Hazardous Materials
Management Plan
Be Safe!
Everyone must follow established hazardous materials policies and procedures to ensure the
safety of individuals and the campus environment.
Questions and Requests for Additional
Information Should be Directed to:
Environmental Health & Safety
3801 W. Temple Avenue, Pomona, CA 91768
Phone: (909) 869-4697
Fax: (909) 869-4698
Web: http://www.cpp.edu/ehs
(File: http://www.cpp.edu/~ehs/files/environmental/HazMatMgmtPlan.docx)
(Revised 06/19/2014)
Table of Contents
Section and Title
1.0
Reference
Page
4
2.0
Introduction
4
2.1
University Program
4
3.0
Scope and Policy
4
3.1
Scope
4
3.2
Policy
4
4.0
Compliance
5
5.0
Responsibilities.
5
5.1
Campus Environmental Health & Safety (EH&S) Department
5
5.2
Deans, Directors, Department Chairs and Department Heads
6
5.3
University Development Department
6
6.0
Identification of Chemicals and Hazards
6
7.0
Select Agents and Toxins
7
8.0
Inventory Reporting for the Hazardous Materials Business Plan
7
9.0
Methods of Isolation, Separation, Containment, Engineering and Administrative Control
8
10.0
Hazardous Waste Management
9
11.0
Emergency Response Plans
10
12.0
Incident Response Plan
11
13.0
Training
20
14.0
Safety Concern Reporting
21
APPENDIX A - Table I: Building and Fire Code Limits for Hazardous Materials
23
Page 3
1.0
Reference
Chapter 6.95 (Section 25500 et. seq.) California Health & Safety Code; Section 6300 et. seq. California
Labor Code; Section 117600 California Health & Safety Code; Division 1 Chapter 3.2 Title 8 California
Code of Regulations; Division 2, Chapter 4 (Section 2620 et. seq.) Title 19 California Code of
Regulations; Section 30100 et. seq. Title 17 California Code of Regulations; Section 66260.1 Title 22
California Code of Regulations
2.0
Introduction
The University’s Environmental Health & Safety (EH&S) Department has developed this plan to identify
methods of protecting individuals and the environment from the use and storage of hazardous material
(chemical, infectious or radioactive materials) in teaching, research and development laboratories at the
University.
2.1
University Program
The use of relatively small amounts and large varieties of hazardous material is necessary in carrying
out a university program. Most science related departments and maintenance programs use hazardous
materials in varying amounts. Storing excessive amounts of unneeded hazardous material including
flammable solvents can create fire, explosive and other hazards.
3.0
Scope and Policy
3.1
Scope
All requirements of the Hazardous Materials Management Program will apply to the management of
Hazardous Materials. Hazardous Materials are defined as any substance or mixture of substances
which is infectious, radioactive, toxic, corrosive, flammable, reactive, an irritant, a strong sensitizer or
which generates pressure through decomposition, heat, or other means, if such a substance or mixture
of substances may cause substantial injury, serious illness or harm to humans, domestic livestock or
wildlife.
3.2
Policy
It is the policy of California State Polytechnic University, Pomona, to maintain, insofar as it is
reasonably within the control of the University to do so, a campus environment for students, faculty,
staff and visitors that will not adversely affect their health and safety nor subject them to avoidable risks
of accidental injury. No individual or employee shall be required to perform any task, which is
determined to be unsafe or unreasonably hazardous. Furthermore, the University shall ensure that all
operational activities are carried out in compliance with existing environmental laws, rules, regulations,
and campus policies, in order to protect the environment. While the overall responsibility for campus
environmental protection, health and safety belongs to the University, the primary responsibility lies with
each manager at the department level, under the broad direction of each vice president. Everyone has
a personal responsibility for prevention of campus accidents and environmental protection. Accordingly,
all faculty and staff are to ensure that safe and healthful conditions and practices are provided and
followed in their areas of control, and all members of the campus community are to cooperate fully with
all aspects of the University Environmental Health and Safety program.
In keeping with this policy, managers and supervisors are responsible and will be held accountable for
compliance with environmental, health and safety legal requirements, including the payment of any
fines for non-compliance.
Given the fact that fines may seriously impact a department’s annual
operating budget, vice presidents should implement contingency plans to provide for this possible
expense and establish procedures to provide priority to budget requests for compliance issues.
Page 4
Specifically in managing hazardous materials, it is the policy of the university to:
a. Manage hazardous material to adequately protect individuals and the environment.
b. Manage hazardous material on campus in compliance with applicable federal, state, and local
regulations.
c. Manage in a manner that minimizes short and long term liability associated with hazardous
material.
4.0
Compliance
Each Manager is responsible for conducting periodic inspections to maintain compliance. Additionally,
Environmental Health and Safety is tasked with conducting hazardous materials and hazardous waste
inspections which includes assessments of identification, labeling, storage, handling as well as safety
equipment. Additionally, records for training, procedures, Department Safety Coordinator Inspections,
SDS’s (MSDS’s) and chemical inventory are reviewed as well. Additional information on how this
inspection program will be managed can be found in the Hazardous Materials & Hazardous Waste
Inspection Program.
5.0
Responsibilities.
The campus President has ultimate responsibility for establishing and maintaining effective policies
regarding health and safety within the institution.
The activities and responsibilities of the
Environmental Health and Safety Programs are thereby established under the final authority of the
President. Departmental managers are responsible for the implementation of Environmental Health
and Safety Programs and shall provide continuing support.
5.1
Campus Environmental Health & Safety (EH&S) Department
It is the responsibility of EH&S to develop and maintain this plan and to monitor compliance. Further
responsibilities are outlined below:
a. Provide consultation to administrative personnel, Deans, Directors, Department Chairs,
Department Heads and Safety Coordinators regarding program compliance. Consult and advise
on issues of: hazard identification and evaluation; correction of unsafe conditions; determining and
implementing control measures; employee information and training programs; and employee
medical monitoring
b. Provide centralized monitoring of campus-wide hazardous materials safety activities on a
consultative basis.
c. Maintain centralized copies of records and program documentation.
d. Maintain current information on legal requirements concerning regulated substances.
e. Seek ways to improve this plan.
f. Verify that appropriate audits are conducted. Review and evaluate the effectiveness of the plan
and update if necessary.
g. Provides liaison with off-campus regulatory agencies
Page 5
5.2
Deans, Directors, Department Chairs and Department Heads
It is the responsibility of Deans, Directors, Department Chairs, and Department Heads to develop
departmental procedures to ensure effective compliance with this plan and other university health and
safety policies as they relate to operations within their departments. Specifically, these individuals will:
a. Identify all area were hazardous materials are used in the department.
b. Identify the Leads, Principal Investigators or Course Instructors who are responsible for each area.
c. Ensure that Leads, Principle Investigators, Course Instructors, Technicians and other individuals
have received and completed the required training applicable to this program.
d. Review the departmental program quarterly, including:
 inspection checklists;
 accident reports;
 training records;
 fiscal prioritization.
e. Provide an avenue for fiscal requests.
f. Ensure that all chemical inventory procedures are followed.
g. Ensure that Material Safety Data Sheets (MSDSs) or Safety Data Sheets (SDSs) are readily
available to individuals.
h. Assist Leads, Principle Investigators or Course Instructors in identifying hazardous materials
hazards in areas or other locations under their control where hazardous materials are stored or
handled.
i. Maintain related records.
j. Review and understand all applicable referenced materials and documents in this plan.
5.3
University Development Department
a. Obtains approval for all hazardous material donations through the EH&S Department.
b. Submits to the EH&S Department the name, address, phone number and contact person of the
donating company along with a complete listing of the donated materials including the amount,
condition, potential use and hazards, and any special handling requirements of each specific
material.
c. Insures that the recipient of the hazardous materials has provided storage space to safely and
securely store the materials. Only material that can be used within a reasonable and legal period of
time will be accepted.
d. More Information regarding the procedure for hazardous materials donations can be found in the
University Hazard Communication Manual which is available on the EH&S Web Site at
http://www.cpp.edu/~ehs/files/occupational/doc/HazcomManual.doc.
