ENGR0011 Gorr Group R03 Hydraulic Fracturing: Friend or Foe Dylan Stow (dfs14@pitt.edu) INTRODUCTION Thirty to forty percent of the shale gas resources in the United States are found in Marcellus Shale. Most of which is located in the North East [1]. Experts currently debate the effectiveness of hydraulic fracturing as a method of extracting these shale gas resources. In the 1990’s, with the ability to use directional drilling, enabling a drill bit to be turned ninety degrees and drill horizontally, extracting shale gas became the means to solve the fossil fuel crisis [1]. At the origins of fracturing, drillers used explosive measures. Now these drillers use slick water fracturing, which is the process of pumping massive amounts of water infused with certain chemicals to extract the natural gas from the shale. Such items pumped down the well include proppants, sand and other chemical additives. Pressure is then reduced and most of the water, called “flowback,” travels to the surface [1]. Many chemicals are found in flowback, leading experts to debate on what to do with the massive amounts of chemically infused water. Wells all contain laterals, connecters between two horizontal well bores. Each lateral needs two to four million gallons of water and 15,000 to 60,000 gallons of chemicals in order for it to be effective. By multiplying these quantities by the number of wells at one site, one may calculate how much is really being used to fracture the Marcellus shale. To store the flowback it takes fleets of tankers and large storage containers [2]. Flowback fluid that returns to the surface contains down-hole constituents that include dissolved sands, hydrocarbons, and toxic heavy metals. Untreated flowback cannot be reused in the hydraulic fracturing process because of high concentrations of Barium and Strontium [3]. Flowback is stored on site in ponds and large tanks before being treated. Some states require this flowback to be stored in a pit lined with synthetic material [2]. Hydraulic Fracturing shows both benefits and dangers to society. Experts in the gas industry state that the natural gas found in Marcellus shale will sustain the United States for at least two decades; however, if the gas gets into an aquifer, it will contaminate fresh drinking water. The current process of hydraulic fracturing illustrates many dangers to society. The process needs adjustments to make the gas industry profit and the citizens of the United States safe. Hydraulic Fracturing poses an ongoing ethical debate. Should we, society, corrupt our environment to attain more fossil fuel, or should we stop the fracturing process altogether which will lead us to an energy crisis? These question roots the continuing debate. Engineers debate the topic of hydraulic fracturing every day. As stated in the National Society for Professional Engineers (NSPE) code of ethics, “Engineers, in the fulfillment of the professional University of Pittsburgh, Swanson School of Engineering 1 October 30, 2012 duties, shall hold paramount the safety, health, and welfare to the public [4].” The question begging to be answered should be how to promote the welfare, safety, and health of the public with hydraulic fracturing. Educating new engineering students in current problems in the world shows a high level of importance to the rest of society. If freshman engineering students do not learn the problems of the world, then how will they fix the problems without the basic knowledge? It is good for freshman engineers to not only learn about current problems the world is facing, but also to learn how to write properly in a professional setting. Coming out of college with the skills to write, interview, learn, and understand are important in the work force. BENEFITS Under the current system, hydraulic fracturing produces only few benefits. For example, shale gas emits lower carbon dioxide levels than oil [1]. This will reduce the affects of global warming on the planet. Experts predict that Marcellus shale contains enough removable gas to fuel the Untied States for twenty years. Hydraulic fracturing is one of the best options for creating domestic economic growth and reducing America’s dependence on foreign energy [3]. Under the current system, the cost of producing shale gas outweighs the benefit from producing the shale gas. COSTS Hydraulic Fracturing could be a serious potential threat to the environment and human health. The Environmental Conservation Department of New York State found several categories of hydraulic chemicals with harmful affects to human health, some of which include, petroleum distillates, aromatic hydrocarbons, aldehydes, amides, and surfactants [1]. If any of these chemicals get into the water table, it could potentially be life threatening to the citizens of the United States. Many other chemicals are used during this process as well. Methanol was the most widely used chemical between 2005 and 2009. It classifies as a hazardous air pollutant and is a candidate for regulation under the Safe Drinking Water Act (SDWA) [5]. Members of the House of Representatives report that twenty-nine different chemicals in hydraulic fracturing fluid are known possible human carcinogens and are classified as hazardous air pollutants under the clean air act [1]. People should show concern for the proper treatment of these hazardous chemicals that include benzene, toluene, xylene, and ethyl