Accreditation and Quality Assurance, Springer, Berlin Heidelberg, 2015.
Saioa Elordui-Zapatarietxe 1, Ina Fettig 2, Janine Richter 2, Rosemarie Philipp 2, Fanny Gantois 3, Béatrice Lalère 3, Claudia Swart 4 and Håkan
Emteborg.
Interaction of 15 priority substances for water monitoring at ng L-1 levels with glass-, aluminium- and fluorinated polyethylene bottles for the
containment of water reference materials.
1
European Commission, Joint Research Centre, Institute for Reference Materials and Measurements (IRMM), Retieseweg 111, 2440 Geel,
Belgium.
2
Bundesanstalt für Materialforschung und –prüfung (BAM) , Richard-Willstätter-Str. 11,12489 Berlin, Germany.
3
Laboratoire National de Métrologie et d'Essais (LNE), 5, Avenue Albert Bartholomé, 75015 Paris, France.
4
Physikalisch-Technische Bundesanstalt (PTB), Bundesallee 100, 38116 Braunschweig, Germany.
Corresponding author: hakan.emteborg@ec.europa.eu
Electronic supplementary material Table 1: Individual recoveries (%) of the spiked PAHs (n=2) in the tested containers at
different sampling periods. N: naphthalene; A; anthracene, F: fluoranthene; BaP: benzo(a)pyrene; BbF: benzo(b)fluoranthene; BkF:
benzo(k)fluoranthene; BghiP: benzo(g,h,i)perylene; I: indeno(1,2,3-cd)pyrene.
Glass bottles
3h
Volume (mL)
24 h
72 h
192 h
500
1000
2000
500
1000
2000
500
1000
2000
500
1000
2000
N
98/101
100/100
99/100
97/97
99
99/100
94/95
96/99
98/99
5/24
6/17
8/10
A
90/92
88/89
86/86
83/84
85/90
84/84
73/74
75/77
77/77
13/30
12/21
12/19
F
92/93
92/92
92/92
90/90
93/93
93/94
89/91
91/93
93/94
82/82
- /89
84/90
BbF
88/92
90/90
93/93
89/89
89/92
90/91
90/91
91/91
90/92
80/84
87/90
84/91
BkF
96/97
97/100
99/103
93/95
93/97
97/99
92/95
92/94
95/97
83/85
89/92
87/95
BaP
86/90
88/89
92/93
76/77
77/77
78/79
62/63
65/65
66/68
45/44
47/49
50/50
I
91/92
90/94
93/97
88/90
91/93
92/94
87/89
89/93
89/90
77/81
86/87
83/89
BghiP
91/98
93/96
93/97
91/91
92/92
93/96
88/89
88/92
89/90
75/83
87/87
83/88
Electronic supplementary material Table 1: Individual recoveries (%) of the spiked PAHs (n=2) in the tested containers at
different sampling periods. N: naphthalene; A; anthracene, F: fluoranthene; BaP: benzo(a)pyrene; BbF: benzo(b)fluoranthene; BkF:
benzo(k)fluoranthene; BghiP: benzo(g,h,i)perylene; I: indeno(1,2,3-cd)pyrene.
FPE bottles
3h
Volume (mL)
24 h
72 h
192 h
500
1000
2000
500
1000
2000
500
1000
2000
500
1000
2000
N
100/100
99/100
98/98
98/102
96/97
98/100
97/98
92/96
97/98
3/7
6/13
2/9
A
93/95
82/90
85/89
84/84
77/77
76/83
67/69
55/62
63/66
10/12
6/9
4/10
F
87/88
87/88
86/86
86/90
83/84
85/86
81/81
77/80
83/84
67/67
61/66
66/73
BbF
76/76
76/78
74/76
43/63
58/59
57/59
45/53
48/54
51/54
46/47
41/45
44/47
BkF
84/84
83/84
83/88
47/67
63/63
63/66
49/55
48/54
56/60
46/48
40/44
44/45
BaP
73/76
73/73
71/73
36/51
45/46
45/46
28/31
26/31
28/29
16/18
16/18
16/18
I
78/79
77/79
78/81
36/50
46/46
49/50
29/38
29/36
37/38
30/31
31/35
32/33
BghiP
75/76
77/77
77/79
36/51
48/49
51/52
30/39
31/40
39/41
33/33
33/37
34/35
Electronic supplementary material Table 1: Individual recoveries (%) of the spiked PAHs (n=2) in the tested containers at
different sampling periods. N: naphthalene; A; anthracene, F: fluoranthene; BaP: benzo(a)pyrene; BbF: benzo(b)fluoranthene; BkF:
benzo(k)fluoranthene; BghiP: benzo(g,h,i)perylene; I: indeno(1,2,3-cd)pyrene.