6.0
Identification of Chemicals and Hazards
All employees shall comply with the University Hazard Communication Program
(http://www.cpp.edu/~ehs/files/occupational/doc/HazcomManual.doc), which is incorporated by
reference. Specifically, the Instructor and/or PI shall:
a. Ensure that all requirements of the Hazard Communication Program have been met before
individuals are exposed to hazardous chemicals under normal conditions of use or in a foreseeable
emergency.
b. When ordering any suspected hazardous chemicals through Procurement, Foundation Financial
Services or other sources, Leads, Instructors and/or Principle Investigators will make a request to
the vendor for an SDS (Safety Data Sheet) or MSDS (Material Safety Data Sheet) if one is not
currently present in the area.
Page 6
c. Develop and maintain an inventory of hazardous chemicals present in the area and maintain a
current file of MSDSs or SDSs for each hazardous chemical. Provide copies of the SDSs and/or
MSDSs and the inventory to the EH&S Department. Leads, Instructors and/or Principle
Investigators will report any increases of hazardous chemicals, that are reportable under the
Hazardous Materials Business Plan, to Environmental Health & Safety (EH&S) on a monthly basis
(see Section 8.0). Instructors and/or Principle Investigator/Leads will conduct an annual hazardous
chemicals inventory review and verify that they have an SDS and/or MSDS for each hazardous
chemical. Leads, Instructors and/or Principle Investigator/Leads will be required to obtain copies of
any SDS and/or MSDS that they do not have on file from the vendor or EH&S.
d. Post in a conspicuous location for all workers the HAZARD COMMUNICATION NOTICE, available
on
the
Environmental
Health
&
Safety
Web
Site
at
http://www.cpp.edu/~ehs/files/occupational/doc/HazcomPoster.doc.
e. Develop methods to inform individuals of the hazards of non-routine tasks.
f. Develop methods, as appropriate, to inform outside contractors’ employees and other individuals
who may occasionally work in your room or area of the hazardous chemicals to which they may be
exposed.
g. The posting of a completed Laboratory/Room Warning Sign, available on the Environmental Health
& Safety Web Site at http://www.cpp.edu/~ehs/files/chemical/LabSign.doc, on or near the entry door
to the room or area will be considered as substantial compliance with this section, provided the
Principle Investigator/Lead responds to any questions that may be asked and the sign includes
appropriate information. The appropriate information is the completed NFPA diamond, information
about the general hazards in the room or area (Radiation, Infectious Agents, and/or Chemicals),
personnel protective equipment required Principle Investigator/Lead’s name and campus extension.
h. Ensure that all containers of hazardous chemicals in the workplace are labeled, tagged or marked
with the Identity of the hazardous substance(s), appropriate hazard warnings, and name of the
manufacturer.
i. Labels on all containers of hazardous chemicals shall be maintained. Do not remove or deface
existing labels on incoming containers of hazardous substances unless the container is immediately
marked with the required information
j. All individuals will ensure that the quantities of hazardous chemicals they have in each location do
not exceed the quantities listed on the Department of Homeland Security Appendix A Reportable
Quantity
List
(available
on
the
EH&S
Web
Page
at:
http://www.cpp.edu/~ehs/files/chemcial/ChemicalFacilityDHSAppendixA.xls).
7.0
Select Agents and Toxins
These agents and/or toxins are heavily regulated by the Center for Disease Control (CDC) and Animal
& Plant Health Inspection Service (APHIS). Failure to comply with the laws governing the use of these
agents and/or toxins can result in incarceration, fines and even the death penalty. Use of these agents
is discouraged and prohibited without prior approval of EH&S. A list of these agents is available on the
EH&S Web Site at http://www.cpp.edu/~ehs/files/biosafety/SelectAgentsList.doc.
8.0
Inventory Reporting for the Hazardous Materials Business Plan
Any department using more than 55 Gallons, 200 Cubic Feet of gas at standard temperature and
pressure, 500 Pounds and/or any amount larger than the limits presented on the ‘Extremely Hazardous
List’ for Fire Department (see EH&S Web Page at:
http://www.cpp.edu/~ehs/files/chemical/ExtremelyHazardousChemicalListLAFireDepartment.xlsx). If
the listed amounts are exceeded, the department shall submit Inventory Information on these
hazardous materials to EH&S Department every 30 days. Additionally, Departments are required to
maintain an inventory of all hazardous chemicals present regardless of quantity for all areas (see
Section 6.0 c.).
Page 7
9.0
Methods of Isolation, Separation, Containment, Engineering and Administrative Control
a. The Lead, Instructor and/or PI will provide sufficient storage space to safely and securely store the
hazardous materials.
b. Only quantities of hazardous materials that can be used within a reasonable and legal period of
time will be stored. The quantities of hazardous materials stored or used in a room should not
exceed the limits contained in the Uniform Building and Fire Codes (see Table I in Appendix A).
c. Potentially unstable chemicals having a specific shelf life will be removed for proper disposal prior
to the expiration of the shelf life.
d. Containers of flammable and combustible substances will be stored in Fire Marshal approved
flammable storage cabinets, except when in use.
e. The use of volatile hazardous material that present an exposure risk to individuals will be utilized in
a chemical fume hood, biosafety cabinet or other appropriate control device.
 Departments will ensure that Chemical Laboratory Fume Hoods are calibrated when installed
and annually thereafter. The calibration will be documented on a tag on the hood (EH&S can
provide training, the loan of a calibrated meter, calibration tags, and forms.). Hoods will provide
an average face velocity of at least 100 feet per minute with a minimum of 70 fpm at any point.
Hoods shall be equipped with a quantitative airflow monitor that continuously indicates whether
air is flowing into the exhaust system during operation. Hoods and benches will be clear of
hazardous materials, unless being actively used. Hoods shall comply with Section 5154.1, Title
8 California Code of Regulations.
 Departments shall ensure that Biosafety Cabinets are tested after installation, alterations, or
maintenance, and at least annually. The calibration will be documented on a tag on the
Biosafety Cabinet. Biosafety Cabinets will be clear of hazardous materials, unless being
actively used. Biosafety Cabinets will comply with Section 5154.2, Title 8 California Code of
Regulations.
f. The Lead, Instructor and/or PI will comply with the more detailed procedures for the isolation,
separation and containment of hazardous material found in the following University Hazardous
Substance Management Plans, which are incorporated in this plan by reference:
 Biosafety Portal (http://www.cpp.edu/~ehs/portals/biosafety/index.shtml)
 Bloodborne Pathogen Program Manual (http://www.cpp.edu/~ehs/files/biosafety/blood.doc)
 CDC’s Biosafety in Microbiological and Biomedical Laboratories 5th Edition
(http://www.cdc.gov/od/ohs/biosfty/bmbl5/bmbl5toc.htm).
 Chemical Safety Plan for Laboratories (http://www.cpp.edu/~ehs/files/chemical/CSPLSOP.doc)
 Hazardous Waste Manual (http://www.cpp.edu/~ehs/files/environmental/HazWasteManual.doc)
 Medical Waste Disposal Manual (http://www.cpp.edu/~ehs/files/biosafety/medwst.doc)
 Radiation Safety Manual (http://www.cpp.edu/~ehs/files/radiation/RadiationManual.doc)
g. The Lead, Instructor and/or PI will conduct the periodic inspections in the above listed Hazardous
Substance Management Plans, as applicable. The frequency of inspections varies from daily to
quarterly. Copies or summaries of these inspections will be submitted to the EH&S Department.
h. All Leads, Instructors and Instructors and/or Principle Investigators (PIs) shall comply with the
Standard Operating Procedures and Safe Work Practices for Laboratory Safety (see
http://www.cpp.edu/~ehs/files/chemical/ChemicalLabSafetySOPs.docx on the EH&S Web Page) or
other appropriate safe practices established in the above plans (see Section 9.0i.). Please refer to
the link above for detailed information on Definition and Characteristics, Potential Hazards, Storage
and Handling, Personal Protection Equipment, Common examples, and the First Aid Response.
Page 8
i.
10.0
Proper Storage of Hazardous Materials
 Hazardous materials shall be stored in containers which are chemically inert to and appropriate
for the type and quantity of the hazardous substance
 Hazardous material containers will be maintained in good condition (e.g., no rust or structural
defects). If a container begins to leak, the contents will be transferred to another compatible
container in good condition.
