CMS COLD BOX – CLEANING RISK ANALYSIS 04 December 2015 EDMS Prepared by: Prepared by Checked by Approved by Laetitia Bardo PH-CMX 1/16 TABLE OF CONTENT 1 SCOPE AND OBJECTIVES ............................................................................... 3 2 CLEANING PROCESS DESCRIPTION ................................................................... 3 2.1 Description .................................................................................................................................. 3 2.2 Location....................................................................................................................................... 4 2.3 VERTREL XF Risks and Properties ................................................................................................ 5 3 SAFETY MEASUREMENTS CONTINUOUSLY IMPLEMENTED....................................... 9 4 SCENARIOS STUDY.................................................................................... 10 4.1 Solvent Machine Leak in USC55 –S3 (underground area) ........................................................ 11 4.2 Solvent Machine transport in PM54 lift .................................................................................... 12 4.3 Leak during the disconnection of the solvent machine from the cold Box .............................. 13 4.4 Small leak of a pipe/equipment during the running ................................................................. 14 4.5 Power cut .................................................................................................................................. 15 5 DOCUMENTATION .................................................................................... 16 2/16 1 SCOPE AND OBJECTIVES Due to a pollution of Breox oil identified in the CMS cold box, a cleaning process will be performed during one month in the USC55 – CMS service cavern. The process is unusual. This cleaning has never been drawn up in underground areas. This document aims to analyse critical scenarios endangering people life and the environment and which might occur during different phases of the cleaning process. The goal is to insure that the risks are identified and controlled. Critical Scenarios identified: 1 2 3 4 5 2 Solvent machine in USC55 in S3 Transport of solvent machine filled in in the PM54 lift Leak during disconnection of the solvent machine from the cold box Small leak from the pipes/equipment Power cut (ventilation diesel) CLEANING PROCESS DESCRIPTION 2.1 Description The solvent machine which will be used has been built by an Italian company, MEG, according to CERN requirements. The solvent machine consists of 2 stainless-steel tanks of 1 m3 each, 1 purifier, 2 pumps, … A retention tank of 344L is installed under both tanks and the purifier. All retentions are connected to each other. The tanks containing the solvent are equipped with a high level sensor which stops the machine when activated. Total weight of the machine empty: 1 000 kg One tank weight: Purifier weight: Solvent Machine dimensions: Depth m x width m x height 1.50 m One tank dimension: Purifier dimension: Volume of solvent inside a tank: 1 m3 => 1600 kg The command of the solvent machine are executed via a touch screen, plus an emergency button is installed to stop the machine in case of emergency. The condenser, mixed water chiller and dry vacuum pump will be provided by CERN EN-CV. Total weight of the condenser empty: ??? kg Volume of solvent which might be inside: Where is located the exhaust of the cold box vent? 3/16 Figure 1 : Cleaning PDF – Extracted from CMS cryogenics review TE-CRG/C-Fabre Cleaning process Drying process Distillation 48-55°C depending on the product. Nitrogen exhaust at the surface. 2.2 Location The solvent machine will be located in USC55 in level-2 S3. 4/16 2.3 VERTREL XF Risks and Properties Extract from MSDS 5/16 6/16 7/16 Expansion: 1m3 of liquid solvent = 120 m3 gaseous phase 8/16 3 SAFETY MEASUREMENTS CONTINUOUSLY IMPLEMENTED Technical - Adapt the ventilation Cavern Volume = 2000 m3 air. Only fresh air pulsed : Flow rate= 10 000 m3/hour – (the air is warmed up) + “Brassage” = 30 000 m3/hour pulsing = 40 000 m3/hour pulsing Natural extraction through the pit Air renewed every 12 minutes – 5 renewal/hour - In case of emergency: Extraction (“désenfumage”) 20 000 m3/hour – test will be drawn up by Frederic Juban and he will also explanation on how to activate the system to CMS collaborators (To be completed: 16 5000, Antonio, Maf, Sandro,) -> to be planned Install aerolic connection on the “ desenfumage” system to collect the vapours at the source -> to be done by EN-CV If some areas seems not to be properly ventilated, extractors can be added –> extractors are ordered Portable ODH always worn by personnel intervening in USC55 and UXC55 -> the ODH detector triggered in presence of VERTREL XF Move one of the two ODH sensors located under the cold box Retention tank under the condenser -> check if the CMS retention tank are big enough Retention