Chapter 9 Notes Honors Chemistry Chapter 9: Chemical Names and Formulas Section 1: Naming Ions (read pages 252-259) Monatomic Ions Ions that consist of a _______________ atom with a _______________ or _______________ charge resulting from the ________ or ________ of ______ or more _______________ electrons Two Types Positive Ions o _______________ Negative Ions o _______________ Cations _______________ charged ions Metal atom _______________ _______________ Name _______________ the _______________ Naming Cations Practice Element Sodium # of valence electrons …………………… Ion formed Name of cation …………… …………………………… Ca2+ Magnesium Anions _______________ charged ions Nonmetal atom _______________ _______________ Name changes to _______________ ending Naming Anions Practice Element Nitrogen # of valence electrons Ion formed ……………… …… Name of anion ……………………….. S2Fluoride 1 Chapter 9 Notes Honors Chemistry Note Groups _______________ and _______________ usually ________ _______ form ions Ions of Transition Metals Many of the _______________ metals form _______________ than _______________ cation with _______________ ionic charges Not _____________ transition metals have ______________ than ____________ charge _______________ must be determined from the _______________ of _______________ _______________ Two Methods to Name Transition Metal Ions 1. _______________ _______________ 2. _______________ _______________ Stock System _______________ method of _______________ A _______________ _______________ in _______________ is placed _______________ the name of the element to indicate the _______________ _______________ of the _______________ Number Roman Numeral 1 2 3 4 5 Stock System Naming Practice Ion Formed # of Electrons Lost Cu+ 1 Stock Name Copper (I) ion Cu2+ Lead (II) ion Pb4+ 2 6 Chapter 9 Notes Honors Chemistry Classical Method In the past, scientists used the _______________ names of elements. Example: Ferrum is Latin for Iron. Ferr- is the root of this word. 2+ 3+ Iron forms two ions: Fe and Fe Ion names: 2+ Fe is the ferrous ion 3+ Fe is the ferric ion Practice Problems Name the ions formed by these elements and classify them as anions or cations. a) Selenium ______________________________ b) Barium ______________________________ c) Phosphorous ______________________________ Polyatomic Ions What does the prefix poly mean? _______________ Polyatomic ions are _______________ of _______________ than _______________ atom _______________ bound _______________ of atoms that behave as a _______________ and carry a _______________ The names of most polyatomic ions end in _______________ or _______________ Different Endings o Ammonium _______________ o _______________ CNo _______________ OH- A Closer Look at a Polyatomic Ion Name: _______________ _______________: shows the _______________ on the polyatomic ion PO43_______________: shows the _______________ of atoms of that element Book Work - Page 258 #3-9 3 Chapter 9 Notes Honors Chemistry Section 2: Naming and Writing Formulas for Ionic Compounds (read pages 260-266) Binary Ionic Compounds What does the prefix bi mean? _______________ A binary _______________ compound is composed of _______________ elements - a _______________ and a _______________ Naming Binary Ionic Compounds If you know the formula of the ionic compound, you can write the name To name any binary ionic compound, place the _______________ name _______________, followed by the _______________ name. Naming Binary Ionic Compounds - Examples 1. Naming a Simple Ionic Compound (1 _______________ + 1 _______________) a. CaCl2 ____________________________ 2. Naming an Ionic Compound containing a Transition Metal with only ONE possible charge (1 _______________ + 1 _______________) a. ZnS ______________________________ 3. Naming an Ionic Compound containing a Transition Metal with only ONE possible charge (1 _______________ + 1 _______________) a. Cu2O ____________________________ b. CuO ____________________________ Try It! Name the following binary ionic compounds: 1. NaF _________________________________________ 2. FeCl3 _________________________________________ 3. FeCl2 _________________________________________ Writing Binary Ionic Formulas If you know the name of a binary ionic compound, you can write the formula! Write the ____________ of the ____________ and then the ____________. Then, add the ____________ that are needed to ____________ the ____________. The _______________ charge of the _______________ must balance the _______________ charge of the _______________ so that the net ionic charge of the compound is _______________. 4 Chapter 9 Notes Honors Chemistry Remember the Crisscross Method? 