electrons is permitted until every orbital in the outer energy level has at least one electron C. p orbitals can contain no more than 4 unpaired electrons D. d orbitals can contain no more than 5 electrons 9 E. none of these 0020 2510037 A 15 22024 51 060411780809 The electronic structure for the chloride ion is 5 2 2 6 2 6 A. 1s 2s 2p 3s 3p 5 2 2 2 6 B. 1s 2s 3s 3p 5 2 2 2 5 C. 1s 2s 3s 3p 5 2 2 6 2 5 D. 1s 2s 2p 3s 3p 9 E. none of these 0020 2510038 D 15 22028 32 02630380 How many electrons can be located in the sixth energy level? 9 A. 8 B. 50 C. 32 D. 72 E. 103 2510039 C 15 22030 31 026303801301 The total number of electrons which can theoretically be accommodated in the seventh energy level is 9 A. 56 B. 72 C. 98 D. 196 E. none is correct 0019 0019 2510040 E 15 22033 52 009903510942 Which of the following neutral atoms is diamagnetic? A. Cl B. K C. Ti D. CO E. Cd 94 17 19 22 27 48 0019 2510041 B 15 22035 52 009903511423 Which of the following neutral atoms has the most unpaired electrons? A. V B. Mn C. Co D. Ni E. Zn 94 23 25 27 28 30 0019 2510042 C 15 22038 52 033801891362 What common feature characterizes the electronic configuration of elements 21, 27, 40, and 43? A. They all have only one electron in a subshell B. They all have a filled 5s subshell C. They all have a partially filled d subshell D. They all have a partially filled p subshell 9 E. None of these is correct 0019 2510043 D 15 22043 31 091503730073 Which of the following elements have electronic configurations that involve a total of exactly eight s electrons? A. Ca B. Sr C. Ga D. both A and C 20 38 31 9 E. both A and B 0040 2510044 B 15 22046 31 136203470338 Consider the following electron configuration: 5 2 2 6 2 6 1s 2s 2p 3s 3p . Which of the following pieces of information is consistent with it? A. There are 6 electrons in the 3p orbital B. There are 6 electrons in the 3p subshell C. There are 6 electrons in the number 3 shell D. both B and C 9 E. All choices are correct. 0040 2510045 B 15 22051 31 033804030189 The correct electron configuration for element 53 (iodine) is 5 2 2 6 2 6 10 2 6 10 7 A. 1s 2s 2p 3s 3p 3d 4s 4p 4d 4f 5 2 2 6 2 6 2 10 6 2 10 5 B. 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 5 2 2 6 2 6 2 10 6 14 3 0040 C. 1s 2s 2p 3s 3p 4s 3d 4p 4f 5 2 2 6 2 6 2 6 2 5 D. 1s 2s 2p 3s 3p 4s 4p 5s 5p 5 2 2 6 2 6 3 6 2 10 5 9 E. 1s 2s 2p 3s 3p 4s 4p 5s 4d 5p 5p 2510046 E 15 22058 52 5 2 2 6 2 3 Which element has the electron configuration 1s 2s 2p 3s 3p ? 9 A. Na B. Mg C. Al D. Si E. P OS 2510047 C 15 22061 31 033807940025 5 4 The distinguishing electron configuration of np is charateristic of which group in the periodic table? 9 A. IIa B. IVa C. VIa D. rare gases E. IIIa 0040 2510048 A 15 22064 32 117803380005 When a strontium atom (Sr, # 38) reacts to form an ionic 5 2+ compound, it becomes a strontium ion (Sr ). The electronic configuration of the ion is the same as 5 2+ 2_ 9 A. Kr B. Rb C. Xe D. Ca E. Zr 0040 2510049 B 15 22068 31 033800421178 Which one of the following has an electronic configuration different from the others? 5 2+ + 2_ 2+ 9 A. Ar B. Mg C. K D. S E. Ca 0040 2510050 A 15 22071 31 004211780562 5 2+ The electronic configuration of the Mg is the same as 9 A. Ne B. Si C. Ar D. Na E. Ca 0040 2510051 D 14 22073 32 105503380351 Which one of the following species has the same electron configuration as the argon atom? 5 + _ _ 9 A. Ne B. Na C. S D. Cl 0009 2510052 C 14 22076 32 033811781358 5 2_ The electronic configuration of the oxide ion, O , may be represented as: 0009 5 2 2 4 2 2 2 2 2 2 2 6 2 2 2 9 A. 1s 2s 2p B. 1s 2s 2p 3s 3p C. 1s 2s 2p D. 1s 2s 2p 2510053 E 15 22080 52 035101890263 Atoms of the element silicon contain 14 protons. How many electrons are there in the outer valence electron shell of the 3 _____ _______ silicon atom? A. This cannot be determined from the number of protons. 9 B. 14 C. 12 D. 6 E. 4 0035 2510054 A 15 22084 32 087903510263 The structure of a particular atom is: 18 protons, 22 neutrons, 10 inner electrons, and 8 outer electrons. Which of the following has this structure? A. an argon atom. B. An argon ion. C. A chlorine ion. 9 D. Potassium ion. E. Potassium atom. 0035 2510055 B 14 22088 32 018903370346 An element has an atomic number of 26. Its various "n" shells must contain electrons in which of the following sequences? 9 A. 8,8,8,2 B. 2,8,14,2 C. 2,8,8,8 D. 2,8,16 0038 2510056 B 15 22091 52 0338 Which of the following electron configurations is incorrect? 3 _________ A. halide ions ns(2)np(6) n = 2,3 ns(2)(n_1)d(10)np(6) n = 4,5 B. Se (Ar)5s(2)4d(10)5p(4) C. Be(2+) 1s(2) D. Co(3+) (Ar)3d(6) 9 E. all the above configurations are correct. 2510057 B 15 22096 32 034715050577 The orbital configuration for the atom Cesium is: 5 2 2 6 1 1 1 A. 1s 2s 2p 3s B. (Xe core) 6s C. (Rn core) 6s 5 2 9 D. (Xe core) 6s E. (Xe core) 2510058 D 15 44492 31 The ground state electronic configuration of a sodium cation is 5 1 2 2 6 9 A. [Ne]3s B. [Ne]3s C. [Ar] D. [Ne] E. [He]2s 2d 2510059 A 15 45402 71 The total number of electrons in p orbitals in a zirconium atom 0044 Zr is: 440 9 A. 18 B. 21 C. 31 D. 41 E. 51 2530001 D 15 22099 31 03308001036112 It is sometimes alleged that the occurrence of discrete bright_line spectra provides clear evidence that atoms have discrete energy levels. The existence of such line spectra was known, however, for the better part of a century before discrete energy levels were postulated for the atom. This situation is explained by the circumstance that A. it was not known that there is a connection between radiation and energy B. it was not clear that the bright_line spectra are produced by processes occuring within atoms C. the conclusion does not follow unless it is assumed that atoms are divisible, and composed of electrified particles D. only Bohr's theory of atomic constitution made clear the role of discrete energy levels E. only on the basis of Planck's theory of radiation could a connection be expected between frequencies of radiation 9 and energy states of atoms emitting the radiation ETS2 OS 2530002 B 15 22112 32 03510330800111 In general, when molecules rather than atoms are excited, the type of spectrum produced is A. continuous B. band C. bright line D. Fraunhofer 9 E. absorption ETS2WVW 2530003 C 15 22115 32 05908001800313 5 _12 Two energy levels within an atom differ by 3 x 10 erg. Assuming 5 _27 Planck's constant to be 6.6 x 10 erg_sec., the radiation emitted when an electron jumps from one of the levels to the other is A. in the infra_red B. a gamma ray C. visible D. an x_ray 9 E. in the ultra_violet ETS2WVW 2530004 C ETS2WVW 15 22121 31 03510159800111 When atoms are emitting or absorbing energy A. protons change place with electrons B. neutrons are escaping or being captured C. electrons change their energy levels D. the evidence is always visible to the eye 9 E. the atomic number of the atom is raised or lowered 2530005 E 15 22125 31 00320020800112 Cupric copper has a positive valence of two which means that A. there are six valence electrons in the outer shell of the copper atom B. there are two more protons than electrons in the free atom C. two electrons are needed to complete the outermost shell of the copper atom D. two electrons are always shared in chemical combination 9 E. two electrons have been lent in chemical combination ETS2WVW 2530006 C 14 22131 31 015902638004 The lowest energy level which an electron can have is called the A. O shell B. L shell C. K shell 9 D. F shell 2 OS 2530007 B 14 22133 31 026380048002 The maximum number of electrons that may be found in the "L" shell of an atom is A. 6 B. 8 C. 32 9 D. 18 2 OS 2530008 A 14 22135 31 026301598004 When an electron moves from the K level to the L level, there is an accompanying A. absorption of energy B. emission of a beta particle C. emission of x_rays 9 D. emission of gamma rays 2 OS 2530009 B 14 22138 32 026301598004 Evidence that electrons are located in energy levels around the nucleus is indicated by the A. atomic number of the elements B. atomic mass of the elements C. lines in the spectra of the elements 2 OS 9 D. density of the elements 2530010 B 14 22142 31 062503510189 The wavelengths of light emitted by the excited atoms of a particular element that make up its bright_line spectrum A. are different from the wavelengths in its dark_line spectrum B. are characteristic of the element involved C. come from the nuclei of the atoms D. are evenly distributed throughout the entire visible 9 spectrum 0041 2530011 A 14 22147 31 035106240347 An atom emits a photon when one of its orbital electrons A. jumps from a higher to a lower energy level B. jumps from a lower to a higher energy level C. is removed by the photoelectric effect 9 D. is struck by an x_ray 0041 2530012 D 14 22151 31 059008791202 Which of the following types of radiation are not emitted by the electronic structures of atoms? A. ultraviolet light B. visible light 9 C. infrared light D. gamma rays 0041 2530013 C 14 22154 31 05621694 A neon sign does not produce A. a line spectrum B. an emission spectrum 9 C. an absorption spectrum D. photons 0041 2530014 C 14 22156 31 090901590380 As the quantum number n increases, the energy difference between adjacent energy levels A. increases B. remains the same C. decreases 9 D. sometimes increases and sometimes decreases 0041 2530015 C 14 22159 31 019609290263 A hydrogen atom is said to be in its ground state when the electron A. is at rest B. is inside the nucleus C. is in its lowest energy level 9 D. has escaped from the atom 0041 2530016 E 15 22162 52 033702630346 The phosphorus atom (atomic number 15) contains how many electrons in its third shell (n=3) 0042 9 A. 8 B. 11 C. 3 D. 13 E. 5. 2530017 D 15 22164 32 034609090351 An electron shell of an atom has a principle quantum number of 4 and thus can have the following maximum number of sub_shells: 9 A. one B. two C. three D. four E. five. 0042 2530018 E 15 22167 52 180609130263 A "d" sub_shell can contain no more than: A. three pairs of electrons B. three orbitals C. seven pairs of electrons D. five electrons 9 E. five un_paired electrons. 0042 2530019 D 15 22170 52 026303461352 An electron shell of an atom has a principal quantum number of 4 and thus can have the following maximum number of sub_shells: 9 A. one B. two C. three D. four E. five. 0042 2530020 C 15 22173 52 035600310159 The Rydberg equation for the hydrogen atom in frequency units is 0044 ._ _. | | | | 5 15 | 1 1 | _1 v = 3.29 x 10 | ___ _ ___ | sec 5 | 2 2| |n n | 4 | 1 2 | |_ _| What is the energy in ergs of a quantum of electromagnetic radiation that corresponds to a transition from the fourth excited state (n = 5) to the fifth excited state (n = 6)? 4 1 2 5 _9 13 _13 A. 1.78 x 10 B. 4.02 x 10 C. 2.67 x 10 5 _12 _25 9 D. 1.98 x 10 E. 2.40 x 10 . 2530021 B 15 22184 52 0731 Which of the following has the highest ionization potential (energy)? A. Cs B. Li C. K D. Rb E. all are in group ia so they have the same ionization 9 potential(energy) 0018 2530022 C 15 22187 32 072305130065 0028 5 30 Given the isotope E. The number of electrons in the principal 4 14 energy levels, 1(K), 2(L), 3(M), are: A. 2, 8, 8, respectively, plus 8 in 4(N) and 4 in 5(O) B. 2, 8, 6, respectively C. 2, 8, 4, respectively D. 2, 8, 3, respectively 9 E. none of these 2530023 D 15 22192 32 038003760723 Calculate the maximum number of electrons that can exist in the M principle energy level: 9 A. 8 B. 32 C. 6 D. 18 E. 9 0028 2530024 A 15 22194 32 035307230376 5 36 Given the isotope E. The number of electrons in the principle 4 16 energy levels, that is 1(K), 2(L), 3(M), etc. is A. 2, 8, 6, respectively B. 2, 8, 8, respectively C. 2, 8, 8, 9, respectively plus 9 in 3(N) D. 2, 8, 8, respectively, plus 6 in 3(N) 9 E. none of these 0028 2530025 C 15 22199 32 058607230338 The correct representation of the electronic structure using 5 34 sublevels for S is: 4 16 5 2 2 6 2 6 A. 1s , 2s 2p , 3s 3p 5 2 2 6 2 5 B. 1s , 2s 2p , 3s 3p 5 2 2 6 2 4 C. 1s , 2s 2p , 3s 3p 5 2 2 6 2 6 2 4 D. 1s , 2s 2p , 3s 3p , 4s 4p 9 E. none of these 0028 2530026 D 15 22204 51 A better term for Bohr orbits is A. the ground states 0020 133605860380 9 B. quantum numbers C. Van der Waals forces D. energy levels E. none of these 2530027 B 15 22207 51 038001590909 The energy level that has the highest energy is A. the ground state B. the one with the highest quantum number C. the one with the lowest quantum number D. closest to the nucleus 9 E. none of these 0020 2530028 B 15 22210 51 026303510907 When the electron of a hydrogen atom is in the energy level n = 3 we say that A. it gives off light B. it is in an excited state C. it is in the ground state D. the energy is higher than when n=4 9 E. none of these 0020 2530029 A 15 22214 51 135901591360 Which of the following is a correct order for increasing energy of atomic orbitals in atoms? A. 1s 2s 2p 3s 3d B. 1s 2s 2p 3s C. 1s 2s 3s 2p 3d D. 1s 2s 2p 3d 4s 9 E. none of these 0020 2530030 C 15 22217 51 001409290263 Carbon atoms in the ground state have A. 4 electrons in the 2p level B. 4 unpaired electrons of similar spin C. 2 unpaired electrons D. 4 electrons in the n=2 level that are unpaired 9 E. none of these 0020 2530031 E 15 22220 31 015900700731 The energy involved in the ionization of a metal is known as the A. activation energy B. electronegativity C. electron affinity D. kinetic energy 9 E. ionization energy 0019 2530032 D 14 22223 31 159703801540 Experimental support for the arrangement of electrons in distinct energy levels is based primarily upon A. the law of definite (constant) proportions B. the law of conservation of energy C. x_ray spectra of atoms 9 D. spectra from gas discharge 0009 2530033 D 14 22227 31 026304220380 What is the total electron capacity of the energy level for which n = 4? 9 A. 8 B. 16 C. 18 D. 32 0009 2530034 C 15 22229 31 035103280263 When, during a chemical reaction, atoms are emitting or absorbing energy A. protons change place with electrons. B. neutrons are escaping or being captured. C. electrons change their energy levels. D. the evidence is always visible to the eye. 9 E. the atomic number of the atom is raised or lowered. 0035 2530035 E 15 22234 31 011306060247 The passage of electrical discharge through gases resulted in the discovery of A. isotopes B. the electron C. radioactivity 9 D. alpha_particles E. none of the above 0034 2530036 B 15 22237 31 005403511540 The visible light released by excited atoms in a flame is A. an absorption spectrum B. an emission spectrum C. a continuous spectrum D. an ultraviolet spectrum 9 E. an x_ray analysis 0034 2530037 D 14 22240 52 1944 The theoretical maximum number of electrons in principal quantum level n = 4 is 9 A. 4 B. 8 C. 16 D. 32 2530038 A 14 22242 52 19470731 From which species in the gaseous state can an electron be re_ moved with the least energy? 5 + 2+ 3+ 0055 0058 9 A. Na B. Na C. Na D. Na 2530039 D 15 22245 51 19661352 The maximum number of electrons which can be in an energy level having principal quantum number "n" is: 5 2 2 9 A. 2 B. 8 C. 18 D. 2n E. (2n) BRHM 2530040 D 15 22248 52 A green color is obtained in the flame test for a barium salt. The energy producing this color is emitted when A. oxidation takes place. B. electrons are raised to higher energy levels by the heat of the flame. C. electrons in the highest energy levels are expelled. D. electrons drop back to lower energy levels. 9 E. the barium salt becomes ionized. 2530041 B 15 22253 52 5 _19 Two energy levels in an atom differ by 8.19 x 10 Joules. When an electron falls from the higher to the lower level, it emits a photon with a wavelength characteristic of which part of 5 _34 the electromagnetic spectrum (h = 6.6 x 10 J sec, 5 8 _1 c = 2.99 x 10 m sec )? 9 A. microwaves B. ultraviolet C. visible D. infrared E. x_rays OS 2531001 A 15 22260 31 00540628800111 When a student reported the wave length of light as a certain fraction of a centimeter, he could have been referring to any of these colors EXCEPT A. white B. yellow C. blue D. green 9 E. red ETS2 OS 2531002 C 15 22263 31 03290622800111 The frequencies of the spectral lines in the Balmer series of 5 2 2 hydrogen can be written f = r {(1/2 )_(1/n )} lowest frequency occurs when n is A. 1 B. 2 ETS2WVW 9 C. 3 D. 4 E. 5 2531003 C 15 22267 31 03310330800111 The sun's spectrum is an example of A. a mass spectrum B. a continuous spectrum C. a bright line spectrum D. an absorption spectrum 9 E. a band spectrum ETS2WVW 2531004 D 15 22270 31 06678001032811 According to Kirchhoff's explanation of the Fraunhofer lines, the chief use of studying those lines would be to gain information concerning A. the structure of atoms B. the structure of molecules C. the nature of radiation D. the processes of emission and absorption of radiation 9 E. the chemical composition of celestial bodies ETS2WVW 2531005 D 15 22275 31 00020666800111 If sunlight is passed through a flame containing sodium, and if the fraunhofer d_line is thereby made darker, one concludes that A. the bright regions in the spectrum of the sunlight are less intense than the light emitted by the sodium flame B. the light of the frequency of the sodium line is less intense in the beam of sunlight than in the light emitted by the sodium flame C. the dark d_line in the solar spectrum is really brighter than the bright d_line in the spectrum of the flame D. the intensity of light of the frequency of the sodium line in the beam of sunlight is zero E. the intensity of light of the frequency of the sodium line in the sunlight that has passed through the 9 sodium flame is zero ETS2 OS 2531006 A 15 22286 31 06670668800112 According to Kirchoff and Bunsen, the lines in a bright line spectrum are clearer, the higher the temperature and the weaker the natural illuminating power of the flame. These two conditions together ETS2WVW 9 A. intensify the light constituting the lines, and diminish the intensity of the rest of the spectrum, thus giving a sharper contrast B. intensify the light constituting the lines, and produce destructive interference in the rest of the spectrum, thus giving a sharper contrast C. minimize the effects of diffraction which might tend to reduce the clarity of the lines, and at the same time make the lines themselves brighter D. intensify the brightness of the lines and that of the rest of the spectrum as well, but the former more than the latter E. leave unchanged the intensity of the bright lines, but make the rest of the spectrum darker 2531007 EB 25 22299 31 0667066880011290 MACROITEM STEM 0 Answer the following questions. MACRO SUB_ITEM # 1 The general proposition set forth as a new discovery by Kirchhoff and Bunsen, in their report of their investigation of spectra, is that A. certain substances placed in a flame, or otherwise made to emit light, give a spectrum containing bright lines B. the capacity of a substance to absorb light of a given frequency is inversely proportional to its capacity to emit such light C. the capacity of a substance to absorb light of a given frequency is directly proportional to its capacity to emit such light D. the bright lines occuring in the spectra of certain metals are within wide limits determined by the metal, independently of chemical combination and of the process producing the luminosity E. no two substances can emit light of the same frequency; thus a study of the light emitted permits an 1 identification of the source MACRO SUB_ITEM # 2 One can conclude from this discovery that A. bright line spectra are due to intra_atomic processes B. atoms are capable of only certain discrete energy states C. radiation is emitted discontinuously D. absorption and emission are processes exactly inverse to one another ETS2WVW 9 E. none of the above 2531008 A 15 22316 31 06588001800312 The observation that, while cathode rays are repelled by a negative charge and deflected at right angles to the lines of a magnetic field, x_rays show NO change in direction in either kind of field, is ready proof that A. x_rays, themselves, carry NO charge B. the relatively high speed of the x_rays nullify the effects of any charge or field C. x_rays carry a charge of both positively and negatively charged ions D. x_rays are really a stream of electrons 9 E. x_rays are really a stream of negatively_charged particles ETS2WVW 2531009 D 14 22324 31 80038004 A compound that colors a bunsen flame violet probably contains A. calcium B. copper C. lithium 9 D. potassium 2WVW 2531010 E 15 22326 52 01590351800113 5 _12 Two energy levels within an atom differ by 3 x 10 erg. 5 _27 Assuming Planck's constant to be 6 x 10 erg_sec, the wavelength of the radiation emitted when an electron jumps from one of these levels to the other is 5 _12 A. 3 x 10 cm. 5 _4 B. 1.67 X 10 cm. 5 14 C. 5 X 10 cm. D. 16,700 A. 9 E. 6000 A. ETS2WVW 2531011 E 15 22332 31 03290330800113 Suppose that f and f represent the frequencies of two lines in the 4 1 2 spectrum of hydrogen. Light of frequency f + f 4 1 2 A. must also be present in the spectrum of hydrogen. B. must be present in the spectrum of hydrogen, provided that the higher energy level involved in the emission of ETS2WVW one of the lines is identical with the lower level involved in the emission of the other. C. must be present in the spectrum of hydrogen, provided that the higher energy levels involved in the emission of f and 4 1 f are identical but not otherwise. 4 2 D. must be present in the spectrum of hydrogen, provided that either the higher or the lower energy levels involved in the emission of f and f are identical. 4 1 2 E. need not be present in the spectrum of hydrogen under any of 9 the above circumstances. 2531012 C 15 22346 51 03560328800112 According to Rydberg's formula, the lines in the emission spectrum of hydrogen are given by the equation 1 x 1_ 1 _ = R __ __ 5 2 2 w m _ n where m and N are integers. The quantity w refers to a measurable characteristic of the line, since it represents A. the width (thickness) of the line B. the length (height) of the line C. twice the minimum difference in path that can yield destructive interference between two parts of a single beam of light corresponding to the line D. twice the difference between the distance from the light source of the line as projected on the screen, measured once directly along a straight path, and again along the refracted path through the prism 9 E. the distance of the line from one end of the spectrum ETS2 OS 2700001 E 15 22358 31 03640365800112 Einstein's principle contribution to the quantum theory of light, in 1905, consisted in A. the hypothesis that Planck's quantum postulate, with its basic equation E=hf, applied not only to black body radiation but to all emission and absorption phenomena B. the hypothesis that not only the emission and absorption, but the radiation itself is quantized into elements of magnitude E=hf, each of which is propagated intact C. the application of the idea of quantization to matter as well as to energy D. the extension of the notion of corpuscles of energy to all ETS2 OS 9 forms of radiation, especially to x_rays E. the application of the quantum hypothesis to the theory of the previously unexplained photoelectric effect 2700002 B 15 22369 51 05750159800111 The basic discontinuity of "quantization", postulated by Planck in his theory of black body radiation, was a discontinuity in A. the possible frequencies of vibration of an oscillating charged particle B. the possible energies of an oscillating charged particle C. the possible energies of an oscillating charged particle of given frequency D. the spatial distribution of the energy radiated by an oscillating charged particle E. the spatial distribution of the energy radiated by an oscillating charged particle of given frequency and 9 energy ETS2WVW 2700003 E 15 22377 31 06110613800111 The changing of the amplitude of the carrier wave of a broadcast station to transmit a program is called A. detection B. oscillation C. rectification D. amplification 9 E. modulation ETS2WVW 2700004 A 14 22380 31 05720351 The quantum_mechanical theory of the atom is A. based upon a mechanical model of the atom B. a theory that restricts itself to physical quantities that can be measured directly C. less accurate that the Bohr theory of the atom 9 D. impossible to reconcile with Newton's laws of motion 0041 2700005 A 14 22384 51 1695 0591 The Zeeman effect refers to A. the splitting of spectral lines in a magnetic field B. electron spin C. the existence of the azimuthal quantum number 9 D. the origin of the periodic table 0041 2700006 D 15 22387 52 036505900329 A quantum of electromagnetic radiation has frequency equal to 5 10 _1 0044 1.68 x 10 sec . What is the wavelength of this radiation in 5 10 _27 Angstroms? (c = 3.00 x 10 cm/sec, h = 6.63 x 10 erg_sec.) 5 _16 _17 20 A. 1.11 x 10 B. 6.23 x 10 C. 5.04 x 10 5 8 9 D. 1.79 x 10 E. 0.560 2700007 C 15 22393 52 036505900625 A quantum of electromagnetic radiation has wavelength equal to 5 _1 0.0376 cm. What is the frequency of this radiation in sec ? 5 _12 _25 11 A. 1.25 x 10 B. 1.76 x 10 C. 7.98 x 10 5 14 _15 9 D. 1.89 x 10 E. 5.29 x 10 0044 2700008 D 15 22399 52 036505900329 A quantum of electromagnetic radiation has frequency equal to 5 17 _1 5.69 x 10 sec . What is the energy of this radiation in 5 8 _34 wavenumbers? (c = 3.00 x 10 m/sec., h = 6.63 x 10 J_sec) 5 _18 _9 _19 A. 1.76 x 10 B. 3.77 x 10 C. 1.26 x 10 5 7 _8 9 D. 1.90 x 10 E. 5.27 x 10 . 0044 2700009 C 15 22405 52 036505900329 A quantum of electromagnetic radiation has frequency equal to 5 18 _1 1.05 x 10 sec . What is the energy of this radiation in Joules? 5 8 _34 (c = 3.00 x 10 m/sec., h = 6.63 x 10 J_sec.). 5 21 _15 _16 A. 3.14 x 10 B. 2.86 x 10 C. 6.94 x 10 5 _41 _8 9 D. 1.90 x 10 E. 2.42 x 10 0044 2700010 A 15 22411 31 026801590365 The idea that energy consists of bundles or quanta was first 3 ______ proposed by A. Max Planck B. Ernest Rutherford C. Niels Bohr 9 D. Linus Pauling E. Erwin Schrodinger 0034 2700011 C 15 22414 52 036505900329 A quantum of electromagnetic radiation has frequency equal to 0044 5 14 _1 2.11 x 10 sec . What is the wavelength of this radiation in 5 10 _27 centimeters? (c = 3.00 x 10 cm/sec, h = 6.63 x 10 erg sec.) 5 _9 _12 _4 A. 9.82 x 10 B. 1.40 x 10 C. 1.42 x 10 5 11 3 9 D. 7.15 x 10 E. 7.03 x 10 2700012 D 15 44725 71 19661967 Which of the following investigators presented the idea that no two electrons in the same atom can assume the same quantum state? A. Robert S. Mulliken B. Johannes van der Waals C. Erwin Schroedinger D. Wolfgang Pauli 9 E. Enrico Fermi OS 2710001 D 15 22423 51 02760628800111 Which of the following facts supports a modern corpuscular, or particle, theory of light rather than the wave theory? A. Light travels three_fourths as fast in water as in air. B. Light is diffracted on passing through a small opening. C. The velocity of travel of electromagnetic waves is the same as the velocity of light. D. Light immediately causes ejection of electrons in a photoelectric tube. 9 E. Light exhibits interference and reinforcement effects. ETS2 OS 2710002 E 15 22430 31 02760665800111 Which, if any, of the following phenomena puts a serious theoretical difficulty in the way of attempting to characterize the behavior of light in terms of Newtonian "rays"? A. Separation of the components of composite light by a prism, which would force one to assert that there are at a given point in a beam of light an infinite number of rays B. The spreading out of a beam of light in passing through a small hole, which destroys the possibility of subdividing such a beam indefinitely into ever_narrower ETS2WVW 9 parts C. The speed at which light travels, which is so enormously great as to be an insuperable obstacle to any attempt to separate a "chunk" of light disconnected from its source D. The fact that the light always travels with the same speed in a vacuum, which means that no physical agency can alter the speed of a ray unless it passes into a refracting medium E. none of the above, for all the phenomena listed can be characterized in terms of the behavior of rays 2710003 A 15 22445 52 02638001800313 Electrons in an electron microscope are traveling with a velocity 5 9 of 2 x 10 cm./sec. Assuming the mass of an electron to be 5 _28 _27 9 x 10 gm. and Planck's constant to be 6 x 10 erg sec, the wavelength of the electron is A. 0.33 A. 5 _8 B. 1.33 x 10 cm. C. 3 A. ETS2WVW 5 8 D. 3 x 10 cm. 5 _38 9 E. 108 x 10 A. 2710004 A 15 22451 31 06160615800111 When a beam of x_rays, all of the same wave length, is directed against a very fine wire the shadow formed or photographed in back of it is not just that of a single wire but rather as if several wires were used. The best explanation of this involves A. diffraction B. reflection C. the doppler effect D. an optical illusion 9 E. refraction 2710005 E 15 22456 52 075707588003 The velocity of a beam of neutrons in a nuclear reactor is 5 5 _1 2.0 x 10 cm. sec. . What is the De Broglie wavelength of these neutrons? note mass of neutron, m = 1.00899 amu; ETS2WVW 2WVW 5 5 5 5 5 5 9 _27 h = 6.6 x 10 erg. sec. (Planck's constant); lambda = h/mv, where v is velocity _57 A. 5.4 x 10 cm. _12 B. 2.0 x 10 cm. _10 C. 1.7 x 10 cm. _8 D. 6.6 x 10 cm. _8 E. 2.0 x 10 cm. 2710006 D 15 22463 52 026306120159 A typical electron diffraction experiment is conducted with electrons accelerated through 24600 volts, or with 24600 ev of energy. What is the wavelength of the electrons in Angstroms? 5 _12 (1 electron volt = 1.60 x 10 erg; 5 _28 electron mass = 9.11 x 10 g) 5 _10 A. 12.8 Angstroms B. 7.83 x 10 Angstroms 5 _10 C. 9.39 x 10 Angstroms D. 0.0783 Angstroms 9 E. 0.626 Angstroms. 0044 2710007 A 15 22470 51 060403511349 The wave_theory approach to the electronic structure of atoms is based on A. the fact that electrons can be considered as waves B. the spin of electrons 5 2 C. the fact that electrons have energies equal to mc D. all the above 9 E. none of the above 0020 2750001 A 14 22475 31 03470906 The boundary surface diagram of an orbital outlines A. the region in which there is a certain probability (less than 100) percent of finding the electron it described B. the region in which there is a 100 percent probability of finding the electron it describes C. the shape of the electron it describes 9 D. the orbit followed by the electron it describes 0041 2750002 D 14 22481 31 029303550347 The H O molecule is "bent" so that the two O_H bonds are nearly 4 2 perpendicular to each other because A. the H atoms repel each other B. the H atoms attract each other C. the S orbitals in O which participate in the bonds are perpendicular D. the p orbitals in O which participate in the bonds are 9 perpendicular 0041 2750003 D 15 22486 52 034703510350 The total number of orbitals used in an unexcited atom of silicon (Z = 14) is: 9 A. five or less B. six C. seven D. eight E. nine or more 0042 2750004 D 15 22488 52 026303470351 Electrons in atoms are visualized as occupying atomic orbitals. Which of the following general statements concerning orbitals is not true? 3___ A. In atoms other than hydrogen electrons are assigned to orbitals which have the same symmetry as the hydrogen orbitals. 5 2 2 2 B. The electron configuration of carbon is 1s 2s 2p . The two p electrons will occupy separate p orbitals. C. Orbitals are filled in the order of increasing energy even if it means occasionally jumping to a higher n and returning to the lower n later in the sequence. D. The principal quantum number n describes the shape of the orbital, beginning with a sphere for n = 1, 2 lobes for n = 2, and increasing in complexity with increasing n. 9 E. The 1s orbital of hydrogen has spherical symmetry. 0044 2750005 C 14 22501 51 07800263 A set of d orbitals can hold a total of A. two electrons B. six electrons C. ten electrons 9 D. five electrons 2750006 A 15 22503 31 026303470906 According to the orbital model,electrons are located in A. atomic orbitals that describe an area in which there is a 0018 0018 9 90% probability or better of finding an electron B. the nucleus C. the empty space around the nucleus D. orbitals that circle the nucleus E. none of these 2750007 E 15 22507 51 0916 p orbitals are those for which A. l = 3 B. n = 2 C. m = 1 D. azimuthal quantum number = 2 4 1 9 E. none of these 0020 2750008 D 15 22509 51 130103471350 For the sublevel f, the number of orbitals possible is 9 A. one B. three C. five D. seven E. nine 0020 2750009 B 15 22511 51 135109091197 When the principal quantum number is 2, the permitted values for the azimuthal quantum number are A. 0,1,and 2 B. 0 and 1 C. 1 and 2 D. _1,0,+1 9 E. +1/2, _1/2 0020 2750010 B 15 22514 51 135502630380 The maximum number of electrons permitted in any energy level is 0020 5 2 9 A. 2n B. 2n C. 3(n+1) D. 3n E. none of these 2750011 D 15 22516 51 p orbitals are A. three in number B. perpendicular to each other C. dumbbell_like in shape D. all of these 9 E. none of these 091613650914 0020 2750012 A 15 22518 51 001403510929 The carbon atom in the ground state has A. four unpaired electrons B. two electrons in the 3s orbital C. two unpaired electrons D. no electrons in the 2s orbital 9 E. none of these 0020 2750013 D 15 22521 51 136013391378 An atomic orbital is defined as A. an electronic cloud B. a region in space occupied by an electron or pair of electrons C. the geometric shape that a pair of electrons can occupy D. all of the above 9 E. none of the above 0020 2750014 B 15 22525 31 034702630300 The space around a nucleus in which electrons move can be classified into several subspaces. Which of the following is the simplest of these classifications? A. shell B. orbital C. subshell D. period 9 E. both a and C. 0040 2750015 C 15 22529 31 091702630347 The maximum number of electrons which may occupy a 4d orbital is A. 10 B. 4 C. 2 D. 8 9 E. no correct response is given. 