 Hazardous substance containers shall be closed except when adding or dispensing material.
Additionally, containers shall be kept in approved storage cabinets with spill containment, unless
being utilized.
 Incompatible materials shall not be placed in the same container in order to prevent the
occurrence of the following reactions:
 generate extreme heat or pressure, fire or explosions, or violent reactions;
 produce uncontrolled toxic mists, fumes, dusts, or gases in sufficient quantities to threaten
human health or the environment;
 produce uncontrolled flammable fumes or gases in sufficient quantities to pose a risk of fire
or explosions;
 damage the structural integrity of the device or facility;
 through other like means threaten human health or the environment.
 Hazardous materials shall not be placed in an unwashed container that previously held an
incompatible waste or material.
 Substances which, when mixed, react violently, or evolve toxic vapors or gases, or which in
combination become hazardous by reason of toxicity, oxidizing power, flammability, explosive
nature, or other properties, shall be separated from each other in storage by distance, by
partitions, or otherwise, so as to preclude accidental contact between them.
 Containers of hazardous substances shall not be stored in such locations or manner as to result
in damage to the container. Containers shall not be stored where they are exposed to heat
sufficient to rupture the containers or to cause leakage.
 Containers used to package a substance which gives off toxic asphyxiation, suffocation, or
anesthetic fumes in hazardous amounts shall not be stored in locations where it could be
reasonably anticipated that individuals would be exposed.
 Compressed Gases will used and stored in compliance with the “Safe Storage and Use of
Compressed of Compressed Gas Cylinders” which is available at
http://www.cpp.edu/~ehs/files/occupational/doc/COMPGAS.doc
 Store hazardous materials in separate areas or containment based on the following
classifications.
 Explosives
 Poisons
 Compressed Gases - Flammable
 Corrosive Materials - Acids
 Compressed Gases - Inert
 Corrosive Materials – Bases/Alkalines
 Compressed Gases - Oxidizing
 Pyrophorics (Solid)
 Compressed Gases - Toxic
 Pyrophorics (Liquid)
 Compressed Gases - Corrosive
 Cryrogenics
 Flammable Liquids
 Carcinogens
 Flammable Solids
 Teratogens
 Oxidizers
 Mutagens
Hazardous Waste Management
The Instructor and/or PI will comply with the procedures for the isolation, separation and containment of
hazardous waste found in the following University Hazardous Substance Management Plans, as
applicable:
a) Hazardous Waste Manual (http://www.cpp.edu/~ehs/files/environmental/HazWasteManual.doc)
b) Medical Waste Disposal Manual (http://www.cpp.edu/~ehs/files/biosafety/medwst.doc)
Page 9
c) Radiation Safety Manual (http://www.cpp.edu/~ehs/files/radiation/RadiationManual.doc)
11.0
Emergency Response Plans
a. The Lead, Instructor and/or PI will develop standard operational procedures to maintain control of
hazardous material, including exposure, in compliance with established campus programs for the
management of chemical, infectious or radioactive materials. The Standard Operating Procedures
and
Safe
Work
Practices
for
Laboratory
Safety
(see
http://www.cpp.edu/~ehs/files/chemical/ChemicalLabSafetySOPs.docx on the EH&S Web Page)
can be a used to comply with this requirement.
b. The Lead, Instructor and/or PI will maintain spill response kits to deal with hazardous substance
spills that may occur as a result of their work.
c. All personnel should be trained on and follow the emergency procedures, including the use of the
available hazardous substance spill kits. This training shall be documented in writing and a copy
provided to the EH&S Department. A completed copy of the Safety Training Documentation Form
available on the EH&S Web Site at http://www.cpp.edu/~ehs/files/occupational/doc/Training.doc
can be used to document the training.
d. In the event that a hazardous substance spill occurs that cannot be safely contained and cleaned
up by laboratory or area personnel, the campus Emergency Management Plan will be activated by
dialing Campus Police at 911 and contacting Environmental Health & Safety at Extension 4697.
e. The campus emergency procedures for emergency contacts, medical assistance, gas leaks,
explosions, evacuation, earthquake, fire response, hazardous materials spills, bomb threats and
other emergencies are found in the Emergency Procedures Pamphlet
(http://www.cpp.edu/~ehs/files/common/pdf/EmergencyProcedureManual.pdf). This pamphlet will
be posted in all laboratories.
f. The Lead, Instructor and/or PI will comply with the University’s First-Aid Program
(http://www.cpp.edu/~ehs/files/common/pdf/Firstaid.pdf), which is incorporated in this plan by
reference.
g. Portable Fire Extinguishers shall be inspected monthly to make sure they are in the designated
location, visible, accessible, instruction/nameplate is facing forward, safety seal/pin is intact and
fully charged (Section 574.2 Title 19 CCR). This inspection shall be documented on the fire
extinguisher inspection tag.
h. Emergency Eyewash and Shower Equipment (California Code of Regulations, Title 8, §5162).
 An emergency eyewash is required at all work areas where, during routine operations or
foreseeable emergencies, the eyes of an employee may come into contact with a substance
which can cause corrosion, severe irritation or permanent tissue damage or which is toxic by
absorption.
 An emergency shower is required at all work areas where, during routine operations or
foreseeable emergencies, area of the body may come into contact with a substance which is
corrosive or severely irritating to the skin or which is toxic by skin absorption.
 Emergency eyewash facilities and deluge showers shall be in accessible locations that require
no more than 10 seconds for the injured person to reach.
 Plumbed eyewash and shower equipment shall be activated at least monthly to flush the line
and to verify proper operation. This test shall be documented on the emergency eyewash and
shower inspection tag.
Page 10
12.0
Incident Response Plan
General Information:
This Incident Response Plan is part of the larger campus Emergency Management Plan, which is
coordinated by the University Police Department, under the management of the Chief of Police.
Additional information regarding the campus Emergency Management Plan is available in the
University’s“Emergency Procedures Pamphlet” (http://www.cpp.edu/~ehs/files/common/pdf/firstaid.pdf).
This pamphlet is incorporated by reference as part of this plan. This plan will be made available to
members of the University Police Department, Environmental Health & Safety Department, local
emergency responders, and the local campus community upon request. Contact Information for this
plan is listed below:
Environmental Health & Safety:
1.
University Police (Emergency):
(909) 869-4697
DIAL 911 from a Campus Wired Phone or
2.
(909) 869-3070 from a Cell Phone
University Police (Non-Emergency):
(909) 869-3070
3.
4.
5.
Personnel Roles and Lines of Authority/Communication
Environmental Health & Safety/Responsible Officials
The Director of Environmental Health & Safety (EH&S) or alternate staff in Environmental Health &
Safety in the Director’s absence has primary authority for planning and response to a hazardous
substance (Infectious, Chemical or Radiologic Agents) releases under this plan. In this capacity, the
Director of EH&S or his alternate reports to the Associate Vice President for Human Resource
Services. Additionally, the Director of EH&S or his alternate communicates directly with the University
Police Chief, University Emergency Services Coordinator, Student Health Services Executive Director,
Los Angeles County Fire Department, or others on an as needed basis for planning and response to a
release. More detailed information is included in the larger campus Emergency Management Plan.
If the Director of EH&S or his alternate is on site in the laboratory or area during a release, that
individual will assume the position of Incident Commander. While on site, all responders will comply
with this plan and the directions of the Incident Commander.
University Police
The University Police, as sworn Peace Officers will have primary authority for security and law
enforcement. In all other matters they will follow the directions of the Incident Commander and will
comply with this plan.
Los Angeles County Fire Department
The Los Angeles County Fire Department will have primary authority for fire suppression and will
provide support and/or coordination for other operations as stated in this plan. They will comply with
this plan and follow the directions of the Incident Commander.
Building Marshals and Floor Captains
The Building Marshals and Floor Captains are responsible for planning, assessing and responding to
emergencies in specific campus buildings. If these individuals are on site in the Laboratory or area
during a release they will assume the position of Incident Commander, until relieved by the Director of
EH&S or his alternate or higher ranking official. While on site in the Laboratory or area they will comply
with this plan. More detailed information is included in the larger campus Emergency Management
Plan.
