ABSCISIC ACID A B C D CAS # 14375452 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. Store under nitrogen. Light sensitive. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. Store at -20°C SPECIAL REQUIREMENTS Light sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACACIA A CAS # 9000015 Special Carcinogen E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 16000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 200 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACENAPHTHENE A B C D CAS # 83329 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 1.5 mm Hg @ 20 °C FLASH POINT 257 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi N Indication of Danger: Irritant. Dangerous for the environment. R: 36/37/38 50/53 Risk Statements: Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37/39 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1.25 mg/m3 DOE Ceiling Limit 7.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACENAPHTHENEQUINONE A B C D CAS # 82860 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACENAPHTHYLENE A B C D CAS # 208968 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5677.4 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 251.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .06 mg/m3 DOE Short Term Exposure Limit .2 mg/m3 DOE Ceiling Limit 1.25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACES A B C D CAS # 7365824 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETALDEHYDE A B C D CAS # 75070 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . G H I J NFPA HAZARD CODES (H,F,R,O) 3 4 2 REPRODUCTIVE RISK INDEX 2.1 ACUTE TOXICTY RISK INDEX 2.9 - LD50 661.0 mg/Kg NEUROTOXIC - RISK INDEX 1.0 INHALATION HAZARD INHALATION RISK INDEX 4.1 - LC50 K L 20100.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Lachrymator. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Photosensitizer. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Lungs. Cardiovascular system. Liver. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Pulmonary edema. Effects may be delayed. Nausea. Vomiting. Headache. Blurred vision. Unconsciousness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable Explosive VAPOR PRESSURE 756.4 mm Hg @ 20 °C FLASH POINT -40 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area Forms explosive unstable peroxides Test periodically or discard SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Oxidizing agents, Reducing agents, Acids, Nitric acid, Peroxides, Bases, Caustic soda, Amines, Ammonia, Oxygen Warning: acetaldehyde is oxidized rapidly and exothermically by air, to acetic acid, Acid anhydrides, Alcohols, Halogens, Ketones, P FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep container closed. Keep away from heat, sparks, and open flame. Store under nitrogen. Store under inert gas. May develop pressure. Air sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Open carefully. Avoid all contamination. Always open containers slowly to allow any excess pressure to vent. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store under nitrogen\. Store at 2-8░C SPECIAL REQUIREMENTS Store under inert gas. May develop pressure. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F+ Xn Indication of Danger: Extremely Flammable. Harmful. R: 12 36/37 40 Risk Statements: Extremely flammable. Irritating to eyes and respiratory system. Limited evidence of a carcinogenic effect. S: 16 33 36/37 Safety Statements: Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. Wear suitable protective clothing and gloves. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 100 ppm OSHA Short Term Exposure Limit 150 ppm ACGIH RECOMMENDED LIMITS ACGIH Ceiling Limit 25 ppm Immediately Dangerous to Life and Health US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 45 ppm DOE Ceiling Limit 270 ppm 2000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETALDEHYDE DIMETHYL ACETAL A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 534156 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 2 - LD50 6500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 11035.1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 1 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure\. Refrigerate before opening. STORAGE: Store under inert gas. Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Store under inert gas. Refrigerate before opening. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 9 16 33 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETALDEHYDE OXIME A B C D CAS # 107299 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. S: 26 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDE A B C D CAS # 60355 HAZARDOUS CHEMICAL OF CONCERN Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 7000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 38576.3 J K ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .310 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC . INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 40 Risk Statements: Limited evidence of a carcinogenic effect. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 mg/m3 DOE Short Term Exposure Limit 75 mg/m3 DOE Ceiling Limit 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDEPHENYLBORONIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 101251096 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Boron oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDINE HYDROCHLORIDE CAS # 124425 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOACRYLIC ACID (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 5429561 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOBENZALDEHYDE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 122850 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Blood effects. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Mineral acids, Phenol. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOBENZENESULFONYL CHLORIDE (4-) OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 121608 Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARDOUS CHEMICAL Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 1 W ACUTE TOXICTY RISK INDEX 2.2 - LD50 3200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 37 Risk Statements: Harmful if swallowed. Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOBENZOIC ACID (PARA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 556081 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOCINNAMIC ACID (ALPHA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5469454 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Hygroscopic. Keep container closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place. Store at 2-8░C SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOPHENOL (2-) A B C D CAS # 614802 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 125.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Rabbit 500 mg 24H Remarks: Mild irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOPHENOL (3-) A B C D CAS # 621421 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 196.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAMIDOPHENOL (4-) A B C D CAS # 103902 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . H . NFPA HAZARD CODES (H,F,R,O) 1 0 1 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2404.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETANILIDE A B C D CAS # 103844 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 3 Dermal Hazard Corrosive Eye Damage STEL . . 1 . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . ACUTE TOXICTY RISK INDEX 2.8 - LD50 INHALATION RISK INDEX 1.4 - LC50 800.0 mg/Kg ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .180 mm Hg @ 20 °C FLASH POINT 321.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1 mg/m3 DOE Ceiling Limit 7.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETAZOLAMIDE A B C D CAS # 59665 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 13871.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. L Eye SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Eyes. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Headache. Fatigue. Anorexia. Gastrointestinal disturbances. Drowsiness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETHYDRAZIDE A B C D CAS # 1068571 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A . C . . F G . . . NFPA HAZARD CODES (H,F,R,O) 0 1 1 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.2 - TD50 31.8 mg/Kg EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 42.2 mg/Kg INHALATION RISK INDEX <1 - LC50 K . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/38 Risk Statements: Harmful if swallowed. Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETIC ACID A B C D CAS # 64197 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3310.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Kidneys. SIGNS AND SYMPTOMS OF EXPOSUR To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid VAPOR PRESSURE 11.4 mm Hg @ 20 °C SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10-35 Risk Statements: Flammable. Causes severe burns. S: 23-26-45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 35 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETIC ACID-D A B C D CAS # 1186523 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3310.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Lachrymator. Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Ingestion or inhalation of concentrated acetic acid causes damage to tissues of the respiratory and digestive tracts. Symptoms include: hematemesis, bloody diarrhea, edema and/or perforation of the esophagus and pylorus, hematuria, anuria, uremia, albuminuria, hemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, cardiovascular collapse, shock, and death. Direct contact or exposure to high concentrations of vapor with skin or eyes can cause: erythema, blisters, tissue destruction with slow healing, skin blackening, hyperkeratosis, fissures, corneal erosion, opacification, iritis, conjunctivitis, and possible blindness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE Severe, acute pancreatitis may occur after ingestion of concentrated acetic acid. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 11.4 mm Hg @ 20 °C FLASH POINT 104 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Oxidizing agents, Soluble carbonates and phosphates, Hydroxides, Oxides, Metals, Peroxides, Permanganates, Amines, Alcohols. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10 35 Risk Statements: Flammable. Causes severe burns. S: 23 26 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETIC ACID-D A B C D CAS # 758123 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3310.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 . . . ROUTE OF EXPOSURE skin Absorption: Harmful if absorbed through skin. Inhalation: May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Teeth. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Ingestion or inhalation of concentrated acetic acid causes damage to tissues of the respiratory and digestive tracts. Symptoms include: hematemesis, bloody diarrhea, edema and/or perforation of the esophagus and pylorus, hematuria, anuria, uremia, albuminuria, hemolysis, convulsions, bronchitis, pulmonary edema, pneumonia, cardiovascular collapse, shock, and death. Direct contact or exposure to high concentrations of vapor with skin or eyes can cause: erythema, blisters, tissue destruction with slow healing, skin blackening, hyperkeratosis, fissures, corneal erosion, opacification, iritis, conjunctivitis, and possible blindness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 7.6 mm Hg @ 20 °C FLASH POINT 104 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Soluble carbonates and phosphates, Hydroxides, Oxides, Metals, Acid anhydrides, Peroxides, Permanganates, Amines. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not get in eyes, on skin, on clothing. Do not breathe vapor. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10 35 Risk Statements: Flammable. Causes severe burns. S: 23 26 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 50 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETIC ANHYDRIDE A B C D CAS # 108247 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G H . NFPA HAZARD CODES (H,F,R,O) 3 2 1 W ACUTE TOXICTY RISK INDEX 3 - LD50 1780.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 4166.9 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.0 mm Hg @ 20 °C FLASH POINT 120.2 °F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Bases, Reducing agents, Finely powdered metals, Alcohols, Acids, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. Store at 2-8°C Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Reacts violently with water. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store at 2-8░C SPECIAL REQUIREMENTS Reacts violently with water. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10-20/22-34 Risk Statements: Flammable. Harmful by inhalation and if swallowed. Causes burns. S: 26-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Ceiling Limit 5 ppm OSHA Ceiling Limit 20 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 5 ppm ACGIH Ceiling Limit 21 ppm Immediately Dangerous to Life and Health 200 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 ppm DOE Short Term Exposure Limit 5 ppm DOE Ceiling Limit 5 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOACETANILIDE A B C D CAS # 102012 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 1 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1600.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 325 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 21/22 Risk Statements: Harmful in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOACETIC ACID ETHYL ESTER A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 141979 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3980.0 mg/Kg INHALATION RISK INDEX 1.3 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .700 mm Hg @ 20 °C FLASH POINT 185 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 50 mg/m3 DOE Ceiling Limit 350 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ACETOACETIC ACID ETHYL The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOL A B C D CAS # 116096 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2200.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 5.6 mm Hg @ 20 °C FLASH POINT 132.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep container closed. Keep away from heat, sparks, and open flame. Hygroscopic. Store under inert gas. Air sensitive. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and vapor. Avoid prolonged or repeated exposure. Keep away from heat, sparks, and open flame. REQUIREMENTS Hygroscopic. Store under inert clothing. Do not breathe STORAGE: Keep container closed. Store at 2-8░C SPECIAL gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 200 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETONAPHTHALENE (1'-) CAS # 941980 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1560.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETONAPHTHONE (2'-) A B C D CAS # 93083 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1032.8 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 334.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETONE A B C D CAS # 67641 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . . H I . NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5800.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 3.0 - LC50 . L 13640.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 184.0 mm Hg @ 20 °C FLASH POINT 1 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Bases, Oxidizing agents, Reducing agents Acetone reacts violently with phosphorous oxychloride. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36 66 67 Risk Statements: Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapors may cause drowsiness and dizziness. S: 9 16 26 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 750 ppm OSHA Short Term Exposure Limit 1000 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 500 ppm ACGIH Short Term Exposure Limit 1000 ppm Immediately Dangerous to Life and Health 2500 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 200 ppm DOE Short Term Exposure Limit 200 ppm DOE Ceiling Limit 3200 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETONE-D6 A B C D CAS # 666524 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . . H I . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5800.0 mg/Kg NEUROTOXIC - RISK INDEX 2.0 INHALATION HAZARD INHALATION RISK INDEX 3.0 - LC50 . L 13640.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Causes dermatitis. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 184.0 mm Hg @ 20 °C FLASH POINT -2.2 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Materials to Avoid: B FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under inert gas\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36 66 67 Risk Statements: Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapors may cause drowsiness and dizziness. S: 9 16 26 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 750 ppm OSHA Short Term Exposure Limit 1000 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 500 ppm ACGIH Short Term Exposure Limit 1000 ppm Immediately Dangerous to Life and Health 2500 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 200 ppm DOE Short Term Exposure Limit 200 ppm DOE Ceiling Limit 3200 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETONITRILE A B C D CAS # 75058 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . G H I J NFPA HAZARD CODES (H,F,R,O) 2 3 0 REPRODUCTIVE RISK INDEX 1.9 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2460.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.9 - LC50 K . 9475.0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. Blood. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE The onset of symptoms is generally delayed pending conversion to cyanide. This material can produce a cyanide like effect. Always have a cyanide first-aid kit present when using this material. Adverse effects may include nausea, vomiting, diarrhea, headache, dizziness, rashes and cyanosis. Other symptoms include mental excitement or depression, drowsiness, impaired perception, incoordination, stupor, coma, and death. CONDITIONS AGGRAVATED BY EXPOSURE Acetonitrile is metabolized in the liver to water, formic acid, and hydrogen cyanide. The cyanide is further metabolized to thiocyanate. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 72.8 mm Hg @ 20 °C FLASH POINT 35.6 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Reducing agents, Alkali metals. FIRE EXTINGUISHER: For small (incipient) fires, use media such as foam,dry chemical, or carbon dioxide. For large fires, use media such as foam, dry chemical, carbon dioxide or water. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F-Xn Indication of Danger: Highly Flammable. Harmful. R: 11-20/21/22-36 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes. S: 16-36/37 Safety Statements: Keep away from sources of ignition - no smoking. Wear suitable protective clothing and gloves. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 40 ppm OSHA Short Term Exposure Limit 60 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 20 ppm ACGIH Short Term Exposure Limit 60 ppm Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 40 ppm DOE Short Term Exposure Limit 60 ppm DOE Ceiling Limit 60 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOPHENETIDIN A B C D CAS # 62442 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1650.0 mg/Kg INHALATION RISK INDEX <1 - LC50 10509.0 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Liver. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 Risk Statements: May cause cancer. Harmful if swallowed. S: 53 45 Safety Statements: Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOPHENONE A B C D CAS # 98862 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 2 ACUTE TOXICTY RISK INDEX 4 - LD50 INHALATION HAZARD INHALATION RISK INDEX 2.0 - LC50 . I J K L . . . 0 815.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . 1200.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 1.3 mm Hg @ 20 °C FLASH POINT 168.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 10 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOXYACETAL CHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 13831317 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 160 °F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Alcohols Reacts violently with water. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store under nitrogen\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 36/37 Risk Statements: Reacts violently with water. Causes burns. Irritating to eyes and respiratory system. S: 23 26 27 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOXYBENZOIC ACID (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6304898 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOXYETHANOL (2-) A B C D CAS # 542596 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 1.8 - LD50 8250.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . . skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Nausea, headache, and vomiting. Symptoms of ethylene glycol toxicity: when ingested early symptoms mimic alcohol inebriation and are followed by nausea, vomiting, abdominal pain, weakness, muscle tenderness, respiratory failure, convulsions, cardiovascular collapse, pulmonary edema, hypocalcemic tetany, and severe metabolic acidosis. Without treatment, death may occur in 8 to 24 hours. Victims who survive the initial toxicity period usually develop renal failure along with brain and liver damage. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 190.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETOXYPYRIDONE (3:2,1H-) CAS # 61296148 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1700.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause skin sensitization SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL BENZONITRILE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1443807 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL CHLORIDE A B C D CAS # 75365 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . G . . J NFPA HAZARD CODES (H,F,R,O) 3 3 1 W ACUTE TOXICTY RISK INDEX 2.7 - LD50 910.