Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) Name : ___________________________ Knowledge and Skills Mark Equivalent Grade Knowledge and Understanding / 35 Thinking and Investigation / 35 Communication / 15 Application / 15 Total Grade / 100 Read through the entire test before beginning. There are 10 pages in total, including the Periodic Table and the electron orbitals chart provided at the end of the test. Answer the questions in the spaces provided. If needed, you can use the back of the page, but let me know. I wish you all a successful test! 1 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) Knowledge and Understanding (35%) 1. Multiple Choice Questions a. Which of these elements is the most electronegative? i. Germanium ii. Indium iii. Oxygen iv. Phosphorous b. Nonmetals have i. Small numbers of electrons in the valence shell and form positive ions. ii. Large numbers of electrons in the valence shell and form negative ions. iii. Large numbers of electrons in the valence shell and do not form ions. iv. Large numbers of electrons in the valence shell and form positive ions. c. The ionization energy of an element i. is the energy needed to move an electron from the first energy level to the second one ii. is the energy generated by its nucleus iii. cannot be calculated or observed iv. is the energy needed to detach an electron from an elemental atom 2 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) Multiple Choice Questions (continued) d. The Pauli exclusion principle states that i. any atoms with a free s orbital can form bonds ii. no two atoms can occupy the same orbital unless their spins are different iii. two atoms sharing an orbital are matched exactly iv. atoms of the same configuration do not change e. What is the correct order of the atomic radius in the elements below? i. Cl > Al > Mg ii. Mg > Al > Cl iii. Al < Mg < Cl iv. Mg < Al < Cl v. Mg < Al > Cl 2. For the following subshells give the values of the quantum numbers (n, l and ml) and the number of orbitals in each subshell: a. 4p ___________________________________ b. 3d ___________________________________ c. 3s ___________________________________ d. 5f ___________________________________ e. 2p ___________________________________ 3 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) 3. Write the ground-state electron configuration for the following elements: a. Lithium: ________________________________ b. Copper: ________________________________ c. Bromine: ________________________________ d. Phosphorus: ________________________________ e. Vanadium: 4. ________________________________ Explain, in terms of electron configuration, why the decrease in atomic radius from Ca to Ga is greater than that from Mg to Al. _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ 4 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) 5. Classify the following bonds as ionic, polar covalent or non-polar covalent and draw the corresponding Lewis Diagram: 6. a. HCl _______________________________________ b. KF _______________________________________ c. the CC bond in H3CCH3 _______________________________________ d. O2 _______________________________________ e. MgBr2 _______________________________________ Use the VSEPR model to predict the geometry of the following molecules and ions: a. AsH3 _______________________________________ b. OF2 _______________________________________ c. AlCl4- _______________________________________ d. BrF5 _______________________________________ e. BF3 _______________________________________ 5 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) Thinking and Investigation (35%) 7. Imagine that scientists have discovered a new element X, whose atomic number is 120. Write the new element’s electron configuration (full) and indicate its n and l values for the outermost electron. ________________________________________________________________ _________________________________________________________________ 8. + Why is the ionization energy required to remove an outer electron from Na so much greater than that needed to remove the outer electron from Na? (HINT: if you’re stuck, draw the orbitals of Na and Na+ to help you visualize). _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ 9. Determine which is most polar and explain your reason for making this choice: nitrogen trifluoride OR phosphorus trifluoride. _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ 6 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) 10. In which liquid, HF(l) or H2O(l), will the hydrogen bonds be strongest? Based on this prediction, which of the two liquids will have the highest boiling point? _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ Application (15%) Answer one of the two following questions. 11. How do you think astronomers utilise the fact that every element has its own distinctive electron configuration? _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ 7 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) 12. Frozen water is less dense than liquid water. What would be the effect on Canadian lifestyle if it were not so? _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ _________________________________________________________________ 8 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) 9 of 10 Chemistry Grade 12, SCH 4U: Structure and Properties of Matter Test (Summative Evaluation) 10 of 10