Page 11
Principle Investigator/Lead and Worker
The Principle Investigator/Lead and Workers are responsible for complying with this plan and the
University’s Emergency Procedures. In the absence of the Responsible Official/Alternate Responsible,
Building Marshal, Floor Captains or a higher ranking official, the Principle Investigator/Lead will assume
the role of Incident Commander.
Planning and Coordination with Local Emergency Responders
This plan is a direct result of an ongoing communication and planning with University Police Chief,
University Emergency Services Coordinator, Student Health Services Executive Director, Los Angeles
County Fire Department, and other local responders.
The University Emergency Services Coordinator, University Police, Principle Building Marshal, Floor
Captains, Laboratory Personnel, Los Angeles County Fire Department and others will be invited to
participate in drills of this plan to improve planning and coordination.
Rescue Procedures
Any injury or trapped individual should be reported to the laboratory or area supervisor, and timely and
appropriate action shall be taken to evacuate such individuals from the laboratory/area and to obtain
appropriate medical treatment. Individuals providing medical aid, first-aid or rescuing people should
wearing appropriate personnel protective equipment. The following is a minimum level of personnel
protective equipment for contaminated individuals:



Face protection (goggles, mask, face shield or other splatter guard).
Protective laboratory coat or other appropriate protective clothing.
Gloves.
Follow the “Emergency Medical and First-Aid” below for injured individuals. Medical treatment and firstAid should be administered outside the lab or contaminated area if the injured person is ambulatory.
If an accident involves a biohazard spill, move the injured person away from the spill. Inactivate the spill
after attending the injured person. Do not attempt to move a non-ambulatory person unless it is
absolutely necessary.
Remove all protective clothing (i.e., lab coat) from the injured person that may have been
contaminated, and cut/rip away the protective clothing only if necessary. Do not move a seriously
injured person to remove protective clothing. Wash any contaminated skin with disinfectant such as
Betadine or soap and water. If it is not feasible to decontaminate an injured individual needing
extensive medical assistance, follow procedures for a contaminated patient listed under the “Release
Response” Section of this plan.
Page 12
Emergency Medical Treatment and First-Aid
ILLNESS/INJURY
 In the event of a serious illness or injury on campus, immediately call University Police. Dial 9-1-1
on a campus phone do not call 9-1-1 using a cell phone. Dial (909) 869-3070 to access University
Police on a cell phone.
 Do not move a seriously injured person, or one who appears to be seriously ill, unless it is a lifethreatening situation.
 Determine if the injured individual is contaminated. If the injured individual is contaminated advised
emergency response personnel, follow procedures listed in this plan to protect yourself and others
from exposure/contamination.
 Give your name, location and telephone number, and as much information as possible
regarding the nature of the injury or illness, and whether or not the victim is conscious
or contaminated.
 All on-campus injuries, even though minor, must be reported to your immediate
supervisor.
 The university has an agreement with MEDIC-1 ambulance so that any injured or ill student will be
transported to Student Health during business hours at no charge to the patient. Dial (909) 869-3070
to request medical transport. For emergency treatment of injuries or illnesses dial 9-1-1 from any on
campus telephone.
FIRST AID
 Campus police officers are trained in First-Aid and cardio pulmonary resuscitation (CPR). An
automatic external defibrillator is available through University Police. Do not attempt to render FirstAid unless you have been trained to do so.
 Remain with the victim until campus police officers arrive. Keep the ill or injured person as calm and
comfortable as possible. You should list the names of persons in your building or department who are
trained in first aid and/or CPR on the back of the Emergency Procedures Pamphlet, should they be
needed.
Notification:
Any of the following will be reported to University Police and EH&S.



Suspected or known loss or theft of any chemicals, infectious agents or radioactive material.
Security breaches of storage locations.
Security breaches in computer systems containing information on chemicals, infectious agents or
radioactive materials.
If this incident occurs after hours, the University Police shall be notified first. The University Police shall
contact the Director of EH&S or his alternate.
Release Response:
The release of any agent or chemical may be caused by a spill in the use location, the result of a terrorist
act, earthquake or theft. The following are methods and observation to detect the presence of a spill or
release of a hazardous agent:
 The presence of broken containers.
 The presence of overturned containers with missing lids.
 The presence of a somewhat reflective clear film on cabinets, counters or other equipment, etc.
 The presence of any strange or unusual odor.
 The presence of visible smoke or vapors.
Page 13
In the event of notification of a pending severe weather condition work with any chemicals, infectious
agents or radioactive materials will be discontinued and the agents returned to secure containment or
storage. If a release does occur as a result of any of the above, laboratory or area personnel will
initiate the procedures described below under “Decontamination/Clean-Up Procedures for
Spills/Releases” and the procedures in Annex R of the University’s Emergency Management Plan will
be activated. The Annex R procedures are listed below for convenience.
Rooms Containing Chemicals and Infectious Organisms:
 Only trained personnel shall be allowed to enter, wearing appropriate personal protective
equipment (e.g. protective clothing, eye protection, gloves, etc.).
 All fires must be contained in these rooms and be allowed to burn themselves out. Fire fighters
may then enter with respirators after all walls and contents of the room have been wetted down with
a fine spray of water or foam, depending on emergency response guidelines.
 Refrigerators and freezers, in most cases, should remain intact; however, they should be
isolated and removed or disposed of only by qualified personnel wearing appropriate personal
protective equipment (e.g. protective clothing and self-contained breathing apparatus).
 In the event of mass contamination of individuals. The Countywide Hazardous Materials
Incident Response Plan will be activated to establish a large scale decontamination unit to
decontaminate individuals. For seriously injured individuals refer to “Contaminated – Injured
Patients” below.
Rooms containing radioactive materials:



Only authorized personnel equipped with radiation dosimeters and wearing appropriate personal
protective equipment (e.g. protective clothing and HEPA respirators) should be admitted. Radiation
detectors such as Geiger Counters or Ion Chambers should also be carried.
Short exposure to radiation at the levels present in these rooms is not considered to be lethal;
therefore, entry to save human life by emergency personnel other than EH&S personnel should not
be prevented.
In the event of mass contamination of individuals. The Countywide Hazardous Materials Incident
Response Plan will be activated to establish a large scale decontamination unit to decontaminate
individuals. For seriously injured individuals refer to “Contaminated – Injured Patients” below.
Contaminated - Injured Patients
In the unlikely event that the University would have a contaminated-injured patient, the County will be
informed. The County Health Officer, through the Los Angeles County Fire Department, will dispatch
an ambulance to Cal Poly Pomona and then contract for the receiving hospital (Huntington Memorial in
Pasadena (626) 397-5000 or Whittier Presbyterian Intercommunity Hospital (562) 698-0811 to prepare
for the arrival of contaminated patients. The ambulance will be instructed by radio/or by Police and
Parking personnel at the access control point, so that the ambulance driver can be directed to the
location of contaminated-injured individual(s) on campus. San Antonio Community Hospital (909) 9852811 is the nearest (out of County) hospital equipped to handle patients of this type.
Page 14
Personal Protective Equipment:
The following is a list of Personal Protective Equipment that Departments have available in use/storage
locations and when they will be used.
 Face protection (goggles, mask, face shield or other splatter guard) will be available in the
laboratory or area where the chemicals, infectious agents or radioactive material is used.
 Protective laboratory coats or other appropriate protective clothing are worn while in the laboratory.
 Gloves are worn when hands may contact chemicals, potentially infectious materials, radioactive
materials, contaminated surfaces or equipment.
 Additional protective equipment may be necessary depending on the hazard of the substances or
process in the laboratory or area.
Evacuation
Evacuation of the area will be via the established fire exits in the building as referenced in the
Emergency Procedures Manual (Flip Book) which is actively distributed on campus and available below
via the embedded link. Evacuees will initially gather at their pre-determined evacuation site of staging
area (if applicable) to check in with Building Marshals, Floor Captains or other emergency personnel.