benzene. Under the SDWA, they are classified as hazardous air pollutants [5]. The health risks Dylan Stow outweigh the benefit of natural gas. Some hydraulic fracturing fluids contain chemicals named “proprietary” or “trade secrets.” In most cases, companies themselves have trouble identifying what chemicals they pump into the ground [5]. If the companies cannot identify what is going into the ground, they show no respect to the general welfare of the people. Many cases show how failure to follow the right procedure leads to problems. In Pennsylvania, regulators confirm that methane migrates into water wells from drilling sites [5]. If the flowback is not stored properly, it could seep through the ground and contaminate many water wells [5]. If the right storage procedure happened from the beginning, the wells would not have become contaminated. After the hydraulic fracturing process completes, the vertical pipe should be cemented shut to stop the threat of potential leakage. The most suspected source of possible contamination is faulty cementation of the vertical pipe. Another potentially bad occurrence is casing failure. If the case fails, then the chemical infused flowback, which is at high pressure, could leak out. Yet another source of contamination could potentially be from pre-existing fissures in the well connecting to the fissures being created [2]. The potential for disaster is greater than the overall gains. Many government agencies use their authorities to conduct research and gather data. The Environmental Protection Agency (EPA), under the Comprehensive Environmental Response, Cleanup and Liability Act (CERCLA), measured the quantity and quality of water from wells near a gas development. The EPA found several wells contained a compound used in hydraulic fracturing [5]. Under the current process of hydraulic fracturing, health risks for both humans and the environment continue to grow, proving that the costs out weigh the benefits. ETHICS Hydraulic fracturing raises an ethical argument among engineers. The process of hydraulic fracturing produces few benefits and many costs for society. As stated in the American Institute of Chemical Engineers (AIChE) code of ethics, “Members of the American Institute of Chemical Engineers shall uphold and advance the integrity, honor and dignity of the engineering profession by using their knowledge and skill for the enhancement of human welfare. [7]” One could argue that hydraulic fracturing breaches this ethical code. Engineers who are involved in the hydraulic fracturing process know about the adverse affects the process brings. Many of the chemicals involved in the fracturing process are known cancer-causing substances. At any point in time, these chemicals can travel through cement casings in the wells and contaminate aquifers. Knowing these dangers and going forward with the fracturing process breaches the AIChE code of ethics. The NSPE code of ethics also states that engineers need to hold above everything else the safety, health, and welfare University of Pittsburgh, Swanson School of Engineering 2 October 30, 2012 of the public [4]. The process of hydraulic fracturing especially breaks this ethical code. In order to extract the gas from the ground, many companies use chemicals that are classified as hazardous air pollutants. If people come into contact with these pollutants, their safety is jeopardized. Although the welfare of the people would be improved by attaining the natural gas to sustain the United States for two decades, the possibility of the loss of fresh water aquifers dwarfs sustainability. Both fossil fuels and fresh water are limited resources. In order to live, people need to have fresh drinking water; however, fossil fuels are not a necessity. Therefore, hydraulic fracturing could be a violation in the NSPE code of ethics. EDUCATION Educating freshman engineering students on the current problems in today’s world is important. Research, like this paper, is key to the development of learning how to analyze and interpret information. Tingting Liu and Haibin Sun interpret the concept of constructivism for students, including engineering students, to attain information literacy. Their argument states that students positively construct knowledge based on existing concepts. Teachers, society, and other outside sources all contribute to the student’s gain of knowledge [8]. We, as engineers, can use the knowledge from the outside sources to interpret what is best for mankind. For future freshman engineering students, this paper shows vital importance to learning about the current world problems. Being exposed to these problems at the start of one’s career allows for one to become more enthralled in a certain topic. This research paper allows one to find a focus on which type of engineering one wants to major in the future. If one is not excited about what he learned, then he is in the wrong major. This paper allows freshman engineers to dive head first into the problems of the world and begin to allow them to think of possible solutions. POSSIBLE SOLUTIONS / CONCLUSION Hope for the future motivates. Companies challenge themselves to find an approach for water treatment that will contribute to the long-term sustainability of natural gas development in the Marcellus shale [3]. Treating the flowback is one of the many concerns that many people have. Another alternative could be