Page: 1/4 Material Safety Data Sheet (MSDS) in accordance with 91/155/EEC Printed on: 28.08.2010 1 Identification of the substance / compound and company ■ Product details ■ Trade name: Moss and algae remover ■ Product number: ■ Manufacturer / supplier: HSK S. Kotlewski Wiehenstrasse 21 32289 Rödinghausen , Germany Tel.: 49 (0) 5746 911171 Fax.: 49 (0) 5746 937 811 ■ Further information can be obtained from: For the Research and Development department, refer to section 16 ■ SOS information point: Poisons Information Centre: University and Polyclinic Bonn, Germany Tel.: (0228) 287-3211, Fax: (0228) 287-3314 2 Composition / information on the constituents ■ Chemical characterisation ■ Description: Mixture of substances listed below with non-hazardous additives. Hazardous constituents: CAS no. Designation percent Hazard symbol; risk phrases Alkyldimethylbenzyl ammonium chloride 50% CAS: 85409-22-9 EINECS: 287-089-1 ■ Additional information: For the wording of the listed risk phrases, refer to section 16. ■ 3 C; R 21/22-34 2.5-10% Potential hazards ■ Hazard description: Not applicable. ■ Special information on hazards to humans and the environment: The product is not subject to classification based on the calculation procedure of the "General Classification Guideline for Compounds of the EU" in the latest valid version. ■ Classification system: The classification is in line with current EC lists, but it is supplemented by information from specialised literature and company information. ■ Additional Information: Do not allow the product, even in small quantities, to reach the groundwater, water bodies or sewage system. 4 First aid measures ■ General information: No special measures required. ■ After inhalation: Provide fresh air, seek medical advice in case of complaints. ■ After skin contact: In general, the product does not irritate the skin. Normal cleaning with soap and water is recommended. ■ After eye contact: Flush eyes for several minutes under running water with eyelids open. Consult a doctor if symptoms persist. ■ If symptoms persist following ingestion , consult a physician. 5 Fire-fighting measures ■ Suitable fire-extinguishing media: CO2, sand, fire-extinguishing powder or water spray. Fight larger fires with alcohol-resistant foam. ■ Fire-extinguishing agents that are unsuitable for safety reasons: None ■ Special hazards caused by the material, its products of combustion or resulting gases: Hydrogen chloride, nitrogen oxides and sulphur oxides are released. (Continued on page 2) D— Page: 2/4 Material Safety Data Sheet (MSDS) in accordance with 91/155/EEC Printed on: 28.08.2010 Product name: moss and algae remover ■ Special protective equipment: No special measures required. 6 (Continued on page 1) Accidental release measures ■ Personal precautions: Not mandatory. ■ Environmental precautions: Dilute with plenty of water. Do not discharge into the drains / surface waters or allow percolation into the groundwater. ■ Measures for cleaning / collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders or sawdust). ■ Additional information: No release of hazardous substances. * 7 Handling and storage ■ Handling: ■ Information on safe handling: No special measures required. ■ Precautions against fire and explosion: No special measures required. ■ ■ ■ ■ ■ 8 Storage: Requirements to be met by storerooms and containers: Above -15 °C. Further information about storage conditions: See note on the label. Storage class: Classification under BetrSichV (Ordinance on Industrial Safety and Health): Exposure controls and personal protection equipment ■ Additional information about design of technical facilities: No further data; see section 7. ■ Components with workplace-related limits to be monitored: The product does not contain any relevant quantities of materials with workplace-related exposure limits to be monitored. ■ Additional information: The lists valid during the drafting process were used as basis. ■ Personal protective equipment: ■ General safety and hygiene measures: The usual precautionary measures for handling chemicals should be followed. ■ Respiratory protection: Not mandatory. ■ Protection of hands: The glove material has to be impermeable and resistant to the product / the substance / the compound. Due to missing tests, no recommendation can be made on the glove material for the product / the compound / the chemical mixture. Selection of the glove material in consideration of the penetration times, rates of diffusion and the degradation. Not mandatory. ■ Material of gloves The selection of suitable gloves does not only depend on the material, but also on other quality characteristics and varies from manufacturer to manufacturer. As the product