5-Piezoelectric materials: 5.1-Introduction: (abstract): Is the charge that accumulates in certain solid materials in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure. The piezoelectric effect is understood as the linear electromechanical interaction between the mechanical and the electrical state in crystalline materials. The piezoelectric effect is a reversible process in that materials exhibiting the direct piezoelectric effect (the internal generation of electrical charge resulting from an applied mechanical force) also exhibit the reverse piezoelectric effect (the internal generation of a mechanical strain resulting from an applied electrical field). Piezoelectricity is found in useful applications such as the production and detection of sound, generation of high voltages, electronic frequency generation, microbalances, and ultrafine focusing of optical assemblies. It is also the basis of a number of scientific instrumental techniques with atomic resolution, the scanning probe microscopes such as STM, AFM, MTA, SNOM, etc., and everyday uses such as acting as the ignition source for cigarette lighters and push-start propane barbecues. Gautschi, G (2002). Piezoelectric Sensorics: Force, Strain, Pressure, Acceleration and Acoustic Emission Sensors, Materials and Amplifiers.. Springer. 5.2-Discovery and early research The pyroelectric effect, by which a material generates an electric potential in response to a temperature change, was studied by Carl Linnaeus and Franz Aepinus in the mid-18th century. Drawing on this knowledge, both René Just Haüy and Antoine César Becquerel posited a relationship between mechanical stress and electric charge. The first demonstration of the direct piezoelectric effect was in 1880 by the brothers Pierre Curie and Jacques Curie. They combined their knowledge of pyroelectricity with their understanding of the underlying crystal structures that gave rise to pyroelectricity to predict crystal behavior, and demonstrated the effect using crystals of tourmaline, quartz, topaz, cane sugar, and Rochelle salt (sodium potassium tartrate tetrahydrate). Quartz and Rochelle salt exhibited the most piezoelectricity. For the next few decades, piezoelectricity remained something of a laboratory curiosity. More work was done to explore and define the crystal structures that exhibited piezoelectricity. Lippman, G. (1881). "Principe de la conservation de l'électricité" (in French). Annales de chimie et de physique 24: 145. 5.3-Mechanism: The nature of the piezoelectric effect is closely related to the occurrence of electric dipole moments in solids. The latter may either be induced for ions on crystal lattice sites with asymmetric charge surroundings (as in BaTiO3 and PZTs) or may directly be carried by molecular groups (as in cane sugar). Dipoles near each other tend to be aligned in regions called Weiss domains. The domains are usually randomly oriented, but can be aligned using the process of poling (not the same as magnetic poling), a process by which a strong electric field is applied across the material, usually at elevated temperatures. Not all piezoelectric materials can be poled. Of decisive importance for the piezoelectric effect is the change of polarization P when applying a mechanical stress. This might either be caused by a re-configuration of the dipole-inducing surrounding or by re-orientation of molecular dipole moments under the influence of the external stress. Piezoelectricity may then manifest in a variation of the polarization strength, its direction or both, with the details depending on: 1. the orientation of P within the crystal, 2. crystal symmetry and 3. the applied mechanical stress. The change in P appears as a variation of surface charge density upon the crystal faces. S. Trolier-McKinstry (2008). "Chapter3: Crystal Chemistry of Piezoelectric Materials". In A. Safari, E.K. Akdo˘gan. Piezoelectric and Acoustic Materials for Transducer Applications. New York: Springer. ISBN 9780387765389. 