Following check in, evacuees will be directed/moved by emergency personnel, if necessary; to the final
Evacuation Staging Area as indicated in the Emergency Procedures Pamphlet. Individuals that are
contaminated will be held for proper decontamination. Please refer to the “Emergency Procedures
Pamphlet” (http://www.cpp.edu/~ehs/files/common/pdf/EmergencyProcedureManual.pdf) for additional
information on “Evacuation”. This pamphlet is incorporated by reference as part of this plan.
Decontamination/Clean-Up Procedures for Spills/Releases
EH&S has establish basic written procedures to contain/destroy a spill within a room/area (see below).
Departments are required to train personnel in these procedures. These procedures and any
modifications to these procedures will be based on the hazard(s) associated with the hazard(s) present.
In the event of any spill, personnel will notify EH&S. If the spill cannot be contained within the
room/area, the room/area will be evacuated, locked down and EH&S and the University Police notified
to activate the campus Emergency Management Plan. Personnel will ensure that they are
decontaminated before leaving the area. The activation of the Management Plan shall include
notification of the EH&S and the University Police.
Procedures to Clean-Up a Chemical Spill
1. Telephone numbers for emergency response should be posted on the room door.
2. A spill kit shall be maintained by the Department and made available and stored in a readily
accessible area for quick access.
3. All precautions must be taken to avoid ingestion by any route, skin contact, or inhalation of fumes at
any point of toxin handling and during the destruction process. Observe all Universal Precautions,
Federal, State and Local laws.
4. Do not leave the spill unattended or unlabeled. Make sure people in the lab are informed of the
spill.
5. For smaller and contained spills, please follow the steps below to clean up the spill immediately and
then report to EH&S.
6. Before cleaning up a spill/accident, make sure you wear appropriate personal protection equipment
and place an appropriate and compatible disposal container in close proximity.
7. PPE includes disposable suits/lab coats, gloves, safety goggles, and/or appropriate
respirator/mask. Shoe covers may be needed for cleaning floor spills. Face shield should be worn if
at risk of splashes.
Page 15
8. For liquid spills cover with an appropriate chemical absorbent. Make sure all the spilled material is
absorbed.
9. For solid spills that may present a present a serious dust hazard, consider misting with water or
other appropriate solvent.
10. For gases consider exhausting the vapors or fumes using fume hoods or other exhaust devices,
provided this will not present a serious risk to individuals or the environment.
11. If there are no sharps or broken glass, wrap up the towels and/or absorbent paper, and place it in
the disposal container for waste disposal. If sharps or broken glass is present, use remote
equipment (e.g. plastic dust pan, tongs, and squeegee/scraper) to transfer the items to the
disposal container.
12. Once the spilled liquid or solid is removed, utilize wipes wetted with an appropriate solvent or
neutralizing agent to removing the remaining material as necessary.
13. Label the disposal containers with a completed hazardous waste label (AKA Green Form) and
submit to EH&S for proper disposal.
Procedures to Clean-Up an Infectious Material Spill
1. Telephone numbers for emergency response should be posted on the room door.
2. All precautions must be taken to avoid ingestion by any route, skin contact, or inhalation of fumes at
any point of toxin handling and during the destruction process. Observe all Universal Precautions,
Federal, State and Local laws.
3. Do not leave the spill unattended or unlabeled. Make sure people in the lab are informed of the
spill.
4. For smaller and contained spills, please follow the steps below to clean up the spill immediately and
then report to EH&S.
5. Before cleaning up a spill/accident, make sure you wear appropriate personal protection equipment
and place the disposal container in Biosafety Cabinet (BSC).
6. PPE includes disposable lab coats, gloves, safety glasses, and mask. Shoe covers will be needed
for cleaning floor spills. Face shield should be worn if at risk of splashes.
7. A spill kit and extra autoclave bags should be made available and stored in a readily accessible
area for quick access.
8. Large and small sharp containers should also be stored in the room.
9. Cover the spill with a damp cloth or paper towel that has been prewetted with a 10% bleach
solution. Soak for 10 minutes.
10. If there are no sharps or broken glass, wrap up the towels and/or absorbent paper, and place it in
a red biohazard bag for waste disposal. If sharps or broken glass is present, use remote
equipment (e.g. plastic dust pan, tongs, and squeegee/scraper) to transfer the items to a sharp
container for waste disposal.
11. Repeat the cleaning with more 10% bleach and place these wipes into the red biohazard bag.
12. Ventilate the area.
13. Autoclave the waste immediately at 121°C and 15 psi for 60 minutes, if possible or transport it to
the collections bins behind Building 46 for transportation to an appropriate treatment facility.
Procedures to Clean Up a Radioactive Material Spill
1. Telephone numbers for emergency response should be posted on the room door.
2. All precautions must be taken to avoid serious ambient radiation exposure, ingestion by any route,
skin contact, or inhalation of fumes during the clean-up process. Observe all Universal
Precautions, Federal, State and Local laws. The clean-up of most radioactive material at the
University will not result in a significant ambient radiation exposure.
Page 16
3. Do not leave the spill unattended or unlabeled. Make sure people in the lab are informed of the
spill.
4. For smaller and contained spills, please follow the steps below to clean up the spill immediately and
then report to EH&S.
5. Before cleaning up a spill/accident, make sure you wear appropriate personal protection equipment
and place an appropriate and compatible disposal container in close proximity.
6. PPE includes disposable suits/lab coats, disposable gloves, safety goggles, and/or appropriate
respirator/mask. Shoe covers may be needed for cleaning floor spills. Face shield should be worn if
at risk of splashes.
7. For liquid spills cover with absorbent paper towels or similar disposable absorbent material. Make
sure all the spilled material is absorbed.
8. For solid spills that may present a present a serious dust hazard, consider misting with water or
other appropriate solvent.
9. If there are no sharps or broken glass, wrap up the towels and/or absorbent paper, and place it in
the disposal container for waste disposal. If sharps or broken glass is present, use remote
equipment (e.g. plastic dust pan, tongs, and squeegee/scraper) to transfer the items to the
disposal container.
10. Once the spilled liquid or solid is removed, utilize paper towels or other disposal wipes wetted with
an appropriate solvent or neutralizing agent to removing the remaining material as necessary.
Usually, wiping the contaminated area with three separate wipes is sufficient to remove the
contamination.
11. All the contaminated paper towels, disposable wipes, disposable gloves and other material should
be placed in the disposal container.
12. Perform wipe test to verify that all the radioactive material has been removed.
13. Seal and label the container with the words “Radioactive Waste”, isotope and activity. Contact the
EH&S Department at (909) 869-4697 to arrange for disposal of the waste.
Remember, if you feel uncomfortable handling a spill clean-up, contact EH&S.
Fires
The procedure to extinguish a fire is to use the PASS method. The ABC fire extinguisher is the most
common extinguisher; comprised of a dry chemical powder. This extinguisher can put out class A, B,
and C fires (combustibles, liquid, and electrical fires). Hands on training to handle a fire extinguisher is
conducted every 3 years as well as an annual Fire Safety lecture which is done by EH&S. Refer to the
“EmergencyProceduresPamphlet”(http://www.cpp.edu/~ehs/files/common/pdf/EmergencyProcedureMa
nual.pdf) for additional information about fire safety.
How to Use a Fire Extinguisher
P
PULL safety pin from handle.
A
AIM nozzle, cone, or horn at base of the fire.
S
SQUEEZE the trigger handle.
S
SWEEP from side-to-side.
Page 17
Security Breaches
Suspicious Persons or Activities
•
•
•
•
•
•
•
•
•
Report any suspicious persons, unauthorized entries, damage and/or tampering with any locks,
entry doors, access doors or other devices utilized to secure inventory or other suspicious activities
immediately to the University Police.
Unauthorized or unescorted persons shall be asked to immediately leave the room, if safe to do so.
If the individual(s) refuses to leave the room or if you feel that the situation may be unsafe, the
following procedures should be taken:
Do not attempt to apprehend or further confront the individual(s).
If safe to do so, return all materials to respective storage containers/areas and secure all locks.
Find a safe location (locked office etc.), Telephone University Police at 9-1-1 from any campus
phone or dial (909) 869-3070 from a Cell Phone.
Be ready to give your name, location and description of the problem.
