msds for stampcrete high gloss clear sealer

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STAMPCRETE
CLEAR ACRYLIC SOLVENT BASE HIGH GLOSS CONCRETE SEALER
MATERIAL SAFETY DATA SHEET — 16 Sections
SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Identifier STAMPCRETE ACRYLIC HIGH
[WHMIS Classification]
GLOSS CLEAR SEALER
Health 2
Flammability 3
Reactivity 0
Product Use CLEAR COATING FOR SEALING
CONCRETE
Manufacturer’s Name Solvents & Petroleum Service,
Supplier’s Name
Inc.
STAMPCRETE
Street Address
325 Commerce Blvd
Street Address 1405
Brewerton Road
City Syracuse
Postal Code 13208
State New York
Emergency Telephone 800 315
City Liverpool
Postal Code 13088
State New York
Emergency
4467
Telephone 800
451 9037
Date MSDS Prepared June 4, 2015
MSDS Prepared By
Phone Number 412 726
Erwin Ratajczak
2986
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients (specific)
Xylene, mixed isomers
%
40 to 60%
CAS Number
1330-20-7
LD
50
of Ingredient (specify
LC 50 of Ingredient (specify
species and route
species)
LD50 oral rat 4300 mg/kg
LC50 inhalation gas cat 9500
ppm
LD50 oral mouse 2119 mg/kg
LC50 inhalation gas rat 5000
ppm
Ethyl benzene
8 to 12%
100-41-4
LD50 dermal rabbit >5000
mg/kg
LD50 oral rat 3500 mg/kg
No data available
–2–
Cumene
0.22 to
0.3%
98-82-8
LD50 dermal rabbit 12300
LC50 inhalation vapor 10 g/m3
microliter/kg
LD50 oral rat 2.9 g/kg
LD50 oral rat 4000 mg/kg
Aromatic 100
10 to 20%
63231-510-6
LD50 oral rat >5g/kg
LC50 inhalation rat 1970
ppm/4 hours
SECTION 3 — HAZARDS IDENTIFICATION
Route of Entry
❐
❐
Skin
Skin Absorption
❐
Eye Contact
❐
Inhalation
❐
Ingestion
Contact
[Emergency Overview]
WHMISSymbols] Health 2
Flammability 3 Reactivity 0
Potential Health
Effects
Skin Contact:
Contact may cause
mild skin irritation
including redness,
burning, drying and
cracking of skin.
Continued exposure
may develop into
dermatitis
Skin Absorption:
Eye Contact:
Inhalation:
ingestion:
Solvents can
penetrate the skin
and cause
systematic effects
similar to those of
inhalation
symptoms.
Contact with eyes
may cause irritation
including burning,
watering and
redness.
High vapor
concentrations are
irritating to the eyes
and respiratory
tract. Also may
cause headache
dizziness and
drowsiness
Can cause gastrointestinal
Irritation, nausea,
Vomiting and
diarrhea
SECTION 4 — FIRST AID MEASURES
Skin Contact Thoroughly wash exposed area with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If irritation develops and
persists, seek medical attention.
Eye Contact: Flush with water for at least 15 minutes while holding eye lids apart. Get medical attention immediately
Inhalation: Move to fresh air. If required, give artificial respiration or administer oxygen by trained personnel. Avoid further over exposure. If symptoms persist, get medical
attention.
–3–
Ingestion: Do not induce vomiting unless advised by a physician. Call nearest poison control center or physician immediately.
Product Identifier
SECTION 5 — FIRE FIGHTING MEASURES
Flammable
If yes, under which conditions?
❐Yes
Vapor concentrations in enclosed are may ignite explosively. Product may ignite if
heated in excess of it flash point. Vapors may travel to source of ignition and flash
back. Closed containers may burst when exposed to extreme heat Empty containers
may contain ignitable vapors.
Means of Extinction
For small fire use dry chemical powder extinguisher. For large fire, use alcohol foam water
spray or fog Cool containing vessels with a water jet in order to prevent pressure build up,
auto ignition or explosion.
