Topic 5 Pollution Management Semester Exam Review Questions Answers Notes Ch. 5 – Part 1 5.1 – 5.2 Nature of Pollution. Detection pp. 217- 222 1. Is the spraying of pesticides on a field an example of point or non-point source pollution? Explain your answer. Non-point source as pollutant drains through soil into water bodies [1]/mixes with other pollutants [1]; is untraceable to a particular source [1]/blown by wind over large area [1]. Allow marks for a reasoned argument for a point source e.g. a single nozzle spray and a contact pesticide [2] 2. State and explain which type of pollution, point source or non-point source, is easier to identify, control and eliminate. point source pollution is easier to control and eliminate than non-point source pollution as the discharge can be treated or diverted/dealt with at source 3. State one human activity that may cause eutrophication and is an example of a point source of pollution. a pipe discharging domestic waste water/sewage/detergents (into the lake); 4. State one human activity that may cause eutrophication and is an example of non-point source pollution. run-off from farms/animal sewage/silage/fertilizers/run-off and erosion from cultivation; 1 5. What is BOD? Biochemical oxygen demand. Basically the demand for oxygen in a river by aerobic organisms 6. The BOD in a river at any point can be determined by what? - number of aerobic organisms at that point their rate of respiration 7. Why do organic pollutants cause a high BOD? Organic pollutants stimulates organisms that feed on the organic pollutant to break it down. In doing this the organisms respire and use up a lot of oxygen so the demand for oxygen ( BOD) is high. HIGH BOD = ORGANIC POLLUTION. 8. Why is photosynthesis a problem when measuring BOD? Because you only want to measure the demand of oxygen by aerobic organisms. If you allow photosynthesis it will increases oxygen in water and give artificially low BOD by raising the second measurement of DO 2 .So when you subtract ( DO1 – DO2) the over all BOD is artificially low. 9. List a 5 – step method to measure BOD: 5-step Method - BOD 1. Take a sample of water and measure volume. 2. Measure the oxygen level ( DO1) – should be HIGH 3. Place the sample in a dark place for 5 days ( lack of light prevents photosynthesis which would release oxygen and give an artificially low BOD) 4. After 5 days measure the DO2 again- should be LOW 5. The BOD is the difference between the DO ( DO1 – DO2) which shows how much O2 was consumed by the organisms over the 5 days NOT including O2 produced by photosynthesis. 6. HIGH BOD = HIGH ORGANIC POLLUTANTS = HIGH AMOUNT OF AEROBIC ORGANISMS stimulated by organic pollutants. 2 10. By looking at fig. 5.2 which has a higher tolerance for organic pollution, Tubifex or mayfly nymphs? Tubifex 11. Why is there less oxygen available in the water ( less DO) on warm days? Higher temp. decreases DO in water – O2 tends to “evaporate” due to gaining more kinetic energy from higher temp. 12. How do warm organic pollutants affect DO? Fish? Decreases DO. Decreases fish since they need more O to respire. 3 13. How and why does the population of Tubifex change close to the point source pollution of the organic pollutant and further down stream? Increases due to organic pollutant and feeds on the organic pollutant. Then it is decreases going down stream as the organic pollutant becomes less. 14. How and why does the population of mayfly nymphs change close to the point source pollution of the organic pollutant and further downstream? Decreases due to organic pollutant and increases down stream as organic pollutant becomes less. 15. Make sure you understand fig. 5.3 p. 221 4 5 16. Outline one method of indirect measurement using a biotic index, that would indicate that a lake is becoming eutrophic. measure the abundance and diversity of species upstream/downstream the abundance of low oxygen tolerant species (e.g. carp fish , Tubifex worms) would increase the abundance of high oxygen tolerant species (e.g. trout fish , may flies) would decrease 5.3 Pollution Management, DDT pp 223-230 17. What is DDT , what was it used for during WWII and after WWII? DDT – dichlorodiphenyltrichloroethane. Synthetic pesticide and persistant organic pollutant (POP) that was used during WWII to control lice, typhus and malaria via mosquitoes. Used after WWII as insecticide in farming. 18. Who is Rachel Carson, the name of her book and what did she claim? An American biologist , whose book “ Silent Spring” ( 1962) claimed that DDT was killing wildlife and could cause cancer in humans. 