Notes for Using an LED as a SPAD [Please read the student handout before going over these notes.] Brief background: In this experiment students build, test, and use a circuit with a very inefficient single photon avalanche diode (SPAD) – an inexpensive GaP light emitting diode (LED). With this device, students can explore the probabilistic nature of the arrival of photons at a detector, without using delicate and easily damaged SPADs or photomultiplier tubes, and without the need for any high voltages. The experiments compliment traditional experiments using radioactive decay. A SPAD uses a reverse biased p-n junction as the photon detector – in this case an LED. At the appropriate bias voltage, no current will flow ‘backward’ through the LED when no light is incident on the junction, but the absorption of a photon will produce an electron-hole pair that is quickly separated by the large electric field in the junction. The electrons are accelerated by the field and collide with other atoms, which produce additional excited electrons. The process continues (see figure), building up an ‘avalanche’ of electrons that produces a current/voltage pulse that is large enough to be measured. This process is analogous to the behavior of a Geiger-Müller tube. Avalanche Photodiodes – Geiger Mode • Reverse biased p-n junction Electron energy diagram E gap n photon p Vbias ~ 15 – 150V conduction band valence band n-doped p-doped Figure 1. Electron energy diagram in a reverse biased p-n junction. An absorbed photon creates an electron (solid circle) and a hole (empty circle). The large reverse bias voltage produces an electric field in the junction that accelerates the electrons toward the n-doped side. When an electron collides with an atom, its kinetic energy can be used to excite an additional electron into the conduction band. Inset: diagram of a reverse biased p-n junction. The voltage pulse produced may only be a few hundred millivolts, so it can be helpful to use a comparator to condition the pulses up to the common 5V digital level. (A comparator is basically an op-amp without any feedback, so that the output of the op-amp is bistable – ‘high’ when the voltage at the + input terminal is greater than the voltage at the – input terminal, and ‘low’ when the reverse is true.) The LED used in this experiment is obviously not designed to detect light, and so its quantum efficiency is extremely low. We would probably never want to use this as an actual light sensor, unless the light sources were quite bright. However, this means that students can do the experiments in ambient light, without worrying about damaging the detector. The data collected are the times that the electrical pulses occur and how frequently they occur. Measurements of the number of the pulses (‘events’ or ‘counts’) during a specific time interval ought to be described by the Poisson distribution, if the pulses occur randomly. Similarly, the distribution of the times between the pulses ought to be described by an exponential distribution. Students can collect and analyze this data in exactly the same way that they might for radioactive decay measurements. Counts per Interval 700 80 Gaussian 2 red 500 = 57.8 Gaussian 2red = 1.50 60 Frequency Frequency Poisson 2red = 2.02 Poisson 2red = 2.57 600 400 300 200 40 20 100 0 0 1 2 3 4 5 0 0 6 5 10 15 20 25 cts per 0.15s cts per 0.015s 50 Poisson 2red = 3.01 40 Frequency • Compare to Poisson and Gaussian predictions for same mean and s. • Gaussian approximates Poisson for large mean values • s2 > mean due to ‘afterpulsing’ Gaussian 2red = 0.997 30 20 10 0 80 90 100 110 120 130 140 150 cts per 1.5s Figure 2. The distribution of the number of photons (counts) detected in intervals of 0.015s, 0.15s, and 1.5s. The data visually appears to be described by a Poisson distribution, but the reduced 2 value indicates that there is not quantitative agreement. The disagreement results from the variance of the distribution being greater than the mean due partly because of afterpulsing. Afterpulsing One crucial aspect of the behavior of SPADs is afterpulsing. After a photon initiates an avalanche, it is possible for an electron in the p-n junction to be left in an excited state, and if that electron gains enough energy (usually thermal energy) to obtain the conductance band, a second avalanche will occur, without a photon initiating it. So, a single photon can cause not one, but a sequence of two or more pulses that are not independent and that occur at very short time intervals. Afterpulsing can show up in the data as non-Poisson distributions (since some of the pulses are no longer random), and as a large spike at short times when examining the time between pulses. Figure 3. The distribution of the time between pulses (events). The data shows the expected exponential behavior, but with a significant deviation at short times - the result of afterpulsing. Dead time and pulse widths By varying the value of the resistor in series with the LED/SPAD, the RC time constant of the circuit can be controlled. This effectively controls the dead time of the detector (the time during which the detector cannot register the arrival of a photon). Figure 4. Left: Pulses produced by the comparator for four different values of the resistance in series with the LED, showing the increase in the time constant. Right: The distribution of the time between events (data shown for short times only). As the pulse width increase, the apparent dead time of the circuit (the range where the number of counts is too low) increases also – showing that photons arriving during