0040 2750016 C 15 22531 31 091509171362 After the 5s subshell of an atom is filled the next electron will enter the A. 5p subshell B. 5d subshell C. 4d subshell D. 5f subshell 9 E. 4f subshell. 0040 2750017 C 14 22534 32 018903510347 The element whose neutral, isolated atoms have three half_filled 2p orbitals is: 9 A. B B. C C. N D. O 0009 2750018 D 15 22536 51 034711570628 In the wave mechanical model, an electronic orbital must A. possess an integral number of wavelengths B. possess an electronic "standing wave" C. have only certain diameters D. all of the above 9 E. none of the above 0034 2750019 A 15 44880 31 The maximum number of electrons possible in a d orbital is 9 A. 2 B. 6 C. 10 D. 14 E. 18 2750020 A 15 45391 71 The number of orbitals having a given value of l is equal to A. 2l + 1 B. 2n + 1 C. 2m + 1 D. n + m E. l + m 94 l l l 2770001 D 14 44456 31 090905860263 The quantum number that does not describe the orbital of an atomic electron is the A. principal quantum number B. orbital quantum number, l C. magnetic quantum number, m 4 l D. spin magnetic quantum number m 4 s 9 E. The J_value 2770002 D 14 22544 31 16960263 The angular momentum of an electron in an atom A. is not quantized B. is quantized in magnitude only C. is quantized in direction only 9 D. is quantized in both magnitude and direction 0041 0041 2770003 D 15 22547 32 034709091197 In a "d" orbital having a principle quantum number of 4, what are the possible numerical values of the magnetic quantum number m ? 4 l A. 1/2, _1/2, 0 B. _1, 0, 1 C. _3, _2, _1, 0, 1, 2, 3 9 D. _2, _1, 0, 1, 2 E. _4, _3, _2, _1, 0, 1, 2, 3, 4 0042 2770004 C 15 22552 52 090917920351 Which of the following combinations of quantum numbers do not 3 ___ represent permissible solutions of the Schroedinger wave equation for the hydrogen atom: n l m s 1. 7 _3 0 _1/2 2. _2 3 _1 1/2 3. 4 3 _2 _1/2 0044 9 A. 2 B. 3 C. 1 and 2 D. 1 and 3 E. none of them is permissible. 2770005 A 15 22559 51 062215400909 The Balmer series of emission spectral lines arises from transitions in the hydrogen atom in which the excited electron falls into the first excited state (n=2). Calculate the 0044 quantum number, n, of the initial state for the Balmer line 5 4 at 2.31 x 10 wavenumbers. The Rydberg constant in wavenumbers 5 _1 is 110000 cm .) 9 A. 5 B. 8 C. 4 D. 7 E. 6. 2770006 A 15 22565 J is the abbreviation for A. a quantum number B. an energy unit C. an energy level D. a quantum state 9 E. none of these 51 13460909 0020 2770007 A 15 22567 51 135309090969 For an azimuthal quantum number of 2, the magnetic quantum can have the values A. 2,1,0,_1,_2 B. 1,2,3 C. only 0,1,and 2 D. 1,0 _1,_2,_3 9 E. none of these 0020 2770008 D 15 22570 52 090917920351 Which of the following combinations of quantum numbers do NOT represent permissible solutions of the Schroedinger wave equation for the hydrogen atom? 0044 n l 9 2 1 0 1 3 4 1. 2. 3. 9 m l 0 0 3 A. 1 B. 3 C. 1 & 2 m s _5/2 _1/2 1/2 D. 1 & 3 E. none of them is permissible. 2780001 C 15 22576 31 1 07759027 95 Which one of the drawings in Figure 27 would most likely represent the electron density distribution for a solution of the Schrodinger wave equation for the H atom, for which n = 3 and l = 1? A. A B. B C. C D. D 9 E. E 2WVW 2780002 C 15 45385 71 The product of the normalized wave function of an electron in an atom and its complex conjugate A. describes the energy of the electron. B. specifies the momentum of the electron. C. gives the probability density of finding the electron in a region of space. D. is proportional to the velocity of the electron. E. is inversely proportional to the distance between the electron 9 and the nucleus. 2790001 B 14 22580 31 112802630909 According to the Pauli principle, A. four different quantum numbers are needed to describe each electron in an atom B. no more than one electron in an atom can have the same set of quantum numbers C. eight electrons occupy each energy level 9 D. electrons move in elliptical as well as circular orbits 0041 2790002 B 15 45068 51 135902630347 In order for two electrons to "occupy" a given orbital, A. their spin directions must be the same B. their spin directions must be opposite C. their spin directions must be perpendicular D. they must both be electrically neutral E. This statement is incorrect. Two electrons cannot occupy the 9 same orbital. 0041 2790003 A 14 22589 51 026303471128 According to the ____________ an atomic orbital may hold no more than two electrons. A. Pauli exclusion principle B. Hund rule C. Bohr theory 9 D. none of these 0018 2790004 D 15 22592 51 112802630909 The Pauli exclusion principle states A. the size of the orbital is determined by the principle quantum number B. only two electrons can have identical quantum numbers C. all electrons around a nucleus may be in different orbitals D. no two electrons in a given atom can have the same set of quantum numbers 0020 9 E. none of the above 2900001 D 15 22597 31 04630642800111 The difference between chemical reactions and nuclear reactions is that chemical reactions involve A. chemicals and nuclear reactions do not B. the formation of new substances and nuclear reactions do not C. the formation of new elements and nuclear reactions deal with the formation of radioactive elements D. outer electron changes usually and nuclear reactions involve changes within the nuclei of the atoms E. elements or compounds only while nuclear reactions are 9 those taking place between nuclei of atoms ETS2WVW 2900002 D 15 22605 31 06210379800111 The curvature of the path (i.e., amount of deflection) of beta rays emitted by radioactive substances in an electric field, compared with the curvature of the path of cathode rays in the same field, is A. less B. the same C. greater D. either greater, less or the same, depending on the relative speeds of cathode rays and beta rays E. no comparison can be made, because beta rays are not 9 affected by an electric field ETS2WVW 2900003 BCDAEA 65 22611 31 80018003 1190 MACROITEM STEM 2To answer the following questions, mark space 5 A. if the item is true of 235 2 U 4 92 5 B. if the item is true of 238 2 U 4 92 5 C. if the item is true of 239 2 U 4 92 5 D. if the item is true of 239 2 Pu 4 94 0 E. if the item is ture of none of the above MACRO SUB_ITEM # 1 The isotope of uranium of greatest abundance in ordinary ETS2WVW 1 uranium MACRO SUB_ITEM # 2 Is produced when one neutron enters the nucleus 2 Atom of U_238 MACRO SUB_ITEM # 3 Is produced from U_239 through the loss of first one electron 3 and then another MACRO SUB_ITEM # 4 Is the original source of the neutrons in the uranium pile 4 used in the production of plutonium MACRO SUB_ITEM # 5 5 Is the chief source of the energy of the sun MACRO SUB_ITEM # 6 9 along with plutonium, it may be used to produce an atom bomb 2900004 BCBAB 55 22623 52 1 80019013 119095 MACROITEM STEM 2The following questions refer to Figure 13. The diagram represents 2one kind of a cathode_ray tube. After each exercise number 2on the answer sheet, blacken the one lettered space which 3 ___ 0 designates the correct answer. MACRO SUB_ITEM # 1 Cathode rays are composed of A. positive ions B. negative ions C. electrons D. both positive and negative ions 1 E. none of the items mentioned in A, B, C or D MACRO SUB_ITEM # 2 In a cathode tube the mass of the electron A. depends on the kind of anode metal B. depends on the kinds of cathode metal C. is independent of the anode or cathode metal D. depends on the gas in the tube 2 E. is independent of the factors mentioned in a, b, c, or d MACRO SUB_ITEM # 3 When cathode rays strike a metal target the radiation emitted from the target is most similar to A. a stream of electrons B. gamma rays from radium C. a beam of alpha particles D. fluorescent light 3 E. a stream of protons MACRO SUB_ITEM # 4 The tube pictured is most useful in showing that cathode rays ETS2 OS 3 ________ A. travel in a straight line B. possess kinetic energy C. cause x_rays to be emitted from glass D. travel with the speed approaching that of light 4 E. are positively charged MACRO SUB_ITEM # 5 The cathode in a different kind of cathode tube is in the center of the tube and consists of a metal disc containing several holes. Cathode rays travel toward the positive electrode at one end of the tube, while other rays or particles pass through the holes in the cathode in the opposite direction. These rays or particles are A. x_rays B. positive rays or protons C. beta particles D. neutrons 9 E. positrons 2900005 ADD 35 22645 32 1 9014 119095 MACROITEM STEM 0 The following questions refer to Figure 14. MACRO SUB_ITEM # 1 In a tube similar to the one shown, cathode rays were discovered by A. Crookes B. Moseley C. Thomson D. Rutherford 1 E. Curie MACRO SUB_ITEM # 2 Roentgen found that if a target were placed in the path of cathode rays, energy was released that came to be known as A. beta rays B. cosmic rays C. neutrons D. x_rays 2 E. alpha rays MACRO SUB_ITEM # 3 Very lightweight objects that are free to rotate are set into motion by cathode rays, thus proving the rays possess A. negative charge B. positive charge C. neutral charge D. both mass and motion or kinetic energy 9 E. potential energy ETS2 OS 2900006 BDDAC 54 22654 31 80018003 1190 MACROITEM STEM 2To answer the following questions, select from the key 2the most appropriate apparatus. 2 A. Zinc_sulphide fluorescent screen 2 B. Wilson cloud_chamber 2 C. Geiger counter 0 D. mass spectrograph MACRO SUB_ITEM # 1 Used to photograph such phenomena as the track of an alpha 1 particle MACRO SUB_ITEM # 2 2 Used to determine the "weight" of an atom MACRO SUB_ITEM # 3 Used to determine the rate of disintegration of radio_active substances and the velocity and energy of the emitted 3 particles MACRO SUB_ITEM # 4 Used to determine the rate of disintegration of atoms but 4 not the velocity and energy of the emitted particles MACRO SUB_ITEM # 5 9 Commonly used to detect cosmic rays audibly ETS2WVW 2900007 BDEAC 55 22662 31 80018003 1190 MACROITEM STEM 2After each item number on the answer sheet, blacken the 2one lettered space which designates the term below to which 3___ 2the item correctly refers. 2 A. fog_track apparatus 2 B. electroscope 2 C. geiger counter 2 D. mass spectrograph 0 E. none of the above MACRO SUB_ITEM # 1 1 Used by Madame Curie to detect the presence of radio_active material MACRO SUB_ITEM # 2 Artificial transmutation of elements was first detected by the 2 use of this instrument MACRO SUB_ITEM # 3 Can distinguish positive electric charges from negative ones, 3 Is commonly used for this purpose MACRO SUB_ITEM # 4 4 Makes the paths of ionizing particles visible MACRO SUB_ITEM # 5 9 Used in prospecting for uranium ETS2WVW 2900008 BBCAEDCB 85 22670 31 80018003 1190 MACROITEM STEM 2For each of the following nuclear changes, blacken space 2 A. if the item is true of the loss of a neutron 2 B. if the item is true of the loss of an alpha particle 2 C. if the item is true of the loss of a beta particle 2 D. if the item is true of the capture of a neutron 0 E. if the item is true for none of the above MACRO SUB_ITEM # 1 The atomic weight decreases by four and The atomic number 1 decreases by two. MACRO SUB_ITEM # 2 An element of group III moves two places to the left in the 2 periodic chart. MACRO SUB_ITEM # 3 An element of group II moves one place to the right of the 3 periodic chart. MACRO SUB_ITEM # 4 The atomic weight decreases by one but the atomic number 4 remains the same. MACRO SUB_ITEM # 5 There is no change in either the atomic weight or the 5 atomic number. MACRO SUB_ITEM # 6 The atomic weight increases by one but the element remains in 6 the same place in the periodic chart. MACRO SUB_ITEM # 7 The atomic weight remains the same but the atomic number 7 increases by one. MACRO SUB_ITEM # 8 The ejected particle will eventually pick up two planetary 9 electrons and become a neutral helium atom. 2900009 C 15 22683 51 06618003 Which one of the proposed induced nuclear reactions given below would definitely not give the product suggested? The terminology used is "e = symbol_mass" for each isotope. 5 2 (Note D = H ; a = alpha particle; n = neutron; p = proton.) 4 1 5 19 16 A. F (n,a) N 4 9 7 5 191 194 ETS2WVW 2WVW B. Ir (a,n) Au 4 77 79 5 55 57 C. Mn (p,n) Fe 4 25 26 5 237 238 D. Np (a,3n) Am 4 93 95 5 6 7 E. Li (D,p) Li 4 3 3 9 2900010 C 15 22691 51 121212130495 The cyclotron is an example of A. an atom smasher B. a machine for making subatomic particles C. a particle accelerator D. a nuclear reactor 9 E. all of these 0020 2900011 C 15 22694 31 1212 A cyclotron is used to A. accelerate neutrons B. separate the isotopes of an element C. accelerate charged particles D. increase the rate of disintegration of a radioactive substance 9 E. both A and B 0040 2900012 C 15 22697 51 0661 "Breeder" reaction is one in which A. neutrons are produced B. a fusion reaction occurs C. a nonfissionable isotope is converted into a fissionable one D. electrical energy is produced 9 E. both A and B 0040 2900013 D 15 22700 31 1221 In nuclear power plants A. the fusion process is used to generate heat to turn water to steam B. radioactive atoms are used to generate electricity directly C. steam is produced by passing water over a radioactive substance D. the principles of operation are very different to those of a 0040 9 coal_fired plant E. both A and C 2900014 A 15 22705 31 1216 The smallest amount of fissionable material that will support a self_sustaining chain reaction is called the A. critical mass B. atomic weight C. mass number D. isotopic weight 9 E. no correct response is given. 2900015 B 15 22708 31 148306421484 A great problem that must be overcome before nuclear fusion can be used as a useful source of energy in applications other than bombs is A. obtaining sufficient amounts of fusionable materials B. development of suitable reaction containers C. development of suitable methods of disposing of the radioactive waste D. more than one response is correct 9 E. development of a good theoretical model 2900016 C 15 22714 31 0632 The use of fission reactions to generate electricity is attractive because A. no wastes are produced B. all technical problems have been resolved C. other energy sources are in short supply D. the generators are inexpensive to build 9 E. all of the above 2900017 A 15 22718 31 06601223 The most recent of the man_made elements to be produced is element 105. The longest lived isotope of this element has a half_life of A. less than 1 hour B. between 1 hour and 1 day C. between 1 day and 1 month D. between 1 and 10 months 9 E. no correct response is given. 2900018 C 15 22722 31 1212 Some unidentified particles are accelerated in a cyclotron and allowed to strike a target. The exact identity of the particles must be determined. Which of the following could not possibly 3 _________ be the unknown particles? A. electrons B. protons C. neutrons D. positrons 9 E. either A or D 0040 0040 0040 0040 0040 2900019 C 14 22727 51 043604951563 Which one of the following instruments would be least suitable for detecting particles given off in radioactive decay? A. Geiger counter B. scintillation counter 9 C. electron microscope D. cloud chamber 0009 2910001 B 15 22730 31 06170069800111 The term radioactivity refers to A. the activity of electronic devices B. the spontaneous disintegration of certain atomic nuclei C. the gain or loss of electrons from the outer orbits of the atoms D. certain elements, like cobalt, which are necessary in television and radio manufacture E. the chemical combinations between elements catalyzed 9 by radio frequency waves ETS2WVW 2910002 E 15 22736 31 06200617800111 The half_life of a radioactive substance is A. half the life_span of the substance B. usually 50 years C. the time for radium to change to lead 5 2 D. found from Einstein's equation, E = mv 9 E. the time for half the material to disintegrate ETS2WVW 2910003 B 15 22740 31 03790621800111 In considering the various "rays" from radioactive material we think of beta rays as A. high_frequency x_rays B. high_speed electrons C. infra_red radiation D. hydrogen nuclei 9 E. helium nuclei ETS2WVW 2910004 A 15 22743 31 06190376800111 An alpha particle from radioactive material is A. a helium atom from which two electrons have been removed B. an aggregate of two or more electrons C. a hydrogen atom D. the ultimate unit of positive electricity 9 E. sometimes negatively charged ETS2WVW 2910005 B 15 22747 Beta radiation is/are ETS2WVW 31 06230379800111 9 A. high_frequency x_rays B. high_speed electrons C. high_energy electromagnetic radiation D. a stream of photons E. fast helium nuclei 2910006 A 15 22750 31 06160626800111 X_rays are A. electromagnetic waves of short wave_length B. negatively charged ions C. reflected cathode rays D. nuclei of hydrogen atoms 9 E. positrons ETS2WVW 2910007 D 15 22753 31 06160574800111 All except one of the following are properties of x_rays. You are to select this one item which does not apply A. The ability to make certain materials fluoresce B. The ability to pass through opaque matter C. The tendency to ionize the air through which they pass D. The ability to cause a tiny paddle wheel to move away from the cathode 9 E. The ability to darken a photographic plate ETS2 OS 2910008 D 15 22759 32 06260628800111 If the following electromagnetic radiations are supposed to be arranged in order of increasing wave length, the one which is out of place is A. gamma rays B. ultra_violet C. infra_red D. x_rays 9 E. radio waves ETS2 OS 2910009 D 15 22763 31 03790588800111 Radioactive disintegration may be characterized by all of these except A. the emission of alpha, beta, and gamma rays B. definite half_life periods C. the formation of helium as a by_product D. the ejection of large quantities of matter 9 E. transmutations of elements ETS2WVW 2910010 B 15 22767 31 03790189800111 A radioactive element X emits beta particles (electrons). This results in the production of ETS2WVW 9 A. an element which is very reactive chemically B. an element of higher atomic number C. an element with an atomic weight one unit less D. a radioactive element which emits protons E. stable positive ions of the element X 2910011 E 15 22772 31 01590495800111 Energy resulting from motion of particles deep within the structure of the atom was unknown until the discovery of A. ionization B. the atomic bomb C. the photoelectric effect D. electromagnetic radiation 9 E. radioactivity ETS2WVW 2910012 C 15 22776 31 05730189800111 In the uranium disintegration series A. the disintegrating element merely throws off planetary electrons B. when an element loses a beta particle, the production of another element takes place, that second element having an atomic weight one unit larger and an atomic number one unit smaller than the original atom C. when an element loses an alpha particle an element is produced that has an atomic weight four units less and an atomic number two units less than those constants for the disintegrating atom D. in all atomic disintegrations the nucleus is unaffected E. the series of disintegrations continues until an element having eight electrons in its outermost orbital level 9 is obtained ETS2WVW 2910013 C 14 22787 31 01898001034211 If thallium, element number 81, ejects a beta particle from the nucleus A. no new element is formed B. mercury, element number 80, is formed C. lead, element number 82, is formed 9 D. thallium becomes radioactive ETS2WVW 2910014 B 15 22790 31 06180619800111 If radium, element number 88 in the periodic table, ejects an alpha particle from the nucleus A. no change takes place, as radium is constantly ejecting alpha particles B. radon, element number 86, would be formed ETS2WVW 9 C. actinium, element number 89, would be formed D. thorium, element number 90, would be formed E. stable negative ions of radium would result 2910015 DAB 35 22795 31 80018003 1190 MACROITEM STEM 2To answer the following questions, select the appropriate 2answer from the key 2 A. alpha particles 2 B. beta particles 2 C. cathode rays 2 D. gamma rays 0 E. positive rays MACRO SUB_ITEM # 1 Are not affected by the most intense magnetic fields. 1 Are very penetrating and of very short wave length. MACRO SUB_ITEM # 2 Are slightly bent by intense magnetic fields. One of the products of the disintegration of radium. Each particle 2 carries two positive charges. MACRO SUB_ITEM # 3 Are greatly deflected even by weak magnetic fields. Consist of electrons and are one of the products of the disintegration 9 of radium. ETS2WVW 2910016 A 15 22803 51 07728003 Which of the following nuclides do not occur in the radioactive decay series indicated? The terminology used is "z_symbol_mass" for the isotopes. (Hint: all four of the series involve only alpha and beta decay.) 5 224 (1) Ra ; thorium_232 4 88 5 210 (2) Po ; uranium_238 4 84 5 228 (3) Ac ; uranium_235 4 84 5 221 (4) Fr ; neptunium_237 4 87 5 233 (5) U ; uranium_235 4 92 2WVW 9 A. 3 and 5 B. 2 and 4 C. 1 D. 5 E. 3 2910017 B 14 22810 52 06200847 The half_life of tritium is 12 1/2 years. If we start out with 1 g of tritium, after 25 years there will be A. no tritium left B. 1/4 g of tritium left 9 C. 1/2 g of tritium left D. a total of 4 g of tritium 0041 2910018 B 14 22813 52 039203790192 After 2 hr have elapsed, one_sixteenth of the original quantity of a certain radioactive substance remains undecayed. The half_ life of this substance is 9 A. 15 min B. 30 min C. 45 min D. 60 min 0041 2910019 A 14 22816 51 066006061337 Radioactive decay was discovered by 9 A. Becquerel B. Marie Curie C. Pierre Curie D. Rutherford 2910020 B 14 22818 51 037914990097 Radioactive materials do not emit 9 A. electrons B. protons C. alpha particles D. gamma rays 0041 0041 2910021 D 14 22820 31 057312060353 Uranium eventually decays into a stable isotope of 9 A. radium B. polonium C. radon D. lead E. plutonium 0041 2910022 C 14 22822 51 006603790618 If radium and chlorine combine to form radium chloride, the compound is A. no longer radioactive B. half as radioactive as the radium content C. as radioactive as the radium content 9 D. twice as radioactive as the radium content 0041 2910023 D 15 22826 52 062003530379 The half_life of a radioactive isotope is 2.28 years. How long will it take the activity of a given sample to be reduced to 97.0% of the original activity? 0044 5 0.693 (100 ) A. + _____ x 2.28 x log ______ yrs. 4 2.303 (97.0) 5 2.303 (97.0) B. + _____ x 2.28 x log ______ yrs. 4 0.693 (100 ) 5 2.303 (97.0) C. + _____ x 2.28 x log ______ yrs. 4 0.693 (100 ) 5 2.303 (100 ) D. + _____ x 2.28 x log ______ yrs. 4 0.693 (97.0) 5 (97.0) E. 2 x 2.28 x ______ yrs. 94 (100 ) 2910024 C 15 22835 72 035306201206 If 29.0 percent of a radioactive isotope decays in 265 days, what is its half_life? 0044 2.303 265 A. _____ x __________ days .693 log (71.0) 2.303 29.0 B. .5 x _____ x ____ days .693 265 .693 265 C. _____ x _________ days 2.303 (100) log______ (71.0) 2.303 265 D. _ _____ x _________ days 0.693 (29.0) log______ (100 ) 9 E. none of the above. 2910025 D 15 22842 52 035306200379 The mass of a sample of a radioactive isotope is found to be 7.10 grams. Given a half_life of 13.4 days, what amount of the isotope will be left after 32 days? 9 A. 0.807 g B. 0.288 g C. 0.0 g D. 1.36 g E. 0.895 g 0044 2910026 C 15 22846 52 120906200375 What is the approximate age of an artifact found by an archaeologist which has a specific activity due to carbon_14 of 10.2 counts per minute per gram of carbon? Assume that living matter on the earth has an activity of 15.3 counts per minute per gram of carbon. The half_life of carbon_14 is 5570 years. A. 8340 Years B. 1420 years C. 3260 years D. 1820 years 9 E. 7510 years. 0044 2910027 E 15 22852 52 179602820620 The technique of radiocarbon dating relies on the following principles: (select the one wrong statement.) 3 _____ A. The specific C_14 activity, counts per minute per gram of carbon, is not affected by chemical decomposition and volatilization of the object. B. When C_14 decays it emits a beta particle which can be detected in an instrument such as a geiger counter. C. Living organisms have always contained the same fraction of C_14 as the atmosphere. D. Recent military nuclear explosions have not effected the C_14 content of old objects. E. C_14 decays with a half life of 5770 years in living 9 organisms, but is stable in inorganic compounds. 0044 2910028 C 15 22862 52 062006600288 The half_life of a radioactive isotope, Z, is 2.00 years. How many years would it take 10.0 g of Z to decay and have only 1.25 g remain? A. 2.00 years B. 4.00 years C. 6.00 years 9 D. 8.00 years E. 16.0 years 0028 2910029 B 14 22865 31 061706600379 A substance that spontaneously emits rays and particles without any apparent inducement is said to be A. charged B. radioactive 9 C. magnetically imbalanced D. irritable. 0026 2910030 D 15 22868 51 109700100379 A sample of radioactive ore gives off A. only alpha particles B. only beta particles C. only gamma particles D. all of these 9 E. only two of these 0020 2910031 D 15 22871 31 120212030384 Which of the following has the greatest penetrating power? A. alpha particles B. beta particles C. electrons D. gamma particles 9 E. helium ions 0020 2910032 A 15 22874 31 120403590282 Both the geiger_muller counter and the cloud chamber utilize the following principle A. ionization of gases by subatomic particles B. formation of fog when air is suddenly cooled C. conduction of an electric current D. alpha particles are stopped by thin metal 9 E. electrons move faster than alpha particles 0020 2910033 B 15 22879 51 120505900418 The intensity of radiation can be measured in A. lumens B. curies C. half_lives D. becquerels 9 E. none of these 0020 2910034 E 15 22881 51 121908350353 One of the biggest dangers from nuclear explosions is A. gamma radiation B. shock_waves C. radioactivity D. long_lived isotopes 9 E. all of these 0020 2910035 E 15 22884 51 035306320620 An isotope that fissions spontaneously and has a fission half_life of 85.5 years is A. kurchatovium_254 B. lawrencium_252 C. uranium_233 D. berkelium_252 9 E. californium_252 0020 2910036 E 15 22887 31 061706061337 Radioactivity was discovered by A. Rutherford 0020 9 B. Bohr C. Roentgen D. Moseley E. Becquerel 2910037 B 14 22889 31 035806600340 The alpha particle is 9 A. a positron B. a helium nucleus C. an electron D. a proton 0019 2910038 A 15 22891 31 062006600353 A 0.1 g sample of an isotope has a half life of 10 hours. The half life of a 0.2 g sample of the same isotope is ______hours. 9 A. 10 B. 5 C. 20 D. 2 E. 50 0019 2910039 A 13 22894 31 035803420660 The loss of an alpha particle by a nucleus produces_______in the neutron to proton ratio. 9 A. an increase B. a decrease C. no change 0019 2910040 B 15 22896 31 06601285 5 234 The isotope Th decays by the emission of a beta particle. 4 90 The daughter produced is 5 230 234 234 233 A. Ra B. Pa C. Ac D. Th 4 88 91 89 90 9 E. the beta particle 0040 2910041 C 15 22900 52 028806600620 A sample of a radioisotope with a nonradioactive daughter is found to lose 87.5% of its radioactivity in 30 minutes. The half_life of this isotope is A. 20 min B. 15 min C. 10 min D. 5 min 9 E. no correct response is given. 0040 2910042 D 15 22904 32 028806600620 After four half_lives have elapsed, the amount of a radioactive sample which has not decayed is A. 40% of original amount B. 1/4 of original amount C. 1/8 of original amount D. 1/16 of original amount 9 E. no correct response is given. 0040 2910043 D 15 22908 32 06600288 0040 If 1/8 of an isotope sample is present after 22 days, what is the half_life of the isotope? A. 10 days B. 5 days C. 2 3/4 days D. 7 1/3 days 9 E. 5 1/3 days 2910044 C 15 22911 31 06600620 Naturally occurring radioactive isotopes 3_________ A. must have very long half_lives B. must have very short half_lives C. can have either very long or very short half_lives D. do not exist 9 E. are only found on the earth[s crust 0040 2910045 E 15 22915 52 8003 The decay constant, k, of a certain radioactive nuclide is 5 _1 0.6 day . If a sample of this nuclide initially has an activity 5 _1 of 3000 disintegrations min. , how many days will have elapsed 5 _1 before it has an activity of 5.9 disintegrations min. ? (Note 2.303 log (N /N) = kt.) 4 o A. 3 days B. 5 days C. 7 days D. 9 days 9 E. 10 days 2WVW 2910046 A 0040 15 22922 31 1209 5 14 Which of the following is least likely to be dated using C? 4 6 A. ore deposits B. human skeletons C. spear shaft D. both A and B 9 E. both B and C 2910047 E 15 22926 31 0660 The rate of disintegration of a sample of a radioactive element A. can be increased by heating the sample B. is usually increased by a cyclotron C. is decreased by surrounding the sample with liquid air D. is decreased by converting the element into a compound by chemical reaction with another substance 0040 9 E. no correct response is given. 2910048 B 14 22931 51 038214990325 In determining the age of organic material, one measures A. the time required for half of the C_14 in the sample to decay B. the ratio of C_14 to C_12 in the sample C. the percentage of carbon in the sample 9 D. the time required for half the sample to decay 0009 2910049 C 14 22935 52 062005730353 The half life of uranium_238, which decomposes to lead_206, is 5 9 about 4.5 x 10 years. A rock which contains equal numbers of grams of these two isotopes would be ______ years old. 5 9 9 A. Less than 4.5 x 10 B. 4.5 x 10 5 9 9 C. more than 4.5 x 10 D. cannot say 0009 2910050 B 15 22940 31 061606061337 X_ray were discovered by A. W. Roentgen B. H. Becquerel C. M. Curie and P. Curie 9 D. J. J. Thompson E. E. RuTherford 0034 2910051 B 15 22942 31 06170606 Natural radioactivity was discovered by A. W. Roentgen B. H. Becquerel C. M. Curie and P. Curie 9 D. J. J. Thompson E. E. Rutherford 2910052 C 15 22944 31 018903790606 The two radioactive elements radium and polonium were discovered by A. W. Roentgen B. H. Becquerel C. M. Curie and P. Curie 9 D. J. J. Thompson E. E. Rutherford 2910053 D 14 22947 31 0358 An alpha particle is essentially A. an electron B. a proton 9 C. a positron D. a helium nucleus 2910054 B 14 22949 31 06200660 A very unstable isotope has a A. very high kinetic energy B. very short half_life C. strong tendency to undergo fusion 0034 0034 0003 0003 9 D. strong tendency to emit positrons 2910055 C 14 22952 31 Gamma rays are A. high_energy electrons B. low_energy electrons C. high_energy photons 9 D. high_energy positrons 1202 0003 2910056 B 14 22954 31 00971465 It is believed that one particle which is usually found in the nucleus is the 9 A. electron B. proton C. beta particle D. gamma ray 0003 2910057 A 14 22956 31 06171251 Which of the following is not radioactive? 5 13 13 3 5 A. C B. N C. H D. He 94 6 7 1 2 0003 2910058 A 14 22958 31 06610379 An isotope which has too high a neutron_proton ratio can gain stability by A. beta emission B. gamma emission 9 C. proton emission D. K capture 0003 2910059 A 14 22961 31 0620 If 1.0 g of an isotope has a half_life of 15 hr, the half_life of a 0.50_g sample is: 9 A. 15 hr B. 30 hr C. 7.5 hr D. 60 hr 2910060 C 14 22963 72 195412020185 Which carries no charge? 9 A. alpha rays B. beta rays C. gamma rays D. positrons 2910061 A 15 22965 31 06608001800313 An atom with mass number 238 and atomic number 92 emits in succession an alpha particle, a beta particle, a beta particle and an alpha particle. The resultant atom must have A. mass number 230, atomic number 90 B. mass number 232, atomic number 92 C. mass number 228, atomic number 90 D. mass number 230, atomic number 88 9 E. mass number 230, atomic number 92 2910062 DAEDBDEC 85 22972 31 1390 0003 0061 ETS2WVW ETS2WVW MACROITEM STEM 2After each exercise number on the answer sheet, blacken the one 3 ___ 2lettered space which designates the correct answer. 