Name: Period: Date: PAP Scientific Measurement UNIT Booklet How do we measure how much matter is present in a sample? Student Goal: Read, analyze and interpret graphs and other representations of data Table of Contents Topic Page Number Measuring with Precision and Accuracy Precision vs. Accuracy Expressing errors in measurements Rules for calculating significant numbers Calculating with Sig Figs Rounding numbers rules Reading Instruments 2-3 3-4 7 4-5 5 9 6-7 Dimensional analysis Dimensional analysis steps Sample and practice problems 8 - 10 8 9- 10 Scientific Notation 11 Math Skills Review Manipulating variables review Chemistry Math Review Practice Problems 12-13 12 13 Density 14 - 18 14 14 15 16 16 - 17 17 - 18 What is Density? How is density related to an object’s ability to float? How do I solve problems related to density? Density example problems Deriving Information from a Graph Using Density DENSITY PRACTICE PROBLEMS Study Guide for Measurement Unit 18 - 21 Answers cannot be more precise that the least precise of the measurements. 1 Name: Period: http://www.chemistryland.com/CHM130S/02-MMM/Measure/Measuring.htm Date: OBJECTIVE: you will be able to understand and be able to apply the concepts of accuracy and precision. PRECISION VERSUS ACCURACY Define precision. Define accuracy. 1. Woody and Buzz ran an experiment to the spring constant of Slinky Dog dropping his back of a building and measuring the height he sprung back up. Their trials showed that Slink had the following measurements of force: 0.333 N, 0.454 N, and 0.222 N in their three trials. Hamm and Rex ran their own trials, and got 0.788 N, 0.780 N, and 0.788 N. Slinky told them his actual force was actually 0.350 N. a. What team was more precise? Why? b. What team was more accurate? Why? 2. Use box #2 to draw a picture that is more precise but less accurate than shown in picture #1. 3. Use the empty box to draw a picture that is more precise and accurate than in picture #1. Figure 1 2 Figure 2 Figure 3 4. Determine the accuracy and precision (Poor/Good) represented by each group of darts in the figures above. Explain your choices using complete sentences. Name: Period: Figure 1 Date: Figure 2 Figure 3 Precision? Accuracy? 4. Three students made multiple weighings of a copper cylinder, each using a different balance. Describe the accuracy and precision of each student’s measurements if the correct mass of the cylinder is 27.32 g. Hint: find the average mass for each student. Weighing 1 Weighing 2 Weighing 3 Weighing 4 Brian 27.92 26.99 27.40 27.50 Mass of Cylinder Calvin 27.98 27.96 27.97 27.99 Evelyn 27.30 27.33 27.32 27.31 Brian: Calvin: Evelyn: Expressing Errors in Measurement: Scientists often express their uncertainty and error in measurement by giving a percent error. The percent error is defined as: PRACTICE PROBLEMS 1. While doing a lab, a student found the density of a piece of pure aluminum to be 2.85g/cm 3. The accepted value for the density of aluminum is 2.70 g/cm 3. What was the student's percent error? 2. A student measured the specific heat of water to be 4.29 J/g · Co. The literature value of the specific heat of water is 4.18 J/g · Co. What was the student’ percent error? 3 Name: Period: Date: OBJECTIVE: you will be able to measure with accuracy and precision. Significant Figures: http://www.chemistryland.com/CHM130S/02-MMM/SigFigs/SignificantNumbers.html A. B. C. D. RULES FOR CALCULATING SIGNIFICANT FIGURES All Non –zero Digits ARE Significant (ie 1,2,3,4,5,6,7,8,9) All Leading Zeros ARE NEVER Significant (ie 0.000279) All Middle Zeros ARE Significant (ie 204) All Trailing Zeros ARE significant IF AND ONLY IF there is a DECIMAL in the Number (ie 2.0) EXAMPLE PROBLEMS 1. 23.50 2. 402 _____________sig figs. Rule (s) __________ _____________sig figs. Rule (s) __________ 3. 5,280 _____________sig figs. Rule (s) __________ 4. 