a pulse cannot be counted. Vary Pulse Width to Determine Capacitance Vbias 80 = (62.3 1.3 s) 3.2pF) R+ (-0.8 R Pulse width (s) 60 40 20 0 0 200 400 600 800 Resistance (k) 1000 Pulse width is determined by the time constant of RC circuit: = R*C The slope gives the capacitance of the circuit. Figure 5. Data showing how the average pulse width varies linearly with the resistance in series with the LED. The slope of the line gives the capacitance of the circuit, which is mainly due to the LED. Additional exploration: Students can extend this experiment to look at temperature effects, spectral response, material variation, etc. There is a huge parameter space for students to explore with this experiment. Equipment list: Andor AND-114R LED ($0.279 for quantities less than 100, Newark.com ) LM311N/NOPB comparator ($0.91 for qty less than 10, Mouser.com) 10k potentiometer (T63YB103KT20, $2.86 for qty less than 10, Mouser.com) 5V, 15V, and 0-30V DC power supplies Electronic breadboard/protoboard Two channel storage oscilloscope (>100 MHz if possible) Pulse counter/interval timer, LabView &DAQ, LabQuest, etc. Building and adjusting the circuit The construction of the circuit is quite straight forward, but students will need to know/learn/discover a few things in order to be successful: - - - - The proper orientation of the LED (I encourage them to determine the forward bias direction of the Andor AND114R LED by applying a voltage to see light emission) The proper choice of the reverse bias voltage. For these LEDs, this voltage is ~24V. While this is much lower than the ~100V bias voltage used in some SPADs, students are often reluctant to raise the voltage above 5V for fear of damaging something. Students can use an oscilloscope to monitor the voltage signal sent to the positive input of the comparator as they raise the bias voltage. A power supply with a fine voltage control knob is best. Too high of a bias voltage is also a problem - students need to be sure that when no light is incident on the LED, no (or very few) pulses are produced. The proper choice of the passive quenching resistor (100-900 k), which determines the RC time constant of the circuit and therefore the duration of the pulse produced by the LED. I encourage students to explore how this resistance determines the dead time of the detection circuit – which can be directly measured by collecting data on the time between the pulses. How to properly choose the resistance of the 10 k potentiometer. I’ve found this to be a valuable place for students to struggle – because of the direct correlation between this comparator circuit and the ‘trigger level’ of an oscilloscope. Students can monitor the pulses from the LED on one channel of an oscilloscope, and the voltage level at the negative input of the comparator on a second channel of the oscilloscope. They can then visually bring the comparison voltage down to below the peak value of the pulses. Observant students will quickly understand that the choice of the ‘trigger level’ has an impact on how many pulses are missed and therefore not counted. On the output of the comparator, the choice of the ‘pull-up’ resistor is important, particularly if the device used to measure the output pulses has a low internal resistance. Using a Vernier LabQuest to collect data The signal from the op-amp can be sent to the digital input of a Vernier LabQuest to be detected. Telling the LoggerPro software that it is connected to a Radiation Monitor allows students to quickly and easily collect ‘events per time interval’ data that can be compared to Poisson and Gaussian distributions. To obtain information regarding the times of the photon arrival events, the LabQuest can be set as if it were connected to a Photogate. LoggerPro provides several functions that let students easily calculate the time between the events that they can then compare to an exponential distribution and examine the dead time of the circuit. Figure 6. A picture of the SPAD circuit. The decade resistor is used to vary the resistance in series with the LED. Using LabView to collect data A simple LabView VI, along with a ‘fast enough’ DAQ can be used to collect both the number of pulses from the LED and the times that the pulses occur. An example is shown in the Figures 7 and 8. We’ve used a USB 6251 (1.25 MS/s) DAQ to collect data both from the output of the op-amp as well as directly from the LED itself. The crucial part of the LabView program is the “Threshold Detector.vi” that is used to determine when a peak occurs. Figure 7. The front panel of a LabView VI to count the number of pulses and the times at which the pulses occur. Figure 8. The Block Diagram of the LabView VI shown in Figure 7. Useful references about SPADs S. Cova , M. Ghioni , A. Lotito , I. Rech & F. Zappa “Evolution and prospects for single-photon avalanche diodes and quenching circuits”, J. Mod. Opt., 51 (9-10), 1267-1288 (2004). S. Cova, M. Ghioni, A. Lacaita, C. Samori, and F. Zappa, “Avalanche photodiodes and quenching circuits for single-photon detection”, Appl. Opt. 35 (12), 1956 – 1976 (1996). V. A. Krasnov, S. V. Shutov, Yu. M. Shwarts, and S. Yu. Yerochin, “Note: Determination of temperature dependence of GaP bandgap energyfrom diode temperature response characteristics” Rev. Sci. Instrum. 82, 086109 (2011) A. Gallivanoni, I. Rech, and M. Ghioni, “Progress in Quenching Circuits for Single Photon Avalanche Diodes”, IEEE Trans. Nuc. Sci., 57 (6), 3815-3826 (2010) F. K. Reinhart, “Reverse-Biased Gallium Phosphide Diodes as High-Frequency Light Modulators,” J. Appl. Phys. 39 (7), 3426 – 3434 (1968).