19. When was it banned? Several dates but by 1980 20. Explain bioaccumulation and biomagnification. Bioaccumulation – retention and build up of non-biodegradable chemicals in the body. Biomagnification – concentration of a chemical increases at each trophic level. Top predators may have concentrations of a chemical several million times higher than the primary producer. 21. What is the WHO ? world health organization 6 22. Fill in the blank: Farmers exposed to DDT have higher risk of ___asthma and ____diabetes. DDT may cause _liver __, _breast__ and __pancreatic__ cancer. In Ecuador the use of ____DDT___ ___increased___ and there was a 61% reduction of _____malaria___. 23. If a lake is sprayed with a non-biodegradable insecticide to kill mosquitoes, after a few years the highest concentrations of insecticide are most likely to be found in the D A. upper layers of the lake. B. tissues of the mosquitoes and other insects. C. tissues of the freshwater plants. D. tissues of predatory fish and fish-eating birds. 7 24. The figure below shows a simple aquatic food chain which has been exposed to a pesticide called DDT. Land progressive sequence Milk Meat Aquatic progressive sequence Humans, the ultimate accumulators Third carnivore (larger fsh) Grazing animals Second carnivore (larger fsh) First carnivore (larger fsh) Herbivore (smaller fsh) Grass DDT spray First accumulator (algae, water plants) Pollutant in molecular form [Source: Adapted from Goudie, A (1993) The Human Impact on the Natural Environment, Blackwell, p.219] (a) (i) State how many trophic levels are shown in the figure above. (ii) Identify which trophic level represents: Ans : 6 the producers the top carnivores producers = first accumulator/algae, plants/level 1 top carnivores = ultimate accumulators/humans/level 6 (iii) State and explain what may be happening to the concentration of pesticide in the food chain. 8 Bioaccumulation – retention and build up of non-biodegradable chemicals in the body. Biomagnification – concentration of a chemical increases at each trophic level. Top predators may have concentrations of a chemical several million times higher than the primary producer. pesticide becomes increasingly concentrated as you go up the food chain because each successive trophic level supports fewer organisms and so the pesticide becomes concentrated in the tissues (b) An estimated 1000 kg of plant plankton are needed to produce 100 kg of animal plankton. The animal plankton is in turn consumed by 10 kg of fish, the amount needed by a person to gain 1 kg of body mass. (i) Explain why the amount of biomass declines at each successive trophic level. 10% of energy is used in respiratory processes at each trophic stage and is lost as heat or waste (ii) Distinguish between a pyramid of biomass and a pyramid of productivity. pyramid of biomass represents biomass at a given time – SNAPSHOT whereas pyramid of productivity represents rate at which stocks are being generated over longer periods of time 9 5.4 Eutrophication pp. 230 – 237 25. Outline one method of direct measurement that would indicate that a lake is becoming eutrophic. measure nitrate/phosphate/turbidity levels repeatedly over a period of time measure turbidity by lowering a secchi disc into the water nitrate levels increase as input of nutrients increases/phosphate levels increase as input of nutrients increases/ turbidity increases as algae populations increase measure amount of dissolved oxygen/BOD or similar; 26. Outline one method of indirect measurement using a biotic index, that would indicate that a lake is becoming eutrophic. measure the abundance and diversity of species upstream/downstream the abundance of low oxygen tolerant species (e.g. carp fish , Tubifex worms) would increase the abundance of high oxygen tolerant species (e.g. trout fish , may flies) would decrease 27. What are the there main ways of dealing with eutrophication? changing human activities that produce pollution by using alternative types of fertilizers regulating and reducing pollutants – sewage treatment plants that reduce nitrates clean up restoration of lake by pumping mud out 10 28. Changing human activities. Know these : 29. Regulating and reducing pollutants. a) What does “ divert sewage effluent” mean? To divert sewage from body of water b) List 3 domestic campaigns used in Australia. 11 30. Clean up strategies. List the main clean up methods. 31. Prevention of eutrophication at the source. List basic ideas. 