Honors Chemistry Chapter 19 – Acids and Bases Review Answers Name: _________________ 1. In the list below, circle the properties of acids and box the properties of bases. Sour taste Feel slippery Contains hydroxide ions Turns litmus blue Reacts with metals to form H2 Turns litmus red Bitter taste Contains hydrogen ions Corrosive 2. Complete the chart below: Acid-Base Definitions Type Arrhenius Acid Definition Donates an H+ ion in solution Base Definition Donates an OH- ion in solution Bronsted-Lowry Donates an H+ ion Accepts an H+ ion Lewis Accepts an electron pair Donates an electron pair 3. What term(s) describe a substance that can act as an acid or a base? Amphoteric or amphiprotic 4. Neutralization reactions always produce a SALT and WATER 5. If the [H+] is greater than the [OH-], the solution is acidic basic neutral 6. If the [OH-] is greater than the [H+], the solution is acidic basic neutral 7. If the [H+] is equal to the [OH-], the solution is acidic basic neutral 8. If the pH is 7, the solution is acidic basic neutral 9. If the pH is greater than 7, the solution is acidic basic neutral 10. If the pH is less than 7, the solution is acidic basic neutral 11. How many moles of lithium hydroxide are required to neutralize 19.2 grams of chloric acid? LiOH + HClO3 LiCl + H2O (19.2 g HClO3) x (1 mol HClO3/84 g HClO3) x (1 mol LiOH/1 mol HClO3) = 0.228 mol LiOH 12. How many grams of calcium hydroxide are required to neutralize 132.4 grams of nitric acid? Ca(OH)2 + 2 HNO3 Ca(NO3)2 + 2 H2O (132.4 g HNO3) x (1 mol HNO3/63 g HNO3) x (1 mol Ca(OH)2/2 mol HNO3) x (74 g Ca(OH)2/1 mol Ca(OH)2) = 77.76 g Ca(OH)2 Honors Chemistry Chapter 19 – Acids and Bases Review Answers Name: _________________ 13. How many moles of hydrochloric acid are required to neutralize 12.2 moles of aluminum hydroxide? 3 HCl + Al(OH)3 AlCl3 + 3 H2O (12.2 mol Al(OH)3) x (3 mol HCl/1 mol Al(OH)3) = 36.6 mol HCl 14. What is the molarity of H3PO3 if 23.1 mL is completely neutralized by 98.2 mL of 0.21 M Ba(OH)2? 2 H3PO3 + 3 Ba(OH)2 Ba3(PO3)2 + 3 H2O 0.21 M Ba(OH)2 = moles / (98.2 mL/1000) so 0.020 moles Ba(OH)2 (0.020 mol Ba(OH)2) x (2 moles H3PO3/3 moles Ba(OH)2) = 0.0137 mol H3PO3 Molarity = (0.0137 moles H3PO3)/(23.1 mL/1000) = 0.595 M H3PO3 15. What is the molarity of HCl if 45.3 mL is completely neutralized by 72.1 mL of 1.78 M NaOH? HCl + NaOH NaCl + H2O 1.78 M NaOH = moles / (72.1 mL/1000) so 0.128 moles NaOH (0.128 mol NaOH) x (1 mole HCl/1 mole NaOH) = 0.128 mol HCl Molarity = 0.128 moles / (45.3 mL/1000) = 2.83 M HCl 16. How many mL of 0.32 M HClO3 are required to neutralize 4.21 L of 0.79 M strontium hydroxide? 2 HClO3 + Sr(OH)2 Sr(ClO3) + 2 H2O 0.79 M Sr(OH)2 = moles / (4.21 L) so 3.318 moles Sr(OH)2 (3.318 moles Sr(OH)2) x (2 mole HClO3/1 mole Sr(OH)2) = 6.636 moles HClO3 0.32 M HClO3 = 6.636 moles / L so L = 20.73 L x 1000 = 20,730 mL HClO3 17. A 2.34 L solution of HCN is completely neutralized by 1.78 L of 1.03 M KOH. What is the concentration of the HCN solution? HCN + KOH KCN + H2O 1.03 M KOH = moles / (1.78 L) so 1.8334 moles KOH (1.8334 mol KOH) x (1 mole HCN/1 mole KOH) = 1.8334 mol HCl Molarity = 1.8334 moles / 2.34 L) = 0.78 M HCN 18. A 52.6 mL solution of H2CO3 is completely neutralized by 24.5 mL of 1.28 M NaOH. What is the concentration of the H2CO3 solution? H2CO3 + 2 NaOH Na2CO3 + 2 H2O 1.28 M NaOH = moles / (24.5 mL/1000) so 0.03136 moles NaOH (0.03136 mol NaOH) x (1 mole H2CO3/2 mole NaOH) = 0.0157 mol H2CO3 Molarity = 0.0157 moles / 52.6 mL/1000) = 0.298 M H2CO3 Honors Chemistry Chapter 19 – Acids and Bases Review Answers Name: _________________ 19. Complete the chart below: [H+] 0.079 M [OH-] 1.25 X 10-13 M pH 1.10 pOH 12.9 Acidic, Basic, or Neutral Acidic 0.0049 M 2.04 x 10-12 M 2.31 11.69 Acidic 7.24 x 10-5 M 1.38 x 10-10 M 4.14 9.86 Acidic 1.12 x 10-12 M 0.009 M 11.95 2.05 Basic 7.8 x 10-11 M 1.26 x 10-4 M 10.10 3.9 Basic 1.0 x 10-7 M 1.0 x 10-7 M 7 7 Neutral 1.62 x 10-11 M 6.2 x 10-4 M 10.79 3.21 Basic 1.34 x 10-14 M 0.7413 M 13.87 0.13 Basic