Activity: Reverse Engineering of Diapers Summary Our goal is to discover why these disposable diapers work so well and what makes them different from the old cloth diapers. This is also a great lesson in the concept of reverse engineering, which is used by virtually every manufacturing company in the world, and especially the “big two” diaper manufacturers Kimberly-Clark and Proctor & Gamble. Engineering Connection Diapers continue to become thinner and more absorbent. During the 1990s a modification of the SAP was developed. It uses a surface cross-linker to reduce the "gel block" problem: If the absorbent is saturated with a liquid, it prevents the liquid from moving. Independent inventors also are continuing to modify the diaper. Marlene Sandberg of Stockholm has constructed a diaper that is 70 percent biodegradable. She uses cornstarch in the preparation of the outer layer of the diaper. This allows her to reduce the amount of polyacrylate used by designing channels in the fill material that help disperse the urine. Other workers in the field dispute that the diaper is 70 percent biodegradable: They say the diapers will not degrade that much in a landfill—their ultimate destination. Contents 1. 2. 3. 4. 5. 6. 7. 8. Learning Objectives Materials Introduction/Motivation Vocabulary Attachments Procedure Assessment Extensions Grade Level: K-12 Time Required: 30 minutes Expendable Cost Per Group: US$ 0 Group Size: 2 Keywords: polymer, Reverse Engineering, SAP Reviews: Read Reviews | Be the First to Write a Review Related Curriculum: Chemistry Educational Standards: Oregon Science Based on observations and science principles, identify questions that can be tested, design an experiment or investigation, and identify appropriate tools. Collect and record multiple observations while conducting investigations or experiments to test a scientific question or hypothesis. (5) Using science principles describe a solution to a need or problem given criteria and constraints.(5) Explain that inventions may lead to other inventions and once an invention exists, people may think of novel ways of using it. (5) Describe physical and chemical properties of matter and how they can be measured. (6) Based on observation and scientific principals, propose questions or hypotheses that can be examined through scientific investigation. Design and conduct an investigation that uses appropriate tools and techniques to collect relevant data. (6-8) Define a problem that addresses a need and identify science principals that may be related to possible solutions. (6-8) Describe examples of how engineers have created inventions that address human needs and aspirations. (6) Explain how new scientific knowledge can be used to develop new technologies and how new technologies can be used to generate new scientific knowledge. (7) Explain how scientific explanations and theories evolve as new information becomes available. (8) Evaluate a proposed design solution in terms of design and performance criteria, constraints, priorities, and trade-offs. Identify possible design improvements. (8) Explain how creating a new technology requires considering societal goals, costs, priorities, and trade-offs. (8) Describe how different types and strengths of bonds affect the physical and chemical properties of compounds. (9-12) Explain how chemical reactions result from the making and breaking of bonds in a process that absorbs or releases energy. Explain how the rate of a chemical reaction is affected by temperature, pressure, and concentration. (9-12) Explain how energy and chemical elements pass through systems. Describe how chemical elements are combined and recombined in different ways as they cycle through the various levels of organization in biological systems. (9-12) Explain how technological problems and advances create a demand for new scientific knowledge and how new knowledge enables the creation of new technologies. (9-12) Describe how new technologies enable new lines of scientific inquiry and are largely responsible for changes in how people live and work. (9-12) Create and test or otherwise analyze at least one of the more promising solutions. Collect and process relevant data. Incorporate modifications based on data from testing or other analysis. (9-12) Identify the strengths and weaknesses or a proposed solution to a problem, and describe how it is better than alternative designs. Identify further engineering that might be done to refine the recommendations. (912) Learning Objectives After this activity, students should be able to: List reasons disposable diapers sell so well Describe reverse engineering Describe other uses of SAP Materials List Each student needs: Cotton squares (1” x 1”) typically used for face cleansing. One disposable diaper (per group of four people) One Ziploc bag, gallon size and Scissors Two small containers, like Petri dish halves One syringe, pipette or graduated cylinder (10 ml size) Water (approx. 200 mL per group) and Salt Water (approx. 