Questions Q1. Each element has an atomic number. (i) State what is meant by atomic number. (1) .............................................................................................................................................. .............................................................................................................................................. (ii) The atomic number of boron is 5. Boron exists as two isotopes boron-10 and boron-11. Use this information to explain why boron-10 and boron-11 are isotopes. (2) .............................................................................................................................................. .............................................................................................................................................. .............................................................................................................................................. .............................................................................................................................................. Q2. The positions of five elements, A, B, C, D and E, are shown in the periodic table. These letters are not the atomic symbols of these elements. (a) Use only elements A, B, C, D and E to answer (i) and (ii). (i) Give the letters of all the elements that are metallic. (1) (ii) Give the letters of the two elements that have the most similar chemical properties. (1) (b) An atom of element B contains more protons than an atom of element A. State how many more protons there are in an atom of element B than in an atom of element A. (1) (c) An atom of element E has atomic number 10 and mass number 22. (i) How many electrons does this atom contain? Put a cross ( ) in the box next to your answer. (1) A 10 B 12 C 22 D 32 (ii) 10% of the atoms in a sample of element E have a mass number of 22. All the other atoms in this sample have a mass number of 20. Calculate the relative atomic mass of element E. (3) relative atomic mass = . . . . . . . . . . . . . . . . . . . . . . (d) The element below E in the periodic table is used to fill filament light bulbs. Explain why this element is suitable for this use. (2) (Total for Question is 9 marks) Q3. Boron exists as two isotopes. These are boron-10, 105B, and boron-11, 115B. (a) The diagram shows an atom of the isotope, boron-10. (i) State the electronic configuration of boron. (1) .............................................................................................................................................. (ii) Complete the sentence by putting a cross ( ) in the box next to your answer. In the periodic table, boron is in period (1) A 2 B 3 C 5 D 10 (iii) The table shows the three particles present in atoms and their relative masses and charges. Complete the table. (2) particle relative mass relative charge electron neutron proton +1 *(b) A sample of boron contains 20% boron-10 and 80% boron-11. In part (a) you were given the structure of a boron-10 atom. Describe the structure of a boron-11 atom and explain why, in this sample, boron has a relative atomic mass of 10.8. 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(c) Mendeleev was a Russian chemist who produced the first version of the periodic table. Give one similarity and one difference between his version of the periodic table and the periodic table shown on page 2. .............................................................................................................................................. .............................................................................................................................................. .............................................................................................................................................. .............................................................................................................................................. (2) (Total for Question is 12 marks) Q4. Boron exists as two isotopes. These are boron-10, 105B, and boron-11, 115B. * A sample of boron contains 20% boron-10 and 80% boron-11. In part (a) you were given the structure of a boron-10 atom. Describe the structure of a boron-11 atom and explain why, in this sample, boron has a relative atomic mass of 10.8. 