IB Chemistry Food Chemistry Web Quest Visit Mrs. Mucci’s home page and scroll down to the food chemistry web quest and follow the links to answer the following questions. Text http://www.pearsonschoolsandfecolleges.co.uk/Secondary/Science/IB%20Resources/PearsonBaccalaureate/S amples/SampleMaterialChemistry/ChemistryHigherLevelChapter17.pdf Your Mother was a Chemist http://kitchenscience.sci-toys.com/Introduction Fats and oils http://kitchenscience.sci-toys.com/fats http://kitchenscience.sci-toys.com/protein http://kitchenscience.sci-toys.com/oxidation http://kitchenscience.sci-toys.com/heating 1. Olive oil is mainly mono-unsaturated, whereas sunflower oil is mainly poly-unsaturated. Explain what is meant by these terms. How would you expect the melting points of these two oils to compare? Explain why this is so. 2. Most naturally occurring unsaturated oils are the cis-isomer, but hydrogenation of poly-unsaturated oils can give the trans-isomer of unsaturated oils. Explain how cis- and trans- isomers differ and state what differences you would expect between these isomers firstly with regard to melting point and secondly with regard to nutritional value. 3. You are planning to make a ‘strawberry candy’ with a texture similar to chocolate by blending together a lipid base, sucrose, food colouring and artificial strawberry essence. What kind of lipid would you choose for this? Justify your choice. 4. Going from lard, through olive oil to canola oil to corn oil the degree of unsaturation increases. How would you expect the chemical stability of these lipids to vary? Explain this. 5. Vegetable oils are frequently hydrogenated. Give the reagents and conditions used for these reactions. Give two advantages for the food industry of doing this and two health concerns that the general public might have about the products. IB Chemistry Food Chemistry Web Quest Shelf Life http://www.medlabs.com/Downloads/food_product_shelf_life_web.pdf http://www.thenfl.com/product-integrity-services/shelf-life http://www.pearsonschoolsandfecolleges.co.uk/Secondary/Science/IB%20Resources/PearsonBaccalaureat e/Samples/SampleMaterialChemistry/ChemistryHigherLevelChapter17.pdf Methods of Food Preservation Introduction Description: Food Preservation is the process of increasing the shelf life of foods by preventing spoilage from microorganisms by the use of chemical preservatives, heat or the removal of moisture from the food. Various methods are used to achieve this, some of which are: Dehydration/Drying, Fermentation and Pickling, Canning, and Freezing. Grade Level: First year college students Curriculum: Food Science Keywords: Food Preservation, dehydration, drying, fermentation, pickling, canning, freezing microorganisms, preservatives, moisture content. Task Students are required to read information and make notes on: 1. reasons for food preservation 2. methods of Food preservation, namely: dehydration, drying, fermentation and pickling, canning, freezing. Process Reading assignment: Students will access the following websites to read and make notes and answer questions on food preservation . You may also wish to refer to your notes. http://www.buzzle.com/articles/food-preservation-methods-ofpreserving-food.html http://hubpages.com/hub/Methods-of-Food-Preservation 6. Give three specific examples of changes you might notice in specific foods that would indicate that they had been in storage beyond their shelf life. IB Chemistry Food Chemistry Web Quest 7. Many cultures have traditional ways of preserving foods. Some that are common across a number of cultures are fermentation, pickling, salting and drying. For each of these give an example of a food that is preserved in this way and explain the reason why this method of preservation works. 8. What is meant by the term ‘rancidity’? State which food group becomes rancid and give two changes you could make to the way in which the food is stored which would decrease this effect. 9. Adding antioxidants can increase the shelf life of foods. What is meant by the term antioxidant and what type of food degradation does it combat? Name one synthetic and one naturally occurring antioxidant used in foods. 10. Rancidity can occur by two distinct processes. Describe a way in which substances become rancid that i) affects all types of lipids. ii) affects unsaturated lipids much more than saturated ones. In the case of the latter what other conditions are likely to accelerate the reaction? 11. If you were wanting to increase your consumption of antioxidants, name two foods that you would be advised to eat more of and for each food name the active antioxidant present in it. 12. In food storage often the packaging is very important. Explain how each of these will help to increase the shelf life of the product. i) the moisture level is kept very low. ii) the packaging excludes air. iii) the wrapping is opaque. iv) the product is stored at a low temperature. IB Chemistry Food Chemistry Web Quest See text and PPT Food Additives 13. Additives are often introduced into foods to delay the onset of microbial growth. Name two specific additives used for this along with one example for each of a foodstuff they are generally added to. 14. Auto-oxidation occurs by a free radical chain reaction. Explain what this means. Write equations for the two reactions that are responsible for generating the major product. 