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.0 - LC50 K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 604.4 mm Hg @ 20 °C FLASH POINT 41 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Readily hydrolyzed. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 14 34 Risk Statements: Highly flammable. Reacts violently with water. Causes burns. S: 9 16 26 45 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0025 ppm DOE Short Term Exposure Limit .0075 ppm DOE Ceiling Limit .05 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL CYCLOHEXANE (1:1-) CAS # 932661 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 150 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL CYSTEINE A B C D CAS # 616911 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5050.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause bronchospasm, nausea, vomiting, stomatitis, and nasal discharge. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Heavy metals, Heavy metal salts, Rubber, Oxygen, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL GALACTOSAMINE A B C D CAS # 14215680 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL GALACTOSAMINE (N,D-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1811310 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL GLUCOSAMINE A B C D CAS # 7512176 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL HISTIDINE MONOHYDRATE (ALPHA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 39145523 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL LYSINE A B C D CAS # 1946823 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL METHIONINE A B C D CAS # 1115475 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be . irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL METHIONINE (N,L-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 65827 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL PIPERIDONE (1,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 32161061 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 230 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL THIOUREA A B C D CAS # 591082 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . C . E . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4 - LD50 50.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL TRYPTOPHAN A B C D CAS # 87321 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLIN User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYL TYROSINE A B C D CAS # 537553 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLACETONATODICARBONYL RHODIUM(I) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 14874829 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . K . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE May liberate 2,4-pentanedione upon decomposition. 2,4-Pentanedione has the following toxicological hazards: toxic, irritant, neurological hazard, teratogen, possible mutagen, target organ - thymus. In humans, 2,4-pentanedione is reported to cause contact dermatitis and contact urticaria. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 63 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Possible risk of harm to the unborn child. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLALANINE (N,L-) A B C D CAS # 97698 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLAMINOPHENYL BORONIC ACID (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 78887395 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLBENZOIC ACID (2-) CAS # 577560 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLBENZOIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 586890 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLBENZONITRILE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6136681 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLCAPROLACTAM (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1888911 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.6 - LD50 1300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 251.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 24/25 Safety Statements: Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLCHOLINE BROMIDE A B C D CAS # 66239 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Vascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas Store at -20°C Hygroscopic. Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at -20░C SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLCHOLINE CHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 60311 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2500.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . . skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and uppe respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Vascular system. Heart. Central nervous system. Smooth muscle. Skeletal muscle. Adrenal medulla. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Spastic paralysis PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at -20°C Very hygroscopic. Store under inert gas. Keep tightly closed. Store under nitrogen. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under nitrogen\. Store at -20░C SPECIAL REQUIREMENTS Very hygroscopic. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLCHOLINE IODIDE A B C D CAS # 2260506 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 4838.7 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Vascular system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: Hydrogen iodide Nitrogen oxides Store at 2-8° Hygroscopic. Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Store at 2-8░ SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLCHOLINESTERASE A B C D CAS # 9000811 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLCYSTEAMINE (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1190734 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 F G . . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea, headache, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLENE DICARBOXYLATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 762210 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 201.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Bases, Oxidizing agents, Reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLENEDICARBOXYLIC ACID A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 142450 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 203.2 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Bases, Reducing agents, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLENEDICARBOXYLIC ACID MONOPOTASSIUM A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 928041 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . . J NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 203.2 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Reducing agents, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 23/25 27 36/37/38 Risk Statements: Toxic by inhalation and if swallowed. Very toxic in contact with skin. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLETHYLENEDIAMINE (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1001532 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 1 ACUTE TOXICTY RISK INDEX 2 - LD50 5100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 23 24/25 Safety Statements: Do not breathe vapor spray. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLFERROCENE (1-) A B C D CAS # 1271552 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.3 - LD50 25.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be fatal if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Iron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 28 Risk Statements: Very toxic if swallowed. S: 28 36/37 45 Safety Statements: After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLGLYCINE A B C D CAS # 543248 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLGUANIDINE (1-) A B C D CAS # 5699401 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLHYDROXAMIC ACID A B C D CAS # 546883 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE CARBON DIOXIDE, DRY CHEMICAL POWDER OR NITROGEN OXIDES REACTIVE PROPERTIES DURING PREPARATION OF OXIME FROM AN ALDEHYDE, AN ETHER SOLUTION OF THEREACTION MIXTURE, CONTAINING HYDROXYLAMINE HYDROCHLORIDE DECOMPOSED VIOLENTLYUNDER VACUUM DISTILLATION AT 80F. SOLID HYDROXYLAMINE SULFATE WILL EXPLODEWHEN HEATED TO 170C. MAY CAUSE EXPLOSIVE DECOMPOSITION OF MALEIC ANHYDRIDE. REACTS VIOLENTLY WITH TRIISOBUTYL ALUMINUM. MINOR AMOUNTS OF ACID CAUSEACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT. BENZYL ALCOHOL CONTAINING ACIDICCONSTITUENTS AND DISSOLVED IRON WAS FOUND TO POLYMERIZE WITH A RAPIDTEMPERATURE INCREASE WHEN HEATED IN EXCESS OF 100C.(AMINES, PYRIDINE, ANDALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENT POLYMERIZATION.) REACTVIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGH CONCENTRATIONS OF ACID REACTEXPLOSIVELY WITH NICKEL NITRIDE AND HEAT. INITIATE A FAST DECOMPOSITION OFSODIUM OZONATE. REACTS WITH THORIUM PHOSPHIDE TO RELEASE SPONTANEOUSLYFLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITH TRI-ISO-BUTYL ALUMINUM. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLINDOLE (3-) A B C D CAS # 703800 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLINDOLE CARBOXALDEHYDE (1:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . CAS # 22948943 Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLMANNOSAMINE (N,D-) A B C D CAS # 7772943 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLPHENYL ISOCYANATE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 23138649 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 7 26 27 37/39 Safety Statements: Keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLPHENYL ISOCYANATE (4-) CAS # 49647203 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 7 26 27 37/39 Safety Statements: Keep container tightly closed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLPHENYLBORONIC ACID (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 204841190 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLPHENYLBORONIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 149104905 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Borane/boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLPHENYLHYDRAZINE (1,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 114830 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A . . . . F G . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.3 - TD50 26.0 mg/Kg ACUTE TOXICTY RISK INDEX 2.8 - LD50 871.0 mg/Kg INHALATION RISK INDEX <1 - LC50 K L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Liver. Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 22 26 36 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLPIPERAZINE (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 13889980 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAG Suitable: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLSALICYLIC ACID A B C D CAS # 50782 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLTHIOCHOLINE CHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6050813 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLTHIOCHOLINE IODIDE (S-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1866155 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 21 36/37/38 Risk Statements: Toxic if swallowed. Harmful in contact with skin. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLTHIOGLYCOLIC ACID HYDROXYSUCCINAMIDE ESTER ( A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . CAS # 76931936 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLTRIBENZOYL RIBOFURANOSE (10:2,3,5:ORTHO-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . CAS # 6974329 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACETYLTYROSINE ETHYL ESTER A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 36546506 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID ALIZARIN VIOLET N A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2092559 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID BLUE 45 A B C D CAS # 2861021 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9354.8 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Sodium/sodium oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.5 mg/m3 DOE Short Term Exposure Limit 35 mg/m3 DOE Ceiling Limit 250 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID FUCHSIN A B C D CAS # 3244880 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID GREEN 25 A B C D CAS # 4403901 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 10000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID ORANGE 74 A B C D CAS # 10127272 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID ORANGE I A B C D CAS # 523444 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 0 Dermal Hazard Corrosive Eye Damage STEL . . 0 . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 546.0 mg/Kg TOXICITY DATA PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID PHOSPHATASE A B C D CAS # 9001778 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep container closed. Store away from heat. REACTIVE PROPERTIES STORAGE: Keep container closed. Store away from heat. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID RED 1 A B C D CAS # 3734676 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID VIOLET 7 A B C D CAS # 4321691 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 23160.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACID YELLOW A B C D CAS # 6359906 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACLARUBICIN A B C D CAS # 57576440 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. Nausea, vomiting, diarrhea. Blood effects. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. Light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36/37/39-45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACONIC ACID A B C D CAS # 585682 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACONITIC ACID (CIS-) A B C D CAS # 585842 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ON MONOXIDEHYDROGEN CHLORIDE REACTIVE PROPERTIES MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WAS FOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESS OF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE AND HEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITH THORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACONITIC ACID (TRANS-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 4023658 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 INHALATION RISK INDEX <1 - LC50 . . . . . . PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: ON MONOXIDEHYDROGEN CHLORIDE REACTIVE PROPERTIES MINOR AMOUNTS OF ACID CAUSE ACROLEIN TO POYLMERIZE WITH RELEASE OF HEAT.BENZYL ALCOHOL CONTAINING ACIDIC CONSTITUENTS AND DISSOLVED IRON WAS FOUND TOPOLYMERIZE WITH A RAPID TEMPERATURE INCREASE WHEN HEATED IN EXCESS OF100C.(AMINES, PYRIDINE, AND ALKALI HYDROXIDES ACT AS INHIBITORS AND PREVENTPOLYMERIZATION.) REACT VIGOROUSLY WITH LITHIUM ALUMINUM HYDRIDE. HIGHCONCENTRATIONS OF ACID REACT EXPLOSIVELY WITH NICKEL NITRIDE AND HEAT.INITIATE A FAST DECOMPOSITION OF SODIUM OZONATE. REACTS WITH THORIUMPHOSPHIDE TO RELEASE SPONTANEOUSLY FLAMMABLE PHSOPHINE. REACTS VIOLENTLY WITHTRI-ISO-BUTYL ALUMINUM. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRIDINE A B C D CAS # 260946 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . I NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. Nerves. Blood. Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Exposure can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSUR Causes sneezing. Do not inhale. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .000500 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLIN User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRIDINE ORANGE A CAS # 10127023 Special Carcinogen E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . J K L . . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRIDINE ORANGE FREE BASE CAS # 494382 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .4 mg/m3 DOE Short Term Exposure Limit 1.25 mg/m3 DOE Ceiling Limit 7.5 mg/m3 Immediately Dangerous to Life and Health 40 mg/m3ACRIDINE ORANGE FREE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRIDINE ORANGE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 65612 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . . . J K . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRIFLAVINE A B C D CAS # 8048520 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 2 Dermal Hazard Corrosive Eye Damage STEL . 0 . 0 G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I J K . ACUTE TOXICTY RISK INDEX 2.7 - LD50 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 1048.0 mg/Kg ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Cardiovascular effects. CNS depression. Respiratory depression. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 22 37/38 41 50/53 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 39 60 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACROLEIN A B C D CAS # 107028 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . B C D E F G H . J NFPA HAZARD CODES (H,F,R,O) 4 4 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 4.2 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 26.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.8 - LC50 . . 46.8 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Cardiovascular system. Lungs. Eyes. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 209.4 mm Hg @ 20 °C FLASH POINT -20.2 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents, Oxygen, Bases, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. Keep away from heat, sparks, and open flame. Store under inert gas. May develop pressure. Open carefully. Light sensitive. Heat- and air-sensitive REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store at 2-8░C SPECIAL REQUIREMENTS Store under inert gas. May develop pressure. Open carefully. Light sensitive. Heat- and air-sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F T+ N Indication of Danger: Highly Flammable. Very toxic. Dangerous for the environment. R: 11 24/25 26 34 50 Risk Statements: Highly flammable. Toxic in contact with skin and if swallowed. Very toxic by inhalation. Causes burns. Very toxic to aquatic organisms. S: 23 26 28 36/37/39 45 61 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .1 ppm OSHA Short Term Exposure Limit .3 ppm ACGIH RECOMMENDED LIMITS ACGIH Short Term Exposure Limit .1 ppm Immediately Dangerous to Life and Health 2 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .03 ppm DOE Short Term Exposure Limit .03 ppm DOE Ceiling Limit .1 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACROLEIN DIMETHYLACETAL A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6044684 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 26.6 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. Store at 2-8°C Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 16-29-33-23-24/25 Safety Statements: Keep away from sources of ignition - no smoking. Do not empty into drains. Take precautionary measures against static discharges. Do not breathe vapor. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACROLIEN DIETHYL ACETAL A B Special Carcinogen Human Terato\Repro Haz CAS # 3054953 E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . K L . . Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 59 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Acids, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 9 16 33 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACROLOYLMORPHOLINE (4-) CAS # 5117124 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 1 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L G . . 0 588.0 mg/Kg 5280.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Nausea. Headache. Exposure can cause: PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Polymerizing initiators, Free radical initiators, Peroxides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Light sensitive. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Store in a cool dry place. Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-41-43-48/22 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. S: 23-26-36/37/39 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRYLAMIDE A B C D CAS # 79061 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A B . D E . . . I . NFPA HAZARD CODES (H,F,R,O) 2 1 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.1 - TD50 3.8 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 4.8 ACUTE TOXICTY RISK INDEX 4 - LD50 124.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 2.2 - LC50 . L 1500.0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Acrylamide toxicity is manifested as a sensorimotor peripheral neuropathy. Symptoms include: drowsiness, loss of balance, confusion, memory loss, hallucinations, numbness, paresthesias (ataxia, tremor, dysarthria), and incoordination. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .380 mm Hg @ 20 °C FLASH POINT 280 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Avoid contact with acid., Oxidizing agents Iron and iron salts., Copper, Brass, Free radical initiators FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45-46-20/21-25-36/38-43-48/23/24/25-62 Risk Statements: May cause cancer. May cause heritable genetic damage. Also harmful by inhalation and in contact with skin. Also toxic if swallowed. Irritating to eyes and skin. May cause sensitization by skin contact. Also toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Possible risk of impaired fertility. S: 53-45 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .03 mg/m3 Immediately Dangerous to Life and Health 60 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .3 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3 DOE Ceiling Limit 60 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRYLIC ACID A B CAS # 79107 Special Carcinogen Human Terato\Repro Haz HAZARDOUS CHEMICAL OF CONCERN E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL K L Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . . J NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 4 - LD50 2590.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.0 - LC50 K . 