SUPPLEMENTARY MATERIAL DUST EMISSION MODELING FOR THE WESTERN BORDER REGION OF MEXICO AND THE UNITED STATES Johana M. Carmona,1 Ana Y. Vanoye,1 Fabian Lozano,2 and Alberto Mendoza1. 1 Department of Chemical Engineering, 2 Center for Environmental Quality Content: 1. Emission versus ambient air concentrations at one location Figure S1. Map of Higley Air Quality site (ID: 04-013-4006) located at Gilbert, AZ urban center. Figure S2. Predicted PM10 emission rates (base case scenario) versus observed PM10 concentrations during the entire episode at Higley Air Quality site, AZ. Figure S3. Predicted versus observed PM10 concentration in the base case scenario and sensitivity tests for January 8th, 2006 at Higley Air Quality site, AZ. 2. Dataset references 3. Acknowledgment 1. Emission versus ambient air concentrations at one location The Higley Air Quality site (ID: 04-013-4006) was selected for this analysis. The site represents both urban and rural emissions in a semi arid region. The Higley station is located in Gilbert, AZ (33º 18' 38.664" N -111º 43' 21.179" W) in the Maricopa county, southeast of Phoenix, within the Phoenix metropolitan area (Figure S1). Figure S1. Map of Higley Air Quality site (ID: 04-013-4006) located at Gilbert, AZ urban center. The simulated hourly dust emissions (g km−2) were compared against surface hourly PM10 concentrations (µg m−3) data reported by the U.S. Environmental Protection Agency (EPA) (see section 4 in this SM document for data references). Simulated dust emissions were extracted from one grid cell of the modeling domain, with the same location of the monitoring EPA site in Gilbert, AZ (33º 18' 38.664" N -111º 43' 21.179" W). As a result of this comparison, a correlation (r2) of 48% was obtained for the entire modeling period using the base case results. p-values suggest that the observed concentration could be a predictor of the simulated emissions in this location; however, other issues including variation in aerosol type, sources contributions and transport dynamics must be completely understood before establishing a relationship between emissions and concentrations. Additionally, the time series of PM10 concentrations along with time series of simulated PM10 emissions were analyzed. Figure S2 illustrates a similar temporal behavior between predicted emissions and observed concentration. Results indicate that, considering the 4-km domain, the model was able to replicate with reasonable accuracy events of high PM10 concentrations. In some periods, few or no dust emissions were predicted; this could mean that the threshold wind velocities necessary to re-suspend dust were not reached and the dust model was not able to reproduce the events. Figure S2. Predicted PM10 emission rates (base case scenario) versus observed PM10 concentrations during the entire episode at Higley Air Quality site, AZ. The wind erosion model was subject to three sensitivity tests based on perturbation of the input surface parameters: soil density (SD), plastic pressure (PP), Leaf Area Index (LAI) and fraction of vegetation cover. The sensitivity analysis was performed following a “brute-force” approach: the wind erosion model was run changing one parameter of interest at a time. In the base case scenario, the statistical majority value contained in each computational cell was selected for estimating LAI and FPAR. In addition, the average value was selected in order to test the sensitivity of the estimated emissions to this choice. Satellite data were used to estimate this values (see references) In the base case soil density and plastic pressure were given the values of 1,000 kg m−3 and 20,250 N m−2, respectively. In the sensitivity analysis were tested with 1,700 kg m3 and 50,000 N m2, respectively. These last values were the highest values reported in NRCS (2005) for the soil types found in the United States domain (see section 2 in this SM document for data references). We then compared the simulated dust emissions (g km−2) on hourly basis, with surface hourly PM10 concentrations (µg m−3) data. As a result of this comparison, a correlation (r2) of 78% was obtained for January 8th in the base case. Additionally, the time series of PM10 concentrations along with time series of simulated PM10 emissions were plotted for the base case and sensibility scenarios. Figure S3 illustrates a similar temporal behavior between predicted emissions and observed concentration in all scenarios. When dust emissions increased, usually PM concentration increases. Overall, we concluded that the model output was more sensitive to changes in soil parameters (soil density and plastic pressure) than to changes in land surface data (Leaf Area Index and Fraction of Vegetation Cover). However, it can be observed in Figure S3 that for the specific site selected, the peak emission rate varied the least under the soil density case. Variable PM10 Base Case Density Pressure LAI/FVEG 100 90 80 70 300 60 50 200 40 30 100 20 PM10 predicted (g km-2) PM10 observed (ug m-3) 400 10 0 0 2 4 6 8 10 12 14 Hour 16 18 20 22 24 Figure S3. Predicted versus observed PM10 concentration in the base case scenario and sensitivity tests for January 8th, 2006 at Higley Air Quality site, AZ. 2. Dataset references Pedological map for Mexico side is available at http://www.conabio.gob.mx/informacion/gis/ Soil map and Database for US side are avaliable.at http://datagateway.nrcs.usda.gov/ Raw data (sample data as reported) are available at http://aqsdr1.epa.gov/aqsweb/aqstmp/airdata/download_files.html#Raw Satellite MOD15A2 products used for estimating Leaf Area Index and vegetation coverage were: MCD15A2.A2006001.h08v05.005.2008091210144.hdf MCD15A2.A2006001.h08v06.005.2008091211621.hdf MCD15A2.A2006001.h09v05.005.2008091211540.hdf 3. Acknowledgment Authors would like to thank to the MODIS Land Science Team and the EPA team for their contributions to the production data sets using in this research.