2U(238/92) _ U x 1 + alpha 0 U x 1 = U x 2 + beta MACRO SUB_ITEM # 1 The uranium atom is radioactive, emitting an alpha_particle to become a new atom Ux1. the the atomic number of Ux1 is A. 94 B. 92 C. 91 D. 90 1 E. 88 MACRO SUB_ITEM # 2 The basis for the above prediction is A. the alpha_particle has a charge of two positive units B. the alpha_particle has no charge C. the alpha_particle has a charge of one positive unit D. the alpha_particle has a mass of four units 2 E. the alpha_particle has a charge of two negative units MACRO SUB_ITEM # 3 The atomic weight of Ux1 is A. 240 B. 238 C. 237 D. 236 3 E. 234 MACRO SUB_ITEM # 4 The basis for the above prediction is that the alpha_particle has A. a charge of two negative units B. no charge C. a mass of two units D. a mass of four units 4 E. a mass negligible to that of the uranium atom MACRO SUB_ITEM # 5 The atom Ux1 emits a beta_particle, forming a new atom, Ux2. the atomic number of Ux2 is A. 92 B. 91 C. 901 D. 89 5 E. 88 MACRO SUB_ITEM # 6 The basis for the above prediction is that The beta_particle has A. no charge B. a charge negligible compared with that of the nucleus of the Ux1 atom C. a mass negligible compared with that of the Ux1 atom D. a charge of one negative unit 6 E. a charge of two negative units MACRO SUB_ITEM # 7 The atomic weight of Ux2 is A. 240 B. 238 C. 237 D. 236 7 E. 234 MACRO SUB_ITEM # 8 The basis for the above prediction is that The beta_particle has A. no charge B. a charge negligible compared with that of the nucleus of the Ux1 atom C. a mass negligible compared with that of the Ux1 atom D. a charge of one negative unit 9 E. a charge of two negative units 2930001 A 15 22996 31 03790351800111 Substances are radioactive when A. the atomic nucleus is unstable B. the orbital electrons are easily lost C. the atom gains electrons readily D. they readily form ions 9 E. they are chemically reactive ETS2WVW 2930002 C 15 22999 31 03420097800111 A general rule for nuclear stability is A. instability increases as the charge on the nucleus decreases B. a heavier nucleus is usually more stable than a lighter one C. when a nucleus contains more protons than neutrons it is unstable D. emission of alpha, beta, or gamma particles contributes to increased instability of the nucleus 9 E. none of the above offers a general rule ETS2WVW 2930003 A 14 23005 31 034200970341 Stable atomic nuclei weigh A. less than the total weight of their constituent protons and neutrons B. the same as the total weight of their constituent protons and neutrons C. more than the total weight of their constituent protons and 0041 9 neutrons D. sometimes more and sometimes less than the total weight of their constituent protons and neutrons 2930004 D 14 23011 51 027603171683 According to Yukawa's theory, nuclear forces arise through the exchange between nucleons of 9 A. electrons B. protons C. neutrinos D. mesons 0041 2930005 A 15 23013 52 179516851683 An important parameter for judging the stability of a nuclide is the binding energy for nucleon. Calculate the binding energy per 3 ___ nucleon in MEV for C_13, which has a mass of 13.00335 amu. Mass of proton = 1.007277 mass of neutron = 1.008665 mass of electron = 0.0005486 0044 5 2 conversion factor for E = mc is 931 MEV/amu. 9 A. 7.47 B. 97.1 C. 7.23 D. 94.0 E. 7.00 2930006 A 15 23020 51 035310960417 Isotopes below the belt of stability (low neutron_to_proton ratio) are likely to be A. positron emitters B. electron emitters C. stable D. alpha emitters 9 E. gamma ray emitters 0018 2930007 A 14 23023 51 034100970337 The ratio of neutrons to protons in stable isotopes A. increases with increasing atomic number B. decreases with increasing atomic number C. follows NO general pattern with increasing atomic number 9 D. does not change appreciably with atomic number 0018 2930008 B 15 23027 31 Radioactivity is caused by A. electrons in the nucleus B. unstable nuclei in atoms C. gamma radiation D. short half_lives 9 E. too many isotopes 0020 061702910342 2930009 D 15 23030 51 035312140341 Which of the following isotopes are fissionable when struck by slow neutrons? A. U_234 B. U_238 C. Np_239 D. Pu_239 9 E. Cf_250 0020 2930010 C 15 23032 31 015906610398 The energy obtained from nuclear reactions comes from A. endothermic reactions B. explosions C. conversion of mass to energy D. helium being converted to hydrogen 9 E. radioactive decay of uranium 0020 2930011 B 15 23035 31 0660 Isotopes whose neutron_to_proton ratios lie above the "region of stability" are most likely to emit A. alpha particles B. beta mimus particles C. gamma rays D. beta plus particles (positrons) 9 E. both B and D 2930012 D 15 23039 52 06600628 0040 0040 5 9 The half_life of uranium_238 is 4.5 x 10 years. This means that 5 9 after 4.5 x 10 years, for a given sample of uranium_238, A. the sample disappears B. the sample is half as radioactive C. the sample has a weight 1/2 its original weight D. the sample contains 1/2 as many uranium_238 atoms as originally 9 E. both B and D are correct 2930013 C 14 23045 52 03530632 Which one of the following isotopes would be most likely to undergo fission? 5 14 59 239 2 A. C B. Co C. Pu D. H 94 6 27 94 1 2930014 D 14 23048 72 195417950620 0009 0061 Two nuclides of Pa, each with mass number 234 and half_lives of 1.18 minutes and 6.66 hours respectively, are best described as: 9 A. isotopes B. isobars C. isotones D. nuclear isomers 2930015 D 15 23051 52 8003 Nuclides having different numbers of neutrons and protons but equal mass numbers are referred to as isobars. Nuclides having 3 _______ equal numbers of neutrons but differing in atomic number and mass number are called isotones. Which one of the classifications given 3 ________ for the following pairs of nuclides is incorrect? 3 _________ 5 14 14 A. C and N isobars 4 6 7 5 14 15 B. C and N isotones 4 6 7 5 58 60 C. Co and Co isotopes 4 27 27 5 102 102 D. Ru and Rh no relationship 4 44 45 5 39 40 E. K and Ca isotones 94 19 20 2WVW 2930016 E 15 23063 51 Pick the nucleus most likely to emit a beta particle. 5 16 15 16 14 16 A. O B. O C. O D. O E. O 94 8 8 8 8 8 OS82 2930017 D 15 23066 51 Pick the nucleus most likely to emit a positron: 5 12 13 16 14 16 A. C B. C C. O D. O E. N 94 6 6 8 8 7 OS82 2930018 B 15 23069 51 Nuclei with high neutron_to_proton ratios decay by A. positron emission C. neutron emission E. alpha capture 9 B. beta emission D. neutron capture OS82 2950001 D 15 23072 31 06560657800112 5 27 4 30 In the nuclear reaction 13Al + 2He = 14Si + ( ), the missing particle is A. an alpha particle B. a beta+ C. a beta_ 9 E. a neutron 2950002 A 15 23075 31 03510159800111 Atomic energy changes are spontaneous in all of these except 3 ______ A. platinum B. uranium C. radium D. thorium 9 E. plutonium ETS2WVW 2950003 C 15 23078 31 06148001006911 The element plutonium has gained special significance in connection with the development of A. qualitative analysis of the composition of the planets B. heat resistant steels for power jets C. the release of atomic energy D. the complete periodic table 9 E. research in some area other than one of the above ETS2WVW 2950004 A 15 23083 31 01590642800111 The energy produced in a nuclear fission bomb is the result of the A. transformation of an equivalent amount of mass B. energy produced by a chemical reaction C. energy of combustion of the subdivided atoms D. energy of the neutrons which are sent in all directions 9 E. energy of the gamma rays ETS2WVW 2950005 E 15 23088 31 05730632800111 When uranium undergoes fission as a result of neutron bombardment, the energy released in the fission process is due to A. oxidation of uranium B. the kinetic energy of the bombarding neutrons C. the radioactivity of the uranium nucleus D. the radioactivity of the fission products 9 E. the conversion of matter into energy ETS2WVW 2950006 DEDCCA 65 23093 MACROITEM STEM 31 1290 ETS2WVW ETS2WVW 2After each exercise number on the answer sheet, blacken the one lettered space which designates the correct answer. 3___ "The first clue as to the nature of the unusual radioactive changes that were observed with uranium lay in the statement of Hahn and Strassman in January, 1939, that barium was found in the disintegration products." (The uranium referred to is 0 one of the uranium isotopes and the atomic number of barium is 56.) MACRO SUB_ITEM # 1 the above statement refers to A. a chemical reaction of uranium and barium B. combustion of uranium and oxygen, barium is in the ashes C. U_238 when, in presence of neutrons, it fissions or disintegrates D. U_235 when, in presence of neutrons, it undergoes fission 1 E. U_238 when, in presence of protons, it reacts to produce barium MACRO SUB_ITEM # 2 A radioactive isotope is an element which A. has a high temperature B. is chemically reactive__orbital electrons are in an unstable state C. has a nucleus which undergoes a change with absorption of energy D. is chemically inert E. has a nucleus which spontaneously undergoes change liberating 2 energy and often some kind of charged particle MACRO SUB_ITEM # 3 An explosion does not result from a small piece of U_235 because A. U_235 does not fission. B. The neutrons released move too fast to start a chain reaction. C. U_238 is needed. D. So many neutrons escape a small piece of the metal that a chain reaction cannot start. 3 E. A little U_236 is needed as a trigger. MACRO SUB_ITEM # 4 5 14 Radioactive carbon C has a half life of 4700 years. 4 6 5 14 It changes slowly to ordinary nitrogen N according to 4 7 514 14 C _____> N + X 46 7 The particle X must be A. a proton B. a deuteron C. an electron D. an alpha particle 4 E. a gamma ray MACRO SUB_ITEM # 5 The atomic pile consists of bars of uranium interspersed with graphite rods. The purpose of the latter is to A. furnish neutrons for the fission process B. react with U_235 and release energy C. act as a neutron moderator slowing down fast neutrons D. release energy by combustion and this energy in turn triggers the atomic fire 5 E. furnish deuterons to fission atoms of u238 MACRO SUB_ITEM # 6 The energy produced in a nuclear fission bomb is the result of the A. disappearance of an equivalent amount of mass B. energy produced by a chemical reaction C. energy of combustion of the subdivided atoms D. energy of the neutrons which are sent in all directions 9 E. energy of the gamma rays 2950007 ABD 35 23127 31 0656063205181290 MACROITEM STEM 2Consider the following five nuclear reactions 5 238 90 146 2 2 A. U + n(1/0) = Kr + Cs + H + n(1/0) 4 92 36 55 1 239 96 141 2 B. Pu + n(1/0) = Sr + Ba + n(1/0) 4 94 38 56 5 238 234 4 2 C. U = Th + He 4 92 90 2 5 3 2 4 2 D. H + H = He + n(1/0) 4 1 1 2 5 107 108 108 2 E. Ag + n(1/0) = Ag = Cd + e_ 4 47 47 48 2Indicate, by marking the appropriate space on the answer sheet, 0 which one represents the following. MACRO SUB_ITEM # 1 1 A fission reaction which can be activated by slow neutrons. MACRO SUB_ITEM # 2 A fission reaction which cannot be activated by slow neutrons. 23 ______ ETS2WVW MACRO SUB_ITEM # 3 9 A fusion reaction which would yield large amounts of energy. 2950008 E 15 23140 31 80018003 12 5 24 2 4 In the nuclear reaction Mg + H = ( ) + He the missing 4 12 1 2 particle is 5 23 A. Na 4 11 5 22 B. Ne 4 11 5 22 C. Na 4 10 5 21 D. Ne 4 10 5 22 E. Na 94 11 ETS2WVW 2950009 EA 25 23145 31 0632 1290 MACROITEM STEM 2The following questions refer to the equation for fission type 5 235 140 80 2 n(1/0) + U ___> La + D + (x)n(1/0) 4 92 57 A 0 MACRO SUB_ITEM # 1 The atomic number of element D is A. 92 B. 56 C. 46 D. 36 1 E. 35 MACRO SUB_ITEM # 2 The number, (x), of neutrons produced in the reaction is A. 16 B. 15 C. 10 D. 1 9 E. 0 ETS2WVW 2950010 CDB 35 23151 31 0656 1290 MACROITEM STEM 2The following questions refer to the transmutation reaction 5 54 2 4 52 2 Fe + H ___> He + E 04 26 1 2 A MACRO SUB_ITEM # 1 5 2 The bombarding particle ( H ) is a(an) 4 1 A. positron B. proton C. deuteron D. alpha particle 1 E. electron MACRO SUB_ITEM # 2 5 4 The particle produced, ( He ), is a(an) 4 2 A. positron B. proton C. deuteron D. alpha particle 2 E. electron MACRO SUB_ITEM # 3 Element E is A. iron B. manganese C. cobalt D. chromium 9 E. nickel 2950011 CEEB 45 23160 31 0656800180031290 MACROITEM STEM 2The following questions represent changes involving the nuclei of 2atoms. After each item number on the answer sheet, blacken the 2one lettered space which designates the correct answer, choosing 3___ 2your answer from the group of answers below. 2 A. If X is X(239/94) 2 B. if X is X(234/90) 2 C. if X is X(239/93) 2 D. if X is X(242/94) 0 E. if X is X(239/92) MACRO SUB_ITEM # 1 1 U(239/92) ___> X + e_ ETS2WVW ETS2WVW MACRO SUB_ITEM # 2 2 Np(239/93) ___> X + e_ MACRO SUB_ITEM # 3 3 U(238/92) + neutron ___> X MACRO SUB_ITEM # 4 5 4 U(238/92) ___> He + X 94 2 2950012 BDDEAA 65 23167 31 0656800180031290 MACROITEM STEM 2For the following questions, select your answer from the list of 2nuclear reactions below. 2 A. If X is Cm(242/96) 2 B. if X is Pu(241/94) 2 C. if X is Cm(240/96) 2 D. if X is Pu(239/94) 02 E. if X is Np(238/93) MACRO SUB_ITEM # 1 1 U(238/92) + He(4/2) ___> n(1/0) + X MACRO SUB_ITEM # 2 2 X + He(4/2) ___> n(1/0) + Cm(242/96) MACRO SUB_ITEM # 3 e_ e_ 3 U(238/92) + n(1/0) ___> U(239/92) ___> Np(239/93)___> X MACRO SUB_ITEM # 4 4 U(238/92) + h(2/1) ___> 2 n(1/0) + X MACRO SUB_ITEM # 5 5 Pu(239/94) + He(4/2) ___> X + n(1/0) MACRO SUB_ITEM # 6 9 Am(242/95) ___> e_ + n 2950013 DAEC 45 23174 31 0656800180031290 MACROITEM STEM 2Radioactive sodium can be obtained from ordinary sodium by the 2following nuclear reaction 02 Na(23/11) + H(2/1) ___> Na(24/11) + H(1/1) MACRO SUB_ITEM # 1 The particle used in causing the change shown above is A. a neutron B. an alpha particle C. a proton D. a deuteron 1 E. a beta particle MACRO SUB_ITEM # 2 This particle is usually obtained through use of a ETS2WVW ETS2WVW A. cyclotron B. cloud chamber C. mass spectrograph D. uranium pile 2 E. radioactive element fround in nature MACRO SUB_ITEM # 3 The particle formed in addition to the radioactive sodium is A. an alpha particle B. an electron C. a neutron D. a deuteron 3 E. a proton MACRO SUB_ITEM # 4 The atomic weight of the radioactive element is A. 11 B. 23 C. 24 D. 12 9 E. none of these 2950014 ECAEDBBC 85 23184 31 0656 1290 MACROITEM STEM 2After the number on the answer sheet corresponding to that of 2each of the numbered nuclear reactions at the right, blacken the 2one lettered space which indicates the correct substitute for "X". 3___ 5 13 2 A. If X is N 4 7 5 17 2 B. If X is F 4 9 5 15 2 C. If X is O 4 8 5 14 2 D. If X is C 4 6 5 16 2 E. If X is N 04 7 MACRO SUB_ITEM # 1 5 15 2 1 N + H ___> X + H 147 1 1 MACRO SUB_ITEM # 2 ETS2WVW 5 16 1 1 O + n ____> X + n 248 0 0 MACRO SUB_ITEM # 3 5 12 2 1 C + H _____> X + n 346 1 0 MACRO SUB_ITEM # 4 5 19 1 4 F + n _____> X + He 449 0 2 MACRO SUB_ITEM # 5 5 14 1 1 N + H _____> X + H 547 0 1 MACRO SUB_ITEM # 6 5 16 1 O + H _____> X 648 1 MACRO SUB_ITEM # 7 5 14 4 1 N + He _____> X + n 747 2 0 MACRO SUB_ITEM # 8 5 16 1 O _____> X + n 948 0 2950015 E 15 23198 31 03510159023511 Atomic energy changes are spontaneous in A. uranium B. radium C. thorium D. plutonium 9 E. all of these 2950016 C 14 23200 31 03420632 5 235 The splitting of an atomic nucleus, such as that of U , into two or more large pieces is called 9 A. sublimation B. fusion C. fission D. a chain reaction 2950017 D 14 23203 31 015903421221 Which of the following does not make use of the energy evolved when two light nuclei fuse together to make a heavier one? A. The generation of energy within stars B. Proposed thermonuclear power plants 9 C. Hydrogen bombs D. Nuclear reactors ETSZWVW 0041 0041 2950018 B 14 23207 31 121506320341 The term chain reaction is used to refer to A. the linking together of protons and neutrons to form nuclei B. the successive fissions of nuclei induced by neutrons from the fissions of other nuclei C. the setting off of a hydrogen bomb by an atomic bomb D. the combustion of uranium in a special type of furnace 9 called a nuclear reactor 0041 2950019 C 14 23212 52 009703421167 5 11 A fast proton strikes a B nucleus and reacts with it to produce a 4 5 511 C nucleus. There is emitted in the process 46 9 A. a proton C. a neutron E. an alpha particle 0041 2950020 B 14 23216 32 066103510342 5 14 The first nuclear reaction ever observed occurred when N atoms 4 7 5 4 were bombarded with He nuclei (which are alpha particles) and 4 2 protons were ejected. This reaction produces 5 17 17 17 17 A. N B. O C. F D. Ne 94 7 8 9 10 0041 2950021 A 14 23222 51 049512060097 The only one of the following particles that does not decay in free space into another particle is the 9 A. proton B. neutron C. pion D. muon 0041 2950022 D 15 23224 52 116704071159 5 4 9 One gram of He reacts with an excess of Be in the reaction 4 2 4 5 9 4 12 1 Be + He _____> C + N 4 4 2 6 0 5 12 How many grams of C will be formed? 4 6 9 A. 0.33 g B. 12. 0 g C. 9.0 g D. 3.0 g E. 18.0 g 0047 2950023 B 15 23230 52 122104070189 In a present day nuclear reactor a typical reaction is: U_235 + neutron _____> Kr_93 + Ba_140 + 3 neutrons select the one correct statement. 3 _______ A. This reaction is called fusion. B. A variety of reactions creating pairs of elements similar to these can occur when neutrons strike U_235. C. The sum of the masses of the products exceeds that of the reactants. D. In the above reaction the number of nucleons is conserved but two positive charges are created. E. The above reaction could not become explosive under any 9 conditions. 0044 2950024 B 14 23238 52 06611076064251 Which nuclear reaction is properly balanced? 5 4 9 12 1 A. He + Be _____> C + H 4 2 4 6 1 5 4 14 17 1 B. He + N _____> O + H 4 2 7 8 1 5 12 1 14 1 C. C + H _____> N + n 4 6 1 7 0 5 14 0 14 D. N + e _____> O 4 7 _1 8 5 16 0 16 E. O + e _____> F 94 8 _1 9 9000 2950025 B 15 23245 51 101210150642 The liquid_metal_cooled fast breeder reactor (LMFBR) is A. a kind of nuclear reactor that produces NO radioactive wastes B. a kind of nuclear power plant in which plutonium serves as a fuel C. a reactor involving fusion D. a reactor involving uranium_235 as the main fuel 9 E. none of these 0018 2950026 D 15 23250 51 037901891094 All of the following are released by radioactive elements except 0018 9 A. gamma rays B. beta rays C. alpha particles D. canal rays (positive ions) E. positrons 2950027 A 15 23253 52 035306201097 If 1 g of an isotope has a half_life of 15 hr, the half_life of a 0.50 g sample is 9 A. 15 hr B. 30 hr C. 7.5 hr D. 60 hr E. 45 hr 0018 2950028 D 14 23255 51 049103791106 The rate of decay of radioactive substances A. depends on whether the substance is a gas, liquid, or solid B. depends on the temperature and is faster at higher temperature C. depends on the temperature and is slower at higher temperature D. is independent of temperature, state, or chemical form of 9 the substances 0018 2950029 E 15 23260 32 035806600656 Astatine_218 (At) decays by alpha emission. The other atom formed is: 0028 5 216 218 217 218 214 A. Bi B. Bi C. Po D. Rn E. Bi 94 83 83 84 86 83 2950030 C 15 23264 32 06600656 Neptunium_234 (Np) decays by positron emission. The other element formed is: 5 233 230 234 234 234 A. U B. Pa C. U D. Pu E. Np 94 92 91 92 94 92 2950031 B 15 23267 32 062106600656 Californium_253 (Cf) decays by beta emission. The other element formed is: 5 252 253 253 249 A. Es B. Es C. Bk D. Cm E. none of these 94 99 99 97 96 2950032 A 5 14 23270 31 03580656800113 14 1 0028 0028 ETS2WVW 4 In the nuclear reaction N + H = C + He 4 7 1 2 A. the carbon atom produced will have a mass of 11 and an atomic number of 6 B. the carbon atom produced will have a mass of 12 and an atomic number of 5 C. the carbon atom produced will have a mass of 12 and an atomic number of 6 9 D. none of the above statements is true 2950033 A 15 23277 51 057312060358 Uranium_238 decays to give an alpha particle plus A. element 90 B. element 89 C. element 91 D. neutrons 9 E. positrons 0020 2950034 E 15 23279 51 120705731208 The end product of the uranium_238 decay series is A. carbon_14 B. thorium C. protactinium D. radon 9 E. nonradioactive 0020 2950035 C 15 23281 51 128503790341 Beta particles coming from radioactive elements are A. always of low energy B. very difficult to detect C. the result of neutrons changing to protons D. the result of protons changing to neutrons 9 E. none of these 0020 2950036 D 15 23285 51 Carbon_14 has a half_life of A. 36 years 5 8 B. 5 x 10 years C. 42 minutes 9 D. 5570 years 12090620 2950037 B 15 23287 31 120903211210 Carbon_14 is formed in the atmosphere from A. cosmic ray bombardment of oxygen B. cosmic ray bombardment of nitrogen 0020 0020 9 C. neutrons and protons D. radioactive disintegration of nitrogen_15 E. none of these 2950038 B 15 23290 52 003103580341 5 10 13 Complete the equation: B + alpha particles ___> N + _____ 4 5 7 A. electrons B. neutrons C. cosmic radiation D. positrons 9 E. more alpha particles 0020 2950039 C 15 23294 51 062005730398 5 9 The half_life of uranium_238 is 4.5 x 10 years. This means that 5 9 after 4.5 x 10 years A. the sample disappears B. half the original mass remains C. half the 238 isotope remains D. the sample is half as radioactive 9 E. none of these 0020 2950040 D 15 23299 51 04071211 5 30 30 0 The reaction: P ___> Si + e 4 15 14 1 A. illustrates artificial transmutation B. is impossible C. is typical of all samples of phosphorus D. produces particles similar to those discovered by anderson 9 E. illustrates artificial radioactivity 0020 2950041 E 15 23304 51 078706320342 In the process of nuclear fission A. the nucleus of an atom actually splits B. many neutrons are produced C. large amounts of energy are liberated D. gamma radiation is produced 9 E. all of these 0020 2950042 C 15 23307 31 039812151216 The mass of U_235 just large enough to sustain a chain reaction is called A. the mass number B. the nuclear mass C. the critical mass 0020 9 D. the moderator mass E. none of these 2950043 D 15 23310 51 Thermonuclear reactions A. are fission reactions B. are atomic bomb reactions C. involve lithium deuteride D. are fusion reactions 9 E. are due to radioactivity 121704070518 0020 2950044 A 15 23313 51 121806320407 The hydrogen bomb A. utilizes a nuclear fission reaction B. must be fused by a fusion reaction C. contains a large amount of plutonium D. all of these 9 E. none of these 0020 2950045 D 15 23316 51 122012210852 A moderator for use in nuclear reactors is A. cadmium B. neptunium C. boron D. graphite 9 E. U_238 0020 2950046 B 15 23318 51 004912210353 Using thorium_232 as a fuel in a nuclear reactor, it is possible to produce the fissionable isotope A. protactinium_233 B. uranium_233 C. uranium_235 D. plutonium_239 9 E. thorium_234 0020 2950047 A 14 23321 51 035306321096 An unstable isotope A. undergoes fission B. readily emits positrons C. has a short half life 9 D. lies within the belt of stability 0019 2950048 E 15 23323 51 035303580417 Isotopes whose neutron to proton ratio lie below the belt of stability are 0019 9 A. nonradioactive B. alpha emitters C. beta emitters D. positron emitters E. both B and D. 2950049 E 15 23326 51 035317410097 Isotopes whose neutron to proton ratio lie below the belt of stability A. emit protons B. emit neutrons C. emit electrons D. undergo K electron capture 9 E. both A and D. 0019 2950050 B 14 23329 31 035306321096 Isotopes which undergo fission in nature are found_______ the belt of stability 9 A. below B. above C. beyond D. in 0019 2950051 A 15 23331 31 063203530379 The products of a fission process are_____ mass than that of the radioactive isotope. 9 A. Of lower B. of higher C. of the same 0019 2950052 D 15 23333 31 0661 Nuclear reactions differ from ordinary chemical reactions in that A. different isotopes of an element have different nuclear properties B. the nuclear reactivity is independent of the state of combination C. elements may be changed into other elements during nulcear reactions D. all of the above are correct 9 E. both B and C are correct 0040 2950053 A 15 23338 31 0661 Which of the following is not true of nuclear reactions? A. all isotopes of an element undergo similar reactions B. the reactivity of an element depends upon the compound form it is in C. nuclear reactions involve large amounts of energy D. B and C are correct 9 E. no correct response is given. 2950055 A 15 23348 31 06610660 5 23 2 The bombardment of Na with H gives two products, one of which 4 11 1 is a proton. The other product is 5 24 25 25 22 A. Na B. Mg C. Na D. Mg 0040 0040 4 11 12 11 12 9 E. no correct response is given. 2950056 B 15 23353 31 06610660 5 250 11 Bombardment of Cf by B yields 4 neutrons and an isotope of 4 98 5 an element of atomic number A. 104 B. 103 C. 102 D. 99 9 E. either A or B 0040 2950057 C 15 23356 31 06610660 Which particle is needed to balance the following nuclear reaction? 5 7 4 Li + _____ _____> 2( He) 4 3 2 A. an alpha B. a beta minus C. a proton D. a neutron 9 E. either C or D 0040 2950058 C 15 23360 31 06600661 5 234 A uranium isotope, U, decays by alpha emission. The resulting 4 92 isotope is 5 238 230 230 234 A. Cm B. Ra C. Th D. Np 4 96 88 90 93 9 E. no correct response is given. 0040 2950059 D 15 23364 31 06600661 5 56 56 The isotope Mn spontaneously decays to give Fe. The process 4 25 26 also involves A. the capture of an electron by the Mn_56 nucleus B. the emission of a positron 9 E. either A or B 2950060 E 15 23368 31 05181538 Fusion is the process of A. bombarding a large nucleus with small particles B. splitting a nucleus into many small fragments C. splitting a nucleus into two fragments of about equal mass D. making a nonradioactive substance radioactive 9 E. both A and D 0040 0040 2950061 D 15 23372 31 06610632 Nuclear fission is the process A. of putting light nuclei together to form heavier nuclei B. which occurs in the hydrogen bomb explosion C. which occurs on the sun D. of splitting heavier nuclei to form lighter nuclei 9 E. the splitting of molecules into their constituent atoms 2950062 C 15 23376 31 1223 Transuranium elements A. are made by nuclear fusion B. result from natural radioactive decay C. have atomic numbers greater than 92 D. have greater half_lives than uranium 9 E. are made from uranium 0040 0040 2950063 D 14 23379 51 037907870358 5 235 A certain radioactive series starts with U and ends with 4 92 5207 Pb. In the overall process, _____ alpha_particles and _____ 4 82 beta_particles are emitted. 9 A. 8, 6 B. 14, 10 C. 7,10 D. 7, 4 0009 2950064 D 15 23383 52 009703530587 5 75 2 Bombardment of As by a deuteron, H, forms a proton and an 4 33 1 isotope which has a mass number of _____ and an atomic number of 9 A. 73,32 B. 75,33 C. 75,32 D. 76,33 E. 76,34 0009 2950065 C 14 23387 52 018900650353 The element silicon has an atomic weight of about 28. The 5 30 isotope Si would most likely decay by emitting a(n) 4 14 9 A. positron B. proton C. electron D. alpha particle 0009 2950066 B 15 23390 52 0031 Which of the following equations is incorrect? 5 28 1 28 1 A. Si + n _____> Al + H 4 14 0 13 1 5 28 1 28 1 0034 B. Si + H _____> Al + n 4 14 1 13 0 5 25 4 1 28 C. Mg + He _____> H + Al 4 12 2 1 13 5 27 2 28 1 D. Al + H _____> Al + H 4 13 1 13 1 5 40 40 0 E. K ______> Ca + e 94 19 20 _1 2950067 A 14 23397 72 19540341 5 7 2 8 In Li + H ___> Be + (?), the missing species is: 4 3 1 4 5 1 4 0 1 A. n B. He C. e D. H 94 0 2 _1 1 0061 2950068 D 15 23400 52 19541285 5234 234 Th is converted into Pa by: 4 90 91 A. proton emission B. positron emission 9 D. beta emission E. alpha capture 0061 C. K electron capture 2950069 DDECADCAD95 23403 31 80018003 1290 MACROITEM STEM 2For the following items, the notation used is as follows M(A/Z), 2where M is the symbol for the element or particle, A is the atomic 2mass and Z is the atomic number or charge. Thus uranium 238 becomes 2U(238/92). Now, consider the following nuclear reactions 2 U(238/92) + n(1/0) ___> U(239/92) 2 U(239/92) ___> Np(239/93) + energy + e(0/_1) 2 Np(239/92) ___> Pu(239/94) + e(0/_1) 2If the neutron concentration becomes too high as shown by neutron 2counters placed within the pile the condition is corrected by 2insertion of Cd bars. An outside continuous source of neutrons 2is not required because neutrons are supplied by fission of 2some of the U_235 atoms and by fission of some of the newly formed 2Pu_239 (the product of the pile). Using this information, answer 0 the following questions. MACRO SUB_ITEM # 1 To be accepted into the nucleus by uranium_238, neutrons must be A. fast ETS2WVW 1 2 3 4 5 6 B. energetic C. hot D. slow E. fresh from an outside source MACRO SUB_ITEM # 2 Np(239/94) which is formed first, must be converted to Pu(239/94) by A. bombardment with more neutrons B. bombardment with deuterons C. bombardment with alpha particles D. allowing it to undergo natural radioactive decay E. chemical treatment MACRO SUB_ITEM # 3 Of the particles and nuclei listed in symbols above, the one which is an isotope of U_238 is A. Pu(239/99) B. electron C. Np(238/93) D. U(238/92) E. U(239/92 MACRO SUB_ITEM # 4 After the reaction has started, it is kept going by neutrons supplied in part by A. an outside source B. Np(239/93) C. Pu(239/94) D. U(234/92) E. U(239/92) MACRO SUB_ITEM # 5 Pu_239 is produced at an increasingly rapid rate because A. as in the fission of U(235/92) the fission of Pu(239/94) releases 3 neutrons B. in addition to the main reaction there are certain side reactions that produce Pu(239/94) C. no Pu(239/94) atoms are lost once they are formed D. presence of Cd stabilizes and prevents decay of the Pu(239/94) E. presence of carbon stabilizes and prevents decay of the Pu(239/94) MACRO SUB_ITEM # 6 Hydrogen nuclei tend to trap neutrons because of the tendency to form A. alpha particles B. positrons C. gamma rays D. deuterons E. beta rays MACRO SUB_ITEM # 7 The use of cadmium in the pile is to A. make the neutrons go faster B. absorb heat C. remove neutrons D. interfere with the action of the graphite 7 E. convert the neutrons to alpha particles MACRO SUB_ITEM # 8 The first atomic pile was set into operation by A. Fermi B. Rutherford C. Seaborg D. Nier 8 E. Joliot MACRO SUB_ITEM # 9 when U(239/92) changes to Np(239/94) the electron comes from A. an orbital electron B. a nuclear proton C. a nuclear alpha particle D. a nuclear neutron 9 E. a nuclear deuteron 2950070 E 15 23439 31 06568001800312 Carbon serves as a moderator in the atomic pile. It captures a few neutrons according to the following equation 5 12 13 C + n(1/0) ___> C 4 6 6 The most important use of this product is for A. producing very hot flames B. making atom bombs C. curing cancer D. making artificial diamonds 9 E. a tracer element in chemistry 2950071 C 12 12167 32 03851486 5 226 Emission of an alpha particle from a Ra nucleus yields 4 88 A. Th B. Ra C. Rn D. Po 94 90 88 86 84 2950072 B 15 44766 31 5 210 Emission of a beta particle from a Pb nucleus yields 4 82 5 211 210 210 206 212 ETS2WVW 0003 A. 94 Pb 82 B. Bi 83 C. Tl 81 D. Hg 80 E. Pb 82 2970001 C 15 23445 31 05188001800312 The sun radiates a large amount of energy as a result of the union of four hydrogen atoms to form the helium atom. The reason for this release of energy is that A. the hydrogen atoms are in a high state of thermal excitation B. the coulomb forces of attraction between the nuclei of the hydrogen atoms are large C. the mass of the helium atom is less than the mass of the four hydrogen atoms D. large numbers of neutrons are released during the formation of the helium atom 9 E. gamma rays released in this process have very high energy ETS2WVW 2970002 D 14 23453 31 06090590800311 Cosmic rays are usually considered to be A. by_products of some process of atomic creation B. by_products of atomic annihilation C. diffused radiation in space congealing into particles of matter_electrons, atoms, and molecules D. high_energy radiation coming from the far reaches 9 of interstellar space ETS2WVW 2970003 D 15 23458 31 06090633800111 Cosmic rays may be audibly detected by A. a fluorescent tube B. the cyclotron C. the oscilloscope D. the geiger counter 9 E. the stroboscope ETS2WVW 2970004 C 15 23461 32 05840196800111 In the underwater explosion of an atomic bomb at Bikini in 1946, a fusion chain reaction of the hydrogen in the water did not occur because A. ocean water has enough salts in solution to absorb extra neutrons B. the possibility of a release of energy by fusion of hydrogen was not known at that time C. the temperature produced by the atomic bomb was too low to initiate the reaction D. the bomb was particularly designed to prevent a fusion reaction E. direct fusion of protons proceeds at a very slow rate even in ETS2WVW 9 the interior of stars 2970005 C 15 23469 52 The mass spectrum in the parent molecular ion region of PBr , a 4 3 5 o colorless liquid boiling at 173 C, shows four peaks at 268, 270, 272 and 274 amu. Assuming the existence of Br_79 and Br_81, what are the isotopes of phosphorous and their relative abundance? 2 3 2 5 2 5 2 5 2 5 2 5 92 Isotopes ________ 30 A. P 30 31 B. P and P 31 C. P 29 32 D. P and P 30 33 E. P and P 2WVW Relative abundance __________________ 100% abundant 1:3 100% abundant 3:1 1:1 2970007 BD 25 44770 31 0656 1290 MACROITEM STEM 2The following questions refer to the transmutation equation 5 13 2 X 1 C + H ___> N + n 04 6 1 7 0 MACRO SUB_ITEM # 1 The bombarding particle is a(an) A. positron B. proton C. deuteron D. alpha particle 1 E. electron MACRO SUB_ITEM # 2 The atomic weight, (X), of the nitrogen is A. 21 B. 19 C. 14 D. 13 9 E. 12 ETS2WVW 2970008 BEA ETS2WVW 35 23498 31 0656 1290 MACROITEM STEM 2The following question refer to the equation for a simple capture 2type of nuclear reaction 5 12 1 2 C + H ___> N 4 6 1 0 Using this information, answer the following questions. MACRO SUB_ITEM # 1 The atomic number of the nitrogen produced would be A. 5 B. 7 C. 8 D. 11 1 E. 13 MACRO SUB_ITEM # 2 The atomic weight of the nitrogen produced would be A. 5 B. 7 C. 8 D. 11 2 E. 13 MACRO SUB_ITEM # 3 The carbon is being bombarded with a(an) A. proton B. deuteron C. alpha particle D. beta particle 9 E. neutron 2970009 B 15 23506 52 077307748003 One of the fusion reactions believed to take place during a thermonuclear explosion is 5 6 2 4 Li + H = 2( He ) 43 1 2 where the terminology used is "Z_symbol_mass" for each isotope. Calculate the energy released for every two atoms of helium formed by this reaction. 