Name: Period: Chemistry Unit 2 – Atomic Structure Matter has definite structure that determines characteristic physical and chemical properties: Apply an understanding of atomic and molecular structure to explain the properties of matter, and predict outcomes of chemical reactions. Chemistry Daily Journal What do I need to accomplish today? Today’s Date What do I need to finish up at tonight at home? Chemistry Course Objectives: 1. Count the number of protons, neutrons, and electrons in any given isotope (DOK 1-3). 2. Calculate the average atomic mass for an element with more than one isotope (DOK 2-3). 3. Justify modifications to a scientific theory when new evidence is discovered (DOK 1-3). Objective Learning Opportunities Due Date □ Podcast 3.1 Basic Atomic Structure 2.1 Describe the number and type of subatomic particles in an atom 2.2 Recognize contributions various scientists have made to the development of modern atomic theory 2.3 Calculate mass number and average atomic mass Unit 2 Test □ □ Read p. 101-112, answer p. 112, 17-18 Drawing and making atom-The Fruity Pebbles Lab □ BioPoem – Introduction to a Scientist □ Atomic Structure Podcast: What is Matter Made Of Podcast: Discovering the Electron □ Podcast: Discovering the Nucleus □ Models of the Hydrogen Atom-PhET Simulation 08/29 □ □ 09/02 □ Atomic Structure Quiz □ □ □ □ □ Podcast 3.3 Isotopes Read p. 112 – 117, answer p. 113, 19-20; p. 117, 23-24 □ Unit 2 Review and Test Isotopes and Average Atomic Mass Beanium Lab Quiz on Atomic Structure and Isotopes 09/05 09/09 SCALE: Structure of the Atom 4 – SWBAT Differentiate between isotopes of the same element, ions and/or atoms of different elements to identify atomic number, mass number, and the numbers of protons, neutrons, and electrons using both symbols and models. Given graphical data about isotopes, analyze the average atomic mass for any given element. Examples: 128 2− 52𝑇𝑒 3 – SWBAT Differentiate between isotopes of the same element and/or atoms of different elements to identify atomic number, mass number, and the numbers of protons, neutrons, and electrons using both symbols and models. Given data about isotopes, analyze the average atomic mass for any given element. Examples: 89 39𝑌 2 – SWBAT Using mass number and atomic number, give the number of protons, electrons, and neutrons in isotopes and/or atoms. Given data about 3 or fewer isotopes, calculate the average atomic mass for any given element. 1 – SWBAT With help, Ss are able to use mass number and atomic number to determine the number of protons, electrons, and neutrons in isotopes and/or atoms. Given data about 2 or 3 isotopes, calculate the average atomic mass for any given element. 0 – Even with help, Ss are not able to use mass number and atomic number to determine the number of protons, electrons, and neutrons in isotopes and/or atoms. Given data about 2 or 3 isotopes, calculate the average atomic mass for any given element. SCALE: Modifications to the Atomic Theory 4 – Justify the modifications to atomic theory by evaluating implications of each of the historical experiments that led to our current understanding of atomic structure, including but not limited to: John Dalton, Antoine LaVoisier, JJ Thomson, Ernst Rutherford, Max Planck, Niels Bohr, Louis DeBroglie, and Erwin Schroedinger. 3 - Using a variety of experimental data, explain how and why our ideas of relative size, charge, and location of protons, neutrons and electrons have been modified from the ancient Greeks to the Bohr Model. 2 – Describe how ideas of relative size, charge, and location of protons, neutrons and electrons change because of the Plum Pudding Model, the Gold Foil Experiment, and the Bohr Model. 1 – With help, Ss can describe how ideas of relative size, charge, and location of protons, neutrons and electrons change because of the Plum Pudding Model, the Gold Foil Experiment, and the Bohr Model. 0 - With help, Ss are not able to describe how ideas of relative size, charge, and location of protons, neutrons and electrons change because of the Plum Pudding Model, the Gold Foil Experiment, and the Bohr Model. Drawing and Making Atoms – The Fruity Pebbles Lab Purpose: To use information from the periodic table to draw box and Bohr representations of atoms. Materials: Periodic Table, pencil, paper, cereal Procedure: 1. Use your periodic table to determine the name of the element. 