1643.0 ROUTE OF EXPOSURE skin Contact: Causes severe burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes severe burns. Inhalation: Harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 4.0 mm Hg @ 20 °C FLASH POINT 114.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C N Indication of Danger: Corrosive. Dangerous for the environment. R: 10 20/21/22 35 50 Risk Statements: Flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes severe burns. Very toxic to aquatic organisms. S: 26 36/37/39 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 10 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value 2 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 46 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRYLONITRILE A B C D CAS # 10713 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E F G . . J NFPA HAZARD CODES (H,F,R,O) 3 3 1 ACUTE TOXICTY RISK INDEX 4 - LD50 78.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.1 - LC50 K L 721.2 cancer hazard ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Central nervous system. Cardiovascular system. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. May be partially metabolized to cyanide in the body. CNS depression. Ataxia. Symptoms may be delayed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 86.0 mm Hg @ 20 °C FLASH POINT 23 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents Copper, Copper alloys. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Heat and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 45 11 23/24/25 41 43 51/53 37/38 Risk Statements: May cause cancer. Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system and skin. S: 53 9 16 45 61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRYLONITRILE A B C D CAS # 107131 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A . . D E . G H I . NFPA HAZARD CODES (H,F,R,O) 4 3 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.4 - TD50 16.9 mg/Kg ACUTE TOXICTY RISK INDEX 3.8 - LD50 78.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 4.1 - LC50 K L cancer hazard ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Central nervous system. Cardiovascular system. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. May be partially metabolized to cyanide in the body. CNS depression. Ataxia. Symptoms may be delayed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 86.0 mm Hg @ 20 °C FLASH POINT 23 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Oxidizing agents Copper, Copper alloys. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Heat and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 45 11 23/24/25 41 43 51/53 37/38 Risk Statements: May cause cancer. Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to respiratory system and skin. S: 53 9 16 45 61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 85 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 ppm DOE Short Term Exposure Limit 10 ppm DOE Ceiling Limit 35 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRYLOYL CHLORIDE A B C D CAS # 814686 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D . . G . . . NFPA HAZARD CODES (H,F,R,O) 4 3 1 W EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . . 28.5 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Lachrymator. Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 57.2 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Phosgene gas Hydrogen chloride gas Store at 2-8°C Keep tightly closed. Keep away from heat, sparks, and open flame. Do not allow contact with water Light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. Incompatible Materials: Do not allow contact with water Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-T+ Indication of Danger: Highly Flammable. Very toxic. R: 11-14-26-34 Risk Statements: Highly flammable. Reacts violently with water. Very toxic by inhalation. Causes burns. S: 7/9-16-26-36/37/39-45-28 Safety Statements: Keep container tightly closed and in well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). After contact with skin, wash immediately with plenty of water. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .05 ppm DOE Short Term Exposure Limit .15 ppm DOE Ceiling Limit .243 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACRYLOYL CYSTAMINE (N,N',BIS-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 60984578 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACTH A B C D CAS # 12279413 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . K L 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Stimulates the adrenal cortex. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACTIDIONE A B C D CAS # 66819 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . C . . . . . I NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5+ - LD50 2.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX 2.4 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be fatal if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Kidneys. Adrenal cortex. Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Dermatitis. Nausea, vomiting, diarrhea. Tremors. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .006000 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Bases, Strong oxidizing agents, Acid anhydrides, Acid chlorides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 61 28 51/53 68 Risk Statements: May cause harm to the unborn child. Also very toxic if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Also possible risks of irreversible effects. S: 53 45 61 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .1 mg/m3 DOE Short Term Exposure Limit .3 mg/m3 DOE Ceiling Limit 2 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACTINOMYCIN C A B C D CAS # 8052162 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A B C D . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 5++ - TD50 .0 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.8 - LD50 7.2 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . L ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes burns. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Liver. Bone marrow. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Anemia. Drowsiness. Weakness. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases, Strong acids, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 46-61-26/27/28 Risk Statements: May cause heritable genetic damage. May cause harm to the unborn child. Very toxic by inhalation, in contact with skin and if swallowed. S: 53-36/37/39-45 Safety Statements: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACTINOMYCIN D A B C D CAS # 50760 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A B C . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 5++ - TD50 .0 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.8 - LD50 7.2 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. Chronic ingestion of large doses may cause gastrointestinal disturbances including nausea and diarrhea, urinary effects involving urine acidification, oxalate and uric crystallizaton in the bladder and kidney, and decreased reaction times and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong FIRE EXTINGUISHER: surrounding fire conditions. bases. REACTIVE PROPERTIES HANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACTIVATED CARBON A B C D CAS # 64365113 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. TOXIC EMISSIONS WHEN BURNED: AIR PROMOTES THE OXIDATION OF THE SODIUM BOROHY REACTIVE PROPERTIES EXPLOSIONS MAY OCCUR WHEN MIXED WITH: AMMONIUM NITRATE, AMMONIUMPERCHLORATE, BROMATES, CHLORATES OR IODATES OF BARIUM, CALCIUM, MAGNESIUM,POTASSIUM, SODIUM OR ZINC, CALCIUM HYPOCHLORITE, CHLORINE, CHLORINE MONOXIDE,FLUORINE, IODINE PENTOXIDE, MERCUROUS NITRATE, NITRIC ACID, ZINC NITRATE. FATTY OILS ARE SPONTANEOUSLY FLAMMABLE WHEN DISTRIBUTED IN ACTIVATED CARBON. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3ACTIVATED CARBON CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACTIVATED COCOANUT CHARCOAL A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7740440 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. TOXIC EMISSIONS WHEN BURNED: AIR PROMOTES THE OXIDATION OF THE SODIUM BOROHY REACTIVE PROPERTIES EXPLOSIONS MAY OCCUR WHEN MIXED WITH: AMMONIUM NITRATE, AMMONIUMPERCHLORATE, BROMATES, CHLORATES OR IODATES OF BARIUM, CALCIUM, MAGNESIUM,POTASSIUM, SODIUM OR ZINC, CALCIUM HYPOCHLORITE, CHLORINE, CHLORINE MONOXIDE,FLUORINE, IODINE PENTOXIDE, MERCUROUS NITRATE, NITRIC ACID, ZINC NITRATE. FATTY OILS ARE SPONTANEOUSLY FLAMMABLE WHEN DISTRIBUTED IN ACTIVATED CARBON. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ACYLASE I A B C D CAS # 9012377 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep tightly closed. REACTIVE PROPERTIES STORAGE: Keep tightly closed. Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANAMINE (1-) A Special Carcinogen CAS # 768945 E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 900.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANAMINE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 665667 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 900.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANAMINE HYDROCHLORIDE (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 10523689 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANECARBONYL CHLORIDE (1-) CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2094726 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . G 1 HAZARDOUS CHEMICAL OF I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 230 °F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 37 Risk Statements: Reacts violently with water. Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANECARBOXYLIC ACID (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 828513 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANEMETHYLAMINE (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 17768411 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 198 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store under nitrogen. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANOL (1-) CAS # 768956 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTANONE (2-) A B C D CAS # 700583 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION R: 52 Risk Statements: Harmful to aquatic organisms. S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTYL BROMOMETHYL KETONE (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5122827 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. . Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADAMANTYL UREA (N,1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 13072690 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 F I J K L G . . 0 432.9 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENINE A B C D CAS # 73245 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 227.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE . To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENINE HEMISULFATE A B C D CAS # 321302 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. . Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENINE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6055727 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENOSINE A B C D CAS # 58617 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX .9 - LD50 64516.1 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause dilation of the blood vessels and an increase in contraction of some smooth muscles. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENOSINE DIPHOSPHATE SODIUM (5'-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 20398349 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. effect. May cause convulsions. Weakness. Ingestion can cause: Nausea, headache, and vomiting. Dizziness. Confusion. Unconsciousness. Can cause CNS depression. Methyl alcohol may be fatal or cause blindness if swallowed. Cannot be made non-poisonous. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Alkali metals, Reducing agents, Ammonia, Peroxides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Phosphorous oxides REACTIVE PROPERTIES HANDLING skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn R: 20/21/22 68/20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Harmful: possible risk of irreversible effects through inhalation, in contact with skin, and if swallowed. Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENOSINE MONOPHOSPHATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 18422054 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADENOSINE TRIPHOSPHATE DISODIUM (5'-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 51963612 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Heart. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sodium/sodium oxides Nitrogen oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADIPAMIDE A B C D CAS # 628944 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 19354.8 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADIPIC ACID A B C D CAS # 124049 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5050.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .130 mm Hg @ 20 °C FLASH POINT 385 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 5 mg/m3 DOE Ceiling Limit 5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADIPIC DIHYDRAZIDE A B C D CAS # 1071938 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 302 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADIPOYL CHLORIDE A B C D CAS # 111502 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 F G 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 233.6 °F Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC CORROSIVE INCOMPATIBILITIES:Water, Alcohols, Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Phosgene gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADONITOL A B C D CAS # 488813 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. . Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADRENALIN A B C D CAS # 51434 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Heart. Smooth muscle. SIGNS AND SYMPTOMS OF EXPOSURE Laboratory experiments in animals have shown fetotoxic results. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .25 mg/m3 DOE Ceiling Limit .25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ADRENOCORTICOTROPIC HORMONE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 9061272 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . K L 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE Stimulates the adrenal cortex. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at -20°C REACTIVE PROPERTIES STORAGE Store at -20°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. S: 22 36 Safety Statements: Do not breathe dust. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AGAR A B C D CAS # 9002180 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11000.0 mg/Kg . . . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Moisture sensitive. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 500 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AGAROSE A B C D CAS # 68652905 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AGAROSE A B C D CAS # 9012366 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE A B C D CAS # 338692 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (BETA-) A B C D CAS # 107959 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (BOC,BETA-) A B C D CAS # 3303842 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (BOC-) A B C D CAS # 15761383 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (DL-) A B C D CAS # 302727 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: de and nitrogen oxides HAZARDOUS POLYMERIZATION Hazardous Polym REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (FMOC,BETA-) A B C D CAS # 35737101 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C REACTIVE PROPERTIES STORAGE Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (FMOC,L-) A B C D CAS # 35661393 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. . SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE (L-) A B C D CAS # 56417 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE HYDROXYSUCCINIMIDE ESTER (BOC,L-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 3392050 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Store at -20°C Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE METHYL ESTER HYDROCHLORIDE (BETA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 3196734 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Store at -20°C Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALANINE METHYL ESTER HYDROCHLORIDE (L-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2491205 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBAMYCIN A B C D CAS # 1476535 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . G . . NFPA HAZARD CODES (H,F,R,O) 2 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 129.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K ROUTE OF EXPOSURE skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material may be Ingestion: Toxic if swallowed. . TARGET ORGAN(S) OR SYSTEM(S) Blood. Liver. Kidneys. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Do not use if skin is cut or scratched. Wash thoroughly after handling. Suitable: Keep tightly closed. Keep away from heat, sparks, and open flame. Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. Risk Statements: May cause sensitization by skin contact. S: 36 Safety Statements: Wear suitable protective clothing. Indication of Danger: Irritant. Risk Statements: May cause sensitization by skin contact. Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBENDAZOLE A B C D CAS # 54965218 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2400.0 mg/Kg . . . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBUMIN A B C D CAS # 70024907 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Potentially biohazardous material. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: B Indication of Danger: Biohazard. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBUMIN A B C D CAS # 9048468 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 150 mg/m3 DOE Short Term Exposure Limit 500 mg/m3 DOE Ceiling Limit 500 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBUMIN (EGG WHITE) A B C D CAS # 9006502 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBUMIN (EGG) A B C D CAS # 9006591 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 24000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALBUMIN BOVINE A B C D CAS # 2329362 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. TOXIC EMISSIONS WHEN BURNED: WILL NOT OCCUR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALCIAN BLUE 8GK A B C D CAS # 75881231 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson's disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas Copper oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALCIAN BLUE 8GX A B C D CAS # 33864992 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Chronic copper poisoning is typified by hepatic cirrhosis, brain damage and demyelination, kidney defects, and copper deposition in the cornea as exemplified by humans with Wilson's disease. It has also been reported that copper poisoning has lead to hemolytic anemia and accelerates arteriosclerosis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALCOHOL DEHYDROGENASE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 9031725 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at -20°C Hygroscopic. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C SPECIAL REQUIREMENTS Hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALDOLASE A B C D CAS # 9024526 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Store away from heat. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALDRIN A B C D CAS # 309002 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A B C . E . . . I . NFPA HAZARD CODES (H,F,R,O) 4 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.1 - TD50 4.1 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 5.2 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 39.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Reproductive system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea. Vomiting. Headache. Tremors. Incoordination. Dizziness. Cyanosis. Seizures. Unconsciousness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 24/25 40 48/24/25 50/53 Risk Statements: Toxic in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22 36/37 45 60 61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .25 mg/m3 DOE Short Term Exposure Limit .75 mg/m3 DOE Ceiling Limit 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALDRIN A B C D CAS # 309012 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . E . . . I NFPA HAZARD CODES (H,F,R,O) 4 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 39.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Reproductive system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea. Vomiting. Headache. Tremors. Incoordination. Dizziness. Cyanosis. Seizures. Unconsciousness. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 24/25 40 48/24/25 50/53 Risk Statements: Toxic in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 22 36/37 45 60 61 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALGINIC ACID AMMONIUM-CALCIUM A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 9005316 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALGINIC ACID SODIUM CAS # 9005383 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALIZARIN A B C D CAS # 72480 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5+ - LD50 4.5 mg/Kg J K . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.25 mg/m3 DOE Short Term Exposure Limit 4 mg/m3 DOE Ceiling Limit 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALIZARIN BLUE BLACK B A B C D CAS # 1324216 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALIZARIN RED S A B C D CAS # 130223 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Sodium oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36 26 Safety Statements: Wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALIZARIN YELLOW 2 G A B C D CAS # 584429 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be Eye irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sodium oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALIZARIN YELLOW R A B C D CAS # 2243767 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALIZARIN YELLOW R SODIUM A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1718349 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALKALI BLUE 6B A B C D CAS # 1324761 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALKALINE PHOSPHATASE A B C D CAS # 9001789 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surrounding fire conditions. Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLANTOIN A B C D CAS # 97596 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 Safety Statements: Do not breathe dust. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLOC ETHYLENEDIAMINE (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 223741660 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLOXAN MONOHYDRATE A B C D CAS # 2244113 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. TARGET ORGAN(S) OR SYSTEM(S) Pancreas. SIGNS AND SYMPTOMS OF EXPOSURE Alloxan has been used to produce diabetes in animals by selective necrosis of the pancreatic islet beta-cells. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Open carefully. STORAGE: Keep tightly closed\. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLOXAN TETRAHYDRATE A B C D CAS # 50715 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2 - LD50 5210.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . TOXICITY DATA PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Store at 2-8°C Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE Store at 2-8°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLOXAN TETRAHYDRATE A B C D CAS # 6010919 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Pancreas. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C SPECIAL REQUIREMENTS May develop pressure. Open carefully. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL ACETATE A B C D CAS # 591877 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . . . . J NFPA HAZARD CODES (H,F,R,O) 1 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 130.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE K . 4086.5 skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Damage to the lungs. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 51.8 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Oxidizing agents, Bases, Peroxides. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T Indication of Danger: Highly Flammable. Toxic. R: 11 21 23/25 36 Risk Statements: Highly flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes. S: 16 26 36 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 10 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL ALCOHOL A B C D CAS # 107186 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E F G H I J NFPA HAZARD CODES (H,F,R,O) 4 3 0 ACUTE TOXICTY RISK INDEX 4 - LD50 64.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION HAZARD INHALATION RISK INDEX 3.7 - LC50 K L 1000.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be fatal if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Causes photosensitiveity. Exposure to light can result in allergic reactions resulting in dermatologic lesions, which can vary from sunburnlike responses to edematous, vesiculated lesions, or bullae TARGET ORGAN(S) OR SYSTEM(S) Lungs. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 19.0 mm Hg @ 20 °C FLASH POINT 72 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC CORROSIVE INCOMPATIBILITIES:Alkali metals, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 10 23/24/25 36/37/38 50 Risk Statements: Flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms. S: 36/37/39 38 45 61 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit 2 ppm OSHA Short Term Exposure Limit 4 ppm ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value .5 ppm Immediately Dangerous to Life and Health 20 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 ppm DOE Short Term Exposure Limit 2.1 ppm DOE Ceiling Limit 4.2 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL BROMIDE A B C D CAS # 106956 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . G . . J NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 120.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . 4110.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 30.2 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 11 23/25 34 50 Risk Statements: Highly flammable. Toxic by inhalation and if swallowed. Causes burns. Very toxic to aquatic organisms. S: 16 26 36/37/39 45 60 61 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 4 ppm DOE Short Term Exposure Limit 12.5 ppm DOE Ceiling Limit 75 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL CHLORIDE A B C D CAS # 107051 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . G H . J NFPA HAZARD CODES (H,F,R,O) 3 4 0 REPRODUCTIVE RISK INDEX 2.8 ACUTE TOXICTY RISK INDEX 2.8 - LD50 700.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.8 - LC50 K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Lachrymator. Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Dyspnea. Respiratory depression. Tremors. Somnolence. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 295.2 mm Hg @ 20 °C FLASH POINT -25.6 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Boron trifluoride, Sulfuric acid, Nitric acid, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Store at 2-8°C Keep tightly closed. Incompatible Materials: Acids Bases Metals REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Incompatible Materials: Acids Bases Metals Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Xn N Indication of Danger: Highly Flammable. Harmful. Dangerous for the environment. R: 11 20/21/22 36/37/38 40 48/20 68 50 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Possible risk of irreversible effects. Very toxic to aquatic organisms. S: 16 25 26 36/37 46 61 Safety Statements: Keep away from sources of ignition - no smoking. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. If swallowed, seek medical advice immediately and show this container or label. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 250 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 ppm DOE Short Term Exposure Limit 3 ppm DOE Ceiling Limit 40 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL CHLOROACETATE A B C D CAS # 2916145 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 142 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL CHLOROFORMATE A B C D CAS # 2937500 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . . G . . J NFPA HAZARD CODES (H,F,R,O) 3 3 0 ACUTE TOXICTY RISK INDEX 5 - LD50 244.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.0 - LC50 K . 7.2 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 189.7 mm Hg @ 20 °C FLASH POINT 87.8 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Amines, Alcohols, Strong bases, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Phosgene gasHydrogen chloride gas Store at 2-8°C Keep tightly closed. Keep away from heat, sparks, and open flame. Vent periodically. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store at 2-8░C SPECIAL REQUIREMENTS Vent periodically. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 10-22-26-34 Risk Statements: Flammable. Harmful if swallowed. Very toxic by inhalation. Causes burns. S: 26-28-36/37/39-45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .01 ppm DOE Short Term Exposure Limit .03 ppm DOE Ceiling Limit .15 ppm Immediately Dangerous to Life and Health .15 ppmALLYL CHLOROFORMATE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL CYANIDE A B C D CAS # 109751 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . . J NFPA HAZARD CODES (H,F,R,O) 0 3 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 115.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.4 - LC50 K . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 14.0 mm Hg @ 20 °C FLASH POINT 75.2 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong acids, Strong bases, Strong reducing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water may be effective for cooling, but may not effect extinguishment. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10 21 23/25 36/38 Risk Statements: Flammable. Harmful in contact with skin. Toxic by inhalation and if swallowed. Irritating to eyes and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL ISOCYANATE A B C D CAS # 1476239 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 178.0 mg/Kg J K L INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SENSITIZATION Sensitization: May cause allergic reaction. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged contact can cause: Nausea, dizziness, and headache. Lung irritation, chest pain, and edema which may be fatal. Repeated exposure may cause asthma. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 109.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Water, Alcohols, Strong bases, Amines, Acids, oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Store at 2-8°C May develop pressure. Open carefully. Keep tightly closed. Keep away from heat and open flame. Strong REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store at 2-8░C SPECIAL REQUIREMENTS May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36/37/38 42 Risk Statements: Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL ISOTHIOCYANATE A B C D CAS # 57067 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . G . I NFPA HAZARD CODES (H,F,R,O) 3 2 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 112.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: Vesicant. Causes blisters on contact with skin. Causes burns. skin Absorption: Toxic if absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 114.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Water, Alcohols, Strong bases, Amines, Acids Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Hydrogen cyanide Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 10 24/25 42/43 34 Risk Statements: Flammable. Toxic in contact with skin and i swallowed. May cause sensitization by inhalation and skin contact. Causes burns. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 25 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .35 ppm DOE Short Term Exposure Limit 1 ppm DOE Ceiling Limit 2.5 ppm Immediately Dangerous to Life and Health 12.5 ppmALLYL ISOTHIOCYANATE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL PHENYL SULFIDE A B C D CAS # 5296640 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.STORAGE: Keep container closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21 S: 23 36/37/39 Safety Statements: Do not breathe vapor. Wear suitable protective clothing, gloves, and eye/face protection. Indication of Danger: Harmful. Risk Statements: Harmful by inhalation and in contact with skin. Safety Statements: Do not breathe vapor. Wear suitable The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL THIOUREA (1,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 109579 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 200.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. . SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYL TRIBUTYLTIN (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 24850337 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 217.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Tin/tin oxides Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 21 25 36/38 48/23/25 50/53 Risk Statements: Harmful in contact with skin. Toxic if swallowed. Irritating to eyes and skin. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 35 36/37/39 45 60 61 Safety Statements: This material and its container must be disposed of in a safe way. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLAMINE A B C D CAS # 107119 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . G . . J NFPA HAZARD CODES (H,F,R,O) 4 4 1 ACUTE TOXICTY RISK INDEX 3.7 - LD50 102.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 4.3 - LC50 K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be fatal if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Cardiovascular system. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 211.5 mm Hg @ 20 °C FLASH POINT -20.2 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Acids, Oxidizing agents, Chlorine, Hypochlorites, Halogens, Chemically active metals. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F T N Indication of Danger: Highly Flammable. Toxic. Dangerous for the environment. R: 11 23/24/25 51/53 Risk Statements: Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 9 16 24/25 45 61 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. Avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .125 ppm DOE Short Term Exposure Limit .42 ppm DOE Ceiling Limit 3.3 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLCHLOROBISDIPROPYLPHENYLIMIDAZOLYLIDENE PALLAD A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . CAS # 478980039 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLDIMETHYLAMINE (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2155944 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 891.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Inhalation: Harmful if inhaled. Ingestion: May be harmful if swallowed. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT -4 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 20 34 Risk Statements: Highly flammable. Harmful by inhalation. Causes burns. S: 16 26 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 1000 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLHYDROXYLAMINE HYDROCHLORIDE (ORTHO-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 38945210 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 S PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLIMIDAZOLE (1-) A B C D CAS # 31410012 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 219.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLMAGNESIUM CHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2622051 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 INHALATION RISK INDEX <1 - LC50 . G 2 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L W ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable Explosive FLASH POINT 1.4 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area Forms explosive unstable peroxides Test periodically or discard Reacts violently with water SEGREGATION: SHELF # 3 STORAGE GROUP(S): b - Pyrophoric/Water Reactive k - Explosive/Unstable l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Acids, Alcohols, Oxidizing agents, Water. FIRE EXTINGUISHER: Dry chemical powder. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Carbon monoxide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 11-14/15-34 Risk Statements: Highly flammable. Reacts violently with water, liberating extremely flammable gases. Causes burns. S: 7/8-16-26-36/37/39-43-45 Safety Statements: Keep container tightly closed and dry. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry powder. Never use water. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLMETHYLAMINE (N-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 627372 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 17.6 °F Store in an explosion-proof refrigerator or tightly stoppered in a well-ventilated area SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. Keep away from heat, sparks, and open flame. Store under nitrogen. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store under nitrogen. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 34 Risk Statements: Highly flammable. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLOXYBENZALDEHYE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 40663681 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Do not breathe vapor. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 43 Risk Statements: May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLTRICHLOROSILANE A B C D CAS # 107379 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . W ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable VAPOR PRESSURE 10.0 mm Hg @ 20 °C FLASH POINT 64.4 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE REACTIVE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Silicon oxide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Handle and store under nitrogen\. Incompatible Materials: Do not allow contact with water GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 34 Risk Statements: Highly flammable. Causes burns. S: 16 26 33 36/37/39 43 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves, and eye/face protection. In case of fire, use dry chemical. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALLYLTRIMETHYLSILANE A B C D CAS # 762721 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 3 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 60.8 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Silicon oxide Store at 2-8°C Keep container closed. Keep away from heat, sparks, and open flame. REACTIVE PROPERTIES HANDLING: Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F Xi Indication of Danger: Highly Flammable. Irritant. R: 11 36/37/38 Risk Statements: Highly flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALPHAZURINE A A B C D CAS # 3486304 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Use protective clothing, gloves, and mask. Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUM CARMINE A B C D CAS # 000032 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUM CARMINE A B C D CAS # 32 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. CARBON DIOXIDE, DRY CHEMICAL POWDER OR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINA A B C D CAS # 1344281 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bones. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. Damage to the lungs. Prolonged exposure can cause: IRRITATION DATA Eyes Rabbit Remarks: No irritation effect skin Rabbit Remarks: No irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .010000 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Ethylene oxide, Halocarbons, Oxygen difluoride, Sodium nitrate, Vinyl acetate, Strong acids, Strong bases, Chlorine trifluoride. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Very hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 15 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINA A B C D CAS # 701236 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bones. Lungs. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Coughing, chest pains, difficulty in breathing. Gastrointestinal disturbances. Damage to the lungs. Prolonged exposure can cause: IRRITATION DATA Eyes Rabbit Remarks: No irritation effect skin Rabbit Remarks: No irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .010000 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Ethylene oxide, Halocarbons, Oxygen difluoride, Sodium nitrate, Vinyl acetate, Strong acids, Strong bases, Chlorine trifluoride. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Very hygroscopic. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINON A B C D CAS # 569584 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Male reproductive system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .0004 mg/m3 DOE Short Term Exposure Limit .001 mg/m3 DOE Ceiling Limit .0075 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM CAS # 7429905 HAZARDOUS CHEMICAL OF CONCERN DEPARTMENT OF HOMELAND SECURITY CHEMICAL OF CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 2 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE***** mm Hg @ 20 °C Reacts violently in air SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Acids, Acid chlorides, Halogens, Oxidizing FIRE EXTINGUISHER: Dry chemical powder. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide agents. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 15 17 Risk Statements: Contact with water liberates extremely flammable gases. Spontaneously flammable in air. S: 7/8 43 Safety Statements: Keep container tightly closed and dry. In case of fire, use special powder for metal fire. Never use water. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM ACETATE BASIC A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 142030 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM AMMONIUM SULFATE DODECAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 7784261 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Ammonia Sulfur oxides Aluminum oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM CHLORIDE ANHYDROUS A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7446700 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARDOUS CHEMICAL OF CONCERN I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . B . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 3.7 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3450.0 mg/Kg INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. . . L skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Damage to the lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Damage to the lungs. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Prolonged exposure can cause: Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .200 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Mixtures of nitrobenzene and aluminum chloride are thermally unstable and may lead to explosive decomposition due to a multi-step decomposition reaction occurring above 90 degree C, which self-accelerates with high exothermicity producing azoFIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Aluminum oxideHazardous Decomposition Products Formed Upon Contact with Water: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Store under inert gas. Vent periodically. May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 7/8-28-45 Safety Statements: Keep container tightly closed and dry. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 9.88 mg/m3 DOE Short Term Exposure Limit 9.88 mg/m3 DOE Ceiling Limit 60 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM CHLORIDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM CHLORIDE HEXAHYDRATE CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7784136 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARDOUS CHEMICAL OF I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 1 W ACUTE TOXICTY RISK INDEX 2.2 - LD50 3450.