Aluminium bottles
3h
Volume (mL)
24 h
72 h
192 h
500
1000
2000
500
1000
2000
500
1000
2000
500
1000
2000
N
92/101
99/101
88/98
96/98
99/101
92/95
95/95
98/99
85/85
8/10
3/4
2/4
A
89/95
94/95
94/97
87/87
86/87
86/87
72/72
75/75
71/71
11/11
8/8
3/5
F
88/94
96/97
98/99
93/95
94/96
95/96
92/92
95/95
95/95
81/82
85/87
81/83
BbF
87/92
91/93
94/95
93/93
91/92
93/95
90/91
89/92
92/95
87/87
85/87
85/87
BkF
88/97
96/97
98/99
92/95
95/96
95/98
90/91
90/94
94/96
82/83
83/86
85/85
BaP
82/98
86/88
90/94
73/74
73/74
80/81
54/57
57/59
64/65
36/36
41/42
38/40
I
96/90
93/95
97/102
91/92
86/88
94/96
85/88
80/86
92/94
72/75
74/75
80/82
BghiP
90/99
91/94
95/99
90/92
85/86
90/94
84/88
82/84
90/93
70/74
73/74
78/78
Electronic supplementary material Table 2: Individual recoveries (%) of the spiked PBDEs (n=2) in the tested containers at
different sampling periods.
Glass bottles
3h
Volume (mL)
24 h
72 h
192 h
500
1000
2000
500
1000
2000
500
1000
2000
500
1000
2000
BDE28
93/100
107/109
96/105
93/99
101/116
97/99
89/93
90/101
93/103
35/50
51/54
75/77
BDE47
92/102
108/110
89/97
101/119
92/101
91/101
98/102
78/100
94/96
55/66
42/43
71/75
BDE99
80/106
82/90
104/105
97/98
86/87
101/109
72/98
66/82
91/103
30/35
47/50
76/80
BDE100
84/95
82/90
98/103
88/88
78/89
96/109
83/85
83/57
85/104
28/46
39/40
72/77
BDE153
98/98
98/112
76/89
98/98
96/99
74/84
83/85
79/92
75/94
33/34
68/73
55/55
BDE154
82/89
86/87
87/94
88/94
83/88
82/92
85/86
55/77
86/88
35/38
47/52
63/64
Electronic supplementary material Table 2: Individual recoveries (%) of the spiked PBDEs (n=2) in the tested containers at
different sampling periods.
FPE bottles
3h
Volume (mL)
24 h
72 h
192 h
500
1000
2000
500
1000
2000
500
1000
2000
500
1000
2000
BDE28
86/104
89/89
75/78
68/92
88/96
73/73
50/82
85/85
58/62
33/50
36/56
47/48
BDE47
95/114
81/86
65/67
84/91
75/75
56/57
80/101
69/76
42/48
62/68
55/56
38/41
BDE99
87/88
76/79
74/76
64/76
62/63
46/59
53/73
41/55
35/39
41/47
21/45
24/29
BDE100
62/72
62/62
67/68
39/53
45/48
55/57
28/47
46/49
42/47
36/37
26/46
33/38
BDE153
70/71
62/65
86/92
41/49
37/39
72/75
49/49
30/33
59/66
27/30
36/42
56/57
BDE154
83/86
77/79
77/78
57/57
55/57
60/64
55/60
52/52
43/53
40/47
46/46
40/41
Electronic supplementary material Table 2: Individual recoveries (%) of the spiked PBDEs (n=2) in the tested containers at
different sampling periods.
Aluminium bottles
3h
Volume (mL)
24 h
72 h
192 h
500
1000
2000
500
1000
2000
500
1000
2000
500
1000
2000
BDE28
73/80
105/105
86/98
88/94
100/108
97/101
92/100
103/109
103/107
83/91
82/95
94/100
BDE47
126/133
114/124
98/99
138/144
111/126
101/102
115/119
89/90
99/100
101/110
67/83
96/97
BDE99
54/59
87/103
95/100
92/97
92/101
98/99
94/98
88/94
87/99
81/87
57/60
92/94
BDE100
64/72
85/91
98/100
82/90
86/90
95/98
79/82
83/84
97/97
66/77
62/67
89/92
BDE153
92/95
92/93
95/102
79/87
87/89
92/95
81/81
74/80
96/100
61/71
58/73
79/85
BDE154
92/102
91/99
88/93
79/88
87/93
94/96
81/87
74/86
93/96
69/74
59/70
80/89