2. The atomic number indicates the # of protons in the nucleus. It also gives the number of electrons in a neutral atom. 3. The atomic mass gives the # of protons plus the average # of neutrons in the nucleus. (Ex: Round atomic mass to nearest number, then subtract that by the atomic number to get the number of neutrons in the nucleus) 4. Remember that electrons exist in energy levels around the nucleus. The 1st energy level holds 2 electrons, 2nd level holds 8, and 3rd level holds 8. Box Diagram example of Argon: 18 Represents atomic # 2 Ar Represents atomic mass Represents electron energy levels 8 8 Represents atomic symbol 39.948 Ar From the information in the periodic table you can create a 2-D model of what an atom looks like called the Bohr model. This model shows the nucleus with the protons and neutrons, and it shows energy levels with electrons. _ _ _ + + + __ + ++ _ What element is this? + _ _ __ __ Fill in the box with the correct information. _ ___ ________________________________________________________________________________________________________________________ Oxygen: __ Drawing: __ Hydrogen: __ __ ___ __ Nitrogen: ____ ____ __ __ __ __ __ ___ ______ ___ Carbon: __ Drawing: ___ Chlorine: __ Drawing: __ Extra Credit: __ __ __ __ __ __ ___ ___ Magnesium: __ ____ __ ____ __ __ __ __ ___ __ Sodium: Drawing: Aluminum: Drawing: __ ___ Sulfur: ____ __ ___ __ ____ __ __ __ __ __ __ ___ ____ ____ Boron: Drawing: PhET Simulation Exploration – Models of the Hydrogen Atom http://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atom Overview One of the most tantalizing puzzles at the beginning of the 1900s for scientists was to describe the make-up of the atom. As I explained in class, light was used to investigate the make-up of the atom. In this activity, you will first observe a simulated light spectrum of hydrogen gas. This is the same spectrum that you observed in class. You will then look at spectra predicted by different models of the atom. The models you will test include: John Dalton’s Billiard Ball model J.J. Thomson’s Plum Pudding model Ernest Rutherford’s Classical Solar System model Niels Bohr’s Shell model Louis deBroglie’s Electron Wave model Procedure and questions 1. Explain why, with white light, the light photons passing up through the box have different colors. 2. Decide how you can distinguish between UV and IR photons. Record that information below. 3. Watch the photons carefully. Most of the light gun photons pass through the box of hydrogen unaffected. Occasionally a photon is absorbed by something in the ? box and a new photon of the same energy (color) leaves the box. Describe what is going on in the ? box. 4. Describe what is happening to the spectrum below. Include in your description the colors, estimated wavelengths, and relative numbers of stacked colored balls. These colored balls correspond to photons emitted by the ? box. 5. John Dalton proposed that an atom was simply a very tiny hard ball. To see this simulated, in the top left corner, switch from Experiment to Predict and highlight the Billiard Ball model. Describe what is happening below. 6. Below, sketch your idea of what the spectrum will look like for Dalton’s model. 7. Does the spectrum for the Billiard Ball model match that of the experimental (real) hydrogen spectrum? 8. Switch to Thomson’s Plum Pudding model, describe what is happening within the atom below. 9. Compare the Spectrometer snapshot of the Plum Pudding model to the Experiment. Does the spectrum for the Plum Pudding model match that of the real hydrogen spectrum? 10. Just for fun, switch to the Classical Solar System model. This was Rutherford’s model that assumes the atom is like our solar system. Describe what happens below. 11. Switch to the Bohr model. Describe what you see in the atom diagram. 12. Describe what you see in the energy level diagram 13. Describe how the atom diagram and energy level diagrams are related. 