Chemistry Semester 2 Final Exam Balance the following equations: NaOH (aq) + H3PO4 (aq) → Na3PO4 (aq) + H2O (l) Al + Fe2O3→Al2O3 + Fe What do these symbols mean in a chemical equation: s, l, g, aq Pb(NO2)2 + H2S→PbS + HNO2 Molar Mass: Substance Formula Molar Mass Mass of given sample bromine Br2 40.0 g carbon dioxide CO2 17.6 g sucrose C12H22O11 684.0 g hydrogen peroxide H2O2 510.0 g Number of moles Number of molecules Find the volume in liters of 60.0 g of NO₂ at STP. Calculate the volume in liters of 3.24x10^22 molecules. How many atoms in 6.8 L N₂O gas at STP? Stoichiometry: 1.) When sodium azide is activated in an automobile airbag, nitrogen gas and sodium are produced: 2NaN3(s) → 2Na(s) + 3N2(g) If 0.500 mol of NaN3 react, what mass in grams of nitrogen would result? 2.) What mass in grams of SO2 is needed to react completely with 1200. grams of O2 ? 2SO2(g) + O2(g) + 2H2O(l) → 2H2SO4(l) 3.) What mass of carbon (with excess water) is required to produce 1.00 mol CH4 in the following? 2C(s) + 2H2O(l) → CH4(g) +CO2(g) 4.) Calculate the number of moles of sodium oxide, Na2O, that will be produced when 5.00 moles of solid sodium completely react with oxygen gas. 5.) Using this reaction: 4 NH₃ + 7 O₂ ---> 4 NO₂ + 6 H₂O a) What mass of NO2 can be produced from 3.56 x 1022 molecules of oxygen? b) 13.8 g of NH3 would be able to produce how many moles of H2O? c) How many grams of O2 are needed to produce 15.5 g of H2O? 6.) What volume of sulfur dioxide gas is needed to produce 11.4 L of water vapor? SO₂ + 2H₂S 3S + 2H₂O Recognize and classify types of reactions What is STP? What is gas pressure? What causes it? What are Kelvins? Why is it used? What happens at 0K? Convert Celsius to Kelvins. How are pressure, temperature, and volume related? Explain the Kinetic Molecular Theory. Use the Combined Gas Law and Ideal Gas Law to solve: P₁V₁ = P₂ V₂ pV=nRT T₁ T₂ 1.) A gas has a pressure of 10.56 atm at 25 degrees Celcius. If gas is heated to 40 degrees C, what will the new pressure be? 2.) A 350 mL air sample collected at 35 C has a pressure of 550. torr. What pressure will the air exert if it is allowed to expand to 425 mL at 57 C? 3.) How many moles of a gas at 104 oC would occupy a volume of 6.9 L at 0.355 atm? What are the properties of Acids and Bases? How do Arrhenius vs. Bronsted-Lowry define acids and bases? What characterizes a strong acid/base? Where are acids/bases on the pH scale? Find pH from the [H⁺] or [OH⁻]. Define solution, solvent, solute, solubility. What factors affect solubility? How are gases different? What makes water unique? Shape, type of molecule, intermolecular forces, etc. Explain “Like Dissolves Like” What are electrolytes? What types of substances are electrolytes? How much substance can be dissolved in 150 g water if its solubility is 30g/100 g H₂O? Chemistry Semester 2 Final Exam What is the molarity of a soln that has 5 moles of solute in 2 liters soln? M=mol/volume What are the moles of solute in 300mL of a 0.5M soln? Describe Endothermic and Exothermic processes (include bond formation). Describe how energy flows. Sketch a phase change diagram. What happens to temperature during a phase change? How much heat is required to raise the temperature of 300.0 g of aluminum by 25°C? (C=0.88 J/gC) Q=mCΔT What is the specific heat if 3000 cal are required to raise 400g by 20°C? Explain relationship between a system and its surroundings. What happens at equilibrium? What factors affect the reaction rate? How does a catalyst work? Explain Le Chatelier’s Principle. Complete the chart for the following reaction: 9 KJ + 2 SO2(g) + O2(g) < -- > 2 SO3(g) Disturbance affect on SO₂ affect on O₂ affect on SO₃ Decrease SO₂ Increase O₂ Increase SO₃ Increase Pressure Decrease Temp What is entropy? What are the characteristic of a system with high entropy? Low entropy? Organic Chem: Practice naming and drawing structures, review worksheets Complete Charts: Prefix 1 2 Sketch Name Ending Numbered? alkane alkene 3 4 alkyne 5 side chain/ baby group Aldehyde 6 7 8 Ketone 9 Alcohol 10 Ether Ester Draw the following: 1. CH₃CH₂CH₂CH₂CH₃ 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 4-ethyl, 4-propyl decane 3-methyl, 3 ethyl heptane 2-butene 2,2,3-trimethyl pentane 4-methyl, 2-pentene 3-ethyl heptane 2-butene 3-hexanone 3-methyl octanal 4-ethyl, 2-nonanone 3,5 diethyl octanal Dipropyl ether Acid 14. 15. 16. 17. 18. 19. 20. 21. 