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. TARGET ORGAN(S) OR SYSTEM(S) Damage to the lungs. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Damage to the lungs. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Prolonged exposure can cause: Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .200 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE TOXIC INCOMPATIBILITIES:Mixtures of nitrobenzene and aluminum chloride are thermally unstable and may lead to explosive decomposition due to a multi-step decomposition reaction occurring above 90 degree C, which self-accelerates with high exothermicity producing azoFIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. Do not use water. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Aluminum oxideHazardous Decomposition Products Formed Upon Contact with Water: Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Store under inert gas. Vent periodically. May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 7/8-28-45 Safety Statements: Keep container tightly closed and dry. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 17.9 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM CHLORIDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM HYDROXIDE A B C D CAS # 21645512 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Nausea. Vomiting. Constipation. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Reacts violently with chlorinated rubber when heated. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1.5 mg/m3 DOE Short Term Exposure Limit 4.5 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 125 mg/m3ALUMINUM HYDROXIDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM IODIDE A B C D CAS # 7784238 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . K L W ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms of exposure include: skin rash, running nose, headache and irritation of the mucous membrane. For severe cases the skin may show pimples, boils, hives, blisters and black and blue spots. Iodides are readily diffused the placenta. Neonatal deaths from respiratory distress secondary to goiter have been reported. Iodides have been known to cause drug-induced fevers, which are usually of short duration. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .110 mm Hg @ 20 °C Reacts violently with water SEGREGATION: SHELF # 1 STORAGE GROUP(S): b - Pyrophoric/Water Reactive WASTE CHARACTERISTIC HAZARD: REACTIVE across INCOMPATIBILITIES:Water. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place\. Incompatible Materials: Do not allow contact with water Special REQUIREMENTS Light sensitive. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 14 34 40 42/43 Risk Statements: Reacts violently with water. Causes burns. Limited evidence of a carcinogenic effect. May cause sensitization by inhalation and skin contact. S: 22 26 36/37/39 45 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM ISOPROPOXIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 555317 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Flammable FLASH POINT 61 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide REACTIVE PROPERTIES HANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Avoid prolonged or repeated exposure. STORAGE: Keep container closed. Keep away from heat, sparks, and open flame\. SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F Indication of Danger: Highly Flammable. R: 11 Risk Statements: Highly flammable. S: 8 16 Safety Statements: Keep container dry. Keep away from sources of ignition - no smoking. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 15.1 mg/m3 DOE Short Term Exposure Limit 45.4 mg/m3 DOE Ceiling Limit 75.7 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM ISOPROPOXIDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM NITRATE A B C D CAS # 7784272 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 2 Dermal Hazard Corrosive Eye Damage STEL . . 0 . 1 I J K L . OX Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ACUTE TOXICTY RISK INDEX 2.1 - LD50 INHALATION RISK INDEX <1 - LC50 3671.0 mg/Kg ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Finely powdered metals, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Aluminum oxide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi Indication of Danger: Oxidizing. Irritant. R: 8 36/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 27.8 mg/m3 DOE Short Term Exposure Limit 27.8 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM NITRATE CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM POTASSIUM SULFATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7784249 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Bases, Steel, Aluminum, Copper, Zinc. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Aluminum oxide REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 35.2 mg/m3 DOE Short Term Exposure Limit 105 mg/m3 DOE Ceiling Limit 176 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM POTASSIUM The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM POTASSIUM SULFATE SESQUIHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 10043671 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 19.1 mg/m3 DOE Short Term Exposure Limit 57.4 mg/m3 DOE Ceiling Limit 95.7 mg/m3 Immediately Dangerous to Life and Health 100 mg/m3ALUMINUM POTASSIUM The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM SULFATE A B C D CAS # 10043013 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 1.4 - LD50 20022.6 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Bones.SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 12.7 mg/m3 DOE Short Term Exposure Limit 38 mg/m3 DOE Ceiling Limit 63.4 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3ALUMINUM SULFATE CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM SULFATE HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 17927650 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Bones.SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 37/38 41 Risk Statements: Irritating to respiratory system and skin. Risk of serious damage to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. ALUMINUM SULFATE OCTADECAHYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 7784318 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1.7 - LD50 9000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Bones. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Aluminum oxide Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMARANTH A B C D CAS # 915673 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSUR skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 36/37/39 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERJET 1200(H) A B C D CAS # 39389203 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLIN User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERJET 4200-CL A B C D CAS # 60177391 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Alkylbenzenes vinylbenzenes naphthalene benzaldehydes and phenol may also form REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Dry ion exchange resins expand when wetted, which may cause column to shatter. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMBERJET 4200-CL CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE A B C D CAS # 78922040 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE CARBON DIOXIDE, DRY CHEMICAL POWDER OR SULFUR OXIDES REACTIVE PROPERTIES THE MAXIMUM OPERATING TEMPERATURE THAT IS RECOMMENDED IS 120 C. DRY ION EXCHANGE RESINS EXPAND WHEN WETTED, WHICH MAY CAUSE COLUMN TO SHATTER. NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPE REACTIONS WHEN MIXED WITH ION EXCHANGE RESINS. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE CG-120 A B C D CAS # 37360751 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ACUTE EFFECTS CAUSES EYE IRRITATION. MAY BE HARMFUL IF INHALED. THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE. DRY CHEMICAL POWDER. SPRAY. TOXIC EMISSIONS WHEN BURNED: ACIDS STRONG OXIDIZING AG WATER REACTIVE PROPERTIES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE IR-120 A B C D CAS # 63182081 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE CARBON DIOXIDE, DRY CHEMICAL POWDER OR SULFUR OXIDES REACTIVE PROPERTIES THE MAXIMUM OPERATING TEMPERATURE THAT IS RECOMMENDED IS 120 C. DRY ION EXCHANGE RESINS EXPAND WHEN WETTED, WHICH MAY CAUSE COLUMN TO SHATTER. NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPE REACTIONS WHEN MIXED WITH ION EXCHANGE RESINS. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE IR-120 A B C D CAS # 9002237 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE CARBON DIOXIDE, DRY CHEMICAL POWDER OR SULFUR OXIDES REACTIVE PROPERTIES THE MAXIMUM OPERATING TEMPERATURE THAT IS RECOMMENDED IS 120 C. DRY ION EXCHANGE RESINS EXPAND WHEN WETTED, WHICH MAY CAUSE COLUMN TO SHATTER. NITRIC ACID AND OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPE REACTIONS WHEN MIXED WITH ION EXCHANGE RESINS. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMBERLITE IR-120 CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE IRA-400 A B C D CAS # 122560638 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMBERLITE IRA-400 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE IRC-50 A B C D CAS # 9002293 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE MB-150 A B C D CAS # 100915966 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 ACUTE TOXICTY RISK INDEX 2 - LD50 5000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMBERLITE MB-150 CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE MB-3 A B C D CAS # 100915977 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE. TOXIC EMISSIONS WHEN BURNED: WITH: DRY CHEMICAL POWDER. WATER SPRAY. ACIDS STRONG OXIDIZING AGENTS HA The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE XAD 1180 A B C D CAS # 9003694 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . . . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36 Risk Statements: Irritating to eyes. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 25 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMBERLITE XAD 1180 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE XAD-4 A B C D CAS # 37380420 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE XAD-7 A CAS # 37380431 Special Carcinogen E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 J K L . . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 17.0 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMBERLITE XAD-7 CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE XE-305 A B C D CAS # 9003536 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 30 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3AMBERLITE XE-305 CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLITE# IRA-68 A B C D CAS # 9056591 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . OX Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide. Dry chemical powder. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Acrylate monomer and divinylbenzene may also be formed REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. Dry ion exchange resins expand when wetted, which may cause column to shatter. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLYST A-21 A B C D CAS # 9049938 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 17.0 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Amines REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMBERLYST A-26 A B C D CAS # 39339850 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 17.0 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMILORIDE HYDROCHLORIDE HYDRATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2016888 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.1 - LD50 36.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Hyperkalaemia, nausea, vomiting, abdominal pain, diarrhea or constipation, paraesthesia, thirst, dizziness, skin rash, pruritus, weakness, muscle cramps, and minor psychiatric or visual changes. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 36 45 Safety Statements: Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINE-TERMINATED MAGNETIC PARTICLES A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 105808728 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.STORAGE: Keep tightly closed\. Store at 2-8°C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINO ACID OXIDASE A B C D CAS # 9000899 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . - LC50 SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of toxic exposure include hypotension, reduced circulating plasma volume, shock, hemorrhage, edema, and myonecrosis. CONDITIONS AGGRAVATED BY EXPOSURE May be fatal if enters bloodstream. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Inhibited by ammonium ions, benzoate, iodoacetate, and octyl alcohol. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C REACTIVE PROPERTIES STORAGE Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 26/27/28 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. S: 36/37/39-45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINO ACID OXIDASE (D-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 9000888 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Use extinguishing media appropriate to surroundingfire conditions. REACTIVE PROPERTIES User Exposure: Avoid contact with eyes, skin, and clothing. Avoid inhalation. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINO DIFLUOROBENZONITRILE (4:2,5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 112279615 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.9 - LD50 64.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen fluoride Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 Risk Statements: Toxic if swallowed. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINO-TEMPO (4-) A B C D CAS # 14691884 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOACETANILIDE (4'-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 122805 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 302 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 36 42/43 Risk Statements: Irritating to eyes. May cause sensitization by inhalation and skin contact. S: 22 26 36/37 Safety Statements: Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOACETONITRILE BISULFATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 151633 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOACETONITRILE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 6011149 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Carbon nitrogen oxides monoxide and REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22-36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOACETOPHENONE (4'-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 99923 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 381.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid delayed SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOACETOPHENONE (META-) CAS # 99036 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 995.9 mg/Kg INHALATION RISK INDEX <1 - LC50 J K ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION L skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. delayed PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents, Strong reducing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 43 Risk Statements: Harmful if swallowed. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOANTHRAQUINONE (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 82451 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Chloroformates, Acid anhydrides, Acid chlorides, Acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOANTIPYRINE (4-) A B C D CAS # 83078 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1700.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZAMIDE (4-) A B C D CAS # 2835689 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if inhaled or swallowed. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 36/38 Risk Statements: Harmful by inhalation and if swallowed. Irritating to eyes and skin. S: 38 Safety Statements: In case of insufficient ventilation, wear suitable respiratory equipment. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZAMIDINE DIHYDROCHLORIDE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 2498502 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZENEMETHANOL (2-) CAS # 5344901 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZENESULFONIC ACID (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 121471 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12300.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Rabbit 500 mg 24H Remarks: Mild irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 23 28 Safety Statements: Do not breathe fumes. After contact with skin, wash immediately with plenty of soap-suds. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZO COUMARIN (6:3,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 83527995 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 99058 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 1.4 - LD50 20322.6 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 302 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 150130 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 6000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. L Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .000280 mm Hg @ 20 °C SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36/37/38-43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 100 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOBENZOIC ACID (4-) The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID (BOC,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 68790385 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID (BOC,3-) A B Special Carcinogen Human Terato\Repro Haz CAS # 111331829 E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . K L . . Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID (BOC,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 66493398 E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 0 Dermal Hazard Corrosive Eye Damage STEL . . 0 . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID ETHYL ESTER METHANESULFONATE (3A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . CAS # 886862 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOIC ACID POTASSIUM (PARA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 138841 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Causes irritation. May be harmful by inhalation, ingestion, or skin absorption. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES STORAGE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZONITRILE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2237301 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 878.7 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 233.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 43 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZONITRILE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 873745 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 283.0 mg/Kg NEUROTOXIC - RISK INDEX 5.0 INHALATION RISK INDEX <1 - LC50 J K ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE . Absorption into the body leads to the formation of methemoglobin in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. which PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acid anhydrides, Chloroformates, Strong oxidizing agents, Acid chlorides, Acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOPHENONE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1137413 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.4 - LD50 18.4 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOTHIAZOLE (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 136958 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 1000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 3 Risk Statements: Harmful if swallowed. Irritating to eyes. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZOTRIFLUORIDE (PARA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 455141 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 3.6 - LD50 128.0 mg/Kg J K . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. SENSITIZATION Sensitization: Will not occur SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). Prolonged exposure can cause: Nausea, dizziness, and headache. Narcotic effect. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 188 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZYL ALCOHOL (4-) A B C D CAS # 623041 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . . Dermal Hazard Corrosive Eye Damage STEL . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Air sensitive. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZYLAMINE (2-) CAS # 4403694 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acids. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. Incompatible Materials: Absorbs carbon dioxide from air. Avoid contact with acid. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBENZYLAMINE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 4403718 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Handle and store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBIPHENYL (2-) A B C D CAS # 90415 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2340.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 307.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 40 52/53 Risk Statements: Harmful if swallowed. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 61 Safety Statements: Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBIPHENYL (4-BIPHENYLAMINE) (4-) CONCERN A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 92671 Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARDOUS CHEMICAL OF Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A . . . E . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 4.9 - TD50 .6 mg/Kg ACUTE TOXICTY RISK INDEX 3 - LD50 500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 K . cancer suspect agent ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Bladder. Skin. