Don’t pay any attention to number 26! 1. Manganese makes up 1.3 10–4 percent by mass of the elements found in a normal healthy body. How many grams of manganese would be found in the body of a person weighing 261 lb? (2.205 lb = 1 kg) a) 0.75 g b) 0.15 g c) 15 g d) 75 g e) 1.5 10–4 g Ans: b Algorithm: Yes Chapter/Section: 1.6 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: general concepts Keyword 4: measurement Keyword 5: factor label method 2. In 1984, some drums of uranium hexafluoride were lost in the English Channel, which is known for its cold water (about 15°C). The melting point of uranium hexafluoride is 148°F. In what physical state is the uranium hexafluoride in these drums? (T °F = T°C (9°F / 5°C) + 32°F) a) solid b) liquid c) gas d) a mixture of solid and liquid e) not enough information Ans: a Algorithm: Yes Chapter/Section: 1.7 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: general concepts Keyword 4: measurement Keyword 5: SI unit Keyword 6: temperature 3. A freighter carrying a cargo of uranium hexafluoride sank in the English Channel in late August 1984. The cargo of uranium hexafluoride weighed 2.251 108 kg and was contained in 30 drums, each containing 1.47 106 L of UF6. What is the density (g/mL) of uranium hexafluoride? a) 1.53 g/mL b) 5.10 g/mL c) 2.25 g/mL d) 0.196 g/mL e) 51.0 g/mL Ans: b Algorithm: Yes Chapter/Section: 1.8 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: general concepts Keyword 4: measurement Keyword 5: SI unit Keyword 6: density 4. Which of the following pairs can be used to illustrate the law of multiple proportions? a) SO and SO2 b) CO and CaCO3 c) H2O and C12H22O11 d) H2SO4 and H2S e) KCl and KClO2 Ans: a Algorithm: No Chapter/Section: 2.2 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter 5. A sample of chemical X is found to contain 5.0 grams of oxygen, 10.0 grams of carbon, and 20.0 grams of nitrogen. The law of definite proportion would predict that a 67 gram sample of chemical X should contain how many grams of carbon? a) 5.0 grams b) 6.7 grams c) 10. grams d) 15 grams e) 19 grams Ans: e Algorithm: Yes Chapter/Section: 2.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter Keyword 5: Dalton's atomic theory 6. Rutherford's experiment was important because it showed that: a) Radioactive elements give off alpha particles. b) Gold foil can be made to be only a few atoms thick. c) A zinc sulfide screen scintillates when struck by a charged particle. d) The mass of the atom is uniformly distributed throughout the atom. e) An atom is mostly empty space. Ans: e Algorithm: No Chapter/Section: 2.4 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter Keyword 5: structure of the atom Keyword 6: nuclear model of atom 7. The element rhenium (Re) exists as two stable isotopes and 18 unstable isotopes. Rhenium-185 has in its nucleus a) 75 protons, 75 neutrons b) 75 protons, 130 neutrons c) 130 protons, 75 neutrons d) 75 protons, 110 neutrons e) not enough information Ans: d Algorithm: No Chapter/Section: 2.5 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter Keyword 5: isotope 8. Which of the following statements are true of uranium-238? I. Its chemical properties will be exactly like those of uranium-235. II. Its mass will be slightly different from that of an atom of uranium-235. III. It will contain a different number of protons than an atom of uranium-235. IV. It is more plentiful in nature than uranium-235. a) III, IV b) I, II, III c) I, II, IV d) II, III, IV e) all of these Ans: c Algorithm: No Chapter/Section: 2.5 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter Keyword 5: isotope 9. Which of the following statements is true? a) Ions are formed by adding or removing protons or electrons. b) Scientists believe that solids are mostly open space. c) Heating water with a Bunsen burner results in a 2:1 mixture of hydrogen and oxygen gases. d) At least two of the above statements (A-C) are true. e) All of the statements (A-C) are false. Ans: b Algorithm: No Chapter/Section: 2.5 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory 10. How