Weathering Notes Weathering, erosion, and deposition act together in a cycle that wears down and builds up Earth’s surface. The weathering, erosion, and deposition that geologists observe today also shaped Earth’s surface millions of years ago. There are two types of weathering: 1. Mechanical weathering 2. Chemical weathering. (Both types of weathering act slowly, but over time they break down even the biggest, hardest rocks.) Weathering is the result of the physical and chemical alteration of rock and mineral material; the resultant products might or might not be transported. Mechanical Weathering (physical weathering): the type of weathering in which rock is physically broken into smaller pieces. These smaller pieces have the same composition as the rock they came from. *Causes of mechanical weathering include: freezing and thawing, Exfoliation-release of pressure, plant growth, actions of animals, abrasion, and thermal expansion 1. Freezing: Ice Wedging; Frost Wedging: water seeps into cracks in rocks and then freezes when temperature drops. Water expands when it freezes. Ice therefore acts like a wedge that forces things apart. Wedges of ice in rocks widen and deepen cracks. When the ice melts, the water seeps deeper into the cracks. With repeated freezing and thawing, the cracks slowly expand until pieces of rock break off. 2. Abrasion: refers to the grinding away of rock by rock particles carried by water, ice, wind, or gravity (ex. River rocks rounded because they have been tumbled in the riverbed by fast-moving water for many years; rocks shaped by blowing sand (ventifacts); rocks grind against each other in rock slides, which creates smaller and smaller rock fragments. 3. Exfoliation: As overlying rock is removed by uplift and erosion, the pressure on the rock is reduced. As the pressure is reduced, the rock expands in volume and long, curved cracks develop parallel to the rocks surface. In this way, an outcrop “sheds” layers of rock. Exfoliation can often be observed in granite outcrops. (Granite forms underground, so it forms under a great deal of pressure from the rock above. A granite pluton 15 km underground forms at 5, 000 times the pressure at Earth’s surface. As the granite is pushed toward the surface and the overlying rock is weathered away, the pressure on the rock is reduced and the granite exfoliates.) 4. Thermal stress weathering: results from the expansion and contraction of rock, caused by temperature changes. For example, heating of rocks by sunlight or fires can cause expansion of their constituent minerals. As some minerals expand more than others, temperature changes set up differential stresses that eventually cause the rock to crack apart. Because the outer surface of a rock is often warmer or colder than the more protected inner portions, some rocks may weather by exfoliation- peeling away of outer layers. (desertslarge temperature changes- hot in the day and cold at night; forest fires- intense localized heat can rapidly expand a boulder 5. Plant growth: Plants send their roots into existing cracks in rocks. As the plant grows, the force of the expanding root becomes so strong that the crack widens. Eventually, the entire rock can split apart. (ex. Grass and roots in the cracks of sidewalks and streets) 6. Actions of animals: animals burrow through the soil and move soil particles around. This exposes fresh surfaces to continued weathering. Any animal that burrows can cause mechanical weathering. Ants, worms, mice, coyotes, and rabbits are just some of the animals that contribute to weathering. Chemical Weathering: the process that breaks down rock as a result of chemical reactions. *Causes of chemical weathering include: dissolution, hydrolysis, and oxidation, living organisms, carbon dioxide 1. Dissolution: soluble rocks and minerals dissolve in acidic waters (acid precipitation): Rain, sleet, or snow that contain a high concentration of acids. Over the past 150 years, people have been burning large amounts of coal, oil, and gas for energy. Burning these fuels can pollute the air with sulfur, carbon, and nitrogen compounds. 2. 3. 4. 5. Such compounds react chemically with the water vapor in clouds, forming acids. These acids mix with raindrops and fall as acid rain. Acid rain causes very rapid chemical weathering of rock. Small amounts of sulfuric and nitric acids from from natural sources, such as volcanoes, can make precipitation acidic. Hydrolysis: (hydro- means “water” and lysis- means “separation”) usually means the cleavage of chemical bonds by the addition of water. (ex. feldspars altered to clay; groundwater comes in contact with limestone, dissolving forms of limestone forms karst features, such as caverns.) Oxidation: a chemical reaction in which an element, such as iron, combines with oxygen to form an oxide. This common form of chemical weathering is what causes rust. (The oxygen in the ari is reacting with the iron in old cars, aluminum cans, or even a bike creating the rusting of iron.) Biological Weathering: living organisms, such as a plant’s roots growing, produce weak acids that slowly dissolve rock around the roots. Lichens- plantlike organisms that grow on rocks- also produce weak acids that chemically weather rock. Carbon Dioxide: another gas found in air, carbon dioxide, also causes chemical weathering; carbon dioxide dissolves in rainwater and in water that sinks through air pockets in the soil. The result is a weak acid called carbonic acid. Carbonic acid easily weathers rocks such as marble and limestone. Rate of Weathering: The rate at which a rock weathers. * The most important factors that determine the rate at which weathering occurs are the type of rock and the climate. Type of Rock:(Differential Weathering): The minerals that make up the rock determine how fast it weathers. Rock made of minerals that do not dissolve easily in water weathers slowly. Rock made of minerals that dissolve easily in water weathers faster. Some rock weathers more easily because it is permeable. Permeable means that a material is full of tiny, connected air spaces that allow water to seep through it. Permeable rock weathers chemically at a fast rate. As water seeps through he spaces in the rock, it dissolves and removes material broken down by weathering. Also, the more surface area that is exposed to weathering, the faster the rock will be worn down. A large rock has a large surface area, but a large rock also has a large volume. Because of the large rock’s volume, the large rock will take a long time to wear down. If a large rock is broken down into smaller fragments, weathering of the rock happens much more quickly. The rate of weathering increases because a smaller rock has more surface area to volume than a larger rock has. So, more of a smaller rock is exposed to the weathering process. Climate: Climate refers to the average weather conditions in an area. Both chemical and mechanical weathering occur faster in wet climates. Rainfall provides the water needed for chemical changes as well as for freezing and thawing. Chemical reactions occur faster at higher temperatures. That is why chemical weathering occurs more quickly where the climate is both hot and wet. (granite is a very hard rock and weathers very slowly in cool climates and is often used as building stone, but in hot and wet climates granite weathers more rapidly and eventually crumbles apart.) Elevation also effects the rate of weathering because rocks at peaks of a mountain weather faster because they are exposed to more ice, rain, and wind.