14. Click on the Spectrometer camera to take a snapshot of the Bohr model. Compare the snapshot of the Spectrometer of the Bohr model to the Experiment. How well does the Bohr Shell model spectrum match the experimental (real) hydrogen spectrum? Explain in detail. Luis de Broglie was the first atomic theorist to incorporate the ideas of Planck and Einstein that electrons can be both waves and particles. He developed the de Broglie hypothesis stating that any moving particle or object had an associated wave (wave-particle duality). De Broglie thus created a new field in physics called wave mechanics, uniting the physics of light and matter. For this he won the Nobel Prize in Physics in 1929. Among the applications of this work has been the development of electron microscopes. 15. Describe what is the same and different about the de Broglie and Bohr models of the hydrogen atom. 16. Compare the deBroglie Spectrometer to the Experiment. How well does the de Broglie Electron Wave model spectrum match the real hydrogen spectrum? 17. Describe what you see in the 3-D view. Atomic Mass of Beanium Purpose : To calculate the average atomic mass of the new element Beanium. Materials: Three or four different samples of beans, balance, pencil, and laboratory record sheet and weighing dishes. Procedure: 1) Obtain the sample of Beanium. 2) Separate the 3 or 4 isotopes (white beans, kidney beans, and brown beans etc) and count how many of each are present. Record this number on your data table below. 3) Measure the mass of each isotope as a group (each bean type is an isotope of the element Beanium). Record the data on your data table. 4) Fill in the rest of the information in the table according to the direction given in analysis section below. DataTable Kidney beans 1) Total mass 2) Number 3) Average mass (g) 4) Percent abundance 5) Relative abundance 6) Relative mass White beans Brown beans Totals Analysis: Using the experimental data, record the answers to the following questions. 1) Calculate the average mass of each isotope by dividing its total mass by the number of particles of that isotope. Record your data in the table. 2) Calculate the percent abundance of each isotope by dividing its number of particles by the total number of particles and multiplying by 100. 3) Calculate the relative abundance of each isotope by dividing the percent abundance from step 2 by 100. 4) Calculate the relative mass of each isotope by multiplying its relative abundance from step 3 by its average mass. 5) Calculate the atomic mass of all Beanium particles by adding the relative masses. This average mass is the average atomic mass of Beanium. 6) Explain the difference between percent abundance and relative abundance. What is the result when you total the a) individual percent abundances? And b) the individual relative abundances? 7) The percent abundance of each kind of bean tells you how many of each kind of bean there are in every 100 particles. What does relative abundance tell you? 8) Compare the total values for Rows 3 and 6 in the table. Why can’t the atomic mass in Row 6 be calculated the way the total for Row 3 is calculated? 9) Explain any difference between the atomic mass of your Beanium sample and that of your neighbor. Explain why the difference would be smaller if larger samples were used. Unit Two Review Questions 1. Match the following historical experiments with the significance of their results. ___ Ancient Greeks and philosophy A. Discovery of the small positively charged nucleus ___ 4 Tenants and Billiard Ball Model B. Discovery of the electron Determined that electrons were located in energy ___ Cathode Ray Tube Experiments and C. Plum Pudding Model levels. Proposed the first idea of the atom in the 4th ___ Gold Foil Experiment D. century BC. ___ The Photoelectric Effect and Bohr E. Proposed first modern version of the atomic theory Model 2. Complete the table for the following elements. Element Isotope Atomic Mass # of # of # of Hyphen or Ion Notation Number Number Protons Electrons Neutrons Notation Manganese 25 30 (Mn) Na-23 Sodium (Na) 9 10 Bromine (Br) 35 45 Barium Yttrium (Y) 81 89 39𝑌 Arsenic (As) 75 33 24 24 227 28 89 3. A sample of hydrogen is 99% 1H, 0.8% 2H, and 0.2% 3H. What is its average atomic mass? 16. Write the isotope notation of the ion with 29 p+’s and 27e-’s. 17. Write the Isotope Notation for the ion with 27 p+’s , 32 no, and 25 e-’s. 18. How many protons, neutrons, and electrons are in 59Ni+2? 19. How many protons, neutrons, and electrons are in 140Ce+3?