STSE #3 – Diamond Formation and Properties Diamonds are: - made of pure carbon (C); - formed deep within Earth’s upper mantle (150 km down so in the asthenosphere); - valued based on carats (1 carat = 0.2 grams and 1 carat is divided into 100 points); - found in an intrusive (plutonic) igneous rock called kimberlite; - more transparent than all other minerals; - harder than all other minerals; - extremely useful (e.g. drill bits for mineral industry, petroleum industry, and dentist profession); and - extremely good conductors of heat due to their high thermal conductance (good semiconductors). It is easy to process diamonds. Here is how you do it: - Roll the crushed ore over a greased table. The ore needs to be mixed with water. The diamonds will repel water and be attracted to the grease on the table. The water washes away all of the waste materials. Diamonds are not forever. Let me explain! - Diamonds may be the hardest mineral, but they are not the toughest mineral (fair to moderate ranking). There are areas of weak bonding in the crystal lattice of a diamond and as a result, the atomic arrangement of the carbons can change over time, particularly when the diamond has reached the surface and the pressure is greatly reduced. This happens over geologic time though! Facts about Conditions of formation: - Conditions have to be favourable (i.e. certain temperature and pressure conditions). - Graphite (also pure carbon) will be produced is temperature is below 600 degrees Celsius and pressure is below 4 gigapascal. - Such favourable conditions can be found in the upper mantle just below continental cratons. - A craton is the stable foundation of a continental landmass that is made of very old rocks. - Temperatures are not quite as high (so a little colder) in the upper mantle beneath cratons. - If temperature and pressure conditions are too high, then the diamonds could be destroyed. The SWEET SPOT! How do diamonds get to the surface? - Thick kimberlitic magmas called pipes force their way up through the upper mantle and cratons and picks up diamonds along their way. - Kimberlitic magmas are ultramafic in composition. - The process is explosive so the diamonds survive. - The expanding gases keep the pressures high. - Upward speed is between 10 and 30 km/h (otherwise graphite would form). - Pipes are carrot-shaped due to the fact that gases escape as they move upwards. CARROT-SHAPED! Expanding gases! Explosion. Kimberlite Annimation: http://www.bcminerals.ca/i/video/kimberl ite-anim.swf - Diamonds have also been found in association with subduction zones at convergent plate boundaries (plate subducts down below craton into upper mantle). - They get brought down into the upper mantle by subduction and get brought back to the surface by upwelling magmas (volcanoes). This occurs about 80 km down and at temperatures of about 200 degrees Celsius. Diamonds at the surface: - Look for kimberlite! It is rare and may or may not contain diamonds. - Kimberlite will look different from surrounding rock (i.e. host or country rock). - Look for indicator minerals such as garnet, olivine, ilmenite, diopside, and chrome pyrope. These form at the same conditions as diamond. The G10 garnet is very significant! - Kimberlite can be weathered and eroded so diamonds (and indicator minerals) can be found in fluvial and glacial environments. - It is hard to find kimberlites within stable cratons. Kimberlite weathers faster than surrounding host rock so looking for circular depressions is key! Lakes often form in these circular lows. Kimberlite pipe found by geophysical means. “Bulls-eye”! Kimberlite has been mined out, but you can see the circular depression. Diamond Properties: Property Category Formula Colour Cleavage Crystal Shape Fracture Toughness or Tenacity Hardness on Moh’s Scale Lustre Fluorescence Other Properties Diamond Native nonmetal Carbon (C) Colourless to yellow or brown, can sometimes be pink, orange, green, blue, or grey Octahedral (Perfect) Octahedral, spherical, or cubic Conchoidal (ropy) Fair to good 10 Adamantine (diamond-like) Exhibits fluorescence Good electrical insulator, good heat conductor, extremely low compressibility, nonreactive with most acids and bases, highly transparent, combustible if oxygen is available and temperatures are extremely high, high density, high specific gravity Structure of diamond Questions: 1. What possible igneous textures could the rock kimberlite exhibit given the location of crystal formation and cooling rate? _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 2. Determine the weight of the 3106 carat Cullinan Diamond in grams [1 carat = 0.2 grams]. 