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Mark Scheme Q1. Answer (i) number of protons (in nucleus of atom) (ii) An explanation including (atoms of) both contain 5 /same number of protons/same atomic number (1) boron-10 atoms contain 5 neutrons but boron-11 atoms contain 6 neutrons / different numbers of neutrons/ different mass number (1) Acceptable answers ignore number of electrons eg number of protons and electrons worth (1) ignore electrons boron-11 atoms contain 1 more neutron / boron-10 atoms contain 1 less neutron Mark (1) (2) Q2. Answer (a)(i) A, B and C (a)(ii) A and B (b) (c)(i) (c)(ii) 8 (protons) A : 10 (in 100 atoms) mass of mass number 20 atoms = 20 × 90 (1) mass of mass number 22 atoms = 22 × 10 (1) relative atomic mass = (22 × 10) + (20 ×90)/100 (=20.2) (1) OR 20 contributes = 90/100 ×20(1) 22 contributes = 10/100 ×22(1) relative atomic mass 90/100 × 20 + 10/100 x 22 (= 20.2) (1) An explanation linking any two of (the element is) group 0 / noble gas /unreactive / inert / does not react (1) (has) 8 electrons / full outer shell (1) prevents filament from reacting (1) (d) Acceptable answers Mg Ca Au (any order) magnesium calcium gold (any order) Mg Ca (any order) magnesium calcium (any order) 20.2 = 3 marks 21.8 = 2 marks (only 1 error made) ignore 'not very reactive' does not gain / lose / share electrons Mark (1) (1) (1) (1) (3) (2) Q3. Answer (a)(i) (a)(ii) (a)(iii) Acceptable answers Mark (1) (1) (2) 2.3 A 4 correct = 2 marks 2/3 correct = 1 mark 1/0 correct = 0 mark QWC *(b) Indicative Content Mark An explanation linking some of the following Structure of boron-11 boron-11 atom has 5 /same number of protons 5 /same number of electrons 6 neutrons / one more neutron than boron 10 Working out RAM relative atomic mass is 10.8 because weighted mean more boron-11 than boron-10 boron-11 atoms are heavier (therefore) relative atomic mass nearer 11 than 10 OR in sample given 20/100 of the atoms have a mass of 10 in sample given 80/100 of the atoms have a mass of 11 20/100*10=2 80/100*11=8.8 2+8.8=10.8 NB the diagram in part (a) gives the structure for boron10 so do not give credit for this (even if claimed to be structure of boron-11 (6) Level 1 0 1-2 by referring to it as 'it') No rewardable content a limited description e.g. boron-11 has 5 protons and 6 neutrons the answer communicates ideas using simple language and uses limited scientific terminology spelling, puncuation and grammar are used with limited accuracy 2 3-4 a simple explanation e.g. boron-11 has 5 protons, 5 electrons and 6 neutrons and is heavier than boron-10. the answer communicates ideas showing some evidence of clarity and organisation and uses scientific terminology appropriately spelling, punctuation and grammar are used with some accuracy 3 5-6 a detailed explanation e.g. boron-11 has 5 protons, 5 electrons and 6 neutrons, is heavier than boron-10 and there is more of boron-11 therefore relative atomic mass nearer to 11 than 10. the answer communicates ideas clearly and coherently uses a range of scientific terminology accurately spelling, puncuation and grammar are used with few errors Answer (c) Answer should include one idea from each list similarities both put elements into groups / periods (1) elements with similar properties in same group (1) metals and nonmetals in separately (1) differences Mendeleev's table was arranged by relative atomic mass(1) had gaps (1) had fewer elements (1) did not include the noble gases (1) Acceptable answers Mark (2) reverse argument for modern periodic table specific examples e.g germanium Q4. Indicative Content QWC Level 1 * 0 1-2 Mark (6) An explanation linking some of the following Structure of boron-11 boron-11 atom has 5 /same number of protons 5 /same number of electrons 6 neutrons / one more neutron than boron 10 Working out RAM relative atomic mass is 10.8 because weighted mean more boron-11 than boron-10 boron-11 atoms are heavier (therefore) relative atomic mass nearer 11 than 10 OR in sample given 20/100 of the atoms have a mass of 10 in sample given 80/100 of the atoms have a mass of 11 20/100*10=2 80/100*11=8.8 2+8.8=10.8 NB the diagram in part (a) gives the structure for boron10 so do not give credit for this (even if claimed to be structure of boron-11 by referring to it as 'it') No rewardable content a limited description e.g. boron-11 has 5 protons and 6 neutrons the answer communicates ideas using simple language and uses limited scientific terminology spelling, puncuation and grammar are used with limited accuracy 2 3-4 a simple explanation e.g. boron-11 has 5 protons, 5 electrons and 6 neutrons and is heavier than boron-10. the answer communicates ideas showing some evidence of clarity and organisation and uses scientific terminology appropriately spelling, punctuation and grammar are used with some accuracy 3 5-6 a detailed explanation e.g. boron-11 has 5 protons, 5 electrons and 6 neutrons, is heavier than boron-10 and there is more of boron-11 therefore relative atomic mass nearer to 11 than 10. the answer communicates ideas clearly and coherently uses a range of scientific terminology accurately spelling, puncuation and grammar are used with few errors