5 2 4 (Isotopic wt H = 2.01410 amu, He = 4.00260 amu, 4 1 2 5 6 Li = 6.01513 amu; 1 amu = 931 mev) 43 A. 0.024 MEV B. 22.4 MEV 2WVW 9 C. 27.3 MEV D. 93 MEV E. 400 MEV 2970010 B 15 23514 51 04070331 One of the reactions occurring on the sun is probably 5 238 1 237 A. U ___> n + U 4 92 0 92 5 1 2 3 B. H + D ___> He 4 1 1 2 5 4 4 8 C. He + He ___> Be 4 2 2 4 D. all of these 9 E. none of these 0020 2970011 E 15 23519 52 033903400847 56 1 4 Li + n ___> He + ______ 43 0 2 A. deuterium B. beryllium C. H D. protons E. tritium 94 1 0020 2970012 D 15 23522 52 026305731222 5239 U ___> electron + ##### 4 92 A. plutonium_240 B. uranium_238 C. thorium D. neptunium_239 9 E. plutonium_239 0020 2990001 D 15 23524 31 00690159800111 The term, "atomic energy," refers to energy obtained from A. the electron clouds which surround atoms B. reactions between two different atoms C. endothermic chemical reactions D. within the nucleus of the atom 9 E. electrons passing into different energy levels ETS2WVW 2990002 C 15 23528 31 01590573800111 The energy released when uranium (238) atoms disintegrate results from A. the change of uranium into radium B. the emission of high speed electrons C. the conversion of matter to energy ETS2WVW 9 D. the formation of the isotope u235 E. the emission of alpha particles 2990003 C 15 23532 32 00698001015911 Early in 1905, the possibility of an atomic bomb had been forecast in the work of Dr. Albert Einstein. His suggestion was that A. matter and energy were separate and distinct from one another B. while matter and energy were not entirely separate and distinct, they could not be changed one into another C. matter and energy were not separate and distinct and they could be changed one into another D. although energy could possibly be derived from matter, the amount of energy that could possibly be SO derived would be of little consequence E. while matter and energy were both separate and distinct, it was likely that energy could be converted into great quantities 9 of matter ETS2WVW 2990004 E 15 23542 52 8003 In the fusion reaction 5 2 3 4 1 H + H ___> He + n 4 1 1 2 0 17.6 MEV of energy is released. Using the data given, calculate 2WVW 5 3 the mass of a tritium atom, H . (Note: the terminology used is 4 1 "Z_symbol_mass" for each species.) 5 1 2 (isotopic wt. n = 1.00899 amu. H = 2.01410 amu, 4 0 1 5 4 He = 4.00260 amu; 1 amu = 931 MEV) 42 A. 2.60899 amu B. 2.97947 amu C. 2.99749 amu D. 3.01286 amu 9 E. 3.01639 amu 2990005 D 15 23551 52 015906320642 Calculate the amount of energy in MEV liberated in the following nuclear fission reaction, given the information below: U_235 + neutron _____> Rb_91 + Cs_142 + 3 neutrons 0044 5 2 conversion factor for E = mc is 931 mev/amu mass of neutron = 1.01 amu mass of U_235 = 235.04 mass of Rb_91 = 90.91 mass of Cs_142 = 141.92 9 A. 39400 B. 0.00237 C. 763 D. 177 E. 1770 2990006 B 15 23557 52 051802860414 How many tons of carbon would have to be burned, 5 o C + O (g) ____> CO (g) /\H = _393 kJ 4 2 2 __ reaction 0044 to generate as much heat as is generated when one pound of He_4 is formed according to the following fusion reaction: 5 4 9 2 3 4 1 H + H _____> He + n + 17.6 meV 1 1 2 0 A. 5230 tons B. 6270 tons C. 11.5 tons D. 49200 tons E. 434 tons. 2990007 A 15 23565 52 01590642 Calculate the amount of energy in mev liberated in the following nuclear decay reaction, given the information below: 5 2 conversion factor for E = mc is 931 mev/amu mass of proton = 1.00728 amu mass of neutron = 1.00867 mass of electron = 0.00055 mass of Cl_36 = 35.96831 mass of Ar_36 = 35.96755 5 _ Cl_36 _____> Ar_36 + beta 9 A. 0.196 B. 0.000816 C. 3.16 D. 0.00118 E. 0.7080 2990008 C 15 23571 Einstein's equation says A. E = mass x c 5 2 B. E = length x c 5 2 C. E = c x mass 5 2 31 036400310159 0044 0020 9 D. E = mass x c E. none of these 2990009 A 15 23574 31 038503980031 When the units for c in m/s and for mass in kg are used when solving Einstein equation problems, the energy units obtained are A. joules B. ergs C. neutons D. calories 9 E. dynes 0020 2990010 C 15 44651 51 16850587 The binding energy per nuclear particle is greatest for elements of ______ mass number. 9 A. high B. low C. intermediate D. integral E. negative 0019 2990011 B 13 23579 31 16850587 The slope of the binding energy curve is steepest in the region of ________mass number. 9 A. high B. low C. intermediate 0019 2990012 D 14 23581 52 015903640661 5 2 According to the Einstein relation (E = mc ), the energy given off in a nuclear reaction in which the decrease in mass is 2.0 mg would be 5 21 20 A. 1.8 x 10 ergs B. 1.5 x 10 ergs 5 20 9 C. 9.0 x 10 ergs D. some other number 0009 2990013 B 14 23586 52 039803420159 5 4 6 10 The masses of He, Li and B are 4.0015, 6.0135 and 10.0102 4 2 3 5 amu, respectively. The splitting of a boron_10 nucleus to helium_4 and lithium_6 would A. evolve energy B. absorb energy 9 C. result in no energy change D. cannot say 0009 3100001 D 15 23590 31 00670068800112 "The properties of the elements are periodic functions of their atomic weights" means that A. in a given group certain properties recur at regular intervals as the atomic weight increases ETS2 OS 9 B. elements function periodically C. the atomic weights of the elements, plotted against their atomic numbers, give a wave_like curve D. with progressive increase in atomic weight of the elements, types of chemical behavior recur at regular intervals E. in a collection of elements picked at random, one element in eight will have a valence of one 3100002 D 15 23598 31 03370367800111 The modern form of the periodic law states that the properties of the elements are a periodic function of their A. atomic volume B. ionization potential C. atomic weight D. atomic number 9 E. valence ETS2 OS 3100003 E 15 23601 31 03698001800211 Elements that lose electrons from more than one electronic energy level in ordinary chemical reactions are called the A. alkali elements B. alkaline earth elements C. light elements D. radioactive elements 9 E. transition elements ETS2 OS 3100004 B 14 23605 31 037104638004 According to Mendeleev the chemical properties of elements are periodic functions of their A. atomic mass B. atomic weight C. atomic number 9 D. isotopic weight 2 OS 3100005 C 14 23608 31 018903628004 A vertical column of elements in the periodic table is known as a (an) A. octave B. period C. group 9 D. triad 2 OS 3110001 E 15 23610 31 03718001800211 Mendeleev A. showed that there were fifteen rare earth elements B. predicted the existence of the inert gases ETS2 OS 9 C. proved that there were 92 elements D. discovered the elements gallium, scandium and germanium E. corrected the values of certain atomic weights 3110002 B 14 23614 31 018902658004 The grouping of elements according to the law of octaves is credited to A. Dobereiner B. Newlands C. Ramsay 9 D. Stras 2 OS 3110003 D 14 23616 31 037001890064 The periodic table of the elements does not A. permit us to make accurate guesses of the properties of undiscovered elements B. reveal regularities in the occurrence of elements with similar properties C. include the inert gases 9 D. tell us the arrangement of the atoms in a molecule 0041 3110004 A 15 23621 31 01891366 Element 101 was named in honor of A. Mendeleev B. Mendel C. Mendelevium D. Mennin 9 E. none of these 0020 3110005 B 15 23623 52 14220065 Two members of a Dobereiner triad have atomic weights 40 and 137. The third member of the triad should be of atomic weight_____. 9 A. 79 B. 87 C. 20 D. 115 0019 3110006 D 15 23626 31 136600670065 Mendeleev stated that the properties of the elements are periodic functions of A. their atomic number B. the number of protons which they contain C. their atomic radius D. their atomic weight 9 E. the number of neutrons which they contain 0019 3110007 D 15 23630 31 036200670189 The modern form of the periodic table states that the properties of the elements are a periodic function of their 0035 9 A. atomic volume B. atomic weight. C. ionization potential. D. atomic number. E. valence. 3110008 A 15 23633 31 136600680189 Mendeleev based his periodic system of the elements on A. the recurrence of similar chemical properties when the elements were arranged in order of atomic weights B. the ionization potential of the elements C. the recurrence of similar chemical properties when the elements were arranged in order of atomic number D. theoretical arguments involving atomic structure 9 E. the nature of covalent and ionic bonds 0034 3120001 B 15 23639 32 072207238003 Which one of the following elements does not belong to 3 ___ the family of elements indicated? A. technetium (Tc)__transition metal B. tellurium (Te)__rare earth metal C. barium (Ba)__alkaline earth metal D. francium (Fr)__alkali metal 9 E. fermium (Fm)__actinide 2WVW 3120002 A 14 23644 31 01890015 The most conspicuous distinction among the elements is their division into A. metals and nonmetals B. solids, liquids, and gases 9 C. atoms and molecules D. active and inactive elements 0041 3120003 B 14 23647 51 The number of nonmetals is 9 A. 2 B. 20 C. 60 D. 92 0041 13010028 3120004 B 14 23648 31 036714020337 According to the periodic law, the chemical properties of the elements are periodic functions of their 9 A. density B. atomic number C. atomic mass D. mass number 3120005 D 14 23651 31 0370 The elements of the periodic chart are arranged in accordance with their A. atomic weight C. electron number 9 B. electrical properties D. atomic number 3120006 C 15 23654 31 006701890989 The properties of the elements are a periodic function of 0041 0026 0020 their A. isotopic composition B. atomic mass C. atomic number D. total number of neutrons 9 E. none of these 3120007 A 15 23657 31 01890015 Most of the 104 elements are 9 A. metals B. gases C. liquids D. nonmetals E. none of these 0020 3120008 B 15 23659 31 037003370189 The modern periodic table is based on the A. order of discovery of the elements B. atomic numbers of the elements C. atomic masses of the elements D. size of the elements 9 E. electronegativity of the elements 0020 3120009 A 15 23662 31 079403620263 The vertical groups of the periodic chart consist of elements that have the same number of A. electrons in the outer shell. B. electrons in the nucleus. C. total electrons. D. neutrons. 9 E. protons. 0035 3120010 B 14 23666 52 1945 The elements in the periodic table are in the order of increasing A. atomic weight B. atomic number C. neutron number 9 D. mass number 3120011 CEBD 45 23668 31 019203510199 90 MACROITEM STEM 2For each of the numbered items which follow, choose the option 2which best matches. 2 A. Hydrate 2 B. Metaloid 2 C. Oxidizing agent 2 D. Triad 0 E. Kernel MACRO SUB_ITEM # 1 1 A substance which takes up electrons during a chemical reaction 0056 2 OS MACRO SUB_ITEM # 2 2 The portion of the atom excluding the valence elecctrons MACRO SUB_ITEM # 3 An element having certain properties characteristic of a metal, 3 but which is generally classed as a nonmetal MACRO SUB_ITEM # 4 A group of elements, the middle one of which has an atomic weight which is approximately the same as the average of the atomic 9 weights of the other two elements 3121001 B 14 23676 31 03700820 Horizontal rows in the periodic table are usually called 9 A. groups B. periods C. shells D. subshells E. families 0041 3121002 D 14 23678 31 037001891445 Each horizontal row of the periodic table includes elements with chemical characteristics that are, in general A. identical B. similar C. different 9 D. sometimes similar and sometimes different 0041 3122001 B 14 23681 31 081200190344 The alkali metal which is naturally radioactive: A. radium B. francium C. lithium D. sodium 9 E. cesium 2 OS 3122002 A 12 23683 31 07940370 Vertical rows in the periodic table are usually called 9 A. groups B. periods C. shells D. subshells 0041 3122003 B 14 23685 31 037001891445 Each vertical row of the periodic table includes elements with chemical characteristics that are, in general, A. identical B. similar C. different 9 D. sometimes similar and sometimes different 0041 3122004 D 15 23688 31 037001890794 In the periodic table, elements that have a similar arrangement of electrons are grouped together in vertical columns called A. transition elements B. periods C. actinides D. periodic groups 9 E. clusters 0020 3123001 C 14 23692 31 036908448003 An example of a transition element is A. aluminum B. astatine C. nickel 9 D. rubidium 2WVW 3123002 D 14 23694 31 036201898004 In the periodic table, the percentage of elements generally regarded as metals is closest to which one of the following? A. 20 B. 35 C. 55 9 D. 75 2WVW 3123003 C 14 23697 31 80038004 An element in the same chemical family as potassium is A. copper B. helium C. lithium 9 D. zinc 2WVW 3123004 B 14 23699 31 03620722 05 Elements which are the most metallic are found in what general area of the periodic table? A. lower right C. upper right 9 B. lower left D. upper left 3124001 A 14 23702 31 03620722 05 Elements which are the most nonmetallic are found in what general area of the periodic table? A. upper right C. upper left 9 B. lower right D. lower left 3210001 C 15 23705 51 03620351800112 In the periodic table of elements, there occurs immediately after each inert gas one of the chemically very active alkali metals. This sequence is due, according to the Bohr theory, to A. a sudden increase in the nuclear charge, between the inert gas and the metal B. a sudden increase in atomic weight, owing to the high energy of the nuclei of metallic elements C. a sudden increase in the radius of the atom, leaving the outermost electron relatively loosely bound in the metallic atom ETS2 OS 9 D. a sudden change in the quantum numbers of the atom E. a sudden increase in the ionization energy, between the inert gas and the metal 3210002 D 15 23714 32 03700374800111 A series of elements in the periodic chart has atomic numbers 10, 11, 12, 13, 14, 15, 16, 17. A correct statement about this series is that A. the valence is constant for the series B. they are all metals C. the valence steadily decreases from left to right D. each element belongs to a different group 9 E. the activity steadily increases from left to right ETS2 OS 3210003 EBCDDA 65 23719 32 03801138 MACROITEM STEM 2The diagrams below symbolize the electron configurations of the 2atoms of four different elements. The symbol (n) represents the 2nucleus, and the number in front of each right parenthesis 2represents the number of electrons contained in each shell. To 2answer the following questions, mark the letter of the diagram 2which best represents the element described. If none applies, 2mark space E. 2A. (n) 2) 1) 2B. (n) 2) 4) 2C. (n) 2) 6) 2D. (n) 2) 8) 0 E. none of the above MACRO SUB_ITEM # 1 1 Cannot be converted to a gas without decomposing MACRO SUB_ITEM # 2 2 Will lose or gain electrons with almost equal ease MACRO SUB_ITEM # 3 3 Oxidizes other substances readily MACRO SUB_ITEM # 4 4 Has the highest atomic number MACRO SUB_ITEM # 5 5 Least apt to form compounds MACRO SUB_ITEM # 6 9 The best reducing agent ETS2 OS 3210004 CDAB 45 23729 32 0045001280011290 MACROITEM STEM 2The diagrams below symbolize the electron configurations of the 2atoms of four different elements. The symbol (n) represents the 2nucleus, and number in front of each right parenthesis represents ETS2 OS 2the number of electrons contained in each shell. To answer the 2following questions, mark the letter of the diagram which best 2represents the element described. If none applies, mark space E. A. (n) 2) 1) B. (n) 2) 4) C. (n) 2) 6) D. (n) 2) 8) 0 E. none of the above MACRO SUB_ITEM # 1 1 Oxidizes other substances readily MACRO SUB_ITEM # 2 2 Chemically inactive MACRO SUB_ITEM # 3 3 A very good reducing agent MACRO SUB_ITEM # 4 9 Shows a great tendency to form compounds by sharing electrons 3210005 BEDBD 55 23738 52 0337001980011290 MACROITEM STEM 2The following questions refer to the diagram of the chemical 2reaction shown below. 2 1 2 3 4 2(4P, 5n) 2) 2) + (8p, 8n) 2) 6) ___> (_p, _n) 2) + (_p, _n) 2) 8) 02 Be O Beo MACRO SUB_ITEM # 1 The atomic number of number 1 is A. 2 B. 4 C. 5 D. 6 1 E. 9 MACRO SUB_ITEM # 2 Number 4 in the diagram is A. an atom of the free element B. a compound C. a charged particle D. a gas 2 E. a radical MACRO SUB_ITEM # 3 Number 3 in the diagram A. has the same chemical properties as number 1 B. is sharing electrons with number 4 C. is an oxidizing agent D. is in an ionized state 3 E. has been reduced MACRO SUB_ITEM # 4 ETS2 OS The number of protons and neutrons in number 4 is respectively A. 9p, 8n B. 8p, 8n C. 8p, 9n D. 9p, 9n 4 E. 7p, 9n MACRO SUB_ITEM # 5 Number 1 in the diagram A. acquires a negative valency in chemical reaction B. is an oxidizing agent C. decreases the valence of number 2 in chemical reaction D. is non_metallic in character 9 E. is bi_valent in its compounds 3210006 CACCBDDE 85 23752 31 0338800102371290 MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the item is true of the element of electron structure 2_4 2 B. if the item is true of the element of electron structure 2_8 2 C. if the item is true of the element of electron structure 2_8_2 2 D. if the item is true of the element of electron structure 2_8_7 0 E. if the item is true of none of the above elements MACRO SUB_ITEM # 1 1 The valence of this element is +2. MACRO SUB_ITEM # 2 2 this element is found in all carbohydrates. MACRO SUB_ITEM # 3 3 This element is one of the metals. MACRO SUB_ITEM # 4 4 This element forms an ionic compound with chlorine. MACRO SUB_ITEM # 5 5 This element forms no compounds. MACRO SUB_ITEM # 6 6 This element is the most active of the non_metals listed. MACRO SUB_ITEM # 7 7 The atoms of this element gain electrons easily. MACRO SUB_ITEM # 8 This element belongs in the same group in the periodic table as 9 sodium. ETS2 OS 3210007 CDCDAEC 75 23762 32 0338001903421290 MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the item is true of the element of electron structure 2_4 2 B. if the item is true of the element of electron structure 2_8 2 C. if the item is true of the element of electron structure 2_8_2 ETS2 OS 2 D. if the item is true of the element of electron structure 2_8_7 0 E. if the item is true of none of the above elements MACRO SUB_ITEM # 1 1 The atom of this element has 12 electrons outside its nucleus. MACRO SUB_ITEM # 2 2 This element belongs in the seventh group in the periodic table. MACRO SUB_ITEM # 3 3 The atoms of this element form positive ions. MACRO SUB_ITEM # 4 4 This element forms an ionic compound with sodium. MACRO SUB_ITEM # 5 If we let X represent the symbol of this element, the formula of Its chlorine compound is XCl . 54 4 MACRO SUB_ITEM # 6 If we let Y represent the symbol of this element, the formula of its sodium compound is Na Y. 64 2 MACRO SUB_ITEM # 7 If we let Z represent the symbol of this element, the formula 9 of its oxygen compound is ZO. 3210008 CEDBDACE 85 23775 32 0347033803481290 MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the item is true of an atom of orbital electron structure 2 2,2 2 B. if the item is true of an atom of orbital electron structure 2 2,4 2 C. if the item is true of an atom of orbital electron structure 2 2,8 2 D. if the item is true of an atom of orbital electron structure 2 2,8,7 2 E. if the item is true of an atom of orbital electron structure 0 2,8,8,1 MACRO SUB_ITEM # 1 1 Of the elements listed, it is the most non_reactive. MACRO SUB_ITEM # 2 2 Of the metals listed, it is the most reactive. MACRO SUB_ITEM # 3 3 Of the non_metals listed, it is the most reactive. MACRO SUB_ITEM # 4 4 It forms many compounds by electron_sharing. MACRO SUB_ITEM # 5 5 It will form a negative monatomic ion. MACRO SUB_ITEM # 6 ETS2 OS 6 It will form an ion of the type x++ MACRO SUB_ITEM # 7 7 it most resembles argon in its properties. MACRO SUB_ITEM # 8 9 It is in the same group in the periodic table as sodium. 3210009 CBCDCBE 75 23786 52 1290 MACROITEM STEM 2To answer the following questions, refer to the list below 5 24 2 A. Mg 4 12 5 32 2 B. S 4 16 5 23 2 C. Na 4 11 5 35 2 D. Cl 4 17 5 63 2 E. Cu 04 29 MACRO SUB_ITEM # 1 1 This atom would lose one electron when it combined with a non_metal. MACRO SUB_ITEM # 2 2 This atom would gain two electrons when it united with a metal. MACRO SUB_ITEM # 3 The oxide of this element will form the strongest base when 3 dissolved in water. MACRO SUB_ITEM # 4 Through gain of one electron, an atom of this element forms the 4 negative ion of a strong acid when dissolved in water. MACRO SUB_ITEM # 5 5 This element would be highest in an activity list of metals. MACRO SUB_ITEM # 6 6 Oxygen acids of this element are used in ordinary storage batteries. MACRO SUB_ITEM # 7 9 This element would not replace hydrogen from acids. 3210010 C 15 23796 32 04070604800113 An element with the electronic structure 2, 8, 1 will react with an element the electronic structure of which is 2,8,7 to form a substance which, at room temperature is A. a gas ETS2 OS ETS2 OS 9 B. a liquid C. a crystalline solid D. an acid E. a covalent compound 3210011 D 15 23800 51 03510263800111 If an atom has one or two electrons in the outer electron orbital, it will have the greatest tendency to A. gain enough electrons to form eight B. change some electrons from inner shells to the outer shell C. take electrons from the nucleus and put them in the outer shell D. lose electrons from the outer shell 9 E. gain electrons from the outer orbital into the nucleus ETS2 OS 3210012 D 15 23806 51 01920337800112 In chemical combination, a substance with atomic number 12 should acquire a valence of A. _1 B. +1 C. _2 D. +2 9 E. none of these ETS2 OS 3210013 C 15 23809 32 05670189800111 The rare earths A. are a group of elements whose chemical behavior is very similar because all have eight electrons in the outside shell B. are a series of elements which combine with no other elements C. are a series of elements whose chemical similarity is due to the fact that the two outermost electron shells are identical D. are a group of elements with the same atomic number E. are a number of sparsely distributed miners, whose 9 constituent elements are not yet known ETS2 OS 3210014 E 15 23816 31 8003 Which of the following elements does not belong to the family of elements indicated? A. samarium (Sm) = lanthanide B. curium (Cm) = actinide C. iridium (Ir) = transition metal D. thallium (Tl) = representative element 9 E. iodine (i) = chalcogen 2WVW 3210015 D ETS2 OS 15 23820 51 01920337800112 In chemical combination, a substance with atomic number 12 should acquire a valence of A. _1 B. +1 C. _2 D. +2 9 E. none of these 3210016 D 14 23823 31 80038004 A metal may have an atomic number of A. 9 B. 18 C. 35 9 D. 37 3210017 D 14 23825 32 035103468004 The atom whose outermost shell structure most closely resembles that of neon has the atomic number A. 11 B. 2 C. 16 9 D. 18 2WVW 2 OS 3210018 A 14 23827 32 035100028004 An atom in the fourth series whose outermost structure most closely resembles that of sodium has the atomic number A. 19 B. 20 C. 21 9 D. 22 2 OS 3210019 C 14 23830 31 018903378004 The element having atomic number 9 most closely resembles, in physical and chemical properties, the element having atomic number A. 10 B. 11 C. 17 9 D. 35 2 OS 3210020 A 15 23833 32 07308003 Which one of the following sets of ions or atoms are isoelectronic? (1) B, C, N, O, F, Ne (2) H(+1), He(+2), Li(+3) (3) Ne, Ar, Kr, Xe (4) K(+1), Ca(+2), Sc(+3), Ti(+4) 2WVW (5) Na(+1), Mg(+2), Al(+3), Sr(+2) A. (2) and (4) B. (1) and (3) C. (2), (4), and (5) D. all of them 9 E. none of them 3210021 D 15 23838 31 1 072303389001 95 The following question refers to the periodic table, Figure 1. Which one of the following elements does not have an exactly half_filled electronic subshell in its ground state electronic 3 ________ configuration? A. lithium B. nitrogen C. chromium D. iodine 9 E. antimony 3210022 E 15 23843 32 03628003 Which one of the following classifications, based on the ground state electronic configurations of the elements is incorrect? 3 _________ 5 1 note: (Ne)3s means neon core plus one electron in the 3s orbital 5 1 A. (Ne) 3s ; alkali metal 5 2 3 B. (Ne) 3s 3p ; nonmetal 5 2 10 5 C. (Ar) 4s 3d 4p ; halogen 5 2 1 D. (Kr) 5s 4d ; transition metal 5 2 10 1 9 E. (Kr) 5s 4d 6s ; noble gas 2WVW 2WVW 3210023 A 14 23851 31 140203510337 The chemical properties of an atom are determined by its A. atomic number B. mass number 9 C. number of isotopes D. binding energy 0041 3210024 A 14 23853 31 002809430015 The nonmetal whose chemical behavior is most like that of typical metals is 9 A. hydrogen B. helium C. chlorine D. carbon 0041 3210025 C 14 23855 51 026303400909 The two electrons in a helium atom A. occupy different shells B. occupy different subshells of the same shell C. have different spin quantum numbers 9 D. have the same spin quantum number 3210026 B 14 23858 31 1433 0351 An important factor in determining the chemical behavior of an atom is its A. nuclear structure B. electron structure 9 C. atomic weight D. solubility 3210027 B 14 23861 31 035103500014 In its ability to link atoms together, silicon resembles 9 A. oxygen B. carbon C. sulfur D. iron 0041 0041 0041 3210028 C 15 23863 52 018900710885 Element no. 19 is more active than element no. 11 because element no. 19 A. is a metalloid B. is a metal C. has its valence electron farther from the nucleus D. has its valence electron nearer the nucleus 9 E. forms a larger ion. 0042 3210029 B 15 23867 52 033800991370 Which of the electron configurations for the following neutral atoms would you expect to have the lowest ionization potential? 5 2 2 6 2 A. 1s , 2s , 2p , 3s , 5 2 2 6 1 B. 1s , 2s , 2p , 3s , 5 2 2 6 C. 1s , 2s , 2p , 5 2 2 6 2 6 D. 1s , 2s , 2p , 3s , 3p , 5 2 2 3 9 E. 1s , 2s , 2p . 0042 3210030 E 15 23872 31 09090362 The principle quantum number in period V of the periodic table is: 9 A. 1 B. 2 C. 3 D. 6 E. 5 3210031 D 14 23874 51 036903510263 A transition_element atom (gaseous) whose 4s subshell contains but one electron is: 0042 0043 9 A. Sc (Z = 21) B. Mn (Z = 25) C. Fe (Z = 26) D. Cu (Z = 29). 3210032 B 14 23877 51 00350369 The highest oxidation state exhibited by any of the transition metals is: 9 A. +6 B. +8 C. +10 D. +12. 0043 3210033 B 14 23879 31 003514480002 Sodium is not ordinarily observed in the +2 oxidation state because of its: A. high first ionization potential B. high second oxidation potential 9 C. high ionic radius D. high electronegativity. 0043 3210034 B 14 23882 52 11780730002351 The most stable ion of magnesium is isoelectronic with the A. sodium atom B. most stable ion of fluorine C. argon atom 9 D. magnesium atom. 9000 3210035 A 15 23884 52 02930730002551 The molecule O is isoelectronic with 4 2 5 _ A. formaldehyde, CH O B. cyanide ion, CN 4 2 C. nitrogen, N D. hydrogen peroxide, H O E. methanol, CH OH 94 2 22 3 9000 3210036 A 14 23888 52 01890338082051 The element in period 4, group 5a, has the outer electron configuration 5 2 3 2 4 2 5 2 5 9 A. 4s 4p B. 5s 5p C. 5s 5p D. 4s 4p 9000 3210037 C 14 23891 31 03510338090051 5 2 If an atom has a valence shell electron configuration of ns one may conclude that the element is a A. transition metal B. rare earth 9 C. alkaline earth D. alkali metal 9000 3210038 A 15 23895 31 035404510189 Which of the following elements does not exist in diatomic form? 9 A. argon B. oxygen C. fluorine D. nitrogen E. hydrogen 0018 3210039 D 15 23897 31 140202630338 The chemical properties of an element are very much related to A. the number of neutrons in the atom B. the number of neutrons and protons in the atom C. the number and arrangement of protons in the atom D. the number and arrangement of electrons in the atom 9 E. both C and D. 0040 3210040 C 15 23901 31 026303540338 Which group represents species that contain the same number of electrons? 5 _ + A. F, Ne, Na C. Cl , Ar, K E. both A and B 5 2_ 2_ 2_ 9 B. Mg, Al, Si D. O , S , Se 0040 3210041 A 15 23905 31 088503380025 What are the valence electrons in an element with the following 5 2 2 4 electronic configuration: 1s 2s 2p ? 5 2 4 4 2 2 6 A. 2s 2p B. 2p C. 2p D. 2s 2p 9 E. all are valence electrons. 0040 3210042 C 15 23909 51 036200640003 In the periodic table there occurs immediately after each inert gas one of the chemically very active alkali metals according to the Bohr theory. This sequence is due to A. a sudden increase in the nuclear charge, between the inert gas and the metal. B. a sudden increase in atomic weight, owing to the high energy of the nuclei of metallic elements. C. a sudden increase in the radius of the atom, leaving the outermost electron relatively loosely bound. D. a sudden charge in the quantum nos. E. a sudden increase in the ionization energy, between the 9 inert gas and the metal. 0035 3210043 D 14 23918 32 018902630351 The imaginary element D has one electron in its outer shell. E has 3; G has 5; L has 7. Which atom will show the least metallic 3 _____ character? 9 A. D B. E C. G D. L 0038 3210044 A 14 23922 52 19470339 0058 Which atom does not contain a principal quantum shell of 8 elec_ trons? 9 A. Li B. Na C. Cs D. Fr 3210045 D 14 23924 52 194903390211 The Li compound analogous to Mg N is: 4 32 A. Li N B. Li N C. LiN D. Li N 94 32 23 3 3 3220001 BDAEC 55 23927 52 1 033703779001129095 MACROITEM STEM 2The numbers in the modern periodic table given (Figure 1) are 2the atomic numbers of the elements. After each exercise number 2on the answer sheet, blacken the one lettered space which designates 3 ___ 2the correct answer. (The numbers given in the listed answers are 2the atomic numbers of certain elements.) 2 A. 93, 94, 95, 96 2 B. elements of group Ia 2 C. elements of group VIIa 2 D. 2, 10, 18, 36, and 54 0 E. 11, 12, 13, 14, 15, 16, and 17 MACRO SUB_ITEM # 1 in this sequence of elements, the larger the atomic number, the 1 greater the tendency to lose electrons. MACRO SUB_ITEM # 2 2 All of the elements in this sequence are inert. MACRO SUB_ITEM # 3 All of these elements have been synthesized and none occur in 3 nature. MACRO SUB_ITEM # 4 Electrons in the outermost energy level increase from one to as 4 many elements as are listed in the answer. MACRO SUB_ITEM # 5 In this sequence of elements, the smaller the atomic number, the 9 greater the tendency to gain electrons. 0060 3220002 BEADC 55 23939 52 1 80029001 129095 MACROITEM STEM 2The numbers in the modern periodic table given (Figure 1) are the 2atomic numbers of the elements. After each exercise number on 2the answer sheet, blacken the one lettered space which designates 3 ___ 2the correct answer. (The numbers given in the listed answers are 2the atomic numbers of certain elements.) 2 A. 26, 27, 28, 42, and 78 ETS2 OS ETS2 OS 2 2 2 0 B. elements in groups ia and IIa C. 6, 14, 12, and 20 D. 13, 31, 49, and 81 E. 6, 7, 16, and 17 MACRO SUB_ITEM # 1 1 in general, the hydroxides of these elements are strong bases. MACRO SUB_ITEM # 2 These elements form the negative ions, or part of the negative 2 ions, of certain acids widely used in industry. MACRO SUB_ITEM # 3 These elements are some of the ductile heavy metals of industrial 3 importance. MACRO SUB_ITEM # 4 In these elements the number of electron orbits are respectively, 4 3, 4, 5, and 6. MACRO SUB_ITEM # 5 one of these elements is a constituent of all plant and animal 9 tissue while the others are major constituents of various rocks. 3220003 A 15 23952 52 00670189800111 Which of the following is most important in predicting the chemical properties of a given element? A. the number of protons in the nucleus B. the number of neutrons in the nucleus C. the sum of the protons and neutrons in the nucleus D. the charge on its ion 9 E. the number of electron energy levels in the atom ETS2 OS 3220004 E 15 23957 52 03490337800112 Beryllium has an atomic number of 4. Its valence should be A. 3 B. _2 C. 1 D. _1 9 E. none of these ETS2 OS 3220005 B 15 23959 31 00200014800111 Both positive and negative valences can be acquired by A. neon, atomic number 10 B. carbon, atomic number 6 C. oxygen, atomic number 8 D. sodium, atomic number 11 9 E. magnesium, atomic number 12 ETS2 OS 3220006 A Silicon 15 23962 51 03500578 ETS2 OS 9 A. has four valence electrons in the atom B. forms long chains by linking silicon atom to silicon atom, as does carbon C. forms a basic oxide D. is found in the free condition in nature E. when fused, forms a glass of high transparency 3220007 B 15 23966 31 072207238003 Which one of the following elements does not belong to the 3 ___ family of elements indicated? A. samarium (Sm)__lanthanide B. curium (Cm)__alkaline earth metal C. iridium (Ir)__transition metal D. thallium (Tl)__representative element 9 E. iodine (i)__halogen 2WVW 3220008 A 15 23971 31 8003 Which one of the following elements would you expect to have the greatest affinity for an electron? A. bromine B. gallium C. arsenic D. selenium 9 E. potassium 2WVW 3220009 E 15 23974 31 8003 Which one of the following elements would you expect to have the least affinity for an electron? 3_____ A. bromine B. gallium C. arsenic D. selenium 9 E. potassium 2WVW 3220010 DA 25 23977 51 8003 90 MACROITEM STEM 2To answer the following questions, use the key below. 