12 32. Describe and evaluate management strategies to restore a eutrophic lake. Describe: add aerators to the lake (to maintain survival of species) remove aquatic plants during their growing period dredge the mud from the bottom of the lake to remove nutrients introduce species of fish which consume algae; Evaluate: aerators are expensive to operate aerators do not reduce the pollution problem, so must be used continuously; aquatic plants which have been removed from the lake transfer the nutrient overload to another ecosystem; mud pumped from the lake transfers nutrient overload to another ecosystem; 33. Development of a tourist resort near a lake is proposed. Outline strategies for determining the environmental impact of the development on the lake. Environmental Impact Assessment/EIA/baseline study must occur before any development begins select biological (species diversity) biotic index to tes abundance of species in relation to pollution. Tubifex worms, may flies, carp fish ( low DO) and trout fish ( high DO). Compare DO and BOD. Select chemical (nutrient status) indicators to test : nitrates, phosphates. monitoring of the environment must continue at regular intervals during and after development 13 Notes Ch. 5 – Part 2 5.5 Solid Domestic Waste, Ozone pp. 238- 242 Know the following table 1. List 4 major types of solid household waste that is being recycled today by most countries. Which item is worth the most money? Material type Examples Organic material garden waste, food/kitchen waste, wood Paper newspaper, writing paper, packaging, cardboard, milk cartons Plastics soft drink bottles, plastic bags, plastic containers Glass jars, bottles, plate glass Metals steel cans, aluminium packaging and cans, copper pipes Household hazardous paint, dry cell batteries, car batteries, fluorescent light bulbs Miscellaneous ceramics (bricks, tiles etc.) rock, ash, soil 2. What are the main categories in how household waste is being separated – sorted at home? See table above 3. What does the government do ( depending on the country) to motivate and ensure that people are recycling waste? 14 IB general comments about recycling : incentives may be necessary to encourage householders to recycle rubbish; recycling is cheaper if householders sort their own waste; recycling will not continue if there is no demand for recycled goods Composting 4. Define composting – aerobic decomposition of BIODEGRADABLE material. 5. How does it help in terms of recycling? It recycles organic household waste into humus-like soil. It returns valuable nutrients to the soil. Landfills and Incineration pp. 240-241 – know all 15 16 IB Qs 6. Which of the following pairs are both examples of recycling? C Notes A. Manufacturing new aluminum cans from old ones; biodegradation of plastic bags B. Processing newspapers into toilet paper; breaking down of raw sewage in the oceans C. Converting used car tires to rubberized road surfaces; producing compost from organic waste D. Producing methane from landfill sites; incinerating plastics 17 7. The table below shows the different types of domestic waste and the amounts produced per capita each year in a city in a developed country. Material type Examples Waste produced per capita / kg yr–1 Organic material garden waste, food/kitchen waste, wood Paper newspaper, writing paper, packaging, cardboard, milk cartons 91.2 Plastics soft drink bottles, plastic bags, plastic containers 25.1 Glass jars, bottles, plate glass 23.9 Metals steel cans, aluminium packaging and cans, copper pipes 14.4 Household hazardous paint, dry cell batteries, car batteries, fluorescent light bulbs 1.9 Miscellaneous ceramics (bricks, tiles etc.) rock, ash, soil Total 188 10.2 354.7 [Based on Australian Bureau of Statistics data] (a) (a) Calculate the proportion of paper, glass, plastics and organic material combined as a percentage of total waste. (b) Outline and evaluate strategies for the management of the domestic waste in the table above. 100 × (91.2 23.9 25.1 188) = 92.5 %; (accept 92.0 to 93.0 %) 354.7 (b) Outline most of the waste generated can be recycled or composted some of the waste could be reused e.g. jars/bottles/textiles Evaluate composting and recycling would significantly reduce the amount of domestic waste going to landfill/combustion 18 the advantages of reducing landfill should be explained to householders incentives may be necessary to encourage householders to recycle rubbish recycling is cheaper if householders sort their own waste; recycling will not continue if there is no demand for recycled goods; 8. The diagram below shows amounts of waste being recycled or sent to landfill in Australia between 1993 and 2002. Key: 8 Waste to landfill Recycled materials 7 6 5 Mass/ ×105 tonnes 4 3 2 1 0 1993 1994 1995 1996 1997 1998 Year 1999 2000 2001 [Source: adapted from www.environmentcommissioner.act.gov.au/_data/assets/image/12231/graph2_03.jpg] (a) (b) (i) State, to the nearest hundred thousand tonnes, how much material was recycled in Australia during 2001. (ii) Explain why the amount of waste sent to landfill in Australia has remained relatively constant since 1994 despite the increase in recycling. (i) Outline two ways in which technology can reduce the amount of solid domestic waste that is sent to landfill within a country. 