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 45 22 Risk Statements: May cause cancer. Also harmful if swallowed. S: 53 45 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMINOBIPHENYL The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMOMETHYLPYRIMIDINOL (2:5:4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 6307353 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMONITROPYRIDINE (2:5:3-) A B C Special Carcinogen Human Terato\Repro Haz Highly Toxic E F G CAS # 6945682 Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 L . . . Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMOPYRIDINE (2:3-) CAS # 13534991 A B C E F G Special Carcinogen Human Terato\Repro Haz Highly Toxic Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 L . . . Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMOPYRIDINE (2:5-) CAS # 1072975 A E Special Carcinogen Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 297.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. ADDITIONAL INFORMATION The preceding data, or interpretation of data, was determined using Quantitative Structure Activity Relationship (QSAR) modeling. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMOPYRIDINE (2:6-) CAS # 19798813 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMOPYRIDINE (3:6-) CAS # 13534979 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBROMOPYRIDINE (4:2-) CAS # 7598358 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K L 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 37/38 41 43 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by skin contact. S: 26 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBUTYRIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 56122 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1 - LD50 47296.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBUTYRIC ACID (BOC,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 57294389 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOBUTYRIC ACID (DL,3-) CAS # 2835827 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCAPROIC ACID (6-) A B C D CAS # 60322 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 1 - LD50 46129.0 mg/Kg INHALATION RISK INDEX <1 - LC50 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Exposure may cause itching, erythema, skin rash, diuresis, heartburn, nausea and diarrhea. Blood effects. Other symptoms include orthostatic hypotension and bradycardia. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCHLORONITROPYRIDINE (2:5:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5409392 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCHLOROPHENOL (2:4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 95852 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 690.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Severe irritation or burns. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Prolonged contact can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCHLOROPHENOL (2:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 28443507 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCHLOROPYRAZINE (2:6-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 33332284 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.1 - LD50 399.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: Causes blisters on contact with skin. Causes skin irritation. skin Absorption: Skin absorption may occur. May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 37/38 41 43 Risk Statements: Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by skin contact. S: 26 28 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCHLOROPYRIDINE (3:2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6298197 E F G H HAZARD INDEX . . . . NFPA HAZARD CODES (H,F,R,O) 0 Dermal Hazard Corrosive Eye Damage STEL . 0 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE May cause cyanosis (blue-gray coloring of skin and lips caused by lack of oxygen). To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8°C Keep container closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep container closed. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCHLOROPYRIMIDINE (2:5-) A B Special Carcinogen Human Terato\Repro Haz CAS # 5428897 E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL K L Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 3.2 - LD50 275.8 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Severe eye irritant. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. Sensitization: Sensitizer. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 41 43 Risk Statements: Harmful if swallowed. Risk of serious damage to eyes. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCINNAMIC ACID HYDROCHLORIDE (PARA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 54057953 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCRESOL (META,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2835974 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCRESOL (META,6-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2835985 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCROTONIC ACID (TRANS,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 38090538 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCYANOPYRIDINE (2:5-) CAS # 4214737 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCYANOPYRIDINE (5:2-) CAS # 55338733 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen cyanide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOCYCLOPROPANE CARBOXYLIC ACID (1:1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 22059218 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINODIETHYLAMINOPENTANE (2:5-) CAS # 140807 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 F G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 155 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINODIMETHYL PHENOL (4:2,5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 3096717 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and swallowed. Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. if The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINODIMETHYLPHENOL HYDROCHLORIDE (4,2,3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 619603 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: SITION PRODUCTS TOXIC FUMES OF: CARBON MO The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINODIPHENYLAMINE (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 534850 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OX ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. Oral Rat 450 mg/kg LD50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn R: 20/22 38 Risk Statements: Harmful by inhalation and if swallowed. Irritating to skin. S: 22 24 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL BENZENESULFONYL FLOURIDE HYDROCHLORIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . G CAS # 30827997 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. CONDITIONS AGGRAVATED BY EXPOSURE A protease inhibitor. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong bases, Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas Hydrogenfluoride Store at 2-8°C Keep tightly closed. Store under argon. Moisture sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under argon\. Store at 2-8░C SPECIAL REQUIREMENTS Moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 250 mg/m The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL HYDROGEN SULFATE (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 926396 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3548.4 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL PIPERAZINE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 140318 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2140.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Readily absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .0500 mm Hg @ 20 °C FLASH POINT 197.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 21/22 34 43 52/53 Risk Statements: Harmful in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26 36/37/39 45 61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.5 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOETHYL PIPERAZINE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL PIPERIDINE (1,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 27578605 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 136.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL PROPANEDIAMINE CAS # 13531527 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 F 0 G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 205 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: CORROSIVE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 28 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL PYRROLIDINE (1,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 7154736 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 116.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS Air and moisture sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 10 34 Risk Statements: Flammable. Causes burns. S: 16 26 27 36/37/39 45 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYL VINYL ETHER (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7336290 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . 0 G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 84.2 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place\. SPECIAL REQUIREMENTS May develop pressure. Open carefully. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 34 36/37 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to eyes and respiratory system. S: 16 26 33 36 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take precautionary measures against static discharges. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYLAMINO NITROPYRIDINE (2,2:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 29602399 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Damage to the eyes. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Damage to the eyes. Nausea, dizziness, and headache. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYLAMINOETHANOL (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 111411 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Lachrymator. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 291.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents Avoid contact with acid. Copper, Copper alloys, Zinc, Galvanized iron FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 43 Risk Statements: Causes burns. May cause sensitization by skin contact. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYLCARBAZOLE A B C D CAS # 132321 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.5 - LD50 144.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. Liver. Kidneys. Bladder. Brain. Heart. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 45 Safety Statements: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYLMETHYL CARBAMIC ACID BUTYL ESTER (N,2:N: A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . CAS # 121492066 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 23 26 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYLMORPHOLINE (4,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2038031 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . G . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1850.0 mg/Kg INHALATION RISK INDEX 1.5 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .700 mm Hg @ 20 °C FLASH POINT 186.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 43 Risk Statements: Harmful if swallowed. Causes burns. May cause sensitization by skin contact. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOETHYLPYRIDINE (2,2-) CAS # 2706561 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 212 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOFLUOROPYRIDINE (2:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 21717964 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen fluoride REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOGLUTETHIMIDE A B C D CAS # 125848 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 240.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Adrenal cortex. Thyroid. Blood. CONDITIONS AGGRAVATED BY EXPOSURE Aminoglutethimide blocks the synthesis of adrenal steroid hormones and the physiological conversion of androgens to estrogens. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOGUANIDINE HEMISULFATE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 996190 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Materials to Avoid: S FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOGUANIDINO PROPIONIC ACID HYDROCHLORIDE (L,2, A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . CAS # 1482991 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOHYDRAZINOMERCAPTOTRIAZOLE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1750125 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t TOXIC EMISSIONS WHEN BURNED: ZARDOUS POLYMERIZATION Store at -20°C REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Store at -20░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOHYDROXYPYRAZOLE (3:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 6126223 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOHYDROXYPYRIDINE (2:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 16867031 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 570.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOIMIDAZOLE SULFATE (2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1450937 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOINDANOL (CIS,1:2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 136030007 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Acids, Bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOINDAZOLE (5-) A B C D CAS # 19335116 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 645.2 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Toxic if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Cyanosis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 25 36/37/38 Risk Statements: Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOINDAZOLE (6-) A B C D CAS # 6967120 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3448.3 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: SITION PRODUCTS TOXIC FUMES OF: CARBON MO The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOINDOLE (4-) A B C D CAS # 5192234 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOIODOBENZOIC ACID (2:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 5326476 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide Store at 2-8°C Keep tightly closed. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOIODOBENZONOTRILE (4:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 33348344 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOIODOPYRIDINE (2:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 20511120 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen iodide REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOISOBUTYRIC ACID (2-) CAS # 62577 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOISOINDOLE HYDROCHLORIDE (3,1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 76644741 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. IRRITATION DATA Eyes Remarks: Moderate irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOISOXAZOLE (3-) A B C D CAS # 1750421 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOLEVULINIC ACID HYDROCHLORIDE (5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5451092 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8°C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMERCAPTOTHIADIAZOLE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2349679 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHOXYISOXAZOLE (3:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1072679 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 2 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Explosive SEGREGATION: SHELF # 3 STORAGE GROUP(S): k - Explosive/Unstable WASTE CHARACTERISTIC HAZARD: REACTIVE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHOXYPROPANE (2:1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 37143547 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Female reproductive system. Eyes. Bone marrow. Blood. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Exposure can cause: Blood effects. Narcotic effect. Nausea, dizziness, and headache. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 48 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Acid anhydrides, Acid chlorides, Strong acids, oxidizing agents. Strong FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: F-C Indication of Danger: Highly Flammable. Corrosive. R: 11-22-34-52/53 Risk Statements: Highly flammable. Harmful if swallowed. Causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 9-26-36/37/39-45-61 Safety Statements: Keep container in a well-ventilated place. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. EU ADDITIONAL CLASSIFICATION Symbol of Danger: F-T Indication of Danger: Highly Flammable. Toxic. R: 45-46-11-34 Risk Statements: May cause cancer. May cause heritable genetic damage. Highly flammable. Causes burns. S: 53-26-36/37/39-45 Safety Statements: Restricted to professional users. Attention Avoid exposure - obtain special instructions before use. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL BENZENESULFONAMIDE HYDROCHLORIDE HYDRA A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L CAS # 138374 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.3 - LD50 25800.0 mg/Kg . . L INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SENSITIZATION Respiratory: May cause allergic respiratory reaction. skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause pain or burning sensation at the site of contact. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22 36/37 45 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL BENZOIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 56917 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL BENZONITRILE (4:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 78881217 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. Harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21 43 Risk Statements: Harmful by inhalation and in contact with skin. May cause sensitization by skin contact. S: 36/37 Safety Statements: Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL BUTANE (R,2-) CAS # 34701332 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L G . . 0 531.0 mg/Kg 5200.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 70 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 22 34 Risk Statements: Highly flammable. Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL BUTANE (S,2-) CAS # 22526461 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 3 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 70 °F Forms ignitable mixtures in air at room temperature - Danger of remote ignition and flashback SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: F C Indication of Danger: Highly Flammable. Corrosive. R: 11 20/21/22 35 Risk Statements: Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes severe burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL ISOXAZOLE (5:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 14678025 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL PROPANEDIOL A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 115695 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.5 - LD50 17000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .002837 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Aluminum, Copper, Brass, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL PROPANOL A B C D CAS # 124685 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2900.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes severe eye irritation. nhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE .800 mm Hg @ 20 °C FLASH POINT 154.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents, Strong acids Copper, Copper alloys, Brass, Aluminum. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: and nitrogen oxides Store at -20°C Store under inert gas. Air sensitive. Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store under nitr REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store under nitrogen\. Store at -20░C SPECIAL REQUIREMENTS Store under inert gas. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 52/53 METHODS FOR CLEANING UP Absorb on sand or vermiculite and place in closed containers for disposal. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Suitable: Keep tightly closed. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Mechanical exhaust required. Safety shower and eye bath. PERSONAL PROTECTIVE EQUIPMENT Respiratory: Government approved respirator. Hand: Compatible chemical-resistant gloves. Eye: Chemical safety goggles. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Section 9 - Physical/Chemical Properties Appearance Physical State: Liquid Property Value At Temperature or Pressure Molecular Weight pH BP/BP Range MP/MP Range Freezing Point 671.1 AMU N/A 178 ░C -52 ░C N/A 760 mmHg Vapor Pressure Vapor Density Saturated Vapor Conc. SG/Density Bulk Density Odor Threshold Volatile% VOC Content Water Content Solvent Content Evaporation Rate Viscosity Surface Tension Partition Coefficient Decomposition Temp. Flash Point Explosion Limits Flammability Autoignition Temp Refractive Index Optical Rotation Miscellaneous Data Solubility 1.3 mmHg 23.3 g/l N/A 1.89 g/cm3 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 1.3 N/A N/A N/A 25 ░C N/A = not available Section 10 - Stability and Reactivity STABILITY Stable: Stable. Materials to Avoid: Finely powdered metals, Alkali metals. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen oxides, Hydrogen fluoride, May also form perfluoroisobutylene. HAZARDOUS POLYMERIZATION Hazardous Polymerization: Will not occur Section 11 - Toxicological Information ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DATA Oral Rat > 10000 mg/kg LD50 Intravenous Mouse 12 GM/KG LD50 Section 12 - Ecological Information No data available. Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: None Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport. IATA Non-Hazardous for Air Transport: Non-hazardous for air transport. Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .03 mg/m3 DOE Short Term Exposure Limit .075 mg/m3 DOE Ceiling Limit .6 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOMETHYL PROPANOL The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYL PYRIDINE (2-) CAS # 3731519 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 694.0 mg/Kg J K . INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 210.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLAMINOMETHYL BENZENE (1:N,BOC,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 108468004 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26-36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLANLINE (4:1,N,BOC-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 94838558 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLBENZIMIDAZOLE (2:1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1622577 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLBENZIMIDAZOLE DIHYDROCHLORIDE HYDRATE ( A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . CAS # 5993919 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLBENZOIC ACID HYDROCHLORIDE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . CAS # 876039 Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLCYCLOHEXANOL HYDROCHLORIDE (1:1-) CAS # 19968855 A I Special Carcinogen E Dermal Hazard Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . J K L . . Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. STORAGE: Keep container closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLISOTHIAZOLE HYDROCHLORIDE (5:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 52547009 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMETHYLPYRIDINE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 3731531 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 219.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 37 Risk Statements: Causes burns. Irritating to respiratory system. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOMORPHOLINE (4-) A B C D CAS # 4319497 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 3225.8 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 137 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents Carbon dioxide. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONAPHTHALENE (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 134327 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.9 - LD50 680.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Harmful if absorbed through skin. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be fatal if inhaled. Ingestion: Harmful if swallowed. Bladder. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin delayed 2 to 4 hours or longer. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 314.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air and light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Indication of Danger: Harmful. Dangerous for the environment. R: 22 51/53 Risk Statements: Harmful if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic S: 24 61 Safety Statements: Avoid contact with skin. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .6 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 12.5 mg/m3 Immediately Dangerous to Life and Health 350 mg/m3AMINONAPHTHALENE (1-) The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONAPHTHALENE CARBONITRILE (4:1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 58728646 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. S: 36 Safety Statements: Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONAPHTHOL HYDROCHLORIDE (1,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 1198272 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, onclothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/21/22 36/37/38 40 Risk Statements: Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. S: 26 27 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONAPHTHOL HYDROCHLORIDE (4,1) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 5959568 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONAPHTHOL SULFONIC ACID (1,2,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 116632 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONAPHTHOLSULFONIC ACID (6,1,3-) A Special Carcinogen E CAS # 87025 Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 11500.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged exposure can cause: Chemical pneumonitis. Pulmonary edema. Effects may be delayed. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 27 36/37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONICOTINIC ACID METHYL ESTER (6-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 36052241 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 2100.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROBENZOIC ACID (2:5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 616795 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROBENZONITRILE (4:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 6393404 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROBENZOPHENONE (4:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 31431193 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITRONAPTHELENE (1:4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 776341 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROPHENOL (2:4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 99570 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2400.0 mg/Kg INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 212 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid chlorides, Acid anhydrides, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROPHENOL (4,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 119346 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1470.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid all contact. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROPHENOL (4:3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 610811 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROPYRIDINE (2:3-) CAS # 4214759 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 332.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROQUINOLINE (5:6-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 35975009 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONITROTOLUENE (2,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 99558 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D E . . . . J NFPA HAZARD CODES (H,F,R,O) 2 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: Toxic if absorbed through skin. Readily absorbed through skin. Eye Contact: May cause eye irritation. Inhalation: Toxic if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .0000100 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid chlorides, Acid anhydrides, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 40 52/53 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 36/37 45 61 Safety Statements: Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 7.5 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 150 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMINONITROTOLUENE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINONORBORNANE (EXO,2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 7242924 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . . . . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 95 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPENICILLANIC ACID (6-) CAS # 551166 A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: May cause eye irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: May cause allergic respiratory and skin reactions SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides Store at 2-8°C Keep tightly closed. REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 42/43 Risk Statements: May cause sensitization by inhalation and skin contact. S: 22-36/37 Safety Statements: Do not breathe dust. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPEPTIDASE A B C D CAS # 9031941 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE Multiple Routes: May cause irritation. May be harmful by inhalation, ingestion, or skin absorption. SENSITIZATION Sensitization: Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Store at -20°C Keep container closed. Store away from heat. REACTIVE PROPERTIES STORAGE: Keep container closed. Store away from heat. Store at -20░C The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENOL (2-) A B C CAS # 95556 Special Carcinogen Human Terato\Repro Haz Highly Toxic E F G Dermal Hazard Corrosive Eye Damage I J K Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz D Inhalation Hazard H STEL L Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 1 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 951.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 2.1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible VAPOR PRESSURE 1.8 mm Hg @ 20 °C FLASH POINT 334.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids, Acid anhydrides, Acid chlorides, Chloroformates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 20/22 68 Risk Statements: Harmful by inhalation and if swallowed. Possible risk of irreversible effects. S: 28 36/37 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. Wear suitable protective clothing and gloves. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 mg/m3 DOE Short Term Exposure Limit 1.5 mg/m3 DOE Ceiling Limit 10 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOPHENOL (2-) CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENOL (3-) A B C D CAS # 591275 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L . . . 0 924.0 mg/Kg 1162.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Eyes. SIGNS AND SYMPTOMS OF EXPOSURE Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue. Exposure can cause: Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. Dangerous for the environment. R: 20/22 51/53 Risk Statements: Harmful by inhalation and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 28 61 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. Avoid release to the environment. Refer to special instructions/safety data sheets. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 1 mg/m3 DOE Short Term Exposure Limit 3 mg/m3 DOE Ceiling Limit 20 mg/m3 Immediately Dangerous to Life and Health 125 mg/m3AMINOPHENOL (3-) CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENOL (PARA-) A B C D CAS # 123308 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 1 1 ACUTE TOXICTY RISK INDEX 5 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L . . . 0 375.0 mg/Kg 5.0 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K L ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION Sensitization: May cause allergic reaction. TARGET ORGAN(S) OR SYSTEM(S) Blood. Kidneys. Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 383 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 20/22 50/53 68 Risk Statements: Harmful by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of irreversible effects. S: 28 36/37 60 61 Safety Statements: After contact with skin, wash immediately with plenty of polyethylene glycol. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENOL HYDROCHLORIDE (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 51785 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . 0 ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. L Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t TOXIC EMISSIONS WHEN BURNED: XPOSURE REACTIVE PROPERTIES User Exposure: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store under argon. Store in a SPECIAL REQUIREMENTS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 43 36/37/38 Risk Statements: May cause sensitization by skin contact. S: 28 36 Safety Statements: After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing. Indication of Danger: Harmful. Risk Statements: May cause sensitization by skin contact. Irritating to eyes, respiratory system and skin. Safety Statements: Wear suitable protective clothing, gloves, immediately with plenty of water and seek medical advice. US Statements: Target organ(s): Blood. Kidneys. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYL BORONIC ACID (BOC,4-) A B Special Carcinogen Human Terato\Repro Haz E F CAS # 380430499 Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . K L . . Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYL BORONIC ACID HYDROCHLORIDE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 85006231 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas Boron oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYL BORONIC ACID MONOHYDRATE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 280563635 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 INHALATION RISK INDEX <1 - LC50 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Boron oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYL DISULFIDE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 722270 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYL ETHYLAMINE (2,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 13472009 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 1 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYLACETIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 1197553 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 1.9 - LD50 5882.4 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22-24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYLACETYLENE (3-) CAS # 54060309 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . . Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 138 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. Keep away from heat and open flame. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store at 2-8░C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHENYLMERCURIC ACETATE (PARA-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 6283245 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers I . . . - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be fatal if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: May be fatal if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Kidneys. Nerves. SIGNS AND SYMPTOMS OF EXPOSURE Exposure to mercury compounds can cause tremors, loss of appetite, weight loss, anuria, and uremia. CONDITIONS AGGRAVATED BY EXPOSURE May cause nervous system disturbances. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Mercury/mercury oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T+ N Indication of Danger: Very toxic. Dangerous for the environment. R: 26/27/28 33 50/53 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13 28 36 45 60 61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. After contact with skin, wash immediately with plenty of soap-suds. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Immediately Dangerous to Life and Health 10 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHTHALHYDRAZIDE (3-) CAS # 521313 A B C D E F G H Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 ACUTE TOXICTY RISK INDEX 3 - LD50 INHALATION RISK INDEX <1 - LC50 . I J K L . . . 0 500.0 mg/Kg Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers J K . ROUTE OF EXPOSURE skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC FIRE EXTINGUISHER: appropriate foam. REACTIVE PROPERTIES HANDLING and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPHYLLIN HYDRATE A B C D CAS # 317340 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . I NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 3.3 - LD50 243.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. May cause irritation. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. Heart. Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Adverse reactions: nausea, vomiting, diarrhea, anorexia, dyspepsia, epigastric pain, hematemesis, dizziness, vertigo, headache, light- headedness, nervousness, insomnia, hyperreflexia, fasciculations, clonic and tonic convulsions, palpitation tachycardia, extrasystoles, hypotension, circulatory failure, increased respiratory rates, urticaria. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPIPERIDINE (1-) A B C D CAS # 2213436 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 3 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Flammable FLASH POINT 97 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: IGNITABLE INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 10 36/37/38 Risk Statements: Flammable. Irritating to eyes, respiratory system and skin. S: 16 26 36/37/39 Safety Statements: Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPANOL (2:1-) A B C D CAS # 2749113 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 2 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. Vapor or mist is irritating to the eyes, mucous membranes, and upper respiratory tract. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 145 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Oxidizing agents Avoid contact with acid. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store under nitrogen\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPANOL (3,1-) A B C D CAS # 156876 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . G . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2830.0 mg/Kg INHALATION RISK INDEX 1.7 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE 2.1 mm Hg @ 20 °C FLASH POINT 213.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 22 34 Risk Statements: Harmful if swallowed. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .015 mg/m3 DOE Short Term Exposure Limit .04 mg/m3 DOE Ceiling Limit .3 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOPROPANOL (3,1-) The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPANOL (DL,1:2-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 78966 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 2 INHALATION RISK INDEX 1.7 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE***** mm Hg @ 20 °C FLASH POINT 159.8 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place\. Store at 2-8°C GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 34 Risk Statements: Causes burns. S: 23 26 36 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPYL SILICA GEL A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 000039 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: When heated to decomposition it may emit: HAZARDOUS EXOTHERMIC REACTIONS Hazardous Exothermic Reactions: Will not occur REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPYL SILICA GEL A B C D CAS # 39 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . 0 . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . OTHER HEALTH HAZARDS MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: WATER SPRAY. appropriate foam. CARBON DIOXIDE, DRY CHEMICAL POWDER OR The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPYLMORPHOLINE (4,3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 123002 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . F G . . NFPA HAZARD CODES (H,F,R,O) 2 1 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 3560.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Absorption: Readily absorbed through skin. Harmful if absorbed through skin. Inhalation: May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 210 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Oxidizing agents, Chloroformates, sensitive to carbon dioxide. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C Indication of Danger: Corrosive. R: 21 34 Risk Statements: Harmful in contact with skin. Causes burns. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPYLTRIETHOXYSILANE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 919302 Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.4 - LD50 1780.0 mg/Kg . . . SOLVENT NARCOTIC OR NEUROTOXIN INHALATION RISK INDEX <1 - LC50 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid SEGREGATION: SHELF # 1 STORAGE GROUP(S): WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: DO NOT USE WATER. CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: MBUSTION OR DECOMPOSITION PRODUCTS THERMAL DE US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 6 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPROPYLTRIMETHOXYSILANE (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 13822565 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 2 INHALATION RISK INDEX <1 - LC50 . G I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 197.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Silicon oxide REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store at 2-8░C SPECIAL REQUIREMENTS Moisture sensitive. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPTERIN A B C D CAS # 54626 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . B C . . . . . . NFPA HAZARD CODES (H,F,R,O) 4 0 0 HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 6.2 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 4.7 - LD50 9.7 mg/Kg INHALATION RISK INDEX <1 - LC50 J . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be fatal if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Blood. SIGNS AND SYMPTOMS OF EXPOSURE Blood effects. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at -20°C Keep tightly closed. Light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at -20░C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 61 28 Risk Statements: May cause harm to the unborn child. Very toxic if swallowed. S: 53 28 36/37 45 Safety Statements: Avoid exposure - obtain special instructions before use. After contact with skin, wash immediately with plenty of polyethylene glycol. Wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 5 mg/m3 DOE Short Term Exposure Limit 15 mg/m3 DOE Ceiling Limit 25 mg/m3 The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPYRAZINE A B C D CAS # 5049616 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . E F G H . . Dermal Hazard Corrosive Eye Damage STEL . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .5 ppm DOE Short Term Exposure Limit 1.5 ppm DOE Ceiling Limit 2.5 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPYRIDINE (2-) A B C D CAS # 504290 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . I NFPA HAZARD CODES (H,F,R,O) 2 2 0 ACUTE TOXICTY RISK INDEX 3.4 - LD50 200.0 mg/Kg NEUROTOXIC - RISK INDEX 3.0 INHALATION RISK INDEX <1 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: Harmful if absorbed through skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Toxic if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Nerves. SIGNS AND SYMPTOMS OF EXPOSURE May cause convulsions. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 197.6 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 21 25 36/37/38 Risk Statements: Harmful in contact with skin. Toxic if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37/39 45 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Immediately Dangerous to Life and Health 5 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPYRIDINE (3-) A B C D CAS # 462088 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D E . . . I J NFPA HAZARD CODES (H,F,R,O) 0 2 0 ACUTE TOXICTY RISK INDEX 3.5 - LD50 165.0 mg/Kg SOLVENT NARCOTIC OR NEUROTOXIN INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 K . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) Nerves. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 190.4 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: T Indication of Danger: Toxic. R: 23/24/25 33 Risk Statements: Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. S: 36/37/39 45 Safety Statements: Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPYRIMIDINE (2-) A B C D CAS # 109126 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPYRIMIDINE (4-) A B C D CAS # 591548 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid anhydrides, Acid chlorides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 37/39 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves and eye/face protection. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOPYRROLIDINE HYDROCHLORIDE (1-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 63234719 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Hydrogen chloride gas REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOQUINOLINE (3-) A B C D CAS # 580176 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOQUINOLINE (6-) A B C D CAS # 580154 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOQUINOLINE (8-) A B C D CAS # 578665 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. STORAGE: Keep tightly closed. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/38 Risk Statements: Irritating to eyes and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOSALICYLIC ACID (3-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 570230 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOSALICYLIC ACID (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 65496 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 1.6 - LD50 12903.2 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. Liver. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place. Handle and store under nitrogen\. SPECIAL REQUIREMENTS Handle and store under inert gas. Light sensitive. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOSALICYLIC ACID (5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 89576 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.2 - LD50 2800.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Store at 2-8°C Keep tightly closed. Light sensitive. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C SPECIAL REQUIREMENTS Light sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOSALICYLIC ACID SODIUM (4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 6018195 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE Inhalation: Material is irritating to mucous membranes and upper respiratory tract. Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. Causes eye and skin irritation. TARGET ORGAN(S) OR SYSTEM(S) G.I. System. Liver. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. STORAGE: Keep tightly closed. Store in a cool dry place\. SPECIAL REQUIREMENTS Light sensitive. Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTETRAHYDRONAPHTHALENE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 2217416 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 1 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Ccombustible FLASH POINT 235 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Store under nitrogen. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 Risk Statements: Irritating to eyes, respiratory system and skin. S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTETRAMETHYL PIPERIDINE A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 36768624 E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 2 0 ACUTE TOXICTY RISK INDEX 2.7 - LD50 906.0 mg/Kg INHALATION RISK INDEX 1.4 - LC50 J K . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible VAPOR PRESSURE .200 mm Hg @ 20 °C FLASH POINT 167 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTETRAZOLE MONOHYDRATE (5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H CAS # 4418615 Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L 0 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DAT Oral Rat 1,300 mg/kg LD50 Intraperitoneal Mouse 2500 MG/KG LD50 IRRITATION DATA Eyes Remarks: Moderate irritation effect PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Metals. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36/37/38 43 Risk Statements: Harmful if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wea protective clothing and gloves. suitable The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTHIAZOL (2-) A B C D CAS # 96504 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . E . . . . NFPA HAZARD CODES (H,F,R,O) 3 0 0 ACUTE TOXICTY RISK INDEX 2.8 - LD50 799.5 mg/Kg INHALATION RISK INDEX <1 - LC50 J K L ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Sulfur oxides REACTIVE PROPERTIES HANDLING: Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 36 43 Risk Statements: Harmful if swallowed. Irritating to eyes. May cause sensitization by skin contact. S: 26 36/37 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing and gloves. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTHIOPHENOL (2-) A B C D CAS # 137075 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . D E . G NFPA HAZARD CODES (H,F,R,O) 3 2 0 INHALATION HAZARD INHALATION RISK INDEX I J K L . <1 Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . L - LC50 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SENSITIZATION skin: May cause allergic skin reaction. SIGNS AND SYMPTOMS OF EXPOSURE Pulmonary edema. Effects may be delayed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Coughing, chest pains, difficulty in breathing. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Liquid Ccombustible FLASH POINT 174.2 °F SEGREGATION: SHELF # 1 STORAGE GROUP(S): l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Chloroformates, Acid anhydrides, Acid chlorides, Acids. FIRE EXTINGUISHER: Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Sulfur oxides Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe vapor. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Keep away from heat and open flame. Store under nitrogen\. SPECIAL REQUIREMENTS Store under inert gas. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: C-N Indication of Danger: Corrosive. Dangerous for the environment. R: 22-34-43-50/53 Risk Statements: Harmful if swallowed. Causes burns. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 26-36/37/39-45-60-61 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTOLUENE SULFONIC ACID A B Special Carcinogen Human Terato\Repro Haz CAS # 118887 E F Dermal Hazard Corrosive I J Neurotoxin Suspect Carcinogen C D Highly Toxic Inhalation Hazard G H Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . K L . . Suspect Terato\Repro Haz Sensitizers . . . . 0 PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: CARBON DIOXIDE, DRY CHEMICAL POWDER OR appropriate foam. TOXIC EMISSIONS WHEN BURNED: IDE NITROGEN OXIDES SULFUR OXIDES The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOTRIAZOLE (3,1,2,4-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 61825 E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX A B . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 SPECIAL CARCINOGEN - DESIGNATED AREA MAY BE REQUIRED CHRONIC TOXICITY RISK INDEX 3.7 - TD50 9.9 mg/Kg HUMAN TERATOGEN - DESIGNATED AREA MAY BE REQUIRED REPRODUCTIVE RISK INDEX 4.0 ACUTE TOXICTY RISK INDEX 5 - LD50 25000.0 mg/Kg INHALATION RISK INDEX <1 - LC50 400.0 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Thyroid. Liver. Kidneys. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): a - Organic Base/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Copper Iron and iron salts. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn N Indication of Danger: Harmful. Dangerous for the environment. R: 48/22 63 51/53 Risk Statements: Harmful: danger of serious damage to health by prolonged exposure if swallowed. Possible risk of harm to the unborn child. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S: 13 36/37 61 Safety Statements: Keep away from food, drink, and animal feedingstuffs. Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Permissible Exposure Limit .2 mg/m3 ACGIH RECOMMENDED LIMITS ACGIH Threshold Limit Value .2 mg/m3 US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .2 mg/m3 DOE Short Term Exposure Limit .6 mg/m3 DOE Ceiling Limit 125 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMINOTRIAZOLE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOUNDECANOIC ACID (11-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARD INDEX . . CAS # 2432997 E F G H C Dermal Hazard Corrosive Eye Damage STEL . . . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K . NFPA HAZARD CODES (H,F,R,O) 1 0 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOURACIL (6-) A B C D CAS # 873836 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 0 ACUTE TOXICTY RISK INDEX 2.1 - LD50 4032.3 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. CONDITIONS AGGRAVATED BY EXPOSURE The toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: FIRE EXTINGUISHER: appropriate foam. Water spray. Carbon dioxide, dry chemical powder, or REACTIVE PROPERTIES STORAGE GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMINOVALERIC ACID (5-) A B C D Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard CAS # 660888 E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 1 STORAGE GROUP(S): d - Organic Acid/Flammable/Toxic WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides REACTIVE PROPERTIES User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 22 24/25 Safety Statements: Do not breathe dust. Avoid contact with skin and eyes. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIA A B C D CAS # 7664417 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard HAZARDOUS CHEMICAL OF CONCERN E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . C D . . G H . . NFPA HAZARD CODES (H,F,R,O) 3 1 0 EXTREMELY TOXIC - DESIGNATED AREA MAY BE REQUIRED ACUTE TOXICTY RISK INDEX 5 - LD50 mg/Kg INHALATION HAZARD INHALATION RISK INDEX <1 - LC50 . . 44940.0 ROUTE OF EXPOSURE skin Contact: Causes burns. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes burns. Inhalation: Can cause rapid suffocation. Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Central nervous system. Liver. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Inhalation may result in spasm, inflammation and edema of the larynxand bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Gas Ccombustible VAPOR PRESSURE 6196.1 mm Hg @ 20 °C FLASH POINT 269.6 °F SEGREGATION: SHELF # 3 STORAGE GROUP(S): i - CorrosiveorNon-Toxic Gas l - Flammable/Combustible Solvent WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Oxidizing agents, Galvanized iron, Zinc, Copper, Silver/silver oxides, Cadmium/cadmium oxides, Alcohols, Acids, Halogens, Aldehydes. FIRE EXTINGUISHER: Use water spray or fog nozzle to keep cylinder cool. Move cylinder away from fire if there is no risk. TOXIC EMISSIONS WHEN BURNED: Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe gas. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Use with equipment rated for cylinder pressure, and of compatible materials of construction. Close valve when not in use and when empty. Make sure cylinder is properly secured when in use or stored Cylinder temperature should not exceed 125░F (52░C)\. SPECIAL REQUIREMENTS Contents under pressure. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: T N Indication of Danger: Toxic. Dangerous for the environment. R: 10 23 34 50 Risk Statements: Flammable. Toxic by inhalation. Causes burns. Very toxic to aquatic organisms. S: 9 16 26 36/37/39 45 61 Safety Statements: Keep container in a well-ventilated place. Keep away from sources of ignition - no smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. OSHA REGULATORY LIMITS OSHA Short Term Exposure Limit ACGIH RECOMMENDED LIMITS 35 ppm ACGIH Threshold Limit Value 25 ppm ACGIH Short Term Exposure Limit 35 ppm Immediately Dangerous to Life and Health 300 ppm US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 25 ppm DOE Short Term Exposure Limit 30 ppm DOE Ceiling Limit 160 ppm The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM ACETATE A B C D CAS # 631618 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 0 ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE Exposure can cause: Gastrointestinal disturbances. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2.5 mg/m3 DOE Short Term Exposure Limit 7.5 mg/m3 DOE Ceiling Limit 50 mg/m3 Immediately Dangerous to Life and Health 250 mg/m3AMMONIUM ACETATE CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM BICARBONATE A B C D CAS # 1066337 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . D . F G . . . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1576.0 mg/Kg INHALATION HAZARD INHALATION RISK INDEX 3.0 - LC50 . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE The chemical, physical, and toxicological properties of this product have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE 50.3 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC CORROSIVE INCOMPATIBILITIES:Oxidizing agents, Strong acids, Nitrites, Nitrates. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Ammonia Store at 2-8°C Heat sensitive. Keep tightly closed. REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. Store at 2-8░C SPECIAL REQUIREMENTS Heat sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22 Risk Statements: Harmful if swallowed. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 2 mg/m3 DOE Short Term Exposure Limit 6 mg/m3 DOE Ceiling Limit 40 mg/m3 Immediately Dangerous to Life and Health 200 mg/m3AMMONIUM BICARBONATE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM BROMIDE A B C D CAS # 12124979 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 1 0 0 ACUTE TOXICTY RISK INDEX 2.3 - LD50 2700.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: May cause eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: May be harmful if swallowed. TARGET ORGAN(S) OR SYSTEM(S) Central nervous system. SIGNS AND SYMPTOMS OF EXPOSURE Prolonged contact with moist skin can produce severe irritation or burns. Prolonged inhalation of dust can produce bronchitis. Ingestion of large quantities can cause irritability, confusion, tremors, acne- like skin erruptions, memory loss, headache, slurred speech, and anorexia. To the best of our knowledge, th chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .1000 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong oxidizing agents, Strong acids, Strong bases, Heavy metals, Silver salts, Potassium. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Ammonia Hydrogen bromide gas REACTIVE PROPERTIES HANDLING: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION S: 24/25 22 Safety Statements: Avoid contact with skin and eyes. Do not breathe dust. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 35 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM BROMIDE CAS The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM CARBONATE A B C D CAS # 10361292 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 . . I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . 1 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 52/53 Risk Statements: Irritating to eyes, respiratory system and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM CARBONATE A B C D CAS # 506876 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 INHALATION RISK INDEX <1 - LC50 ROUTE OF EXPOSURE skin Contact: Causes skin irritation. . . 0 I J K L . Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . . . . skin Absorption: May be harmful if absorbed through the skin. Eye Contact: Causes eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: May be harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong acids. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Air sensitive. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: Xi Indication of Danger: Irritant. R: 36/37/38 52/53 Risk Statements: Irritating to eyes, respiratory system and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment S: 26 36 Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit .75 mg/m3 DOE Short Term Exposure Limit 2.5 mg/m3 DOE Ceiling Limit 15 mg/m3 Immediately Dangerous to Life and Health 75 mg/m3AMMONIUM CARBONATE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM CERIUM(IV) NITRATE A Special Carcinogen CAS # 16774213 E Dermal Hazard I Neurotoxin B C D Human Terato\Repro Haz Highly Toxic Inhalation Hazard F G H Corrosive Eye Damage STEL J K L Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . . . NFPA HAZARD CODES (H,F,R,O) 2 0 1 OX ACUTE TOXICTY RISK INDEX 2.4 - LD50 1720.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: May cause skin irritation. Eye Contact: Causes eye irritation. Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract. Ingestion: Harmful if swallowed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong reducing agents, Organic materials, Finely powdered metals. FIRE EXTINGUISHER: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam\. Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits t TOXIC EMISSIONS WHEN BURNED: SITION PRODUCTS HAZARDOUS POLYMER REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, STORAGE: Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame\. SPECIAL REQUIREMENTS Store under inert gas. Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU ADDITIONAL CLASSIFICATION Symbol of Danger: O Xi R: 8 36/37/38 Risk Statements: Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. S: 17 26 36 Safety Statements: Keep away from combustible material. In case seek medical advice. Wear suitable protective clothing. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 39.1 mg/m3 DOE Short Term Exposure Limit 117 mg/m3 DOE Ceiling Limit 200 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM CERIUM(IV) The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM CHLORIDE A B C D CAS # 12125029 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H Dermal Hazard Corrosive Eye Damage STEL I J K L Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers HAZARD INDEX . . . . . . . H . NFPA HAZARD CODES (H,F,R,O) 2 0 0 ACUTE TOXICTY RISK INDEX 2.5 - LD50 1650.0 mg/Kg INHALATION RISK INDEX <1 - LC50 . . . ROUTE OF EXPOSURE skin Contact: Causes skin irritation. skin Absorption: May be harmful if absorbed through the skin Eye Contact: Causes severe eye irritation. Inhalation: Material is irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. Ingestion: Harmful if swallowed. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid VAPOR PRESSURE .120 mm Hg @ 20 °C SEGREGATION: SHELF # 2 STORAGE GROUP(S): g - Non-Reactive/Non-Hazardous WASTE CHARACTERISTIC HAZARD: TOXIC INCOMPATIBILITIES:Strong oxidizing agents, Strong bases, Strong acids. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Hydrogen chloride gas Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe dust. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed\. SPECIAL REQUIREMENTS Hygroscopic. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION EU DIRECTIVES CLASSIFICATION Symbol of Danger: Xn Indication of Danger: Harmful. R: 22-36 Risk Statements: Harmful if swallowed. Irritating to eyes S: 22 Safety Statements: Do not breathe dust. US DEPARTMENT OF ENERGY TEEL'S DOE Occupational Exposure Limit 10 mg/m3 DOE Short Term Exposure Limit 20 mg/m3 DOE Ceiling Limit 500 mg/m3 Immediately Dangerous to Life and Health 500 mg/m3AMMONIUM CHLORIDE The information presented in the OPMSDS is intended as a synopsis of relative hazard characteristics for this chemical, for application within the UMass-Boston Chem/XL Laboratory Program. This information is derived from a wide range of sources documented in that program. While these sources are considered credible, the user is cautioned that the university cannot guarantee the accuracy nor accept responsibility for damages which may arise from errors, omissions, or the use of this information in any context other than intended. The user is strongly encouraged to seek additional information whenever feasible. AMMONIUM CHROMATE A B C D CAS # 7788989 Special Carcinogen Human Terato\Repro Haz Highly Toxic Inhalation Hazard E F G H HAZARDOUS CHEMICAL OF CONCERN Dermal Hazard Corrosive Eye Damage STEL HAZARD INDEX . . . . E NFPA HAZARD CODES (H,F,R,O) 0 0 INHALATION RISK INDEX <1 - LC50 . . 1 I J K L H Neurotoxin Suspect Carcinogen Suspect Terato\Repro Haz Sensitizers . J K L OX ROUTE OF EXPOSURE Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. TARGET ORGAN(S) OR SYSTEM(S) Lungs. Kidneys. SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. PHYSICAL CHARACTERISTICS PHYSICAL STATE: Solid Oxidizing Agent SEGREGATION: SHELF # 2 STORAGE GROUP(S): e - Oxidizer/Organic Peroxide WASTE CHARACTERISTIC HAZARD: INCOMPATIBILITIES:Strong acids, Organic materials, Finely powdered metals. FIRE EXTINGUISHER: Noncombustible. Use extinguishing media appropriate tosurrounding fire conditions. TOXIC EMISSIONS WHEN BURNED: Nitrogen oxides Ammonia REACTIVE PROPERTIES HANDLING: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. STORAGE: Keep tightly closed. Store in a cool dry place. Unsuitable: Do not store near, nor allow contact with, clothing and other combustible material. GLOBALLY HA