2 A. S(_2) 2 B. Mn(+7) C. Ti(+4) D. P(_3) 02 E. Sc(+3) MACRO SUB_ITEM # 1 Which one of the ions would you expect to have the largest atomic 2WVW 3 1 radius? MACRO SUB_ITEM # 2 9 Which would have the second largest? _______ 3220011 B 14 23981 32 000404388004 The halogen which is a liquid at room temperature A. iodine B. bromine C. fluorine 9 D. chorine 2 OS 3220012 B 14 23983 31 018903398004 Of all the common elements, the most active reducing agent is A. sodium B. lithium C. fluorine 9 D. oxygen 2 OS 3220013 B 14 23985 32 006601898004 The least stable compounds are usually A. combinations of the most active elements B. combinations of the least active elements C. the products of exothermic reactions 9 D. the ones most abundant in the earth"s crust 2 OS 3220014 B 15 23989 31 00020015 Which of the following would be classified as a metal? 9 A. nitrogen B. sodium C. phosphorus D. neon E. fluorine 0018 3220015 E 15 45410 51 All of the following are periodic functions of atomic number EXCEPT: A. density D. boiling point B. electronegativity E. number of electrons in the neutral atom 9 C. atomic radius 3221001 C 15 23991 52 1 0062002890011195 The following question refers to the periodic table, Figure 1. If a diagonal line is drawn from the upper left hand corner to the lower right in the periodic table, elements will be found along the line A. of the same valence B. which in oxide form produce only acids in solution C. which have both metallic and non_metallic properties D. which will include the most active metal 9 E. with similar properties ETS2 OS 3221002 BAECCDC 75 23997 31 1 002800619001129095 MACROITEM STEM 2The following items refer to the horizontal series in the periodic 2table (Figure 1). Select from the key the most appropriate 2description for each item. 2 Key 2 A. This member is a typical non_metal. 2 B. This member is a typical base former and reducing agent. 2 C. Decrease in metallic character 2 D. Increase in metallic character 0 E. Not descriptive of any of the above MACRO SUB_ITEM # 1 1 The element in series 2, group 1 MACRO SUB_ITEM # 2 2 The element in series 1, group 7 MACRO SUB_ITEM # 3 3 The element in series 2, group 4 MACRO SUB_ITEM # 4 4 Proceeding from Bi to C vertically MACRO SUB_ITEM # 5 5 Proceeding from K to Ti MACRO SUB_ITEM # 6 6 Proceeding from S to Al MACRO SUB_ITEM # 7 9 Proceeding from P to Cl ETS2 OS 3221003 ECABEDD 75 24006 31 1 0063001500071290 MACROITEM STEM 2The following items concern elements in the periodic table 2(Figure 1). Select from the key the most appropriate response for 2each item. 2 Key 2 A. Outer shell contains eight key electrons 2 B. A metal which will float on water 2 C. An oxidizing agent 2 D. A high specific gravity 0 E. Shares electrons and combines with itself MACRO SUB_ITEM # 1 1 Silicon MACRO SUB_ITEM # 2 2 Iodine MACRO SUB_ITEM # 3 3 Neon MACRO SUB_ITEM # 4 4 Lithium ETS2 OS MACRO SUB_ITEM # 5 5 Carbon MACRO SUB_ITEM # 6 6 Platinum MACRO SUB_ITEM # 7 9 Manganese 3221004 ECDC 45 24012 51 1 037503769001119095 MACROITEM STEM 2The following refer to the periodic table (Figure 1). For each 2question select the correct response. 2 A. Left to right 2 B. Right to left 2 C. Top to bottom 2 D. Bottom to top 0 E. Two of these MACRO SUB_ITEM # 1 1 Chemical activity decreases but valence remains constant. MACRO SUB_ITEM # 2 2 Metallic character increases but valence remains constant MACRO SUB_ITEM # 3 3 Oxidizing power increases but valence remains constant MACRO SUB_ITEM # 4 9 The number of electronic shells increases 3221005 ABBBABDC 84 24018 31 0015002880011290 MACROITEM STEM 2After each item number on the answer sheet, blacken space 2 A. if the item is true of metals 2 B. if the item is true of non_metals 2 C. if the item is true of both metals and non_metals 0 D. if the item is true of neither metals nor non_metals MACRO SUB_ITEM # 1 1 Are good conductors of heat and electricity MACRO SUB_ITEM # 2 2 Combine readily with elements of group I of the periodic table MACRO SUB_ITEM # 3 3 Many are gases or low_melting solids MACRO SUB_ITEM # 4 4 The halogens are examples MACRO SUB_ITEM # 5 5 Their oxides in water form basic solutions MACRO SUB_ITEM # 6 6 Are frequently good electron acceptors or oxidizing agents MACRO SUB_ITEM # 7 7 Are chemically inert and form no compounds ETS2 OS ETS2 OS MACRO SUB_ITEM # 8 9 Combine chemically with oxygen to form oxides 3221006 CABDED 65 24027 52 1 019603819003129095 MACROITEM STEM 2Figure 3 represents, in skeleton form, the periodic table. 2Certain columns of the table are labeled A, B, C, and D. The 2letter E designates the location of elements of atomic numbers 288_96. After the number on the answer sheet corresponding to that 2of each statement, blacken the one lettered space indicating the 0 location in the table to which the statement correctly refers. MACRO SUB_ITEM # 1 Elements near the top of this column share electrons when forming 1 compounds. MACRO SUB_ITEM # 2 With one exception, the outer shells of the atoms of these elements 2 always contain eight electrons. MACRO SUB_ITEM # 3 3 All of the elements of this column are classified as metals. MACRO SUB_ITEM # 4 The great chemical activity of the element at the top of this column when reacting with metals is attributed to its relatively 4 small atomic radius. MACRO SUB_ITEM # 5 Most of the naturally occuring radioactive elements are found in 5 this location. MACRO SUB_ITEM # 6 Near the top of this column are elements which gain electrons most 9 readily. ETS2 OS 3221007 ACDBAA 65 24040 52 1 000403829002129095 MACROITEM STEM 2Figure 2 represents an outline of the periodic table. After the 2item number on the answer sheet, blacken the one lettered space 3 ___ 2which designates the position in the table to which the item 0 correctly refers. MACRO SUB_ITEM # 1 An element from this column is used in dirigibles because of its 1 lightness and non_inflammability. MACRO SUB_ITEM # 2 An element of this column is found in all organic compounds, while another element in the same column is found in combination in 2 numerous rocks. MACRO SUB_ITEM # 3 3 The halogens are located in this column. ETS2 OS MACRO SUB_ITEM # 4 The elements near the bottom of this column lose electrons most 4 readily. MACRO SUB_ITEM # 5 One of the elements in this column was discovered to be present in 5 the atmosphere of the sun, before it was discovered on earth. MACRO SUB_ITEM # 6 An element whose single outer electron is at the greatest distance from the nucleus of the atom is located at the bottom of this 9 column. 3221008 BBEDADC 75 24052 52 80018002 1290 MACROITEM STEM 2The following questions refer to part of the periodic table 2 series 2 0 I II III IV V VI VII VIII 3________________________________________________ 21 H 22 He Li Be B C N O F 23 Ne Na Mg Al Si P S Cl 24 Ar K Ca Sc Ti V Cr Mn Fe CO Ni 2for each question select from the key the group in which the 2element lies. 2 A. Group I 2 B. Group II 2 C. Group III 2 D. Group IV 0 E. Group V MACRO SUB_ITEM # 1 1 The carbonate of this element is found in marine fossils. MACRO SUB_ITEM # 2 2 An element forming compounds by gaining 2 electrons. MACRO SUB_ITEM # 3 3 The most active non_metal listed. MACRO SUB_ITEM # 4 4 The fused oxide of this element transmits ultra_violet. MACRO SUB_ITEM # 5 5 An element forming compounds by losing 1 electron. MACRO SUB_ITEM # 6 An element usually combustible but not in its purest form. 63 ___ MACRO SUB_ITEM # 7 9 An oxide of this element is a well known laboratory catalyst. 3221009 ABBCABDC 84 24064 MACROITEM STEM 32 0015002880011190 ETS2 OS ETS2 OS 2The following questions are to be answered according to the key 2below. 2 A. The item is true for metals. 2 B. The item is true for non_metals. 2 C. The item is true for both metals and non_metals. 0 D. The item is true for neither metals nor non_metals. MACRO SUB_ITEM # 1 1 Good conductors of heat and electricity MACRO SUB_ITEM # 2 2 Combine readily with elements of group I of the periodic table. MACRO SUB_ITEM # 3 3 Many are gases or low_melting solids. MACRO SUB_ITEM # 4 4 Many have variable valence. MACRO SUB_ITEM # 5 5 Their oxides in water form basic solutions. MACRO SUB_ITEM # 6 6 Frequently good electron acceptors or oxidizing agents. MACRO SUB_ITEM # 7 7 Chemically inert and form NO compounds. MACRO SUB_ITEM # 8 9 Combine chemically with oxygen to form oxides. 3221010 C 15 24073 31 00150028800111 Which of the following statements states correctly a characteristic distinction between metals and nonmetals? A. Metals are high in melting point and density whereas nonmetals are not. B. Nonmetals are either gases or solids whereas all metals are liquids above their melting points C. Nonmetals usually exert a stronger attraction for electrons than do metals D. Metals are fewer in number than nonmetals 9 E. Nonmetals form covalent bonds whereas metals form ionic bonds ETS2 OS 3221011 C 15 24080 32 05590015800111 During chemical combinations metallic atoms always A. become larger B. gain electrons C. lose electrons D. lose kinetic energy 9 E. gain kinetic energy ETS2 OS 3221012 D 14 24083 32 033900048004 Lithium readily reacts with all of the following except A. oxygen 2 OS 9 B. water C. the halogens D. helium 3221013 C 14 24085 32 018900028004 The element which unites most vigorously with sodium is A. bromine B. chlorine C. fluorine 9 D. iodine 2 OS 3221014 C 15 24087 31 033809171362 What common feature characterizes the electronic configuration of elements 21, 27, 40, and 43? A. They all have only one electron in a subshell. B. They all have a filled 5s subshell. C. They all have a partially filled d subshell. D. They all have a partially filled p subshell. 9 E. Both B and C. 0040 3221015 E 15 24092 31 019201040852 Which of the following substances is a good electrical conductor? A. sulfur B. diamond C. black phosphorus 9 D. ozone E. graphite 0034 3221016 D 14 24094 52 19470845 Which oxide is amphoteric? A. CO B. SO C. CaO D. ZnO 94 2 2 3222001 A 15 24096 32 80018002 13 Judging by the implications of the periodic table, one can validly infer that there might exist a compound with molecular composition A. MgCl 4 2 B. HeO 4 2 C. Al Sn 4 3 2 D. CO 4 5 9 E. CaF 3222002 D 15 24100 51 80010253003211 Aluminum A. in a finely powdered state is a powerful oxidizing agent 0058 ETS2 OS ETS2 OS 9 B. dissolves in mineral acids but not in alkaline solution C. was one of the first metals to be produced on a large scale D. is a better electrical conductor than copper, weight for weight E. is used for the casing of incendiary bombs 3222003 ECBAD 55 24105 52 1 9001 129095 MACROITEM STEM 2The numbers in the modern periodic table given (Figure 1) are the 2atomic numbers of the elements. After each exercise number on the 2answer sheet, blacken the one lettered space which designates the 3 ___ 2correct answer. (The numbers given in the listed answers are the 2atomic numbers of certain elements.) 2 A. 6, 14, 12, and 20. 2 B. 6, 7, 16, and 17 2 C. 9, 17, 35, 53, and 85 2 D. elements in the b sub_groups 0 E. elements in groups Ia and IIa MACRO SUB_ITEM # 1 When These elements form ions, through loss of one or more electrons, the ions have structures similar to the atoms of the 1 inert gases. MACRO SUB_ITEM # 2 2 These elements are often referred to as the "halogens." MACRO SUB_ITEM # 3 these elements form the negative ions, or part of the negative 3 ions, of certain common acids. MACRO SUB_ITEM # 4 One of these elements is a constituent of all plant and animal tissue while the other elements are major constituents of various 4 rocks. MACRO SUB_ITEM # 5 Some of these metallic elements are used in producing important 9 steel alloys. ETS2 OS 3222004 E 15 24118 31 00158001026311 During chemical combinations, metallic atoms always A. undergo nuclear changes B. gain electrons C. lose kinetic energy D. become larger 9 E. lose electrons ETS2 OS 3222005 A 15 24121 31 00200189800111 An element with a positive valence of 2 is ETS2 OS 3 9 ________ A. calcium B. silver C. aluminum D. suphur E. oxygen 3222006 CEADB 55 24123 52 1 026303789001129095 MACROITEM STEM 2The numbers in the modern periodic table given (Figure 1) are the 2atomic numbers of the elements. After each exercise number on the answer sheet, blacken the one lettered space which designates the 3 ___ 2correct answer. (The numbers given in the listed answers are the 2atomic numbers of certain elements.) 2 A. 93, 94, 95, and 96 2 B. elements in group VIIa 2 C. 3, 4, 5, 6, 7, 8, and 9 2 D. elements in group Ia 0 E. elements in group O MACRO SUB_ITEM # 1 1 Electrons in the second energy level increase from one to seven. MACRO SUB_ITEM # 2 All of these elements with one exception contain 8 electrons in 2 their outermost energy levels. MACRO SUB_ITEM # 3 All of these elements have been synthesized rather than found in 3 natural sources. MACRO SUB_ITEM # 4 In this sequence of elements, the larger the atomic number the 3 ______ 4 greater the tendency to lose electrons. MACRO SUB_ITEM # 5 In this sequence of elements, the smaller the atomic number the 3 _______ 9 greater the tendency to gain electrons. ETS2 OS 3222007 DBEAC 55 24137 52 1 037900289001129095 MACROITEM STEM 2The numbers in the modern periodic table given (Figure 1) are the 2atomic numbers of the elements. After each exercise number on the 2answer sheet, blacken the one lettered space shich designates 3 ___ 2the correct answer. (The numbers given in the listed answers are 2the atomic numbers of certain elements.) 2 A. 88, 89, 90, 91, and 92 ETS2 OS 2 2 2 0 B. 3, 11, 12, 19, 20, and 56 C. elements in group IIa D. 6, 7, 8, 14, 16, 18, and 53 E. 26, 27, 28, 42, and 78 MACRO SUB_ITEM # 1 1 These elements are some of the nonmetals. MACRO SUB_ITEM # 2 These elements, from different groups, are some of the light 2 metals. MACRO SUB_ITEM # 3 3 These elements are some of the ductile heavy metals. MACRO SUB_ITEM # 4 4 These are naturally radioactive elements. MACRO SUB_ITEM # 5 The numbers of energy levels of these elements are successively 3 _____________ 9 2, 3, 4, 5, 6, and 7 3222008 B 14 24148 31 80048003 Which physical property is common to most metals? A. Low melting point B. Luster C. Reactions with acids 9 D. Yellow color 2WVW 3222009 D 14 24150 31 001501968004 A metal which liberates hydrogen from water so vigorously that the hydrogen ignites is A. calcium B. magnesium C. sodium 9 D. potassium 2 OS 3222010 A 14 24153 31 019600568004 Hydrogen may be produced from sulfuric acid by A. replacement with a metal B. replacement with a nonmetal C. evaporation 9 D. catalysis 2 OS 3222011 B 14 24156 31 007304328004 The member of the calcium family with the highest melting and boiling point is A. calcium B. beryllium C. magnesium 2 OS 9 D. barium 3222012 B 14 24158 31 001503448004 A metal which is generally stored under kerosene is A. calcium B. potassium C. barium 9 D. aluminum 2 OS 3222013 A 14 24160 31 000800198004 Hard water is due to the presence of any of the following ions except A. sodium B. calcium C. magnesium 9 D. iron 2 OS 3222014 D 14 24162 31 046304078004 In a chemical reaction, metals generally A. act as oxidizing agents B. share electrons C. donate protons 9 D. acquire positive oxidation numbers 2 OS 3222015 B 14 24165 31 144500670015 An important characteristic property of metals is A. their hardness B. their ability to conduct electricity readily C. their ability to form oxides 9 D. the stability of their compounds 0041 3222016 B 14 24168 31 006213171367 The metallic luster exhibited by sodium is explained by the presence of: 5 + A. Na ions B. conduction electrons 9 C. free protons D. a body_centered cubic lattice. 0043 3222017 D 14 24171 31 027003620723 The 19th element has chemical properties like which element? 9 A. 10th B. 18th C. 15th D. 11th. 3222020 E 15 24173 32 019213170315 Substances that typically have a particular luster, are good conductors of electricity, and can be melted are called A. elements B. isotopes 0026 0020 9 C. diatomic molecules D. nonmetals E. metals 3222021 C 14 24176 31 00150263 A metal A. usually has more protons than neutrons B. combines readily with hydrogen C. readily gives up electrons 9 D. readily accepts electrons 3222022 E 15 24179 32 0015 Which is the most strongly metallic? A. C B. Si C. Ge D. Sn E. Pb 94 6 14 32 50 82 3222023 C 15 24181 32 01890015 Which of the following elements would most likely be a metal? 9 A. Si B. P C. Be D. O E. Cl 0019 0019 0035 3222024 A 15 24183 31 035101890263 The atoms of which of the following elements would you expect to lose electrons most readily? 9 A. Al B. B C. C D. Si E. N 0035 3222025 C 15 24185 31 010413670172 In general, good conductors usually exhibit A. high melting and boiling points and low densities B. high densities and low melting and boiling points C. high melting and boiling points and high densities D. high densities but no correlation in melting and boiling points 9 E. NO correlation in density, melting, or boiling points 0034 3223001 E 15 24190 51 01890263800111 Elements which take on electrons are also classified as A. oxides B. halogens C. metals D. hydrates 9 E. non_metals 3223002 CAEBA 55 24192 31 0401004980011190 MACROITEM STEM 2To answer the following questions, select from the key the most 2appropriate response. ETS2 OS ETS2 OS 2 2 2 2 0 A. Hydrogen B. Oxygen C. Nitrogen D. Chlorine E. None of these MACRO SUB_ITEM # 1 An element present in proteins which distinguishes proteins from 1 carbohydrates MACRO SUB_ITEM # 2 2 An element present in the most important fuels MACRO SUB_ITEM # 3 3 An element which is always inert MACRO SUB_ITEM # 4 4 An element which is a constituent of quartz MACRO SUB_ITEM # 5 An element which, from its presence in other substances, is 9 generally a ready source of protons 3223003 A 14 24199 31 80048003 In the periodic table, most of the nonmetals are found in the A. upper right_hand side B. upper left_hand side C. lower right_hand side 9 D. lower left_hand side 3223004 B 14 24202 31 A solid nonmetal is usually A. malleable B. brittle C. a good electical conductor 9 D. ductile 002807938004 3223005 B 14 24204 32 001804048004 A colorless salt solution turns brown upon the addition of chlorine water, this solution probably contains A. calcium choride B. sodium iodide C. carbon tetrachloride 9 D. potassium fluoride 3223006 A 14 24207 31 002800198004 Nonmetals tend to form A. negative ions B. positive ions C. bases 9 D. alloys 2WVW 2 OS 2 OS 2 OS 3223007 E 15 24209 32 035108241178 When an atom of an electronegative element becomes an ion in a chemical reaction: A. it loses electron(s) B. it is oxidized C. the ionic radius becomes smaller than the atomic radius 9 D. it serves as a reducing agent E. none of these. 3223008 E 15 24213 32 01890263 Which of the following elements would tend most to take on electrons? 9 A. Li B. Be C. C D. S E. O 0042 0035 3230001 EDABBA 65 24215 51 1 80029001 129095 MACROITEM STEM 2The following items refer to the periodic table (Figure 1). Select 2from the key the principle which applies to each item. 2 A. A group forming no compounds because their electron grouping 2 is very stable 2 B. A group having two outer electrons 2 C. A regular increase in the number of valence electrons to a 2 maximum in this group 2 D. All the elements in this group form compounds by losing one 2 electron per atom 0 E. None of the above apply to this group. MACRO SUB_ITEM # 1 1 Group 4 MACRO SUB_ITEM # 2 2 Group 1 MACRO SUB_ITEM # 3 3 Group 0 MACRO SUB_ITEM # 4 4 Group 8 MACRO SUB_ITEM # 5 5 Group 2 MACRO SUB_ITEM # 6 9 Group 7 ETS2 OS 3230002 EAEA 45 24223 31 0015006480011290 MACROITEM STEM 2The following items are based on a short periodic table which lists 2symbol of each element and its atomic number. 2 3 4 5 6 7 8 9 10 2 Li Be B C N O F Ne 3________________________________________ 2 11 12 13 14 15 16 17 18 0 Na Mg Al Si P S Cl Ar ETS2 OS 1 2 3 9 MACRO SUB_ITEM # 1 Which of the following elements would tend most to take on electrons? A. Li B. Be C. C D. S E. O MACRO SUB_ITEM # 2 Which of the following elements would most likely be a metal? A. Mg B. O C. P D. Be E. Cl MACRO SUB_ITEM # 3 Which of the following is an inert gas? A. Mg B. Si C. C D. P E. Ar MACRO SUB_ITEM # 4 The atoms of which of the following elements would you expect to lose electrons most readily? A. Al B. B C. C D. Si E. N 3230003 D 15 24234 72 02240058800112 The most probable formula for a binary solid compound of Mg and N is A. MgN B. Mg N C. MgN D. Mg N E. Mg N 94 2 2 22 23 OS90 3230004 CADEB 55 24248 52 1 002800199002129095 MACROITEM STEM 2Figure 2 represents an outline of the periodic table. After the 2item number on the answer sheet, blacken the one lettered space 3 ___ 2which designates the position in the table to which the item 0 correctly refers. MACRO SUB_ITEM # 1 1 The element in this position is most likely a non_metal. MACRO SUB_ITEM # 2 ETS2 OS The positive ion of the element in this position has the electronic 3 ___ 2 structure or configuration 2_8_8. MACRO SUB_ITEM # 3 One would expect to find in this position the element which forms 3 most fuels. MACRO SUB_ITEM # 4 The element in this position, and others in the same group, have high melting points, tensile strength, and density, and are 4 malleable and ductile. MACRO SUB_ITEM # 5 The element in this position floats in water and combines rapidly 9 with it forming a strong base. 3230005 DCADEB 65 24258 52 1 80019002 129095 MACROITEM STEM 2Figure 2 represents an outline of the periodic table. After the 2item number on the answer sheet, blacken the one lettered space 3 ___ 2which designates the position in the table to which the item 0 correctly refers. MACRO SUB_ITEM # 1 Just below the element in this position is the element which occurs 1 in most rocks. MACRO SUB_ITEM # 2 The hydrogen compounds of the element in this position, and of the elements above and below it, when dissolved in water have strong 2 acidic properties. MACRO SUB_ITEM # 3 Elements in the group containing this element form positive ions 3 which combine with chlorine ions, ion for ion. MACRO SUB_ITEM # 4 The element in this position forms compounds which, as a rule, do 4 not conduct an electric current in aqueous solution. MACRO SUB_ITEM # 5 One of the elements in the group which includes this element 5 is the most widely used metal. MACRO SUB_ITEM # 6 The positive ion of the element in this position has the electronic 9 structure or configuration 2_8. 3230006 B 15 24270 32 04040028800111 Chlorine is a more active non_metal than iodine. This is probably because A. chlorine loses electrons more readily than does iodine. B. the incomplete shell of electrons in the chlorine atom ETS2 OS ETS2 OS 9 is closer to the nucleus than is the one in the iodine atom. C. iodine adds electrons more readily than does chlorine. D. the negative valence electron of the chlorine atom is farther away from the nucleus than is the one in the iodine atom. E. chlorine is an oxidizing agent. 3230007 D 15 24277 32 060206038001 Al O and CCl are the correct formulae of the oxide of aluminum 4 23 4 and the chloride of carbon. The formula of the compound aluminum carbide is therefore A. Al C 4 42 B. Al C 4 34 C. AlC D. Al C 4 43 9 E. none of these formulae ETS2 OS 3230008 A 15 24281 31 Which one of these is inert? A. argon B. nitrogen C. hydrogen D. oxygen 9 E. two of the above 03770359800111 ETS2 OS 3230009 E 15 24283 31 01130064800111 Which one of the following is an inert gas? A. ammonia B. carbon monoxide C. hydrogen D. carbon dioxide 9 E. helium ETS2 OS 3230010 D 15 24285 31 01130181800111 A gas commonly used in electric light bulbs to retard vaporization of the filament is A. neon B. helium C. oxygen D. argon 9 E. krypton ETS2 OS 3230011 D 15 24288 31 02930340800111 Which one of these cannot form molecules through combination 3 ______ of atoms? A. oxygen B. nitrogen C. hydrogen D. helium 9 E. two of the above ETS2 OS 3230012 A 15 24291 31 04030004800111 Iodine may be characterized as A. a halogen B. an element behaving chemically similarly to carbon C. an inert gas D. a radioactive element 9 E. an active metal ETS2 OS 3230013 B 15 24294 32 02240037 What is the correct formula for a compound formed from the elements potassium and phosphorus? A. P K B. K P C. KP D. K P E. none of these 94 3 3 2 0018 3230014 B 15 24297 52 02240037 The correct formula for a covalent compound between fluorine and oxygen is A. OF B. OF C. O F D. OF E. none of these 94 2 2 3 0018 3230015 C 14 24300 31 060407220794 Elements in the same vertical group of the periodic table generally A. have the same atomic weight B. have the same atomic numbers C. react with the same chemicals to give products with similarly proportioned formulas 9 D. have no relationships between each other. 0026 3230016 A 15 24304 31 140201890794 Elements in the same group A. have similar chemical properties B. are called isotopes C. have consecutive atomic numbers D. constitute a period of elements 9 E. have similar physical properties 0040 3230017 A 14 24307 52 1945 Most basic: A. LiOH B. Be(OH) C. B(OH) 94 2 3 0056 D. Co(OH) 2 3231001 C 15 24309 31 00150189800112 A chemically active metal is an element whose atoms A. gain a relatively large amount of energy in losing electrons B. gain a relatively small amount of energy in losing electrons C. lose a relatively large amount of energy in losing electrons D. lose a relatively small amount of energy in losing electrons 9 E. can lose electrons without undergoing an energy change ETS2 OS 3231002 C 15 24314 52 03380003800112 The electron structure of the alkali metals indicates that A. they should be very ready to take on a single electron for each atom B. in general, they should tend to form covalent compounds C. they should not be found in the free condition in nature D. lithium should be the most active of them 9 E. all of them should be excellent oxidizing agents ETS2 OS 3231003 A 15 24319 52 00030058800112 The alkali metals of group Ia, lithium, sodium, potassium, rubidium, and cesium are the most active metals. Cesium is the most active in the list because as one proceeds from lithium to cesium A. the atomic radius increases B. the number of valence electrons increases C. the metallic properties become less pronounced D. the valence increases 9 E. the atomic weight decreases ETS2 OS 3231004 D 15 24325 51 03270373800111 Which one of these is not true concerning the periodic table? 3 ___ A. The series vary in the number of elements each contains. B. Except for inert elements those elements at the left tend to lend electrons. C. Except for inert elements those elements at the left are reducing agents. D. Elements in group IIa are more active than those in ia. E. With increase in atomic number, chemical activity of the 9 active metals increases. ETS2 OS 3231005 D ETS2 OS 15 24332 52 00580375800111 In the family of the most active metals in the periodic table, activity increases A. with increase in valence B. as one reads from left to right C. as the atomic number decreases D. as one proceeds from top to bottom 9 E. as the number of electron rings decrease 3231006 E 15 24336 52 03720071800112 Three elements belonging to group Ia have atomic numbers 11, 19, 55. the one true statement about this group is A. the elements are inert B. the activity is unpredictable C. number eleven is the most active D. number nineteen is more active than number fifty_five 9 E. number fifty_five is the most active ETS2 OS 3231007 A 14 24341 31 80018003 Sodium and potassium A. are reducing agents B. are oxidizing agents C. have complete outer rings 9 D. form ions with a negative charge 2WVW 3231008 B 14 24343 31 80038004 Which metal is often stored under kerosene? A. copper B. potassium C. silver 9 D. zinc 2WVW 3231009 B 14 24345 31 Oxides of the very active metals are A. acid anhydrides B. basic anhydrides C. hydrates 9 D. inactive 2WVW 3231010 A 14 24347 31 000200088004 When sodium reacts with water, one sodium atom replaces A. one hydrogen atom B. two hydrogen atoms C. one oxygen atom 9 D. two oxygen atoms 2 OS 3231011 C 2 OS 14 24350 31 001901898004 The ions of the elements of the sodium family have all the following properties except A. high stability B. oxidation number of plus one C. formation of compounds by covalence D. electron configuration similar to that of the proceeding 9 inert gas 3231012 A 14 24354 31 000303510263 An alkali metal atom A. has one electron in its outer shell B. has two electrons in its outer shell C. has a filled outer shell 9 D. lacks one electron of having a filled outer shell 0041 3231013 D 14 24357 31 000403510263 A halogen atom A. has one electron in its outer shell B. has two electrons in its outer shell C. has a filled outer shell 9 D. lacks one electron of having a filled outer shell 0041 3231014 C 14 24360 31 006403510346 An inert gas atom A. has one electron in its outer shell B. has two electrons in its outer shell C. has a filled outer shell 9 D. lacks one electron of having a filled outer shell 0041 3231015 A 14 24363 31 035102630015 An atom that loses its outer electron or electrons readily is A. an active metal B. an active nonmetal 9 C. an inactive metal D. an inactive nonmetal 0041 3231016 B 14 24366 31 00030020 The alkali metals all have valences of 9 A. +2 B. +1 C. 0 D. _1 3231017 B 15 24367 51 018900150900 Which one of the following elements does not belong to the family of elements indicated? A. samarium (Sm)__lanthanide B. curium (Cm)__alkaline earth metal C. iridium (Ir)__transition metal D. thallium (Tl)__representative element 9 E. iodine (I)__halogen 0041 0042 3231018 A 15 24371 52 036201891370 Where on the periodic table would you find an element Q with a second ionization potential that was very high and with a first that was very low? Q forms salts that give vivid flame tests, 5 _ and its ions have a complete set of e in "d" orbitals (but no "f" electrons). A. anywhere in the Ia family B. somewhere in the IIa family C. somewhere in period 4 D. somewhere in the transition elements 9 E. Q is either rubidium or cesium. 0042 3231019 D 14 24378 51 026316210087 Electrons behave like solute anions in a dilute solution of which of the following in liquid ammonia? A. Cl B. Pt C. NH Cl D. Na 94 2 4 0043 3231021 B 14 24381 31 01890035000251 Of the following elements, which exhibits just one oxidation state other than zero? 9 A. sulfur B. sodium C. lead D. chlorine. 9000 3231022 E 15 24383 32 000304070008 Alkali metals react with water to give A. an acid solution B. a precipitate of NaOH C. sodium oxide and hydrogen D. sodium hydroxide and hydrogen 9 E. none of these 0020 3231023 D 15 24386 31 006700031369 Which of the following properties are characteristic of alkali metals? A. react with water B. are ductile C. have a silvery luster when cut D. all of the above 9 E. none of the above 0020 3231025 A 15 24389 52 04850977 ________ in the presence of a catalyst yields MNH + H 4 2 2 A. M + NH B. M + H + N C. M + H + N D. M + N + H 0020 4 3 2 9 E. none of the above 2 2 3231026 C 15 24393 31 117806041375 5 + The rubidium ion, Rb , has an electronic structure similar to 9 A. sodium B. helium C. krypton D. neon E. argon 0020 3231027 D 15 24395 32 137113700344 Which of the following would be expected to have the lowest first ionization potential? 9 A. Li B. Be C. Na D. K E. Ca 0019 3231028 A 15 24397 32 140300210339 Which of the following has the highest oxidation potential? 9 A. Li B. Na C. K D. Rb E. Ca 0019 3231029 D 15 24399 32 007113980008 Which of the following is not active enough to displace H from 4 2 water? A. K B. Mg C. Al D. Ag E. more than one correct 9 0019 3231030 A 15 24402 32 142101590180 Which of the following has the largest energy of hydration? 5 + + + + + 9 A. Li B. Na C. K D. Rb E. Cs 0019 3231031 A 15 24404 52 000100030021 The best reducing agent of the alkali metals as indicated by oxidation potentials is 9 A. Li B. Na C. K D. Rb E. Cs 0019 3231032 E 15 24406 52 000109000021 The best reducing agent of the alkaline earth metals as indicated by oxidation potentials is 9 A. Be B. Ca C. Sr D. Ba E. Ra 0019 3231033 A 14 24408 52 117801800159 The ion with the highest hydration energy is 5 + +2 + +2 9 A. Li B. Be C. Cs D. Ra 0019 3231034 A 15 24410 31 037203470781 Among the elements of group Ia, which orbital provides the 0040 electron most used in bonding? A. s B. d C. p D. f 9 E. no correct response is given. 3231035 C 15 24413 31 037402900885 In the series of active metals (Na, K, etc.) cesium is the most active. The best explanation of this is that A. it has a greater attractive force on valence electrons than the others. B. its atomic number is greater. C. its valence electron has an orbit with a greater radius than the others. D. its incomplete shell or energy level is closer to the nucleus. 9 E. it has more valence electrons than the others. 0035 3231036 D 15 24419 32 006901890337 When the atomic volume of the elements is plotted as a function of the atomic number of the elements, a series of maxima and minima appear on the graph. If the atomic volume of sodium represents one of the maxima, it could be predicted that one of the other maxima would be represented by the atomic volume of the element A. magnesium. B. neon. C. chlorine. D. potassium. 9 E. plutonium. 