0.080 ____________sig figs. Rule (s) __________ PRACTICE PROBLEMS I How many significant figures are there in each of the following numbers? 1) 2) 3) 4) 5) 6) 7) 27 ________________ 2700 ________________ 2700. ________________ 2700.0 ________________ 3 2.7 x 10 ________________ 3 2.70 x 10 ________________ 3 2.700 x 10 ________________ 8) .524 ________________ 9) 0.0524 ________________ 10) 0.0524 ________________ 11) 0.05240 ________________ -1 12) 5.24 x 10 ________________ -2 13) 5.24 x 10 ________________ -2 14) 5.240 x 10 ________________ Another way to find out the number of significant numbers: The Pacific-Atlantic Rule: _ _ _ _ _ _ Ocean _ _ _ _ _ _ _ Ocean ______________ ______________ To find the number of significant figures: 1. If the decimal point is _________, start on the ____________ side. If the decimal point is _________, start on the ____________ side. 2. Start counting digits with the first ______________ number that you reach. Then count all the digits in the direction determined above. 4 Name: Period: Date: PRACTICE PROBLEMS II How many significant figures are in the numbers listed below? _____ 3.9802 L _____ 10000 Kg _____ 40200 mL _____ 2005 N _____ 0.005709 g/mL _____ 298.009 atoms _____ 4.0001 cm _____ 284 moles Calculating with Sig Figs _ Add/Subtract - The # with the lowest decimal value determines the place of the last sig fig in the answer. (This is the measurement that is the LEAST precise) – Multiply/Divide - The # with the fewest sig figs determines the # of sig figs in the answer. • (This is the measurement that is the LEAST precise) Addition/Subtraction and Multiplication/Division Rules Add/Subtract: COUNT LEAST AMOUNT OF DECIMAL PLACES Multiply/Divide: COUNT LEAST AMOUNT OF SIG FIGS Rounding rules Look at the number behind the one you’re rounding. If it is 0 to 4 don’t change the number you want to round. If it is 5 to 9 make change the number you want to round to number bigger. PRACTICE PROBLEMS III Perform the following calculations using the correct number of significant figures: 1. 2.98+4.1 5. 3.098 + 238 2. 3.094-0.987465 6. 459.0 / 45 3. 452÷50 7. 2901 × 25.3 4. 2.7 × 6.0 8. 2.01 + 3 5 Name: Period: Date: READING INSTRUMENTS 1. Directions: Read the following instruments. Don't forget to include the correct number of significant figures and units. a. _________ b. _________ c. _________ d. _________ 2. You have two pieces of equipment. One reads 47 ml, and the other reads 47.00 ml. Explain why these measurements are different in terms of the marks found on each instrument 3. Name the following laboratory apparatus, and circle the one that will give the most precise results for measuring the volume of a liquid. c) a) b d) 6 3) Name: Period: Date: https://www.youtube.com/watch?v=uZ0ILIG_l7w 7 Name: Period: Date: OBJECTIVE: To be able to change units of measurement by using dimensional analysis. DIMENSIONAL ANALYSIS. http://www.chemistryland.com/CHM130S/02-MMM/DimensionalAnalysis/DimensionalAnalysis.htm Dimensional Analysis (also called Factor-Label Method or the Unit Factor Method) is a problem-solving method that uses the fact that any number or expression can be multiplied by one without changing its value. It is a useful technique. The only danger is that you may end up thinking that chemistry is simply a math problem - which it definitely is not. Unit factors may be made from any two terms that describe the same or equivalent "amounts" of what we are interested in. For example, we know that 1 inch = 2.54 centimeters We can make two unit factors from this information: Now, we can solve some problems. Set up each problem by writing down what you need to find with a question mark. Then set it equal to the information that you are given. The problem is solved by multiplying the given data and its units by the appropriate unit factors so that only the desired units are present at the end. (1) How many centimeters are in 6.00 inches? (2) Express 24.0 cm in inches. Dimensional Analysis Steps: 1. Begin by setting up the given value as a fraction. 