many protons and electrons does the most stable ion for magnesium have? # protons # electrons a) 10 p 12 e b) 12 p 14 e c) 14 p 12 e d) 12 p 12 e e) 12 p 10 e Ans: e Algorithm: Yes Chapter/Section: 2.8 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: periodic table Keyword 5: group 11. You are given a compound with the formula MCl2, in which M is a metal. You are told that the metal ion has 25 electrons. What is the identity of the metal? a) Mn b) Al c) Cu d) Fe e) Co Ans: e Algorithm: Yes Chapter/Section: 2.7 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical substance Keyword 5: chemical formula Keyword 6: ionic substance 12. The atomic mass of rhenium is 186.2. Given that 37.1% of natural rhenium is rhenium-185, what is the other stable isotope? 183 a) 75 Re b) 187 75 Re c) 189 75 Re d) 181 75 Re 190 75 Re e) Ans: b Algorithm: No Chapter/Section: 3.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter Keyword 5: atomic weight Keyword 6: mass spectroscopy 13. Naturally occurring copper exists in two isotopic forms: 63Cu and 65Cu. The atomic mass of copper is 63.55 amu. What is the approximate natural abundance of 63Cu? a) 63% b) 90% c) 70% d) 50% e) 30% Ans: c Algorithm: No Chapter/Section: 3.2 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: atomic theory of matter Keyword 5: atomic weight Keyword 6: mass spectroscopy 14. A sample of ammonia has a mass of 45.5 g. How many molecules are in this sample? a) 2.67 molecules b) 2.74 1025 molecules c) 2.25 1023 molecules d) 1.61 1024 molecules e) 9.02 10–16 molecules Ans: d Algorithm: Yes Chapter/Section: 3.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: mass and moles of substance Keyword 5: mole 15. Calculate the molar mass of calcium perchlorate. a) 254.98 g/mol b) 222.98 g/mol c) 279.06 g/mol d) 179.61 g/mol e) 238.98 g/mol Ans: e Algorithm: Yes Chapter/Section: 3.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: mass and moles of substance Keyword 5: molecular weight 16. Phosphoric acid can be prepared by reaction of sulfuric acid with “phosphate rock” according to the equation: Ca3(PO4)2 + 3H2SO4 3CaSO4 + 2H3PO4 How many oxygen atoms are there in 3.80 ng of Ca3(PO4)2? a) 7.38 1012 b) 2.95 1013 c) 1.83 1016 d) 5.90 1022 e) 5.90 1013 Ans: e Algorithm: Yes Chapter/Section: 3.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: mass and moles of substance Keyword 5: mole 17. What is the mass of a 6.267-mol sample of sodium hydroxide? a) 40.00 g b) 250.7 g c) 150.4 g d) 6.382 g e) 0.1567 g Ans: b Algorithm: Yes Chapter/Section: 3.4 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: mass and moles of substance Keyword 5: mole 18. How many atoms of hydrogen are present in 3.18 g of ammonia? a) 1.12 1023 b) 6.33 1023 c) 5.74 1024 d) 3.37 1023 e) 4.65 1019 Ans: d Algorithm: Yes Chapter/Section: 3.4 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: mass and moles of substance Keyword 5: mole 19. A substance contains 35.0 g nitrogen, 5.05 g hydrogen, and 60.0 g of oxygen. How many grams of hydrogen are there in a 179-g sample of this substance? a) 9.03 g b) 897 g c) 18.1 g d) 5.05 g e) 35.4 g Ans: a Algorithm: Yes Chapter/Section: 3.6 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas 20. How many grams of potassium are in 21.9 g of K2CrO7? a) 3.54 g b) 1.120 g c) 7.07 g d) 78.2 g e) 43.8 g Ans: c Algorithm: Yes Chapter/Section: 3.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas 21. Chloric acid, HClO3, contains what percent hydrogen by mass? a) 1.92% b) 20.0% c) 18.9% d) 1.19% e) 4.20% Ans: d Algorithm: Yes Chapter/Section: 3.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas 22. A mixture of KCl and KNO3 is 44.20% potassium by mass. The percentage of KCl in the mixture is closest to a) 40% b) 50% c) 60% d) 70% e) 80% Ans: a Algorithm: No Chapter/Section: 3.6 Difficulty: Difficult Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas Keyword 5: mass percentage 23. A substance contains 23.0 g sodium, 27.0 g aluminum, and 114 g fluorine. How many grams of sodium are there in a 119-g sample of the substance? a) 5.17 g b) 23.0 g c) 16.7 g d) 119 g e) none of these Ans: c Algorithm: Yes Chapter/Section: 3.6 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas Keyword 5: mass percentage 24. An oxide of iron has the formula Fe3O4. What mass percent of iron does it contain? a) 0.72% b) 28% c) 30% d) 70% e) 72% Ans: e Algorithm: No Chapter/Section: 3.