0035 3231037 A 15 24425 31 031911780185 Which of the following is a correct comparison of sodium ion with potassium ion? A. Both ions have the same net charge B. Both ions have the same charge on the nucleus C. Both ions have the same mass D. Both ions will react with water to release hydrogen and form a strong base 9 E. Potassium ion is easier to reduce than sodium ion 0038 3232002 D 15 24430 32 02630404800111 Which one of the following atoms receives one electron in chemical combination? 9 A. P B. Ne C. Li D. Cl E. O ETS2 OS 3232003 D 15 24432 31 The most active non_metal is A. oxygen B. chlorine C. manganese ETS2 OS 00280560800111 9 D. fluorine E. iodine 3232004 D 14 24434 31 80048003 Nitrogen combines directly with the more active metals to produce A. nitrates B. nitrites C. hydrides 9 D. nitrides 2WVW 3232005 C 14 24436 31 079606628004 Starch paste added to iodine produces a color which is A. violet B. yellow C. blue 9 D. red_orange 2 OS 3232006 A 14 24438 31 046300948004 In its chemical action with other elements, sulfur most closely resembles A. oxygen B. phosphorus C. hydrogen 9 D. carbon 2 OS 3232007 C 14 24440 31 002800040094 Of the following nonmetals, the one not a halogen is 9 A. chlorine B. bromine C. sulfur D. iodine 0041 3232009 B 15 24442 32 018911780407 Element Y forms ions as a result of its participation in certain chemical reactions, but it forms covalent compounds in other reactions. Y ions are always larger than Y atoms, therefore, the element is A. a metal B. a non_metal C. a semi_metal 9 D. a noble gas E. none of these 0042 3232010 A 15 24446 52 002300041506 Fluorine is the most active halogen element. One explanation is that fluorine, compared with the other halogens: A. has the smallest atomic radius B. is the least dense C. has seven valence electrons D. is the strongest reducing agent 9 E. needs one electron to complete its outer shell. 0042 3232011 D 15 24450 32 000611670008 Chlorine reacts with water to give A. an acid solution B. hydrochloric acid C. hypochlorous acid D. all of these 9 E. none of these 3232012 D 15 24453 31 01890015 Which of the following elements is not a metal? 9 A. K B. Pb C. Au D. P E. Mg 0020 0020 3232013 D 15 24455 31 018900230067 The element most similar to fluorine in its properties is 9 A. O B. Ne C. S D. Cl E. none of these 0020 3232014 D 15 24457 51 000411670212 Halogens (X) react with A. methane to give CH X + HX 4 3 B. B to give BX 4 3 C. water to give acids D. all of the above 9 E. none of the above 0020 3232016 D 14 24460 52 080500211403 The halide ion with the highest oxidation potential is 5 _ _ _ _ 9 A. F B. Cl C. Br D. I 0019 3232017 D 14 24462 52 00040007 The halogen that is the poorest oxidizing agent is A. F B. Cl C. Br D. I 94 2 2 2 2 0019 3232018 B 14 24464 51 019604980105 The hydrogen halide with the lowest boiling point is 9 A. HF B. HCl C. HBr D. HI 0019 3232019 D 14 24466 52 14350001 Which would be expected to be the best reducing agent? A. H O B. H S C. H Se D. H Te 94 2 2 2 2 0019 3232020 B 0019 14 24468 52 04981371 Which has the lowest boiling point? A. H O B. H S C. H Se D. H Te 94 2 2 2 2 3232021 C 15 24470 31 140207940189 Which of the following elements would you expect to have chemical properties similar to those of oxygen (Z = 8)? A. N B. F C. S D. Cl E. Ar 94 7 9 16 17 18 0040 3232022 A 15 24473 31 002800940339 Which of the following elements is a nonmetal? 9 A. S B. Ag C. Pb D. Li E. Ca 0040 0040 3232023 B 15 24475 32 000804740067 Water, when compared to compounds of elements in the oxygen family with hydrogen, is found to have anomalous properties. One of these properties is A. a lower boiling point than expected B. the solid is less dense than the liquid C. a lower freezing point than expected D. the liquid density decreases with decreasing temperature down to 4 degrees C 9 E. no correct response is given. 3233001 D 15 24481 52 1 0020006690011295 Select the statement or statements which can be correctly deduced from the periodic table (Figure 1). A. It would be expected that calcium would combine with chlorine to form a compound, Cacl3 B. The valence number of copper is practically always +2 C. There probably exists a compound PH 4 3 The correct selection includes A. only A B. only B C. only C D. only B and C 9 E. A,B, and C 3233004 C 15 24487 52 018903371362 The elements with atomic numbers 21, 27, 40, and 43, have what common feature? A. They all have only one electron in a subshell B. They all have a partially filled p subshell C. They all have a partially filled d subshell 0040 ETS2 OS 0020 9 D. They all have a filled 5s subshell E. None of these 3233005 A 15 24491 52 018011780092 5 +2 The hydration energy of the Sc ion which does not exist in aqueous solution can be estimated best from data on the hydration energy of 5 +3 +2 + +3 9 A. Sc B. Ca C. K D. Cl E. Ti 0019 3233006 D 15 24495 51 036911780662 Which ion would you predict to be colored? 5 + + 2+ 3+ 3+ 9 A. Na B. Cs C. Cd D. Mo E. Y 0019 3233007 B 15 24497 52 036911780662 Which of the following ions are colored? 5 3+ 2+ 2+ 3+ 2+ 9 A. Ti B. Ni C. Cd D. Y E. V 0019 3233008 C 15 24499 31 036903380015 5 2 2 6 2 2 The electronic structure 1s 2s 2p 3s 3p is charateristic of which of the following? A. a metal B. transition metal C. a nonmetal D. a rare gas 9 E. no correct response is given. 0040 3233009 D 15 24503 51 036902630346 The transition metals A. do not fit into the periodic classification B. differ only in the number of electrons in the outermost shell C. have identical chemical and physical properties D. differ in the number of electrons in one of the inner shells 9 E. are not true metals 0034 3234001 E 15 24507 52 06840687800111 Silica A. is notable for a high coefficient of thermal expansion B. consists of chains of silicon atoms, giving it a fibrous structure C. is much harder than quartz D. decomposes at red heat into its elements 9 E. is transparent to ultraviolet light ETS2 OS 3234002 D 15 24511 52 03500022800111 Silicon carbide A. contains oxygen B. is used as a lubricant C. is a conductor of electricity D. is made by the action of coke on silica 9 E. is harder than the diamond ETS2 OS 3234003 B 15 24514 52 04770685800111 In mineral silicates A. silicon atoms are bound together directly, atom to atom B. SiO ions are bound together, through sharing 4 4 oxygen atoms C. most silicates are soluble in water D. if the binding of the silicate ions takes place in one direction only, the mineral exists in plates E. the most abundant of the mineral silicates is the 9 uncombined silicate ion ETS2 OS 3234004 B 15 24520 52 00080336800111 Water glass A. is ordinary glass which has been hydrated B. is used as an adhesive C. is made by dehydrating silicic acid D. has a high melting point 9 E. is a type of glass with a very high (95%) silica content ETS2 OS 3234005 B 15 24524 52 03360018800111 Glass A. is a compound having a definite chemical formula B. is a mixture of salts resulting from the process of heating together acidic and basic oxides C. has a fixed melting point D. is made up of individual crystals E. never is made of other ingredients than limestone, 9 soda and silica ETS2 OS 3234006 D 15 24529 52 00140066800111 Carbon forms a large number of compounds because A. of its small ionic radius B. of its great chemical activity C. it shows many valences D. of the ability of carbon atoms to form covalent linkages with each other ETS2 OS 9 E. it forms electrovalent and covalent compounds with equal ease 3234007 D 15 24534 32 05820020800111 Both positive and negative valence may be exhibited by A. hydrogen B. chlorine C. neon D. carbon 9 E. none of the above 3234008 C 15 24536 51 80018002 12 A number of new plastics and lubricants are being produced which contain the element, silicon. Which of the following facts probably most stimulated the research which led to this development? A. Silicon (or silicon dioxide) is a constituent of numerous minerals. B. Silicon compounds are very abundant. C. Silicon's position in the periodic table shows that its properties are in many respects similar to carbon. D. Silicon compounds and petroleum occur together in nature. 9 E. Our petroleum resources are being depleted rapidly. 3234009 C 14 24544 51 0192 0845 A substance which is not amphoteric is: A. V O B. Cr(OH) C. Cr(OH) D. Cr O 94 25 3 2 23 ETS2 OS ETS2 OS 0043 3234010 A 15 24546 31 018915510350 Elements used in semiconductors (in transistors) are the semi metals which conduct electricity better than non metals but not so well as metals. A good choice for this purpose would be 9 A. silicon B. chlorine C. lithium D. argon E. barium. 0047 3234011 A 15 24550 52 140313700014 Which of the following has the highest first ionization potential? A. C B. Si C. Ge D. Sn E. Pb 94 6 14 32 50 82 0019 3234012 B 14 24553 52 1945 The amphoteric (capable of reacting as either an acid or a base) element in the third period is 9 A. Mg B. Al C. Si D. P 0056 3235001 E 15 24555 31 1 072607599001 95 The following question refers to the periodic table, Figure 1. The most stable oxidation state of gadolinium is A. Gd(_3) B. Gd(_) C. Gd(+) D. Gd(+2) 9 E. Gd(+3) 3235002 E 15 24558 Lanthanides are A. elements 90 to 103 B. elements 122 up C. the nonmetals D. all gases 9 E. none of these 51 07590189 2WVW 0020 3235003 B 14 24560 31 075913621740 The lanthanide series corresponds to the filling of which subshell? 9 A. 3f B. 4f C. 5f D. 5d 3236001 D 14 24562 31 079401898004 Of the following groups, the one composed only of artificially produced elements is A. polonium, francium, actinium B. procectinium, neptunium, radon C. berkelium, rhenium, hafnium 9 D. curium, californium, americium 0019 3236002 A 14 24566 31 018908258004 The element californium, is a member of the A. actinide series B. alkali metal family C. alkaline earth family 9 D. lanthanide series 2 OS 2 OS 3236003 C 15 24568 51 01891223 Which of the following is not a transuranium element? A. Lawrencium B. Nobelium C. Hafnium D. Curium 9 E. Einsteinium 0020 3236004 E 15 24570 51 01890825 Which of the following elements is not an actinide? 0020 9 A. U B. Cm C. Os D. Bk E. Th 3236005 C 14 24572 31 082512231740 The group of elements in which the 5f subshell is being filled is A. transitional B. lanthanides C. actinides 9 D. representatives 0019 3238001 E 15 24574 31 03770340800211 Which one of these is an inert gas? A. ammonia B. carbon monoxide C. sulphur dioxide D. hydrogen 9 E. helium ETS2 OS 3238002 C 15 24576 32 03400263800111 Helium contains 2 electrons in its outer ring. The other inert gases are inert because they A. need 2 electrons in the outer ring B. have 2 electrons in the outer ring C. have 8 electrons in the outer ring D. have 6 electrons in the outer ring 9 E. have lower atomic weights than the other elements ETS2 OS 3238003 A 15 24581 32 01968001800211 All of these gases are alike in a certain respect except A. hydrogen B. helium C. neon D. argon 9 E. krypton ETS2 OS 3238004 E 15 24583 51 03770569800111 Concerning the inert gases, A. argon is used in lifting balloons B. helium atoms contain NO neutrons C. xenon is given off in the disintegration of radium D. neon is too rare to have any practical use 9 E. krypton has eight electrons in its outermost orbit ETS2 OS 3238005 C 14 24587 31 011302938004 The gas which differs in molecular composition from that of all of the others listed below is 2 OS 9 A. hydrogen B. nitrogen C. neon D. chlorine 3238006 A 14 24590 51 091402930873 The shape of the XeF molecule is: 4 4 A. square_planar B. tetrahedral 9 C. square pyramidal D. trigonal bipyramidal. 0043 3238007 C 15 24592 51 142308850263 The number of lone electron pairs in xenon difluoride is 9 A. 1 B. 2 C. 3 D. 4 E. 0 0043 3238008 A 14 24595 51 003700370378 The first noble_gas compound ever synthesized is: A. XePtF B. Xe(RuF ) C. XeOF D. XeOF 94 6 62 4 2 3238009 C 14 24597 51 006404150321 The noble gas which occurs most abundantly in the atmosphere is: 9 A. He B. Ne C. Ar D. Kr. 0043 3238010 A 14 24599 51 078307810347 In the valence_bond approach to the bonding in XeOF it is 4 4 assumed that the orbitals of xenon hybridize to form: 5 32 222 A. sp d hybrids B. s p d hybrids 5 23 3 9 C. sp d hybrids D. sp d hybrids. 3238011 A 14 44527 51 09140293 The geometry of the XeOF molecule is: 4 4 A. square pyramidal B. tetrahedral C. distorted tetrahedral 9 D. trigonal bipyramidal E. octahedral 0043 0043 0043 3238012 C 14 24606 51 1117 F_Xe_F bond angle in XeF is: 4 4 5 o o o o 9 A. 109 B. 103 C. 90 D. 60 0043 3238013 C 14 24608 51 1117 The f_Xe_f bond angle in Xeof is: 0043 4 5 0 9 A. 109 4 0 B. 103 0 C. 90 0 D. 60 3238014 B 14 24610 52 078209800781 The molecular orbital treatment of the bonding in XeF considers 4 2 that the three atoms are bonded together by a A. pi bond B. three_center bond 9 C. nonbonding orbital D. nonlocalized orbital. 0043 3238015 B 15 24614 31 018900640113 Which of the following elements is not a noble gas? 9 A. He B. H C. Ar D. Xe E. Rn 0020 3238016 B 14 24616 32 026300640945 Of the outermost electrons of the noble "inert" gases, it is true that A. all are in filled p orbitals B. all are paired C. they complete a principal energy level 9 D. all are very difficult to remove from the atom 0009 3238017 B 14 24620 52 033700640606 The atomic number of the next_to_bediscovered noble gas, below radom, Rn, would be 9 A. 109 B. 118 C. 173 D. 222 0009 3238018 A 15 24622 72 054000040293 Given the following information concerning some halogen compounds of Xe, choose the best statement from the list pertaining to the molecular structures. XeF is nonpolar 4 4 XeF Cl is polar, as prepared by chemist X 4 2 2 XeF Cl is nonpolar, as prepared by chemist Y 4 2 2 A. All of the above are square planar, so that there could be two forms (isomers) of XeF Cl , one symmetrical and the 4 2 2 other unsymmetrical. B. The geometries are tetrahedral, in agreement with CF 4 4 (nonpolar) and CF Cl (polar), which are known 4 2 2 0019 C. Trigonal pyramidal, which agrees with XeF being nonpolar 4 4 D. Square pyramidal, which agrees with XeF being nonpolar 4 4 9 E. could be B, C, or D. 3238019 D 14 24636 51 006411670023 Of the following rare gases, which reacts most readily with fluorine? 9 A. He B. Ne C. Kr D. Xe 0009 3238020 A 15 24638 31 006402930351 The inert gas molecules contain only one of these particles. This particle is the 9 A. atom. B. electron. C. ion. D. neutron. E. proton. 0035 3238021 D 15 24640 32 137003370562 When ionization potential is plotted against atomic number for each of the elements, a series of peaks occurs on the graph. If one of these peaks is occupied by helium, another peak could be predicted for 9 A. lithium. B. carbon. C. fluorine. D. neon. E. tungsten. 0035 3238022 C 14 24644 31 03770562800111 The inert gas most used in signs made of glass tubing is A. helium B. xenon C. neon 9 D. krypton ETS2WVW 3240001 D 15 24646 52 00690070800112 When ionization potential is plotted against atomic number for each of the elements, a series of peaks occurs on the graph. If one of these peaks is occupied by helium, another peak could be predicted for A. lithium B. carbon C. fluorine D. neon 9 E. tungsten ETS2 OS 3240002 D 15 24650 52 00698001800212 When the atomic volume of the elements is plotted as a function of the atomic number of the elements, a series of maxima and minima appear on the graph. If the atomic volume of sodium represents one of the maxima, it could be predicted that one of ETS2 OS the other maxima would be represented by the atomic volume of the element A. magnesium B. neon C. chlorine D. potassium 9 E. plutonium 3240003 C 15 24656 51 00030071800112 In the family of alkali metals (Na, K, etc.), Cesium is the most active. The best explanation of this is that A. it has a greater attractive force for valence electrons than the others B. its atomic number is greater C. its valence electron has an orbital with a greater radius than the others D. its incomplete shell or energy level is closer to the nucleus 9 E. it has more electrons in the outer orbital than the others ETS2 OS 3240004 B 15 24663 51 00710006800112 Chlorine is a more active non_metal than is iodine. This is probably because A. chlorine loses electrons more readily than does iodine B. the incomplete shell of electrons in the chlorine atom is closer to the nucleus than is the one in the iodine atom C. iodine adds electrons more readily than does chlorine D. the negative valence electron of the chlorine atom is farther away from the nucleus than is the one in the iodine atom 9 E. chlorine is an oxidizing agent ETS2 OS 3240005 C 14 24670 31 018903378004 The element with atomic number 7 is likely to have properties similar to the element whose atomic number is A. 11 B. 2 C. 15 9 D. 17 2WVW 3240006 B 14 24672 31 026303468004 The number of electrons in the outer shell of the elements in group IIa of the periodic table is A. 1 B. 2 C. 3 9 D. 4 2WVW 3240007 D 14 24674 71 8003 Which of the following disubstituted cyclopropanes is most easily hydrogenated? A. cis_1,2_dimethylcyclopropane B. trans_1,2_dimethylcyclopropane C. trans_1,2_diisopropylcyclopropane 9 D. cis_1,2_diisopropylcyclopropane 2WVW 3240008 C 15 24678 51 026300730347 The last two electrons in calcium (element 20) are in a A. 2s orbital B. 3s orbital C. 4s orbital D. 3p orbital 9 E. none of these 0020 3240009 A 15 24680 32 018903471356 Elements in group via have outer orbitals designated by the 5 2 5 notation ns np . Since sulfur is in the third period, its outer electrons are 5 2 5 2 5 2 5 2 5 9 A. 3s 3p B. 3s np C. ns 3p D. ns n3 E. none of these 0020 3240010 A 15 24684 52 060601890067 When discovered, element 113 should have properties resembling those of the element 9 A. Tl B. Pb C. Au D. Hg E. U 0020 3240011 B 15 24686 32 03380028 5 2 6 The outer electron configuration ns np is found in A. all members of the noble gas family B. some members of a family of nonmetals C. all members of the alkaline_earth family D. several members of the alkali metal family 9 E. only elements for which N equals three or greater 3240012 C 15 24691 31 033800030189 The electronic configuration of element X is 5 2 2 6 2 6 2 10 6 1 1s 2s 2p 3s 3p 4s 3d 4p 5s . Judging from its electronic configuration, element X is A. in group Va B. in period 2 0019 0040 9 C. a representative element D. a transition metal E. a non_metal. 3240013 A 15 24695 31 033807940076 The distinguishing electron of selenium, element number 34, is in which of the following groups? 5 4 4 2 6 4 9 A. 4p B. 3p C. 3s D. 4d E. 5p 3240014 D 15 24698 32 03380369 Which electron configuration represents a transition element? 5 2 2 2 2 2 6 2 4 2 2 6 2 A. 1s 2s 2p B. 1s 2s 2p 3s 3p C. 1s 2s 2p 3s 5 0040 0047 2 2 6 2 6 2 8 D. 1s 2s 2p 3s 3p 4s 3d 5 2 2 6 2 6 10 2 6 9 E. 1s 2s 2p 3s 3p 3d 4s 4p . 3250001 C 15 24703 51 1 0020006590011295 By means of the periodic table (Figure 1) identify the element described as follows a certain element exercises only the valence +2 in compounds. The atomic weight of the element is greater than that of chromium but is less than that of silver. The element is A. bromine B. calcium C. strontium D. rubidium 9 E. potassium ETS2 OS 3250002 D 15 24708 51 1 0020006590011295 By means of the periodic table (Figure 1) identify the element described as follows a certain element may exercise either positive or negative valence, its principal valences ranging from +4 to _4. The atomic weight of the element is greater than that of fluorine and is less than that of calcium. The element is A. argon B. chlorine C. potassium D. silicon 9 E. sulfur ETS2 OS 3250003 B 14 24714 31 018903378004 The element with atomic number 8 is likely to have properties 2WVW similar to the element with atomic number A. 12 B. 16 C. 3 9 D. 18 3250004 B 15 24716 31 033705620587 An isotope with a mass number of 21 and an atomic number of 10 would correctly be represented by which of the following symbols? 5 10 21 10 21 11 A. Ne B. Ne C. Sc D. Sc E. Ne 94 21 10 21 10 10 0040 3250005 C 15 24720 32 081203410097 The chemical symbol for an atom which contains 40 electrons and 51 neutrons is A. Pa B. Nb C. Zr D. Na 9 E. impossible to tell from information given 0040 3250006 B 15 24723 31 033701890369 The element with atomic number 42 is an example of what kind of element? A. representative B. transition C. rare gas 9 D. innertransition E. lanthanide. 0040 3250007 A 15 24726 32 033801850337 An ion of element 26 has the following electronic configuration: 5 2 2 6 2 6 0 5 1s 2s 2p 3s 3p 4s 3d . What is the charge on this ion? 9 A. 3+ B. 3_ C. 2+ D. 2_ E. +1 0040 3250008 B 15 24729 31 088500160338 The number of valence electrons that Al has is 4 13 9 A. 1 B. 3 C. 13 D. 8 E. 5 0040 3250009 C 15 24731 31 007311780338 5 2+ A Ca ion contains how many electrons? 9 A. 20 B. 22 C. 18 D. 40 E. 29 0040 3300001 D 14 24733 31 034400738004 Compared with potassium, calcium A. has larger atoms B. has a lower density C. is more easily oxidized 2WVW 9 D. is less active chemically 3300002 D 14 24735 31 018900678004 Elements with similar chemical properties A. occur only within the same period B. have identical atomic mass (weight) C. have identical numbers of neutrons 9 D. have the same number of electrons in the outer shell 3300003 E 15 24738 31 8003 Within group VIa of the periodic table with increasing atomic number, which one of the following properties does not change in the manner indicated? A. atomic radius _ increases B. density _ increases C. ionization energy _ decreases D. electron affinity _ decreases 9 E. electronegativity _ increases 3300004 B 15 24743 32 07228003 Within group VIa of the periodic table, with increasing atomic number, which one of the following properties does not change in 3 ___ the manner indicated? A. atomic radius _ increases B. electronegativity _ increases C. ionization energy _ decreases D. electron affinity _ decreases 9 E. density _ increases 2WVW 2WVW 2WVW 3300005 B 14 24748 52 136707451403 Which of the following exhibits the highest bond energy? A. F B. Cl C. Br D. I 94 2 2 2 2 0043 3300006 D 14 24750 52 136707451371 Which of the following exhibits the lowest bond energy? 9 A. HF B. HCl C. HBr D. HI 0043 3300007 E 15 24752 51 136713680068 Which of the following exhibit periodic relationships A. boiling points B. ionization potentials C. chemical properties D. melting points 9 E. all of the above 0020 3300008 C 14 24755 52 006703680207 Which one of the following properties of an element would you expect not to be a periodic function of atomic number? A. atomic volume B. specific heat 9 C. ionization potential D. boiling point 3300009 D 14 24758 52 1946 The highest average bond energy is: 9 A. C_H B. C_I C. C_Cl D. C_F 3300010 C 14 24760 52 19480110 5 2+ 2+ From a mixture of Mg and Be , which one of the following re_ 5 2+ 2+ agents will precipitate Mg and leave Be in solution? A. HCl B. NH OH C. NaOH D. H SO 94 4 2 4 3310001 C 15 24764 52 03750028800111 In order to determine the relative activity of several non_metals it would be most useful to know the A. valences of the non_metals B. atomic weights of the non_metals C. atomic numbers of the non_metals D. family to which each non_metal belongs 9 E. group to which each non_metal belongs 3310002 A 14 24768 31 006703448004 Of the following, which one is the property of potassium and chlorine that determines the relative acidity of koh and hCl A. electronegativity B. atomic radius C. oxidation potential 9 D. melting point 0009 0057 0059 ETS2 OS 2WVW 3310003 C 14 24771 71 8003 Which of the following is most reactive to nucleophilic reagents? A. CH F B. CH Br C. CH I D. CH Cl E. CH OH 94 3 3 3 3 3 2WVW 3310004 D 14 24774 71 8003 Which of the following is most reactive to anionic reagents? A. CBr 4 4 B. HCBr 2WVW 4 C. 4 D. 94 3 H CBr 2 2 H CBr 3 3310005 A 14 24777 71 8003 Which of the following is most reactive to anionic reagents? A. H CI 4 3 B. H C(I) 4 2 2 C. HC(I) 4 3 D. C(I) 94 4 3310006 A 14 24780 31 80038004 Which element would most readily replace the oxygen in an oxide? A. fluorine B. chlorine C. nitrogen 9 D. sulfur 2WVW 2WVW 3310007 C 14 24782 32 018908248004 Of the following, the element possessing the highest electro_negativity is A. lithium B. cesium C. fluorine 9 D. astatine 2 OS 3310008 B 15 24784 31 003702370355 Which of the following compounds are very covalent in their bonding? A. Li S B. IBr C. FrCl D. Na O E. NaCl 94 2 0042 3310009 D 14 24787 32 036203370067 Within group VIa of the periodic table with increasing atomic number, which one of the following properties does not change in 3 ____ ___ the manner indicated? A. atomic radius _ increases B. density _ increases C. ionization energy _ decreases 0042 9 D. electronegativity _ increases 3310010 A 14 24792 52 140308240023 Which of the following has the highest electronegativity? 9 A. F B. Cl C. Br D. I. 0043 3310011 B 15 24794 52 000503550887 Given the following table of Pauling electronegativity values: atom / Be In Pb Bi B H Se C Br N O F _____________________________________________________________ electro_ / 1.5 1.7 1.8 1.9 2.0 2.1 2.4 2.5 2.8 3.0 3.5 4.0 negativity / 0044 Which one of the following sequences would you predict to have decreasing ionic character of the bond indicated? A. Pb_Br>Pb_C>Pb_N>Pb_Se B. Pb_N>Pb_Br>Pb_C>Pb_Se C. Pb_Se>Pb_N>Pb_Br>Pb_C D. Pb_Se>Pb_C>Pb_Br>Pb_N 9 E. Pb_Se>Pb_C>Pb_N>Pb_Br. 3310012 E 15 24801 51 0824 Electronegativity is A. the charge on an atom B. the charge on negative ions C. a measure of an electrical potential D. an arbitrary number assigned to each atom 9 E. none of these 3310013 A 15 24804 31 082401890023 The most electronegative element is 9 A. F B. Cs C. H D. O E. Al 0020 0020 3310014 A 15 24806 31 14030824 Which of the following has the highest electronegativity? A. Cl B. Se C. Sb D. Rb E. Na 94 17 34 51 37 11 0019 3310015 E 15 24809 51 13711370 Which would be expected to have the lowest second ionization 3 ______ potential? 9 A. Na B. K C. Mg D. Ca E. Sr 0019 3310016 A 15 24812 31 082400230557 The electronegativity scale has A. fluorine as the most electronegative element B. cesium as the most electronegative element 0040 9 C. hydrogen as the most electronegative element D. element 105 as the most electronegative element E. xenon as the most electronegative element. 3310017 C 15 24816 31 082407221359 The correct sequence for the ordering of the element O, Ge, 4 8 32 Se, and Pb in terms of increasing electronegativity is 434 82 A. Pb, Se, Ge, O B. Se, Pb, Ge, O C. Pb, Ge, Se, O D. O, Se, Pb, Ge 9 E. O, Se, Ge, Pb 0040 3310018 B 15 24820 31 082400230722 Which of following elements has the highest electronegativity? 9 A. cesium B. fluorine C. francium D. uranium E. helium. 0040 3310019 A 15 24822 31 082407221359 Which of the following sets of elements is arranged in order of decreasing electronegativity? 3__________ A. Cl, S, Se, Te B. F, B, O, Li C. Br, Cl, S, P D. F, B, O, Li 9 E. Te, Se, S, Cl 0040 3310020 A 14 24825 52 1948 Of the following, the most electronegative is: 9 A. C B. Si C. Sn D. Pb 0059 3310021 C 15 44825 51 Which will be most easily hydrogenated? A. cyclohexane C. propylene E. benzene 9 B. cyclopropane D. hexane 3320001 C 15 24827 32 00150577800111 In the family of active metals (Na, K, etc.) cesium is the the most active. The best explanation of this is that A. it has a greater attractive force on valence electrons than the others. B. its atomic number is greater. C. it has an atomic radius greater than that of the others. D. its incomplete shell or energy level is closer to the nucleus. 9 E. it has more valence electrons than the others. ETS2 OS 3320002 B 15 24833 32 03440002800111 Potassium is more active than sodium because A. it has a greater number of valence electrons. B. its valence electron is farther from the nucleus C. it accepts electrons more readily. D. its atomic weight is less than that of sodium. 9 E. its incomplete shell is closer to the nucleus. 3320003 A 15 24837 32 00030015800111 The alkali metals of group Ia, lithium, sodium, potassium, rubidium, and cesium are the most active metals. Cesium is the most active in the list because as one proceeds from lithium to cesium A. the atomic radius of the valence electron increases B. the number of valence electrons increases C. the first ionization potential increases D. the valence increases 9 E. the atomic weight decreases ETS2 OS ETS2 OS 3320004 A 14 24843 31 033701898004 As the atomic number of the elements in the second period of the periodic table increases, the ionization potential A. generally increases B. generally decreases C. first increases then decreases 9 D. first decreases then increases 2WVW 3320005 E 15 24847 32 073107228003 Which one of the following elements would you expect to have the largest first ionization energy? 3 _______ A. cesium B. thallium C. bismuth D. polonium 9 E. radon 2WVW 3320006 A 14 24850 31 07310064 The highest ionization energies are found in the A. inert gases B. alkali metals 9 C. transition elements D. halogens 0041 3320007 B 14 24852 31 07310003 The lowest ionization energies are found in the A. inert gases B. alkali metals 9 C. transition elements D. halogens 0041 3320008 E 15 24854 52 018907311421 Which one of the following elements would you expect to have the largest first ionization energy? 3_______ 9 A. cesium B. thallium C. bismuth D. polonium E. radon 0042 3320009 A 15 24857 52 018914031370 Which element has the highest ionization potential for the removal of one electron? 9 A. Ne B. Li C. Na D. Ca E. Ba. 0042 3320010 A 14 24859 52 018913701403 Choose the element with the highest first ionization potential: 9 A. Boron B. Aluminum C. Gallium D. Indium 0043 3320011 D 14 24861 52 018914481371 Choose the element with the lowest oxidation potential: 9 A. B B. Al C. Ga D. Ln. 0043 3320012 A 14 24863 52 000413701403 The halogen with the highest ionization potential is: 9 A. F B. Cl C. I D. At. 0043 3320013 C 15 24865 52 1370 Which of the following trends in first ionization potential is NOT correct? A. Ba<Sr<Ca<Mg B. Ca<As<Cl<He C. N<P<Sb<Bi 9 D. K<Ca<Ge<As E. Li<B<N<F 0044 3320014 C 15 24868 52 1370 The first ionization potential of Se is 225 kcal/mole. Which of the values below would you predict for the first ionization potential of Br? A. 549 kcal/mole B. 178 kcal/mole C. 273 kcal/mole 9 D. _225 kcal/mole E. 113 kcal/mole. 0044 3320015 A 14 24872 52 01891370033951 Which of the following elements would have the largest difference between its first and second ionization potentials? 9 A. lithium B. sodium C. potassium D. fluorine E. cesium 3320016 B 15 24875 52 01890731 Which of the following statements is true concerning the element potassium? A. potassium is smaller than lithium. B. Potassium has a lower ionization potential(energy)than 9000 0018 lithium. 5 2+ C. Potassium loses two electrons to form K D. Potassium is in group IIa. 5 + 9 E. Potassium gains one electron to form K 3320017 A 15 24881 31 00620722 As one moves from left to right across the periodic table A. the metallic properties decrease B. the metallic properties increase. C. the metallic properties do not change D. the metallic properties increase with every other element 9 E. none of these 0028 3320018 D 15 24885 51 000313701371 Of the alkali metals, the one (of those listed) that has the lowest ionization potential is 9 A. Li B. K C. Ca D. Cs E. Na 0020 3320019 A 14 24887 52 018907310362 The element with the largest value for the first ionization energy is located in the _________ portion of the modern extended form of the periodic table. A. upper right B. lower right 9 C. middle D. lower left 0009 3320020 B 15 24890 31 13701403 Which of the following has the highest ionization potential? A. P B. S C. As D. Se E. Te 94 15 16 33 34 52 3320021 C 15 24893 32 026814650342 According to our ideas of atomic structure, we say that it takes more electrical energy to remove an electron from a helium atom than from a hydrogen atom because A. helium initially has two electrons. B. the helium nucleus has a greater mass. C. the helium nucleus has a greater charge. D. when hydrogen converts to helium (as in the stars) energy is released. 9 E. helium has neutrons in its nucleus. 3320022 E 15 24899 52 1370 0337 Ionization potentials do not lead to an understanding of A. valences 0019 0035 0034 9 B. the nature of the bonds formed (ionic vs. covalent) C. the extreme reactivity of the alkali metals; i.e., Li, Na, K, etc. D. the inertness of the noble gases E. atomic numbers 3320023 D 14 24903 52 Lowest first ionization energy: 9 A. S B. Se C. Te D. Po 1945 3330001 A 15 24904 31 072407228003 Which one of the following elements would you expect to have the greatest affinity for an electron? 3________ A. bromine B. gallium C. arsenic D. selenium 9 E. potassium 3330002 A 14 24907 31 8003 Which of the following atoms has the highest assigned electronegativity? 9 A. oxygen B. phosphorus C. nitrogen D. sulfur 0056 2WVW 2WVW 3330003 D 14 24909 32 033700048004 As the atomic number of the halogens increases, the halogens A. lose their outermost electrons less easily B. become less dense C. become lighter in color 9 D. gain electrons less easily 2 OS 3330004 D 14 24912 31 Bromine atoms can oxidize A. chlorine atoms B. chloride ions C. iodine atoms 9 D. iodide ions 2 OS 078603518004 3330005 A 15 24914 32 018907240786 Which one of the following elements would you expect to have the greatest affinity for an electron? 