3-hexanol 4-octanol 2,2- dimethyl, 3-heptene 6-methyl, 2,5 –nonadiene 2-methyl pentanoic acid Pentyl hexanoate Methyl propanoate 1,3 butadiene 22. Dimethyl ether Chemistry Semester 2 Final Exam Balance the following equations: NaOH (aq) + H3PO4 (aq) → Na3PO4 (aq) + H2O (l) Al + Fe2O3→Al2O3 + Fe What do these symbols mean in a chemical equation: s, l, g, aq Pb(NO2)2 + H2S→PbS + HNO2 Molar Mass: Substance Formula Molar Mass Mass of given sample Number of moles Number of molecules bromine Br2 159.8 40.0 g 0.250 1.51 E 23 carbon dioxide CO2 44.01 17.6 g 0.400 2.41 E sucrose C12H22O11 342.34 684.0 g 1.99 1.2 E hydrogen peroxide H2O2 34.02 510.0 g 15.0 9.02 E Find the volume in liters of 60.0 g of NO₂ at STP. 29.3 Calculate the volume in liters of 3.24x10^22 molecules. 1.26 L How many atoms in 6.8 L N₂O gas at STP? 1.83 E23 Stoichiometry: 1.) When sodium azide is activated in an automobile airbag, nitrogen gas and sodium are produced: 2NaN3(s) → 2Na(s) + 3N2(g) If 0.500 mol of NaN3 react, what mass in grams of nitrogen would result? 21.0 g 2.) What mass in grams of SO2 is needed to react completely with 1200. grams of O2 ? 2SO2(g) + O2(g) + 2H2O(l) → 2H2SO4(l) 4805 g 3.) What mass of carbon (with excess water) is required to produce 1.00 mol CH4 in the following? 2C(s) + 2H2O(l) → CH4(g) +CO2(g) 24.02 g 4.) Calculate the number of moles of sodium oxide, Na2O, that will be produced when 5.00 moles of solid sodium completely react with oxygen gas. 2.5 mol 5.) Using this reaction: 4 NH₃ + 7 O₂ ---> 4 NO₂ + 6 H₂O a) What mass of NO2 can be produced from 3.56 x 1022 molecules of oxygen? b) 13.8 g of NH3 would be able to produce how many moles of H2O? 1.21 mol c) How many grams of O2 are needed to produce 15.5 g of H2O? 32.1 g 6.) What volume of sulfur dioxide gas is needed to produce 11.4 L of water vapor? SO₂ + 2H₂S 3S + 2H₂O 5.7 L Recognize and classify types of reactions What is STP? What is gas pressure? What causes it? What are Kelvins? Why is it used? What happens at 0K? Convert Celsius to Kelvins. How are pressure, temperature, and volume related? Explain the Kinetic Molecular Theory. Use the Combined Gas Law and Ideal Gas Law to solve: P₁V₁ = P₂ V₂ pV=nRT T₁ T₂ 1.) A gas has a pressure of 10.56 atm at 25 degrees Celcius. If gas is heated to 40 degrees C, what will the new pressure be? 10.0 atm 2.) A 350 mL air sample collected at 35 C has a pressure of 550. torr. What pressure will the air exert if it is allowed to expand to 425 mL at 57 C? 485 torr 3.) How many moles of a gas at 104 oC would occupy a volume of 6.9 L at 0.355 atm? 0.0791 mol What are the properties of Acids and Bases? How do Arrhenius vs. Bronsted-Lowry define acids and bases? What characterizes a strong acid/base? Where are acids/bases on the pH scale? Find pH from the [H⁺] or [OH⁻]. Define solution, solvent, solute, solubility. What factors affect solubility? How are gases different? What makes water unique? Shape, type of molecule, intermolecular forces, etc. Explain “Like Dissolves Like” What are electrolytes? What types of substances are electrolytes? How much substance can be dissolved in 150 g water if its solubility is 30g/100 g H₂O? 45 g Chemistry Semester 2 Final Exam What is the molarity of a soln that has 5 moles of solute in 2 liters soln? M=mol/volume 2.5 M What are the moles of solute in 300mL of a 0.5M soln? 0.15 mol Describe Endothermic and Exothermic processes (include bond formation). Describe how energy flows. Sketch a phase change diagram. What happens to temperature during a phase change? How much heat is required to raise the temperature of 300.0 g of aluminum by 25°C? (C=0.88 J/gC) Q=mCΔT 6600 J What is the specific heat if 3000 cal are required to raise 400g by 20°C? 0.375 J/gC Explain relationship between a system and its surroundings. What happens at equilibrium? What factors affect the reaction rate? How does a catalyst work? Explain Le Chatelier’s Principle. Complete the chart for the following reaction: 9 KJ + 2 SO2(g) + O2(g) < -- > 2 SO3(g) Disturbance affect on SO₂ affect on O₂ affect on SO₃ Up Up Down Decrease SO₂ D D U Increase O₂ U U D Increase SO₃ Increase Pressure D D U Decrease Temp u U D What is entropy? What are the characteristic of a system with high entropy? Low entropy? Organic Chem: Practice naming and drawing structures, review worksheets Complete Charts: Prefix 1 2 Sketch Name alkane alkene 3 4 alkyne 5 side chain/ baby group Aldehyde 6 7 8 Ketone 9 Alcohol 10 Ether Ester Draw the following: 1. CH₃CH₂CH₂CH₂CH₃ 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 4-ethyl, 4-propyl decane 3-methyl, 3 ethyl heptane 2-butene 2,2,3-trimethyl pentane 4-methyl, 2-pentene 3-ethyl heptane 2-butene 3-hexanone 3-methyl octanal 4-ethyl, 2-nonanone 3,5 diethyl octanal Dipropyl ether 14. 3-hexanol Acid Ending Numbered?