1 2 19 2002 (ii) (a) (i) Explain why the technological solutions you have described in part (b)(i) may still have negative environmental effects. 400 000 (tons) (ii) * total amount of waste produced has increased but a larger proportion is now recycled : reasons : as demand for goods increases people consume more economic/industrial growth so more waste produced increase in packaging over time some products cannot be recycled so will still have to be sent to landfill increase in population has lead to more consumption some people simply do not bother to recycle (b) (i) recyclable packaging (e.g. cartons/recycling bins/devices) transporting waste to other countries; incineration technology; manufacturing goods which can be recycled; (ii) collecting recycling still uses petrol/energy waste is sent elsewhere but still contributes to global economic footprint; incineration produces atmospheric pollutants; 20 5.6 Depletion of Stratospheric Ozone pp. 242- 248 Ozone and temperature : 10. Fill in the blanks : the ozone is found between approximately ___10____ to ___50_____ km with the highest concentration found between about __20___ and __30__ km. This is found mainly in the lower ___strato______sphere and causes the temperature to __increase_____ with a(n)_____increase_________ in altitude. IB Qs True or False : mark T or F . If false rewrite statement to make it true: 11. Ozone gas is increasing in the upper atmosphere through the action of CFCs – F ; decreasing 12. Ozone gas is increasing in the upper atmosphere because of global warming – F ; decreasing 13. Ozone gas is decreasing in the upper atmosphere because of the increase in the amount of nitrogen oxides produced by the combustion of fossil fuels – T see text p. 246 14. The formation of ozone involves the absorption of ultra-violet radiation – T see text p. 243 : UV radiation breaks down oxygen atoms to combine with O2 resulting in O3 = ozone. . 15. The type of ultra-violet radiation absorbed by the ozone layer does not affect living organisms – F does affect 16. Chlorofluorocarbons in the stratosphere are rapidly broken down allowing them to escape into the outer atmosphere – F p. 244 : rapidly broken down by UV radiation in stratosphere allowing them to release Halogen atoms ( Cl, F and Br). 21 17. True or False : Ozone is destroyed by carbon dioxide released by burning fossil fuels – F nitrogen oxide. 18. The ozone layer can be protected by B I. using substitutes for ozone-depleting chemicals. II. reducing cattle production. III. recycling old refrigerators. A. I and II only B. I and III only C. II and III only D. I, II and III 22 19. The figure below shows the mean October ozone concentrations recorded at the Halley research station, Antarctica, over a 45 year period. 350 300 250 200 Dobson units 150 100 50 1950 1960 1970 1980 1990 2000 2010 Year [Source: J Shanklin, British Antarctic Survey, in Climate Change, 2001, Royal Society of Chemistry] (a) (i) Describe the trend in ozone concentration in the figure above. (ii) Suggest reasons for the trend you have described in (a) (i). (b) Outline the role of ozone in the absorption of ultraviolet (UV) radiation. (c) State one negative consequence to humans of exposure to UV radiation and one negative consequence to plants. Humans Plants (d) Outline three methods of reducing the quantity of ozone depleting substances in the environment. 1 2 23 3 ANSWERS : (a) (i) ozone concentration has declined (ii) increase of halogenated gases – CFCs in the atmosphere inhibiting the production of ozone. (b) UV radiation passing through the Earth’s upper atmosphere is absorbed by the formation and destruction of ozone. (c) humans: genetic mutation/skin cancer/cataracts/impaired immune system. plants: reduced photosynthesis/reduced crop yield due to cell damage. (d) use inert gases in refrigeration units do not use halogenated organic gases - CFCs to blow insulation foam recycle harmful gases dispose of appliances such as refrigerators safely (removing gas) setting national and international limits on halogenated organic gases - CFCs 24 Notes Ch. 5 – Part 3 1. What are the common names for the troposphere and stratosphere? Lower atmosphere , upper atmosphere 2. What is the difference between ozone found in the troposphere versus that found in the stratosphere? ( include how each is formed in your explanation) Ozone in troposphere is a pollutant and forms as a result of pollution by volatile organic compounds ( VOC’s) , hydrocarbons and nitrogen oxides ( NOx ) Ozone in stratosphere is considered a protective layer against UV radiation. It is formed by sunlight ( UV radiation) splitting oxygen molecules into atoms which regroup to form ozone. 