9 A. bromine B. gallium C. arsenic D. selenium E. potassium 0042 3330006 E 15 24917 32 018907240344 Which one of the following elements would you expect to have the 0042 least affinity for an electron? 9 A. bromine B. qallium C. arsenic D. selenium E. potassium 3340001 D 15 45413 51 In which of the following lists do the ions NOT appear in the order of increasing ionic radius? 5 + + + 2_ _ + A. Li < Na < K D. S < Cl < K 5 3+ 2+ + _ _ _ B. Al < Mg < Na E. Cl < Br < I 5 + _ 2_ 9 C. Na < F < O 3340002 B 14 24920 31 80048003 The halogen with the smallest atomic radius is A. least active B. most active C. inert 9 D. found free in nature 2WVW 3340003 C 14 24922 32 001900158004 Of the following, which one is a correct statement: A. The ionic radius of a metal is the same as its atomic radius B. The ionic radius of a metal is greater than its atomic radius C. The ionic radius of a metal is less than its atomic radius D. The atomic radius of a non_metal is more than its ionic 9 radius 2 OS 3340004 D 15 24927 32 117807250026 Which one of the following ions would you expect to have the largest ionic radius? 5 2_ +7 +4 3_ 3+ 9 A. S B. Mn C. Ti D. P E. Sc 0042 3340005 A 15 24930 52 117807250026 Which one of the following ions would you expect to have the second largest ionic radius? 5 2_ +7 +4 3_ 3+ 9 A. S B. Mn C. Ti D. P E. Sc 0042 3340006 A 15 24933 32 08051178 The size of halide ions; 5 _ _ _ _ A. increases from F to I , B. increases from I to F 0042 9 C. is about the same for all halides D. is smaller than the size of the corresponding atom. E. depends mainly on which isotope forms the ion. 3340007 D 15 24937 52 073011780351 Of the following isoelectronic ions or atoms the smallest is: 5 _2 _ + 2+ 9 A. S B. Cl C. K D. Ca E. Ar 3340008 B 15 24939 52 00260725 Which one of the following trends in atomic and ionic radii is not correct? 5 3+ + 2_ 3_ 2+ 2+ 2+ 2+ A. Al <Na <O <N B. Sr <Ca <Mg <Be 9 C. C<Al<Ca<RB D. C<Si<Ge<Sn E. C<B<Be<Li. 0042 0044 3340009 C 14 24942 52 105508231435 Which of the following species would you expect to have the largest radius? 5 + _ A. Na B. Ne C. F D. O 94 11 10 9 8 0009 3340010 C 14 24945 52 018915060195 Which of the elements listed below would you expect to have the smallest atomic volume? 9 A. P B. Cl C. F D. all the same 0009 3340011 B 15 24947 31 08231421 Which of the following has the largest radius? A. S B. As C. Cl D. K E. Br 94 16 33 17 19 35 0019 3340012 D 15 24949 52 14210823 Which of the following has the largest radius? 5 + _ _2 + A. Na B. Ne C. F D. O E. Li 94 11 10 9 8 3 0019 3340013 A 14 24952 52 1945 Largest radius: 9 A. Na B. Mg C. Al D. Si 3340014 A 14 24953 52 19480725 Of the following, the one with smallest radius is: 5 3+ 3+ 3+ 3+ 0056 0059 9 A. B B. Al C. Ga D. In 3350001 C 14 24955 51 04300431800111 Tungsten is used as a filament in electric light bulbs because of its A. low density B. high electrical resistance C. high melting point 9 D. high coefficient of expansion ETS2 OS 3350002 B 14 24958 31 04130433800111 Mercury is used in barometers because of its A. good electrical conductivity D. high thermal conductivity B. high density E. low reactivity 9 C. attractive luster ETS2 OS 3350003 A 15 24961 31 00020015800111 Sodium is different from common metals in being A. lighter than water B. opaque C. malleable D. of metallic lustre 9 E. a nonconductor of heat ETS2 OS 3350004 A 14 24964 32 037701138004 The inert gas with the lowest boiling point is A. helium B. radon C. xenon 9 D. argon 2 OS 3350005 A 14 24966 31 004400198004 The bromide ion in solution is 9 A. colorless B. red_orange C. violet D. yellow 2 OS 3350006 D 14 24968 31 The metal of lowest density is A. beryllium B. deuterium C. boron 9 D. lithium 001501868004 3350007 D 14 24970 52 0808 Choose the least soluble of the following0 A. AgNO B. AgF C. AgCl D. AgBr. 94 3 E. blue 2 OS 0043 3350008 D 14 24972 52 016004620438 Which of the following exhibits the largest electrical conductivity in the liquid state? A. F B. Cl C. Br D. I 94 2 2 2 2 3350009 A 14 24975 52 13710498 Which of the following has the lowest boiling point? A. F B. Cl C. Br D. I 94 2 2 2 2 3350010 B 14 24977 52 006604981371 Select the compound with the lowest boiling point: A. NH B. PH C. AsH D. SbH 94 3 3 3 3 3350011 E 15 24979 31 01890062 Which of the following elements is the most metallic ? 9 A. Cr B. B C. Br D. As E. Rb 3350012 D 14 24981 52 018614131500 To estimate the density of hafnium, Hf, one would expect to 4 72 average the densities of A. La and Ta B. Zr and Ce 9 C. Zr and U D. Ta and Lu 3350013 C 14 24984 52 0498 Which of the following would have a boiling point lower than SiCl ? 4 4 A. GeCl B. SiBr C. CCl D. LiCl 94 4 4 4 3350014 B 15 24987 52 13710498 Which of the following has the lowest boiling point? 9 A. HF B. HCl C. HBr D. HI 3350015 A 15 24989 32 000800670722 Which of the following properties of water is anomalous according to the periodic law? A. boiling point B. molecular weight C. density at 40 degrees C D. more than one correct response 9 E. no correct response is given. 0043 0043 0043 0020 0009 0009 0019 0040 3350016 D 15 24993 31 000800670722 Which of the following properties for water is not anomalous 3 ______ (unexpected)? A. boiling point B. freezing point C. heat of vaporization D. molecular weight 9 E. no correct response is given. 0040 3350017 D 15 24997 32 000800670722 Which of the following properties of water would be considered anomalous or different than expected? A. boiling point B. density behavior with temperature change C. molecular weight D. more than one correct response 9 E. no correct response is given. 0040 3350018 C 14 25001 52 1945 Which element is the most metallic? 9 A. Se B. Br C. Te D. I 3350019 D 14 25002 52 19480110 Of the following, the least water_soluble is: A. Hg F B. Hg Cl C. Hg Br D. Hg I 94 22 2 2 2 2 22 3350020 D 14 25004 52 1948 The least water soluble of the following is: 9 A. TlF B. TlCl C. TlBr D. TlI 0056 0059 0059 3360001 A 14 25006 52 117801910016 Choose the ion which tends to hydrolyze the most0 5 3+ 3+ + 3+ 9 A. Al B. Ga C. Tl D. Tl . 0043 3360002 B 14 25008 52 105514211531 Choose the species which shows the largest tendency to form 5 3+ complexes with Al : 5 _ _ 2_ A. H O B. F C. Cl D. SO 94 2 4 0043 3370001 A 14 25011 31 80048003 In general, an atom will form a positive ion most easily if the 2WVW 9 A. size of the atom is large B. size of the atom is small C. charge on the ion is large D. atoms appear below hydrogen in the activity series 3370002 B 15 25014 52 0035 Which one of the following oxidation states would NOT be expected? 5 3+ 4_ 6+ + A. Y B. P C. Te D. Na 9 E. all of these oxidation states would be expected. 0044 3370003 B 15 45676 52 072613240189 Which one of the following sets of oxidation numbers would you predict for these elements: Pb V Nb Sr La A. 5 6 7 4 5 B. 4 5 5 2 3 C. 5 5 7 4 3 D. 4 7 6 2 3 9 E. 5 5 7 4 3 0044 3370004 B 14 25022 51 003500370218 The oxidation states of nitrogen compounds include all numbers A. between + 3 and _5 B. between _3 and +5 C. between +3 and _3 9 D. between +5 and _5 0019 3370005 C 15 25025 52 00351355 The maximum oxidation state of As 9 A. +2 B. +3 C. +5 D. +6 E. +7 3370006 D 14 25027 52 117805590189 If ions were formed in the combination of tin ( Sn) and another 4 50 element, what would be the likely charge on the tin atoms? 9 A. _2 B. +1 C. +3 D. +4 3370007 B 14 25030 52 1947 The most positive oxidation state of oxygen in any known compound is: 9 A. 0 B. 2+ C. 3+ D. 4+ 3380001 A 14 25032 31 024200668004 An ionic compound will form when A. an element with 7 electrons in the outer shell unites with 0019 0009 0058 2WVW 9 an element with 1 electron in the outer shell B. two elements with the same number of electrons in the outer shell unite C. electrons are shared by two atoms D. an electric current is passed through a compound E. when water is electrolyzed 3380002 D 14 25037 31 006601898004 A compound formed by uniting the element having atomic number 55 with the element having atomic number 16 will probably involve bonds that are A. polar covalent B. nonpolar covalent C. coordinate covalent 9 D. electrovalent 3380003 B 14 25041 31 80048003 Which compound is highly covalent? A. cesium chloride B. carbon bisulfide C. potassium bromide 9 D. calcium fluoride 2WVW 2WVW 3380004 D 15 25043 32 132313670355 Which of the following oxides exhibits the highest covalent character in its bonding? A. BaO B. MgO C. BeO D. B O E. Al O . 94 23 23 0042 3380005 D 14 25046 52 023712130846 An example of a covalent hydride is: A. NaH B. CaH C. SrH D. AsH 94 2 2 3 0043 3380006 C 15 25048 52 000511390237 Indicate whether the bonding in the following compounds is primarily ionic (I), polar covalent (PC), or non_polar covalent (NC). H CsF SrF PO NH 4 2 2 23 3 A. NC PC PC PC PC B. PC I I I NC C. NC I I PC PC D. NC I PC I PC 9 E. I PC I PC I 0044 3380007 D 15 25056 51 02931376 The NaCl molecule A. has electrovalent bonds B. has covalent bonds C. has coordinate covalent bonds D. does not exist 9 E. has nonpolar bonds 0020 3380008 A 15 25059 51 035513760351 The bond that exists between two chlorine atoms in chlorine gas is A. pure covalent B. partially ionic C. polar D. coordinate covalent 9 E. none of these 0020 3380009 E 15 25062 51 035501130351 The bond between two nitrogen atoms in nitrogen gas is A. ionic B. double C. polar D. single 9 E. triple 0020 3380010 B 15 25064 51 035500050411 The bond between Cs and F in CsF would be expected to be A. pure covalent B. pure ionic C. nonpolar D. coordinate covalent 9 E. none of these 0020 3380011 C 15 25067 32 11390355 Which of the following has the least polar bond? A. NaCl B. BrF C. Cl D. KBr E. HCl 94 2 3380012 B 14 25069 52 019602371377 Which hydrogen halide has the greatest covalent character? 9 A. HCl B. HI C. HF D. HBr 3380013 C 15 25071 51 02931394 Which of the following molecules is nonpolar? A. HOH B. HI C. CO D. HF E. CH OH 94 2 3 0020 0020 0020 3380014 A 15 25073 31 12961425 Which of the following contains the most purely ionic bonding? A. CsCl B. CH C. SO D. AlCl D. Cl 94 4 2 3 2 0019 3380015 E 15 25076 31 09261296 Which of the following contains the most purely covalent bonding A. CsCl B. CH C. SO D. AlCl E. Cl 94 4 2 3 2 0019 3380016 D 14 25079 32 11390293 The most polar molecule is A. F B. BrI C. BrCl D. ICl 94 2 0019 3380017 A 14 25081 32 000502370355 Which one of the following contains both ionic and covalent bonds? A. NaOH B. HOH C. C H Cl D. SiO 94 65 2 0009 3390001 A 14 44989 31 01890337 An element with atomic number 19 will most likely combine chemically with the element whose atomic number is 9 A. 17 B. 18 C. 21 D. 20 E. 16 2WVW 3390002 D 14 25085 51 018911671323 Which of the following elements does not react with oxygen to form an oxide? 9 A. hydrogen B. carbon C. sulfur D. chlorine 3390003 B 14 25087 31 0189 0006 An element which is never found free in nature is 9 A. carbon B. chlorine C. oxygen D. sulfur 3390004 A 14 25089 52 018900771323 Choose the element which forms the most acidic oxide: 9 A. B B. Al C. Ga D. Be E. Ca 3390005 C 14 25091 52 1446 Choose the strongest acid: A. H S B. H Se C. H Te D. H O 94 2 2 2 2 3390006 A 14 25093 52 080517781403 The halide ion with the highest hydration energy is: 0041 0041 0043 0043 0043 5 _ _ _ _ 9 A. F B. Cl C. I D. At . 3390007 B 14 25095 52 08080008 Which of the following is least soluble in water? A. NaF B. CaF C. AgF D. HF 94 2 0043 3390008 D 14 25097 52 08080008 Which of the following is most soluble in water? A. AgCl B. AgBr C. SrF D. SrCl 94 2 2 0043 3390009 A 14 25099 52 0007 0023 Which of the following is the most powerful oxidizing agent? A. F B. Cl C. Br D. I 94 2 2 2 2 0043 3390010 D 14 25101 51 00771455 Of the following acids, which is the strongest? A. H TeO B. H SeO C. H SeO D. H SO 94 2 4 2 3 2 4 2 4 0009 3390011 D 15 25103 52 117814350180 Which ion below would be expected to have the largest hydration energy? 5 _ _ _ _ 9 A. Br B. Cl C. I D. F 0019 3390012 C 15 25105 31 087900030263 The electron structure of the alkali metals indicates that A. they should be very ready to take on a single electron for each atom. B. in general, they should tend to form covalent compounds. C. they should not be found in the free condition in nature. D. lithium should be the most active of them. 9 E. all of them should be relatively inert. 0035 3390013 C 15 25110 52 019203370263 In chemical combination, a substance with an atomic number of 12 should readily A. acquire one electron. B. lose one electron. C. lose two electrons. D. acquire a valence of +4. 9 E. gain two electrons. 0035 3390014 D 0043 14 25113 31 037314480189 Of all the group II elements, the one with the highest oxidation potential is: 9 A. Li B. Be C. Ba D. Ra. 3390015 D 14 25115 52 1945 Of the following, the element possessing the highest combining power toward oxygen is 9 A. Si B. P C. S D. Cl 0056 3390016 D 14 25117 52 1947 Of the following metals, which one reacts most vigorously with cold water? 9 A. Zn B. Ca C. Na D. K 0058 3390017 B 14 25119 52 194703440348 Of the following, which is most reactive with cold water? 9 A. Na B. K C. Mg D. Ca 3390018 A 14 25121 52 1949 With increasing atomic number within the halogen family A. hydrides become more acidic B. hydrides become more stable C. the tendency to assume a positive oxidation state decreases 9 D. free halogens become stronger oxidizing agents 3390019 A 14 25125 72 19540238 Of the following, the weakest acid is 9 A. HF B. HCl C. HBr D. HI 0058 0060 0061 3390020 E 15 25127 72 196614680119 If equal volumes of 0.1 M thallium(I) dithionate and strontium formate solutions are mixed together nothing happens, but if equal volumes of zinc thiocyanate and thallium(I) formate are mixed, a white precipitate forms. The identity of the precipitate must be A. thallium(I) formate B. thallium(I) thiocyanate C. strontium dithionate D. zinc formate 9 E. The question does not contain sufficient information to decide STOR 3390021 C 14 25133 31 07250180 40 In a group of ions, the most strongly solvated would be the ion with A. the greatest charge and the largest radius. B. the smallest charge and the largest radius. C. the greatest charge and the smallest radius. MSU 9 D. the greatest charge and the largest radius. 4100001 D 14 25137 31 044500318004 The weight proportions in a equation are most conveniently expressed in terms of A. the molar volumes B. gram_atoms C. mole 9 D. grams 2 OS 4100002 C 14 25140 31 003105538004 In a balanced equation, the numerical coefficients arrived at in balancing the equation are identical with A. the molar volumes B. the number of gram _ atoms C. the number of moles of each substance 9 D. the specific gravity of each gas 2 OS 4100003 C 14 25144 31 003103928004 That which is excluded in a word equation is A. the substances which enter into the chemical reaction B. the substances which are produced by a chemical reaction C. the quantities of substances involved 9 D. an experimental fact or facts 2 OS 4100004 A 15 25148 32 081200180008 Which of the following symbols is used to designate NaCl dissolved in water? A. NaCl(aq) B. NaCl(l) C. NaCl(wat) D. NaCl(w) 9 E. None of these 0020 4100005 A 14 25151 31 0224 05 Hydrochloric acid is represented by which formula? A. HCl B. H O C. HeCl D. HClO 94 2 4 4100006 D 14 25153 32 0224 05 The formula NaNO represents which compound. 4 3 9 A. Sodium nitrotrioxide C. Sodium nitrite B. Sodium nitride D. Sodium nitrate 4100007 A 14 25156 32 0224 05 Magnesium bromide is represented by the formula A. MgBr B. Mg Br C. MgBr D. Mg Br 94 3 2 3 2 3 4100008 C 14 44461 32 0224 05 Potassium carbonate is represented by the formula A. P C B. P CO C. K CO D. K C 94 25 2 3 2 3 2 E. KCO 3 4100009 D 14 25160 32 0224 05 Potassium sulfide is represented by the formula A. P S B. K SO C. P SO D. K S 94 25 2 4 2 4 2 4120001 E 15 25162 31 03620812 Sb is the chemical symbol for the element? A. Suberium B. Tin C. Bismuth 9 D. Strontium E. None of these 0028 4120002 D 14 25164 31 13360224 In the formula H SO , the 4 indicates 4 2 4 A. 4 parts by weight of oxygen B. 4 parts by weight of sulfur and oxygen C. 4 atoms of sulfur and oxygen per molecule 9 D. 4 atoms of oxygen per molecule 0026 4120003 C 15 25168 31 08120189 The symbol for the element sodium is 9 A. So B. Sd C. Na D. S E. Nt 0020 4120004 B 15 25170 31 081213091310 Which of the following symbols is not derived from a Latin name? 9 A. Fe B. Ca C. Pb D. Ag E. K 0020 4120005 E 15 25172 31 018907971311 Elements are named after A. famous people B. planets c. Greek gods D. cities 9 E. all of these 0020 4120006 B 15 25174 31 08120189 The symbol for the element arsenic is 9 A. A B. As C. An D. Ar E. Ac 0020 4120007 E 0040 15 25176 31 018908120002 Consider the following set of five elemental symbols: Be, Na, P, S, Cl. It is correct that these symbols 44 11 15 16 17 stand for, respectively, the elements A. boron, nitrogen, phosphorus, selenium, chlorine B. beryllium, sodium, plutonium, sulfur, californium C. boron, sodium, phosphorus, sulfur, chlorine D. beryllium, nitrogen, plutonium, sulfur, chlorine 9 E. beryllium, sodium, phosphorus, sulfur, chlorine. 4120008 D 15 25182 31 018908120002 The elements sodium, chlorine, and beryllium have, respectively, the symbols A. S, C, B B. S, Cl, B C. Na, C, Be D. Na, Cl, Be 9 E. So, Cl, Be 0040 4120009 E 15 25185 31 033703510812 Which of the following pairs of symbols represent atoms which have the same atomic number? 5 7 7 10 10 10 7 A. X and X B. X and X C. X and X 4 4 2 4 5 4 3 0040 5 7 6 10 9 D. X and X E. X and X 4 4 5 4 4 9 4120010 B 15 25190 31 009703530812 Which pair of the following symbols represents atoms that contain the same number of protons? 5 7 5 10 11 A. X and X B. X and X 4 4 2 5 5 5 7 7 D. X and X 4 4 2 9 E. Both B anD D 10 7 C. X and X 3 4 0040 4120011 A 15 25195 31 034108120351 Which pair represents atoms that contain the same number of neutrons? 5 7 5 10 10 A. X and X B. X and X 4 4 2 4 5 5 10 10 D. X and X 94 8 4 0040 10 7 C. X and X 8 4 10 11 E. X and X 5 5 4120012 A 15 25200 31 081205870341 5 14 The number 14 in the notation N refers to the 4 7 A. mass number B. atomic weight C. number of protons in the nucleus D. number of neutrons in the nucleus 9 E. number of electrons in the nucleus. 0040 4120013 B 15 25204 31 009703410812 An atom contains 26 protons, 30 neutrons, and 26 electrons. For this atom it is true that A. Z = 30 and A = 26 B. Z = 26 and A = 56 C. Z = 26 and A = 30 D. Z = 56 and A = 30 9 E. Z = 56 and A = 26. 0040 4120014 B 15 25207 31 035305870812 An isotope has an atomic number of 30 and a mass number of 65. this means that the nucleus of the atom contains A. 65 protons and 35 neutrons B. 30 protons and 35 neutrons C. 30 neutrons and 35 protons D. 65 neutrons and 35 protons 9 E. 65 neutrons and 30 protons. 0040 4120015 B 15 25211 32 131603370065 A certain atom has an atomic number of 20 and an atomic weight of 41.0 amu. The number of electrons contained in this atom is 9 A. 41 B. 20 C. 61 D. 21 E. 60 0040 4140001 C 15 25214 52 071101 The formula of calcium nitrite, Ca(NO ) , indicates that for 0064 4 32 every one dozen calcium atoms there will be ____ dozen oxygen atoms. 9 A. 1 B. 2 C. 4 D. 5 E. 6 4140002 C 14 25217 31 022400668004 The simplest formula for a compound is called the A. correct formula B. molecular formula C. empirical formula 9 D. atomic formula 2 OS 4140003 B 15 25219 31 07040224 The total number of atoms in the molecular formula, C H N O 4 20 24 2 2 (quinine) is 9 A. 20 B. 48 C. 44 D. 1 E. none of these 0028 4140004 A 15 25222 32 07040224 Write the molecular formula for sodium pentothal, having 11 atoms carbon, 17 atoms hydrogen, 1 atom sodium, 2 atoms nitrogen, 2 atoms oxygen, and 1 atom sulfur in one molecule. A. C H NaN O S B. C H SON O S C. C H NaN O Su 4 11 17 2 2 11 17 2 2 11 17 2 2 0028 D. C H N O 94 11 17 2 2 E. none of these 4140005 E 15 25227 32 002007040202 5 3+ Determine the formula of the compound composed of aluminum (Al ) 5 2_ and sulfide ions (S ) A. AlS B. Al S C. AlS 94 32 2 D. Al S E. Al S 2 23 4140006 C 15 25231 32 002007040202 5 2+ Determine the formula of the compound composed of tin(II) (Sn ) 4 1_ and nitrate ions (NO ) 4 3 A. SnNO B. Sn NO 0028 C. Sn(NO ) D. SnN O E. None of these 0028 94 3 2 3 32 22 4140007 D 15 25236 32 002007040202 Determine the formula of the compound composed of Fe(III) 5 _ and Cl . A. FeCl B. Fe Cl C. Fe Cl D. FeCl E. None of these 94 2 3 3 0028 4140008 C 15 25240 31 022400770100 The correct formula for nitric acid is A. HNO B. HNO C. HNO D. HNO E. None of these 94 2 3 4 0028 4140009 B 15 25242 31 022400350797 The correct name for K CrO is 4 2 4 A. potassium chromite B. potassium chromate C. potassium dichromite D. potassium dichromate 9 E. none of these 0028 4140010 D 15 25245 32 022400380077 The correct formula for tin(IV) chlorite is A. Sn(ClO ) B. Sn(ClO ) C. Sn(ClO ) D. Sn(ClO ) 4 32 22 34 24 9 E. none of these 0028 4140011 E 15 25248 32 022400770035 The correct formula for lithium hypobromite is A. Li BrO B. Li BrO C. Li BrO D. Li BrO E. LiBrO 94 2 4 2 3 2 2 2 0028 4140012 B 15 25251 31 008207970006 The correct name for Cl O is 4 2 A. chlorine peroxide B. dichlorine oxide C. clorox 9 D. Dicarbon monoxide E. None of these 0028 4140013 D 15 25254 31 045508510224 The common name for sodium hydrogen carbonate is 9 A. slaked lime B. lye C. vinegar D. baking soda E. chalk 0028 4140014 B 15 25256 31 025102240018 The correct name for NaH PO is 4 2 4 A. sodium hydrogen phosphate 0028 9 B. sodium dihydrogen phosphate C. sodium dihydrogen phosphite D. sodium hydrogen phosphite E. sodium metaphosphate 4140015 D 15 25259 32 022405520351 In the formula for sugar, C H O , the 12 indicates 4 12 22 11 9 0020 A. the mass of carbon B. 12 parts by weight of C C. the atomic mass of C D. 12 atoms of C per molecule E. none of these 4140016 E 15 25263 32 053502240351 Ethyl alcohol has the formula CH CH OH. How many atoms of 4 3 2 hydrogen are contained in each molecule? 9 A. 3 B. 5 C. 4 D. 2 E. 6 4140017 D 15 25266 32 1321 C H O is not 426 A. the molecular formula for ethyl alcohol B. an empirical formula C. the molecular formula for an ether D. a structural formula 9 E. any of these 0020 0020 4140018 B 15 25269 32 022403511284 The formula Fe O represents which of the following 4 34 A. 3 grams of Fe combine with 4 grams O B. 3 atoms of Fe combine with 4 atoms O C. 3 atoms of Fe combine with 4 molecules of oxygen D. 3 moles of Fe combine with 4 moles of oxygen 9 E. none of the above 0019 4140019 C 15 25273 31 125401890351 In which of the following pairs do the compounds have the same number of elements as well as the same number of atoms? A. COCl and CoCl 4 2 2 0040 B. Na SO and K PO 4 2 4 3 4 C. NH Cl and BaSO 4 4 4 D. H PO and HClO 4 3 4 4 5 +3 +3 E. Cr(H O) and Cr(NH ) 94 2 6 36 4140020 D 15 25279 31 125407040351 In the formula H SO , the four indicates 4 2 4 9 0040 A. four parts by weight of oxygen in the compound B. four parts by weight of oxygen and sulfur in the compound C. four atoms of sulfur and oxygen per molecule in the compound D. four atoms of oxygen per molecule in the compound E. oxygen is the haviest atom in the compound. 4140021 E 15 25284 31 125401890066 The formula (AB ) CD for a compound conveys which of the 4 32 4 0040 following pieces of information: A. There are three different elements involved. B. There are nine atoms involved per formula unit. C. A and C are in a 1:1 ratio. D. A and B are both bonded to C E. AB is a structual unit 94 3 4140022 D 15 25289 32 019602241318 Which of the following compounds contains the same percentage of hydrogen as does C H ? 4 22 4 9 A. CH 4 B. C H 26 C. C H 24 0040 D. C H 66 E. No correct response is given. 4140023 D 15 25293 32 019602241318 In which of the following samples will the percentage of H be the 0040 greatest? A. 10 g C H 4 6 14 9 B. 20 g C H 6 14 C. 30 g C H 6 14 D. All samples have the same percentage of H E. No correct response is given. 4140024 D 14 25297 32 1702 One mole of H S contains: 4 2 A. two atoms of hydrogen B. two molecules of H S 4 2 9 C. 2 moles of hydrogen gas D. 2 moles of hydrogen atoms 0003 4140025 C 14 25300 32 0727 One gram of NaCl: A. is 58.448 moles of NaCl 5 _2 B. contains 1.71 x 10 g of Cl C. contains 0.393 g of Na 9 D. contains 0.607 gram_atom of Cl 0003 4140026 CDBEC 55 25303 32 0020 1290 MACROITEM STEM 2To answer the following questions, select from the key the 2appropriate valence. 2A. valence 2 2B. valence 3 2C. valence 4 2D. valence 5 0 E. valence 6 MACRO SUB_ITEM # 1 Pb in the formula PbO 4 2 1 MACRO SUB_ITEM # 2 N in N O 4 25 2 MACRO SUB_ITEM # 3 Cr in Cr O 4 23 3 MACRO SUB_ITEM # 4 S in SO 4 3 ETS2 OS 4 MACRO SUB_ITEM # 5 SiO in Na SiO 94 4 4 4 4140027 E 15 25308 52 071101 The formula, (NH ) HPO indicates that for every dozen combined 4 42 4 oxygen atoms in this compound, there are ____dozen combined hydrogen atoms. 9 A. 2 B. 1 and 1/4 C. 9 D. 8 E. 2 and 1/4 4141001 C 14 25312 31 056303518004 A radical is a group of atoms which A. has variable valence B. is never positive C. acts like a single atom 9 D. acts like a molecule 0064 2 OS 4160001 C 15 25314 52 03838003 Nitrogen pentoxide, N O , was prepared first in 1849 by passing 4 25 2WVW dry chlorine gas over heated silver nitrate. The "skeleton equation" for the reaction that occurs is (?)AgNO + (?)Cl ___> (?)AgCl + (?)N O + (?)O 4 3 2 25 2 Which set of stoichiometric coefficients correctly balances the equation? (?)AgNO + (?)Cl ___> (?)AgCl (?)N O (?)O 4 3 2 25 2 3 ________ ______ _______ _______ _____ 9 A. B. C. D. E. 2 2 4 3 16 1 4 2 2 8 2 2 4 3 16 1 4 2 2 8 1 1 1 2 4 4160002 B 14 25325 31 022400318004 How do you balance a formula equation? A. Adjust the subscripts in the formula B. Adjust the coefficients to the smallest possible whole number ratio C. Adjust the number of elements produced 9 D. Adjust an incorrect formula of a compound 2 OS 4160003 C 14 25329 52 094300311076 Which of the following chemical equations is balanced? A. Fe O + CO _____> 2Fe + 2CO 4 23 2 4 0041 B. Na S + SO _____> Na S O + S 2 2 223 C. 3CuO + 2NH _____> 3Cu + 3H O + N 4 3 2 2 94 D. 4Al + 3Fe O _____> 4Al O + 9Fe 34 2 4160004 D 14 25334 32 094300311076 Which of the following chemical equations is unbalanced? A. 2Hg + O _____> 2HgO 4 2 0041 B. 2H S + 3O _____> 2H O + 2 SO 4 2 2 2 2 4 4 9 C. Na O + H O _____> 2NaOH 2 2 D. SO + H O _____> H SO 2 2 2 4 4160005 C 15 25338 32 038308180031 If the equation Al (SO ) + BaCl _____> BaSO + AlCl is 4 2 43 2 4 3 correctly balanced, the coefficient of BaCl will be 4 2 9 A. 1 B. 2 C. 3 D. 4 E. 5 0018 4160006 E 15 25342 51 105109991070 Carbon monoxide, CO, an extremely toxic gas and one of the major air pollutants, can be oxidized to carbon dioxide, CO , by iodine 4 2 pentoxide, I O . consequently its detection and determination 4 25 are possible even in small quantities and when mixed with other gases. Balance the equation for this reaction in acid solution. I O +CO _____> I +CO 0018 425 2 2 What is the correct coefficient for CO when the equation is properly balanced(using smallest whole numbers)? 9 A. 1 B. 2 C. 3 D. 4 E. 5 4160007 B 15 44958 31 081807040383 If the equation, FeCl + AgNO _____> AgCl + Fe(NO ) 4 3 3 33 is correctly balanced, the coefficients that must be added to the equation would be 9 A. 1,1 B. 3,3 C. 2,2 D. 3,1 E. 1,2 0026 4160008 D 15 25353 32 130110760031 The numbers needed to balance the equation Al + Cl ____> AlCl 4 2 3 are A. 1, 3, 2 B. 2, 1, 2 C. 4, 3, 2 D. 2, 3, 2 9 E. None of these 0020 4160009 B 15 25356 52 1076 3Fe(s) + H O(g) ___> Fe O (s) + 4H (g) 4 2 34 2 0020 A. This is a balanced equation B. 4 H O's are needed to balance 4 2 C. This equation cannot be balanced D. To balance, 3H O's are needed 4 2 9 E. None of these 4160010 A 14 25360 31 107614190325 A balanced chemical equation shows A. The mole ratio in which substances react B. The direction a chemical system will move in and the extent of yield of the reaction C. The speed with which the reaction proceeds 9 D. The individual molecular steps by which the reaction occurs 0009 4160011 C 14 25364 32 141904070224 To write a chemical equation for a given reaction, you would need to know at least: A. The masses of the reactants and products in the given reaction B. The mole ratios of all reactants and products in the 0009 9 reaction C. The formulas of all reactants and products in the reaction D. All of the above 4160012 B 15 25369 32 14191076 Which of the following is a balanced chemical equation? A. H + O = H O 4 2 2 2 0019 B. Cu + Cl = CuCl 4 2 2 4 9 C. Ag + Cl = AgCl 2 D. All of the above E. None of the above 4160013 C 15 25373 32 081803830031 When the following equation is properly balanced, what is the sum of the coefficients of H O and Fe O ? 4 2 23 4 9 0040 Fe + H O _____> Fe O + H 2 23 2 A. 7 B. 8 C. 4 D. 5 E. 9 4160014 C 15 25377 32 038308180031 When the equation CaCl + Fe (SO ) _____> CaSO + FeCl 4 2 2 43 4 3 0040 is correctly balanced the number that appears before CaSO is 4 4 9 A. 1 B. 2 C. 3 D. 4 E. 5 4160015 B 15 25381 32 038308180031 Which of the following equations is balanced? A. 2NaHCO + 2HCl _____> 2NaCl + CO + 2 H O 4 3 2 2 B. Fe O + 3H _____> 2Fe + 3H O 4 23 2 2 C. 2KClO _____> 2KClO 0040 4 3 2 D. Na O + 2H O ____> 2NaOH + O 4 22 2 2 9 E. Both A and D. 4160016 E 15 25386 32 038308180031 The equation Na O + H O _____> NaOH + O , when correctly 4 22 2 2 balanced, appears as A. Na O + 2H O _____> 2NaOH + O 4 22 2 2 B. 2Na O + 2H O _____> 4NaOH + 2 O 4 22 2 2 C. 4Na O + 3H O _____> 4NaOH + 2 O 4 22 2 2 D. 3Na O + 2H O _____> 6NaOH + O 4 22 2 2 E. 2Na O + 2H O _____> 4NaOH + O 94 22 2 2 4160017 C 14 25393 52 1419 05 Which of the following equations is a balanced chemical equation corresponding to the statement "the diatomic elements hydrogen and bromine react to form hydrogen bromide?" A. H + Br = HBr C. H + Br = 2HBr 4 2 2 B. H + B = 2HB 4 2 2 9 D. H + Br = H Br 2 2 2 2 4160018 C 14 25398 52 1419 05 Which of the following statements corresponds to the equation 2Cs + Cl = 2CsCl. 4 2 A. Cesium chlorate is formed by the reaction of two atoms of cesium with one atom of chlorine. B. The reaction between cesium and chlorine produces cesium chlorate. C. Two atoms of cesium react with one molecule of chlorine to form two formula units of cesium chloride. 0040 9 D. Two molecules of cesium chlorite are formed by the reaction of two atoms of cesium with two atoms of chlorite. 4160019 C 14 25406 32 07041419 0540 According to the equation N + 3H = 2NH , 4 2 2 3 A. one molecule of nitrogen reacts with 3 atoms of hydrogen B. one molecule of nitrogen reacts with 3 moles of hydrogen C. one mole of nitrogen reacts with 3 moles of hydrogen 9 D. one atom of nitrogen reacts with 3 moles of hydrogen 4160020 C 14 25411 32 07041419 0540 According to the equation 2NH = N + 3H , one mole of 4 3 2 2 ammonia (NH ) decomposes to form 4 3 A. one mole of nitrogen C. one_half mole of nitrogen 9 B. one mole of hydrogen D. one_half mole of hydrogen 4160021 A 14 25415 32 07041419 0540 According to the equation 2NH = N + 3H , one mole of 4 3 2 2 ammonia decomposes to form A. 1.5 moles of hydrogen B. one mole of hydrogen C. one mole of nitrogen D. three moles of hydrogen 9 4160022 B 15 25419 32 07041419 0540 According to the equation 2Al + 6HCl = 2AlCl + 3H , 4 3 2 A. production of 2 moles of H requires 3 moles of HCl 4 2 B. production of 1 mole of AlCl requires 3 moles of HCl 4 3 C. production of 2 moles of H requires 2 moles of Al 4 2 E. production of 0.5 mole of AlCl requires 3 moles of HCl 4 3 9 4160023 E 15 25426 32 07041419 0540 According to the equation 2Al + 6HCl = 2AlCl + 3H , 4 3 2 A. 1 mole of HCl yields 1 mole of H 4 2 B. 1 mole of HCl yields 1 mole of AlCl 4 3 C. 2 moles of HCl yields 1 mole of AlCl 4 3 D. 2 moles of HCl yields 2 moles of H 4 2 E. 2 moles of HCl yields 1 mole of H 94 2 4160024 E 14 25433 51 1809 05 Which of the following is the correct net ionic equation for the reaction of silver nitrate and calcium chloride to form insoluble silver chloride? 5 + _ 2+ _ + _ 2+ _ A. Ag + NO + Ca + Cl ___> Ag + Cl + Ca + NO 4 3 3 5 2+ _ 2+ _ B. AgNO + Ca + 2Cl ___> AgCl(s) + Ca + 2NO 4 3 3 5 + _ 2+ _ 2+ _ C. 2Ag + 2NO + Ca + 2Cl ___> 2AgCl(s) + Ca + 2NO 4 3 3 5 + _ 2+ _ 2+ _ D. Ag + 2NO + Ca + 2Cl ___> AgCl(s) + Ca + 2NO 4 3 3 5 + _ 9 E. Ag + Cl ___> AgCl(s) MSU 4160025 C 14 25445 51 1809 05 Which of the following is the correct detailed ionic equation for the reaction of silver nitrate and calcium chloride to form insoluble silver chloride and calcium nitrate? 