is a compound made of several substances, the resistance of the glove material cannot be calculated in advance and therefore, has to be checked prior to the application. ■ Penetration time of glove material The exact penetration time has to be obtained from the safety glove manufacturer and must be observed. ■ Eye protection: Safety glasses recommended for refilling. ■ Body protection: Safety work clothing 9 Physiochemical properties ■General Information Form: Colour: Odour: Fluid light yellow, cloudy Pungent (Continued on page 3) D— Page: 3/4 Material Safety Data Sheet (MSDS) in accordance with 91/155/EEC Printed on: 28.08.2010 Trade name: Moss and algae remover (Continued on page 2) ■Change of state Melting point / range: 0°C boiling point / range: ■ Self-ignitability: Product is not self-ignitable. ■Danger of explosion: Product is not explosive. ■ Vapour pressure at 20°C: 23 hPa ■ Density at 20°C: 1 g/cm3 (DIN 51757) ■ Solubility in / miscibility with water: Fully miscible ■ pH at 20°C: 6.5 ■Solvent content: Organic solvent: Water: ■ Solid content: 10 100°C 0.0 % 95.1 % 0.0 % Stability and reactivity ■ Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. ■ Dangerous reactions No dangerous reactions known. ■ Hazardous decomposition products: If properly stored / handled / transported, no known hazardous decomposition products. 11 Toxicological information ■ Acute toxicity: ■ Primary irritant effect: ■ On the skin: No irritant effect. ■ On the eye: No irritant effect. ■ Sensitisation: No sensitising effects known. ■ Sub-acute to chronic toxicity: If used properly, health risks are not known or expected. ■ Additional toxicological information: The product is not subject to classification based on the calculation procedure of the "General Classification Guideline for Compounds of the EU" in the latest valid version. Based on our experience and the information provided to us, the product does not have any adverse health effects when used and handled according to specifications. 12 Ecological information ■ Information about elimination (persistence and degradability): No product data available. ■ Eco-toxicity: ■ Aquatic toxicity: The product is dangerous for all aquatic organisms and therefore, may not reach water bodies without clarification. ■ General information: Water hazard class 3 (self-assessment): extremely hazardous for water Do not allow the product, even in small quantities, to reach the groundwater, water bodies or sewage system. Danger to drinking water even when small quantities percolate into the ground. 13 Disposal instructions ■ Product: ■ Recommendation: Contact manufacturer for recycling. (Continued on page 3) (Continued on page 4) D— Page: 4/4 Material Safety Data Sheet (MSDS) in accordance with 91/155/EEC Printed on: 28.08.2010 Product name: moss and algae remover Contaminated packaging: ■ Recommendation: Do not puncture, cut or weld unclean containers. In case of a returnable packaging: After optimum emptying, close immediately and return to the supplier without cleaning. Care should be taken that no foreign substances get into the packaging! ■ Recommended cleaning agent: Water together with cleansing agents, if necessary. • 14 Transport information ■ Land transport ADR / RID and ADR / RID (cross-border / domestic): ■ ADR / RID-GGVS /E class: ■ Comments: Exemption from the provisions of ADR (LQ 19) ■ Transport by inland waterways IMDG/GGVSee: ■ IMDG/GGVSee class: ■ Air transport ICAO-TI and IATA-DGR: ■ ICAO / IATA class: ■ Comments: Not dangerous according to transport regulations. * 15 Regulations ■ Labelling according to EU guidelines: Precautions that usually apply to handling of chemicals shall be observed. The product is not subject to classification under EC Directives / GefStoffV - Ordinance on Hazardous Materials. ■ Safety phrases: 59 Obtain information on reuse / recycling from manufacturer / supplier. ■ Special labelling of certain compounds: Material safety data sheet available for professional users on request. ■ National regulations: ■ Classification under BetrSichV (Ordinance on Industrial Safety and Health): ■ Water hazard class: Water hazard class 3 (self-assessment): strongly hazardous for water. 16 Other information This information is based on our present state of knowledge; it is provided without any warranty of product features and shall not establish a legally valid contractual relationship. ■ Relevant risk phrases 21/22 Harmful in contact with skin and if swallowed. 34 Causes burns. ■ Department issuing the MSDS: Research and Development department ■ Validity: This MSDS supersedes all previous versions. ■ * Data modified compared to the previous version ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- D —