2. Add a second term, being sure that the unit in the numerator of the first term ends up in the denominator of the second term, so that it can divide out (or vice versa, if the starting unit is in the denominator). 3. Be sure that the quantities in the numerator and denominator of each term are equivalent, even though their units are different. 4. Be sure to stop adding terms when you reach the unit of interest! 5. Cancel out any units that can be. 6. Solve. 8 Name: Period: Date: Dimensional analysis problems always involve a Given value and one or more conversion factors that allow you to determine the Desired value. Conversion factor Known Value (Given units) (Desired units) (Given units) Scientists generally work in metric units. Common prefixes used are the following: Prefix megakilocentimillimicronano- Abbreviation M k c m n Meaning 106 103 10-2 10-3 10-6 10-9 Example 1 megameter (Mm) = 1 x 106 m 1 kilogram (kg) = 1 x 103 g 1 centimeter (cm) = 1 x 10-2 m 1 milligram (mg) = 1 x 10-3 g 1 micrometer ( g) = 1 x 10-6 g 1 nanogram (ng) = 1 x 10-9 g Basic Units in the metric system: liter, grams, meter Useful conversion factors: LENGTH 1 inch = 2.54 cm 1 ft = 12 inches 1 mile = 5280 feet 1 mile = 1.61 km 1 m = 1.09 yards MASS 1 lb = 454 g 1 kg = 2.21 lb 1 lb = 16 oz FLUID VOLUME 1 L = 1.06 qt 4 qts = 1 gal 1 qt = 2 pints 1 pint = 2 cups Example problems: How many quarters in $120 dollars? Unkown = quarters; Knows: ? = = How many seconds are in 2.0years? Unknown: seconds; ? = 9 Knowns: 1 year 1 day 1 hour 1 minute _ = = = = 365 days 24 hours 60 minutes 60 seconds = Name: Period: Date: How many kilograms in 240.0 pounds? Unkown = ? Knows: = = PRACTICE PROBLEMS Use the following information for questions 1 through 4: Knowns: 3 blarps = 7 glorps 8 glorps = 17 trangs 1. How many slurps are in 107 kilps? 2. How many blarps are in 73 trangs? 3. How many kilps are in 3 blarps? 4. How many glorps are in 245 trangs? 10 11 trangs = 5 slurps 2 slurps = 23 kilps Name: Period: Date: OBJECTIVE: To be able to use scientific notation. SCIENTIFIC NOTATION http://www.purplemath.com/modules/exponent3.htm Scientific notation is __________________________________________________________ __________________________________________________________________________ How to express a number in scientific notation: 1. Move the decimal until there is one number to the _____________ of the decimal. You should now have a number that is between 1 and 10. 2. Count the number of places you have moved the decimal from its original location. This will be the ______________________. 3. If you moved the decimal to the __________, the exponent will be _______________. 4. If you moved the decimal to the _________, the exponent will be _______________. Examples: Express the following number in scientific notation: 1) 2) 3) 4) 5) 61,500 0.0000568 321 64,960,000 0.07085 _________________ _________________ _________________ _________________ _________________ How to change a number back from scientific notation: 1. Look at the exponent. If it is ____________, move the decimal point to the _________. 2. If it is ________________, move the decimal point to the ______________. 3. Move the decimal the number of spaces specified by the ______________________. Examples: Convert the following numbers from scientific notation to regular numbers: 1) 2) 3) 4) 5) 1.09 x 103 4.22715 x 108 3.078 x 10-4 9.004 x 10-2 5.1874 x 102 _________________ _________________ _________________ _________________ _________________ Convert the following numbers between standard notation and scientific notation. 11 Name: Period: OBJECTIVE: you will be able to manipulate equations to isolate variables. 