4.4 Percent Composition 3 Steps to Determining Chemical Formulas 1. ____________________________________________________ 2. Convert this information into an empirical formula 3. Find the true number of atoms/ elements in the compound (Molecular Formula) 1. Percent Composition • Compounds are ______________ composed of elements in ____________________. This is often referred to as the ________________________________________. • This law states that elements are always present in the ______________________________ in a compound. I.e. H2O is always 2H:1O any other proportions would not form water. H2O2 is hydrogen peroxide • Since compounds always form in fixed proportions, we can calculate the ______________________________________ of an element in a compound. % Composition = Problems 1. Calculatethe percentage composition of C3H7NO2 Step 1: Findthe molar mass of C3H7NO2 Step 2: Findthe % of eachelement by dividing the mass of eachelement by the total mass 2. What is the percentagecomposition of N2O? Step 1: Findthe molar mass of N2O Step 2: Findthe % of eachelement by dividing the mass of eachelement by the total mass CHEMICAL QUANTITIES CHEMISTRY 20 4.4 Percent Composition 3. Calculatethe mass of aluminum in 28g of aluminum oxide. Step 1: Findthe molar mass of aluminum oxide Step 2: Calculate the % mass of aluminum in aluminum oxide Step 3: Findthe mass of aluminum in28g of aluminum oxide Assignment 1. Calculate the percent composition of all of the elements in the following compounds: a. cupric bromide [Cu=28.45%, Br=71.55%] b. sodium hydroxide[Na = 57.5%, O= 40%, H= 2.5%] c. ammonium sulphide [N= 41.1%, H= 11.9%, S= 47%] d. dinitrogen disulphide[N=30.4%, S=69.6%] e. hydrobromic acid [H=1.2%, Br=98.8%] f. ammonium bromide [N=14.3%, H=4.1%, Br=81.6%] CHEMICAL QUANTITIES CHEMISTRY 20 4.4 Percent Composition 2. What is the percent composition in a sample that contains 4.5g of magnesium and 6.7g of sodium. [Mg=40.2%, Na=59.8%] 3. What is the percent composition in a sample that contains 25g of oxygen and 50g of hydrogen. [O=33.3%, H=66.7%] 4. What is the percentage of carbon in sucrose, C12H22O11? [42.1%] 5. What is the percentage of strontium in SrCl2? [55.3%] 6. How many grams of hydrogen can be obtained from 35mL of water? [3.92g] 7. How much iron can be obtained from 100.0g of Fe3O4? [72.4g] CHEMICAL QUANTITIES CHEMISTRY 20 4.4 Percent Composition 8. A piece of magnesium reacts with 16.0g of oxygen to form 40.3g of a compound. a. Calculate the % of magnesium in the compound. [60.3%] b. Calculate the mass of magnesium that would be present in 10,000g of the compound. [6.03 x 103g] 9. a. Calculate the % composition of iron(III) oxide. [69.94% Fe, 30.06% O] b. Calculate the mass of iron that could be obtained from 20,000g of this compound. [1.399 x 104g] 10. A sample of a compound (with K, Cl and O in it) was placed in a test tube and decomposed by heating into a residue and oxygen gas. From the given data, a. calculate the % of oxygen in the compound. [39.2%] 1. mass of empty test tube 2. mass of test tube and compound 3. mass of test tube and residue = 18.00g = 24.13g = 21.73g 11. Indigo, C16H10O2, is the common name of the dye that gives blue jeans their characteristic colour. Calculate the mass of oxygen in 25.0 g of indigo. [3.42 g] 12. Potassium perchlorate, KClO4, is used extensively in explosives. Calculate the mass of oxygen in a 24.5 g sample of potassium chlorate. [11.3g] CHEMICAL QUANTITIES CHEMISTRY 20