3. Could diamonds be discovered along mid-ocean ridges (e.g. MidAtlantic Ridge), located along divergent plate boundaries? Explain. _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 4. At which location would you expect to discover a kimberlite pipe? Explain your reasoning. A: the middle of the landmass of Australia B: the middle of the Pacific Ocean _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 5. Pretend you are a prospector with the Government of Newfoundland and Labrador and your job is to find diamonds in northern Labrador. Briefly describe two techniques or methods that you could use (or follow) to find them. _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 6. Predict the colour of the rock kimberlite to be based on its described composition. _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 7. List three indicator minerals and explain why they are given the term “indicator”. _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 8. Of all the properties of the mineral diamond, why should geologists not focus on colour? _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ How do geologists describe diamonds’ extremely low compressibility? _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ 9. 10. Explain how graphite (extremely soft carbon) could be formed instead of diamond (extremely hard carbon)? _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ _____________________________________________________________ Questions (Answers): 1. Most diamonds crystallize slowly deep inside Earth so the crystals are large. The kimberlite magma then explodes to the surface where it cools quickly, thereby causing crystallization of the remaining magma to occur quickly. The end result is large crystals (i.e. phenocrysts) surrounded by a fine-grained matrix (i.e. groundmass). This would be called a porphyritic texture. The other possibility is an aphanitic texture if the kimberlitic magma reaches the surface (becoming lava) (containing or not containing diamonds) whereby it cools quickly resulting in all small crystals. 2. Solution = 3106 carats X 0.2 grams = 621.2 grams. Remember that 1 carat = 0.2 grams. 3. No since there are no cratons along mid-ocean ridges. No cratons mean no locations for favourable conditions for diamond formation. Temperatures in the upper mantle would be too high (without cratons) and diamonds would be destroyed. There is also no subduction along divergent plate boundaries. 4. A: the middle of the landmass of Australia. This landmass comprises of a craton, which acts as its foundation. Beneath the craton in the upper mantle is where conditions are favourable for diamond formation. Kimberlitic magmas would pick up the diamonds on their ascent. In doing so, the kimberlitic magmas would create carrot-shaped pipes at various locations across the landmass. 5. (1) Use geophysical surveys and try to identify bull’s-eyes or round targets. (2) Try to locate from the air circular depressions (or lows) that are filled with water (i.e. lakes). (3) Look for indicator minerals, which are minerals that form at the same conditions as diamond. You could look for all of these minerals in fluvial and glacial environments (past and present) due to the fact that kimberlite rocks can also be weathered and eroded. 6. You would think that since kimberlite came from the upper mantle that it would be really dark in colour (similar to peridotite which is ultramafic). As the kimberlitic magma burns up through a continent, which is mostly granitic (i.e. felsic), you get a mixing of felsic magma with ultramafic magma. As a result, I would expect kimberlite to be intermediate in composition (i.e. mixture of dark and light minerals). Similar to diorite and Andesite. 7. Garnet, olivine, ilmenite, diopside, and chrome pyrope. All these minerals form at the same temperature and pressure conditions as diamond. So if you find these minerals around a kimberlite pipe or in a fluvial or glacial environment, then the chances are high that you could also find diamonds. 8. Colour is not a reliable physical property since trace impurities (i.e. elements) in the crystal lattice of a mineral such as diamond could cause the colour to vary/change. 9. Diamonds may be the hardest mineral on Earth; however, they are not the toughest (fair to moderate). This is due to areas of weak bonding in the crystal lattice. As a result, diamond has a low compressibility. 10. If temperature conditions are below 600 degrees Celsius and pressure conditions are below 4 gigapascals, then graphite (pure carbon) will form instead of diamond (pure carbon).