Be a good witness. Make a note of the suspect’s appearance, details of the incident, weapons
seen and vehicles involved.
Remain calm!
Wait for help to arrive.
If the suspicious persons or unauthorized entrant could have removed any items of materials or
there is evidence of damage and/or tampering with any locks, entry doors, access doors or other
devices utilized, the University Police may conduct a physical inventory or ask that you do so.
Information System Breaches
•
•
•
•
•
•
•
•
•
•
•
•
•
For compromised computers, security incidents or suspected compromises disconnect the
computer from the network and contact the I&IT Help Desk immediately at Extension 6776 or (909)
869-6776 and Campus Police.
When reporting the breach, be prepared to provide the following information:
Your Name
Your Telephone Number
An Alternate Telephone Number
Your Location (Building and Room Number)
Additionally, for extensive network security incidents, please be prepared for the possibility of
providing the following information:
The date/time and a complete description of the incident.
The IP addresses of all the computers involved.
Security measures implemented before the incident occurred.
The steps taken after the incident occurred.
All logs from the computer.
Any other information that you feel is relevant to the investigation
Page 18
Severe Weather and Other Natural Disasters
•
•
•
•
•
•
•
In the event of severe weather, forecast of severe weather and/or natural disaster (e.g.,
Earthquake) that could adversely affect the area where chemicals or hazardous materials are used
or stored, the following steps should be taken:
Shutdown or stabilize any experiments or work that is in progress.
Return all materials to their respective storage containers/areas and secure all locks.
Notify your supervisor or manager.
If the severe weather and/or natural disaster cause a release or spill, follow the procedures listed
under the “Release Response” section of this plan.
Remain calm. Follow the appropriate procedures in the Emergency Procedures Pamphlet
(http://www.cpp.edu/~ehs/files/common/pdf/EmergencyProcedureManual.pdf).
Following a severe weather incident and/or natural disaster (e.g., Earthquake) that could
adversely affect the area where chemicals or hazardous materials are used or stored, the
area should be inspected to verify that there have been no releases.
Workplace Violence



•
•
For immediate threats of violence/danger directed at you/others or threats of violence/danger
directed internally (suicidal individual) call University Police at 9-1-1 from any campus phone.
If you need immediate consultation after hours and/or on the weekend, call University Police at
(909) 869-3070. You may ask to talk to the University Police Watch Commander or ask the
dispatcher to contact the Police Chief, Emergency Services Coordinator, or Director of Counseling
and Psychological Services (off campus/at home) and request that they call you back. Please
provide your call-back number to the Police Dispatcher.
Two confidential Email addresses are available:
• mailto:BroncoSafe@cpp.edu (University Police), and
• mailto:BroncoConcerns@cpp.edu (Counseling & Psychological Services).
To pass on non-emergency or non-immediate information, confidential calls can be made to the
University Police Department’s anonymous tip-line at (909) 869-3399. Referring individuals should
provide as much information as is available in order to enable the team to make the most accurate
and timely assessment.
If you suspect the possibility of any future threats of violence/danger directed at you/others or
threats of violence/danger directed internally (suicidal individual) contact Campus Police.
Bomb Threats
•
•
•
•
•
Immediately call University Police at 9-1-1 from any campus phone. If directed to evacuate, make
note of anything unusual and report it after you have safely left the building.
Remain calm. If possible use the checklist provided at the back of the Emergency Procedures
Pamphlet (http://www.cpp.edu/~ehs/files/common/pdf/EmergencyProcedureManual.pdf), to get as
much information possible from the person making the Bomb Threat.
Write down exact words of caller. Note time of call, voice (male or female, age, accent or
background sounds), location of bomb and time it will explode.
Ask the caller, if possible, what type of bomb, what it looks like, the reason for placing it and who is
claiming responsibility, etc.
Share any information you obtain with the University Police.
Page 19
Suspicious Letters or Parcels
•
•
•
13.0
Be alert for suspicious letters or parcels.
Typical characteristics of a suspicious letter or parcel include:
• Excessive Postage, no postage, or non-cancelled postage.
• No return address or obvious fictitious return address.
• Parcels/Packages that are unexpected or from someone unfamiliar to you.
• Excessive tape.
• Improper spelling of addressee names, titles or locations.
• Parcels/Packages that are addressed to someone no longer with your organization or
otherwise outdated.
• Rigid or bulky, lopsided or uneven.
• Unexpected envelopes from foreign countries.
• Restrictive markings.
If you receive a suspicious letter or package:
• STOP - Don’t handle it.
• Isolate it immediately.
• Don’t open, smell, or taste.
• Call University Police at 9-1-1 from any campus phone.
• Don’t open, smell, or taste.
• Call University Police at 9-1-1 from any campus phone.
Training
All individuals using hazardous materials will receive training on the following. Employees can attend
EH&S Training Sessions or utilize the Skillsoft Web Based Training System. Employees (Faculty, Staff
and Student Workers) can utilize the Skillsoft Web Based Training System by linking to
https://www.cpp.edu/skillsoft. Employees can utilize their Bronco Name and Password to access the
system. Individuals can also complete training on their own by reading material, asking questions,
completing documentation forms and submitting copies to EH&S.
Training for students is coordinated by the Principle Investigator, Department or College.
a. Initial/Reassignment Safety Training. This training is required initially and when reassigned.
This training shall be documented in writing using the Employee Training Documentation Initial
Training form or equivalent, which is available on the EH&S Web Site at
http://www.cpp.edu/~ehs/files/occupational/doc/TrainingIndividual.doc
Copies
of
training
documentation shall be sent to the EH&S Department. This training includes the following.
 The University’s Injury & Illness Prevention Plan.
 Potential occupational hazards associated with the assigned tasks and in the work area
 Mandatory Safe Work Practices
 Hazards of any chemicals to which they may be exposed and their right to information contained
on safety data sheets for those chemicals.
 Their right to ask any questions, or provide any information to the employer on safety either
directly or anonymously without any fear of reprisal (See Safety Concern Reporting below).
 Responsibility to report hazards.
 Responsibility to report accidents or near miss accidents and injuries.
 Disciplinary procedures the employer will use to enforce compliance with Mandatory Safe Work
Practices.
b. Emergency Procedures. All personnel should be trained on and follow the emergency
procedures, including the use of the available hazardous substance spill kits. This training is
required initially upon assignment and annually thereafter. The training can be completed by
Page 20
c.
d.
e.
f.
g.
h.
i.
j.
k.
attending and EH&S Training Session or by reading the Emergency Procedures and completing
and signing the Emergency Procedures - Individual Training Form and returning copy to EH&S.
Fire Safety. This training is required initially upon assignment and annually thereafter.
First Aid. This training is required initially upon assignment and annually thereafter.
Hazard Communication. This training is required initially upon assignment and annually
thereafter.
Chemical Safety in Laboratories. This training is required initially upon assignment and annually
thereafter.
Hazardous Waste Management. This training is required initially upon assignment and annually
thereafter.
Bloodborne Pathogens. This training is required if the individual will use bloodborne pathogens.
This training is required initially upon assignment and annually thereafter.
Infectious Materials. This training is required if the individual will use infectious materials. This
training is required initially upon assignment and annually thereafter.
Medical Waste. This training is required if the individual will generate of handle infectious waste.
This training is required initially upon assignment and annually thereafter.
Radiation Safety. This training is required if the individual will use radioactive materials or
radiation generating machines.
Employees, except auxiliary employees, can utilize the Skillsoft Web Based Training System to
complete most of the above training. Information about using Skillsoft is available by linking to
https:/www.cpp/skillsoft.html. Individuals can access Skillsoft by using their Bronco Name and
Password. Classroom training is also available. All training should be documented in writing, except
training completed using Skillsoft, and a copy sent to the EH&S Department. The Safety Training
Documentation
Form,
available
of
the
EH&S
Web
Site
at
http://www.cpp.edu/~ehs/files/occupational/doc/Training.doc, or equivalent shall be used for this
purpose. Information on training, including a training schedule, is available on the EH&S Web Site at
http://www.cpp.edu/~ehs/training.shtml.
14.0
Safety Concern Reporting
The University has established procedures for reporting safety-related issues as part of the Injury and
Illness Prevention Program.
