Supporting Information
Imide-Functionalized Naphthodithiophene Based
Donor-Acceptor Conjugated Polymers for Solar
Cells
Tanmoy Dutta, Yong Li, Aaron L. Thornton, Da-Ming Zhu and Zhonghua Peng*
pengz@umkc.edu
S1
Table of contents
Page
1. 1H and 13C NMR spectra of compounds 2–6……....…...…………………..…..…………S3-13
2. 1H NMR spectra of polymers.……………...……....………………….…………………S14-16
3. Optical properties of PDR.….……………...……....…………………………..……………S17
4. Optical properties of PBOR.….……………...……....……………………..……………….S18
5. Optical properties of PBH.….……………...……....…………………….…………….……S19
6. Picture of dilute solutions of polymers……...……....…………………………….…………S20
S2
~~
**
~~
*
~
*
Figure S1: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 2a (*solvent).
S3
*
~~
*
Figure S2: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 2b (*solvent).
S4
*
~
*
Figure S3: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 3a (*solvent).
S5
*
~~
*
Figure S4: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 3b (*solvent).
S6
*
~~
*
Figure S5: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 4a (*solvent).
S7
*
~~
*
Figure S6: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 4b (*solvent).
S8
~~
*
Figure S7: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 5a (*solvent).
S9
*
~~
*
Figure S8: 1H (top) and 13C (bottom) NMR (CDCl3, 298K) spectra of 5b (*solvent).
S10
*
Figure S9: 1H NMR (CDCl3, 298K) spectra of 6a (*solvent).
S11
*
Figure S10: 1H NMR (CDCl3, 298K) spectra of 6b (*solvent).
S12
*
Figure S11: 1H NMR (CDCl3, 298K) spectra of 6c (*solvent).
S13
~~
*
~~
*
Figure S12: 1H NMR(C2D2Cl4) of PBOR, top: spectra at 298K; bottom: spectra at 348K
(*solvent).
S14
~~
*
~~
*
Figure S13: 1H NMR(C2D2Cl4) of PBH , top: spectra at 298K; bottom: spectra at 348K
(*solvent).
S15
~~
*
~~
*
Figure S14: 1H NMR(C2D2Cl4) of PDR, top: spectra at 298K; bottom: spectra at 348K
(*solvent).
S16
a
Intensity (au)
Intensity (au)
b
200
300
400
500
Wavelength (nm)
600
400
500
600
Wavelength (nm)
700
Figure S15: (a) Excitation spectra of PDR in THF, black: emission wavelength at 531 nm; red:
emission wavelength at 600 nm. (b) Emission spectra of PDR in THF, black: exited at 404 nm;
red: excited at 432 nm.
S17
800
Figure S16: Dilution effects on the emission spectra of PBOR in THF (black: 10-5 M solution).
S18
Figure S17: Dilution effect on the emission intensity ratio of peaks at 524, 558 and 595 nm of
PBH (excited at 442 nm), black: 10-5 M solution in THF, red: 10-6 M solution in THF.
Intensity (au)
200
b
Normalized Intensity (au)
a
300
400
500
W avelength (nm)
600
400
500
600
700
W avelength (nm)
800
Figure S18: (a) Excitation spectra of PBH in THF, black: emission wavelength at 524 nm; red:
emission wavelength at 558 nm; green: excitation wavelength at 595 nm. (b) Emission spectra of
PBH in THF, black: exited at 442 nm; red: excited at 530 nm.
S19
Figure S19: 10-4 M solutions of the polymers. PDOR in chlorobenzene, other polymers in THF.
S20