Flashpoint (° C)
24 degrees C Closed cup 75.2 F
37.8 degrees C open cup 100 degree F
and Method
Auto ignition
400 degrees C
752 degrees F
Temperature (°C)
Upper Flammable
Lower Flammable
Limit (% by volume)
Limit (% by volume)
12.3%
1.9%
Explosion Data —
Explosion Data —
Sensitivity to Impact
Sensitivity to Static
Discharge
Hazardous
Combustion
Carbon monoxide, carbon dioxide and acrylic monomers
Products
[NFPA]
Health 2 Flammability 3
Reactivity 0k
SECTION 6 — ACCIDENTAL RELEASE MEASURES
Leak and Spill Procedures
Keep all sources of ignition and hot metal surfaces away from the spill or release. Use explosion proof non-sparking equipment. Stay upwind
from area. Isolate danger and keep nonauthorized personnel out. Stop source of leak or spill if possible with minimum risk. Prevent spill from entering sewers, storm drain or
any other unauthorized treatment system and natural waterways by diking ahead of the spill or leak. Always wear appropriate protective equipment including respiratory
protection. Spilled material may be absorbed with an appropriate spill kit. Notify fire authorities and appropriate federal, state and local authorities if required.
SECTION 7 — HANDLING AND STORAGE
Employees who come in contact with this material must be trained in accordance with 1910.1200 of the Hazard Communication Standard. Open container slowly to relieve any
pressure. Bond and ground all equipment when transferring from one vessel to another. Static charge can accumulate by flow and agitation. Ignition can occur by static
discharge. The use of explosion proof equipment is required. The use of respiratory protection is advised when concentration exceed any established exposure limits and in
confined spaces. Use good industrial and personal hygiene practice. Wash thoroughly after handling and do not wear contaminated clothing. Keep containers tightly closed. Use
and store in a cool dry and well ventilated areas away from heat. Post no smoking or open flame signs. Keep away from incompatible materials. Protect containers from physical
damage. Indoor storage should meet OSHA standards and appropriate fire codes. Empty containers from all residue, liquids and vapors. All containers should be disposed of in
–4–
an environmentally safe manner in accordance with all government regulations
SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limits ❐ ACGIH TLV
❐ OSHA TLV
Xylene ACGIH TWA 100ppm 8 hour
Xylene TWA 100 ppm 8 hours
TWA 434 mg/m3
TWA 435 mg/m3
STEL 150 ppm 15 minutes
STEL 651 mg/m3
Ethyl benzene ACGIH TWA 100 ppm 8 hours
TWA 100 ppm 8 hours
TWA 435 mg/m3
Aromatic 100 ACGH TWA 19 ppm 8 hours
STEL 100mg/m3
TWA100 ppm 8 hours
TWA 435 mg/m3
Specific Engineering Controls (such as ventilation, enclosed
process)
Personal Protective Equipment
Respiratory Protection: Engineering or administration controls should be implemented to reduce exposure. A NIOSH//MSHA approved respirator with organic vapor cartridge
should be used under conditions where airborne concentrations are expected to exceed exposure limits. Use a positive pressure air supplied respirator if there is potential for
uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection
Ventilation: If current ventilation are not adequate to maintain airborne concentrations below the established exposure limits, additional ventilation or exhaust systems may be
required. Where exposure mixtures may be present, explosion proof electrical systems safe for such locations must be used.
Protective Gloves: Prevent prolonged and repeated contact by wearing gloves impervious to solvents.
Eye Protection: Always wear safety glasses to reduce eye contact potential. Chemical goggles (ANSI Z87.1 or approved equivalent) are appropriate if splashing is likely. Eye
wash stations must be available where eye contact can occur.
Other Protective Clothing and Equipment: A source of clean water should be available for flushing skin Shower stations to should be available in case of larger spills.
Contaminated clothing should be laundered before reuse.
Work and Hygienic Practices: Efforts should be made to minimize contact and spills. Always wash hands before eating, drinking or smoking. Clean up spills promptly. Follow
OSHA and company guidelines.