All safety concerns should be reported immediately to your
supervisor/principal investigator, as well as the department responsible for abatement or control of the
hazard.
Serious Injuries or Crimes
Dial 911 from a Campus Phone or (909) 869-3070 from a Cell Phone for Police Services
Hazardous Substance Releases
Dial 911 from a Campus Phone or (909) 869-3070 from a Cell Phone for Police Services
and
Dial 4697 for Environmental Health and Safety
Routine Repairs/Maintenance
Dial 3030 for Facilities Management (M-F, 8 am—5 pm)
or
Dial 3070 for Police Services (after hours)
Pedestrian/Vehicle Safety
Dial 3070 for Police Services
Page 21
Other Safety Information
Dial 4697 for Environmental Health and Safety
EH&S Confidential Voice Mailbox
Dial 4313
In addition to the telephone numbers listed above, a confidential voice mailbox (extension 4313), webbased/on-line reporting (http://www.cpp.edu/~ehs/contact-us/safety-concern.shtml) and an Employee
Safety Information Form (F-2554-00) are available to assist staff in reporting potential safety hazards.
Every effort has been made to maintain the confidentiality of those using the voicemail extension; David
Patterson, Director of Environmental Health and Safety, is the only individual with access to the
voicemail messages. Please do not use the voicemail number or the information form for reporting
hazards that require immediate assistance. Emergency calls should be directed to 911, urgent calls
should be directed to University Police Services (3070) or Facilities Management (3030).
Supervisors and departments receiving a report of an imminent safety hazard should respond
immediately to prevent serious injuries. Most safety hazards can be avoided by the abatement or
removal of the hazard, posting warning signs, closing the area to prevent entry, or through the proper
use of person protective equipment.
Page 22
APPENDIX A
Table I: Building and Fire Code Limits for Hazardous Materials
NFPA Classification
Carcinogens
Carcinogens
Carcinogens
Combustible Liquids II
Combustible Liquids IIIA
Combustible Liquids IIIB
Corrosives
Corrosives
Corrosives
Explosives
Explosives
Flammable Gas
Flammable Gas
Flammable Liquids IA
Flammable Liquids IB
Flammable Liquids IC
Flammable Solid
Highly Toxics
Highly Toxics
Highly Toxics
Organic Peroxide
Detonatable
Organic Peroxide
Detonatable
Organic Peroxide Class I
Organic Peroxide Class II
Organic Peroxide Class II
Organic Peroxide Class III
Organic Peroxide Class III
Organic Peroxide Class IV
Organic Peroxide Class IV
Organic Peroxide Class V
Organic Peroxide Class V
Other Health Hazards
Other Health Hazards
Other Health Hazards
Form
Units
Cubic
Gas
Feet
Liquid
Gallons
Solid
Pounds
Liquid
Gallons
Liquid
Gallons
Liquid
Gallons
Cubic
Gas
Feet
Liquid
Gallons
Solid
Pounds
Liquid
Pounds
Solid
Pounds
Cubic
Gas
Feet
Liquefied Gallons
Liquid
Gallons
Liquid
Gallons
Liquid
Gallons
Solid
Pounds
Cubic
Gas
Feet
Liquid
Pounds
Solid
Pounds
Liquid
Pounds
Solid
Solid
Liquid
Solid
Liquid
Solid
Liquid
Solid
Liquid
Solid
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Cubic
Feet
Gallons
Pounds
Gas
Liquid
Solid
Building/
Fire
Code
Limit
Building/
Fire Code
Building/
Building/
Limit
Fire Code
Fire Code
w/Sprinklers
Limit
Limit
and
w/Sprinklers w/Cabinets Cabinets
810
500
5,000
120
330
13,200
810
500
5,000
240
660
26,400
240
660
26,400
810
500
5,000
0
0
1,620
1
1
0
0
750
15
30
60
90
125
1,500
30
60
120
180
250
1,500
30
3,000
60
60
120
180
250
20
20
10
10
0
2
0
10
10
0
1
1,620
500
5,000
2
2
0
1
0
2
5
10
10
20
50
100
100
200
50
100
100
200
125
250
250
500
125
250
250
500
500
1,000
1,000
2,000
500
1,000
1,000
2,000
No Limit
No Limit
No Limit
No Limit
No Limit
No Limit
No Limit
No Limit
810
No Limit
No Limit
No Limit
No Limit
Page 23
1,620
1,620
No Limit
No Limit
No Limit
No Limit
Page 24
APPENDIX A Continued
Table I: Building and Fire Code Limits for Hazardous Materials
NFPA Classification
Oxidizer 1
Oxidizer 1
Oxidizer 2
Oxidizer 2
Oxidizer 3
Oxidizer 3
Oxidizer 4
Oxidizer 4
Oxidizer Gas
Oxidizer Gas
Pyrophorics
Pyrophorics
Pyrophorics
Toxics
Toxics
Toxics
Water Reactive 1
Water Reactive 1
Water Reactive 2
Water Reactive 2
Water Reactive 3
Water Reactive 3
Form
Liquid
Solid
Liquid
Solid
Liquid
Solid
Liquid
Solid
Units
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Pounds
Cubic
Gas
Feet
Liquefied Gallons
Liquid
Pounds
Solid
Pounds
Cubic
Gas
Feet
Cubic
Gas
Feet
Liquid
Pounds
Solid
Pounds
Liquid
Gallons
Solid
Pounds
Liquid
Pounds
Solid
Pounds
Liquid
Pounds
Solid
Pounds
Building/
Fire
Code
Limit
4,000
4,000
250
250
10
10
0
0
Building/
Fire Code
Limit
w/Sprinklers
8,000
8,000
500
500
20
20
1
1
Building/
Fire Code
Limit
w/Cabinets
8,000
8,000
500
500
20
20
0
0
Building/
Fire Code
Limit
w/Sprinklers
and
Cabinets
16,000
16,000
1,000
1,000
40
40
2
2
1,500
15
0
0
3,000
30
4
4
3,000
30
0
0
6,000
60
8
8
50
50
810
1,620
1,620
500
500
500
500
No Limit
No Limit
No Limit
No Limit
No Limit
No Limit
No Limit
No Limit
50
100
100
200
50
100
100
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Definitions
CARCINOGEN is a substance that causes the development of cancerous growths in living tissue. A chemical
is considered to be a carcinogen if:
 It has been evaluated by the International Agency for Research on Cancer (IARC) and found to be a
carcinogen or potential carcinogen, or
 It is listed as a carcinogen or potential carcinogen in the latest edition of the Annual Report on Carcinogens
published by the National Toxicology Program, or
 It is regulated by OSHA as a carcinogen.
COMBUSTIBLE LIQUID is a liquid having a flash point at or above 100'F. (37.8'C.). Combustible liquids are
subdivided as follows. The category of combustible liquids does not include compressed gases or cryogenic
fluids.
 Class II liquids are those having flash points at or above 100'F. (37.8'C.) and below 140'F. (60-C.).
 Class III-A liquids are those having flash points at or above 140'F. (60'C.) and below 200'F. (93.3-C.).
 Class Ill-B liquids are those liquids having flash points at or above 200'F. (93.3'C.).
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APPENDIX A Continued
CORROSIVE is a chemical that causes visible destruction of, or irreversible alterations in, living tissue by
chemical action at the site of contact. A chemical is considered to be corrosive if, when tested on the intact skin
of albino rabbits by the method described in Appendix A to C.F.R. 49, Part 173, it destroys or changes
irreversibly the structure of the tissue at the site of contact following an exposure period of four hours. This
term does not refer to action on inanimate surfaces.
EXPLOSIVE is
 A chemical that causes a sudden, almost instantaneous release of pressure, gas and heat when subjected
to sudden shock, pressure, or high temperatures, or
 A material or chemical, other than a blasting agent, that is commonly used or intended to be used for the
purpose of producing an explosive effect and is regulated by Article 77.
FLAMMABLE GAS is any material which is a gas at 68'F. (20'C.) or less at 14.7 psia (101.3 kPa) of pressure [a
material has a boiling point of 680F. (200C.) or less at 14.7 psia (101.3 kPa)] which:
 Is ignitable at 14.7 psia (101.3kPa) when in a mixture of 13 percent or less by volume with air, or
 Has a flammable range at 14.7 psia (101.3kPa) with air of at least 12 percent, regardless of the lower limit.
