Supplementary Information Optoelectric Patterning: effect of electrode material and thickness on laser-induced AC electrothermal flow A. Mishra,a J.-W. Khora , K. Claytona, S. J. Williamsb, X. Panc, T. Kinzer-Ursemd and S. Wereleya a Birck Nanotechnology Center, School of Mechanical Engineering, Purdue University, West Lafayette, IN, USA 47907. b Department of Mechanical Engineering, University of Louisville, KY, USA. c School of Mechatronics Engineering, Harbin Institute of Technology, China. d Weldon School of Biomedical Engineering, Purdue University, West Lafayette, IN, USA 47907. Figure S1: Experimental and simulated velocity profile produced by an 80 nm Ni layer with a 39.6 mW laser beam and 8 Vpp AC signal. The velocity profile was measured at a height of 190 µm from the bottom electrode. Figure S2: Effect of laser power on velocity magnitude at different positions along z axis. Solid lines are the linear fits to the corresponding data points. Velocity magnitude of the electrothermal flow linearly increases as laser power is increased. For simulating the electrothermal flow, 25 nm Ti films were selected as electrodes and an AC signal of 8 Vpp was selected. Figure S3: Electrothermal velocity profile produced by laser induced heating of the 700 nm ITO film at different positions along z axis. Laser power was kept at 1 mW, and an AC signal of 8 Vpp was applied between electrodes. Figure S4: Electrothermal velocity profile produced by laser induced heating of the 12 nm Ni film at different positions along z axis. Laser power was kept at 1 mW, and an AC signal of 8 Vpp was applied between electrodes. Figure S5: Electrothermal velocity profile produced by laser induced heating of the 25 nm Ti film at different positions along z axis. Laser power was kept at 1 mW, and an AC signal of 8 Vpp was applied between electrodes. Table 1: Optical and thermal parameters of materials Thermal Absorption Reflectance Reflectance Conductivity Coefficient (electrode- (electrode- (W/m/K) (m-1) air) water) 0.09348 0.03369 0.08124 0.02638 0.1335 0.05696 0.39 - 0.2196 - 0.4384 0.3378 Thickness Material (nm) ITO 70 3.21 ITO 350 5.9 ITO 700 10.22 Au 6.4 61.93 Ni 5.0 30.04 Ni 12.0 50.24 1.181×105 8.226×107 6.900×107 Ni 20.0 59.54 0.5863 - Ni 50.0 72.04 0.7617 - Ti 25.0 11.62,5 4.734×107 0.4877 0.3851 Pt 15.0 206 7.042×107 0.5227 - Table 2: Properties of the solution Property Value Relative Permittivity 80 Electrical Conductivity (mS/m) 8.8 Thermal Conductivity (W/m·K) 0.59 Density (kg/m3) 999.65 Dynamic Viscosity (N·s/m2) 0.001 References 1 T. Yagi, K. Tamano, Y. Sato, N. Taketoshi, T. Baba and Y. Shigesato, J. Vac. Sci. Technol. A Vacuum, Surfaces, Film., 2005, 23, 1180. 2 D. Thuau, I. Koymen and R. Cheung, Microelectron. Eng., 2011, 88, 2408–2412. 3 H. Lin, S. Xu, C. Li, H. Dong and X. Wang, Nanoscale, 2013, 5, 4652–6. 4 S. P. Yuan and P. X. Jiang, Int. J. Thermophys., 2006, 27, 581–595. 5 C. A. Paddock and G. L. Eesley, J. Appl. Phys., 1986, 60, 285. 6 Q. G. Zhang, B. Y. Cao, X. Zhang, M. Fujii and K. Takahashi, J. Phys. Condens. Matter, 2006, 18, 7937–7950.