3. What does VOC stand for? How do they react? List some examples. volatile organic compounds – evaporate into gases and take part in photochemical reactions. Methane, ethane and alcohol. 4. Nitrogen Oxides : remember that these can also deplete ozone ( ODS – ozone depleting substances) in the stratosphere ( upper atmosphere) although they help form the ozone in the troposphere ( lower atmosphere). 5. Use the following to explain the reaction that causes urban haze commonly known as smog: fossil fuel, nitrogen monoxide, oxygen, and nitrogen dioxide. Fossil fuels burn and produce nitrogen monoxide. Nitrogen monoxide reacts with oxygen in the air to produce nitrogen dioxide a brown gas that contributes to urban haze – smog. 6. List damage done by tropospheric ozone on crops and humans: damages crops, irritates eyes, causes breathing difficulties, susceptibility to infection. It is highly reactive and can attack fabrics and rubber materials. Can cause up to 15% reduction in lung capacity in children born and raised in areas of high level of ozone. 25 7. Photochemical smog is formed when primary pollutants interact with which of the following? D A. Water vapour B. Heat C. Oxygen D. Sunlight 8. Which factor greatly increases the likelihood of photochemical smog forming over a city? C A. Low altitude B. High rainfall C. Thermal inversion D. Short daylight hours 9. Which statement about photochemical smog is correct? Notes and test D A. Photochemical smog is independent of local topography and climate. B. Photochemical smog is a mixture of snow and rain formed when the upper air temperature is below freezing. C. Photochemical smog results from the meeting of two air streams in areas of low pressure. D. Photochemical smog is a mixture of pollutants formed under the influence of sunlight. Know the Following: Major Green house gases : water vapor, CO2 , nitrous oxide, methane, CFCs and ozone. 10. What is the difference between dry deposition and wet deposition? Explain using examples. 26 11. Explain the formation of acid rain. 27 Effects of Acid Rain 12. List the characteristics of an acidified lake 13. How does acid rain cause high levels of mercury or aluminum in fish? How can this harm humans? 14. Explain the effect ( in detail) of acid rain on coniferous trees and subsequent loss of NEEDLES: 28 15. Define leaching In general, leaching is the extraction of certain materials from a carrier into a liquid (usually, but not always a solvent). Specifically, it may refer to: Leaching (agriculture), the loss of water-soluble plant nutrients from the soil Acid rain leaches calcium and other nutrients - minerals form the soil 16. Explain why the effects of acid rain are regional rather than global. In other words, areas affected by acid rain have what in common? Done for you: These areas are usually around industrialized cities They are DOWNWIND of dense concentrations of fossil- fuel power stations, smelters ( steel mills) and large cities. They have high rainfall They have lots of forests, streams and lakes They have thin soils The main trend in the distribution of acid deposition is due to increased sulfur emissions in newly industrializing countries ( NICs) and in developing countries. In China, the worst affected areas have been in the south – the Pearl River Delta. In South Africa, coal-burning power stations and large metal working industries are concentrated in the Eastern Transvaal Highveld. 29 Management of Acid Deposition – Know the following: Add chalk - limestone ( Calcium carbonate) to neutralize acid rain in lakes 30 17. Which of the following is not a result of acid deposition from burning of fossil fuels? D notes A. Leaching of calcium from soils B. Death of coniferous trees in forests C. Killing of fish due to high levels of aluminium in lakes D. Thermal expansion of oceans 18. Lime was put into Scandinavian lakes in the 1980s as A notes A. a response to acid rain from the combustion of fossil fuels in other European countries. B. an attempt to replace nitrogen lost by excessive harvesting of fish. C. an attempt to combat eutrophication caused by excessive local use of fertilisers. D. a waste product from local industrial processes 19. Which method would be most effective in reducing the acidity of rain downwind of a coal-fired power station? C notes A. Burning high sulfur coal B. Increasing the temperature at which fuel is burned C. Fitting wet scrubbers (filters) to chimneys D. Converting the power station to burn high sulfur oil 31