The limits specified shall be determined at 14.7 psi (101.3 kPa) of pressure and a temperature of 68'F. (20'C.)
in accordance with nationally recognized standards. See Article 90, Standard a.4.9.
FLAMMABLE LIQUEFIED GAS is a liquefied compressed gas which under the charged pressure is partially
liquid at a temperature of 68'F. (20'C.) and which is flammable.
FLAMMABLE LIQUID is a liquid having a flash point below 100'F. (37.8'C.) and having a vapor pressure not
exceeding 40 psia (276 kPa) at 100'F. (37.8'C.). The category of flammable liquids does not include
compressed gases or cryogenic fluids. Class I liquids include those having flash points below 100'F. (37.8'C.)
and are subdivided as follows:
 Class I-A liquids include those having a flash point below 73'R (22.8'C.) and having a boiling point below
100'F. (37.8'C.).
 Class I-B liquids include those having a flash point below 73'F. (22.8'C.) and having a boiling point at or
above 100'F. (37.8'C.).
 Class I-C liquids include those having a flash point at or above 73'F. (22.8'C.) and below 100'F. (37.80C.).
FLAMMABLE SOLID is a solid substance, other than one which is defined as a blasting agent or explosive,
that is liable to cause fire through friction or as a result of retained heat from manufacture, which has an
ignition temperature below 212'F. (100'C.), or which burns so vigorously or persistently when ignited that it
creates a serious hazard. Flammable solids include finely divided solid materials which when dispersed in air
as a cloud could be ignited and cause an explosion.
HIGHLY TOXIC MATERIAL is a material which produces a lethal dose or lethal concentration which falls within
any of the following categories:
 A chemical that has a median lethal dose (LD50) of 50 milligrams or less per kilogram of body weight when
administered orally to albino rats weighing between 200 and 300 grams each.
 A chemical that has a median lethal dose (LD50) of 200 milligrams or less per kilogram of body weight
when administered by continuous contact for 24 hours, or less if death occurs within 24 hours, with the
bare skin of albino rabbits weighing between 2 and 3 kilograms each.
 A chemical that has a median lethal concentration (LC50) in air of 200 parts per million by volume or less of
gas or vapor, or 2 milligrams per liter or less of mist, fume or dust, when administered by continuous
inhalation for one hour, or less if death occurs within one hour, to albino rats weighing between 200 and
300 grams each.
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APPENDIX A Continued
ORGANIC PEROXIDE is an organic compound that contains the bivalent -0-0- structure and which may be
considered to be a structural derivative of hydrogen peroxide where one or both of the hydrogen atoms have
been replaced by an organic radical. Organic peroxides can present an explosion hazard (detonation or
deflagration) or they can be shock sensitive. They can also decompose into various unstable compounds over
an extended period of time. Organic peroxides can be split into the following classes:
 Class I - capable of deflagration but not detonation.
 Class II - burn very rapidly and are a severe reactivity hazard.
 Class III - burn rapidly and have a moderate reactivity hazard.
 Class IV - burn in the same manner as ordinary combustibles and have a minimal reactivity hazard.
 Class V - burn with less intensity than ordinary combustibles or they do not support combustion and
present no reactivity hazard.
OTHER HEALTH HAZARD MATERIAL is a hazardous material which affects target organs of the body,
including, but not limited to, those materials which produce liver damage, kidney damage, damage to the
nervous system, act on the blood to decrease hemoglobin function, deprive the body tissue of oxygen, or affect
reproductive capabilities, including mutations (chromosomal damage) or teratogens (effects on fetuses).
OXIDIZER is a chemical other than a blasting agent or explosive that initiates or promotes combustion in other
materials, thereby causing fire either of itself or through the release of oxygen or other gases. Oxidizers can
be split into the following classes:
 Class 1 Oxidizers:
 Slightly increase the burning rate of combustible materials.
 Do not cause spontaneous ignition when they come in contact with combustible materials.
 Examples are:
 aluminum nitrate
 ammonium persulfate
 barium peroxide
 hydrogen peroxide solutions (8% to 27.5% by weight)
 magnesium nitrate
 nitric acid (40% concentration or less)
 perchloric acid solutions (less than 50% by weight)
 potassium dichromate
 potassium nitrate
 silver nitrate
 sodium dichloroisocyanurate dihydrate
 sodium dichromate
 sodium nitrate
 sodium nitrite
 sodium perborate (and its monohydrate)
 sodium persulfate
 strontium nitrate
 strontium peroxide
 trichloroisocyanuric acid
 zinc peroxide
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APPENDIX A Continued



Class 2 Oxidizers:
 Increase the burning rate of combustible materials moderately with which they come in contact.
 May cause spontaneous ignition when in contact with a combustible material.
 Examples are:
 calcium chlorate
 calcium hypochlorite (50% or less by weight)
 chromic acid (chromium trioxide)
 1,3-dichloro-5,5-dimethylhydantoin
 hydrogen peroxide (27.5 to 52% by weight)
 magnesium perchlorate
 nitric acid (concentration greater than 40% but less than 86%)
 potassium permanganate
 sodium permanganate
 sodium chlorite (40% or less by weight)
 sodium perchlorate (and its monohydrate)
 sodium peroxide
Class 3 Oxidizers:
 Severely increase the burning rate of combustible materials with which they come in contact.
 Will cause sustained and vigorous decomposition if contaminated with a combustible material or if
exposed to sufficient heat.
 Examples are:
 ammonium dichromate
 hydrogen peroxide (52 to 91% by weight)
 nitric acid, fuming (concentration greater than 86%)
 perchloric acid solutions (60 to 72% by weight)
 potassium bromate
 potassium chlorate
 potassium dichloroisocyanurate
 sodium chlorate
 sodium chlorite (greater than 40% by weight)
 sodium dichloroisocyanurate
Class 4 Oxidizers:
 Can explode when in contact with certain contaminants.
 Can explode if exposed to slight heat, shock, or friction.
 Will increase the burning rate of combustibles.
 Can cause combustibles to ignite spontaneously.
 Examples are:
 ammonium perchlorate (particle size greater than 15 microns)
 ammonium permanganate
 hydrogen peroxide (greater than 91% by weight)
 perchloric acid solutions (greater than 72.5% by weight)
 tetranitromethane
PYROPHORIC is a chemical that will spontaneously ignite in air at or below a temperature of 130-F. (54.5-C.).

.
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APPENDIX A Continued
TOXIC MATERIAL is a material which produces a lethal dose or a lethal concentration within any of the
following categories:
 A chemical or substance that has a median lethal dose (LD50) of more than 50 milligrams per kilogram but
not more than 500 milligrams per kilogram of body weight when administered orally to albino rats weighing
between 200 and 300 grams each.
 A chemical or substance that has a median lethal dose (LD5D) of more than 200 milligrams per kilogram
but not more than 1,000 milligrams per kilogram of body weight when administered by continuous contact
for 24 hours, or less if death occurs within 24 hours, with the bare skin of albino rabbits weighing between 2
and 3 kilograms each.
 A chemical or substance that has a median lethal concentration (LC50) in air more than 200 parts per
million but not more than 2,000 parts per million by volume of gas or vapor, or more than two milligrams per
liter but not more than 20 milligrams per liter of mist, fume or dust, when administered by continuous
inhalation for one hour, or less if death occurs within one hour, to albino rats weighing between 200 and
300 grams each.
WATER-REACTIVE MATERIAL is material which explodes; violently reacts; produces flammable, toxic or
other hazardous gases; or evolves enough heat to cause self-ignition or ignition of nearby combustibles upon
exposure to water or moisture. Water Reactive Materials can be split into the following classes:
 Class 1 – Reacts with water with some release of energy, but not violently.
 Class 2 – Reacts violently with water or has the ability to boil water. Produces flammable, toxic or other
hazardous gases, or evolves enough heat to cause autoignition or ignition of combustibles upon exposure
to water.
 Class 3 – Reacts explosively with water without requiring heat or confinement.
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