1. __________________________________________________________________ 2. __________________________________________________________________ 3. __________________________________________________________________ 4. __________________________________________________________________ Writing Binary Ionic Formulas - Examples 1. Simple Ionic Compounds: a. Sodium Bromide _______________ 2. Ionic Compounds with Transition Metals: a. Iron (III) Oxide _______________ Writing Formulas for Binary Ionic Compounds Write formulas for these binary ionic compounds. a. Copper (II) sulfide _________________________________________ b. Potassium nitride _________________________________________ 11. Write formulas for these compounds a. Sodium iodide _________________________________________ c. Potassium sulfide _________________________________________ d. Calcium iodide _________________________________________ What is a polyatomic ion? _________ bound groups of _________ that behave as a ___________ and carry a ___________ Polyatomic Ions behave as a UNIT. You _______________ change the _______________ or the _______________ of _______________ of each _______________ in a polyatomic ion or you will change the _______________ of that ion!! Naming Compounds with Polyatomic Ions To name a compound containing a polyatomic ion, state the _______________ _______________, and then the _______________. Just like naming binary _______________ compounds! Except you _______________ _______________ change the anion name! 5 Chapter 9 Notes Honors Chemistry Naming Compounds with Polyatomic Ions Example 1. 2. 3. 4. CaSO4 ______________________________ AlPO4 ______________________________ NaC2H3O2 ______________________________ CuSiO3 ______________________________ Writing the Formula of a Compound containing a Polyatomic Ion Remember: Polyatomic ions _______________ as a _______________. You _______________ change the assigned _______________. Write the ____________ for the ____________, followed by the ____________ for the ____________ ion, then ____________ the charges. Use _____________. Writing Formulas with Polyatomic Ions Example 1. 2. 3. 4. 5. 6. Aluminum chromate _______________ Ammonium sulfide _______________ Ammonium sulfate _______________ Tin (II) cyanide _______________ Magnesium hydroxide _______________ Potassium sulfate _______________ Try It! Write the formulas of the following binary ionic compounds: 1. 2. 3. 4. Tin (IV) sulfide ______________________________ Magnesium nitrate ______________________________ Calcium bromide ______________________________ Sodium hydroxide ______________________________ Book Work - Page 266 #14-19 Section 3: Naming and Writing Formulas for Molecular Compounds (read pages 268-270) Binary Molecular Compounds A binary _______________ compound is composed of _______________ elements – _______________ are _______________ Binary molecular compounds do not contain _______________ – they are made of… _______________ 6 Chapter 9 Notes Honors Chemistry Naming Binary Molecular Compounds Use _______________ The _______________ in the name of a binary molecular compound tells how many _______________ of each _______________ are present in each _______________ of the _______________ Number Prefix 1 2 3 4 5 6 7 8 9 10 Steps for Naming a Binary Molecular Compound 1. _______________ that the compound is a binary _______________ compound. 2. _______________ the elements in the _______________ that they appear in the _______________ a. Use _______________ to indicate the _______________ of each kind of atom. b. The name of the _______________ element _______________ the _______________. The _______________ of the _______________ element changes to _______________ Special Rules If there is only _______________ atom of the _______________ element in the formula, drop the _______________ Example: CCl4 is called ___________________, NOT monocarbon tetrachloride. If the element _______________ with a _______________, drop the _______________ on the end of the _______________. Example: CO is called _________________________, NOT carbon monooxide. Naming Binary Molecular Compounds - Examples 1. N2O ______________________________ 2. Cl2O8 ______________________________ Try It! 1. 2. 3. 4. CBr4 ______________________________ N2H4 ______________________________ PCl5 ______________________________ S2F10 ______________________________ 7 Chapter 9 Notes Honors Chemistry Writing Formulas for Binary Molecular Compounds Use the _______________ in the name to tell you the _______________ of each _______________ in the _______________. Then, write the correct _______________ for the two elements with the appropriate _______________. Writing Formulas for Binary Molecular Compounds – Examples 1. Dinitrogen trioxide _______________ 2. Iodine heptafluoride _______________ Try It! a. b. c. d. Carbon disulfide ______________________________ Tribromine octoxide ______________________________ Silicon monocarbide ______________________________ Dihydrogen monoxide ______________________________ Book Work - Page 270 #20-25 Section 4: Naming and Writing Formulas for Acids and Bases (read pages 271-273) Naming Acids Acid – a _______________ that contains _______________ or more _______________ atoms and produces _______________ ions (_____________) when _______________ in _______________ _______________ is most commonly listed _______________ in the compound Formula: _______________ o NOTE: Acids _______________ _______________ have to have _______________ first, but _______________ do. Rules for Naming Acids _______________ rules Dependent of the _______________ (the non _______________ part) 8 Chapter 9 Notes Honors Chemistry Rule #1 When the name of the _______________ ends in _______________, the _______________ name begins with _______________. The _______________ of the _______________ has the suffix _______________ and is followed by _______________. Simply – if there is no _______________ in the acid formula, the formula for the name is ______________________________ _______________ Example o HCl Cation – _______________ Anion – _______________ Name of Acid – _______________ _______________ Rule #2 When the _______________ name ends in _______________, the _______________ name is the stem of the anion with the suffix _______________ followed by the word _______________. Formula for name: ___________________ _______________ Example o HClO2 Cation – _______________ Anion – _______________ Name of Acid – _______________ _______________ Rule #3 When the anion name _______________ in _______________, the _______________ name is the _______________ of the anion with the suffix _______________ followed by the word _______________. Formula for name: _______________ _______________ Example o HClO3 Cation – _______________ Anion – _______________ Name of Acid – _______________ _______________ Practice Problems 1. 2. 3. 4. H2SO3 ______________________________ HNO3 ______________________________ HBr ______________________________ H3PO3 ______________________________ 9 Chapter 9 Notes Honors Chemistry Writing Formulas for Acids Use the _______________ in _______________ Example: o Write the formula for hydrocyanic acid. o Hydro-root-ic acid means the anion ends in –ide. The cation is _______________ (__________). The anion is _______________ (__________). The formula for the acid is _______________. Practice Problems Write the formulas for the following acids: 1. 2. 3. 4. Hydroiodic acid ______________________________ Carbonic acid ______________________________ Carbonous acid ______________________________ Acetic acid ______________________________ Names and Formulas of Bases Base – a _______________that produces _______________ions (____________) when _______________in _______________ Named the _______________way as an _______________compound: Name of _______________, then name of _______________. o __________ is usually _______________ (_____) but it does not have to be. Example: o NaOH Cation: _______________ Anion: _______________ Name of Base: _______________ _______________ Try It! Provide the appropriate name or formula of the following bases: 1. 2. 3. 4. Potassium hydroxide ______________________________ Be(OH)2 ______________________________ RbOH ______________________________ Aluminum hydroxide ______________________________ Book Work – Page 273 #26-33 10 Chapter 9 Notes Honors Chemistry Section 5: The Laws Governing Formulas and Names (read pages 274-279) The Law Governing Formulas and Names The _______________ for naming and writing _______________ are _______________ because elements form compounds in _______________ ways. Two Important _______________ o The Law of _______________ Proportions o The Law of _______________ Proportions The Law of Definite Proportions 1. 2. 3. 4. States that in samples of any chemical _______________, the _______________ of the elements are always in the _______________ _______________. So what does that mean? What is the formula for water? _______________ What is the atomic mass of Oxygen? _______________ What is the atomic mass of Hydrogren? _______________ What is the mass ratio of Oxygen to Hydrogen in water? _______________ 1. What is the formula for Hydrogen Peroxide or Dihydrogen Dioxide? ___________ 2. What is the mass ratio of Oxygen to Hydrogen in hydrogen peroxide? __________ The Law of Multiple Proportions Whenever the _______________ two elements form _______________ than one _______________, the different _______________ of one element that combine with the _______________ mass of the other element are in the _______________ of small _______________ numbers. Guidelines for Writing the Chemical Formula of a Compound 1. An _______________ ending generally indicates a _______________ compound. 2. An _______________ or _______________ ending means a _______________ ion that contains _______________ is in the formula. 3. _______________ in a name generally indicate that the compound is _______________. 4. A _______________ _______________ after the name of a _______________ shows the _______________ of the _______________. 11 Chapter 9 Notes Honors Chemistry Naming Review Naming Practice Formula Name Sodium chloride BrF3 LiNO3 Dinitrogen tetrahydride Potassium hydroxide Rb2O Hydrofluoric acid Book Work - Page 279 #35, 39-41 12 Ionic or Molecular?