Keswick School Chemistry Department Summer A-level preparation work Exercise 1: Consolidating GCSE understanding Fully re-familiarise yourself with the following topics from GCSE which will be rapidly built upon during the first AS units: From C1: Metal extraction Crude oil Atomic structure From C2: Structure, bonding and properties Moles and calculations Reversible reactions Redox reactions From C3: The Periodic Table Energy changes Titrations Organic chemistry Exercise 2: Memorising common formulae You must memorise the formulae of the common ions shown below and the formulae of the other common substances. It is helpful to relate the charge on an ion to the position of the element in the Periodic Table. You will be expected to know the common ions throughout the course. Positive ions: Hydrogen Lithium Sodium Potassium Silver Ammonium Magnesium Calcium Barium Iron (II) Copper (II) Zinc Lead HCl Aluminium HNO3 Iron (III) H2SO4 + H Li+ Na+ K+ Ag+ NH4+ Mg2+ Ca2+ Ba2+ Fe2+ Cu2+ Zn2+ Pb2+ Negative ions: Fluoride FChloride ClBromide BrIodide IHydroxide OHNitrate NO3Oxide O2Sulphide S2Sulphate SO42Carbonate CO32Common substances: Hydrochloric acid Al3+ Nitric acid Fe3+ Sulphuric acid Ammonia NH3 Exercise 3: Determining formulae Use the information from exercise 1 to deduce the formula of the substance given below: 1. Silver bromide ..................... 7. Ammonium sulphide........................ 2. Sodium oxide....................... 8. Aluminium nitrate........................ 3. Lead (II) oxide............................. 9. Ammonia..................................... 4. Iron (III) sulphide........................ 10. Hydrochloric acid.................... 5. Zinc carbonate............................ 11. Sulfuric (VI) acid...................... 6. Calcium hydroxide...................... 12. Nitric acid................................ Exercise 4: Balancing equations Symbol equations require balancing so that the stoichiometry is correct i.e. there are the same number of each type of atom on both sides of the equation. Balance the following equations: S 1. Li + 2. SO2 + O2 SO3 3. Na + O2 Na2O 4. N2 + H2 ⇌ NH3 5. P+ Cl2 PCl5 6. Fe + 7. C2H6 + 8. NH3 + H2O O2 O2 Li2S Fe3O4 + H2 CO2 + H2O NO + H2O Exercise 5: Forming symbol equations At A-level, only symbol equations are used. Apply what you have covered in exercises 2, 3 and 4 to form balanced symbol equations for each of the following: 1. Calcium hydroxide reacts with carbon dioxide to form calcium carbonate and water 2. Titanium reacts with chlorine to form titanium chloride 3. Magnesium reacts with hydrochloric acid to form magnesium chloride and hydrogen 4. Chorine reacts with potassium bromide solution to form potassium chloride and bromine 5. Iron (II) oxide reacts with carbon monoxide to form iron and carbon dioxide 6. Carbon monoxide and nitrogen monoxide react to form carbon dioxide and nitrogen 7. Ammonia and hydrochloric acid react to form ammonium chloride 8. Methane and steam react to form carbon monoxide and hydrogen 9. Sulphuric acid reacts with hydrogen bromide to form bromine, water and sulphur dioxide 10. Sulphur dioxide reacts with hydrogen iodide to form iodine, water and hydrogen sulphide Exercise 6: Presenting numbers There are a number of considerations when presenting a numerical answer at Alevel. Convert the following as described: Significant figures: Represent the following numbers to the stated number of significant figures: 0.07894 (3 sig fig)...................... 345789 (4 sig fig) ..................... 6 (3 sig fig) ....................... 8.174 (2 sig fig)……………….. 7.994 (2 sig fig) 0.01 (4 sig fig) ........................ Decimal places: Represent the following numbers to the stated number of decimal places: 78.544 (2 dp).......................... 0.00747 (2 dp)………………… 1.305 (2 dp)............................. 6.44357 (3 dp)................... 3.071 (1 dp)………………. 4.45 (1 dp)......................... Standard form: Represent the following numbers in standard form: 0.000167........................ 0.1………………………. 0.0524............................ 34500.................... 98…………………. 87000000...................... Decimal form: Represent the following numbers in decimal form: 1.5 x 10-3 ...................... 1 x 10-1.............................. 4.6 x 10-2.................... 5.34 x 104....................... 1x101……………….. 1.3 x 105........................... Converting units: Convert the following quantities as described: 15g into kg..................... 5. 3.8kPa into Pa.................... 15cm3 into dm3.................. 6. 25oC into K.......................... 25cm3 into m3.................... 7. 260K into oC....................... 101300Pa into atm............ 8. 3.3ml into cm3.................... Exercise 7: Practical work and risk assessing As part of the practical element to your course, you must be able to research practical techniques. Before any practical work takes place, you will be expected to do some prepractical research and to familiarise yourself with what to expect and how to ensure the safety of yourself and others. The first two practical’s you will do next year are: 1. Making up a standard solution of potassium hydrogen phthalate(KHP) 2. Determining the concentration of sodium hydroxide by titrating with KHP solution using phenolphthalein as an indicator You should arrive in September with an idea of how to conduct these investigations and a clear knowledge of risk assessing both. Good luck and we look forward to seeing you in September.