5 + _ 2+ _ + _ 2+ _ A. Ag + NO + Ca + Cl _____> Ag + Cl + Ca + NO 4 3 3 5 2+ _ 2+ _ B. AgNO + Ca + 2Cl ____> AgCl + Ca + 2NO 4 3 3 5 + _ 2+ _ 2+ _ MSU C. 2Ag + 2NO + Ca + 2Cl ____> 2AgCl + Ca + 2NO 4 3 3 5 + _ 2+ _ 2+ _ D. Ag + 2NO + Ca + 2Cl ____> AgCl + Ca + 2NO 94 3 3 4160026 C 15 25457 31 1809 05 When AgNO is added to a solution of MgCl , AgCl 4 3 2 precipitates. The detailed ionic equation which represents this reaction is 5 + _ 2+ _ 2+ _ A. Ag + NO + Mg + Cl ____> AgCl(s) + Mg + NO 4 3 3 5 + _ 2+ _ 2+ _ B. Ag + 2NO + Mg + Cl ____> AgCl(s) + Mg + 2NO 4 3 3 5 + _ 2+ _ 2+ _ C. 2Ag + 2NO + Mg + 2Cl ____> 2AgCl(s) + Mg + 2NO 4 3 3 5 + _ 2+ _ 2+ _ D. 2Ag + 2NO + 2Mg + 2Cl ____> 2AgCl(s) + 2Mg + NO 4 3 3 5 + _ 2+ _ + 2+ _ E. 2Ag + 2NO + Mg + Cl ____> AgCl + Ag + Mg + 2NO 94 3 3 MSU 4160027 B 15 25472 51 1809 05 MSU When solid CaCO is treated with a solution of KHSO , 4 3 4 gaseous CO is evolved. The detailed ionic equation which 4 2 represents this reaction is 5 + _ 2+ + 2_ A. CaCO + K + HSO ____> Ca + CO + H O + K + SO 4 3 4 2 2 4 5 + _ 2+ + 2_ B. CaCO + 2K + 2HSO ____> Ca + CO + 2K + 2SO +HO 4 3 4 2 4 2 5 + _ 2+ + 2_ C. CaCO + 2K + 2HSO ____> Ca + CO + K + H O + 2SO 4 3 4 2 2 4 5 + _ 2+ + 2_ D. CaCO + 2K + 2HSO ____> Ca + CO + K + SO +HO 4 3 4 2 4 2 5 + _ 2+ 2_ + E. CaCO + K + HSO 94 3 4 ____> Ca + SO 4 + 2K + H O 2 4160028 D 14 44685 31 1809 05 MSU Which of the following is the correct net ionic equation for the reaction of iron(III) bromide with KOH in water solution to form insoluble iron(III) hydroxide and potassium bromide? A. FeBr (s) + KOH ____> Fe(OH) (s) + KBr(aq) 4 3 3 5 3+ _ + _ + _ B. Fe (aq)+3Br (aq)+K (aq)+OH (aq)___>Fe(OH) (s)+K (aq)+Br (aq) 4 3 5 3+ _ + _ + _ C. Fe (aq)+3Br (aq)+3K (aq)+3OH (aq)__>Fe(OH) (s)+3K (aq)+3Br (aq) 4 3 5 3+ _ D. Fe (aq)+3OH (aq)____>Fe(OH) (s) 94 3 4160029 B 14 25496 51 1809 05 In water solution, strontium chloride reacts with potassium carbonate to form potassium chloride and insoluble strontium carbonate. The correct detailed ionic equation for this reaction is 5 2+ _ + 2_ 2+ 2_ + _ A. Sr + Cl + K + CO ____> Sr + CO + K + Cl 4 3 3 5 2+ _ + 2_ + _ B. Sr + 2Cl + 2K + CO ____> SrCO3 + 2K + 2Cl 4 3 3 2+ _ + 2_ + _ C. Sr + 2Cl + 2K + CO ____> SrCO + K + Cl 4 3 3 5 2+ 2_ D. Sr + CO ____> SrCO 94 3 3 MSU 4160030 C 15 25506 51 1809 05 Which of the following is a detailed ionic equation which represents the reaction of soluble CrCl with the hydroxide 4 3 ion to form insoluble chromium(III) hydroxide ? 5 3+ + _ _ + _ _ A. Cr + 3Na + 3Cl + 3OH ____> Cr(OH) + 3Na + 3Cl + OH 4 2 5 _ 3+ MSU B. 3OH + Cr ____> Cr(OH) 4 3 3+ _ + _ + _ C. Cr + 3Cl + 3Na + 3OH ____> Cr(OH) + 3Na + 3Cl 4 3 5 + D. CrCl + 2NaOH ____> Cr(OH) + 2Na 4 3 2 5 + _ 2+ _ _ E. CrCl + 3Na + 3OH ____> Cr + 2OH + 3Cl 94 3 4160031 D 15 25518 51 1809 05 Consider the equation 5 3+ _ _ Fe + 3Cl + 3NH OH ____> Fe(OH) (s) + 3Cl + 3NH 4 4 3 3 A. It is a balanced detailed ionic equation. B. It is a balanced net ionic equation. C. It is a net ionic equation, but it is not balanced. D. It is a detailed ionic equation, but it is not balanced. 9 E. It is a molecular equation. MSU 4160032 B 14 25524 51 1809 05 Which of the following is a correct detailed ionic equation for the reaction of magnesium and hydrochloric acid to form magnesium(II) chloride and hydrogen gas ? A. Mg + HCl ____> MgCl + H 4 2 2 5 + _ 2+ _ B. Mg + 2H + 2Cl ____> Mg + 2Cl + H 4 2 5 + _ C. Mg + 2H + 2Cl ____> MgCl + H2 4 2 2 5 + + 2+ _ + 9 D. Mg + 2H + 2Cl ____> Mg + 2Cl + 2H MSU 4160033 A 14 25532 51 1809 05 Which of the following detailed ionic equations describes the reaction of Li O with HCl ? 4 2 5 + _ + _ A. Li O(s) + 2H + 2Cl ____> 2Li + H O + 2Cl 4 2 2 5 + _ MSU 4 4 5 94 B. Li O(s) + 2HCl ____> 2Li + H O + 2Cl 2 2 C. Li O(s) + 2HCl ____> 2LiCl(s) + H O 2 2 + _ + _ + _ D. Li O(s) + 2H + 2Cl ____> 2Li + 2Cl + H + OH 2 4160034 B 15 25540 51 1809 05 Consider the equation 5 + 2_ + _ 2H O + Pb(s) + 2Na + CrO ____> PbCrO (s) + H + 2Na + 2OH 4 2 4 4 2 A. The equation is a net ionic equation. B. The equation is a detailed ionic equation. C. The equation is not balanced. D. This is not an ionic equation because PbCrO is not 4 4 written ionically. 5 + E. To be a detailed ionic equation, the Na must be 9 removed from both sides of the equation. MSU 4160035 C 15 25549 51 1809 05 Which of the following equations is of the detailed ionic type? 5 3+ _ A. 2Al + 6HCl ____> 2Al + 6Cl + 3H (g) 4 2 + _ B. 2Al + 6H + 6Cl ____> 2AlCl + 3H (g) 4 3 2 5 + _ 3+ _ C. 2Al + 6H + 6Cl ____> 2Al + 6Cl + 3H (g) 4 2 5 + 3+ D. 2Al + 6H ____> 2Al + 3H (g) 4 2 5 + _ 3+ _ _ 9 E. 2Al + 6H + 6Cl ____> 2Al + 6Cl + 6H MSU 4160036 D 15 25558 51 1809 05 Reaction of solid CaCO with hydrochloric acid, HCl, yields 4 3 gaseous CO . The net ionic equation is represented by 4 2 5 + _ + _ 2+ _ MSU 4 5 4 4 5 4 5 94 A. CaCO (s) + 2H + 2Cl ____> CO + H + OH + Ca + 2Cl 3 2 2+ 2_ + _ 2+ _ B. Ca + CO + 2H + 2Cl ____> CO + H O + Ca + 2Cl 3 2 2 C. CaCO (s) + 2HCl ____> CO + H O + CaCl 3 2 2 2 + 2+ D. CaCO (s) + 2H ____> CO + H O + Ca 3 2 2 + _ 2+ _ E. CaCO (s) + 2H + 2Cl ____> CO + H O + Ca + 2Cl 3 2 2 4160037 D 15 25570 51 1809 05 Consider the equation 5 + _ 2+ _ Ni(OH) (s) + H + I ____> Ni + I + H O 4 2 2 A. The equation is balanced as it is written. B. The equation is a balanced net ionic equation. C. The equation is a balanced detailed ionic equation. D. The equation is an unbalanced detailed ionic equation. E. To be a detailed ionic equation, the Ni(OH) (s) should 4 2 5 2+ _ be represented as Ni + 2OH and the equation 9 should be balanced. MSU 4160038 A 15 25579 51 1809 05 Consider the balanced equation 5 + _ 3H S + 2H + 2NO ____> 2NO(g) + 4H O + 3S 4 2 3 2 A. It is a net ionic equation. B. It is a detailed ionic equation. C. It is a molecular equation. D. It will be a detailed ionic equation if two Na+ ions are added to both sides. E. It will be a detailed ionic equation if 3H S on the 4 2 + 2_ 9 left side is replaced by 6H + 3S . MSU 4160039 D 15 25587 51 1809 05 Consider the following three balanced equations MSU 5 1. 4 5 2. 4 5 3. 9 + 2+ HgS + 2H ____> H S + Hg 2 2+ _ 2+ _ Cu + Hg + 2NO ____> Hg + Cu + 2NO 3 3 2+ _ + _ + + _ Cu + 2Cl + K + HS ____> CuS + K + H + 2Cl A. B. C. D. E. Equations 2 and 3 are net ionic equations. Equations 1 and 2 are net ionic equations. Equations 1 and 2 are detailed ionic equations. Equations 2 and 3 are detailed ionic equations. Equation 1 is a detailed ionic equation. 4160040 C 15 25596 51 1809 05 Which of the following is the correct detailed ionic equation for the reaction of potassium hydroxide and sulfuric acid to form potassium phosphate and water ? 5 + _ + 2_ + 2_ + _ A. K + OH + H + SO ____> K + SO + H + OH 4 4 4 5 + _ + 2_ + 2_ B. K + OH + H + SO ____> K + SO +HO 4 4 4 2 5 + _ + 2_ + 2_ C. 2K + 2OH + 2H + SO ____> 2K + SO + 2H O 4 4 4 2 5 + _ + 2_ + 2_ D. 2K + 2OH + 2H + SO ____> 2K + SO +HO 4 4 4 2 5 + _ + 3_ + 2_ + _ E. K + OH + 2H + PO ____> 2K + SO + H + OH 94 4 4 MSU 4160041 A 15 25609 51 1809 05 Consider the following equation 5 2+ _ + 2_ + _ Ba + 2Cl + 2Na + SO ____> BaSO + 2Na + 2Cl 4 4 4 A. It is a balanced detailed ionic equation. B. It is a balanced net ionic equation. C. It is an unbalanced detailed ionic equation. D. It is an unbalanced net ionic equation. 9 E. It is a molecular equation. MSU 4160042 D 15 25615 51 1809 05 Which of the following is the correct detailed ionic equation for the reaction of barium bromide with ammonium sulfate to form ammonium bromide and solid barium sulfate ? 5 2+ _ + 2_ 2+ 2_ + _ A. Ba + Br + NH + SO ____> Ba + SO + NH + Br 4 4 4 4 4 5 2+ + 2_ 2+ 2_ + B. Ba + 2br + 2NH + SO ____> Ba + SO + 2NH + 2Br 4 4 4 4 4 5 2+ _ + 2_ + _ C. Ba + Br + NH + SO ____> BaSO + NH + Br 4 4 4 4 4 5 2+ _ + 2_ + _ D. Ba + 2Br + 2NH + SO ____> BaSO + 2NH + 2Br 4 4 4 4 4 5 2+ _ + 2_ E. Ba + 2Br + 2NH + SO ____> BaSO + 2NH Br 94 4 4 4 4 MSU 4160043 D 15 25629 51 1809 05 Consider the following equation 5 3+ _ + _ Sb + 3Cl + H S ____> Sb S + H + 3Cl 4 2 23 A. It is a balanced net ionic equation. B. It is a balanced detailed ionic equation. C. It is an unbalanced net ionic equation. D. It is an unbalanced detailed ionic equation. 9 E. It is a molecular equation. MSU 4160044 B 15 25634 51 1809 05 Which of the following is the correct detailed ionic equation for the reaction of solid manganese (IV) oxide with hydrochloric acid to form manganese (II) chloride, chlorine gas and water ? 5 + _ 2+ _ A. MnO + H + Cl ____> Mn + Cl + Cl + H O 4 2 2 2 5 + _ 2+ _ B. MnO + 4H + 4Cl ____> Mn + 2Cl + Cl + 2H O 4 2 2 2 5 + _ 2+ _ C. MnO + 4H + Cl ____> Mn + Cl + 2H O 4 2 2 5 + _ 2+ _ MSU D. MnO + 4H + 4Cl ____> Mn + 4Cl + 2H O 4 2 2 5 + _ E. MnO + 4H + 4Cl ____> MnCl + Cl + 2H O 94 2 2 2 2 4160045 C 15 25646 51 1809 05 Consider the following equation 5 2+ _ + _ Cu + 2Cl + H S ____> CuS + 2H + 2Cl 4 2 A. It is a balanced net ionic equation. B. It is an unbalanced net ionic equation. C. It is a balanced detailed ionic equation. D. It is an unbalanced detailed ionic equation. 9 E. It is a molecular equation. MSU 4160046 B 15 44916 51 1809 05 MSU Which of the following is the correct detailed ionic equation for the reaction of barium nitrate with magnesium sulfate to form barium sulfate and magnesium nitrate ? 5 2+ _ 2+ 2_ 2+ _ A. Ba + NO + Mg + SO ____> BaSO (s) + Mg + NO 4 3 4 4 3 5 2+ _ 2+ 2_ 2+ _ B. Ba + 2NO + Mg + SO ____> BaSO (s) + Mg + NO 4 3 4 4 3 5 2+ _ 2+ 2_ 2+ 2_ 2+ _ C. Ba + NO + Mg + SO ____> Ba + SO + Mg + NO 4 3 4 4 3 5 2+ _ 2+ 2_ 2+ 2_ 2+ _ D. Ba + 2NO + Mg + SO ____> Ba + SO + Mg + 2NO 4 3 4 4 3 5 2+ _ 2+ 2_ 2+ 2_ E. Ba + NO + Mg + SO ___> Mg(NO ) (s) + Ba + SO 94 3 4 32 4 4160047 C 15 25664 32 071101 In the balanced equation for the oxidation of ammonia, ___NH + ___O = ___N O + ___H O 4 3 2 2 2 the coefficient for H O is 4 2 9 A. 1 B. 2 C. 3 D. 4 E. 5 0064 4160048 E 0064 15 25667 52 071101 The complete combustion of ethane, C H , yields carbon 4 26 dioxide and water as products as indicated in the equation, ___C H + ___O = ___CO + ___H O 4 26 2 2 2 The ratio of the number of molecules of O required 4 2 to molecules of ethane burned is 9 A. 1 B. 3/2 C. 2 D. 3 E. 7/2 4160049 C 15 44574 32 071101 ___Ag S + ___Al = ___Ag + ___Al S 4 2 23 For the reaction above, how many moles of silver atoms will be formed when one mole of aluminum atoms reacts? 9 A. 1 B. 2 C. 3 D. 4 E. 7 0064 4160050 B 15 25676 52 071101 Acetylene, C H along with the by_product Ca(OH) , is produced 4 22 by adding CaC to water. The coefficient preceding the formula 4 2 for water, H O, in the balanced equation is 4 2 9 A. 1 B. 2 C. 3 D. 4 E. 5 0064 4160051 E 15 25680 52 071101 The following reaction (unbalanced) is important in the recovery of gold from ores __Au + __KCN + __O + __H O = __KAu(CN) + __KOH 4 2 2 2 The balanced equation shows that for every molecule of 0 4 2 used, ___ atoms of gold reacted. 9 A. 1 B. 2 C. 2.5 D. 3 E. 4 0064 4160052 E 15 25686 52 071101 Under appropriate conditions, ammonia reacts with oxygen as represented by the following unbalanced equation __NH + __O = __NO + __H O 4 3 2 2 The ratio of the coefficients of NH /O in the balanced equation 4 3 2 would be 9 A. 2/1 B. 3/2 C. 1/1 D. 3/5 E. 4/5 0064 4160053 D 15 25691 52 071101 For the reaction (unbalanced) __Fe O + __NH = __Fe O + __N + __H O 4 23 3 34 2 2 the coefficients of NH and Fe O in the balanced equation would 4 3 34 be in the ratio _____, respectively. 9 A. 3/2 B. 1/2 C. 9/2 D. 1/3 E. none of these 4160054 E 15 45189 71 Which of the following equations is (are) NOT balanced? 1. ZnCl + NaOH ___> Zn(OH) + NaCl 4 2 2 2. Fe O + 2CO ___> 2Fe + 2CO 4 23 2 3. NH NO ___> N O + 2H O 4 4 3 2 2 9 A. 1 B. 2 C. 3 D. 1 and 2 E. 1,2 and 3 4160055 C 15 45193 71 Which one of the following equations is properly balanced? A. NH NO ___> 2H O + N 4 4 3 2 2 B. CH CHO + 3O ___> 2CO + 2H O 4 3 2 2 2 C. Sn + 4HNO ___> SnO + 4NO + 2H O 4 3 2 2 2 D. 2Na SO + 3Bi(NO ) ___> Bi (SO ) + 9NaNO 4 2 4 33 2 43 3 E. Na CO + 2H SO ___> Na SO + 2H + CO 94 2 3 2 4 2 4 2 2 4160056 E 15 45199 When the equation 71 __C H N + __N O ___> __N + __CO + __H O 4 282 24 2 2 2 is balanced, the sum of all the coefficients (simplest whole number) is: 9 A. 10 B. 11 C. 12 D. 13 E. 14 4160057 D 15 45288 71 Complete combustion of a 0.20 mol sample of a hydrocarbon, C H , 4 xy 0064 gives 0.80 mol of CO and 1.0 mol of H O. The molecular formula 4 2 2 of the original hydrocarbon is: A. C H B. C H C. C H D. C H E. C H 94 38 45 48 4 10 9 20 4162001 B 14 25696 31 039301138004 When gasoline or natural gas are burned completely the main products are A. carbon monoxide and carbon dioxide B. carbon dioxide and water C. water and carbon (soot) 9 D. carbon monoxide and water 2 OS 4162002 C 14 25699 31 080604078004 A product resulting from the reaction between calcium and water is A. hydrogen peroxide B. calcium oxide C. hydrogen 9 D. oxygen 2 OS 4162003 A 15 25701 31 116711591323 When potassium and oxygen react, the oxide most commonly formed is: A. K O B. K O C. KO D. KO E. None of these. 4 2 22 2 9 0042 4162004 B 15 25704 31 117811670236 Which pair of ions in solution exhibit the lowest molar solubility? 5 + _ 2+ _ A. Ag and NO B. Cu and OH 4 3 5 + 2_ 2+ _ + _ C. K and CO D. Ca and Cl E. Rb and I 4 3 9 0042 4162005 D 15 25708 52 080609431055 Which product is usually produced from the indicated chemical species. A. Sulfide ion when sulfur is oxidized B. MnO when KMnO is reduced in an acidic solution 4 2 4 C. Nitrogen oxide when concentrated nitric acid is used as an 0042 oxidant D. Water when an acidified solution of H O is reduced 4 22 E. Nitrogen dioxide when dilute HNO reacts with iron. 94 3 4162006 E 15 25715 32 022400180080 What is the formula of the salt which is formed by the neutralization of Al(OH) with sulfuric acid? 4 3 A. Al (SO ) B. AlSO C. Al SO 4 3 42 4 2 4 D. Al(SO ) E. None of these. 94 42 0042 4162007 B 14 25719 51 080606000083 A product of the thermal decomposition of sodium bicarbonate is: A. NaH B. CO C. NaHCO D. C H 94 2 3 22 0043 4162008 D 14 25721 51 002109770403 5 2_ Oxidation of S O by I yields: 4 23 2 0043 5 2_ A. SO 94 3 2_ B. SO 4 2_ C. S O 27 2_ D. S O 46 4162009 D 14 25724 51 009404071331 Colloidal sulfur may be produced by reaction between solutions of A. H S O and H SO B. Na S O and I 4 227 2 4 223 2 94 C. Na S and FeCl 2 2 0043 D. FeCl and H S 3 2 4162010 D 14 25728 31 116700250066 When rubidium is reacted with oxygen, the compound formed is: A. RbO B. Rb O C. Rb O D. RbO 94 2 22 2 0043 4162011 D 14 25730 52 013800870008 5 _ The OH concentration of a solution prepared by adding one mole of Na O to enough water to make one liter of solution is: 0043 4 9 2 A. 0.5 M B. 0.2 M C. 1.0 M D. 2.0 M 4162012 D 14 25733 52 00870236040751 A dilute solution of palladium(II) sulfate is mixed with a dilute solution of sodium iodide. A black precipitate results. The products of this reaction are 5 2+ _ A. Pd (aq) + I (aq) + NaI(s) B. I (aq) + SO (g) + PdNa (s) 4 2 2 2 5 + _ C. PdO(s) + Na (aq) + I (aq) + SO (g) 4 2 5 + = D. PdI (s)+Na (aq)+ SO (aq) 94 2 4 9000 4162013 B 15 25740 51 116700080219 Calcium carbide reacts with excess water to give A. acetylene + carbon monoxide B. ethyne + calcium hydroxide C. acetylene + coke D. ethene + calcium oxide 9 E. carbon dioxide and calcium hydride 0020 4162014 A 15 25743 32 131906000407 The general expression for a decomposition reaction is A. AB _____> A + B B. AB + C _____> AC + B C. AB + CD _____> AC + BD D. A + B _____> AB 9 E. AB + C _____> A + CB 0020 4162015 C 15 25746 32 022413240066 The predicted formula for a compound formed from magnesium and fluorine is A. MgF B. Mg F C. MgF D. Mg F E. None oF these 94 2 2 23 0020 4162016 A 15 25749 51 005604070008 Sulfuric acid will react with sugar to give carbon and A. water B. sulfur trioxide C. a hydrate 0020 9 D. sulfur dioxide E. none of these 4162017 C 15 25752 32 140901610968 Under conditions of constant temperature and pressure 1 liter of carbon monoxide (CO) and 2 liters of hydrogen (H ) react to 4 2 produce 1 liter of a compound. The simplest formula of the compound must be _______. A. CH O B. CH O C. CH O D. H O E. C H O 94 2 22 4 2 242 0019 4162018 D 14 25757 52 003104071171 The equation for the reaction of Ag CO , a water insoluble solid, 4 2 3 with a strong acid is best written as 5 + 2_ A. Ag CO (s) _____> 2 Ag (aq) + CO (aq) 4 2 3 3 5 2_ + B. CO (aq) + 2 H _____> CO (g) + H O 4 3 2 2 C. Ag CO (s) _____> Ag O(s) + CO (g) 4 2 3 2 2 5 + + D. Ag CO (s) + 2 H _____> 2 Ag (aq) + CO (g) + H O 94 2 3 2 2 0009 4162019 B 14 25765 32 003104070087 The net ionic equation for the reaction that occurs when solutions of AgNO and Na CO are mixed is 4 3 2 3 A. 2AgNO (aq) + Na CO (aq) _____> Ag CO (s) + 2NaNO (aq) 4 3 2 3 2 3 3 5 + 2_ B. 2Ag (aq) + CO (aq) _____> Ag CO (s) 4 3 2 3 5 + _ C. Na (aq) + NO (aq) _____> NaNO (s) 4 3 3 9 D. No reaction 0009 4162020 D 15 25772 32 035112840097 If an atom containing 3 protons and 4 neutrons combines with a second atom with 9 protons and 10 neutrons, the ion of the second atom will have 0035 9 A. 12 protons. B. 4 Protons. C. 10 Protons. D. 9 Protons. E. None of these. 4162021 B 15 45224 71 The net ionic equation for the acid_base reaction between formic acid and sodium hydroxide is A. HCOOH(aq) + NaOH(aq) ___> NaHCOO(aq) + H O(l) 4 2 5 + _ B. H (aq) + OH (aq) ___> H O(l) 4 2 5 _ _ C. HCOOH(aq) + OH (aq) ___> HCOO (aq) + H O(l) 4 2 5 + _ + _ D. H (aq) + HCOO (aq) + Na (aq) + OH (aq) ___> NaHCOO(aq) + H O(l) 4 2 5 + _ + _ + _ E. H (aq)+HCOO (aq)+Na (aq)+OH (aq)___>Na (aq)+HCOO (aq)+H O(l) 94 2 4162022 A 15 45235 71 All of the following are methods for making hydrogen chloride (hydrochloric acid), EXCEPT A. NaCl(s) + HaHSO (s) ___> Na SO (s) + HCl(g) 4 4 2 4 B. NaCl(s) + H SO (aq) ___> NaHSO (s) + HCl(g) 4 2 4 4 C. CH (g) + Cl(g) ___> CH Cl(g) + HCl(g) 4 4 3 D. H (g) + Cl (g) ___> 2HCl(g) 4 2 2 E. H O(l) + Cl (g) ___> HOCl(aq) + HCl(aq) 94 2 2 4164001 A 15 25776 52 1966 Chemicals DF and E F are produced from a chemical reaction 4 2 2 between D E and F . If one mole of E F is formed in this 4 26 2 2 reaction, how many moles of D E are consumed? 4 26 9 A. 0.33 B. 0.50 C. 1 D. 3 E. None of these CRNS 4164002 D 15 25781 52 1966 Octane burns in air according to the following unbalanced WKMN equation: C H + O ____> CO + H O 8 18 2 2 2 4 If 4 liters of liquid octane are completely oxidized, how many liters of carbon dioxide would be produced at STP? Density of 5 3 liquid octane is 0.703 g/cm . 9 A. 4.420 B. 552.5 C. 8682 D. 4420 E. 55.25 4164003 C 15 25787 32 00090094800113 Iron reacts with sulfur as in the equation, Fe + S___> FeS. The number of grams of FeS that can be obtained from 100 g of S is approximately 9 A. 57 B. 175 C. 275 D. 157 E. 36 ETS2 05 4164004 C 15 25790 72 01990200800113 About how many grams of glucose are formed in the process of photosynthesis if 2,031,000 calories of solar energy are absorbed? The equation for the photosynthesis reaction is as follows: (Assume 100% efficiency) 6CO + 6H O + 677,000 calories ___> C H O + 6O 4 2 2 6 12 6 2 ETS2 OS glucose 9 A. 180 B. 90 C. 540 D. 360 E. 720 4164005 C 15 25796 72 00420025800113 If 10.0 kg magnesium are burned with 10.0 kg oxygen to produce magnesium oxide as shown by the equation 2Mg + O ___> 2 MgO, the weight of magnesium oxide obtained is 4 2 9 A. 10.0 kg B. 8.3 kg C. 16.6 kg D. 33.2 kg E. 25.0 kg ETS2 OS 4164006 A 15 25801 72 02150209800113 The reaction of sodium hydroxide and hydrochloric acid is given by the equation NaOH + HCl ___> NaCl + H O. How many grams of 4 2 NaOH are needed to produce 100 g NaCl? (atomic weights Na, 23.0; O, 16.0; H, 1.0; Cl, 35.5) A. 68.4 g B. 52.3 g ETS2 OS 9 C. 30.8 g D. 23.4 g E. None of these 4164007 B 15 25806 72 02160209800113 Calcium carbonate reacts with hydrochloric acid as represented by the equation CaCO + 2HCl _____> CaCl + H O + CO . 4 3 2 2 2 If 20 grams of calcium carbonate are placed with 20 grams of hydrochloric acid, how many grams of hydrochloric acid will be left over at the close of the reaction? 9 A. 7.6 B. 5.4 C. 0.70 D. 3.7 E. 13 ETS2 OS 4164008 B 15 25812 52 00140216800113 The equation for the preparation of carbon dioxide is CaCO + 2HCl _____> CaCl + H O + CO 4 3 2 2 2 ETS2 OS 100 73 111 18 44 where the numbers are proportional to the relative weights of the compounds. The number of grams of CO obtained from 25 grams 4 2 of CaCO is 4 3 A. 6.25 B. 11 C. 22 D. 44 9 E. None of these 4164009 B 15 25818 32 01970217800113 Given the equation CaO(s) + H O(l) ___> Ca(OH) (s) 4 2 2 the mass of CaO needed to produce 100 g Ca(OH) is 4 2 9 A. 31.1 B. 75.7 C. 100.0 D. 132.1 E. 162.2 ETS2 OS 4164010 A 15 25822 52 02160056800113 NaCl + H SO _____> HCl + NaHSO 4 2 4 4 How many grams of HCl can be prepared from 40 grams of NaCl? (Atomic weights Na = 23; Cl = 35.5; H = 1) A. 24.9 B. 5.1 C. 16.0 D. 4.1 ETS2 OS 9 E. 28.0 4164011 E 15 44934 52 02120014800113 Balance the equation below and answer the following question. ETS2 OS CH + O ___> CO + H O. 4 4 2 2 2 The volume of CO produced in burning 100 L methane is (both volumes 4 2 are measured under the same conditions) 9 A. 50 L B. 275 L C. 33.3 L D. 220 L E. 100 L 4164012 E 15 25831 72 02180196800113 The union of nitrogen and hydrogen with a suitable catalyst and the addition of heat produces ammonia according to the equation (atomic weight N=14, H=1) N (g) + 3H (g) ___> 2NH (g) /\H = _24 kcal 42 2 3 __ when 136 liters of ammonia are produced, the number of liters of nitrogen needed is A. 90.7 liters B. 112.0 liters C. 204.0 liters D. 272.0 liters 9 E. 68.0 liters ETS2 OS 4164013 D 15 25837 72 02190025800113 2C H (g) + 5O (g) ___> 4CO (g) + 2H O(l) 4 22 2 2 2 The statement below which is correct (all gases measured at STP) is A. 4 cc C H will react with 10 cc O to produce 4 cc liq. water. 4 22 2 B. 10 cc C H will react with 30 cc O to produce 24 cc CO . 4 22 2 2 C. 9 cc C H will react with 12.5 cc O to produce 18 cc CO . 4 22 2 2 D. 12.6 cc C H will react with 31.5 cc O to produce 25.2 cc CO . 4 22 2 2 E. 10 cc C H will react with 24 cc O to produce 20 cc CO . 94 22 2 2 ETS2 OS 4164014 A 15 25848 32 01960008800113 The reaction for burning hydrogen at a temperature high enough to give the product water in a gaseous state is given by the equation 2 H + O ___> 2H O. The number of liters of water vapor formed 4 2 2 2 ETS2 OS from 50 liters of hydrogen will be A. 50 B. 100 C. 150 D. 200 9 E. None of these 4164015 B 15 25853 52 00250196800113 If one unit volume of oxygen and two unit volumes of hydrogen are combined at high temperature, the number of unit volumes of water vapor (measured at the same T and P) obtained is A. One B. Two C. Three D. A small fraction of one unit volume 9 E. An indeterminate volume greater than three ETS2 OS 4164016 A 15 25858 52 02140025800113 The reaction for burning carbon monoxide may be shown by the equation 2CO + O ___> 2CO (C = 12; O = 16). The number of 4 2 2 grams of oxygen gas needed to produce 20 grams of carbon dioxide is most nearly A. 7.3 grams B. 11.4 grams C. 14.5 grams D. 3.6 grams 9 E. More data is necessary to answer this item ETS2 OS 4164017 D 15 25863 72 02140014800113 The reaction for burning carbon monoxide may be shown by the equation 2CO + O ___> 2CO . The number of liters of carbon 4 2 2 dioxide formed from burning 100 liters of carbon monoxide would be A. 150 B. 50 C. 200 D. 100 9 E. More data is necessary ETS2 OS 4164018 D 15 25867 72 01960016800113 The volume of hydrogen at STP produced by 0.27 g of aluminum (AW 27 and oxidation state +3) is A. 2.24 liters B. 3.36 liters ETS2 OS 9 C. 7.72 liters D. 0.336 liters E. None of these numbers 4164019 E 15 25870 72 02230025800113 Butane burns in air according to the unbalanced equation ETS2 OS CH + O = CO + HO 4 4 10 2 2 2 The volume (at S.T.P.) of oxygen required to burn 58 grams of butane is (in liters) 9 A. 44.8 B. 179.2 C. 89.6 D. 358.4 E. 145.6 4164020 D 15 25874 72 02120025800113 Consider the equation for the complete combustion of methane in oxygen: CH + 2O ___> CO + 2H O 4 4 2 2 2 The volume of oxygen required to burn 100 liters of methane is A. 20 liters B. 25 liters C. 100 liters D. 200 liters 9 E. 400 liters ETS2 OS 4164021 A 15 25879 52 07048003 If 1.00 g of Zn is to react completely by Zn + 2HCl___> ZnCl + H , at least___________ g of HCl must 4 2 2 be present. (At. Wt H=1.0, Cl=35.5, Zn=65.4) A. 1.12 g B. 2.00 g C. 2.24 g D. 3.00 g 9 E. 4.48 g 2WVW 4164022 E 15 25883 52 07048003 How much CaCO is required to produce 50 g of CaO, according 4 3 to the equation CaCO ___> CaO + CO 4 3 2 assuming all the CaCO reacts? 4 3 (At. Wt C=12, O=16, Ca=40) 2WVW 9 A. 0.89 g B. 2.8 g C. 28 g D. 62.5 g E. 89 g 4164023 A 15 25887 52 8003 If one gram of Zn is to react completely by Zn(s) + 2 HCl (aq) ___> ZnCl (aq) + H (g) 4 2 2 at least ______ grams of HCl must be present. 9 A. 1.12 B. 2.00 C. 2.24 D. 3.00 E. 4.48 2WVW 4164024 B 14 25891 32 019604048004 The complete combination of one liter of hydrogen with one liter of chlorine yields a gaseous product whose volume is A. 1 liter B. 2 liters C. 3 liters 9 D. 4 liters 2 OS 4164025 B 15 25894 52 002311670195 When 3.80 g of fluorine (F ) react completely with H , what 4 2 2 volume of HF gas is produced at stp? 5 _1 _1 (At. Wt. H = 1.0, F = 19.0; R=0.0820 liter atm mole deg ) A. 0.20 liter B. 4.48 liters C. 11.2 liters 9 D. 22.4 liters E. 44.8 liters 0042 4164026 E 15 25899 52 013811780236 5 _ The average concentration of Cl ions in human blood plasma is 0.10 molar. If a 10_ml sample of blood is assumed to precipitate only AgCl upon the addition of 0.050 molar AgNO 4 3 solution, how much AgNO solution must be added if we assume that 4 3 AgCl is completely insoluble? 9 A. 0.050 ml B. 0.10 ml C. 10 ml D. 15 ml E. 20 ml 0042 4164027 A 15 25905 32 002711670031 If one gram of Zn is to react completely by Zn + 2HCl _____> ZnCl + H , at least ______ grams of HCl must be 4 2 2 present. 0042 9 A. 1.12g B. 2.00g C. 2.24g D. 3.00g E. 4.48g 4164028 E 15 25908 32 055313551159 If 0.50 mole of Na PO is mixed with 0.30 mole of BaCl , the 4 3 4 2 maximum number of moles of barium phosphate which can be formed is: 9 A. 0.80 B. 0.50 C. 0.30 D. 0.15 E. 0.10 0042 4164029 B 15 25912 32 107618090407 In the completely balanced ionic equation for the reaction of metallic aluminum with excess hydrogen ions which one is one of the product terms? (Use only whole number coefficients) 5 3+ 3+ A. 6H B. 2Al C. 3H D. Al E. H 94 2 0042 4164030 C 15 25916 32 116700310806 If one liter of C H and 5 liters of O react according to the 4 38 2 0042 equation 4 C H + 5O <=====> 3CO + 4H O 38 2 2 2 and assuming that all products are in the gaseous state, then the products will occupy (under the same conditions) A. 1 liter B. 6 liters C. 7 liters 9 D. 8 liters E. It is impossible to tell. 4164031 B 14 25922 52 007700870045 5 2_ 2+ 3+ 3+ In acid solution Cr O will oxidize Fe to form Cr and Fe . 4 27 how many milliliters of 0.100 M K Cr O are required to oxidize 4 2 27 35.0 ml of 0.500 M FeSO ? 4 4 9 0043 A. 7.00 B. 29.2 C. 42.0 D. 175. 4164032 D 15 25927 52 116501280788 Heavy water has a molecular weight of 20 instead of 18 because it contains, in place of hydrogen, deuterium, a hydrogen isotope with mass number 2. which of the following is the same regardless of whether the water is heavy water or ordinary water? A. Density of the gas produced at the cathode in electrolysis 0044 9 of the water. B. Grams of gas formed when 0.100 mole of Ca (solid) is added to the water. C. Grams of water decomposed per faraday in the electrolysis of the water. D. Density of the gas produced at the anode in electrolysis of the water. E. Density of the gas produced when lithium is added to the water. 4164033 D 15 25936 52 0407 Consider the following hypothetical unbalanced reaction: Ni + S + O _____> NiSO 4 2 4 given: 12.0 grams of Ni, 0.404 moles of S, and 14.5 liters of O at STP, how many moles of NiSO can be prepared? 4 2 4 0044 14.5 22.4 12.0 A. ________ B. ________ C. .404 D. ____ 22.4 x 2 14.5 x 2 58.7 9 E. None of the above. 4164034 D 14 25942 32 10760031055351 Given the balanced equation 4NH + 3O _____> 2N + 6H O 3 2 2 2 9000 how many moles of N could be produced from 6 moles NH ? 4 2 3 9 A. 20 B. 6 C. 4 D. 3 4164035 B 14 25946 32 03980884040751 What mass Na CO (m.w. = 106) Will produce 10 liters CO 4 2 3 2 (measured at stp) in the reaction Na CO (s) + H SO (l) _____> Na SO (aq) + H O(l) + CO (g) 4 2 3 2 4 2 4 2 2 106 10 106 A. ____ grams B. 106 x ____ grams C. ____ grams 22.4 22.4 10 9000 22.4 D. 106 x ____ grams 10 9 4164036 B 14 25953 32 01950884040751 What volume of CO at stp could be prepared by the reaction of 4 2 9000 10.0 g of calcium carbonate with excess hydrochloric acid? CaCO (s) + 2HCl(aq) _____> CaCl (aq) + CO (g) + H O(l) 4 3 2 2 2 9 A. 1.12 liters B. 2.24 liters C. 3.36 liters D. 4.48 liters. 4164037 A 14 25958 32 05531167039851 If one mole of H and one mole of O are allowed to react, 4 2 2 according to the equation below, what is the maximum mass of H O 4 2 that could be produced? 2H (g) + O (g) _____> 2H O(l) 4 2 2 2 9 A. 18 grams B. 36 grams C. 54 grams D. 72 grams 9000 4164038 D 14 25963 52 04070795116751 Aluminum chloride may be prepared by the following reaction: 2Al + 3Cl _____> 2AlCl 4 2 3 how many grams of AlCl can be produced if 284 g Cl react 4 3 2 completely? 9 A. 284 B. 200 C. 227 D. 356 9000 4164039 D 14 25967 32 05530546088451 When one mole of pentane, C H , at STP, is burned completely in 4 5 12 oxygen, how many liters of CO at STP are produced? 4 2 9 A. 4.48 B. 11.2 C. 22.4 D. 112 9000 4164040 B 15 25970 52 040401680002 Suppose you have 78 gm of sodium,Na,and 200 gm of chlorine,Cl. What is the maximum amount of sodium chloride(39% Na and 61% Cl) that can be formed from this mixture? 9 A. 239 G B. 198 g C. 61 g D. 278 g E. None of these 0018 4164041 D 15 25974 32 079500250407 How many grams of oxygen would be produced from a reaction that gave 10 gm of hydrogen? 2H O _____> 2H + O 4 2 2 2 9 A. 32 B. 64 C. 16 D. 80 E. None of these 4164042 D 15 25977 52 00370043 The New York city police department seized a package that they suspected contained LSD (d_lysergic acid diethylamide,C H N O). 4 24 30 3 When the compound was combusted, the following reaction was expected: C H N O + 34O ____> 24CO + 15H O + 3NO 4 24 30 3 2 2 2 2 The crime laboratory combusted a 376 gm sample. If the sample were pure LSD, how many moles NO would have been produced? 4 2 9 A. 12 B. 6 C. 1.5 D. 3 E. None of these 0018 0018 4164043 C 15 25985 32 003103510407 The equation, N + 3H ___> 2NH , says 4 2 2 3 A. Three atoms of hydrogen react with each molecule of nitrogen B. Two molecules of product are produced from every molecule of hydrogen C. There are 6 atoms of hydrogen contained in the reaction products for every molecule of nitrogen which reacts D. A gram of nitrogen will react with 3 grams of hydrogen 9 E. None of the above 0020 4164044 D 15 25991 32 040700310943 The reaction represented by the chemical equation 2H + O ___> 2H O means that 4 2 2 2 0020 9 A. 4 atoms of hydrogen react with 2 atoms of oxygen to give 2 molecules of water B. 2 molecules of hydrogen react with 1 molecule of oxygen to give 2 molecules of water C. 2 molecules of hydrogen react with 2 atoms of oxygen to give 2 molecules of water D. All of the above E. None of the above 4164045 A 15 25997 52 040700310008 The reaction represented by the chemical equation 2H + O ___> 2H O means that 4 2 2 2 A. 4g of hydrogen react with 32 g of oxygen to give 36 g water B. 2 moles of hydrogen react with one mole of oxygen to give two moles of water C. 4 atoms of hydrogen react with 2 atoms of oxygen to give 2 molecules of water D. All of the above 9 E. None of the above 0020 4164046 C 15 26003 52 003107950553 S (s) + 8O (g) ___> 8SO (g) this equation says 48 2 2 A. One molecule of sulfur reacts with 8 moles of oxygen B. One mole of sulfur reacts with 8 molecules of oxygen C. 256.8 g of sulfur react with 8 moles of oxygen D. 256.8 g of sulfur react with 16 molecular masses of oxygen 9 E. None of the above 0020 4164047 A 15 26008 52 039811730302 How many grams of sulfur dioxide can be prepared from 50.0 g of sulfur when it is burned in an excess of oxygen? 9 A. 100 B. 150 C. 200 D. 50 E. 63 0020 4164048 A 15 26011 52 055311591332 How many moles of sulfur dioxide are formed when 4 moles of zinc sulfide are roasted in air? 9 A. 4 B. 1 C. 3 D. 2 E. none of these 0020 4164049 A 15 44631 52 005611670795 What is the theoretical yield in grams of zinc sulfate which can be made from 100 g of zinc metal and excess sulfuric acid? 9 A. 247 g B. 162 g C. 227 g D. 273 g E. 100 g 0020 4164050 E 15 26017 52 133100720196 How many grams of ammonia can be produced from 200 g of hydrogen? N + 3H ___> 2NH 42 2 3 9 A. 567 g B. 283 g C. 113.3 g D. 1133 g E. none of these 0020 4164051 A 15 26020 52 003105531331 Given the equation: 2Al(OH) + 3H SO ___> Al (SO ) + 6H O 4 3 2 4 2 43 2 0020 how many moles of aluminum hydroxide are needed to produce 684 g of aluminum sulfate? 9 A. 4 Moles B. 1 mole C. 3 moles D. 2 moles E. None of these 4164052 A 15 26024 32 116713351331 Ferric oxide reacts with carbon in a blast furnace to produce iron and carbon monoxide. Fe O + 3C ___> 2Fe + 3CO 4 23 How much iron can be produced from 63.9 g ferric oxide? 9 A. 44.7 g B. 89.4 g C. 55.8 g D. 22.3 g E. None of these 0020 4164053 B 15 26028 52 040711590398 In the reaction, CaCO ___> CaO + CO , sixteen grams of CaO was 4 3 2 formed. The mass of CO formed at the same time is 4 2 9 A. 8.8 g B. 12.6 g C. 20.4 g D. 11.2 g E. None of these 0020 4164054 B 15 26032 52 006603020031 The compound C H will burn in air to form water and carbon 4 6 12 dioxide. What number should be written in front of O in the 4 2 correctly balanced equation? 9 A. 3 B. 9 C. 14 D. 6 E. 12 0020 4164055 E 15 26036 52 003202860031 Forty grams of copper are heated with 4 grams of sulfur. The reaction goes to completion without loss of sulfur, as represented by the equation: 2Cu + S ___> Cu S 4 2 approximately how many grams of copper remain uncombined? 9 A. 4 grams B. 16 grams C. 32 grams D. 8 grams E. 24 grams 0020 4164056 D 15 26041 52 079500310113 How many grams of oxygen are needed to burn 88.0 g of propane gas according to the equation: C H + 5O ___> 3CO + 4H O 4 38 2 2 2 9 A. 640 g B. 900 g C. 160 g D. 320 g E. None of these 4164057 A 14 26045 32 007200