50 ml per group) Introduction/Motivation Over 20 billion disposable diapers are sold and used each year. This is enough diapers to cover a football field 3 miles deep. Within the last 10 years the average age to “potty train” children has increased from 2 years to 3 years old. There is a reason that so many homes use so many disposable diapers; they work so well! But where do they all go? To your local landfill…which just keeps getting bigger and bigger each day! This activity is an example of a common engineering practice called “reverse engineering”. By disassembling a product and making a schematic diagram with careful notes, engineers at company A can determine the design of a product by company B. For example, if you worked for Proctor and Gamble (manufacturers of Pampers diapers) you could cut into a Huggies diaper (manufactured by Kimberly-Clark) and see how engineers at Kimberly-Clark have designed their product, which just happens to be your biggest competitor. Vocabulary/Definitions: Polymer: a long chain of repeating molecules. There are many common polymers derived from algae, such a carrageen, xanthan gum, and gelann gum. SAP: Super-Absorbent Polymer Reverse Engineering: Making a diagram of a product by disassembling it and taking careful notes Attachments Disposable Diaper Handout Diaper Evolution Disposable Diaper Chemistry Example Data Procedure Disposable Diaper Reverse Engineering (groups of 2) 1. Examine your disposable diaper. Think about form and function, why and how does it work? Cut the diaper in half down its length and give one-half of the diaper for each group of two people. As you examine your diaper, create a cross-sectional schematic diagram of the important parts (see Fig.1 as a basic example). Make sure to note ALL the parts. Does the cotton feel like normal cotton? INSIDE Figure 1 Schematic crosssectional OUTSIDE diagram of 2. Remove the cotton batting from the diaper and place ait baby in the plastic bag. 3. Cut (or break-off) an approx. 1” x 1” square piece anddiaper put it(very aside for later basic). use. 4. Break-up the batting in the bag and separate the grainy crystals from the cotton. After breaking up the cotton some white crystals (they look like salt granules) will collect in the bottom of the bag. These are the “white gold”, Super Absorbant Polymer (SAP). Absorbancy 1. Obtain a “cotton square” from the teacher. This is the type of cotton typically used for cleansing your face. Place the cotton square in a petrie dish and add 10ml of DIW. Place the 1” square you recovered from your diaper in a petrie dish and add 10ml of DIW. This is an example of the difference between a cloth diaper (physical absorbancy) and the disposable diaper with SAP (chemical absorbancy). Make some observations, note the differences and arrive at an explanation for the difference between physical and chemical absorbancy. 2. Weigh out approximately 0.25 grams of your recovered SAP into a petrie dish and record the exact mass. These crystals are called Super Absorbent Polymer (SAP). SAP is a dehydrated particle (powder) that will rapidly pick up water. 3. In small increments, roughly 5 mL, add deionized water (DIW) to the SAP in the plastic dish. Note how the crystals rapidly absorb the water. Allow 30-60 sec. for the SAP to absorb the water. Continue adding water in small increments until the SAP appears to be “saturated”. The best test for test is what we call the “snail trail test”. Slowly tilt the petrie dish and watch to see if the SAP slides and leaves a slight liquid trail (like a snail moving) on the plastic dish. Once you see the “snail trail” wait about 60 sec. and then repeat the test. If it is gone, add a bit more water. When you see the “snail trail” repeatedly, you are done. This is a subjective determination, so have both partners agree when the experiment is complete! Assessment Post-Activity Assessment Informal discussion: After completing this experiment, and seeing the amazing properties of the SAP, it is clear why kids want to be in diapers longer! They stay dry and end up with a nice gel pad for softer landings! SAP is not only used in diapers. Today SAP is used in a wide range of applications, such as: clean-up of all types of spills, including oil spills; as a fire retardant squirted on the roofs of homes to prevent destruction in wildfires; as artificial snow in indoor ski hills, predominantly in Japan; in garments (hats and bandanas) that can be soaked and worn to prevent overheating; and in planting soil to keep overhead plants from dripping or to decrease the frequency of watering; to prevent erosion of topsoil in some of the worlds’ leading food producing areas. Activity Extensions Absorbancy Extensions for high school/college 1. Record the volume of water that was absorbed by your SAP. 2. Calculate the Absorbancy Ratio (AR) = ml DIW/g SAP 3. Repeat steps 2-5 using salt water with 0.5 g SAP. 4. Calculate AR = ml Salt Water/g SAP. 5. REPEAT steps 2-5 for the commercial ChemSol SAP supplied by your teacher 6. REPORT your DATA for DIW and SALT WATER to the teacher. This data will be later shared with the class for an analysis of the average absorbancy ratio (AR) and experimental error (standard deviation). Owner Dr. Skip Rochefort, Chemical Engineering Department, Oregon State University Last modified: 8/18/09