ELECTRONIC SUPPLEMENTARY MATERIAL Table S1 Demographic and water use data for the City of Atlanta # of residents or employees (ARC 2010) Water use, m3/(capita·yr) (AECOM 2009) Outdoor water use, m3/(capita·yr) (AECOM 2009) Single-family Multi-family Employee Single-family Multi-family Employee Single-family Multi-family Employee 276,000 144,000 378,000 109 101 106 38.7 13.8 23.5 Table S2 Plant capacity and average daily flow for drinking water treatment Water Treatment Plant (WTP) Hemphill Chattahoochee Atlanta-Fulton County Total Plant Capacity (AECOM 2009) 517 246 341 50% 931 Average Daily Flow (the Department of Watershed provided from the City of Atlanta) 152 144 83 379 Unit 103 m3/day Fig. S1 Chattahoochee water treatment plant (WTP) process, which was used for our WTP analysis (Lin 2003) Table S3 Plant capacity and average daily flow for wastewater treatment Wastewater Reclamation Center R.M. Clayton Utoy Creek South River Total Plant Capacity (AECOM 2009) 462 167 204 833 Average Daily Flow (provided from the City of Atlanta) 284 91 95 469 Unit 103 m3/day Fig. S1. Utoy Creek wastewater reclamation treatment (WRT) process, which was used for our WCT analysis (BNR: biological nutrient removal) (Mines et al. 2004; Mines et al. 2006) Table S4 Infrastructure scale and LCI datasets Infrastructure Capacity Data source Water supply system Pump station 1.67E+06 m3/day Water treatment plant 931 m3/day Booster pump station 5.60E+05 m3/day Storage tank 1.57E+05 m3 4,340 km Distribution pipeline (AECOM 2009; DP&CD 2010; Lin 2003; The City of Atlanta 2005; The City of Atlanta 2008; The City of Atlanta 2009) Wastewater collection and treatment system Wastewater collection pipeline 3,420 km Pump station 2.29E+05 m3/day Wastewater treatment plant 8.33E+05 m3/day (AECOM 2009; DP&CD 2010; Mines et al. 2004; Mines et al. 2006; The City of Atlanta 2005; The City of Atlanta 2008; The City of Atlanta 2009) Stormwater collection system Stormwater collection pipeline 3,420 km (The City of Atlanta 2005; The City of Atlanta 2008; The City of Atlanta 2009) Dataset name (CH: Switzerland, RER: Europe) Reference flow: 1.15 m3 pump station/p/CH/I; 1p = 644,546 m3/yr water works/p/CH/I; 1p = 644,546 m3/yr pump station/p/CH/I; 1p = 644,546 m3/yr water storage/p/CH/I; 1p = 2,500 m3 water supply network/km/CH/I Reference flow: 0.77 m3 sewer grid, class 1/km/CH/I pump station/p/CH/I; 1p = 644,546 m3/yr wastewater treatment plant, class 1/p/CH/I; 1p = 47,100,000 m3/yr Reference flow: 1.25 m3 sewer grid, class 1/km/CH/I *p: one unit of infrastructure that has a capacity defined in the column 5 (dataset name) Per FU, 1 m3 water distributed to point-of-use 1.12E-07 p* 6.27E-08 p 3.77E-08 p 7.48E-09 p 5.16E-07 km 2.19E-07 km 1.94E-08 p 9.70E-10 p 3.56E-07 km Calculation The capacities (column 2) were divided by the daily average flow rate of 379 103 m3/day (Table S1) and the life expectancy of 70 years. The capacity (column 2) was divided by the daily average flow rate of 469 103 m3/day (Table S1) and the lifespan of 70 years. The capacities (column 2) were divided by the daily average flow rate of 469 103 m3/day (Table S1) and the lifespan of 30 years. The distance (column 2) was divided by the annual stormwater runoff volume (2.24E+08 m3/yr) and the lifespan of 70 years. The runoff volume was determined for