tank included in the solvent machine -> retention is >1m3 once the machine installed CO2 Fire extinguishers -> check that a sufficient amount of fire extinguisher are present on site. Obstructing plate -> Ordered Absorption kit already in USC55 level -2 S3 -> check if it is compatible with the product used Mobile shower -> to be ordered? + Retention for rinsing water Rinse eye already in USC55 level -2 S3 inside the absorption kit -> keep the absorption cabinet open Organisational - Fire brigade will be informed about the intervention and the risks present (provide the product MSDS) -> organise a visit Access limited -> put barriers level-1 and level-2 with panel indicating the reason, duration, contact person Check if shifters will be present during nights and weekends. If no check with the Fire Brigade if they can patrol the area. 9/16 Documentation - MSDS close to the tank Tank identified with the name of the product and risk pictograms Instruction what to do in case of spill -> to be adapted Instruction what to do in case of projection -> already existing Training - All persons intervening have followed the appropriate safety trainings and have the access to work in the USC55 cavern -> email sent Foreseen a specific training on site to get people -> organise a Safety briefing for people intervening to get familiar with the premises and safety equipment and procedure Chemical awareness on SIR online will be followed by all people intervening List among the people intervening which one are First-aider -> list of people intervening List among the people intervening which one followed the fire extinguisher training courses -> list of people intervening At least 1 chemist will always be on site during working hours - Additional safety measures will be implemented according to the scenario. 4 SCENARIOS STUDY Legend Csq: Cau: Consequence Cause Preventive/Protective actions State Decision Critical situation Remaining questions 10/16 4.1 Solvent Machine Leak in USC55 –S3 (underground area) 1 - Solvent machine leak Cau: Level High Cau: Manufacturing default Cau: Co-activity and transit LHC tunnel/CV room Damage of the machine while moving some objects Csq: Projection of VERTREL SION or XF on people Csq: Spill of VERTREL XF – 1 m3 People injured No Leak detected? Yes Cau: Liquid observed in the retention Caus: No body is in the area Csq: ODH Hazard in level -2 S3 Csq: Retention tank full Chemical in the retention Floor quality? Dispersion at level -3? ODH detectors? Yes No Floor/Air/Water pollution Personnel exposed to ODH ODH alarm Level -2/Level -3 is it tight? 11/16 4.2 Solvent Machine transport in PM54 lift Solvent Machine transport in PM54 Lift No Yes Lift Failure? Cau: Technical problem Csq: 1 m3 of chemical product stucked in the lift No Machine Leak? Yes Yes Machine Leak? No How do we detect the leak? Cau: damaged during the transport Cau: system not properly closed Csq: 1 m3 of chemical product spill in the PM54 pit Csq: Chemical vapours pushed in USC55 service cavern Csq: Exposure of personnel Csq: ODH Lift technicians intervention Solvent Machine leaking in the lift Solvent machines in S3 Acceptance weight inside the lift: 3000 kg Lift dimensions: Depth 2.70 m x width 1.85 m x height 2.70 m Number of lift travels needed: 3, but only two with big quantities of solvent The tank hooks for the transport cannot be used if the machine is full. Transport possible with Forklift? 12/16 4.3 Leak during the disconnection of the solvent machine from the cold Box Leak during disconnection solvent machine/Cold Box Cau: Product not expected still in the pipe Csq: Spill of 10/20L of chemical product in the level -1 and -2 on the floor and electrical equipment located in -2. Floor/Water pollution Power cut, short circuit Csq: exposition of personnel Diziness Csq: Projection of chemical product on people Depends on the product Skin Irritation/ Eye Burn 13/16 4.4 Small leak of a pipe/equipment during the running Stainless-steel pipes’ small leak Condenser’s leak Cau: Technical problem Cau: damaged during the operation Cau: Connection not tight Cau: Technical problem Cau: damaged during the operation How to fix the leak? Who shall be contacted? Csq: Continuous small release creating an accumulation of chemical product in some areas => ODH Oxygen deficiency Csq: Exposition of personnel Diziness Csq: Spill of “volume” of chemical product in chemical product in the level -1 and -2 on the floor and electrical equipment located in -2. Power cut, short circuit Floor/Water/Air pollution Water and floor pollution not taken into consideration for the case of pipes’ leak because the quantities are very small and the solvent will evaporate 14/16 4.5 Power cut Power cut Cau: Someone push on an AUG Cau: Incident in the area cutting the power Csq: Stop of the process Solvent remaining in the lines 15/16 5 DOCUMENTATION [1] MSDS VERTREL XF [2] INSTRUCTION_Projection Produit chimique, (FR) [3] Stockage des produits chimiques – Test du bac de rétention au point 5 – EDMS 1252049 16/16