12 Date: Name: Period: Date: Chemistry Math Review Practice Problems Answer the following questions 1) 2+4x3= 2) 4+2x3= 3) 2x4+3= 4) 2x4+3= 5) 40 + 20 = 10 6) 20 + 40 = 10 7) 40 + 20 = 10 8) 20 + 40 = 10 9) (4 + 3) ÷ 6 = 10) Solve the following equations for x 11) 2x = 8 4+3÷6= 12) 2 = 8x 13) x 8 2 14) x 2 8 15) 2 8 x 16) 8 2 x 18) x y 4 z 17) x y 4 z Answer the following questions 19) (3.0 x 104) + (6.3 x 105) 13 20. (3.0 x 108) x (6.3 x 107) Name: Period: Date: OBJECTIVES: you will be able to organize, analyze, evaluate, make inferences, and predict trends from data. Density OBJECTIVE: you will be able to understand and apply the concept of density. What is Density? DEFINITION FORMULA Density Mass Volume or D m V DENSITY What You are Measuring? Mass (m) Volume (V) Density (D) GRAPH Possible Units UNITS How is density related to an object’s ability to float? In the beaker below, draw your observations from today’s demonstration. If an object is less dense, which means that its density is a object will float. 14 number, then the Name: Period: Date: Example problem The table shows some properties of four different substances. The picture shows a solid sphere of one of the four substances in a water-ethanol solution, which has a density of 0.9199g/mL. The sphere is more likely composed of which substance? A. Substance Q B. Substance R C. Substance S D. Substance T Your Answer and Explanation: How do I solve problems related to density? Use the G.U.E.SS method G U E S S Given Unknown Equation Substitute Solve & box EXAMPLE PROBLEMS 1. What is the density of a piece of metal if the mass of the metal is 562 grams, and it occupies 44.9mL? 2. A box is determined to have a mass of 15.50g. Its dimensions are determined to be 2.4cm x 5.6cm x 6.70cm. What is the density of this box? Would this box float in water (D = 1.00g/mL)? What is water displacement and how do I use it to find the density of an object? Water displacement is used to determine the of an object by looking at the change in water level in a graduated cylinder. How do I know when to use it? Water displacement is usually used for irregular objects. In a problem, look for key words such as: 15 Name: Period: Date: o o Example Problems 1. Omar believes that he found a small piece of gold in the bus parking lot. After getting permission from Ms. Head to perform the experiment, Omar puts on his safety goggles and finds the mass of his object to be 45.2g. He then places the object in a graduated cylinder and notes that the water level rises 5.6mL. If the density of gold is 19.3g/cm3, did Omar find gold? Use calculations to justify your answer. 2. A student was unable to locate a ruler to measure a second metallic object. Its mass was 28.90g. He obtained a graduated cylinder which initially contained 35.0mL of water. When the metallic cylinder was placed into the graduated cylinder, the water level rose to 45.7mL. What is the identity of this metallic object? Use calculations to justify your answer. Silver Lead Gold Aluminum Density (g/cm3) 10.5 11.34 19.3 2.70 Deriving Information from a Graph Using Density Density relates a substance’s mass to its volume. If you have several samples of a single substance of different sizes, and measure the volume and mass of each sample, a plot of each measurement on a graph will produce a straight line. 1. Will the line’s slope be positive or negative? To answer, think about how the mass changes as the size (volume) of the sample increases. 2. The graph at right is the plot of the volumes and masses of the three pure gold bars. What is the density of gold? 3. Use the graph to determine the mass of 4 cm3 of gold. 4. Use your answer to #1 to determine: A. The mass of 8 cm3 of gold B. The volume of 200 grams of gold 16 Name: Period: Date: 5. Draw a line through the 3 points of the graph. The line should originate at (0,0). Does that make sense since density relates mass and volume? What mass would you expect a substance to have at zero volume? Would you expect all density plots to originate at (0,0)? Why/ why not? 6. What does the graph tell you about density and sample size? Does the density of a substance change with sample size, or will it always be the same for any one substance? Explain. 