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas Keyword 5: mass percentage 25. The mineral mimetite has the formula Pb5(AsO4)3Cl. What mass percent of oxygen does it contain? a) 38.70 % b) 16.34 % c) 50.32 % d) 12.90 % e) 1.08 % Ans: d Algorithm: Yes Chapter/Section: 3.6 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas Keyword 5: mass percentage 26. You heat 3.853 g of a mixture of Fe3O4 and FeO to form 4.153 g Fe2O3. The mass percent of FeO originally in the mixture was: a) 92.8% b) 57.9% c) 42.1% d) 40.0% e) none of these Ans: b Algorithm: Yes Chapter/Section: 3.6 Difficulty: Difficult Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas Keyword 5: mass percentage 27. You take an aspirin tablet (a compound consisting solely of carbon, hydrogen, and oxygen) with a mass of 1.00 g, burn it in air, and collect 2.20 g of carbon dioxide and 0.400 g water. The molar mass of aspirin is between 170 and 190 g/mol. The molecular formula of aspirin is a) C6H8O5 b) C9H8O4 c) C8H10O5 d) C10H6O4 e) none of these Ans: b Algorithm: No Chapter/Section: 3.7 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: stoichiometry Keyword 4: determining chemical formulas Keyword 5: elemental analysis; molecular formula 28. Potassium forms an oxide containing 1 oxygen atom for every 2 atoms of potassium. What is the coefficient of oxygen in the balanced equation for the reaction of potassium with oxygen to form this oxide? a) 0 b) 1 c) 2 d) 3 e) 4 Ans: b Algorithm: No Chapter/Section: 3.9 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 29. Indium reacts with chlorine to form InCl3. In the balanced equation for this reaction, the coefficient of the indium trichloride is a) 1 b) 2 c) 3 d) 4 e) 6 Ans: b Algorithm: No Chapter/Section: 3.9 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 30. Give (in order) the correct coefficients to balance the following reaction: H2SnCl6 + H2S SnS2 + HCl a) 1, 2, 1, 6 b) 1, 2, 2, 2 c) 1, 1, 1, 6 d) 6, 2, 1, 1 e) 2, 4, 2, 6 Ans: a Algorithm: No Chapter/Section: 3.9 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 31. In the balanced equation for the reaction: xP4O6(s) + yH2O(l) zH3PO3(aq) if x equals 2, the coefficient z equals: a) 2 b) 4 c) 6 d) 10 e) none of these Ans: e Algorithm: No Chapter/Section: 3.9 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 32. The correct coefficients to balance the following reaction are, in order: I2O5 + H2S I2 + SO2 + H2O a) 1, 1, 1, 1, 1 b) 1, 2, 1, 2, 1 c) 2, 4, 1, 4, 5 d) 2, 5, 2, 5, 5 e) 3, 5, 3, 5, 5 Ans: e Algorithm: No Chapter/Section: 3.9 Difficulty: Moderate Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 33. When the following equation is balanced, what is the sum of the coefficients? Al2(SO4)3 + Ca(OH)2 Al(OH)3 + CaSO4 a) 4 b) 9 c) 8 d) 7 e) 10 Ans: b Algorithm: No Chapter/Section: 3.9 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 34. T F When balancing a chemical equation, it is generally best to start with the least complicated molecules. Ans: False Algorithm: No Chapter/Section: 3.9 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation 35. T F To balance a chemical equation, the coefficients must not be changed. Ans: False Algorithm: No Chapter/Section: 3.9 Difficulty: Easy Keyword 1: Chemistry Keyword 2: general chemistry Keyword 3: early atomic theory Keyword 4: chemical equation Keyword 5: balancing chemical equation In the space shuttle, the CO2 that the crew exhales is removed from the air by a reaction within canisters of lithium hydroxide. On average, each astronaut exhales about 20.0 mol of CO2 daily. What volume of water will be produced when this amount of CO2 reacts with an excess of LiOH? (Hint: the density of water is about 1.oo g/mL.) CO2(g) + 2 LiOH(s) ------> Li2CO3(aq) + H2O