the use of greener chemicals. Halliburton markets a CleanStim fracturing fluid formation for onshore hydraulic fracturing. CleanStim is made from ingredients sourced from the food industry. Dow Chemical also markets environmentally friendly fracturing surfactants [1]. Surfactants are the chemicals that break fissure the shale to allow the gas to escape into the well. If they are green, there would be no need to treat the flowback. Even with these new innovations, drawbacks still occur. One Dylan Stow drawback being that some green fracturing fluids cannot be used in earth with high clay content [1]. The state governments continue to find a compromise between the companies and the people. New York State Environmental Conservation Department proposes that applicants for shale gas permits use as many alternative chemicals as possible to reduce the environmental risk [1]. By using alternatives, permit holders will be able to earn a profit off of the gas, while allowing the people to continue to consume fresh drinking water. Using less water could be another alternative. Liquid carbon dioxide vaporizes, and nitrogen gas mingles with shale gas, leaving only proppant in the fractures [1]. Companies face the challenge of treating massive amounts of flowback. Many are trying to reduce that by engineering a way to treat the flowback and reuse it in the fracturing process again. Krof Well Servies Inc. and Superior Well Servies Inc. collaborated to engineer a method to reuse flowback water in the process [3]. This technique addresses two problems with the fracturing process, the need for consumption of fresh water and the disposal of flowback. When water is reused, no fresh water is used in the fracturing process. If the water is treated after the fracturing process is over, the contaminants will not be in an aquifer. When the product was put on production, selected wells were projected to produce at higher rates than that of traditional wells using fresh water for the fracturing process [3]. Under the current system, hydraulic fracturing could not work. The health risks are more numerous than the benefit of being able to fuel the United States for two decades. The use of toxic chemicals should be outlawed to protect the rights of the people. Greener chemicals should be used to reduce the environmental impact. Ethics play a key role in the profession of engineering. It is the duty of engineers to keep the health, welfare, and safety of the public at the highest priority. The current process of hydraulic fracturing shows a potential danger to the health and safety of the public. If certain hazardous chemicals seep into fresh water aquifers and become contaminated, the public loses drinking water that is necessary for life. It is the duty of engineers to find a better way to reduce the hazards of hydraulic fracturing and keep the welfare of the people above everything else. The engineering code of ethics also states that engineers have to strive to increase proficiency and reputation in the profession of engineering. This means that education is an important role in the engineering community. In order to stay sharp in the engineering field and to protect the welfare of the public, engineers must be current in their thought University of Pittsburgh, Swanson School of Engineering 3 October 30, 2012 process. This research paper shows importance in a freshman level college class by making freshman engineering students practice this vital code right from the beginning. It also prepares students, at a beginner level, to look at current issues in depth. Learning more about controversial topics, like hydraulic fracturing, allows freshman engineering students to formulate the best possible outcomes for the future of the profession. Having a research paper in the freshman curriculum also allows new engineering students to re-evaluate why they want to become an engineer. If research into current engineering problems does not interest the student, then the engineering profession is probably not for them. REFERENCES [1] P. Heyword. (2012). “Fracking Safer and Greener.” TCE: The Chemical Engineer. (Online article). Issue 850, pp 42-45 [2] C. Mooney. (November 2011). “The Truth About Fracking.” Scientific American. (Online Article). Vol. 305 Issue 5, pp 80-85 [3] D. Grottenthaler. (2011). “Recycling Water for Hydraulic Fracturing.” Mechanical Engineering. (Online article) Vol. 133 Issue 12, pp 21-24 [4]NSPE code of ethics. http://www.nspe.org/Ethics/CodeofEthics/index.html [5] B. Knickerbocker. (2011, April 17). “New Warning of Poisonous Chemicals in Natural Gas ‘Hydrofracking’.” Christian Science Monitor. (Online Article). p 1 [6] (2012). “Hydraulic Fracturing Overview: Growth of the Process and Safe Drinking Water Concerns.” Congressional Digest. (Online article). Vol. 93 Issue 3, pp 71-75 [7]AIChE code of ethics. http://www.aiche.org/about/codeethics [8]H. Sun and T. Liu. (October 2011). “Analysis of Information Literacy Education Strategies for College Students Majoring in Science and Engineering.” Modern Applied Science. (Online article). Vol. 5 Issue 5, p227-231 ACKNOWLEDGMENTS I would like to thank Carissa Vyhonsky for proof reading my paper. I would also like to thank Amanda (Mandy) Kelly for being a there for me while writing my paper. Many thanks go out to Professor Heather Gorr for being the best Engineering Analysis professor at the University of Pittsburgh.