7. What is the relationship between density and slope on a mass vs volume graph? The illustration at right shows lines plotted from the data of three metal samples. 8. Which metal, A, B, or C has the highest density? Explain your reasoning. DENSITY PRACTICE PROBLEMS You must show all work using the GUESS method to receive full credit. “I did it in the calculator” does not count as work! Report your answer with the correct units and the proper number of significant figures. 1. What is the density of gas that occupies 4.5L and has a mass of 2.1g? 2. How much space would a 2.75g sample of a substance occupy, if it has a density of 0.993g/cm3? 3. What is the mass of an object that has a density of 5.0g/cm3 and a volume of 8.4cm3? 4. What is the mass of 20.6cm3 of iron? 17 Name: Period: Date: 5. What is the density of a 32.1g metallic box if its dimensions are 2.5cm by 6.0cm by 3.1cm? 6. A cube has a side that measures 8.0cm. The cube also has a mass of 400.0g. Would this cube float? Explain your answer. 7. Initially a student had a graduated cylinder with 21.4mL of water. After a 4.67g object is submerged in the water, the level reads 30.5mL. What is the density of the object? 8. A student has a piece of metal that has a mass of 45.3g and has a volume of 2.35cm3. What is the identity of the metal? Metal Density (g/cm3) Silver 10.5 Lead 11.34 Gold 19.3 Iron 7.87 9. According to the graph below, what is the density of the object? How did you find it? Study Guide for Unit 1 Test: Safety and Measurement Safety 6. What should you do if you spill an acid (i.e. what is different about spilling an acid versus other chemicals)? 7. Where do we meet if we have a fire drill? 8. What should you do before starting ANY lab? 9. What should you do before leaving ANY lab? 18 Name: Period: 19 Date: Name: Period: Date: Measurement 10. Express the following numbers in scientific notation. a. 10, 200 c. 0.102 b. 205,000,000 d. 0.000000000103 11. Express the following numbers in ordinary notation. a. 1.2x101 c. 6.801x105 b. 3.45x10-8 d. 7.4405x10-3 12. How many significant figures are present in each of the following measurements? 13. a. 0.0102m d. 50500s b. 2.00m e. 20L c. c. 20.L f. 2.30x103km Perform the following calculations and report the answers with the correct number of significant figures. a. 12.1m + 0.123m + 0.12m b. 7.50cm x 1.234cm c. 10200s – 3000s d. 20 1500000 g 30300mL Name: Period: Date: Dimensional analysis 14. How many kilograms are equal to350 grams? 15. How many pounds are equal to350 grams? 16. How many miles are in 44,982 inches? 17. A student determines the density of copper to be 9.19g/cm3. Calculate the percent error for this student’s experimental data if the accepted value for the density of copper is 8.94g/cm3 . 18. For each of the following students, explain whether their data is accurate, precise, both, or neither. Assume the accepted value for their measurement is 458.5. Student Name Zoe Jo Melissa Trial #1 458.43 462.78 468.47 Trial #2 458.5 451.33 468.52 Trial #3 458.49 475.89 468.45 Zoe: _________________________________________________________________ Joe: _________________________________________________________________ Melissa: ________________________________________________________________ Density 1. How much space would a 12.75g sample of a substance occupy if it has a density of 4.993g/cm3? 2. What is the mass of 20.6cm3 of lead if lead has the density of 11.34g/cm3 ? 3. What is the density of a 52.1g metallic box if its dimensions are 5.533cm by 6.00cm by 3.12cm? 4. Initially a student had a graduated cylinder with 11.4mL of water. After a 8.67g object is submerged in the water, the level reads 30.5mL. What is the density of the object? 21