15. Antioxidants added to food can reduce oxidative degradation in three specific ways. Outline these mechanisms and give a specific example of an antioxidant that operates in this manner. Colour Watch the video http://www.sciencedaily.com/videos/2009/0112-chemistry_of_cooking.htm Refer to the article starting on pg 214 http://books.google.ca/books?id=KF2A8Cz7BcC&dq=organic+chemistry+food&printsec=frontcover&source=in&hl=en&ei=dsD_S7LlO4P48AbYbHxDQ&sa=X&oi=book_result&ct=result&resnum=11&ved=0CE4Q6AEwCg#v=onepage&q=organic %20chemistry%20food&f=true 16. Name three groups of compounds that are responsible for the colours of foodstuffs and, for each, give two examples of specific foodstuffs in which they produce the colour. 17. One group of naturally occurring pigments has a structure closely related to that of vitamin A. Which group of pigments is this and what are the principal structural features of this group of compounds? 18. The colour of red cabbage often changes when it is cooked or preserved. What is the principal colouring agent in red cabbage? Give three factors that might affect the colour of this group of compounds when being prepared as foodstuffs. IB Chemistry Food Chemistry Web Quest 19. Heme and chlorophyll are both frequently responsible for the colour of foods. Which groups of foods are they found in? They have closely related structures; state one similarity and one difference in their structures. What is the principal change that occurs when heme is converted into myoglobin, the major pigment in muscle tissue? 20. Discuss some health concerns that people have with regard to the use of synthetic dyes in processed foods. What regulatory changes, other than banning their use, would you propose that could reduce public concerns in this regard. 21. When heated on their own, carbohydrates undergo changes that result in the formation of a brown colour. What name is given to this process and how does it occur? 22. When carbohydrates are heated with proteins a second group of browning processes can also occur. What name is given to this second group? Describe how these food groups interact to produce brown products. 23. What is the normal oxidation state of iron in heme. Under some conditions this may alter and lead to undesirable changes in the appearance of meat – describe this change and the conditions required. Give suggestions of two ways in which the storage of meat could be altered to delay this undesirable change. 24. Anthocyanins, carotenoids and chlorophyll all have very different structures. Why is it that all are coloured? 25*. When beetroot is boiled the water becomes a bright purple colour, but when carrots are boiled little colouration of the water is noticed, but if carrots are fried, the oil becomes orange coloured. Use your knowledge of the compounds responsible for the colour of these vegetables to explain these observations. IB Chemistry Food Chemistry Web Quest Genetically Modified foods Web sites to help you http://www.csa.com/discoveryguides/gmfood/overview.php http://www.albrightseed.com/biologicalengineering.htm 26. Briefly describe the process by which a plant or animal can be modified to produce a genetically modified (GM) food. 27. Give three separate ways in which genetic modification might improve the yield from a food crop. 28. As well as improving the viability of plants and animals, genetic modification can also result in novel substances being produced by organisms. Give a specific example of such a modification. 29. Many people are opposed to the introduction of genetically modified plants and animals. Explain what their major concerns are. Texture Websites to help you http://kitchenscience.sci-toys.com/solutions http://kitchenscience.sci-toys.com/Foams http://kitchenscience.sci-toys.com/Emulsions http://kitchenscience.sci-toys.com/Gels 30. What physical properties of a food contribute to its texture? Disperse systems often display highly desirable textures. What is meant by a disperse system? IB Chemistry Food Chemistry Web Quest 31. Three common disperse systems are suspensions, emulsions and foams. Distinguish between these in terms of the states of the components. 32. The production of stabilised disperse systems often depends on additives such as emulsifiers and stabilisers. Explain the role of these two groups of substances and name a synthetic example of each. 33. What characteristics do all emulsifiers have? Explain how these characteristics allow an emulsifier to produce a stable disperse system from two immiscible components. 34. As well as requiring an emulsifying agent, the production of an emulsion always involves vigorous beating of the components. Explain why this mechanical agitation is necessary. IB Chemistry Food Chemistry Web Quest Food Chemistry Lab Next week on food preservation Laboratory activities: In groups of three (3), students will do the following activities: Lab exercise 1. Dehydration and Drying: Cut fruits in thin slices and weigh, add 1tsp citric acid to sliced fruits, Place in container and put in solar dryer for five days. Record weight of dried fruits. Use the lab report format to write up your lab report. Discuss your findings. Lab exercise 2: Fermentation and Pickling: 1. Wash and clean the vegetables and spices. Cut the vegetables in desired shapes approximately one-eight of an inch thick. Add salt to vegetable, after 5minutes, drain off liquid. Prepare jars and lids by boiling in water for 15 - 20 minutes. Remove from hot water and drain. Pack prepared vegetables and spices in. Pour in warm acetic acid. Seal tightly. Lab exercise 3 & 4: Freezing: 1.Vegetables - Wash, clean and blanch vegetables in brine. Drain and cool. Place in plastic freezer bags, seal. Place in freezer for storage. 2. Fruits - wash and prepare fruits, cut in quater inch slices or half inch cubes where appropriate. Boil for 20 minutes in light syrup. Cool and place in plastic freezer bags. Place in freezer for storage.