the sewer system area of 583 km2. Table S5 Materials, processes and direct emissions for system operation and LCI datasets Input Amount Data source Water supply system Aluminum sulfate 2,077,418 kg/yr Sodium hypochlorite 1,316,735 kg/yr Lime 1,017,804 kg/yr Phosphoric acid 110,977 kg/yr Hydrofluosilic acid 231,821 kg/yr Sludge sent to R.M. clayton WRC 586 kg/yr Water for filtration bed backwashing 466 m3/each Natural gas 4,414,266 MJ/yr Electricity 74,048,70 0 kWh/yr Data provided from the Department of Watershed Management (CoA) for Chattahooch ee water treatment plant (144E+03 m3/day) Lin (2003) Georgia Power Dataset name (CH: Switzerland, RER: Europe) Reference flow: 1.15 m3 Aluminum sulfate, powder, at plant/RER U Sodium hypochlorite, 15% in H2O, at plant/RER U Lime, hydraulic, at plant/CH U Phosphoric acid, industrial grade, 85% in H2O, at plant/RER U Fluosilicic acid, 2% in H2O, at plant/US U Disposal, digester sludge, to municipal incineration/CH U Per FU, 1 m3 water distributed to pointof-use 4.55E-02 kg 2.88E-02 kg 2.23E-02 kg 2.43E-03 kg 5.07E-03 kg 1.28E-05 kg Tab water, at user/CH U 6.43E+00 kg Natural gas, at longdistance pipeline/RER U 9.66E-04 m3 * 6.15E-01 kWh Calculation The consumptions (column 2) were divided by the daily average flow rate of 144 103 m3/day for Chattahoochee WTP (Table S2). The water use (column 2) was divided by the treatment capacity of each filtration bed (20.8E+03 m3/day) and backwashing frequency (every 96 hrs) The energy consumption (column 2) was divided by the daily average flow rate of 379 103 m3/day (Table S2). Table S6 Materials, processes and direct emissions for system operation and LCI datasets (continued) Input Amount Data source Wastewater collection and treatment system Ferric Chloride 524,933 kg/yr (40%) Caustic soda (50%) 809,648 Magnesium hydroxide powder 63,565 l/yr Dewatering polymer 29,723 kg/yr Sludge disposal kg/yr 2,519,697 kg/yr Ash to brick 964,608 kg/yr Ash to landfill 318,596 kg/yr Electricity Natural gas CO2 emission from biogas combustion 136,177,852 91,938,667 42.5 kwh Data provided from the Department of Watershed Management (CoA) for Utoy Creek wastewater reclamation center MJ/yr Georgia Power g as carbon Hardy (2011) Dataset name (CH: Switzerland, RER: Europe) Reference flow: 0.77 m3 Iron (III) chloride, 40% in H2O, at plant/CH U Sodium hydroxide, 50% in H2O, production mix, at plant/RER U Sodium hydroxide, 50% (wt.) in H2O, production mix, at plant/RER U Aluminum sulfate Disposal, municipal solid waste, 22.9% water, to municipal incineration/CH U clay and soil, extracted for use Disposal, inert waste, 5% water, to inert material landfill/CH U * Natural gas, at longdistance pipeline/RER U Biogenic CO2 emission to air Per FU, 1 m3 of water distributed to pointof-use 1.22E-02 kg 1.88E-02 kg 5.13E-03 kg 6.89E-04 kg 5.84E-02 kg 2.24E-02 kg 7.39E-03 kg 6.13E-01 kWh 1.09E-02 3 1.2E-01 m kg as CO2 Calculation The consumptions (column 2) were divided by the daily average flow rate of 91E+03 m3/day (the Utoy Creek wastewater reclamation center). Specific gravity of magnesium hydroxide powder = 2.36 The energy consumption (column 2) was divided by daily average flow rate of 469 103 m3/day (Table S2) Carbon amount in 0.07785 Nm3/m3 wastewater (RM clayton WRC) = 3.47 mole/m3 TP, Total phosphorus emission mg/L 