5.4-These are some videos about the piezoelectric effect: http://www.youtube.com/watch?v=Xuw9frP1GNo&feature=endscreen&NR=1 http://www.youtube.com/watch?v=RCOBA3Yfm1k&feature=endscreen&NR=1 5.5-Examples of some piezoelectric materials: Naturally occurring crystals Berlinite (AlPO4), a rare phosphate mineral that is structurally identical to quartz. Sucrose (table sugar). Quartz. Rochelle salt. Topaz. Tourmaline-group minerals. Quartz Topaz Sucrose 5.6-Applications: 5.6.1-Surgery: A recent application of piezoelectric ultrasound sources is piezoelectric surgery, also known as piezosurgery. Piezosurgery is a minimally invasive technique that aims to cut a target tissue with little damage to neighboring tissues. For example, Hoigne et al.Reported its use in hand surgery for the cutting of bone, using frequencies in the range 25–29 kHz, causing microvibrations of 60–210 μm. It has the ability to cut mineralized tissue without cutting neurovascular tissue and other soft tissue, thereby maintaining a blood-free operating area, better visibility and greater precision. Manbachi, A. and Cobbold R.S.C. (November 2011). "Development and Application of Piezoelectric Materials for Ultrasound Generation and Detection". Ultrasound 19 (4): 187–196. doi:10.1258/ult.2011.011027. 5.6.2-Infertility treatment: In people with previous total fertilization failure, piezoelectric activation of oocytes together with intracytoplasmic sperm injection (ICSI) seems to improve fertilization outcome. Baltaci V, Ayvaz OU, Unsal E, et al. (May 2009). "The effectiveness of intracytoplasmic sperm injection combined with piezoelectric stimulation in infertile couples with total fertilization failure". Fertil. Steril. 94 (3): 900–4. doi:10.1016/j.fertnstert.2009.03.107. PMID 19464000. 5.6.3-Reduction of vibrations and noise Different teams of researchers have been investigating ways to reduce vibrations in materials by attaching piezo elements to the material. When the material is bent by a vibration in one direction, the vibration-reduction system responds to the bend and sends electric power to the piezo element to bend in the other direction. Future applications of this technology are expected in cars and houses to reduce noise. In a demonstration at the Material Vision Fair in Frankfurt in November 2005, a team from TU Darmstadt in Germany showed several panels that were hit with a rubber mallet, and the panel with the piezo element immediately stopped swinging. Piezoelectric ceramic fiber technology is being used as an electronic damping system on some HEAD tennis rackets. "Isn’t it amazing how one smart idea, one chip and an intelligent material has changed the world of tennis?". HEAD. Retrieved 2008-02-27. 5.6.4-Frequency standard The piezo-electrical properties of quartz are useful as standard of frequency. Quartz clocks employ a crystal oscillator made from a quartz crystal that uses a combination of both direct and converse piezoelectricity to generate a regularly timed series of electrical pulses that is used to mark time. The quartz crystal (like any elastic material) has a precisely defined natural frequency (caused by its shape and size) at which it prefers to oscillate, and this is used to stabilize the frequency of a periodic voltage applied to the crystal. The same principle is critical in all radio transmitters and receivers, and in computers where it creates a clock pulse. Both of these usually use a frequency multiplier to reach gigahertz ranges. 5.6.5-Piezoelectric motors A slip-stick actuator. Types of piezoelectric motor include: The traveling-wave motor used for auto-focus in reflex cameras Inchworm motors for linear motion Rectangular four-quadrant motors with high power density (2.5 watt/cm3) and speed ranging from 10 nm/s to 800 mm/s. Stepping piezo motor, using stick-slip effect. All these motors, except the stepping stick-slip motor work on the same principle. Driven by dual orthogonal vibration modes with a phase difference of 90°, the contact point between two surfaces vibrates in an elliptical path, producing a frictional force between the surfaces. Usually, one surface is fixed causing the other to move. In most piezoelectric motors the piezoelectric crystal is excited by a sine wave signal at the resonant frequency of the motor. Using the resonance effect, a much lower voltage can be used to produce a high vibration amplitude. Stick-slip motor works using the inertia of a mass and the friction of a clamp. Such motors can be very small. Some are used for camera sensor displacement, allowing anti shake function. Many other applications such as: 5.6.6-Actuators 5.6.7-High voltage and power sources 5.6.8-Sensors Ana gayeb kolo mn el Wikipedia http://en.wikipedia.org/wiki/Piezoelectric_material This page was last modified on 16 February 2012 at 20:08. Abdallah ismail Mohamed bayomy 1095154