–5–
Product Identifier
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
Physical State Liquid
Odor and Appearance Aromatic and clear liquid
Odor Threshold (ppm) Not measured
Specific Gravity 0.922
Vapor Density (air = 1) 3.8
Vapor Pressure (mmHg) 14.2 mm Hg @ 20
degrees C
Evaporation Rate Lower than n-butyl acetate
Boiling Point (° C) 143 to 147 degrees C
Freezing Point (° C) Not applicable
pH :Not applicable
Coefficient of Water/Oil Distribution Not measured
[Solubility in Water]
negligible
SECTION 10 — STABILITY AND REACTIVITY
Stablility: Stable under normal conditions
Conditions to Avoid: All possible sources of ignition
Incompatibility (materials to avoid): Avoid exposure to strong oxidizing agents and reducing agents
Hazardous Decomposition or BY Products: carbon monoxide, carbon dioxide and various oxides of carbon and nitrogen
Hazardous Polymerization: Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
This product contains ethyl benzene. A study conducted by the National Toxicology Program states that lifetime inhalation exposure of rats and mice to high concentrations of
ethyl benzene (750 ppm) results in increases in liver tumors in mice. These effects were not observed in animals exposed to concentrations of ethyl benzene (75 ppm or 250
ppm). The study does not address the relevance of these results to humans. Prolonged or repeated skin contact with this product tends to remove skin oils, possibility leading to
irritation and dermatitis. However, based on experience and available toxicological data, this product is judged to be neither a corrosive nor an irritant by OSHA criteria. This
product will cause eye irritation when in contact with eyes. This product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during
ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. This product is judged to have an acute oral LD50 (rat) greater than 5 grams per kilogram of
body weight and an acute dermal LD50 (rabbit) greater than 3.16 grams per kilogram of body weight.
SECTION 12 — ECOLOGICAL INFORMATION
This material is expected to be toxic to aquatic organisms. It may cause long term adverse effects in the aquatic environment.
This material is volatile and will partition rapidly in air. It is not expected to partition in sediment and waste water solids..
There is no significant transformation due to hydrolysis and phot
–6–
SECTION 13 — DISPOSAL CONSIDERATIONS
This is considered a RCRA hazardous waste due to the characteristics of D001 (ignitability). Waste is subject to land disposal restrictions in 40 CRF 268.40 and may require
treatment standards.
Consult state and local regulations to determine whether there are more stringent regulations than federal requirements.
Container contents should be completely used and containers empty prior to discarding. Container residue is considered a RCRA hazardous waste and must be discarded in
compliance with all applicable regulations. Larger empty containers such as drums, should be returned to a professional drum reconditioner. To assure proper disposal of smaller
empty containers, consult with state and local regulations and disposal authorities.
SECTION 14 — TRANSPORT INFORMATION
Special Shipping Information
Proper DOT Shipping Name
Combustible liquid. Not regulated in containers 119 gallons (450 liters) or less and ground transportation. For containers greater than 119 gallons or air transport:
UN1139, Coatings Solution, 3, III.
SECTION 15 — REGULATORY INFORMATION
Reportable Quantity (RQ), EPA regulation 40 CRF 302 (CERCLA Section 102: The RQ for xylenes is 100 pounds This product contains up to 60% XYLENE AND 20%
Aromatic 100 The RQ for ethyl benzene 1000 pounds. This product contains up to 15% ethyl benzene.
.Threshold Quantity (TPQ) , EPA regulation 40 CRF 355 (SARA Sections 301-304): No TPQ for product or any constituent greater than 1% or 0.1%
Toxic Chemical Release Reporting, EPA regulation 40 CFR 372 (SARA Section 313): This product contains up to 60% xylene, 20% aromatic 100 and 15% ethyl benzene
Hazardous Chemical Reporting, EPA regulation 40 CFR 370 (SARA Sections 311-312): EPA Classification Codes: Acute, Chronic, Fire.
Toxic Substances Control ACT (TSCA): This product does not contain polychlorinated biphenyls (PCB’s) All components of this product are listed on the U.S. TSCA
Inventory.
–7–
SECTION 16 — OTHER INFORMATION
The information and recommendations are offered for the user’s consideration and examination. It is the user’s responsibility to satisfy itself that they are suitable and
complete for its particular use. If the buyer repackages this product, legal counsel should be consulted to insure proper proper health and safety and necessary information is
included on the container.
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