1.22E-04 kg as P Mines et al. to water as P Water pollutant (2004) discharge Mines et al. TN, Total nitrogen emission to (2006) 1.83 mg/L 1.41E-03 kg as N water as N * Electricity, hard Coal, at power plant/US U 67%; Electricity, natural gas, at power plant/US U 10%; Electricity, nuclear, at power plant/US U 21%; Electricity, hydropower, at power plant/FR U 2% 0.158 Table S7. Material transport and LCI datasets System Water supply system Material Supplier location or destination Truck, km Aluminum sulfate Sodium hypochlorite lime phosphoric acid Macon, GA Allied Ranger, GA Campobello, SC Augusta, GA 161 129 322 274 Hydrofluosilic acid Red Hill, NC 418 Sludge sent to RM Clayton WRC R.M clayton WRC Ferric Chloride, 40% Caustic soda, 50% Magnesium hydroxide Dewatering polymer Ash to brick Detroit, MI Savannah, GA Philadelphia, PA Waxhaw, NC Smyrna, GA Ash to landfill Buford, GA Train, km Data source - 16 - 32 418 24 451 16 1,175 1,448 - 88 - Chemical suppliers’ names were provided from CoA The sludge amount was provided form the CoA. Dataset name Transport, combination truck, average fuel mix/US Wastewater collection and treatment system Total 2.12E-03 - 2.06E-07 Total Chemical suppliers’ names were provided from the CoA The ash amounts were provided form the CoA. Per FU, 1 m3 of water distributed to point-of-use Truck, tkm Train, tkm 7.29E-03 3.70E-03 7.15E-03 6.62E-04 Transport, combination truck, average fuel mix/US or Transport, train, diesel powered/US 2.09E-02 3.98E-04 8.01E-03 2.36E-04 3.16E-04 3.66E-04 1.46E-02 1.41E-02 - 6.65E-04 - 9.99E-03 2.86E-02 Table S8. Pollutant concentrations of stormwater runoff (Horowitz 2009; Horowitz et al. 2008; USGS 2012) Water pollutant Phosphorus, water, unfiltered Nitrate, water, filtered Nitrite, water, filtered Ammonia plus organic nitrogen, water unfiltered Potassium, water, filtered Sodium, water, filtered Chloride, water, filtered Silica, water, filtered Sulfate, water, filtered Calcium, water, filtered Magnesium, water, filtered Aluminum, water, filtered Cadmium, water, filtered Chromium, water, filtered Copper, water, filtered Iron, water, filtered Lead, water, filtered Manganese, water, filtered Nickel, water, filtered Silver, water, filtered Zinc, water, filtered Barium, unfiltered Beryllium, unfiltered Cobalt, unfiltered Lithium, unfiltered Mercury, unfiltered Molybdenum, unfiltered Strontium, unfiltered Thallium, unfiltered Vanadium, unfiltered Antimony, unfiltered Arsenic, unfiltered Selenium, unfiltered Concentration 3.71E-01 6.78E-01 1.69E-02 1.53E+00 3.56E+00 6.48E+00 8.19E+00 4.19E+00 1.20E+01 1.05E+01 2.32E+00 1.37E-01 3.26E-05 3.74E-04 3.96E-03 3.08E-01 7.37E-04 5.06E-02 1.42E-03 1.21E-05 1.20E-02 1.18E-01 5.89E-04 5.49E-03 2.28E-06 2.44E-05 6.10E-04 1.67E-02 2.03E-02 2.44E-02 4.06E-03 1.66E-03 1.83E-04 Unit mg/l as P mg/l as N mg/l as N mg/l as N mg/l as K mg/l mg/l mg/l as Si mg/l Calculation Median values of water quality data monitored for rain events (monitoring station number: 02336360, 02336300, 02203655, 02203700, 02336526, and 02336728) Table S9 Data uncertainty of infrastructure System Water supply Wastewater collection and treatment Stormwater collection Infrastructure Pump station for water intake Water treatment plant Booster pump station Storage tank Distribution pipelines Pump station Sewer pipelines Wastewater reclamation centers Sewer pipelines Basic uncertainty Data quality indicators Data uncertainty 3.00 1, 1, 1, 1, 4, na 3.23 3.00 3.00 3.00 3.00 3.00 3.00 1, 1, 1, 1, 4, na 1, 1, 1, 1, 4, na 1, 1, 1, 1, 4, na 1, 1, 1, 1, 4, na 1, 1, 1, 1, 4, na 1, 1, 1, 1, 4, na 3.23 3.23 3.23 3.23 3.23 3.23 3.00 1, 1, 1, 1, 4, na 3.23 3.00 1, 1, 1, 1, 4, na 3.23 Table S10 Data uncertainty of materials, processes, direct emissions, and transportation for system operation System Input Basic uncertainty, GSD2* Water supply Wastewater collection and treatment 1.05 1.05 2, 3, 1, 1, 1, na 2, 3, 1, 1, 1, na 1.05 3, 3, 1, 1, 4, na 1.53 1.05 1.05 1.05 1.05 1.05 1.05 2, 3, 1, 1, 1, na 2, 3, 1, 1, 1, na 2, 3, 1, 1, 1, na 2, 3, 1, 1, 1, na 1, 1, 1, 1, 1, na 1, 1, 1, 1, 1, na 1.09 1.09 1.09 1.09 1.05 1.05 1.05 1, 3, 1, 1, 4, na 1.51 2.00 3, 3, 1, 1, 1, na - 1.05 1.05 1.05 1.05 1.05 1.05 2, 3, 1, 1, 1, na 2, 3, 1, 1, 1, na 2, 3, 1, 1, 4, na 2, 3, 1, 1, 4, na 1, 1, 1, 1, 1, na 1, 1, 1, 1, 1, na 2.02 Not applicable to input or output for nature 1.09 1.09 1.51 1.51 1.05 1.05 1.05 3, 3, 1, 1, 1, na 1.12 1.50 1, 1, 1, 2, 1, na 1.50 1.05 2, 3, 1, 1, 4, na 1.51 Not applicable to input or output for nature 1.09 2.02 2.02 Not applicable to input or output for nature 1.50 - Ash to brick Ash to landfill Truck transport Train transport Stormwater collection 1.05 2.00 2.00 Stormwater discharge Water pollutants Data uncertainty, GSD2 Not applicable to input or output for nature 1.09 1.09 Water intake Aluminum sulfate Sodium hypochlorite Water for filtration bed backwashing Lime phosphoric acid Hydrofluosilic acid Sodium hypochlorite Natural gas Electricity Sludge sent to clayton WRC Truck transport Wastewater effluent discharge Ferric Chloride (40%) Caustic soda (50%) Magnesium hydroxide Dewatering polymer Electricity Natural gas CO2 emission from combustion of sludge digestion gas Water pollutants (TP and TN) Sludge disposal Data quality indicators 2, 3, 1, 1, 1, na 3, 3, 1, 1, 1, na 3, 3, 1, 1, 1, na - 1.50 *GSD2: the square of geometric standard deviation 2, 1, 1, 1, 1, na Table S11 Uncertainty test result Impact category Ozone depletion Global warming Smog Acidification Eutrophication Carcinogenics Non carcinogenics Respiratory effects Ecotoxicity Fossil fuel depletion Mean 7.17E-07 8.12E-05 7.83E-05 1.16E-04 4.66E-04 5.72E-03 5.92E-04 4.16E-05 7.82E-04 1.63E-06 SD 1.46E-07 1.30E-05 1.60E-05 1.93E-05 3.75E-04 4.81E-03 1.37E-03 8.11E-06 3.08E-04 2.43E-06 CV 20.4% 16% 20.5% 16.7% 80.5% 84.1% 232% 19.5% 39.4% 149% 2.5% 4.92E-07 6.10E-05 5.67E-05 8.69E-05 2.69E-04 2.36E-03 3.27E-04 2.99E-05 5.96E-04 5.01E-07 97.5% 1.07E-06 1.12E-04 1.11E-04 1.60E-04 1.27E-03 1.36E-02 1.21E-03 6.16E-05 1.19E-03 5.77E-06 Table S12 Impact changes for ±10% of infrastructure construction, electricity consumption, and water pollutants in stormwater runoff Impact category Ozone depletion Global warming Smog Acidification Eutrophication Carcinogenic effects Non-carcinogenic effects Respiratory effects Ecotoxicity Infrastructure construction 3.0% 3.4% 2.4% 1.9% 0.5% 6.8% 3.5% 3.9% 2.6% Electricity consumption 3.8% 5.4% 4.9% 6.5% 3.9% 2.0% 2.1% 3.9% 1.0% Water pollutants in stormwater runoff 0.0% 0.0% 0.0% 0.0% 4.2% 0.0% 2.0% 0.0% 5.5% References AECOM (2009) Wastewater management plan. 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